JP2003080548A - Method for manufacturing resin molded products - Google Patents
Method for manufacturing resin molded productsInfo
- Publication number
- JP2003080548A JP2003080548A JP2001206060A JP2001206060A JP2003080548A JP 2003080548 A JP2003080548 A JP 2003080548A JP 2001206060 A JP2001206060 A JP 2001206060A JP 2001206060 A JP2001206060 A JP 2001206060A JP 2003080548 A JP2003080548 A JP 2003080548A
- Authority
- JP
- Japan
- Prior art keywords
- resin material
- molten resin
- resin molded
- impeller
- cavity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Injection Moulding Of Plastics Or The Like (AREA)
Abstract
(57)【要約】
【課題】 射出成形時の残留応力を可及的に抑制し得る
樹脂成形品の製造方法を提案する。
【解決手段】 溶融樹脂材17に流動性を促進する流動
性促進材を加え、これを金型10のキャビティ11内に
射出して樹脂成形品2,3を製造することで、溶融樹脂
材17はその高い流動性によって比較的低い射出圧力で
キャビティ11の隅々まで十分に充填され、形状寸法精
度の高い樹脂成形品2,3が得られるとともに、射出圧
力が低いことで樹脂成形品2,3の内部の残留応力が少
なく事後処理としてのアニール処理が不要となり、ある
いはその処理時間の短縮化が図られ、その結果、成形精
度の良好な樹脂成形品2,3をより安価に得ることがで
きる。
(57) [Problem] To provide a method for manufacturing a resin molded product capable of suppressing residual stress during injection molding as much as possible. SOLUTION: A fluidity promoting material for promoting fluidity is added to a molten resin material 17, and this is injected into a cavity 11 of a mold 10 to produce resin molded products 2 and 3, whereby the molten resin material 17 is produced. Is sufficiently filled into the corners of the cavity 11 with a relatively low injection pressure due to its high fluidity, so that the resin molded products 2 and 3 having high dimensional accuracy can be obtained. The residual stress inside 3 is small and annealing treatment as post-processing is not required or the processing time is shortened. As a result, resin molded products 2 and 3 having good molding accuracy can be obtained at lower cost. it can.
Description
【0001】[0001]
【発明の属する技術分野】本願発明は、射出成形による
樹脂成形品の製造方法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a resin molded product by injection molding.
【0002】[0002]
【従来の技術】従来より、多翼送風機に用いられる多翼
羽根車は、これを樹脂材の射出成形によって製造するの
が一般的である。2. Description of the Related Art Conventionally, a multiblade impeller used for a multiblade fan is generally manufactured by injection molding a resin material.
【0003】即ち、多翼送風機に用いられる多翼羽根車
は、図2に示すように、軸長の長いロータ状の外観形態
をもち、これをその軸心回りで回転させることで送風作
用を行うようになっている。この多翼羽根車1は、通常
は、図3に示すように、支軸をもつ円板状の端面板6に
その周方向に所定間隔で多数の翼5,5,・・を平行に
立設した形態をもつ第1多翼羽根車構成体2と、円環状
の端面板7にその周方向に所定間隔で多数の翼5,5,
・・を平行に立設した形態をもつ複数個の第2多翼羽根
車構成体3,3,・・と、支軸を備えた円板体でなる端
部材4とを、それぞれ個別に製作し、これらを順次軸方
向に列設し且つこれら相互間を接合固定してこれを一体
化することで得られる。That is, a multiblade impeller used in a multiblade blower has a rotor-like appearance with a long axial length as shown in FIG. I am supposed to do it. As shown in FIG. 3, this multi-blade impeller 1 normally has a large number of blades 5, 5, ... Standing parallel to a disk-shaped end plate 6 having a support shaft at predetermined intervals in the circumferential direction. The first multi-blade impeller assembly 2 having the installed form, and a large number of blades 5, 5, on the annular end face plate 7 at predetermined intervals in the circumferential direction.
.. A plurality of second multi-blade impeller constituents 3, 3, ... having a configuration in which they are erected in parallel and an end member 4 made of a disk body having a support shaft are individually manufactured. Then, they are obtained by sequentially arranging them in the axial direction and joining and fixing them to each other to integrate them.
【0004】ところで、上記各多翼羽根車構成体2,3
及び上記端部材4を射出成形により製作する場合には、
図5に示すように、射出成形機12を使用し、ホッパー
15に供給された素材樹脂16をその溶融押出部13に
おいて加熱溶融させ、且つ溶融樹脂材17を射出ノズル
14から金型10のキャビティ11内に射出し、該キャ
ビティ11内でこれを固化させるという作業手順を採る
のが通例である。By the way, each of the above multiblade impeller constituents 2, 3
And when the end member 4 is manufactured by injection molding,
As shown in FIG. 5, using the injection molding machine 12, the material resin 16 supplied to the hopper 15 is heated and melted in the melt extrusion section 13, and the molten resin material 17 is injected from the injection nozzle 14 into the cavity of the mold 10. It is customary to employ the work procedure of injecting into the cavity 11 and solidifying it within the cavity 11.
【0005】この場合、特に、上記各多翼羽根車構成体
2,3は、これに備えられる上記翼5,5,・・が、図
4に示すように薄板帯状の形態を有していることから、
上記金型10のキャビティ11のうち、該翼5に対応す
る部分は厚さが薄く且つ奥行きが長い空間形態となる。
しかも、この翼5,5,・・に対応する部分では、溶融
樹脂材17の流動状態を可及的に自然に近い状態として
流動抵抗を低減させるために、該溶融樹脂材17を、該
翼5,・・の長さ方向の一端側、具体的には、上記端面
板6,7に対応する側から射出し、これを該各翼5,
5,・・においてその一端側から他端側へ向けて流動さ
せるのが通例である。In this case, in particular, in each of the multiblade impeller constituents 2 and 3, the blades 5, 5, ... Provided therein have a thin strip shape as shown in FIG. From that,
A portion of the cavity 11 of the mold 10 corresponding to the blade 5 has a thin space and a long depth.
Moreover, in order to reduce the flow resistance of the molten resin material 17 in a state corresponding to the blades 5, 5, ... 5, ... Is ejected from one end side in the length direction, specifically, the side corresponding to the end face plates 6 and 7, and this is injected into each of the blades 5.
In 5, ..., It is customary to flow from one end side to the other end side.
【0006】従って、これら各多翼羽根車構成体2,3
の形状寸法的な精度を確保するには、射出成形に際し、
溶融樹脂材17を上記キャビティ11の厚さが薄く且つ
奥行きが長い空間の隅々まで十分に行き渡らせ且つその
状態で固化させることが必要となる。Therefore, each of these multiblade impeller constituents 2, 3
To ensure the dimensional accuracy of the
It is necessary for the molten resin material 17 to be sufficiently spread to every corner of the space where the cavity 11 has a small thickness and a long depth and to be solidified in that state.
【0007】かかる観点から、上記各多翼羽根車構成体
2,3の射出成形に際しては、高圧射出成形法、即ち、
溶融樹脂材17を高圧で射出し該溶融樹脂材17を上記
キャビティ11の隅々まで十分に押し込む方法を採用す
るのが通例である。尚、この場合、キャビティ11内に
射出された溶融樹脂材17を収縮引けを防止して形状の
保持を図るため、これが所定程度に固化するまで保圧す
る必要があり、またこれに対応して上記金型10の型締
圧も大きいものが必要となる。From this point of view, in the injection molding of the multiblade impeller constituents 2 and 3, the high pressure injection molding method, that is,
It is customary to employ a method of injecting the molten resin material 17 at a high pressure and sufficiently pushing the molten resin material 17 into every corner of the cavity 11. In this case, in order to prevent shrinkage and shrinkage of the molten resin material 17 injected into the cavity 11 and to maintain the shape, it is necessary to maintain the pressure until the molten resin material 17 is solidified to a predetermined degree. The mold clamping pressure of the mold 10 is also required to be large.
【0008】ところで、このように高圧射出成形法によ
り上記各多翼羽根車構成体2,3を成形した場合、成形
された各多翼羽根車構成体2,3においては、高圧下で
の固化に起因する樹脂分子相互間の歪みによって内部に
大きな残留応力を生じた状態となっている。従って、上
記各多翼羽根車構成体2,3をその内部に残留応力を保
有したまま用いて上記多翼羽根車1を形成し、これをそ
のまま製品として使用すると、この残留応力によって上
記各多翼羽根車構成体2,3が時間の経過とともに次第
に変形を生じ、製品としての多翼羽根車1の形状寸法上
の精度を維持できず、その回転時の振動あるいは騒音の
発生原因となる。By the way, when the above-mentioned multiblade impeller constituents 2 and 3 are molded by the high-pressure injection molding method, the molded multiblade impeller constituents 2 and 3 are solidified under high pressure. Due to the distortion between the resin molecules caused by, a large residual stress is generated inside. Therefore, when the multi-blade impeller 1 is formed by using the multi-blade impeller constituents 2 and 3 while retaining the residual stress therein, and when the multi-blade impeller 1 is used as a product as it is, the multi-blade impeller is used as a product. The blade impeller constituents 2 and 3 are gradually deformed with the lapse of time, and the accuracy in terms of shape and dimensions of the multi-blade impeller 1 as a product cannot be maintained, which causes vibration or noise during its rotation.
【0009】尚、このような各多翼羽根車構成体2,3
の残留応力は、その射出成形時のみならず、該各多翼羽
根車構成体2,3相互の接合工程においても生じるが、
ここで発生する残留応力は射出成形時に発生する残留応
力に比して、そのレベルは格段に低く、従って、上記各
多翼羽根車構成体2,3における残留応力はそのほとん
どが射出成形時に生じるものと考えることができ。Incidentally, each of the multiblade impeller constituents 2 and 3 as described above.
The residual stress of occurs not only in the injection molding but also in the process of joining the multiblade impeller constituents 2 and 3 to each other.
The residual stress generated here is much lower in level than the residual stress generated during injection molding. Therefore, most of the residual stress in the multiblade impeller constituents 2 and 3 occurs during injection molding. Can be thought of as something.
【0010】このような各多翼羽根車構成体2,3の残
留応力を除去して、該各多翼羽根車構成体2,3の製品
としての形状寸法の精度及び回転時の振動とか騒音の抑
制を図るべく、従来よりアニール処理が採用されてい
る。このアニール処理は、上記多翼羽根車1をその成形
完了後に、所定温度下で所定時間保持することで上記各
多翼羽根車構成体2,3の残留応力の除去を行う処理で
ある。By removing the residual stress of each of the multiblade impeller constituents 2 and 3 as described above, the accuracy of the shape and dimension of each of the multiblade impeller constituents 2 and 3 as a product and the vibration and noise during rotation. In order to suppress the above, an annealing treatment has been conventionally used. This annealing treatment is a treatment for removing the residual stress in each of the multiblade impeller constituents 2 and 3 by holding the multiblade impeller 1 at a predetermined temperature for a predetermined time after the completion of the molding.
【0011】ここで、従来の射出成形による多翼羽根車
1の製造工程の概要を図6を参照して説明する。Here, the outline of the manufacturing process of the conventional multi-blade impeller 1 by injection molding will be described with reference to FIG.
【0012】この製造工程は、大きく分けて射出成形工
程31と接合工程32とアニール処理工程33及びバラ
ンシング工程34の四つの工程からなっている。射出成
形工程31は、金型10と射出成形機12(図5参照)
とを使用して上記各多翼羽根車構成体2,3を射出成形
する工程である。This manufacturing process is roughly divided into four steps of an injection molding step 31, a joining step 32, an annealing step 33 and a balancing step 34. The injection molding process 31 includes a mold 10 and an injection molding machine 12 (see FIG. 5).
Is a step of injection-molding each of the multi-blade impeller constituents 2 and 3 described above.
【0013】この射出成形工程31で製作された各多翼
羽根車構成体2,3及び端部材4を次の接合工程32に
おいて、超音波接合機21により順次接合し、これを一
体化して多翼羽根車1を得る。In the next joining step 32, the multi-blade impeller constituents 2 and 3 and the end member 4 produced in the injection molding step 31 are sequentially joined by the ultrasonic joining machine 21, and these are integrated into one body. Obtain the wing impeller 1.
【0014】次に、アニール処理工程33において、上
記多翼羽根車1にアニール処理を施こす。即ち、例えば
温風循環式のアニール炉22内に、上記多翼羽根車1を
その軸方向に立てた状態で多数配置し、該各多翼羽根車
1,1,・・を所定温度下で所定時間保持する。この加
熱保持によって、上記各多翼羽根車構成体2,3におい
てはその分子結合が緩んで分子の移動が容易となり、次
第に分子相互間の歪みが除去され残留応力が取り除かれ
る。Next, in the annealing step 33, the multiblade impeller 1 is annealed. That is, for example, a large number of the multiblade impellers 1 are arranged in an axial direction in a warm air circulation type annealing furnace 22, and the multiblade impellers 1, 1 ,. Hold for a predetermined time. By this heating and holding, in each of the multiblade impeller constituents 2 and 3, the molecular bond is loosened to facilitate the movement of the molecules, and the strain between the molecules is gradually removed and the residual stress is removed.
【0015】最後に、バランシング工程34において、
上記多翼羽根車1を実際に回転させてその回転バランス
の調整が行われる。Finally, in balancing step 34,
The rotation balance is adjusted by actually rotating the multiblade impeller 1.
【0016】[0016]
【発明が解決しようとする課題】ところが、このように
成形後の多翼羽根車1にアニール処理を施すことで、該
多翼羽根車1の残留応力が取り除かれ、該多翼羽根車1
の製品としての利用価値が生じるものであるが、上記ア
ニール処理は、アニール炉22が必要であることからそ
の設備が大型化し且つ設備費が嵩むとともに、設備が大
型であるため加熱される多翼羽根車1に温度ムラが生じ
易く、従ってこれを均一に加熱しようとすれば長時間
(通常、8〜20時間)加熱保持しなければならず、作
業経費の増加とか多翼羽根車1の製造工程全体としての
作業効率の低下を招き、結果的に多翼羽根車1の製品コ
ストが高くつくという問題があった。However, by subjecting the multiblade impeller 1 thus formed to the annealing treatment, the residual stress of the multiblade impeller 1 is removed, and the multiblade impeller 1 is removed.
However, since the annealing furnace 22 is required, the equipment is large in size and the equipment cost is high, and the equipment is large in size. The impeller 1 is likely to have temperature unevenness, so if it is attempted to heat it uniformly, it must be heated and held for a long time (usually 8 to 20 hours), which leads to an increase in operating costs and the manufacture of the multiblade impeller 1. There is a problem in that the work efficiency of the entire process is lowered, and as a result, the product cost of the multiblade impeller 1 becomes high.
【0017】そこで本願発明は、射出成形による樹脂成
形品の製造に際して、射出成形時における残留応力の発
生を可及的に抑制することで、事後処理としてのアニー
ル処理を不要とし、あるいはその処理時間を短縮し得る
ようにした樹脂成形品の製造方法を提案することを目的
としてなされたものである。Therefore, in the present invention, when a resin molded article is manufactured by injection molding, the occurrence of residual stress at the time of injection molding is suppressed as much as possible, thereby eliminating the need for an annealing treatment as a post-treatment or a processing time thereof. The present invention has been made for the purpose of proposing a method for manufacturing a resin molded product that can shorten
【0018】[0018]
【課題を解決するための手段】本願発明ではかかる課題
を解決するための具体的手段として次のような構成を採
用している。In the present invention, the following constitution is adopted as a concrete means for solving such a problem.
【0019】本願の第1の発明にかかる樹脂成形品の製
造方法では、溶融樹脂材17に該溶融樹脂材17の流動
性を促進する流動性促進材を加え、これを金型10のキ
ャビティ11内に射出して樹脂成形品2,3を製造する
ことを特徴としている。In the method for producing a resin molded product according to the first invention of the present application, a fluidity promoting material for promoting fluidity of the molten resin material 17 is added to the molten resin material 17, and this is added to the cavity 11 of the mold 10. It is characterized in that it is injected into the inside to manufacture resin molded products 2 and 3.
【0020】本願の第2の発明では、上記第1の発明に
かかる樹脂成形品の製造方法において、上記流動性促進
材として、加熱により化学分解して気体を発生する気体
発生剤を用いることを特徴としている。In a second invention of the present application, in the method for producing a resin molded product according to the first invention, a gas generating agent that chemically decomposes by heating to generate a gas is used as the fluidity promoting material. It has a feature.
【0021】本願の第3の発明では、上記第1又は第2
の発明にかかる樹脂成形品の製造方法において、上記樹
脂成形品2,3が、薄板帯状の翼5,5,・・を同心円
上に所定間隔で平行に配置してなる多翼羽根車であるこ
とを特徴としている。In the third invention of the present application, the above-mentioned first or second
In the method for producing a resin molded product according to the invention, the resin molded products 2 and 3 are multi-blade impellers in which thin plate-shaped blades 5, 5, ... Are concentrically arranged in parallel at predetermined intervals. It is characterized by that.
【0022】本願の第4の発明では、上記第3の発明に
かかる樹脂成形品の製造方法において、上記キャビティ
11の上記各翼5,5,・・に対応する部位における上
記溶融樹脂材17の流れ方向を該翼5,5,・・の長さ
方向に設定したことを特徴としている。According to a fourth invention of the present application, in the method for manufacturing a resin molded product according to the third invention, the molten resin material 17 in the portion of the cavity 11 corresponding to the blades 5, 5, ... It is characterized in that the flow direction is set in the longitudinal direction of the blades 5, 5 ,.
【0023】[0023]
【発明の効果】本願発明ではかかる構成とすることによ
り次のような効果が得られる。According to the present invention, the following effects can be obtained by adopting such a configuration.
【0024】 本願の第1の発明にかかる樹脂成形品
の製造方法では、溶融樹脂材17に該溶融樹脂材17の
流動性を促進する流動性促進材を加え、これを金型10
のキャビティ11内に射出して樹脂成形品2,3を製造
する。In the method for manufacturing a resin molded product according to the first invention of the present application, a fluidity accelerating material for accelerating the fluidity of the molten resin material 17 is added to the molten resin material 17, and the mold 10 is used.
The resin molded products 2 and 3 are manufactured by injecting into the cavity 11.
【0025】従って、この発明の樹脂成形品の製造方法
によれば、溶融樹脂材17に流動性促進材が加えられて
いることで、この溶融樹脂材17が金型10のキャビテ
ィ11内に射出された場合、該溶融樹脂材17はその高
い流動性を保有することから、その射出圧力が比較的低
く設定されていても、該溶融樹脂材17が上記キャビテ
ィ11の隅々まで十分に充填され、該キャビティ11の
内面形状に合致した形状寸法精度の高い樹脂成形品2,
3が得られる。Therefore, according to the method for producing a resin molded product of the present invention, since the fluidity promoting material is added to the molten resin material 17, the molten resin material 17 is injected into the cavity 11 of the mold 10. In this case, since the molten resin material 17 retains its high fluidity, the molten resin material 17 is sufficiently filled in every corner of the cavity 11 even if the injection pressure is set to be relatively low. , A resin molded product 2 having a high shape and dimension accuracy that matches the inner surface shape of the cavity 11.
3 is obtained.
【0026】このように、上記溶融樹脂材17の射出成
形を低い射出圧力で行うことができることで、該射出圧
力が低い分だけ樹脂成形品2,3の内部における残留応
力が少なく、従って、事後処理としてのアニール処理が
不要になり、あるいはアニール処理を行うとしてもその
処理時間を可及的に短縮することができ、製造工程の省
略あるいは簡略化によって樹脂成形品2,3をより安価
に提供できることになる。Since the injection molding of the molten resin material 17 can be performed at a low injection pressure as described above, the residual stress inside the resin molded products 2 and 3 is small due to the low injection pressure. Annealing as a treatment is not necessary, or even if annealing is performed, the treatment time can be shortened as much as possible, and the resin moldings 2, 3 can be provided at a lower cost by omitting or simplifying the manufacturing process. You can do it.
【0027】また、上記溶融樹脂材17が高い流動性を
もつことから、上記樹脂成形品2,3が薄肉品とか薄肉
長尺品であってそのキャビティ11が薄く且つ奥行きの
大きい狭小空間であっても、該溶融樹脂材17を該キャ
ビティ11の隅々まで十分に充填させることができ、薄
肉樹脂成形品とか薄肉長尺樹脂成形品の製造が容易とな
る。Further, since the molten resin material 17 has a high fluidity, the resin molded products 2 and 3 are thin-walled products or thin-walled long products, and the cavity 11 is thin and has a large depth and a small space. However, the molten resin material 17 can be sufficiently filled in every corner of the cavity 11, and the production of a thin resin molded product or a thin long resin molded product becomes easy.
【0028】さらに、溶融樹脂材17の射出成形時の射
出圧力を低く設定できることで、射出成形機の低能力化
あるいは金型10の型締圧の低下による小型化が図れ、
それだけ製造設備費の低廉化にも寄与し得ることにな
る。Further, since the injection pressure of the molten resin material 17 at the time of injection molding can be set to be low, the injection molding machine can be downsized or the die 10 can be downsized by lowering the clamping pressure.
That would contribute to the reduction of manufacturing equipment costs.
【0029】 本願の第2の発明にかかる樹脂成形品
の製造方法によれば、上記流動性促進材として、加熱に
より化学分解して気体を発生する気体発生剤を用いるよ
うにしているので、上記溶融樹脂材17が上記金型10
のキャビティ11内に射出された場合、該気体発生剤が
溶融樹脂材17の熱によって化学分解して気体を発生
し、この気体分子がその分子運動によって樹脂分子相互
間に介入してこれらを引き離し分子間結合を緩和させる
とともに、樹脂分子の流動に伴う樹脂分子相互間の摩擦
抵抗を低減させてその流動を助長し、これらの相乗作用
によって、上記キャビティ11内に射出された溶融樹脂
材17は高い流動性を維持し、この結果、上記に記載
したと同様の効果が得られるものである。In the method for producing a resin molded product according to the second invention of the present application, since the gas generating agent that chemically decomposes by heating to generate gas is used as the fluidity promoting agent, The molten resin material 17 is the mold 10
When the gas generating agent is injected into the cavity 11, the gas generating agent is chemically decomposed by the heat of the molten resin material 17 to generate a gas, and the gas molecules intervene between the resin molecules by the molecular motion to separate them. The intermolecular bond is alleviated, and the frictional resistance between the resin molecules accompanied by the flow of the resin molecules is reduced to promote the flow, and the synergistic effect of these reduces the molten resin material 17 injected into the cavity 11. A high fluidity is maintained, and as a result, the same effect as described above is obtained.
【0030】さらに、この発明においては、流動性促進
材として気体発生剤を用いているので、該気体発生剤か
ら発生する気体の膨張力によって上記キャビティ11内
に射出充填された溶融樹脂材17は内部からキャビティ
内面に押し付けられる作用を受ける。このため、キャビ
ティ11内へ溶融樹脂材17を射出充填した後における
該溶融樹脂材17に対する保圧を低く設定しても該溶融
樹脂材17の収縮引けを有効に抑えることができ、この
保圧を低く設定できる分だけ該溶融樹脂材17の固結時
における残留応力の発生を抑えることができ、溶融樹脂
材17の射出圧力の低下による残留応力の低減効果と相
俟って、アニール処理の省略化がさらに促進され、上記
に記載の効果のより一層の向上が期待できるものであ
る。Further, in the present invention, since the gas generating agent is used as the fluidity promoting material, the molten resin material 17 injected and filled in the cavity 11 by the expansion force of the gas generated from the gas generating agent is used. It is pressed against the inner surface of the cavity from the inside. Therefore, even if the holding pressure for the molten resin material 17 is set low after the molten resin material 17 is injected and filled into the cavity 11, shrinkage shrinkage of the molten resin material 17 can be effectively suppressed. Can be set to a low value, the generation of residual stress at the time of consolidating the molten resin material 17 can be suppressed, and in combination with the effect of reducing the residual stress due to the decrease in the injection pressure of the molten resin material 17, the annealing treatment Omission can be further promoted, and further improvement of the effects described above can be expected.
【0031】 本願の第3の発明にかかる樹脂成形品
の製造方法では、上記樹脂成形品2,3を、薄板帯状の
翼5,5,・・を同心円上に所定間隔で平行に配置して
なる多翼羽根車とし、該多翼羽根車を当該製造方法によ
って製造するようにしているので、上記翼5が薄板帯状
の形態をもち、従って上記金型10のキャビティ11の
うち、この翼5に対応する部分は狭小空間となっている
にも拘わらず、溶融樹脂材17をこの狭小空間に、しか
も低射出圧力で十二分に充填させることができ、上記溶
融樹脂材17の固化によって得られる製品としての多翼
羽根車においては、高精度の形状寸法精度が確保される
とともに、内部の残留応力が少なく経時変形が可及的に
抑制され事後処理としてのアニール処理の省略が可能と
なり、これらの相乗効果として、成形精度の高い多翼羽
根車をより一層安価に提供することができるものであ
る。In the method for producing a resin molded product according to the third invention of the present application, the resin molded products 2 and 3 are arranged by concentric circles of the thin strip-shaped blades 5, 5, ... Since the multi-blade impeller is formed by the manufacturing method, the blade 5 has a thin strip shape, and thus the blade 5 in the cavity 11 of the mold 10 is formed. Although the portion corresponding to is a narrow space, the molten resin material 17 can be filled into this narrow space more than enough with a low injection pressure, and the molten resin material 17 can be obtained by solidification. In the multi-blade impeller as a product to be manufactured, high-precision shape and dimension accuracy is ensured, internal residual stress is small, and time-dependent deformation is suppressed as much as possible, making it possible to omit post-treatment annealing. These synergies As a result, it is possible to provide a multi-blade impeller with high molding accuracy at a lower cost.
【0032】 本願の第4の発明にかかる樹脂成形品
の製造方法では、多翼羽根車の製造に際して、上記キャ
ビティ11の上記各翼5,5,・・に対応する部位にお
ける上記溶融樹脂材17の流れ方向を該翼5,5,・・
の長さ方向に設定しているので、上記キャビティ11内
に射出された上記溶融樹脂材17の上記各翼5,5,・
・側への分配流れがより自然な流れに近い状態となり、
それだけ金型10の構造の簡略化が図れることになる。
しかし、かかる構成とした場合には、上記各翼5,5,
・・の長さが長くなるほど(即ち、キャビティの奥行き
が大きくなるほど)、溶融樹脂材17の流動作用が阻害
され樹脂材の充填不足による成形精度の低下が懸念され
る。In the method for manufacturing a resin molded product according to the fourth invention of the present application, the molten resin material 17 in the portion of the cavity 11 corresponding to each of the blades 5, 5, ... The flow direction of the blades 5, 5, ...
Are set in the length direction of the blades 5, the blades 5, 5, ... Of the molten resin material 17 injected into the cavity 11
・ The distribution flow to the side becomes closer to the natural flow,
Therefore, the structure of the mold 10 can be simplified.
However, in the case of such a configuration, each of the above wings 5, 5,
The longer the length of .. (that is, the larger the depth of the cavity), the more the flow action of the molten resin material 17 is obstructed, and there is a concern that the molding accuracy may decrease due to insufficient filling of the resin material.
【0033】然し乍ら、この発明の製造方法において
は、上記溶融樹脂材17が流動性促進材の添加によって
高い流動性を保有しているので、該各翼5,5,・・の
端部まで十分に溶融樹脂材17を充填させることがで
き、この結果、長尺の翼5,5,・・を備えた多翼羽根
車を安価に提供することが可能となる。However, in the manufacturing method of the present invention, since the molten resin material 17 has high fluidity due to the addition of the fluidity promoting material, the end portions of the blades 5, 5 ,. Can be filled with the molten resin material 17, and as a result, a multi-blade impeller provided with long blades 5, 5, ... Can be provided at low cost.
【0034】[0034]
【発明の実施の形態】以下、本願発明にかかる樹脂成形
品の製造方法を、射出成形によって多翼羽根車1を製造
する場合を例にとって説明する。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, a method for manufacturing a resin molded product according to the present invention will be described by taking a case of manufacturing a multiblade impeller 1 by injection molding as an example.
【0035】図1には、本願発明にかかる製造方法によ
る多翼羽根車1の製造工程説明図を示している。この図
1を、従来の製造方法の工程説明図(図6)と対比すれ
ば明らかなように、この発明の製造方法においては、従
来の製造方法では必要不可欠であってアニール処理のた
めの工程を省略すること、あるいはアニール処理を行う
としてもその処理時間を可及的に短くすること、を狙い
としたものである。即ち、多翼羽根車1の製造に際し、
先ず、射出成形工程31において、射出成形機12(図
5参照)を用いて金型10内に溶融樹脂材を射出し、上
記多翼羽根車1の構成要素である第1多翼羽根車構成体
2と第2多翼羽根車構成体3及び端部材4をそれぞれ成
形する。次に、接合工程32においては、これら各多翼
羽根車構成体2,3と端部材4とを同軸状に接合一体化
して多翼羽根車1を得る。しかる後、アニール処理を行
うことなく、バランシング工程34において回転バラン
ス調整機23を用いて上記多翼羽根車1の回転バランス
を調整し、最終製品としての多翼羽根車1を得るもので
ある。FIG. 1 is an explanatory view of a manufacturing process of a multiblade impeller 1 by the manufacturing method according to the present invention. As is apparent by comparing FIG. 1 with the process explanatory view (FIG. 6) of the conventional manufacturing method, the manufacturing method of the present invention is an essential step in the conventional manufacturing method and is a step for annealing treatment. Is omitted, or the annealing time is shortened as much as possible even if the annealing process is performed. That is, when manufacturing the multiblade impeller 1,
First, in an injection molding process 31, a molten resin material is injected into a mold 10 using an injection molding machine 12 (see FIG. 5), and a first multi-blade impeller structure which is a constituent element of the multi-blade impeller 1 is formed. The body 2, the second multiblade impeller assembly 3 and the end member 4 are respectively molded. Next, in the joining step 32, the multiblade impeller 1 is obtained by coaxially joining and integrating the respective multiblade impeller constituents 2 and 3 and the end member 4. Thereafter, without performing the annealing treatment, the rotation balance of the multiblade impeller 1 is adjusted in the balancing step 34 by using the rotation balance adjuster 23 to obtain the multiblade impeller 1 as a final product.
【0036】以上のように、本願発明の製造方法は、多
翼羽根車を製造するに際して、アニール処理を行うこと
なく形状寸法精度の高い多翼羽根車を得ることをその究
極目的とするものである。As described above, the manufacturing method of the present invention has the ultimate purpose of obtaining a multiblade impeller having a high shape and dimension accuracy without performing an annealing treatment when manufacturing the multiblade impeller. is there.
【0037】そして、かかる目的は、第1には、金型1
0のキャビティ11の隅々まで、特に多翼羽根車1の成
形にあっては薄板帯状形態をもつ翼に対応する狭小な空
間まで十分に溶融樹脂材17を充填させること、第2に
は、できるだけ溶融樹脂材17の射出圧力を低く設定し
て樹脂分子相互間の歪みを抑えて固化後の残留応力を可
及的に少ならしめること、によって実現されるものであ
る。ところが、上記第1の要求は、従来一般には射出圧
力を高圧に設定することで実現するようにしていたもの
であり、従って、この点からすれば、上記二つの要求は
相反するものであって、その両立は困難なものとなる。The first purpose of this purpose is to make the mold 1
No. 0 of the cavity 11 is filled with the molten resin material 17 to a narrow space corresponding to a blade having a thin strip shape particularly in the molding of the multiblade impeller 1. Secondly, This is realized by setting the injection pressure of the molten resin material 17 as low as possible to suppress the distortion between the resin molecules and to minimize the residual stress after solidification as much as possible. However, the above first requirement is conventionally realized by setting the injection pressure to a high pressure. Therefore, from this point, the above two requirements are contradictory. However, it is difficult to achieve both.
【0038】そこで、本願発明者は、上記二つの要求を
同時に満足させるための技術の開発を試みる過程におい
て、溶融樹脂材の流動性を高めればそれだけ射出圧力を
低くしてもキャビティの隅々まで溶融樹脂材を充填で
き、しかも射出圧力を低く設定することで残留応力の発
生が可及的に抑えられアニール処理の省略が可能にな
る、との着想の下、溶融樹脂材中にその流動性の促進作
用をもつ流動性促進材を加えること、さらにこの流動性
促進材として気体発生剤を採用し、発生気体を溶融樹脂
材内において滑材として機能させて流動性を高めると同
時に、該発生気体の膨張力で溶融樹脂材をキャビティ内
面に押し付けることで成形精度の確保と射出圧力の更な
る低下を図ることに想到したものである。Therefore, in the process of attempting to develop a technique for simultaneously satisfying the above two requirements, the inventor of the present application increases the fluidity of the molten resin material to reach every corner of the cavity even if the injection pressure is lowered. Based on the idea that the molten resin material can be filled and the injection pressure is set to be low, the occurrence of residual stress can be suppressed as much as possible and the annealing process can be omitted. The fluidity promoting material having the accelerating action is added, and a gas generating agent is further adopted as the fluidity promoting material to allow the generated gas to function as a lubricant in the molten resin material to enhance the fluidity and The present invention is intended to secure the molding accuracy and further reduce the injection pressure by pressing the molten resin material against the inner surface of the cavity by the expansive force of the gas.
【0039】具体的には、射出成形機12(図5参照)
において溶融され且つ金型10のキャビティ11に射出
される溶融樹脂材17中に流動性促進材として気体発生
剤を加え、これを用いて射出成形するものである。そし
て、この気体発生剤は、溶融樹脂材17の熱によって化
学分解して気体を発生させる性状を有することが必要
で、例えば人体に無害のクエン酸とか重曹を含み、これ
らの気化発泡作用を利用するものが好適である。Specifically, the injection molding machine 12 (see FIG. 5)
A gas generating agent is added as a fluidity promoting agent to the molten resin material 17 which is melted and is injected into the cavity 11 of the mold 10, and injection molding is performed using this. The gas generating agent needs to have a property of chemically decomposing by the heat of the molten resin material 17 to generate a gas. For example, citric acid or baking soda, which is harmless to the human body, is included, and the vaporization and foaming action of these is used. Those that do are preferred.
【0040】このように溶融樹脂材17に流動性促進材
として気体発生剤を加え、これを金型10のキャビティ
11内に射出して上記各多翼羽根車構成体2,3を形成
することで、以下のような特有の作用効果が得られる。In this way, a gas generating agent is added to the molten resin material 17 as a fluidity promoting material, and this is injected into the cavity 11 of the mold 10 to form the multiblade impeller constituent bodies 2 and 3. Thus, the following unique effects can be obtained.
【0041】即ち、溶融樹脂材17に流動性促進材とし
て気体発生剤が加えられていることで、この溶融樹脂材
17が金型10のキャビティ11内に射出された場合、
該気体発生剤が溶融樹脂材17の熱によって化学分解し
て気体を発生し、この気体分子がその分子運動によって
樹脂分子相互間に介入してこれらを引き離し分子間結合
を緩和させるとともに、樹脂分子の流動に伴う樹脂分子
相互間の摩擦抵抗を低減させてその流動を助長し、これ
らの相乗作用によって、上記溶融樹脂材17は高い流動
性を保有することになる。この結果、上記溶融樹脂材1
7の射出圧力を比較的低圧に設定しても、該溶融樹脂材
17はキャビティ11の隅々まで十分に充填され、形状
寸法精度の高い樹脂成形品2,3が得られる。In other words, when the molten resin material 17 is injected into the cavity 11 of the mold 10 by adding the gas generating agent as the fluidity promoting material to the molten resin material 17,
The gas generating agent chemically decomposes by the heat of the molten resin material 17 to generate a gas, and the gas molecules intervene between the resin molecules by their molecular motion to separate them to relax the intermolecular bond, and the resin molecules The frictional resistance between the resin molecules associated with the flow of the resin is reduced to promote the flow, and the synergistic effect of these causes the molten resin material 17 to have high fluidity. As a result, the molten resin material 1
Even if the injection pressure of 7 is set to a relatively low pressure, the molten resin material 17 is sufficiently filled in every corner of the cavity 11, and resin molded products 2 and 3 with high shape dimension accuracy can be obtained.
【0042】また、上記各多翼羽根車構成体2,3は、
溶融樹脂材17の射出圧力が低圧であることから、該溶
融樹脂材17の固化時における樹脂分子相互間の歪みの
発生が少なく、固化後の残留応力も小さいものとなる。
従って、上記各多翼羽根車構成体2,3をその成形後、
相互に接合一体化して多翼羽根車1を形成した状態にお
いても、該多翼羽根車1の残留応力は小さく、アニール
処理を行わずとも経時変形をほとんど生じないか、例え
アニール処理をするとしてもその処理時間を極めて短時
間とすることができ、それだけ多翼羽根車1をより安価
に提供できることになる。The multiblade impeller components 2 and 3 are
Since the injection pressure of the molten resin material 17 is low, the strain between the resin molecules during solidification of the molten resin material 17 is small, and the residual stress after solidification is also small.
Therefore, after molding each of the above multiblade impeller constituents 2 and 3,
Even when the multi-blade impeller 1 is formed by joining and integrating them with each other, the residual stress of the multi-blade impeller 1 is small, and even if it is not annealed, it is hardly deformed with time. The processing time can be made extremely short, and the multiblade impeller 1 can be provided at a lower cost.
【0043】さらに、流動性促進材として気体発生剤を
用いることで、該気体発生剤から発生する気体の膨張力
によって上記キャビティ11内に射出充填された溶融樹
脂材17はその内部からキャビティ内面に押し付けられ
る作用を受ける。従って、キャビティ11内へ溶融樹脂
材17を射出充填した後における該溶融樹脂材17に対
する保圧を低く設定しても、該溶融樹脂材17の収縮引
けを有効に抑えることができ、この結果、保圧を低く設
定できる分だけ溶融樹脂材17の固結時における残留応
力の発生を抑えることができ、上述の如き溶融樹脂材1
7の射出圧力の低下による残留応力の低減効果と相俟っ
て、アニール処理の省略化がさらに促進されることにな
る。Further, by using the gas generating agent as the fluidity promoting material, the molten resin material 17 injected and filled in the cavity 11 by the expansion force of the gas generated from the gas generating agent flows from the inside to the inside surface of the cavity. It is pressed. Therefore, even if the holding pressure for the molten resin material 17 after injection-filling the molten resin material 17 into the cavity 11 is set low, shrinkage shrinkage of the molten resin material 17 can be effectively suppressed, and as a result, As much as the holding pressure can be set low, the generation of residual stress at the time of consolidating the molten resin material 17 can be suppressed.
Combined with the effect of reducing the residual stress due to the reduction of the injection pressure of No. 7, the omission of the annealing process is further promoted.
【0044】また、溶融樹脂材17の射出圧力を低く設
定できるということは、それだけ射出成形機12の低能
力化あるいは金型10の型締圧の低下による小型化が図
れるということであり、製造設備費の低廉化に寄与し得
ることになる。Further, the fact that the injection pressure of the molten resin material 17 can be set low means that the injection molding machine 12 can be made smaller and the die 10 can be downsized by lowering the mold clamping pressure. This can contribute to the reduction of equipment costs.
【0045】さらに、上記溶融樹脂材17が流動性促進
材の添加によって高い流動性を保有していることで、各
多翼羽根車構成体2,3の成形に際し、該各多翼羽根車
構成体2,3の各翼5,5,・・の長さを長く設定し、
上記キャビティ11の上記各翼5,5,・・に対応する
部位の空間を、厚さが薄く且つ奥行きの長い狭小空間と
しても、該狭小空間の隅々まで上記溶融樹脂材17を十
分に充填させることができる。即ち、従来よりも長さの
大きい翼5をもつ多翼羽根車構成体2,3を容易に得る
ことができる。Further, since the molten resin material 17 has a high fluidity due to the addition of the fluidity promoting material, when the multi-blade impeller constituents 2 and 3 are molded, the multi-blade impeller constituents are formed. Set the length of each wing 5, 5, ...
Even if the space of the cavity 11 corresponding to each of the blades 5, 5, ... Is a narrow space having a small thickness and a long depth, the molten resin material 17 is sufficiently filled up to every corner of the narrow space. Can be made. That is, it is possible to easily obtain the multiblade impeller constituents 2 and 3 having the blades 5 having a length longer than the conventional one.
【0046】このように長さの大きい翼5をもつ多翼羽
根車構成体2,3を得ることができることに起因して、
以下のような付随的効果が得られる。Due to the fact that it is possible to obtain the multiblade impeller components 2 and 3 having the blades 5 having a large length,
The following additional effects can be obtained.
【0047】即ち、翼5の長さを大きくできるというこ
とは、上記各多翼羽根車構成体2,3の軸長を大きくで
きることであり、従って、これら各多翼羽根車構成体
2,3を軸方向に連結して構成される多翼羽根車1にお
いては、その軸長を同じとした場合には、上記各多翼羽
根車構成体2,3の軸長が長い分だけその組付個数を少
なくすることができ、それだけ多翼羽根車1の製造時に
おける上記多翼羽根車構成体2,3相互間の接合回数が
減り、これらの組付工数の低減によって該多翼羽根車1
の製造コストの低廉化が図れる。That is, the fact that the length of the blade 5 can be increased means that the axial length of each of the above-mentioned multiblade impeller constituents 2 and 3 can be increased, and accordingly, each of these multiblade impeller constituents 2 and 3 can be increased. In the multiblade impeller 1 configured by connecting in the axial direction, when the axial lengths of the multiblade impeller 1 and the multiblade impeller constituents 2 and 3 are long, the assembling is performed. Since the number of the multiblade impellers 1 can be reduced, the number of joints between the multiblade impeller constituents 2 and 3 at the time of manufacturing the multiblade impeller 1 is reduced.
The manufacturing cost can be reduced.
【0048】また、多翼羽根車1を構成する多翼羽根車
構成体2,3の個数が減るということは、該多翼羽根車
1全体としてみた場合、該各多翼羽根車構成体2,3に
設けられている端面板6,7の数が減るということであ
る。ここで、この端面板6,7は、上記多翼羽根車1を
その軸方向において分断するように存在するものであっ
て、該多翼羽根車1の送風性能を低下させる要因の一つ
となるものであることから、この端面板6,7の数が減
る分だけ、上記多翼羽根車1においてはその送風性能の
向上が期待できることになる。In addition, the fact that the number of the multiblade impeller constituents 2 and 3 constituting the multiblade impeller 1 is reduced means that the multiblade impeller constituents 2 can be viewed as the multiblade impeller 1 as a whole. That is, the number of the end plates 6 and 7 provided on the first and third terminals is reduced. Here, the end plates 6 and 7 exist so as to divide the multiblade impeller 1 in the axial direction thereof, and are one of the factors that lower the air blowing performance of the multiblade impeller 1. Since the number of the end plates 6 and 7 is reduced, the multi-blade impeller 1 can be expected to have improved air blowing performance.
【図1】本願発明にかかる樹脂成形品の製造方法におけ
る製造工程説明図である。FIG. 1 is an explanatory view of a manufacturing process in a method for manufacturing a resin molded product according to the present invention.
【図2】多翼羽根車の斜視図である。FIG. 2 is a perspective view of a multiblade impeller.
【図3】多翼羽根車の構成を示す分解斜視図である。FIG. 3 is an exploded perspective view showing a configuration of a multiblade impeller.
【図4】多翼羽根車の翼構造を示す斜視図である。FIG. 4 is a perspective view showing a blade structure of a multi-blade impeller.
【図5】射出成形装置の全体構成の慨示図である。FIG. 5 is a schematic diagram of an overall configuration of an injection molding device.
【図6】多翼羽根車の製造工程説明図である。FIG. 6 is a drawing explaining the manufacturing process of the multiblade impeller.
1は多翼羽根車、2は第1羽根車構成体、3は第2羽根
車構成体、4は端部材、5は翼、6は端面板、10は金
型、11はキャビティ、12は射出成形機、13は溶融
押出部、14は射出ノズル、15はホッパー、16は素
材樹脂、17は溶融樹脂材、21は超音波接合機、22
はアニール炉、23は回転バランス調整機、31は射出
成形工程、32は接合工程、33はアニール処理工程で
ある。1 is a multi-blade impeller, 2 is a first impeller structure, 3 is a second impeller structure, 4 is an end member, 5 is a blade, 6 is an end plate, 10 is a mold, 11 is a cavity, 12 is Injection molding machine, 13 melt extrusion section, 14 injection nozzle, 15 hopper, 16 resin material, 17 molten resin material, 21 ultrasonic bonding machine, 22
Is an annealing furnace, 23 is a rotation balance adjuster, 31 is an injection molding step, 32 is a joining step, and 33 is an annealing step.
Claims (4)
7)の流動性を促進する流動性促進材を加え、これを金
型(10)のキャビティ(11)内に射出して樹脂成形
品(2),(3)を製造することを特徴とする樹脂成形
品の製造方法。1. The molten resin material (17) is added to the molten resin material (1).
7) A fluidity promoting material for promoting fluidity is added, and this is injected into the cavity (11) of the mold (10) to produce resin molded products (2), (3). Manufacturing method of resin molded product.
を発生する気体発生剤を用いることを特徴とする樹脂成
形品の製造方法。2. The method for producing a resin molded article according to claim 1, wherein a gas generating agent that chemically decomposes by heating to generate a gas is used as the fluidity promoting material.
(5),(5),・・を同心円上に所定間隔で平行に配
置してなる多翼羽根車であることを特徴とする樹脂成形
品の製造方法。3. The resin molded article (2), (3) according to claim 1 or 2, wherein the thin strip-shaped blades (5), (5), ... Are arranged in parallel on a concentric circle at predetermined intervals. A method for producing a resin molded product, which is a multi-blade impeller having the following structure.
・に対応する部位における上記溶融樹脂材(17)の流
れ方向を該翼(5),(5),・・の長さ方向に設定し
たことを特徴とする樹脂成形品の製造方法。4. The blades (5), (5), ... Of the cavity (11) according to claim 3,
The flow direction of the molten resin material (17) in the portion corresponding to the is set to the length direction of the blades (5), (5) ,.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001206060A JP2003080548A (en) | 2001-06-27 | 2001-07-06 | Method for manufacturing resin molded products |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001194628 | 2001-06-27 | ||
| JP2001-194628 | 2001-06-27 | ||
| JP2001206060A JP2003080548A (en) | 2001-06-27 | 2001-07-06 | Method for manufacturing resin molded products |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2003080548A true JP2003080548A (en) | 2003-03-19 |
Family
ID=26617647
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001206060A Pending JP2003080548A (en) | 2001-06-27 | 2001-07-06 | Method for manufacturing resin molded products |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2003080548A (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58126129A (en) * | 1982-01-23 | 1983-07-27 | Kiyoshi Yamada | Mold for injection molding of cylindrical impeller |
| JPH05318541A (en) * | 1992-05-25 | 1993-12-03 | Mitsubishi Petrochem Co Ltd | Method for injection molding of plastic |
| JPH06262644A (en) * | 1993-03-11 | 1994-09-20 | Sanko Gosei Kk | Injection molding method for multiblade wheel for blower and injection mold thereof |
| JPH08333481A (en) * | 1995-06-07 | 1996-12-17 | Goodyear Tire & Rubber Co:The | Tire with silica reinforced tread |
| JPH1142664A (en) * | 1997-05-30 | 1999-02-16 | Grand Polymer:Kk | Polypropylene resin composition for injection molding and injection molded product |
| JP2001030283A (en) * | 1999-07-19 | 2001-02-06 | Asahi Chem Ind Co Ltd | Method for injection molding aliphatic polyketone |
| JP2001105446A (en) * | 1999-10-05 | 2001-04-17 | Mitsubishi Electric Corp | Method for manufacturing synthetic resin fan and molding die for synthetic resin fan |
-
2001
- 2001-07-06 JP JP2001206060A patent/JP2003080548A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58126129A (en) * | 1982-01-23 | 1983-07-27 | Kiyoshi Yamada | Mold for injection molding of cylindrical impeller |
| JPH05318541A (en) * | 1992-05-25 | 1993-12-03 | Mitsubishi Petrochem Co Ltd | Method for injection molding of plastic |
| JPH06262644A (en) * | 1993-03-11 | 1994-09-20 | Sanko Gosei Kk | Injection molding method for multiblade wheel for blower and injection mold thereof |
| JPH08333481A (en) * | 1995-06-07 | 1996-12-17 | Goodyear Tire & Rubber Co:The | Tire with silica reinforced tread |
| JPH1142664A (en) * | 1997-05-30 | 1999-02-16 | Grand Polymer:Kk | Polypropylene resin composition for injection molding and injection molded product |
| JP2001030283A (en) * | 1999-07-19 | 2001-02-06 | Asahi Chem Ind Co Ltd | Method for injection molding aliphatic polyketone |
| JP2001105446A (en) * | 1999-10-05 | 2001-04-17 | Mitsubishi Electric Corp | Method for manufacturing synthetic resin fan and molding die for synthetic resin fan |
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