JP2003073249A - Deodorant composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a deodorant composition which exhibits deodorant function by preferentially adsorbing sebum to become a source of an offensive smell and a lower fatty acid-based offensive smell substance itself, controlling their volatilization and further neutralizing the offensive smell substance. SOLUTION: This deodorant composition is obtained by compounding silicon dioxide and magnesium oxide as main raw materials and mixing the compound with porous powder having >=0.05 ml/g pore volume, 0.5-40 μm average particle diameter and >=50 ml/100 g oil absorption.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a deodorant composition, and more specifically, it uses sebum and a lower fatty acid type malodorous substance as a source of malodorous substance by using a powder having particularly excellent oil absorption. The present invention relates to a deodorant composition which preferentially adsorbs itself, suppresses its volatilization, and further exerts a deodorizing function by neutralizing the above-mentioned malodorous substance.

[0002]

2. Description of the Related Art Conventionally, the problems to be solved by the invention
As a method of suppressing the generation of body odor due to sweating, etc., there is a method of suppressing sweating with an astringent (such as an aluminum compound) to suppress the generation of foul odors.
There was a problem that it was inferior in immediate effect. In addition, although there is a method of preventing the propagation of malodorous substance-producing bacteria with a bactericidal agent, there is a concern that it may have an adverse effect on skin-resident bacteria. Furthermore, there is a method of masking with a fragrance, but it is inferior in sustainability,
There was a problem that the malodorous substances were not removed. Also, there is a method of deodorizing with a metal oxide, a plant extract, etc., but there is a problem that the immediate effect is poor.

Therefore, various proposals have been made in order to solve the above problems (Japanese Patent Laid-Open No. 7-1381).
40, JP-A-10-338621, JP-A-6-87.
No. 729, Japanese Patent Publication No. 3-51651), there has been a demand for the development of a deodorant composition exhibiting a more excellent deodorant function.

The present invention has been made in view of the above circumstances, and an object thereof is to provide a deodorant composition having an unprecedented excellent deodorizing effect.

[0005]

Means for Solving the Problems and Embodiments of the Invention As a result of intensive investigations by the present inventors to solve the above problems,
Magnesium is not supported or coated on silica particles, but porous powder composed mainly of silica (silicon dioxide) and magnesium oxide has a layered structure and adsorbs and deodorizes a wide range of malodorous substances. Is possible, and also
Not only adsorption but also deodorizing effect by neutralization, by improving the oil absorption of such porous powder, sebum,
It has been found that the affinity with fatty acids and the like is increased and the odor efficiently acts on the body odor.

That is, the present inventors have focused on the fact that one of the causes of human body odor is a short-chain fatty acid produced by the decomposition of secreted sebum by bacteria on the skin surface, Since the above-mentioned porous powder (composite powder) having silicon dioxide and magnesium oxide as main components and having specific physical properties is particularly highly lipophilic, it is a foul-smelling substance generated with the sebum that is the cause of the foul odor. It has excellent properties of efficiently adsorbing both fatty acids, is particularly suitable for deodorizing body odor, and since magnesium oxide in the above composite powder neutralizes and deodorizes various malodors due to its neutralizing effect, adsorption The malodorous substance is found to be neutralized with magnesium oxide and is unlikely to be volatilized again from the above composite powder. In particular, if the above composite powder is amorphous, the above composite powder will be applied to human skin. A composition containing When applied, its irregular shape, easily enter the skin grooves on the skin surface, showing the applied portion more smoothly, and found that an effect to smooth feel, the present invention has been accomplished.

Therefore, the present invention is a composite of silicon dioxide and magnesium oxide as the main raw materials, has a pore volume of 0.05 ml / g or more, and an average particle size of 0.5-4.
There is provided a deodorant composition characterized by comprising a porous powder having a particle size of 0 μm and an oil absorption of 50 ml / 100 g or more. Here, the content of magnesium oxide in the porous powder is 20% by mass or more, the content of silicon dioxide is 44% by mass or more, and the ratio of the mass percentage (%) of silicon dioxide / magnesium oxide is 2%. 2-2.
It is more preferable that it is 5.

The present invention will be described in more detail below. The deodorant composition of the present invention is a composite of silicon dioxide and magnesium oxide as main raw materials and has a pore volume of 0.05 ml / g. Above, the average particle size is 0.5 to 4
It contains a porous powder having a diameter of 0 μm and an oil absorption of 50 ml / 100 g or more.

Here, the porous powder of the present invention is not one in which silica particles carry magnesium or form a film, but a silicic acid-magnesium composite porous powder (mainly composed of silicon dioxide and magnesium oxide) Hereinafter referred to as composite powder). And the pore volume is 0.05 ml / g
Or more, preferably 0.05 to 10 ml / g, more preferably 0.1 to 5 ml / g, and have an average particle size of 0.5 to 4
0 μm, preferably 1 to 20 μm, more preferably 3 to
The oil absorption is 10 μm and the oil absorption is 50 ml / 100 g or more, preferably 50 to 500 ml / 100 g, and more preferably 100 to 200 ml / 100 g. If the pore volume is too small, it will not be possible to exert a sufficient deodorizing effect, and
If the average particle size is too small, the dispersibility will be poor, and if it is too large, the feel will be poor. Further, if the oil absorption amount is too small, the deodorizing ability will not last long. The shape of the composite powder of the present invention is not limited to a spherical shape, and may be, for example, an amorphous shape. If the composite powder is an amorphous shape, the deodorant composition of the present invention is applied to the skin. When applied, it is more preferably amorphous because the applied part looks smoother and the feel is smoother.

In the present invention, the composite powder has a pore volume of Sorptomatic Se manufactured by Carlo Erba Co.
It can be confirmed by using Bies method using Ries 1800, and the average particle size is selected by selecting a typical particle from a photographic image obtained by a scanning electron microscope (S-570 manufactured by Hitachi) and using a scale. Can be confirmed by measuring the diameter of the particle image by using, and by using Coulter Counter (TA-II type manufactured by Coulter Electronics Co., Ltd.) method with an aperture tube of 20 μm and 50 μm. K-51
It can be confirmed by measuring according to 01.19.

Here, the content of magnesium oxide in the composite powder is 20% by mass or more, preferably 20 to 56% by mass, more preferably 20 to 30% by mass, and the content of silicon dioxide is 44%. Mass% or more, preferably 45
-80 mass%, more preferably 50-75 mass%, and the ratio of their mass percentages (%) (silicon dioxide / magnesium oxide) is 2.2-2.5. If the content of magnesium oxide is too low, the deodorizing effect may be insufficient, and if the content of silicon dioxide is too low, the powder may become brittle. Further, if the ratio of magnesium oxide to silicon dioxide is too small, whiteness may remain on the skin during use, and if it is too large, the feel may be impaired.

Further, as the above-mentioned composite powder, Mg ₃ Si ₄ O ₁₀ (OH) ₂ .nH ₂ O as a main component (where n is 5
The following numbers. ), And using a synthetic layered magnesium phyllosilicate having a unique laminated structure,
Especially effective.

When the synthetic layered magnesium phyllosilicate is used in the present invention, the production method is not particularly limited, but the production method described in Japanese Patent Publication No. 3-51651 (by acid treatment of clay minerals The obtained active silicic acid or active aluminosilicate and a magnesium oxide, a hydroxide or a compound capable of forming the above oxide or hydroxide under reaction conditions are hydrothermally treated to form a synthetic layered magnesium phyllosilicate. It is particularly effective to use the one manufactured by the manufacturing method).

As the composite powder having the above characteristics, those having the above characteristics can be appropriately selected and used from various commercially available silicic acid / magnesium composite porous powders.

The content of the composite powder in the deodorant composition of the present invention is not particularly limited and can be appropriately selected depending on the dosage form of the composition, etc.
It is suitable that the content is 0.01 to 60% by mass, preferably 0.1 to 30% by mass, and more preferably 0.1 to 25% by mass, based on the total amount of the composition. If the content of the composite powder is too small, it may be difficult to sufficiently obtain the deodorizing effect aimed at by the present invention. In some cases, it may be difficult to prepare a desired dosage form.

The deodorant composition of the present invention can be prepared into various dosage forms and used as a deodorant.
Powder, emulsion, lotion, gel, cream,
Antiperspirant and deodorant for body prepared in various dosage forms such as sheet, powder spray type, roll-on type, stick type, mist type, foam type, and applied to various parts of the body such as armpit and legs Can be used as such.

Further, the deodorant composition of the present invention is usually added depending on its dosage form and application within a range not impairing the effects of the present invention.
Various components to be blended can be blended, and as such components, for example, avocado oil, almond oil, olive oil, grape seed oil, sesame oil, sasanqua oil, safflower oil, soybean oil, camellia oil, corn oil, Rapeseed oil,
Fats and oils such as Persic oil, castor oil, sunflower oil, cottonseed oil, peanut oil, cocoa oil, palm oil, coconut oil, beef tallow, fish oil, hydrogenated oil, turtle oil, pork oil, mink oil, egg yolk oil;
Wax such as whale wax, shellac, beeswax, lanolin, carnauba wax, candelilla wax; hydrocarbons such as liquid paraffin, liquid polyisobutylene, squalane, pristane, petrolatum, paraffin, ceresin; succinic acid,
Fatty acids such as tartaric acid, citric acid, undecylenic acid, lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, oleic acid, linoleic acid, ricinoleic acid, behenic acid; ethanol, isopropanol, lauryl alcohol, cetanol, 2-hexyldecanol , Alcohols such as stearyl alcohol, isostearyl alcohol, oleyl alcohol and lanolin alcohol; polyhydric alcohols such as ethylene glycol, diethylene glycol monoethyl ether, triethylene glycol, polyethylene glycol, propylene glycol, 1,3-butylene glycol, glycerin and patyl alcohol Alcohol; sugars such as glucose, sucrose, lactose, xylitol, sorbitol, mannitol, maltitol, etc .; Pills, cetyl isostearate, oleyl oleate, decyl oleate, lanolin acetate, butyl stearate, isopropyl myristate, diethyl phthalate, hexyl laurate, and other esters; aluminum stearate, magnesium stearate, zinc stearate, and other metals. Soap; gum arabic, sodium alginate, casein, carrageenan,
Natural water-soluble polymer compounds such as karaya gum, agar, quince seed, gelatin, dextrin, starch, tragacanth, pectin, etc., semi-synthetic polymer compounds such as propylene glycol alginate, ethyl cellulose, crystalline cellulose, methyl cellulose; carboxyvinyl polymer, polyvinyl methyl ether , Synthetic polymer compounds such as methoxyethylene maleic anhydride copolymers; Silicone oils such as methylphenylpolysiloxane, dimethylpolysiloxane, decamethylpentasiloxane, methylhydrogenpolysiloxane; sorbitan trioleate, polyoxyethylene monooleate Polyoxyethylene nonyl phenyl ether, polyoxyethylene hydrogenated castor oil, polyoxyethylene alkyl ether phosphoric acid, polyoxyethylene alky Non-ionic surfactants such as luglyceryl and polyoxyethylene alkyl hydrogenated castor oil; anionic surfactants such as dialkyl sulfosuccinates, alkylallyl sulfonates, higher alcohol sulfate salts, phosphate ester salts; Paraoki Ethyl benzoate,
Preservatives such as methyl paraoxybenzoate; vitamins such as vitamin A, vitamin D, vitamin E, vitamin K; hormones such as estradiol, ethyl estradiol, cortisone; red 2, blue 1, red 202, yellow 201, Organic dyes such as green 204 and purple 201;
Inorganic pigments such as aluminum powder, talc, kaolin, bentonite, mica, titanium, red iron oxide, and calamine; UV absorbers such as urocanic acid and synogisate; anti-inflammatory agents such as allantoin, aloe powder, and guaiazulene; Freon 1
1, CFC 12, CFC 21, CFC 22, CFC 11
3, CFC 114, CFC C318, dimethyl ether, liquefied petroleum gas, methyl chloride, methylene chloride, isobutane, isopentane, carbon dioxide, and other propellants, and purified water can be used.

In the deodorant composition of the present invention, as other components, for example, aluminum hydroxy chloride, aluminum chloride, aluminum sulfate, basic aluminum bromide, aluminum phenol sulfonic acid, basic aluminum iodide, etc. Sweat agent; fungicide such as 3,4,4-trichlorocarbanilide (TCC), benzalkonium chloride, benzethonium chloride, alkyltrimethylammonium chloride, resorcinol, phenol, sorbic acid, salicylic acid, and hexachlorophene; jascent, skatole, Masking agents such as lemon oil, lavender oil, absolute, jasmine, vanillin, benzoin, benzyl acetate, menthol and the like can be added by a conventional method.

A list of perfume raw materials used as perfumes that can be incorporated into the deodorant composition of the present invention can be found in various publications, for example "Perfume and Flavor Chem".
icals ", Vol. I and II, Step
fen Arctander, Allured Pu
b. Co. (1994), "Synthetic Perfume Chemistry and Product Knowledge", Genichi Indo, Kagaku Kogyo Nipposha (1996), "P.
erfume and Flavor Material
Is Of Natural Origin ", St
effen Arctander, Allured P
ub. Co. (1994), "Encyclopedia of Fragrances", edited by The Japan Fragrance Association, Asakura Shoten (1989), "Perfumer"
y Material Performance V.I.
3.3 ", Boelens Aroma Chemical
al Information Service (19
96) and "Flower oils and Flo.
ralCompounds In Perfumer
y ”, Danute Lajaujis Anoni
s, Allured Pub. Co. (1993) and the like, each of which is incorporated by reference.

Typical examples of the fragrances are shown below, but the fragrances are not limited to these. <Hydrocarbon compound> Ocimene, dihydromyrcene, farnesene, cedrene, α-pinene, β-pinene, limonene, dipentene, camphene, ferrandrene, terpinene, 3-carene, terpinolene, bisabolen, β
-Caryophyllene, kazinene, valensen, tsuyopsen, guaien, aloocimene, myrcene, longifolene, veldracin (1,3,5-undecatriene),
p-cymene, 4-isopropyl-1-methyl-2-propenylbenzene, diphenyl, diphenylmethane, orange terpene, lemon terpene, bergamot terpene, peppermint terpene, spearmint terpene, lime terpene, vetiver terpene, rose wax, jasmine wax, limonene dimer , Pentane, hexane, heptane, octane, nonane, decane, undecane, dodecane, tridecane, tetradecane, pentadecane, hexadecane, heptadecane, octadecane, nonadecane, icosane, henicosane, docosane, tricosane, tetracosane, pentacosane, hexacosane, heptakosan, octacosan, octacosan , Triacontane and the like.

<Alcohol-based compound> 3-methyl-1-
Pentanol, geraniol, cedrol, citronellol, rosinol, nerol, dihydrolinalool, linalool, tetrahydrolinalool, dimethyloctanol, tetrahydromugol, mugol, myrcenol, dihydromyrcenol, osimenol, tetrahydromyrcenol, lavandulol, isodihydro Lavandulol, hydroxycitronellol, nonadyl (6,8-dimethyl-2-nonanol), ethyl linalool, isopulegol, terpineol, dihydroterpineol, terpineol-4, perilla alcohol,
4-tunanol, 3-tunanol, farnesol, nerolidol, α-bisabolol, β-caryophyllene alcohol, santalol, betiverol, cedrenol, patchouli alcohol, dihydrocarbeol, phytol, isophytol, sclareol, carveol, menthol, 1-heptanol , 2-heptanol, 3-heptanol, 1-octanol, 2-octanol, 3-octanol, 2-ethylhexanol,
1-nonanol, 2-nonanol, isononyl alcohol (3,5,5-trimethyl-1-hexanol), 1
-Decanol, 1-undecanol, 2-undecanol, 1-dodecanol, prenol (3-methyl-2-
Butene-1-ol), 2-methyl-3-butene-2-
All, β-pentenol (1-penten-3-ol), leaf alcohol (cis-3-hexenol), trans-2-hexenol, trans-3
-Hexenol, cis-4-hexenol, 2,4-
Hexadiene-1-ol, matsutakeol (1-octen-3-ol), cis-6-nonenol, cucumber alcohol (2,6-nonadienol), androl (1-nonen-3-ol), rosalva (9 -Decenol), 1-undecenol, undecabertol (4-methyl-3-decen-5-ol), ocilol (3,7-dimethyl-7-methoxy-2-octanol), santalinol (2-methyl-). 4- (2,2,3
-Trimethyl-3-cyclopenten-1-yl) -2-
Butene-1-ol), p, α-dimethylbenzyl alcohol, 2,2,6-trimethylcyclohexyl-3-
Hexanol, 1,2-pentanediol, benzyl alcohol, anis alcohol, β-phenylethyl alcohol, styralyl alcohol (1-phenyl-1-hydroxyethane), hydratropa alcohol, methyl β
-Phenylethyl alcohol, α-propylphenylethyl alcohol, vanillyl alcohol, decahydro β-
Naphthol, furfuryl alcohol, 3-methyl-1-
Phenyl-3-pentanol, amylcinnamic alcohol, cinnamic alcohol, phenoxanol (3-methyl-5-phenylpentanol), 1,2-
Pentanediol, 2-ethylhexanol, dimethol (2,6-dimethylheptanol), 3,6-dimethyl-3-octanol, cohinol (3,4,5,6,6)
6-pentamethyl-2-heptanol), brahamanol (methyltrimethylcyclopentenylbutanol),
Bactanol (2-ethyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -2-butene-
1-ol), sandalol (3-methyl-5- (2,
2,3-Trimethylcyclopent-3-en-yl)-
Pentan-2-ol), cyclohexylethyl alcohol, apopachon (p-isopropylcyclohexanol), fluoralol (2,4-dimethyl-3-cyclohexene-1-methanol), pachone (p-tert).
-Butylcyclohexanol), Belldol (o-te
rt-butylcyclohexanol), mayol (p-
Isopropylcyclohexylmethanol), cyclomethylene citronellol, ambrinol (2,5,5-trimethyl-octahydro-2-naphthol), methylsandeflor (5'or6'-methylnorborn-5 ')
-En-2-yl) -2-methylpent-1-ene-3
-Ol), timbelol (2,2,6-trimethylcyclohexyl-3-hexanol), polysanthol (3,3-dimethyl-5- (2,2,3-trimethyl-
3-Cyclopenten-1-yl) -4-pentene-2-
All), hydroxycitronellol, nonadyl (6,8-dimethyl-2-nonanol), isopulegol, isocyclogeraniol, myrtenol, nopol (6,6-dimethylbicyclo [3.1.1] hept-2)
-Ene-2-ethanol), pinocarbeol, α-phenalkyl alcohol, borneol, isoborneol, patchhomint (2- (3,3-dimethylbicyclo [2.2.1] hept-2-ylidene) ethanol),
Camecol (trimethylnorbornanemethanol), dimethylcyclomol, Santarex T (isocamphylcyclohexanol), geranyl linalool, cumin alcohol, 2-methoxyphenylethyl alcohol,
Phenoxyethyl alcohol (1-hydroxy-2-phenoxyethane), α, α-dimethylphenylethyl alcohol, isobutylbenzylcarbinol, p-methylbenzylcarbinol, hydrocinnamic alcohol, centifold (1,1-dimethyl-3) -Phenyl propanol-1), muguet alcohol (2,2-
Dimethyl-3-phenylpropanol), phenylhexanol, decahydro β-naphthol, AR-1 (3,
6-dimethyloctane-3-ol), avitol (hydroabietyl alcohol), α-propylphenylethyl alcohol, p-methyldimethylbenzylcarbinol, mugetanol (1- (4-isopropylcyclohexyl) ethanol), fluorol (2- Isobutyl-
4-hydroxy-4-methyltetrahydropyran), propylene glycol, dipropylene glycol, hexylene glycol and the like.

<Phenolic and phenol ether compounds> Anisole, estragal, chabicol,
Anethole, cresol, carvacrol, p-cresol, p-cresyl methyl ether, β-naphthol methyl ether, β-naphthol ethyl ether, β-
Naphthol isobutyl ether, veratrol (1,2
-Dimethoxybenzene), 1,3-dimethoxybenzene, 1,4-dimethoxybenzene, catechol, resorcinol, guaiacol, valspice (4-methylguaiacol), 4-ethylguaiacol, orcinyl-3.
(3-methoxy-5-methylphenol), thymol,
Methylthymol, propenyl guaetol (trans
-2-ethoxy-5- (1-propenyl) -phenol), o-ethylphenol, m-ethylphenol,
p-ethylphenol, 2-tert-butylphenol, syringol (2,6-dimethoxyphenol),
Hydroquinone dimethyl ether, resorcinol dimethyl ether, eugenol, isoeugenol, dihydroeugenol, methyleugenol, methylisoeugenol, ethylisoeugenol, benzyleugenol, benzylisoeugenol, diosphenol, hinokitiol, banitrop (1-ethoxy-2-hydroxy-4-propenyl Benzene), shogaol,
Examples thereof include gingerol, acetyleugenol, acetylisoeugenol safrole, isosaflor, diphenyl oxide, vetiver ether (tert-butylhydroquinone dimethyl ether) and the like.

<Aldehyde compound> Citronellal,
Citral, 3,7-dimethyl-1-octanal, hydroxycitronellal, methoxycitronellal, perilaldehyde, myrtenal, caryophyllene aldehyde, n-hexanal, 2-methylbutanal, isovaleraldehyde, n-valeraldehyde, acetaldehyde. , N-heptanal, n-octanal, n-nonanal, 2-methyloctanal, 3,5,5-trimethylhexanal, 1-decanal, undecanal, dodecanal, 2-methyldecanal, 2-methylundecanal, tride Canal, tetradecanal,
2-pentenal, cis-3-hexenal, tra
ns-2-hexenal, trans-2-heptenal, 4-heptenal, trans-2-octenal, trans-2-nonenal, cis-6-nonenal, melonal (2,6-dimethyl-5-heptenal), trans-4 -Decenal, cis-4-decenal, trans-2-decenal, grinal (2,5,6-trimethyl-4-heptenal), 10
-Undecenal, trans-2-Undecenal,
trans-2-dodecenal, mandarin aldehyde (3-dodecenal), trans-2-tridecenal, adoxal (2,6,10-trimethyl-9-undecen-1-al), 2,4-hexadienal,
2,4-heptadienal, 2,4-octadienal, 2,4-nonadienal, 2,6-nonadienal, 2,4-decadienal, 2,4-undecadienal, 2,4-dodecadienal, geralaldehyde (5 ，
9-dimethyl-4,8-decadienal), trimenal (3,7,9-trimethyl-2,6-decadiene-1)
-Earl), oncidar (2,6,10-trimethyl-5,9-undecadienal), bergamar (α-
Methylene citronellal), camphorene aldehyde,
Cyclocitral, isocyclocitral, safranal (2,6,6-trimethyl-1,3-cyclohexadiene-1-carboxaldehyde), muguealdehyde (6,10-dimethyl-3-oxa-9-undecenal), geranyloxy Acetaldehyde, tripral (dimethyltetrahydrobenzaldehyde), chrysantal (3-propylbicyclo [2,2,1] -5-heptene-2-carboxaldehyde), centenal (methoxydicyclopentadienecarboxaldehyde), dupicar (4-tricyclodecyl) Ridenbutanal), 4- (4-methyl-3-cyclohexenylidene-1) pentanal, mylacaldehyde (4 (3)
-(4-Methyl-3-penten-1-yl) -3-cyclohexene-1-carboxaldehyde), setonal (trimethylcyclohexenemethylbutanal), inonal (2-methyl-4- (2,6,6-trimethyl) −
1 (2) -cyclohexenyl) -butenal), terestral (4-cyclooctene-1-carboxaldehyde), benzaldehyde, p-tolylaldehyde, phenylacetaldehyde, trifernal (3-phenylbutanal), cuminaldehyde, p -Methylphenylacetaldehyde, p-isopropylphenylacetaldehyde, hydratropaldehyde, p-methylhydratropaldehyde, p-isopropylhydratropaldehyde, phenylpropionaldehyde, β-methylhydrocinnamic aldehyde, jasmolandi (2
-Methyl-3- (4-methylphenyl) -propanal), burgeonal (p-tert-butylhydrocinnamic aldehyde), cyclamenaldehyde (2
-Methyl-3- (p-isopropylphenyl) -propionaldehyde), Florarozone (p-ethyl-α, α)
-Dimethylhydrocinnamic aldehyde), Suzral (p-isobutyl-α-methylhydrocinnamic aldehyde), cinnamic aldehyde, salicylaldehyde, anisaldehyde, o-methoxybenzaldehyde, o-methoxycinnamic aldehyde, canthoxal (2-methyl -3- (p-methoxyphenyl) -propanal), vanillin, ethylvanillin, methylvanillin (3,4-dimethoxybenzaldehyde), heliotropin, helional (α-methyl-3,4-methylenedioxyhydrocinnamic aldehyde) ), Phenoxyacetaldehyde, p-methylphenoxyacetaldehyde, furfural, 5-methylfurfural, 5-
Hydroxymethyl-2-furfural, furyl acrolein, lyral (4 (3)-(4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde), bernaldehyde (1-methyl-4-)
(4-methylpentyl) -3-cyclohexenecarboxaldehyde), homomylacaldehyde (1-methyl-4 (4-methyl-3-pentenyl) -3-cyclohexenecarboxaldehyde), junipearl (4
(5) -Formyl-7,7,9-trimethylbicyclo [4.3.0] -nonene), vertoral (octahydro-4,7-methanoindenecarboxaldehyde), lilial (p-tert-butyl-α-). Methylhydrocinnamic aldehyde), Mefuranal (3-
Methyl-5-phenylvaleraldehyde), englandal (4-methyl-2-phenyl-2-pentenal),
Cocar (5-methyl-2-phenyl-2-hexenal), α-methylcinnamic aldehyde, α-butylcinnamic aldehyde, α-amylcinnamic aldehyde, α-hexylcinnamic aldehyde, formylethyltetramethyltetralin (6 -Ethyl-7-formyl-1,1,4,4-tetramethyl-1,2,
3,4-tetrahydronaphthalene) and the like.

<Acetal-based and ketal-based compounds> Magnolane (2,4-dimethyl-4,4a, 5,9b-tetrahydroindeno [1.2d] -1,3-dioxane), anthoxane (4-isopropyl-) 5,5-dimethyl-1,3-dioxane), indoflor (dihydroindenyl-2,4-dioxane), boasanbrenforte (formaldehyde cyclododecylethyl acetal), acetaldehyde diethyl acetal, leaf acetal (acetaldehyde ethylhexenyl acetal). ), Acetaldehyde ethylhexyl acetal, citronellyl methyl acetal, elletal (acetaldehyde ethyl linalyl acetal), Bonalox (2,4-dioxane-3-methyl-7,10-methanospiro [5.5]. Decane), efetal (acetaldehyde ethyl phenyl acetal), acetaldehyde ethyl isoeugenyl acetal, acetal R (acetaldehyde phenyl ethyl n-propyl acetal), fluoropearl (acetaldehyde 2-phenyl-2,4-pentanediol acetal), spiroflor ( 3-Ethyl-2,4-dioxaspiro [5.
5] undecene-8-ene), ethyldimethyldioxaspiroundecene, herboxane (2-butyl-4,
4,6-trimethyl-1,3-dioxane), caranal (2- (2,4-dimethylcyclohex-3-cene-1)
-Yl) -5-methyl-5 (1-methylpropyl) 1,
3-dioxane), hexanal dimethyl acetal,
Hexanal diethyl acetal, hexanal propylene glycol acetal, carotene (4,7-dihydro-2- (3-pentanyl) -1,3-dioxepin), 2-hexenal diethyl acetal, cis-
3-hexenal diethyl acetal, heptanal dimethyl acetal, heptanal diethyl acetal,
Heptanal ethylene glycol acetal, 2-hexyl-5-methyl-1,3-dioxolane, 5-methyl-5-propyl-2- (1-methylbutyl) -1,3-
Dioxane, octanal dimethyl acetal, octanal diethyl acetal, nonanal dimethyl acetal, nonanal diethyl acetal, decanal dimethyl acetal, decanal diethyl acetal, 2-
Methyl undecanal dimethyl acetal, dodecanal dimethyl acetal, citral dimethyl acetal, citral diethyl acetal, citral propylene glycol acetal, citronellal cyclomonoglycol acetal, hydroxy citronellal dimethyl acetal, hydroxy citronellal diethyl acetal, cis-3- Hexenal diethyl acetal, benzaldehyde dimethyl acetal, benzaldehyde diethyl acetal, benzaldehyde propylene glycol acetal, benzaldehyde glycerin acetal, phenylacetaldehyde dimethyl acetal, phenylacetaldehyde ethylene glycol acetal, phenylacetaldehyde diisobutyl acetal, phenylacetal Toaldehyde propylene glycol acetal, phenylacetaldehyde 2,3-butylene glycol acetal, phenylacetaldehyde glyceryl acetal, resedabody (phenylacetaldehyde-2,4-dihydroxy-2-methylpentane acetal), 3-phenylpropionaldehyde dimethyl acetal, hydratropa Aldehyde dimethyl acetal, hydratropaldehyde aldehyde ethylene glycol acetal, osminal DMA (amylcinnamic aldehyde dimethyl acetal), osminal DEA
(Amylcinnamic aldehyde diethyl acetal), heliotropin dimethyl acetal, heliotropin diethyl acetal, vanillin propylene glycol acetal, verdoxane (2,2,5,5-tetramethyl-4-isopropyl-1,3-dioxane), amber sage (4,7-Dihydro-2-isopentyl-
2-Methyl-1,3-dioxepin), acetoketal (2,5,5-trimethyl-2-phenyl-1,3-dioxane), jasmonan (2-butyl-4-dioxaspiro [4.4] nonanone), Freiston (Ethyl-
2,4-dimethyl-1,3-dioxolane-2-acetate), fructon (ethyl-2-methyl-1,3-dioxolane-2-acetate) and the like can be mentioned.

<Ketone-based compound> Acetyl caryophyllene, carvone, pulegone, piperitenone, piperiton,
Menthone, Shaw Brain, Oxocedran, Isolongiforanone, Nootkatone, 2-heptanone, 2-pentanone, 3-hexanone, 3-heptanone, 4-heptanone, 2-octanone, 3-octanone, 2-nonanone,
3-nonanone, 2-undecanone, 2-tridecanone,
Methyl isopropyl ketone, ethyl isoamyl ketone,
Mesityl oxide, butylideneacetone, methylheptadienone, methylheptenone, dimethyloctenone,
Coabon (4-methylene-3,5,6,6-tetramethyl-2-heptanone), geranylacetone, farnesylacetone, acetoin, butyroin (5-hydroxy-4-octanone), methyl lavender ketone (3-hydroxymethyl-). 2-nonane), diacetyl, 2,3-
Pentadione, 2,3-hexadione, 3,4-hexadione, 2,3-heptadione, acetylisovaleryl, amylcyclopentanone, amylcyclopentenone, 2-cyclopentylcyclopentanone, hexylcyclopentanone, fluuramon (2 -N-heptylcyclopentanone), cis-jasmon, dihydrojasmon, isojasmon, trimethylpentylcyclopentanone, sedamone (2-butylidene-3,5,5 (3,3)
3,5) -Trimethylcyclopentanone), Sandex (3-methyl-5- (2,2,3-trimethyl-3-)
Cyclopentenyl) -3-penten-2-one), cyclotene, coronol (3,5-dimethyl-1,2-cyclopentadione), methylchorilone (3,4-dimethyl1,2-cyclopentadione), belldone ( 2-ter
t-butylcyclohexanone), p-tert-butylcyclohexanone, Hellback (3,3-dimethylcyclohexylmethylketone), frescomente (2-se)
c-butylcyclohexanone), Artemon (1-acetyl-3,3-dimethyl-1-cyclohexene), celery ketone (3-methyl-5-propyl-2-cyclohexenone), krypton (4-isopropyl-2-cyclohexanone) , Oribbon (p-tert-pentylcyclohexanone), Methylcyclocitron (2,3,5
-Trimethyl-4-cyclohexenyl-1-methylketone), Nerone (1- (p-menthen-6-yl) -1-)
Propane), vetiver (4-cyclohexyl-4-methyl-2-pentanone), havanol (2- (1-cyclohexen-1-yl) -cyclohexanone), maltol, ethyl maltol, oxide ketone (cis-).
2-acetonyl-4-methyl-tetrahydropyran),
Emoxiflon (5-ethyl-3-hydroxy-4-methyl-2 [5H] -furanone), homoflor (2-ethyl-4-hydroxy-5-methyl-3 [2H] -furanone and 5-ethyl-4-hydroxy. 2-Methyl-3 [2H] -furanone), Sotron (3-hydroxy-4,5-dimethyl-2 [5H] -furanone), Furaneol (2,5-dimethyl-4-hydroxy-3 [2]
H] -furanone), acetyldimethylfuran, furfural acetone, 2-acetyl-5-methylfuran, 2-
Acetylfuran, methyltetrahydrofuranone, dibenzyl ketone, benzophenone, methylnaphthyl ketone,
4-Damascol (5-phenyl-5-methyl-3-hexanone), Bethicone (4-methyl-4-phenyl-2)
-Pentanone), α-methylanisalacetone, heliotropylacetone, anisylideneacetone, anisylacetone, p-methoxyphenylacetone, raspberry ketone (4- (p-hydroxyphenyl) -2-butanone), labandone (3- Methyl-4-phenyl-3-
Butene-2-one), benzylideneacetone, p-methoxyacetophenone, p-methylacetophenone, propiophenone, acetophenone, damacenone, damascon, isodamascon, α-dynascon (1- (5,5
-Dimethylcyclohexen-1-yl) -4-penten-1-one), iriton (4- (2,4,6-trimethyl-3-cyclohexen-1-yl) -3-buten-2
-One and 4-3,5,6-trimethyl-3-cyclohexen-1-yl) -3-buten-2-one),
Ionone, pseudoionone, methylionone, methylyriton (3-methyl-4- (2,4,6-trimethyl-3-
Cyclohexenyl) -3-buten-2-one), cyclowood (2,4-di-tert-butylcyclohexanone), iron, allylionone, 2,6,6-trimethyl-2-cyclohexene-1,4-dione, Kamek DH
(2-acetyl-3,3-dimethylnorbornane), Florex (6-ethylideneoctahydro-5,8-methano-2H-1-benzopyran-2-one), plicaton (4-methyltricyclo [6.2]. .1.0 ^2,7] undecane-5-one), Okisosedoran, belt fix (9-acetyl -2,6,6,8- tetramethyl tricyclo [5.3.1 ^1,7 .0 ^1,5 ] -8-Undecen),
Verbenone (4,6,6-trimethyl- (1R) -bicyclohept-3-en-2-one), fencon, caron (7-methyl-3,5-dihydro-2H-benzodioxepin-3-one) , Trimofix O (2, 6,
10-trimethyl-1-acetyl-2,5,9-cyclododecatriene), vittalide (acetyldimethyltetrahydrobenzindane), epiton (7 (8) -acetyl-5-isopropyl-2-methylbicyclo [2.
2.2] Oct-2-ene), Atrinone (4 (5)-
Acetyl-7,7,9 (7,7,9) -trimethylbicyclo [4.3.0] -1-nonene), cashmere (6,7-dihydro-1,1,2,3,3-pentamethyl-) 4 (5H) -indanone), muscone (3-methylcyclopentadecanone-1), civetone (cycloheptadeca-9-en-1-one), exalton (cyclopentadecanone), musk TM-II (cyclohexene) Sadesenone), phantolide (5-acetyl-1,1,2,
3,3,6-hexamethylindane), celestolide (4-acetyl-6-tert-butyl-1,1-dimethylindane), traseolide (5-acetyl-3-)
Isopropyl-1,1,2,6-tetramethylindane), tonalide (6-acetyl-1,1,2,4,4,4)
7-hexamethyltetrahydronaphthalene), vitalide (acetyldimethyltetrahydrobenzindane),
Iso E Super (7-acetyl-1,2,3,3
4,5,6,7,8-octahydro-1,1,6,7-
Tetramethylnaphthalene), dihydrocarboxylic, diosphenol, zingerone and the like.

<Ether Compound> Methylhexyl Ae
Tell, decyl methyl ether, decyl vinyl ether,
Diethylene glycol monomethyl ether, diethylene
Glycol monoethyl ether, citronellyl ethyl ether
Ether, geranyl ethyl ether, α-terpinyl meth
Ruther, Herbabert (3,3,5-trimethyl
Chlorhexyl ethyl ether), isobornyl methyl ether
Ether, tricyclodecenyl methyl ether, isopro
Xene (2-ethylidene-6-isopropoxybicyclo
[2.2.1] heptane), juniparome (methoxy)
Dimethyltricyclo [5.2.1.0] ^2,6] Decane),
Cyclododecyl methyl ether, Madrox (1-me
Cylcyclododecyl methyl ether), Fizeol
(2-Ethoxy-2,6,6-trimethyl-9-methyle
Nbicyclo [3.3.1] -nonane), Sedlumbar
(Cedrol methyl ether), methylbenzyl ether
, Methyl phenyl ethyl ether, ethyl 2-methoxy
Cibenzyl ether, allyl phenyl ethyl ether,
Isoamyl benzyl ether, Answer (isoamyl fluff
Phenyl ethyl ether), jacene (2-methyl-2-
Butenyl phenyl ethyl ether), dibenzyl ether
L, cyclohexyl phenyl ether, myrooxide
(Ocimene epoxide), limonene oxide (p-me
Inter-8-ene-1,2-epoxide), rubofix
(Spiro [1,4-methanonaphthalene-2 (1H),
2'-oxirane], -3, 4, 4a, 5, 8, 8a-
Hexahydro-3 ', 7-dimethyl and spiro
[1,4-methanonaphthalene-2 (1H), 2'-oxy
Silane], -3,4,4a, 5,8,8a-hexahydr
(3-3 ', 6-dimethyl), trimethylcyclododecato
Liene epoxide, caryophyllene oxide, sedre
Epoxide, isolongifolene epoxide, linaro
Oxide, citrooxide (2,2-dimethyl
-5 (1-methyl-1-propenyl) -tetrahydrof
Orchid), herboxoxide (5-isopropenyl-2-)
Methyl-2-vinyltetrahydrofuran), rose hula
(3-methyl-2- (3-methyl-2-butenyl)-
Furan), heptabelt (2-heptyltetrahydrof
Orchid), Mentofuran, Theaspiran, Oxybet
(2-oxaspiro [4,7] dodecane), muscogen
(3-Oxabicyclo [10.3.0] -6-pentade
Sen), cyclumber (13-oxabicyclo [10.
3.0] pentadecane), ambroxane (decahydro)
-3a, 6,6,9a-tetramethylnaphtho [2.1-
b] Furan), glycalva (3a-ethyldodecahydro)
-6,6,9a-Trimethylnaphtho [2.1-b] fura
), 1,8-cineole, 1,4-cineole, gala
Xolide (1,3,4,6,7,8-hexahydro-
4,6,6,7,8,8-hexamethylcyclopenta-
γ-2-benzopyran), rose oxide, nerol
Oxide, Limethol (2,2,6-trimethyl-6
-Vinyl tetrahydropyran), dilan (2-butyl-
4,6-Dimethyldihydropyran), Dremox (Te
Trahydro-4-methyl-2-phenyl-2H-pyra
), Ruvofloor (9-ethylidene-3-oxatrishi)
Black [6.2.1.0]^2,7] Undecane), Hexahide
Loindenopyran and the like can be mentioned.

<Acid compound> Gellan acid, acetic acid, propionic acid, pyruvic acid, butyric acid, isobutyric acid, 2-methylbutyric acid,
2-ethylbutyric acid, valeric acid, isovaleric acid, 2-methylvaleric acid, 3-methylvaleric acid, hexanoic acid, isohexanoic acid,
2-hexanoic acid, 4-pentenoic acid, 2-methyl-2-pentenoic acid, heptanoic acid, 2-methylheptanoic acid, octanoic acid, nonanoic acid, decanoic acid, 2-decenoic acid, undecylenic acid, dodecanoic acid, myristic acid , Palmitic acid, stearic acid, anthranilic acid, oleic acid, levulinic acid,
Lactic acid, benzoic acid, phenylacetic acid, cinnamic acid, 3-phenylpropionic acid, vanillic acid, valine, abietic acid,
Examples thereof include sorbic acid.

<Lactone compound> Pentalide (cyclopentadecanolide), havanolide (oxacyclohexadecen-2-one), ambrettolide, cyclohexadecanolide, 10-oxahexadecanolide, 11-oxahexalide Decanolide, 12-oxahexadecanolide, ethylenedodecanedioate, γ-butyrolactone, γ-valerolactone, angelicalactone, γ-hexalactone, γ-heptalactone, γ-octalactone, γ-nonalactone, whiskey lactone (3-methyl-4-octanolide), γ-decalactone, γ-undecalactone, γ-dodecalactone, γ-jasmolactone, jasmine lactone, cis-jasmon lactone,
Lactojasmon (4-methyl-4-decanolide), Jasmolactone (tetrahydro-6- (3-pentenyl) -2H-pyran-2-one), Mentalactone (3,6-Dimethyl-5,6,7, 7a-tetrahydro-2 (4H) -benzofuranone), n-butylphthalide, propylidenephthalide, butylidenephthalide, δ-
Hexalactone, δ-octalactone, trivalon (4,6,6 (4,4,6) -trimethyltetrahydropyran-2-one), δ-nonalactone, δ-decalactone, δ-2-decenolactone, δ-undeca Lactone, δ-dodecalactone, δ-tridecalactone, δ-
Tetradecalactone, lactocatone (decahydro-
4, α-hydroxy-2,8,8-trimethylnaphthalene-2-carboxyacid-δ-lactone), coumarin, dihydrocoumarin, cyclohexyl lactone, 6-
Methylcoumarin, ε-decalactone, ε-dodecalactone and the like can be mentioned.

<Ester Compound> Ethyl formate, propyl formate, butyl formate, amyl formate, isoamyl formate, hexyl formate, cis-3-hexenyl formate, octyl formate, linalyl formate, citronellyl formate, geranyl formate,
Neryl formate, rosinyl formate, terpinyl formate, ceryl formate, cariofeylene formate, afermat (α,
3,3-trimethylcyclohexanemethyl formate), oxyoctaline formate, benzyl formate, cinnamyl formate, phenylethyl formate, anisyl formate, eugenyl formate, decahydro-β-naphthyl formate, methyl acetate,
Ethyl acetate, propyl acetate, isopropyl acetate, butyl acetate, isobutyl acetate, 2-methylbutyl acetate, isoamyl acetate, amyl acetate, prenyl acetate, hexyl acetate,
Cis-3-hexenyl acetate, trans-2-hexenyl acetate, 2-ethylhexyl acetate, heptyl acetate, octyl acetate, 3-octyl acetate, octenyl acetate, nonyl acetate, decyl acetate, trimethylhexyl acetate, decenyl acetate, nonanediol acetate, Dodecyl acetate, dimethyl undecadienyl acetate, diacetyl, diacetin, triacetin, ethylene glycol diacetate, ethylene glycol monobutyl ether acetate, allyl amyl glycolate, ocimenyl acetate, myrcenyl acetate, dihydromyrcenyl acetate, dimethyl octanyl acetate, linalyl acetate , Citronellyl acetate, rosinyl acetate, geranyl acetate, neryl acetate, tetrahydromugol acetate, ethyl linalyl acetate, lavandulyl acetate, isohydrolavandryl acetate, vinegar Nerolidol, carbyl acetate, dihydrocarbyl acetate, dihydrocuminyl acetate, terpinyl acetate, isopulegol acetate, menthyl acetate, citryl acetate, mirtenyl acetate, nopyr acetate, phenalkyl acetate, bornyl acetate, isobornyl acetate, cedolyl acetate, caryophyllene acetate, santalyl acetate , Vetiveryl acetate, guaiac acetate, cyclopentylidene methyl acetate,
Cyclohexyl acetate, p-isopropylcyclohexanyl acetate, tert-amyl cyclohexyl acetate, dihydroterpinyl acetate, cyclohexyl ethyl acetate, fluorolate (2,4-dimethyl-3-cyclohexenylmethyl acetate), rosamsk (α, 3 acetate). 3-trimethylcyclohexanemethyl), Vertenex (acetic acid p-te
rt-Butylcyclohexyl), Belldox (acetic acid o
-Tert-butylcyclohexyl), 1-ethynylcyclohexyl acetate, dihydroambulate (1-acetoxy-2-sec-butyl-1-vinylcyclohexane), miraldyl acetate (4 (3)-(4-methyl-3)
-Pentenyl) -3-cyclohexenyl methyl acetate), tricyclodecenyl acetate, tricyclodecyl acetate, benzyl acetate, p-cresyl acetate, phenylethyl acetate, styralyl acetate, p-methylbenzyl acetate, anisyl acetate, piperonyl acetate , Acetyl vanillin, rosephenone, hydratropyl acetate, 2,4-dimethylbenzyl acetate, cinnamyl acetate, phenylpropyl acetate, cuminyl acetate, dimethylbenzylcarbyl acetate, phenylglycol diacetate, dimethylphenylethylcarbyl acetate, phenylethylmethyl acetate Ethylcarbinyl, beticol acetate (4-methyl-4-phenyl-2-pentylacetate), α-amylcinnamimiyl acetate, jasmalol (trans-decahydro-β)
-Naphthyl acetate), furfuryl acetate, tetrahydrofurfuryl acetate, jasmar (3-pentyltetrahydropyranyl acetate), jasmeria (5-methyl-3-butyltetrahydropyranyl acetate), ethyl acetoacetate, gesate (2-hexylacetoacetic acid) ethyl),
Ethyl benzyl acetoacetate, allyl cyclohexyl acetate, isopropyl cyclohexenyl acetate, ethyl propionate, propyl propionate, allyl propionate,
Butyl propionate, isobutyl propionate, isoamyl propionate, hexyl propionate, cis-3-hexenyl propionate, trans-propionate
2-hexenyl, decenyl propionate, linalyl propionate, citronellyl propionate, rosinyl propionate, geranyl propionate, neryl propionate,
Carbyl propionate, terpinyl propionate, menthyl propionate, bornyl propionate, isobornyl propionate, tricyclodecenyl propionate, benzyl propionate, styralyl propionate, anisyl propionate, phenylethyl propionate, cinnamyl propionate, propionate Acid phenylpropyl, dimethylbenzylcarbinyl propionate, phenoxyethyl propionate, propylene glycol dipropionate propionate, labdanax (3-hydroxy-
3 phenyl propionate), isobutyl furanpropionate, methyl butyrate, ethyl butyrate, propyl butyrate,
Isopropyl butyrate, allyl butyrate, butyl butyrate, isobutyl butyrate, amyl butyrate, isoamyl butyrate, hexyl butyrate,
Heptyl butyrate, cis-3-hexenyl butyrate, tr butyrate
ans-2-hexenyl, octyl butyrate, propylene glycol dibutyrate, linalyl butyrate, citronellyl butyrate, rosinyl butyrate, geranyl butyrate, neryl butyrate, terpinyl butyrate, cyclohexyl butyrate, benzyl butyrate, cinnamyl butyrate, phenylethyl butyrate, dimethylbenzylcarbyl butyrate , Tetrahydrofurfuryl butyrate, santaryl butyrate, methyl isobutyrate, ethyl isobutyrate, propyl isobutyrate, isopropyl isobutyrate, butyl isobutyrate, isobutyl isobutyrate, isoamyl isobutyrate, hexyl isobutyrate, cis-3-hexenyl isobutyrate, isobutyrate Butyric acid 2,4
-Hexadienyl, isopentylate (isobutyric acid 1,3
-Dimethyl-3-butenyl), octyl isobutyrate, linalyl isobutyrate, citronellyl isobutyrate, rosinyl isobutyrate, geranyl isobutyrate, neryl isobutyrate, terpinyl isobutyrate, tricyclodecenyl isobutyrate, benzyl isobutyrate, isobutyric acid p-cresyl, cinnamyl isobutyrate, phenylethyl isobutyrate, phenylpropyl isobutyrate, styrylyl isobutyrate, dimethylcarbinyl isobutyrate, dimethylphenylethylcarbinyl isobutyrate, floranol (phenoxyethyl isobutyrate), decahydroisobutyrate-
β-naphthyl, methyl 2-methylbutyrate, ethyl 2-methylbutyrate, 2-methylbutyl 2-methylbutyrate, sidorane (hexyl 2-methylbutyrate), cis-2-methylbutyrate
3-hexenyl, benzyl 2-methylbutyrate, phenylethyl 2-methylbutyrate, allyl 2-ethylbutyrate, ethyl 3-hydroxybutyrate, methyl valerate, ethyl valerate, butyl valerate, isobutyl valerate, amyl valerate, yoshi Herb acid c
is-3-hexenyl, benzyl valerate, phenylethyl valerate, furfuryl valerate, methyl isovalerate, ethyl isovalerate, propyl isovalerate, isopropyl isovalerate, allyl isovalerate, butyl isovalerate, iso Isobutyl valerate, isoamyl isovalerate, amyl isovalerate, 2-methylbutyl isovalerate, isovaleric acid cis
-3-hexenyl, hexyl isovalerate, octyl isovalerate, linalyl isovalerate, citronellyl isovalerate, geranyl isovalerate, menthyl isovalerate, terpinyl isovalerate, cyclohexyl isovalerate, benzyl isovalerate, Phenylethyl isovalerate, phenylpropyl isovalerate, cinnamyl isovalerate, manzanate (ethyl 2-methylvalerate), phenyl salicylate,
Peranato (2-methylvaleric acid 2-methylpentyl ester), methyl hexanoate, ethyl hexanoate, propyl hexanoate, isopropyl hexanoate, allyl hexanoate, butyl hexanoate, isobutyl hexanoate, amyl hexanoate, isoamyl hexanoate, Hexyl hexanoate, cis-3-hexenyl hexanoate, hexanoate t
rans-2-hexenyl, heptyl hexanoate, linalyl hexanoate, citronellyl hexanoate, geranyl hexanoate, citronellyl hexanoate, benzyl hexanoate, methyl isohexanoate, methyl 2-hexenoate, t
ethyl trans-2-hexenoate, methyl 3-hexenoate, ethyl 3-hexenoate, methyl 3-hydroxyhexanoate, ethyl 3-hydroxyhexanoate, ethyl 2-ethylhexanoate, mersat (3,5,5-trimethyl Ethyl hexanoate), berifuro (ethyl 6-acetoxyhexanoate), methyl heptanoate, ethyl heptanoate, propyl heptanoate, allyl heptanoate, octyl heptanoate, methyl octanoate, ethyl octanoate,
Amyl octanoate, butyl octanoate, propyl octanoate, allyl octanoate, isoamyl octanoate, hexyl octanoate, heptyl octanoate, octyl octanoate, linalyl octanoate, benzyl octanoate, phenylethyl octanoate, p-cresyl octanoate , 2-
Ethyl octenoate, methyl nonanoate, ethyl nonanoate,
Phenylethyl nonanoate, bouvartate (methyl 2-nonenate), methyl 3-nonenate, methyl decanoate, ethyl decanoate, isopropyl decanoate, butyl decanoate, isoamyl decanoate, ethyl 2-decenoate, 2,4
-Ethyl decadienoate, propyl 2,4-decadienoate, methyl undecylenate, butyl undecylenate, isoamyl undecylenate, methyl dodecanoate, ethyl dodecanoate, butyl dodecanoate, isoamyl dodecanoate,
Ethyl myristate, methyl myristate, isopropyl myristate, ethyl palmitate, ethyl stearate, butyl stearate, methyl oleate, ethyl oleate, methyl benzoate, ethyl benzoate, propyl benzoate, isopropyl benzoate, benzoic acid Allyl,
Isobutyl benzoate, isoamyl benzoate, prenyl benzoate, hexyl benzoate, cis-3-hexenyl benzoate, linalyl benzoate, geranyl benzoate, benzyl benzoate, phenylethyl benzoate, cinnamyl benzoate, methyl anisate, anise. Ethyl acid salt, methyl o-methoxybenzoate, ethyl o-methoxybenzoate, ethyl tiglate, hexyl tiglate, cis-tiglate
3-hexenyl, citronellyl tiglate, geranyl tiglate, benzyl tiglate, phenylethyl tiglate, cinnamyl tiglate, methyl angelica, butyl angelica, isobutyl angelica, isoamyl angelica, prenyl angelica, cis-3 angelica. -Hexenyl, 3-methylpentyl angelica, phenylethyl angelica, ethyl acrylate, phenylethyl methacrylate, ethyl crotonate,
Isobutyl crotonic acid, cyclohexyl crotonic acid, flutinato (4-methyl-pentan-2-ol-crotonate), pyroprunato (2-cyclopentyl-cyclopentyl crotonate), datilato (1-cyclohexylethyl crotonate), levulinate, levulinic acid Butyl, isoamyl levulinate, methyl lactate, ethyl lactate, amyl lactate, isobutyl lactate, cis-3-lactate
Hexenyl, butyl butyryl lactate, ethyl pyruvate,
Methyl gellanate, ethyl gellanate, methyl cyclogelanate, ethyl cyclogellanate, fructate (ethyltricyclo [5.2.1.0 ^2,6 ] decane-2-yl carboxylate), divescon (ethyl-2-ethyl- 6,
6-Dimethyl-2-cyclohexene-1-carboxylate & ethyl-2,3,6,6-tetramethyl-2
-Cyclohexenecarboxylate), ethylsafranate (ethyldehydrocyclogeranate), allyl cyclohexylpropionate, cyclogalvanate (allylcyclohexyloxyacetate), calixol (ethyl-2-methyl-6-pentyl-4-oxocyclohexyl-). 2-enecarboxylate), tachrysate (methyl-1-methyl-3-cyclohexenecarboxylate), floramate (ethyl-2-tert-butylcyclohexylcarbonate), jasmate cyclate (methylcyclooctylcarbonate), mahagonate (1
-Methyl-4-isopropyl-2-carbomethoxybicyclo [2,2,2] -oct-5-ene), phenylethyl pivalate, methyl jasmonate, hedion (methyl dihydrojasmonate), beramos (methyl-3, 6
-Dimethyl-β-resorsylate), methyl furancarboxylate, ethyl furancarboxylate, propyl furan acrylate, methyl heptine carboxylate, ethyl heptine carboxylate, isoamyl heptine carboxylate, methyl octinecarboxylate, ethyl octynecarboxylate , Methyl decincarboxylate, glycomel (3- (bicyclo [2.
2.1] Hept-5-en-2-yl) -3 methyl ester of methyloxirane carboxylic acid), methyl phenylglycidate, ethyl phenylglycidate, aldehyde C-16 (3-methyl-3-phenylglycol) Ethyl sidate), aldehyde C-20 (ethyl p-methyl-β-phenylglycidate), ethyl methyl p-tolylglycidate, ethyl citronellyl oxalate, diethyl succinate, dimethyl succinate, diethyl malonate, diethyl tartrate. , Diethyl adipate, diethyl sebacate, triethyl citrate, dimethyl phthalate, diethyl phthalate, dibutyl phthalate, methyl phenylacetate, ethyl phenylacetate, isopropyl phenylacetate, butyl phenylacetate, propyl phenylacetate, isobutyl phenylacetate, phenyl Acetic acid Amyl, phenyl hexyl acetate,
Cis-3-hexenyl phenylacetate, citronellyl phenylacetate, rosinyl phenylacetate, geranyl phenylacetate, menthyl phenylacetate, benzyl phenylacetate,
Phenylethyl phenylacetate, p-cresyl phenylacetate, eugenyl phenylacetate, isoeugenyl phenylacetate, methyl cinnamate, ethyl cinnamate, propyl cinnamate, isopropyl cinnamate, allyl cinnamate, isobutyl cinnamate, cinnamate Isoamyl cinnamate, linalyl cinnamate, benzyl cinnamate, cinnamyl cinnamate, phenylethyl cinnamate, methyl salicylate, ethyl salicylate, butyl salicylate, isobutyl salicylate, amyl salicylate, isoamyl salicylate, hexyl salicylate, cis-3 salicylate. -Hexenyl, cyclohexyl salicylate, phenyl salicylate, benzyl salicylate, phenylethyl salicylate, cyclopidene (methylcyclopentylidene acetate), ethyl-2,2,6
-Trimethylcyclohexane carbonate, avalin (methyl abietate), hercoline (methyl dihydroabietate), p-cresyl salicylate, allyl phenoxyacetate, ethyl phenylpropionate, ethylene brushlate, triacetin and the like.

<Nitrogen-containing compound> Methyl anthranilate, ethyl anthranilate, butyl anthranilate, cis-3-hexenyl anthranilate, phenylethyl anthranilate, cinnamyl anthranilate, methyl N-methylanthranilate, auranthiol (hydroxy Citronellal-methylanthranilate Schiff base), mevantoral (methylpropylacetaldehyde-methylanthranilate Schiff base), jasmentin (α-amylcinnamic aldehyde-methylanthranilate Schiff base), ligantral (methyl- (3 , 5-dimethyl-3-cyclohexene-
1-yl) methylene anthranilate), indole,
Skatole, clonal (dodecane nitrile), tangerine (2-tridecene nitrile), citralva (geranyl nitrile), citronellyl nitrile, lemonyl (3,7-dimethyl-2,6-nonadienitrile), cuminyl nitrile, cinnamalva (cinna) (Milnitrile), trimethylamine, pyridine, 3-ethylpyridine, 2-acetylpyridine, 3-acetylpyridine, 2
-Isobutylpyridine, 3-isobutylpyridine, 2-
n-pentylpyridine, 5-ethyl-2-methylpyridine, methyl nicotinate, 4- (1,4,8-trimethyl-3,7-nonadienyl) pyridine, quinoline, isoquinoline, p-methylquinoline, tetrahydro-p- Methylquinoline, 6-isopropylquinoline, isobutylquinoline, 2-isobutylquinoline, 6-sec-butylquinoline, 8-sec-butylquinoline, 6 (p) -t
ert-butylquinoline, 2-tert-butylquinoline, pyrazine, 2-methylpyrazine, 2,5-dimethylpyrazine, 2,6-dimethylpyrazine, 2,3,5-trimethylpyrazine, 2-ethylpyrazine, 2-ethyl. −
3-methylpyrazine, 2-ethyl-5-methylpyrazine, 2-ethyl-3,5 (3,6) -dimethylpyrazine, 2,3-diethylpyrazine, 2,3-diethyl-5.
-Methylpyrazine, tetramethylpyrazine, 2-methyl-5-vinylpyrazine, methoxypyrazine, 2-methoxy-3-methylpyrazine, 2-methoxy-3-ethylpyrazine, 2-methoxy-3-isopropylpyrazine, 2
-Isobutyl-3-methoxypyrazine, 2-acetylpyrazine, 2-acetyl-3-ethylpyrazine, methylthiomethylpyrazine, corylonepyrazine (5-methyl-
6,7-dihydrocyclopentapyrazine), 5-methylquinoxaline, cyclohexapyrazine (5,6,7,8)
-Tetrahydroquinoxaline), 1-methylpyrrole,
2-acetylpyrrole, pyrrolidine, indole (Schiff base of indole-hydroxycitronellal),
2-methylbenzoxazole, decahydrocyclododecaxazole, 5-methyl-3-heptanone oxime, bucoxime (bicyclo [3.2.1] octane-8
-One, 1,5-dimethyl-, oxime), Gardamide (N-methyl-N-phenyl-2-methylbutyramide), Musk xylol, Musk ketone, Musk ambrette, Musk tibetan, Mosken, 2,6-lutidine, piperidine , 2- (1,4,8-trimethyl-3,
7-nonadienyl) pyridine, 2- (2-pinene-10)
-Ylmethyl) pyridine, 4- (2-pinene-10-isomethyl) pyridine, piperine, capsaicin, nonanoic acid vanillylamide, quinine, perillartine (L-perilaldehyde α-anti-aldoxime), 2-isopropyl-4-methylthiazole , 2-isobutylthiazole and the like.

<Sulfur-containing compound> Thiazole, 4-methylthiazole, 4,5-dimethylthiazole, trimethylthiazole, 2-methyl-5-methoxythiazole,
2-isopropyl-4-methylthiazole, 4-methyl-5-vinylthiazole, 2-isobutylthiazole,
Sulfurol (4-methyl-5-thiazole ethanol), Sulfuryl acetate (4-methyl-5-thiazole ethanol acetate), 2-acetylthiazole, 5-acetyl-2,4-dimethylthiazole, benzothiazole, propylmercaptan, Hydrogen sulfide, isopropyl mercaptan, 2-methyl-3-butanethiol, allyl mercaptan, isoamyl mercaptan, thiogeraniol, limonene thiol, sulfox (8-mercaptomenthone) phenyl mercaptan, o
-Thiocresol, 2-ethylthiophenol, 2-naphthyl mercaptan, furfuryl mercaptan, 2-methyl-3-furanthiol, dimethyl sulfide, dimethyl disulfide, dimethyl trisulfide, methylpropyl disulfide, methylpropyl trisulfide,
Propyl disulfide, dipropyl trisulfide, diallyl sulfide, diallyl disulfide, dibutyl sulfide, methionol (3- (methylthio) -1-propanol), 3-methylthio-1-hexanol, methional (3- (methylthio) propionaldehyde), mint Sulfide, dithiospirofuran, furfurylmethyl sulfide, 2-methyl-5-methylthiofuran, methylfurfuryl disulfide, furfuryl disulfide, thiophene, tetrahydrothiophene, 3-
Thiophene carboxaldehyde, 5-methyl-2-thiophene carboxaldehyde, tetrahydrothiophen-3-one, trithioacetone, thioglycolic acid,
Methyl methylthioacetate, ethyl methylthioacetate, 2-mercaptopropionic acid, pineapple mercaptan (methylmercaptomethylpropionate), ethyl 3-methylthiopropionate, ethyl thioacetate, furfuryl thioacetate, furfuryl thiopropionate, methyl thiobutyrate, methyl Methanethiosulfonate, allyl isothiocyanate, benzyl isothiocyanate, thirazine (2,4,6-trimethyl-4,5-dihydro-1,
3,5-dithiazone), oxane (2-methyl-4-propyl-1,3-oxathiane) and the like.

<Natural fragrance> Asafetide daresinoid,
Ajowan Oil, Star Anise Oil, Avies Oil, Amiris Oil, Amblet Seed Oil, Ambergris tincture, Ylang Ylang Oil, Ylang Ylang Absolute, Iris Resinoid, Iris Absolute, Iris Oil, Wintergreen Oil, Elemiole Resin, Elemi Resinoid Absolute , Eremitinki, oakmos concrete, oakmos absolute, oakmoss resin, oakmoss resinoid, ocotia oil, osmanthus absolute,
Osmanthus Concrete, Opopanax Resinoid, Opopanax Absolute, Opopanax Oil, Olivananum Resinoid, Olivanum Absolute, Olivanamu Oil, Allspice Oil, Oregano Oil, Oreganooleoresin, Orange Oil, Orange Flower Absolute, Orange Flower Concrete, Cananga oil, garjun balsam, garjun balsam oil, cascari rubber lacquer oil, castorium absolute, cassi absolute, cassiflower oil, cassia oil, gardenia absolute, carnations absolute, cabreuba oil, camomil oil, cardamom oil, galbanum oil, Galvanum Resin, Galvanum Resinoid, Carawash Dooiru, carrot seed oil, Guadalmedina Yak wood oil, Guadalmedina Yak resin, Guadalmedina Yak concrete, camphor oil, Kubebaoiru,
Cumin oil, cumin absolute, cumin oleoresin, clary sage oil, grapefruit oil,
Clove oil, Costas oil, Copaiba balsam,
Copaiba balsam oil, copaiba balsam resin, coriander oil, sassafras oil, sandalwood oil, june absolute, perilla oil, citronella oil, jasmine absolute, jasmine concrete, juniper berry oil, civet absolute, civet tincture, john kill absolute, agarwood oil, Ginger oil, cinnamon oil, cinnamon bark oil, cinnamon leaf oil, cedar oil, styrax oil, styrax resinoid, spearmint oil, savory oil, sage oil, cedar oil, cedar leaf oil, geranium oil, celery seed oil, thyme oil,
Taguette oil, tarragon oil, tuberose absolute, dill oil, tea tree oil, torimos absolute, true balsam, nutmeg oil, narcissus absolute, neroli oil, violet leaf absolute, pine oil, basil oil, parsley relief oil, parsley seed oil, Parsley herb oil, patchouli oil, peppermint oil, vanilla absolute, honeysuckle absolute, palmarosa oil, valerian oil, bitter orange oil, hyssop oil, hiba oil, hyacinth absolute, fennel oil, figua solute, petitgrain oil, butchu oil, vetiver oil, penny. Royal oil, pepper oil, peppermint oil, bergamo Oil, peruvian balsam, benzoin tincture, benzoin resinoid, boad rose oil, borax oil, hop oil, hop concrete, hop absolute, marjoram oil, mandarin oil, mandarin oil, mimosa concrete, mimosa absolute, mimosa oil, millresinoid, mill Absolute, Mill oil, Musk absolute, Muskuki, Eucalyptus oil, Yuzu oil, Wormwood oil, Lime oil, Labdanum oil,
Labdanum Resinoid, Lavender Oil, Lavender Absolute, Lavandin Oil, Lavandin Absolute, Linaloe Oil, Lemon Oil, Lemongrass Oil, Rose Oil, Rose Absolute, Rose Concrete, Rosemary Oil, Lobage Oil, Laurel Oil, Laurel Leaf Oil, Wormwood Oil , Musk, spirit cat incense, dragon incense, raccoon incense, musk, chibata, etc.

<Prepared fragrance> Further, there are the following fragrance bases which are prepared fragrances in which fragrance components are combined. Citrus type base such as lemon tone, lime tone, orange tone, sweet orange tone, mandarin tone, bergamot tone, petit gren tone, neroli tone, lemongrass tone, a gourmet tone, etc. fresh type base, apple tone, peach tone, strawberry Tone, coconut tone, pineapple tone, raspberry tone, watermelon tone etc. fruity type base, rose tone, jasmine tone, muguet tone, lilac tone, carnation tone, hyacinth tone, tuberose tone, gardenia tone, mimosa tone, narciss tone, Floral type base such as violet tone, Iran tone, floral bouquet tone, cinnamon bark tone, cinnamon leaf tone, clove tone, Pimentoberry tone, nutmeg tone, pepper tone, cardamom tone, coriander tone, cumin tone etc. Wood, cedarwood, vetiver, sandalwood, guaiac wood, woody bar, woody iris and other woody type bases, smoky and quinoline leather types, vanilla, tonka, honey, pure Sweet type base such as balsam tone, other aldehideic type base, amber type base, animal type base, anise type base, aromatic herbal type base, agar type base, aqua type base,
Camphor cineole type base, green type base, seed type base, herb type base, pine type base, patchouli type base, balsamic type base, mint type base, musk type base, moss type base, lavender type base, linalool type base, resin Type base etc. are mentioned.

Furthermore, as the solvent for the fragrance, ethanol,
Acetine (triacetin), MMB acetate (3-methoxy-3-methylbutyl acetate), ethylene glycol dibutyrate, hexylene glycol, dibutyl sebacate, deltil extra (isopropyl myristate), methyl carbitol (diethylene glycol monomethyl ether), Carbitol (diethylene glycol monoethyl ether), TEG (triethylene glycol), benzyl benzoate, propylene glycol, diethyl phthalate, tripropylene glycol, aborin (dimethyl phthalate), deltyl prime (isopropyl palmitate), dipropylene glycol D
PG-FC (dipropylene glycol), farnesene, dioctyl adipate, tributyrin (glyceryl tributanoate), hydrolite-5 (1,2-pentanediol), propylene glycol diacetate,
Cetyl acetate (hexadecyl acetate), ethyl abietate, avalin (methyl abietate), citroflex A-2 (acetyltriethyl citrate), citroflex A-4 (tributylacetyl citrate), citroflex No. 2 (triethyl citrate), Citroflex No. 4 (tributyl citrate), Durafix (methyl dihydroabietate), MITD (isotridecyl myristate),
Examples include polylimonene (limonene polymer), propylene glycol, 1,3-butylene glycol and the like.

The amount of these solvents used is 0.1 to 99% by mass in the fragrance composition, preferably 1 to 4
0 mass% is blended.

Examples of the fragrance stabilizer include dibutylhydroxytoluene, butylhydroxyanisole, vitamin E and its derivatives, catechin compounds, flavonoid compounds, polyphenol compounds, etc., and 0.0001 to 10% by mass in the fragrance composition. It is blended, but preferably 0.001 to 5 mass% is blended. Among these,
A preferred stabilizer is dibutyl hydroxytoluene.

The fragrance composition means the above-mentioned fragrance ingredients,
It is a mixture of a solvent, a perfume stabilizer and the like.

The deodorant composition of the present invention is prepared by
The method of use is not particularly limited, and it can be prepared according to a conventional method for each dosage form, and by applying a usual dose to the skin according to a conventional method for each preparation, an excellent deodorant effect can be obtained. Can play.

[0039]

EFFECTS OF THE INVENTION According to the present invention, sebum, which is a source of malodorous substances, and lower fatty acid malodorous substances themselves are preferentially adsorbed, their volatilization is suppressed, and the malodorous substances are further neutralized. It is also possible to obtain a deodorant composition that exhibits a deodorant function, and when applied to human skin, it is possible to obtain a deodorant composition that makes the applied site look smoother and has a smooth feel. .

[0040]

EXAMPLES The present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited to the following Examples. In addition,% in the following table is mass%.

[Examples 1 to 108 and Comparative Examples 1 to 15]
Each deodorant composition was prepared according to the conventional method according to the composition of Tables 1 to 22, and the deodorant property was evaluated by the following evaluation methods. The results are also shown in Tables 1 to 22.

(Evaluation Method of the Effect of the Invention) In the case where there are 15 or more panelists, 10 males and 10 females, using the composition of each example, felt that they were effective in eliminating body odor. The deodorizing power of the composition was designated as ◯. When less than 15 people felt that 5 or more people were effective, it was evaluated as Δ, and when less than 5 people was evaluated as x.

[0043]

[Table 1]

[0044]

[Table 2]

[0045]

[Table 3]

[0046]

[Table 4]

[0047]

[Table 5]

[0048]

[Table 6]

[0049]

[Table 7]

[0050]

[Table 8]

[0051]

[Table 9]

[0052]

[Table 10]

[0053]

[Table 11]

[0054]

[Table 12]

[0055]

[Table 13]

[0056]

[Table 14]

* 1 Pore volume 0.9 ml / g, average particle size 6 μm, oil absorption 160 ml / 100 g, SiO ₂ content 59%, MgO content 26.7%, SiO ₂ / MgO =
2.2 * 2 Falco Rex Eucalyptus E (Ichimaru Falcos) * 3 White birch (C) (Ichimaru Falcos) * 4 See table for specific flavor combinations

[0058]

[Table 15]

* 1 Pore volume 0.9 ml / g, average particle size 6 μm, oil absorption 160 ml / 100 g, SiO ₂ content 59%, MgO content 26.7%, SiO ₂ / MgO =
2.2 * 2 Falco Rex Eucalyptus E (Ichimaru Falcos) * 3 See table for specific combinations of fragrances

[0060]

[Table 16]

[0061]

[Table 17]

[0062]

[Table 18]

* 1 Pore volume 0.9 ml / g, average particle size 6 μm, oil absorption 160 ml / 100 g, SiO ₂ content 59%, MgO content 26.7%, SiO ₂ / MgO =
2.2 * 2 HEC-600 (Daicel Chemical Industries) * 3 Falco Rex Eucalyptus E (Ichimaru Falcos) * 4 Specific combinations of fragrances for the preparation of fragrances are shown in the attached table.

[0064]

[Table 19]

* 1 SH200C 30cs (Toray Dow Corning Silicone Co., Ltd.) * 2 Pore volume 1 ml / g, average particle size 7 μm, oil absorption 1
50 ml / 100 g, SiO ₂ content 59.8%, Mg
O content 24.6%, SiO ₂ /MgO=2.4 * 3 Falco Rex Eucalyptus E (Ichimaru Pharcos) * 4 HPC-L (Nippon Soda Co., Ltd.) * 5 Monatogamu DA (Dainippon Pharmaceutical Co.) * 6 Hibiswako 105 (Wako Pure Chemical Industries, Ltd.) * 7 Specific combinations of fragrances for the preparation of fragrances are shown in the attached table.

Sheet type A: rayon fiber (1.7 dtex × 40 mm) 100
% Spunlace Nonwoven B: Cotton Fiber (1.7 dtex × 24 mm) 100
% Spunlace non-woven fabric C: polypropylene point embossed non-woven fabric (40 g /
on both sides of the m ^2), rayon fiber (1.7 dtex × 40
mm) 70%, polyester fiber (1.6 dtex x 4)
4 mm) 15%, polypropylene / polyethylene composite fiber (2.2 dtex × 51 mm) 15% mixture (15 each)
g / m ² ) and spun lace nonwoven fabric D: polyester spunbonded nonwoven fabric (30 g / m ² )
Rayon fiber (1.7 dtex x 40 mm) on both sides of
Spunlace nonwoven fabric E: 100% (15 g / m ^{2 for} each) and integrated by water flow: Rayon fiber (1.7 dtex × 40 mm) 40%
And polyester / polyethylene splittable conjugate fiber (2.2
dtex, 0.28 dtex × 51mm after division) 60%
Spunlace nonwoven fabric made of a mixture of

[0067]

[Table 20]

* 1 Pore volume 1 ml / g, average particle size 7μ
m, oil absorption 150 ml / 100 g, SiO ₂ content 5
9.8%, MgO content 24.6%, SiO ₂ / MgO
= 2.4 * 2 Pemuren TR-2 by BF Goodrich * 3 Falco Rex Eucalyptus E (Ichimaru Falcos) * 4 There are floral, citrus, fruity, herbal and fuzea fragrances for adjusting each fragrance. The specific combination of fragrances is according to the attached table

Sheet type A: rayon fiber (1.7 dtex × 40 mm) 100
% Spunlace Nonwoven B: Cotton Fiber (1.7 dtex × 24 mm) 100
% Spunlace non-woven fabric C: polypropylene point embossed non-woven fabric (40 g /
on both sides of the m ^2), rayon fiber (1.7 dtex × 40
mm) 70%, polyester fiber (1.6 dtex x 4)
4 mm) 15%, polypropylene / polyethylene composite fiber (2.2 dtex × 51 mm) 15% mixture (15 each)
g / m ² ) and spun lace nonwoven fabric D: polyester spunbonded nonwoven fabric (30 g / m ² )
Rayon fiber (1.7 dtex x 40 mm) on both sides of
Spunlace nonwoven fabric E: 100% (15 g / m ^{2 for} each) and integrated by water flow: Rayon fiber (1.7 dtex × 40 mm) 40%
And polyester / polyethylene splittable conjugate fiber (2.2
dtex, 0.28 dtex × 51mm after division) 60%
Spunlace nonwoven fabric made of a mixture of

[0070]

[Table 21]

* 1 Average particle size 5 μm, manufactured by Miyoshi Kasei * 2 Pore volume 1 ml / g, average particle size 7 μm, oil absorption 1
50 ml / 100 g, SiO ₂ content 59.8%, Mg
O content 24.6%, SiO ₂ /MgO=2.4 * 3 0.5 μm, manufactured by Kunimine Industries Co., Ltd. * 4 Falco Rex Eucalyptus E (Ichimaru Falcos) * 5 Specific combination of fragrances for the preparation of perfumes Is according to the attached table

Sheet type A: rayon fiber (1.7 dtex × 40 mm) 100
% Spunlace Nonwoven B: Cotton Fiber (1.7 dtex × 24 mm) 100
% Spunlace non-woven fabric C: polypropylene point embossed non-woven fabric (40 g /
on both sides of the m ^2), rayon fiber (1.7 dtex × 40
mm) 70%, polyester fiber (1.6 dtex x 4)
4 mm) 15%, polypropylene / polyethylene composite fiber (2.2 dtex × 51 mm) 15% mixture (15 each)
g / m ² ) and spun lace nonwoven fabric D: polyester spunbonded nonwoven fabric (30 g / m ² )
Rayon fiber (1.7 dtex x 40 mm) on both sides of
Spunlace nonwoven fabric E: 100% (15 g / m ^{2 for} each) and integrated by water flow: Rayon fiber (1.7 dtex × 40 mm) 40%
And polyester / polyethylene splittable conjugate fiber (2.2
dtex, 0.28 dtex × 51mm after division) 60%
Spunlace nonwoven fabric made of a mixture of

[0073]

[Table 22]

* 1 Average particle size 5 μm, manufactured by Miyoshi Kasei * 2 Pore volume 1 ml / g, average particle size 7 μm, oil absorption 1
50 ml / 100 g, SiO ₂ content 59.8%, Mg
O content 24.6%, SiO ₂ /MgO=2.4 * 3 0.5 μm, manufactured by Kunimine Industries Co., Ltd. * 4 Falco Rex Eucalyptus E (Ichimaru Falcos) * 5 Specific combination of fragrances for the preparation of perfumes Is according to the attached table

Sheet type A: Rayon fiber (1.7 dtex × 40 mm) 100
% Spunlace Nonwoven B: Cotton Fiber (1.7 dtex × 24 mm) 100
% Spunlace non-woven fabric C: polypropylene point embossed non-woven fabric (40 g /
on both sides of the m ^2), rayon fiber (1.7 dtex × 40
mm) 70%, polyester fiber (1.6 dtex x 4)
4 mm) 15%, polypropylene / polyethylene composite fiber (2.2 dtex × 51 mm) 15% mixture (15 each)
g / m ² ) and spun lace nonwoven fabric D: polyester spunbonded nonwoven fabric (30 g / m ² )
Rayon fiber (1.7 dtex x 40 mm) on both sides of
Spunlace nonwoven fabric E: 100% (15 g / m ^{2 for} each) and integrated by water flow: Rayon fiber (1.7 dtex × 40 mm) 40%
And polyester / polyethylene splittable conjugate fiber (2.2
dtex, 0.28 dtex × 51mm after division) 60%
Spunlace nonwoven fabric made of a mixture of

[0076]

[Table 23]

[0077]

[Table 24]

[0078]

[Table 25]

[0079]

[Table 26]

[0080]

[Table 27]

[0081]

[Table 28]

[0082]

[Table 29]

[0083]

[Table 30]

[0084]

[Table 31]

[0085]

[Table 32]

[0086]

[Table 33]

[0087]

[Table 34]

[0088]

[Table 35]

   ─────────────────────────────────────────────────── ─── Continued front page    (72) Inventor Masatsugu Miyazaki             1-3-7 Honjo, Sumida-ku, Tokyo Rio             Within the corporation (72) Inventor Ryo Chika             1-3-7 Honjo, Sumida-ku, Tokyo Rio             Within the corporation F-term (reference) 4C083 AA122 AB032 AB171 AB172                       AB211 AB212 AB222 AB232                       AB242 AB372 AB432 AB442                       AC012 AC022 AC072 AC092                       AC102 AC112 AC122 AC172                       AC182 AC242 AC302 AC342                       AC352 AC392 AC422 AC432                       AC442 AC472 AC482 AC532                       AC542 AC582 AC692 AC792                       AC812 AC852 AD072 AD092                       AD112 AD152 AD162 AD172                       AD242 AD252 AD282 AD352                       AD432 AD532 AD572 AD662                       BB23 CC17 DD08 DD11 DD12                       DD17 DD23 DD31 DD33 DD41                       EE18                 4G066 AA16B AA22B BA20 BA25                       BA38 CA02 CA05 DA03 FA37                 4G073 BA10 BD11 BD21 CC01 GA11                       GA14 GA20 UB28

Claims (2)

[Claims] 1. A composite of silicon dioxide and magnesium oxide as main raw materials, having a pore volume of 0.05 ml /
A deodorant composition comprising a porous powder having an average particle size of 0.5 to 40 μm and an oil absorption of 50 ml / 100 g or more. 2. The content of magnesium oxide in the porous powder is 20% by mass or more, and the content of silicon dioxide is 44.
The deodorant composition according to claim 1, wherein the deodorant composition is at least mass% and the ratio of silicon dioxide / magnesium oxide mass percentage (%) is 2.2 to 2.5.