JP2002534364A - Transparent hair conditioning composition containing breakable visible particles - Google Patents

Abstract

  (57) [Summary] (1) breakable visible particles comprising a structural material selected from the group consisting of polysaccharides and derivatives thereof, saccharides and derivatives thereof, oligopolysaccharides, monosaccharides, and mixtures thereof; (2) amphoteric viscosifying polymer; A hair conditioning composition comprising a non-ionic viscosifying polymer, an inorganic viscosifying agent, and a mixture thereof; and (3) an aqueous carrier. Disclose.

Description

DETAILED DESCRIPTION OF THE INVENTION

TECHNICAL FIELD [0001] The present invention relates to a hair conditioning composition containing breakable visible particles.

[Background] Human hair is gradually stained by contact with the surrounding environment and sebum secreted from the scalp. When the hair becomes dirty, the hair becomes dirty or greasy and becomes unattractive. Hair stains must be shampooed regularly.

[0003] Shampoos cleanse hair by removing excess dirt and sebum.
However, shampoos can wet hair, become tangled and generally leave it unwieldy. Once the hair dries, the hair often remains wet, rough, dull, or shiny because the natural oils and other natural conditioning and moisturizing components of the hair are removed. . Hair also has an increased static value as it dries, and this static electricity prevents combing, resulting in what is commonly referred to as "jumping hair" or, especially, for long hair, is desirable. There can be no contribution to the "split" phenomenon.

[0004] Various attempts have been made to alleviate these post-shampooing problems.
These attempts range from post-shampoo applications of hair conditioners, such as leave-on and rinse-off products, to hair conditioning shampoos, which attempt to both clean and condition with a single product. While some consumers prefer the ease and convenience of a shampoo that includes a conditioner, a significant percentage of consumers apply it to their hair as a separate step, usually following the shampoo. Prefer more conventional conditioner formulations. Consumers who prefer a conventional conditioner formulation value the relatively higher conditioning effectiveness or convenience of varying the amount of conditioning depending on the condition or part of the hair.

[0005] Conditioning formulations can be in the form of leave-on or rinse-off products, and can be in the form of emulsions, creams, gels, sprays and mousses. Products in the form of creams, gels and mousses are suitable because consumers can easily adjust the quantity and distribution of the product. For this reason, these products are particularly suitable for leave-on products.

[0006] Leave-on products with aesthetic advantages are preferred by consumers. Transparent or almost transparent products containing distinguishable visible particles are particularly preferred for aesthetics. Such visible particles are also useful for including substances that can affect the stability of the formulation of the base formulation. However, while conventional leave-on products deliver good conditioning benefits, they are not entirely satisfactory in providing such aesthetic benefits.

Based on the foregoing, there remains a need to provide hair conditioning compositions suitable for leave-on applications that provide favorable aesthetic benefits and that are compatible with a wide range of additional conditioning agents. No technology offers all the advantages and benefits of the present invention.

[0008] The present invention relates to (1) a destructible visible light containing a structural substance selected from the group consisting of polysaccharides and derivatives thereof, saccharides and derivatives thereof, oligopolysaccharides, monosaccharides, and mixtures thereof. A composition comprising: (2) a thickener selected from the group consisting of amphoteric thickener polymers, nonionic thickener polymers, inorganic thickeners, and mixtures thereof; and (3) an aqueous carrier; The present invention is directed to a hair conditioning composition that is: These and other features, aspects and advantages of the present invention will become apparent to one of ordinary skill in the art upon reading the present disclosure.

DETAILED DESCRIPTION While the specification concludes with claims particularly pointing out and distinctly claiming the invention, it is believed that the present invention will be better understood from the following description. Conceivable. All references cited are hereby incorporated by reference in their entirety. Citation of any reference is not intended to limit its prior art applicability to the claimed invention.

As used herein, “comprising” means that other steps and other ingredients which do not affect the end result can be added. The term "consists of"
And "consisting essentially of". All percentages, parts and ratios are based on the total weight of the composition of the present invention, unless otherwise specified. When such weights relate to the indicated ingredients, they are all based on the activity values, and therefore these weights may be contained in carriers or commercially available substances Contains no by-products.

[0011] The above aspects and embodiments of the invention described herein have a number of advantages. For example, the hair conditioning compositions of the present invention provide advantageous aesthetic effects, e.g., improved conditioning effects such as smoothness, softness and reduced rubbing, are easy to apply to hair, and can be applied to hair and hands. Leave a feeling of cleanliness.

Breakable visible particles The composition of the present invention comprises breakable visible particles. By definition, breakable visible particles are particles that are stable in the present composition and that are also breakable on use that can be clearly detected as individual particles by the naked eye when included in the composition. The breakable visible particles can be of any size, color, or shape according to the desired characteristics of the product, as long as they are clearly detected as individual particles by the naked eye. Generally, breakable visible particles have an average diameter of about 50 μm to about 3000 μm, preferably about 100 μm to about 1000 μm, more preferably about 300 μm to about 1000 μm. By stable is meant that under normal storage conditions, the visible particles do not decompose, do not agglomerate, or separate. By being breakable, it means that the breakable visible particles can be broken down on the hand with small shear forces by the finger during use.

The breakable visible particles herein provide a composition with a favorable aesthetic effect, according to the desired characteristics of the product, typically about 10% by weight of the composition, preferably about 0%. Used at levels from 0.01 to about 5% by weight.

The destructible visible particles herein comprise a structural material, and preferably an encapsulating material. Structural materials provide a certain strength to the destructible visible particles, so that they retain a clearly detectable structure in the composition under normal storage conditions, while using small shear forces with the finger during use With them, you can break and break them up on your hands. Preferably, the breakable visible particles have a compressive strength of about 1 to about 200 grams per particle. The compressive strength is determined by Stable Microsystems Ltd. Can be suitably measured under the following conditions using a batch of 20 particles by using a TA-XT2 type texture analyzer manufactured by Hitachi, Ltd. Style: Measuring force in compression Testing speed: 0.1 mm / sec Distance: 0.8 mm Brake type: Automatic -10 g Accessories: 25 mm cylinder probe on acrylate resin using 5 kg load cell (P / 25) After the destructible visible particles have decomposed, they leave little or no residual feeling in the hands, and preferably no particle fragments larger than about 10 μm.

[0015] The structural material includes a component selected from the group consisting of polysaccharides and derivatives thereof, saccharides and derivatives thereof, oligopolysaccharides, monosaccharides, and mixtures thereof. Preferably,
In order to make the structural material, components having different water solubilities are selected from the above group. More preferably, the structural material comprises a component selected from the group consisting of cellulose, cellulose derivatives, sugars, and mixtures thereof. More preferably, the structural material comprises a mixture of cellulose, cellulose derivatives, and saccharides.

Exemplary ingredients useful for making structural materials include, for example, crystalline cellulose, cellulose acetate, cellulose acetate butyrate, cellulose acetate phthalate, cellulose citrate, ethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, hydroxy Propylmethylcellulose phthalate, methylcellulose, sodium carboxymethylcellulose, acacia gum (gum arabic), agar, agarose, maltodextrin, sodium alginate, calcium alginate, dextran, starch, galactose, glucosamine, cyclodextrin, chitin, amylose, amylopectin, glycogen, laminaran , Rikenan, Curdlan, Inulin, Leban,
Such as pectin, mannan, xylan, alginic acid, arabic acid, glucomannan, agarose, agaropectin, profilan, carrageenan, fucoidan, glucosaminoglycan, hyaluronic acid, chondroitin, peptidoglycan, lipopolysaccharide, guar gum, starch and starch derivatives Polysaccharides and saccharide derivatives;
Sucrose, lactose, maltose, uronic acid, muramic acid, cellobiose,
Oligopolysaccharides such as isomaltose, planteose, melezitose, gentianose, maltotriose, stachyose, glucoside and polyglucoside;
Monosaccharides such as glucose, fructose, and mannose. Further components that may be included in the structural materials include: acrylic polymers and copolymers, including polyacrylamide, poly (alkyl cyanoacrylate), and poly (ethylene-vinyl acetate), and carboxyvinyl polymers, polyamides, poly (methyl Vinyl ether-maleic anhydride), poly (adipyl-L-lysine), polycarbonate, polyterephthalamide, polyvinyl acetate phthalate, poly (terephthaloyl-L-lysine), polyarylsulfone, poly (methyl methacrylate), poly (ε-caprolactone) ), Polyvinylpyrrolidone,
Synthetic polymers such as polydimethylsiloxane, polyoxyethylene, polyester, polyglycolic acid, polylactic acid, polyglutamic acid, polylysine, polystyrene, poly (styrene-acrylonitrile), polyimide, and poly (vinyl alcohol); and fats, fatty acids , Fatty alcohol, milk solids, molasses, gelatin, gluten, albumin, shellac, caseinate, beeswax, carnauba wax, spermaceti, hydrogenated tallow, glycerol monopalmitate, glycerol dipalmitate, hydrogenated castor oil, glycerol monostea And other substances such as glycerol distearate, glycerol tristearate, 12-hydroxystearyl alcohol, proteins and protein derivatives; and mixtures thereof. That. The components herein may be described in other sections as useful components for the composition. However, the components herein are used to create a substantially breakable visible particle structure and are not substantially soluble in the bulk of the composition under normal storage conditions.

The structural components that can be further included in the structural material include crystalline cellulose, cellulose acetate, cellulose acetate butyrate, cellulose acetate phthalate, cellulose nitrate, ethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, hydroxypropyl methyl cellulose phthalate, and methyl cellulose. , Carboxymethylcellulose sodium, acacia gum (gum arabic), agar, agarose, maltodextrin, sodium alginate, calcium alginate, dextran, starch, galactose, glucosamine, cyclodextrin, chitin, amylose, amylopectin, glycogen, laminaran, lichenan, curdlan , Inulin, levan, pectin, mannan, Polysaccharides and sugars such as xylan, alginic acid, arabic acid, glucomannan, agarose, agaropectin, profilan, carrageenan, fucoidan, glucosaminoglycan, hyaluronic acid, chondroitin, peptidoglycan, lipopolysaccharide, guar gum, starch and starch derivatives. Derivatives; sucrose,
Oligopolysaccharides such as lactose, maltose, uronic acid, muramic acid, cellobiose, isomaltose, planteose, melezitose, gentianose, maltotriose, stachyose, glucoside and polyglucoside; glucose,
Monosaccharides such as fructose and mannose, as well as milk solids, molasses, gelatin, gluten, albumin, shellac, caseinate, beeswax, carnauba wax, spermaceti, hydrogenated tallow, glycerol monopalmitate, glycerol dipalmitate, hydrogen Other materials such as added castor oil, glycerol monostearate, glycerol distearate, glycerol tristearate, 12-hydroxystearyl alcohol, proteins, and protein derivatives, and mixtures thereof. The components in this section may be described in other sections as useful components of the compositions of the present invention. However, the components herein are used to create a substantially destructible visible particle structure and are not substantially soluble in the bulk of the composition under normal storage conditions.

The destructible visible particles in the present invention may include, contain, or be filled with an encapsulating substance. Such inclusions may be water-soluble or water-insoluble and may include the following components: vitamins, antioxidants, cooling agents, proteins and protein derivatives, herbal extracts, pigments, dyes,
Antimicrobial agents, chelating agents, UV absorbers, optical brighteners, silicone compounds, fragrances, generally water-soluble wetting agents, generally water-insoluble additional conditioning agents and mixtures thereof. In one embodiment, a water-soluble component is a preferred inclusion material. In such an embodiment, a non-volatile silicone compound can be used as a coating on the destructible visible particles to avoid leakage of the encapsulated material into the composition body.

[0019] Vitamins and amino acids useful herein as inclusion substances include: water-soluble vitamins, such as vitamins B1, B2, B6, B12, C, pantothenic acid, pantothenyl ethyl ether, panthenol, biotin and derivatives thereof. And water-soluble amino acids such as asparagine, alanine, indole, glutamic acid and salts thereof, water-insoluble vitamins such as vitamins A, D and E and derivatives thereof, and water-insoluble amino acids such as tyrosine, tryptamine and salts thereof.

Antioxidants useful herein as inclusion substances include: sesamol, sesamolin,
Gossypol, BHA (butylhydroxyanisole, BHT (dibutylhydroxytoluene), nordihydroguaiaretic acid, propyl gallate, phytic acid, and guaiac resins. Synergists for such antioxidants include citric acid , Ascorbic acid, and malic acid.

[0021] Cooling agents useful as encapsulating materials herein include menthol and camphor in their d- and dl-forms.

[0022] Pigments useful as encapsulating materials herein include inorganic, nitroso, monoazo, diazo, carotenoid, triphenylmethane, triarylmethane, xanthine, quinoline, oxazine, azine, anthraquinone, indigoid, thionindigoid, quinacridone, Examples include phthalocyanine, vegetable, natural colors, including: I. Water-soluble components such as those having names: acidic red 18, 26, 27, 33, 51, 52, 87, 88, 92, 94, 95, acidic yellow 1, 3, 11, 23, 36, 40, 73, Food yellow 3, food green 3, food blue 2, food red 1,6, acid blue 5,9,74, pigment red 57-1,53 (Na), basic purple 10
Solvent red 49, acidic orange 7, 20, 24, acidic green 1, 3, 5, 25, solvent green 7, acidic purple 9, 43; I. Water-insoluble components such as those with names: Pigment Red 53 (Ba), 49 (Na), 49 (Ca), 49 (Ba), 49 (Sr),
57, solvent red 23, 24, 43, 48, 72, 73, solvent orange 2, 7, pigment red 4,
24, 48, 63 (Ca) 3, 64, vat red 1, vat blue 1, 6, pigment orange 1,
5, 13, solvent yellow 5, 6, 33, pigment yellow 1, 12, solvent green 3, solvent purple 13, solvent blue 63, pigment blue 15, titanium dioxide, chlorophyllin copper complex, ultramarine, aluminum powder, bentonite, carbonic acid Calcium, barium sulfate, bismuthine, calcium sulfate, carbon black, bone ash, chromate, cobalt blue, gold, iron oxide, iron hydroxide oxide, ferric ferrocyanate, magnesium carbonate, manganese phosphate, silver, and zinc oxide .

Antimicrobial agents useful as encapsulants, including those useful as cosmetic biocides and dandruff, anti-itch agents: water-soluble components such as pyroctone olamine, 3,4,4 '
Water-insoluble components such as trichlorocarbanilide (triclosan), triclocarban, zinc pyrithione, selenium disulfide, alkylisoquinolinium bromide, bifenamine, thianthol, cantharis flavor, ginger flavor, and pepper flavor.

[0024] Chelating agents useful as encapsulating materials include: 2,2'-dipyridylamine;
10-phenanthroline {o-phenanthroline}; di-2-pyridyl ketone;
2,3-bis (2-pyridyl) pyrazine; 2,3-bis (2-pyridyl) -5,
6-dihydropyrazine; 1,1′-carbonyldiimidazole; 2,4-bis (
5,6-diphenyl-1,2,4-triazin-3-yl) pyridine;
6-tri (2-pyridyl) -1,3,5-triazine; 4,4′-dimethyl-2
, 2'-dipyridyl;2,2'-biquinoline; di-2-pyridylglyoxal
2,2′-pyridyl}; 2- (2-pyridyl) benzimidazole; 2,2′-
Bipyrazine; 3- (2-pyridyl) -5,6-diphenyl-1,2,4-triazine; 3- (4-phenyl-2-pyridyl) -5-phenyl-1,2,4-triazine; 3- (4-phenyl-2-pyridyl) -5,6-diphenyl-1,2,2
4-triazine; 2,3,5,6-tetrakis- (2′-pyridyl) -pyrazine; 2,6-pyridinedicarboxylic acid; 2,4,5-trihydroxypyrimidine; phenyl 2-pyridylketoxime; Amino-5,6-dimethyl-1,2,4-
Triazine; 6-hydroxy-2-phenyl-3 (2H) -pyridazinone; 2,
4-pteridinediol {lumazine}; 2,2′-dipyridyl; and 2,3-dihydroxypyridine.

The silicone compounds, wetting agents, additional conditioning agents, UV absorbers, optical brighteners and herbal extracts useful for the encapsulating material are the same as those exemplified elsewhere herein. It is. However, the components herein are:
It is substantially retained inside the breakable visible particles and is not substantially dissolved in the bulk of the composition of the present invention under normal storage conditions.

Commercially destructible visible particles that are particularly useful in the present invention are Unisphere and Unicerin trade names available from Induchem, Switzerland.
). Unisphere and Unicerin particles are microcrystalline cellulose,
Made of hydroxypropylcellulose, lactose, vitamins, pigments and proteins. In use, the Unisphere or Unicerin can be disintegrated on the hand with virtually no shear by the finger, with virtually no resistance, and readily dissolves in the composition.

The pressurized viscous adhesive composition of the present invention comprise amphoteric pressurized viscous polymer, nonionic pressurized viscous polymer, inorganic vulcanizing viscosity agent, and a pressurized viscous agent selected from the group consisting of mixtures thereof. Thickening agents are included in the composition to give the gel a particular viscosity. In a preferred embodiment, the viscosifying agent is used when the composition of the composition comprises from about 1,000 cps to about 100,0 cps.
It is selected to have a viscosity of 00 cps, preferably from about 2,000 to about 50,000 cps. The viscosity herein is suitably measured by a Brookkfield RVT at 20 ° C., 20 rpm using either spindle # 4, 5, 6, or 7, depending on the viscosity and characteristics of the composition. be able to.

[0028] The viscosifying agent herein is preferably from about 0.01% to about 10% by weight of the composition,
More preferably, it is used at a level of about 0.1% to about 5%. In order to obtain a preferred viscosity and compatibility with a wide range of additional conditioning agents, in particular cationic conditioning agents, it is preferred to use a mixture of thickening agents.

Useful herein are amphoteric viscosifying polymers. The amphoteric viscosifying polymers useful herein may also provide conditioning benefits, some may have hair holding or hair fixing properties, however, such conditioning and hair holding or hair Fixation properties are not a requirement of the amphoteric viscosifying polymer herein. The amphoteric viscopolymers useful herein are at least one cationic monomer and at least one anionic monomer; wherein the cationic monomer is a quaternary ammonium, preferably a dialkyl diallyl ammonium chloride or a carboxamide amide alkyl trialkyl ammonium chloride. And the anionic monomer is such as to include being a carboxylic acid. The amphoteric viscous polymers herein may include nonionic monomers such as acrylamine, methacrylate, or ethacrylate. Further, the amphoteric viscosifying polymers useful herein do not contain betainized monomers.

Useful herein are polymers with CTFA names of Polyquaternium 22, Polyquaternium 39, and Polyquaternium 47. Such polymers include, for example, copolymers of dimethyldiallyl ammonium chloride and acrylic acid, terpolymers of dimethyldiallyl ammonium chloride and acrylamide, and the following formula with a ratio of n ⁶ : n ⁷ : n ⁸ of 45:45. Terpolymer consisting of methacrylamidopropyl trimethylammonium acrylate and methyl acrylate, such as: 10.

[0031]

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Highly preferred commercially available amphoteric viscosifying polymers herein are MERQUAT 280, polyquaternium 22 with Marquat 295, Marquat PLUS 3330, Marquat PLUS3.
Included are Polyquaternium 39 with 331 and Polyquaternium 47 with the trade names Marquat 2001 and Marquat 2001N, all available from Calgon Corporation.

In the present invention, a vinyl monomer having at least one carboxyl group, such as acrylic acid, methacrylic acid, maleic acid, itaconic acid, fumaric acid, crotonic acid or alpha-chloroacrylic acid, and at least one basic acid Also useful are basic monomers which are substituted vinyl compounds containing a nitrogen atom, such as dialkylaminoalkyl methacrylates and acrylates and polymers obtained from copolymerization of dialkylaminoalkyl methacrylamides and acrylamides.

In the present invention: (i) at least one monomer selected from acrylamide or methacrylamide in which the nitrogen is replaced by an alkyl group, (ii) containing one or more reactive carboxyl groups (Iii) esters of acrylic and methacrylic acids having at least one acid comonomer, such as primary, secondary and tertiary amine substituents and quaternary ammonium substituents Also useful are the polymers containing units derived from the quaternization of dimethylaminoethyl methacrylate with dimethyl or diethyl sulfate.

Most particularly preferred N-substituted acrylamides or methacrylamides are the groups in which the alkyl group contains from 2 to 12 carbon atoms, in particular N-ethylacrylamide, N-tert-butylacrylamide, N-tert-octylacrylamide , N-octylacrylamide, N-decylacrylamide and N-dodecylacrylamide, and also the corresponding methacrylamide. Said acid comonomers are, inter alia, acrylic acid, methacrylic acid, crotonic acid, itaconic acid, maleic acid and fumaric acid, and also alkyl monoesters in which the alkyl part of maleic acid or fumaric acid has 1 to 4 carbon atoms Is selected from

Preferred basic comonomers are aminoethyl, butylaminoethyl, N, N′-
Dimethylaminoethyl and N-tert-butylaminoethyl methacrylate.

Highly preferred commercially available amphoteric viscosifying polymers herein include Amphomer, Amphomer SH701, Amphomer trade names supplied by National Starch & Chemical Octyl acrylamine / acrylate / butylaminoethyl mesoacrylate copolymers having A.I. 28-4910, Amphomer LV71 and Amphomer LV47 are included.

In the present invention, cellulose derivatives and modified cellulose polymers such as methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropylmethylcellulose, nitrocellulose, sodium cellulose sulfate, sodium carboxymethylcellulose, crystalline cellulose, cellulose powder, polyvinylpyrrolidone, and polyvinyl alcohol Guar gum, hydroxypropyl guar gum, xanthan gum, xanthan gum, gum arabic, tragacanth, galactan, carob gum, guar gum, karaya gum, carrageenan, pectin, agar, quince seeds (Cydonia oblonga mill), starch (rice, corn, potato, wheat), algal colloid ( Algal extract), microbiological polymers such as dextran, succinoglu , Prelan, starch-based polymers such as carboxymethyl starch, methylhydroxypropyl starch, alginic acid-based polymers such as sodium alginate, propylene glycol alginate, acrylate polymers such as sodium polyacrylate, polyethyl acrylate, polyacrylamide, polyethyleneimine, Also useful are inorganic water-soluble substances such as bentonite, aluminum magnesium silicate, laponite, hectonite and silicic anhydride.

[0039] Polyalkylene glycols having a molecular weight of greater than about 1000 are useful herein. Those having the following general formula are useful:

[0040]

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Where R⁹⁵Is selected from the group consisting of H, methyl, and mixtures thereof. R ⁹⁵ Is H, such a material is a polymer of ethylene oxide,
Also known as lenoxide, polyoxyethylene, and polyethylene glycol
Have been. R⁹⁵When is methyl, these substances are
, Also known as polyoxypropylene and polypropylene glycol
It is a polymer of propylene oxide. R⁹⁵When is methyl, the resulting polymer
It is also understood that various regioisomers of-can exist. In the above structure, x3 is
About 1500 to about 25,000, preferably about 2,500 to about 20,000, and even more
Preferably it has an average value of about 3,500 to about 15,000. Other useful ports
Remers include polypropylene glycol and mixed polyethylene-polypropylene
Glycol or polyoxyethylene-polyoxypropylene copolymer polymer
-. Polyethylene glycol polymers useful herein include:
R⁹⁵Is H and x3 has an average value of about 2,000 PEG-2M (
PEG-2M is also available as Polyox (Polyox available from Union Carbide).
ox) also known as WSR® N-10 and also as PEG-2,000.
R)⁹⁵Is H and x3 has an average value of about 5,000
G-5M (PEG-5M is also available from Union Carbide.
Ox WSR (R) N-35 and Polyox WSR (R) N-
80 and PEG-5,000 and polyethylene glycol 300,0
Also known as 00); R⁹⁵Is H and x3 is an average of about 7,000
PEG-7M with value (PEG-7M is also available from Union Carbide)
Possible polyox WSR® N-750); R ⁹⁵ Is H and x3 has an average value of about 9,000 PEG-9M (PEG
-9M is also a Polyox WSR (registered trademark) available from Union Carbide.
Trademark) also known as N-3333);⁹⁵Is H and x3
Has an average value of about 14,000 (PEG-14M also has
Polyox WSR® N-300 available from Nion Carbide
(Also known as 0).

Commercially available viscosifiers which are very useful herein include acrylate / steareth- with the trade name ACRYSOLL 22 available from Rohm and Haas.
20 Methyl methacrylate copolymer, non-oxynyl hydroxyethylcellulose with AMERCELL polymer HM-1500, trade name available from Amarcol, all trade name Venecel (supplied from Herculus)
BENECEL), hydroxyethyl cellulose with the trade name NATROSOL, hydroxypropyl cellulose with the trade name KLUCEL, cetyl hydroxyethyl cellulose with the trade name POLYSURF 67, and carbowax (CARBOWAX) ) Ethylene oxide and / or propylene oxide based on polymers with PEG, Polyox WASR, and UCON FLUIDS.

Aqueous Carrier The compositions of the present invention include an aqueous carrier, which is present as the continuous phase of the composition. The level and species of the carrier are selected according to the compatibility with other components and other desired properties of the product. Carriers useful herein include water and aqueous solutions of lower alkyl alcohols. Lower alkyl alcohols useful in the present invention are monohydric alcohols having 1 to 6 carbons, more preferably ethanol and isopropanol.

[0044] Preferably, the aqueous carrier is substantially water. Preferably, deionized water is used. Water from natural sources containing cationic minerals can also be used, depending on the desired properties of the product. Generally, the compositions of the present invention contain from about 20% to about 99%, preferably from about 40% to about 98%, and more preferably from about 50% to about 98% water.

The pH of the composition is preferably from about 4 to about 9, more preferably from about 4.5 to about 7.
5 Buffers and other pH adjusting agents can be included to achieve the desired pH. The composition of the present invention is transparent. What is meant by being transparent is that a black material having a size of 1 cm x 1 cm square can be detected with the naked eye through a 1 cm thick composition of the invention.

Cationic Conditioning Agent The compositions of the present invention may further comprise a cationic conditioning agent. The cationic conditioning agent herein is selected from the group consisting of a cationic surfactant, a cationic polymer, and mixtures thereof. Cationic conditioning agents provide conditioning effects to hair, such as softness, smoothness, and antistatic effects, and are compatible with the thickeners herein.

The cationic conditioning agent in the present invention comprises, at the level of the weight of the composition,
Preferably from about 0.05% to about 5%, more preferably from about 0.05% to about 2%.
Used in up to%.

Cationic Surfactants Among the cationic surfactants, those corresponding to general formula (I) are useful herein. :

[0049]

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Wherein at least one of R ⁷¹ , R ⁷² , R ⁷³ and R ⁷⁴ has 8 to 3 carbon atoms
0 aliphatic or aromatic groups, alkoxy, polyoxyalkylene, alkylamide, hydroxyalkyl, aryl or alkylaryl groups having up to about 22 carbon atoms, wherein R ⁷¹ , R ⁷² , R ⁷³ and R ⁷⁴ The rest are independently selected from aliphatic or aromatic groups having 1 to about 22 carbon atoms, alkoxy, polyoxyalkylene, alkylamide, hydroxyalkyl, aryl or alkylaryl groups having up to about 22 carbon atoms; and X forms a salt, such as those selected from halogen, (eg, chlorine, bromine), acetate, citrate, lactate, glycolate, phosphate, nitrate, sulfonate, sulfate, alkyl sulfate, and alkyl sulfonate groups. Anion. Aliphatic groups can contain, in addition to carbon and hydrogen atoms, ether linkages and other groups such as amino groups. For example, long chain aliphatic groups, such as about 12 carbons or more, may be saturated or unsaturated. Preferably, R ⁷¹ , R ⁷² , R ⁷³ and R ⁷⁴ are independently selected from C ₁ to about C ₂₂ alkyl. Non-limiting examples of cationic surfactants useful in the present invention include those having the following CTFA names: quatanium-8, quatanium-14, quatanium-18, quatanium-18 metsulfate, quatanium-24 and the like. Mixture.

Among the cationic surfactants of the general formula (I), those containing at least one alkyl chain having at least 16 carbon atoms in the molecule are preferred. Examples of such preferred cationic surfactants include: Behenyltrimethylammonium available, for example, under the trade name INCROQUAT TMC-80 from Croda and ECONOL TM22 from Sanyo Kasei. Chloride; for example, trade name CA-2350 from Nikko Chemicals
Cetyltrimethylammonium chloride available at: hydrogenated tallowalkyltrimethylammonium chloride, dialkyl (14-18) dimethylammonium chloride, ditallowalkyldimethylammonium chloride, dihydrogenated tallowalkyldimethylammonium chloride, distearyldimethylammonium chloride, Cetyl dimethyl ammonium chloride, di (behenyl / arachidyl) dimethyl ammonium chloride, dibehenyl dimethyl ammonium chloride, stearyl dimethyl behenyl ammonium chloride, stearyl propylene glycol phosphate dimethyl ammonium chloride, stearoyl amide propyl dimethyl benzyl ammonium chloride, stearoyl amide propyl dimethyl (myristyl acrylate) Tate) ammonium chloride, and N- (stearoyl colaminoformyl methyl) include but are pyridinium chloride, and the like.

At least one of the above substituents contains one or more aromatic, ether, ester, amide or amino moieties which are present as substituents or as bonds in the chain, and at least one of R ⁷¹ to R ⁷⁴ groups, alkoxy (preferably C ₁ -C ₃ alkoxy), polyoxyalkylene (preferably C ₁
-C ₃ polyoxyalkylene), alkylamido, hydroxyalkyl, and alkyl esters and one or more hydrophilically substituted cationic surfactants containing a hydrophilic moiety selected from these combinations preferred . Preferably, the hydrophilically substituted cationic conditioning surfactant contains from 2 to about 10 nonionic hydrophilic moieties located within the ranges set forth above. Preferred cationic surfactants that are hydrophilically substituted include those of the following formula (II):
-(VIII):

[0053]

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Wherein n ¹ is from 8 to about 28, m ¹ + m ² is from 2 to about 40, and Z ¹ is short-chain alkyl, preferably C ₁ -C ₃ alkyl, more preferably Methyl or (C
H ₂ CH ₂ O) _{m 3} H, wherein m ¹ + m ² + m ³ is up to 60 and X is a salt-forming anion as defined above;

[0055]

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Wherein n ² is 1 to 5, and one or more of R ⁷⁵ , R ⁷⁶ and R ⁷⁷ is independently C ₁ -C ₃₀ alkyl, and the remainder is CH ₂ CH ₂ OH and R ⁷⁸
, R ⁷⁹ and R ⁸⁰ are independently C ₁ -C ₃₀ alkyl;
And the remainder is CH ₂ CH ₂ OH, and X is a salt-forming anion as described above;

[0057]

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Wherein, with respect to formulas (IV) and (V), independently Z ² is alkyl, preferably C ₁ -C ₃ alkyl, more preferably methyl, and Z ³ is short-chain hydroxy Alkyl, preferably hydroxymethyl or hydroxyethyl,
n ³ and n ⁴ are independently an integer from 2 to 4 (inclusive), preferably 2 to 3 (inclusive), more preferably 2. R ⁸¹ and R ⁸² are independently to, substituted or unsubstituted hydrocarbyl, C ₁₂ -C ₂₀ alkyl or alkenyl,
And X is a salt-forming anion as defined above;

[0059]

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Wherein R ⁸³ is hydrocarbyl, preferably C ₁ -C ₃ alkyl, more preferably methyl, and Z ⁴ and Z ⁵ are independently short chain hydrocarbyl, preferably C ₂
-C ₄ alkyl or alkenyl, more preferably ethyl, m ⁴ is from 2 to about 4
0, preferably from about 7 to about 30, and X is a salt-forming anion as defined above;

[0061]

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Wherein R ⁸⁴ and R ⁸⁵ are independently C ₁ -C ₃ alkyl, preferably methyl, Z ⁶ is C ₁₂ -C ₂₂ hydrocarbyl, alkylcarboxy or alkylamide; Is a protein, preferably collagen, keratin, milk protein, silk, soy protein, wheat protein or a hydrolyzed form thereof; and X is a salt-forming anion as defined above;

[0063]

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Wherein n ⁵ is 2 or 3, R ⁸⁶ and R ⁸⁷ are independently C ₁ -C ₃ hydrocarbyl, preferably methyl, and X is as defined above. It is a salt-forming anion. Examples of hydrophilically substituted cationic surfactants useful in the present invention include the following CTFA designations: Quatanium-16, Quotanium-26, Quotanium-27, Quotanium-30, Quotanium-33, Quotanium-4.
3, Quaternium-52, Quotanium-53, Quotanium-56, Quotanium-60, Quotanium-61, Quotanium-62, Quotanium-70,
Quotanium-71, Quotanium-72, Quotanium-75, Quotanium-76 Hydrolyzed Collagen, Quotanium-77, Quotanium-78, Quotanium-79 Hydrolyzed Collagen, Quotanium-79 Hydrolyzed Keratin, Quotanium-79 Hydrolyzed Milk Protein, Quotanium -79 hydrolyzed silk, quatanium-79 hydrolyzed soy protein and quatanium-79 hydrolyzed wheat protein, quatanium-80, quatanium-81, quatanium-82,
Includes, but is not limited to, materials having Quaternium-83, Quaternium-84, and mixtures thereof.

Highly preferred hydrophilically substituted cationic surfactants include dialkylamidoethylhydroxyethylmonium salts, dialkylamidoethyldimonium salts, dialkiloylethylhydroxyethylmonium salts, dialkiloylethidimonium salts Salts and mixtures thereof; these include, for example, the following trade names: Witco Chemical's VARISOFT 110, Varisoft 222, VARIQUAT K1215 and Variquat 638, Mac Intyre (Mcintyre) MacPro KLP, MacPro WLW
, Mac Pro MLP, Mac Pro NSP, Mac Pro NLW, Mac Pro WWP
, Mac Pro NLP, Mac Pro SLP, Akzo's ETHOQUAD 1
8/25, ethquad 0 / 12PG, ethquad C / 25, ethquad S
/ 25 and ETHODUOQUAD, Henkel's DEHYQUAT and ICI Americas' Atlas G265.

Amines are suitable as cationic surfactants. Primary, secondary and tertiary fatty amines are useful. Tertiary amidoamines having alkyl groups of from about 12 to about 22 carbons are particularly useful. Exemplary tertiary amidoamines include:
Amidopropyl dimethylamine stearate, amide propyl diethylamine stearate, amide ethyl diethylamine stearate, amide ethyl dimethylamine stearate, amide propyl dimethylamine palmitate, amide propyl diethylamine palmitate, amide ethyl diethylamine palmitate,
Amidoethyl dimethylamine palmitate, amide propyldimethylamine behenate, amide propyl diethylamine behenate, amide ethyl diethylamine behenate, amide ethyl dimethylamine behenate, amide propyldimethylamine arachidonic acid, amide propyl diethylamine arachidonic acid, amide ethyl arachidonic acid Examples include diethylamine, ethyldimethylamine arachidonic acid, and diethylaminoethylstearic acid amide. Dimethylstearic amide, dimethylsoyamide, soyamine, myristylamine, tridecylamine, ethylstearylamine, N-tallowpropanediamine, ethoxylated stearylamine (by 5 moles of ethylene oxide), dihydroxyethylstearylamine, and arachidylbehenyl Amines are also useful. Amines useful in the present invention are disclosed in U.S. Pat. No. 4,275,055 (Nachtigal, et al.).

These amines are also acids such as 1-glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, fumaric acid, tartaric acid, citric acid, 1-glutamic acid hydrochloride, maleic acid and mixtures thereof. , More preferably l-glutamic acid, lactic acid,
It can be used in combination with citric acid. The amine in the present invention is preferably from about 1: 0.3 to about 1: 2, more preferably from about 1: 0.4 to about 1: 1.
It has been partially neutralized with any of the above acids, with a molar ratio of amine to acid up to.

Cationic Polymer Cationic polymers are useful in the present invention. As used herein, the term "polymer" refers to a substance made by the polymerization of one type of monomer, or made by two (ie, copolymer) or more than two types of monomers. Include.

Preferably, the cationic polymer is a water-soluble cationic polymer. "
What is meant by a "water-soluble" cationic polymer is that it is sufficiently soluble in water,
A polymer that forms a solution that is substantially transparent to the naked eye at a concentration of 0.1% in water (distilled or equivalent) at 25 ° C. Preferred polymers are sufficiently soluble to form a substantially clear solution at a concentration of 0.5%, more preferably at a concentration of 1.0%.

[0070] The cationic polymer generally has a weight average molecular weight of at least about 5,000, typically at least about 10,000 and less than 10 million. Preferably, the molecular weight is between about 100,000 and about 2,000,000. Cationic polymers generally have a cationic nitrogen-containing moiety, such as a quaternary ammonium or cationic amino moiety and mixtures thereof.

Any anionic counterion can be utilized for the cationic polymer, as long as the water solubility criteria are satisfied. Suitable counterions include halide (eg, Cl, Br, I, or F, preferably Cl, Br, or I) sulfate, and methyl sulfate. This list is not exclusive, so others can be used.

The cationic nitrogen-containing moiety is typically present as a substituent on a portion of the total monomer units of the cationic hair conditioning polymer. Thus, the cationic polymer can include copolymers, terpolymers, etc. of quaternary ammonium or cationic amine substituted monomer units and other non-cationic units referred to herein as spacer monomer units. Such polymers are known in the art and are available from CTFA Cosmetic Ingredient Dictionary, Third Edition, Estrin, Crosley and Haynes editors (The Cosmetic, Toiletry). , and Fragrance Association, I
nc., Washington D.C. C., 1982).

The cationic amine may be a primary, secondary or tertiary amine depending on the specificity of the composition and the pH. Generally, secondary and tertiary amines, especially tertiary amines, are preferred. Tertiary amine substituted vinyl monomers can be polymerized in the amine form and then optionally converted to ammonium in a quaternization reaction. The amine can also be quaternized after the polymer has been formed. For example, quaternary amine functional groups wherein R ⁸⁸ X (wherein, R ⁸⁸ is a short chain alkyl, preferably a C ₁ -C ₇ alkyl, more preferably a C ₁ -C ₃ alkyl, and X in the above (Which is a salt-forming anion as defined) can be quaternized.

Suitable cationic amino and quaternary ammonium monomers include, for example, dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, monoalkylaminoalkyl acrylates, vinyl compounds substituted with monoalkylaminoalkyl methacrylates, trialkyl methacrylates. Roxyalkylammonium salts, trialkylacryloxyalkylammonium salts, diallyl quaternary ammonium salts, and vinyl quaternary ammonium monomers having a cyclic cation nitrogen-containing ring such as pyridinium, imidazolium and quaternary pyrrolidone, for example, alkyl Vinyl imidazolium, alkyl vinyl pyridinium, alkyl vinyl pyrrolidone salts are included. The alkyl portion of these monomers is preferably a C ₁ -C ₃ alkyl group, more preferably a lower alkyl group such as a C ₁ and C ₂ alkyl group. Suitable amine-substituted vinyl monomers for use in the present invention include dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, dialkylaminoalkyl acrylamides, and dialkylaminoalkyl methacrylamides, wherein the alkyl group is preferably C ₁ -C ₇ hydrocarbyl, more preferably C ₁ -C ₃ alkyl.

The cationic polymer can include a mixture of monomer units derived from amine- and / or quaternary ammonium-substituted monomers and / or compatible spacer monomers.

Suitable cationic hair conditioning polymers include, for example, copolymers of 1-vinyl-2-pyrrolidone and 1-vinyl-3-methylimidazolium salt (eg, chloride salt) (Cosmetic, Toiletry, and Fragrance Association, That is, it is referred to in the industry as "Polyquaternium-16" by "CTFA"), for example, Basf Wyandotte Corp. Commercially available from BASF Wyandotte Corp. (Parsippany, NJ, USA) under the trade name LUVIQUAT (eg, Rubiquat FC370); 1-vinyl-
Copolymer of 2-pyrrolidone and dimethylaminoethyl methacrylate (CTFA
Is referred to in the industry as polyquaternium-11), for example,
Gaf Corporation (Wayne, NJ USA) to GAFQUAT (eg, Gafquat 755N)
Cation diallyl quaternary, including dimethyl diallyl ammonium chloride homopolymers and copolymers of acrylamide and dimethyl diallyl ammonium chloride, referred to in the art (CTFA) as polyquaternium 6 and polyquaternium 7, respectively. Secondary ammonium containing polymers; and 3 to 5 as described in US Pat. No. 4,009,256.
Mineral acid salts of aminoalkyl esters of homo- and copolymers of unsaturated carboxylic acids having up to carbon atoms are included. Other cationic polymers that can be used include polysaccharide polymers such as cationic cellulose derivatives and cationic starch derivatives.

[0077] Suitable cationic polysaccharide polymeric materials for use herein include those of the formula:

[0078]

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Wherein Z ⁷ is an anhydrous glucose residue, such as an anhydrous glucose residue of starch or cellulose; R ⁸⁹ is an alkyleneoxyalkylene, polyoxyalkylene, or hydroxyalkylene group, or a combination thereof; ⁹⁰ , R ⁹¹ , and R ⁹² are independently alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, or alkoxyaryl groups, each group containing up to about 18 carbon atoms, and The total number of carbon atoms (ie, the sum of the carbon atoms in R ⁹⁰ , R ⁹¹ and R ⁹² ) is preferably less than about 20, and X is as described above.

Cationic cellulose is a salt of hydroxyethylcellulose that reacts with epoxides substituted with trimethylammonium, which is referred to in the industry (CTFA) as polyquaternium 10 and is a polymer such as JR® and polymer. Available from the Amerchol Corp (Edison, NJ, USA) in the LR® series. Another type of cationic cellulose includes a quaternary ammonium salt polymer of hydroxyethyl cellulose reacted with a lauryl dimethyl ammonium substituted epoxide, referred to in the industry (CTFA) as polyquaternium 24. Such a material is available from Amerchol Corp. (Edison, NJ, USA) under the trade name Polymer LM200®.

Other cationic polymers that can be used include cationic guar gum derivatives such as guar hydroxypropyltrimonium chloride commercially available from Celanese Corp. in the Jaguar R series. Other materials include quaternary nitrogen-containing cellulose ethers as described in U.S. Pat. No. 3,962,418 and etherified celluloses as described in U.S. Pat. No. 3,958,581. Copolymers of starch are included.

Particularly useful cationic polymers in the present invention include polyquaternium-7,
Includes polyquaternium-10, polyquaternium-24 and mixtures thereof. Silicone compound

[0083] The composition of the present invention may further comprise a silicone compound. Silicone compounds useful in the present invention include volatile soluble or insoluble or non-volatile soluble or insoluble silicone conditioning agents. By solubility
It is meant that the silicone compound is miscible with the carrier of the composition so as to form part of the same phase. By insolubility is meant that the silicone forms a discrete phase separate from the carrier, for example, in the form of an emulsion or suspension of silicone droplets. The silicone compound in the present invention can be produced by any suitable method known in the art, including emulsion polymerization. The silicone compound may further be incorporated into the composition of the invention in the form of an emulsion, wherein the emulsion is anionic, nonionic surfactant, at the stage of synthesis by mechanical mixing or by emulsion polymerization. It is produced with or without the aid of surfactants selected from agents, cationic surfactants and mixtures thereof.

[0084] Silicone compounds for use herein have a viscosity at 25 ° C, preferably from about 1,000 to about 2,000,000 centistokes, more preferably from about 10,000 to about 1,000. 800,000 centistokes, even more preferably from about 100,000 to about 1,500,000 centistokes. Viscosity can be measured with a glass capillary viscometer as described in Dow Corning Test Method CTM0004 (July 20, 1970). High molecular weight silicone compounds may be made by emulsion polymerization. Suitable silicone fluids include polyalkylsiloxanes, polyarylsiloxanes, polyalkylarylsiloxanes, polyethersiloxane copolymers, and mixtures thereof. Other non-volatile silicone compounds having hair conditioning properties can also be used.

The silicone compound herein is used at a weight level of the composition, preferably from about 0.1% to about 60%, more preferably from about 0.1% to about 40%.

The silicone compounds herein also include polyalkyl or polyaryl siloxanes having the following formula (I):

[0087]

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Wherein R ⁹³ is alkyl or aryl, and X is an integer from about 7 to 8,000. Z ⁸ represents a group that blocks the end of the silicone chain. Said alkyl or aryl groups, which are substituted on the siloxane chain (R ⁹³ ) or at the terminal Z ⁸ of the siloxane chain, are such that the resulting silicone remains fluid at room temperature, is dispersible and is irritating when applied to the hair. Neither toxic, nor toxic or otherwise harmful, compatible with the other components of the composition, chemically stable under normal use and storage conditions, and deposited on the hair It can have any structure as long as it is possible and the hair can be conditioned. Suitable Z ⁸ groups include hydroxy, methyl, methoxy, ethoxy, propoxy and aryloxy. The two R ⁹³ groups on the silicon atom can represent the same or different groups. Preferably, these two R ⁹³ groups represent the same group. Suitable ^R93 groups include methyl, ethyl, propyl, phenyl, methylphenyl and phenylmethyl. Preferred silicone compounds are polydimethylsiloxane, polydiethylsiloxane and polymethylphenylsiloxane. Polydimethylsiloxane, also known as dimethicone, is particularly preferred. Polyalkylsiloxanes that can be used include, for example, polydimethylsiloxane. Such silicone compounds are available, for example, from the General Electric Company under the Biscasil® and SF96 series and from the Dow Corning 200 series.

[0089] Polyalkylaryl siloxane fluids can also be used, and these include, for example, polymethylphenyl siloxane. These siloxanes are commercially available, for example, from General Electric as SF1075 methylphenyl fluid or from Dow Corning as 556 cosmetic grade fluid.

To enhance the shine properties of the hair, highly arylated silicone compounds, such as highly phenylated, having a refractive index of about 1.46 or greater, especially about 1.52 or greater Polyethyl silicone is particularly preferred. When using these high refractive index silicone compounds, they are mixed with a spreading agent, such as a surfactant or a silicone resin, to reduce surface tension and reduce the film forming ability of the material as described below. Should be raised.

[0091] Silicone compounds that can be used include, for example, polypropylene oxide-modified polydimethylsiloxane, but ethylene oxide or a mixture of ethylene oxide and propylene oxide can also be used. The ethylene oxide and polypropylene oxide values must be low enough so as not to interfere with the dispersion properties of the silicone. These materials are also known as dimethicone copolyols.

Other silicone compounds include amino-substituted substances. Suitable alkylamino-substituted silicone compounds include those represented by the following structure (II):

[0093]

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Wherein R ⁹⁴ is H, CH ₃ or CH, p ¹ , p ² , q ¹ and q ² are integers depending on the molecular weight, and the average molecular weight is approximately 5,000 and 10, 000. This polymer is also known as "Amodimethicone".

Suitable amino-substituted silicone fluids include those represented by formula (III):

[0096]

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Wherein G is selected from the group consisting of hydrogen, phenyl, OH, C ₁ -C ₈ alkyl and is preferably methyl; a represents an integer of 0 or 1-3, preferably 0 and B is 0 or 1, preferably equal to 1; the sum of p ³ + p ^{4 is} a number from 1 to 2,000, preferably from 50 to 150, and p ³ is from 0 to 1, 999
, Preferably can show the number of 49 to 149, and p ⁴ is 1 to 2,000,
It can preferably represent an integer from 1 to 10; R ⁹⁷ is a monovalent radical of the formula C _q3 H _2q3 L, where q ³ is an integer from 2 to 8 and L is selected from Is done.

[0098]

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In the formula, R ⁹⁶ is selected from the group consisting of hydrogen, phenyl, benzyl, and a saturated hydrocarbon group, and is preferably an alkyl group having 1 to 20 carbon atoms, and X ′ represents a halide ion .

Particularly preferred amino-substituted silicones corresponding to formula (II) are those polymers in which R ⁹⁴ is CH ₃ and known as “trimethylsilyl amodimethicone”.

Other silicone polymers which can be used substituted with amino groups are represented by formula (V):

[0102]

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Wherein R ⁹⁸ represents a monovalent hydrocarbon group having 1 to 18 carbon atoms, preferably alkyl or alkenyl such as methyl; R ⁹⁹ represents a hydrocarbon group;
Preferably an alkylene group or a C ₁ -C ₁₈ of C ₁ -C _18, more preferably represents an alkyleneoxy group having C ₁ ~C _8; Q ^- is an halide ion, preferably chlorine; p ⁵ 2-20 , preferably an average statistical value of 2 to 8; p ⁶ is 20 to 200, preferably a mean statistical value of 20 to 50. Preferred polymers of this class are:
Available from Union Carbide under the name UCAR SILICONE ALE56.

References disclosing suitable non-volatile dispersed silicone compounds include US Pat. No. 2,826,551 to Gene; Drakoff.
U.S. Pat. No. 3,964,500, issued Jun. 22, 1976; U.S. Pat. No. 4,364,837, issued to Pader; and U.S. Pat. British Patent No. 849,433. Petrarch Systems, Inc. "Silicone Compounds" distributed by (Petrarch Systems Inc.), 1984, provides a non-limiting, extensive list of suitable silicone compounds.

Another non-volatile dispersed silicone that may be useful in nature is silicone rubber. As used herein, the term “silicone rubber” refers to 1,0
A polyorganosiloxane material having a viscosity greater than or equal to 00,000 centistoke is meant. It is recognized that the silicone rubbers described herein may have some overlap with the silicone compounds disclosed above. This overlap is not intended as a limitation on any of these substances. Silicone rubber is available from Petrarch and US Pat. No. 4,152.
No. 416 (issued May 1, 1979, Spitzer et al.) And the chemistry and technology of silicones from Noll and Walter.
Chnology of Silicones) (New York, Academic Press, 1968). The description of silicone rubber is based on the data sheets SE30, S of General Electric Silicone Rubber Product.
E33, SE54, and SE76. "Silicone rubber" typically has about 2
It has a mass molecular weight of more than 00,000, generally between about 200,000 and about 1,000,000. Specific examples include polydimethylsiloxane, poly (dimethylsiloxane methylvinylsiloxane) copolymer, poly (dimethylsiloxanediphenylsiloxane methylvinylsiloxane) copolymer and mixtures thereof.

Highly crosslinked polymeric siloxane-based silicone resins are also useful. This cross-linking is introduced by incorporating tri- and tetra-functional silanes along with mono- or di-functional silanes or both during silicone resin production. As is well understood in the art, the degree of crosslinking required to obtain a silicone resin will vary according to the particular silane units incorporated into the silicone resin. Generally, a silicone material that has a sufficient value of trifunctional and tetrafunctional siloxane monomer units, and therefore a sufficient value of crosslinks, to result in a dry, hard or hard film is a silicone material. Considered to be a resin. The ratio of oxygen atoms to silicon atoms is an indicator of the crosslinking value for a particular silicone material. Silicone materials having at least about 1.1 oxygen atoms per silicon atom will generally be silicone resins herein. Preferably, the ratio of oxygen atoms: silicon atoms is at least about 1.2: 1.0. Silanes used for the production of silicone resins include monomethyl-, dimethyl-, trimethyl-, monophenyl-,
Mention may be made of diphenyl-, methylphenyl-, monovinyl-, and methylvinylchlorosilane, with tetrachlorosilane usually being most often used together with the methyl-substituted silane. Preferred resins are provided by General Electric as GE SS4230 and GE SS4267. Commercially available silicone resins are generally
It is supplied in a form dissolved in a low viscosity volatile or non-volatile silicone liquid. The silicone resins used herein are provided in dissolved form as described above and incorporated into the compositions of the present invention, as will be readily apparent to those skilled in the art. While not being bound by theory, it is believed that these silicone resins can enhance the deposition of other silicone compounds on the hair, and can enhance hair shine with high refractive index capacity.

Another useful silicone resin is a material given a silicone resin powder, such as the CTFA name polymethylsilsequioxane, which is a product of Toshiba Silicone (Toshiba Silicone).
) Is commercially available as Tospearl ™.

The method for producing these silicone compounds is described in Encyclopedia of Polymer Science and Engineering.
e and Engineering, Vol. 15, Second Edition, pages 204-308 (John Wiley & Sons, Inc., 1989).

In particular, silicone materials and silicone resins can be conveniently identified according to the abbreviated naming system well known to those skilled in the art as “MDTQ” nomenclature. In this system, the silicone is described according to the presence of the various siloxane monomer units that make up the silicone. Briefly, the symbol M denotes a monofunctional unit (CH ₃ ) ₃ SiO _0.5 ; D denotes a difunctional unit (CH ₃ ) ₂ SiO; T denotes a trifunctional unit (CH ₃ ) SiO _1.5 And Q is tetrafunctional-or tetrafunctional-
The unit SiO ₂ is shown. For example, the dashes of unit symbols, denoted M ', D', T 'and Q', represent substituents other than methyl and must be specifically represented at each occurrence.
Typical alternative substituents include groups such as vinyl, phenyl, amino, hydroxyl and the like. The molar ratios of the various units may be based on the MDTQ system based on the MDTQ system, either in relation to the subscript or the average of the symbol indicating the total number of units of each type of the silicone or as a detailed ratio in combination with the molecular weight. Complete the substance description. T, Q, T for D, D ', M and / or M' in silicone resin
A higher relative molar amount of 'and / or Q' is indicative of a higher crosslinking value. However, as mentioned above, the overall degree of crosslinking can also be indicated by the ratio of oxygen to silicon.

Preferred silicone resins useful herein are MQ, MT, MTQ, MQ and M
DTQ resin. Thus, the preferred silicone substituent is methyl. M
: Q ratio is about 0.5: 1.0 to about 1.5: 1.0, and the average molecular weight of the resin is about 100.
MQ resins having 0 to about 10,000 are particularly preferred.

[0111] Particularly suitable silicone compounds herein are non-volatile silicone oils having a molecular weight of about 200,000 to about 600,000, such as dimethicone and dimethiconol. These silicone compounds can be incorporated into the composition as a silicone oil solution; these silicone oils are volatile or non-volatile.

Commercially available silicone compounds useful herein include dimethicone having the tradename DC345 available from Dow Corning Corporation, tradename SE30 available from General Electric. , SE33, SE54 and SE76, dimethiconol having the tradenames DCQ2-1403 and DCQ2-1401 available from Dow Corning Corporation, and UK application 2,303,8
Emulsion polymerized dimethiconol available from Toshiba Silicone as described in US Pat.

Wetting Agent The compositions of the present invention may further comprise a wetting agent. The humectant herein is selected from the group consisting of polyhydric alcohols, water-soluble alkoxylated nonionic polymers and mixtures thereof. The humectant herein, at the weight level of the composition,
Preferably from about 0.1% to about 20%, more preferably from about 0.5% to about 5%
Used up to.

The polyhydric alcohols useful herein include glycerin, sorbitol, propylene glycol, butylene glycol, hexylene glycol, ethoxylated glucose, 1,2-hexanediol, hexanetriol, dipropylene glycol, erythritol, trehalose, Includes diglycerin, xylitol, maltitol, maltose, glucose, fructose, sodium chondroitin sulfate, sodium hyaluronate, sodium adenosine phosphate, sodium lactate, pyrrolidone carbonate, glucosamine, cyclodextrin and mixtures thereof.

[0115] Water-soluble alkoxylated nonionic polymers useful herein include about 10
Polyethylene glycol and polypropylene glycol having a molecular weight of up to 00, such as CTFA names PEG-200, PEG-400, PEG-600,
Includes those with PEG-1000 and mixtures thereof.

Commercially available humectants herein include: The Proctor &
Star and Superol trade names available from The Procter & GamBle Company, Crowda Universal Ltd. (CRODEROL) available from Croda Universal Ltd.
) GA7000, PRESERIN available from Uniceema
Glycerin available from NOF and having the same trade name as the chemical name; Lexole (trade name available from Inolex)
LEXOL) PG-865 / 855, United States Pharmacopeia 1, available from BASF
Propylene glycol having 2-propylene glycol; trade name LIPONIC series available from Lipo, SORBO, ALEX, A-625 and A- available from ICI 641 and UNISWEET 70, available from UPI; sorbitol with Unisuit CONC; dipropylene glycol with the same trade name available from Basff; Solvay GMB
H) Diglycerin with the trade name DIGLYCEROL available from Kyowa and Eizai Xylitol with the same trade name; Malbite available from Hayashibara (MALBIT)
Maltitol with the same trade name available from Freeman and Bioberica and Atomergic
Chondroitin sodium sulfate with the trade name ATOMERGIC SODIUM CHONDROITIN SULFATE available from Chemetals; ACTIMOIST, Intergen (trade name available from Active Organics) AVIAN SODIUM HYALURONATE available from Intergen)
Series, sodium hyaluronate with HYALURONIC ACID Na available from Ichimaru Pharmacos; the same available from Asahikasei, Kyowa and Daiichi Seiyaku Adenosine sodium phosphate with trade name; Merc
k), sodium lactate having the same trade name available from Wako and Showa Kako; trade names CAVITRON, Rhone Poulin available from American Maize -Rhodocap series available from Poulenc) and cyclodextrin with DEXPEAPL available from Tomen; and CARBOWAX brand name available from Union Carbide
Polyethylene glycol having a series is included.

Optical Brightener The compositions of the present invention may further comprise an optical brightener. Optical brighteners are compounds that absorb ultraviolet light and emit its energy again in the form of visible light.
In particular, optical brighteners useful herein have an absorption at a wavelength between about 1 nm and about 420 nm, preferably having a major absorption peak, and a wavelength between about 360 nm and about 830 nm. Emission, preferably having a major emission peak; wherein the major absorption peak has a shorter wavelength than the major emission peak. More preferably, the optical brighteners useful herein are from about 200 nm to about 420 nm.
with a major absorption peak at wavelengths between about 400 nm and about 400 nm to about 780 nm
Has a major emission peak at a wavelength between. Optical brighteners from about 360 nm to about 8
It may or may not have a minor absorption peak in the visible range between wavelengths of 30 nm. Optical brighteners may be described in the art and other industries under other names, such as fluorescent bleaches, optical brighteners and fluorescent dyes.

When applied to the hair via a suitable medium, the optical brighteners herein have 3
One area provides benefits to the hair. First, the optical brighteners of the present invention change hair color by emitting light in the visible range. Second, the optical brighteners of the present invention enhance hair shine by emitting light in the visible range. Third, the optical brightener of the present invention protects hair from ultraviolet light by absorbing ultraviolet light.

Optical brighteners are generally based on structures of aromatic and heteroaromatic systems that provide these unique characteristics. Optical brighteners useful in the present invention can be water-soluble and water-insoluble, and can be classified according to their basic structure, as described below. Preferred optical brighteners herein include polystyrylstilbene, triazinestilbene, hydroxycoumarin, aminocoumarin, triazole, pyrazoline, oxazole, pyrene, porphyrin and imidazole.

The optical brighteners useful herein are used at a weight level of the composition, preferably from about 0.001% to about 10%.

Polystyrylstilbene Polystyrylstilbene is a class of compounds having two or more of the following basic structures.

[0122]

Embedded image

The polystyrylstilbenes useful in the present invention include those having formulas (1), (2) and (3):

[0124]

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In the formula, R ¹⁰¹ is H, OH, SO ₃ M, COOM, OSO ₃ M, OPO (OH)
OM, where M is H, Na, K, Ca, Mg, ammonium, mono-,
Di -, tri - or tetra -C ₁ -C ₃₀ - alkyl ammonium, mono-, - di - or tri -C ₁ -C ₃₀ - hydroxyalkyl ammonium or C ₁ -C ₃ - alkyl and C ₁ -C ₃₀ - hydroxy di by a mixture of alkyl - or tri - a substituted ammonium; or _{SO 2 N (C 1 ~C 30} - _{alkyl) 2, O - (- C} 1 ~C 3 0 - alkyl), CN, Cl, COO (C ₁ ~C ₃₀ - _{alkyl), CON (C 1 ~C 3} 0 - alkyl) ₂ or ^{_{O (CH 2) 3 N +}} (CH 3) 2 X - a, where X ^- is a chlorine, bromine , Iodine, formate, acetate, propionate, glycolate, lactate,
Anion such as acrylate, methanephosphonate, phosphite, dimethyl or diethyl phosphite anion; CN, or alkyl having 1 to 30 carbon atoms,
R ¹⁰² and R ¹⁰³ are independently H, SO ₃ M, wherein M is as defined above; and x is 0 or 1, wherein the compound is in trans planar orientation or cis Has a planar orientation; preferably x is 1; R ¹⁰¹ is SO ₃ Na;
R ¹⁰² and R ¹⁰³ are H; wherein the compound has trans planar orientation;

[0126]

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Wherein R ¹⁰⁴ and R ¹⁰⁵ are independently CN, COO (C ₁ -C ₃₀ -alkyl), CONHC ₁ -C ₄ -alkyl or CON (C ₁ -C ₄ -alkyl) ₂ Wherein the compound has a trans coplanar or cis coplanar orientation; preferably R ¹⁰⁴ and R ¹⁰⁵ are 2-cyano, wherein the compound has a trans coplanar orientation There); and

[0128]

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Wherein each R ¹⁰⁶ is independently H or alkyl of 1 to 30 carbons;
The compound then has a trans-coplanar or cis-coplanar orientation, preferably a trans-coplanar orientation).

[0130] Suitable polystyrylstilbenes include Ciba Specialty Chemicals (Ci
Tinopal CBS- available from Ba Specialty Chemicals)
X-containing disodium-1,4'-bis (2-sulfostyryl) bisphenyl (CI fluorescent brightener 351), available under the trade name Ultraphor (Ul
traphor) 1,4-bis (2-cyanostyryl) benzene having RN (C.I.
. Fluorescent brightener 199).

[0131] Triazinestilbentriazine stilbenes are a class of compounds having both a triazine structure and a stilbene structure in the same molecule. Triazine stilbenes useful in the present invention include those having formula (4):

[0132]

Embedded image

Wherein R ¹⁰⁷ and R ¹⁰⁸ are independently phenylamino, mono- or disulfonated phenylamino, morpholino, N (CH ₂ CH ₂ OH) ₂ , N (CH ₃ ) (CH ₂ C
_{H 2 OH), NH 2,} N (C 1 ~C 4 - _{alkyl) 2, OCH 3, Cl,} NH- (CH 2) 1 -4 SO 3 H or NH- (CH ₂₎ be a _1-4 OH An ^- is a carboxylate, sulfate, sulfonate or phosphate anion, and M is as defined above, wherein the compound has a trans or cis coplanar orientation; preferably , R ¹⁰⁷ is 2,5-disulfophenylamino, and each R ¹⁰⁸ is morpholino; or each R ¹⁰⁷ is 2,5-disulfophenylamino, and each R ¹⁰⁸ is N (C ₂ H ₅ ) ₂ ; or each R ¹⁰⁷ is 3
-Sulfophenyl and each R ¹⁰⁸ is NH (CH ₂ CH ₂ OH) or N (
CH ₂ CH ₂ OH) ₂ ; or each R ¹⁰⁷ is 4-sulfophenyl, and each R ¹⁰⁸ is N (CH ₂ CH ₂ OH) ₂ ; and in each case, the sulfo group is SO ₃ M, where M is sodium; wherein the compound has a trans-coplanar orientation.

Suitable triazine stilbenes include 4,4′-bis-[(4-anilino-6-bis (2-hydroxyethyl) amino having the trade name Tinopal UNPA-GX available from Ciba Specialty Chemicals. -1,3,5-triazine-2-
Il) amino] stilbene-2,2′-disulfonic acid, Ciba Specialty
4,4'-bis-[(4-anilino-6-morpholin-1,3,5-triazin-2-yl) amino] stilbene-2,2 'with the trade name Tinopal AMS-GX available from Chemicals. Disodium sulfonate, 4,4'-bis-[(4-anilino-6- (2-hydroxyethyl) methylamino-1,3, having the trade name Tinopal 5BM-GX available from Ciba Specialty Chemicals. 5
-Triazin-2-yl) amino] stilbene-2,2'-disodium sulfonate, 4 ', 4-bis-[(4,6-dianilino-1,3,5-triazine-2-
Yl) amino] stilbene-2,2'-disodium sulfonate, 4,4'-
Bis-[(4-anilino-6-methylamino-1,3,5-triazin-2-yl) amino] stilbene-2,2′-disodium sulfonate, 4,4′-bis-[(4-anilino -6-ethylamino-1,3,5-triazin-2-yl) amino] stilbene-2,2'-disodium sulfonate and 4,4'-bis-
(4-phenyl-1,2,3-triazol-2-yl) stilbene-2,2 ′
-Disulfonic acid.

[0135] hydroxycoumarin hydroxycoumarin has the following coumarin basic structure, and is a class of compounds having at least one hydroxy moiety:

[0136]

Embedded image

Hydroxy coumarins useful in the present invention include those having formula (5):

[0138]

Embedded image

Wherein R ²⁰¹ is H, OH, Cl, CH ₃ , CH ₂ COOH, CH ₂ SO ₃ H, C
H ₂ OSO ₃ H or CH ₂ OPO (OH) OH, wherein R ²⁰² is H, phenyl,
COO-C ₁ ~C ₃₀ - alkyl, glucose, or a group of the formula (6):

[0140]

Embedded image

And R ²⁰³ is OH or OC ₁ -C ₃₀ -alkyl, and R ²⁰⁴ is OH or OC ₁ -C ₃₀ alkyl, glycoside, or a group of formula (7) :

[0142]

Embedded image

Wherein R ²⁰⁵ and R ²⁰⁶ are independently phenylamino, mono- or disulfonated phenylamino, morpholino, N (CH ₂ CH ₂ OH) ₂ , N (CH ₃ ) (CH ₂ CH ₂ O
_{H), NH 2, N (} C 1 ~C 30 - _{alkyl) 2, OCH 3, Cl,} NH- (CH 2) 1-4 S
O ₃ H or NH— (CH ₂ ) _1-4 OH.

Suitable hydroxycoumarins include 6,7-dihydroxycoumarin available from Wako Chemicals, 4-methyl-7-hydroxycoumarin available from Wako Chemicals, 4-methyl-7-hydroxycoumarin available from Wako Chemicals. Methyl-6
7-dihydroxycoumarin, esculin available from Wako Chemicals and umbelliferone (4-hydroxycoumarin) available from Wako Chemicals.

[0145] Amino coumarin amino coumarin has a coumarin base structure, and a class of compounds having at least one amino moiety of. Aminocoumarins useful in the present invention include those having formula (8):

[0146]

Embedded image

In the formula, R ²⁰⁷ is H, Cl, CH ₃ , CH ₂ COOH, CH ₂ SO ₃ H, CH ₂ OS
O ₃ H, or CH ₂ OPO (OH) OH, and R ²⁰⁸ is H, phenyl, or C
OOC _{1 to} C ₃₀ alkyl, and R ²⁰⁹ and R ²¹⁰ are independently H, NH ₂ , N (C _{1 to} C ₃₀ alkyl) ₂ , NHC _{1 to} C ₃₀ alkyl, or NHCOC _{1 to} C ₃₀ Is an alkyl.

Suitable aminocoumarins include the trade name Calcofluor (Calc, available from Basff)
ofluor) -methyl-7,7'-diethylaminocoumarin with -RWP, 4-methyl-7,7 'with the trade name Calcofluor-LD available from Basff
-Includes dimethylaminocoumarin.

Triazoles Triazoles are a class of compounds having the following basic structure.

[0150]

Embedded image

The triazoles useful in the present invention include those of formulas (9)-(12) and (15)-(20)
And those having:

[0152]

Embedded image

Wherein R ³⁰¹ and R ³⁰² are independently H, C ₁ -C ₃₀ alkyl, phenyl or monosulfonated phenyl; An ⁻ and M are as defined above, wherein compounds have trans planar orientation or cis plane orientation; preferably R ³⁰¹
Is phenyl, R ³⁰² is H, and M is sodium; wherein the compound is in the trans-plane orientation;

[0154]

Embedded image

Wherein R ³⁰³ is H or Cl; R ³⁰⁴ is SO ₃ M, SO ₂ N (C ₁ -C ₃₀ -alkyl) ₂ , SO ₂ O-phenyl or CN; R ³⁰⁵ is , H, SO ₃ M, COO
M, OSO ₃ M, or OPO (OH) OM; and M is as previously defined, wherein the compound has a trans or cis plane orientation; preferably R ³⁰³ and R ³⁰⁵ is H and R ³⁰⁴ is SO ₃ M where M is Na; wherein the compound has trans planar orientation;

[0156]

Embedded image

In the formula, R³⁰⁶And R³¹²Each independently represents H, a sulfonic acid group or a salt thereof,
Ter or amide, carboxylic acid group or its salt, ester or amide, cyan
Group, halogen atom, unsubstituted or substituted alkylsulfonyl, arylsulfonyl
, Alkyl, alkoxy, aralkyl, aryl, aryloxy, aralkoxy
A cycloalkyl group, a few nitrogen atoms or one oxygen atom and one or two nitrogen atoms;
Represents an unsubstituted or substituted 5-membered heterocyclic ring containing³⁰⁷And R³¹³With
, They are methylenedioxy, ethylenedioxy, methyleneoxymethyleneoxy
Si, trimethylene, tetramethylene, propenylene, butenylene or butadienyl
Represents a len group, R³⁰⁷And R³¹³Each independently represents H, a sulfonic acid group or a salt thereof
, Esters or amides, carboxylic acids or salts thereof, esters or amides,
Represents a cyano group, a halogen atom, an unsubstituted or substituted alkyl or alkoxy group,
Or R³⁰⁶And R³¹²With methylenedioxy, ethylenedioxy, methylenedioxy
Xymethyleneoxy, trimethylene, tetramethylene, propenylene, butenile
Or butadienylene;³⁰⁸And R³¹⁴Is independently H, halogen
An atom or an unsubstituted or substituted alkyl group;³⁰⁹And R³¹¹Are independent
To H, a halogen atom, a cyano group sulfonic acid group or a salt, ester or amino group thereof.
Or a carboxylic acid group or a salt, ester or amide thereof; ³¹⁰ Is independently H, a halogen atom, a cyano group sulfonic acid group or a salt, or an alkyl group.
Hydroxy, alkoxy of 1 to 30 carbon atoms, cyano, halogen,
Carbohydrates having 1 to 30 carbon atoms in ruboxy, sulfonic acid, and alkoxy moieties
Represents an alkoxy, phenyl or phenoxy; alkoxy group is hydroxy, 1
Alkoxy, cyano, halogen, carboxy, alkoxy moieties of up to 30 carbon atoms
Carboalkoxy, phenyl or phenoxy having 1 to 30 carbon atoms per minute
Thus, a phenyl, phenylalkyl or phenoxy group can be substituted
Having 1 to 30 carbon atoms in the halogen, cyano, carboxy and alkoxy moieties
Carboalkoxy, sulfo, or alkyl or alkyl of 1 to 30 carbon atoms each
Can be replaced by alkoxy; wherein the compound is in trans-plane orientation
Having a cis or cis plane orientation; a possible cycloalkyl group is preferably 1
Cyclohexyl, which can be substituted by alkyl of -30 carbon atoms; and
A possible five-membered heterocycle is one to four carbon atoms as a substituent;
1 to the alkyl group, halogen, phenyl, carboxy, alkoxy moiety
Carboalkoxy, cyano, benzyl having 30 carbon atoms, 1-30 carbons
V-triazo which can contain the atoms alkoxy, phenoxy or sulfo
Oxazole or 1,3,4-oxodiazole group;
The two adjacent substituents of the carbonyl group and the oxazole group are both substituted or substituted
Can form an uncondensed fused benzene nucleus;
Having planar orientation;

[0158]

Embedded image

Wherein Q ¹ represents ^one of the ring systems (13) or (14);

[0160]

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In the formula, R³¹⁷Is H, alkyl having 1 to 30 carbon atoms, cyclohexyl
Syl, C in alkyl part₁~ C₃₀Phenylalkyl with phenylalkyl, phenyl
, Alkoxy having 1 to 30 carbon atoms, or Cl, or R³¹⁸Combined with
Represents an alkylene having 3 to 30 carbon atoms;³¹⁸Is H or 1 to 30
Represents an alkyl having a carbon atom;³¹⁷Has 3 to 30 carbon atoms
Represents an alkylene;³¹⁹Represents H or methyl;³²⁰Is H, 1-30 carbons
Alkyl with atoms, phenyl, alkoxy with 1 to 30 carbon atoms, or C
l or R³²¹To form a fused benzene ring;³²¹Is H or Cl
Or R³²⁰To form a fused benzene ring;³¹⁵Is H, 1-30 charcoal
Alkyl having 1 to 30 carbon atoms, alkoxy or Cl having 1 to 30 carbon atoms, ³¹⁶ Represents H or Cl;^TwoIs an H, Cl, alkyl having 1 to 30 carbon atoms.
Or phenyl, and Q^ThreeRepresents H or Cl; wherein the compound is
Has lance plane orientation or cis plane orientation, preferably trans plane orientation
;

[0162]

Embedded image

Wherein R ³²² represents H, Cl, methyl, phenyl, benzyl, cyclohexyl or methoxy, R ³²² represents H or methyl, Z represents O or S; Has a planar or cis-plane orientation, preferably a trans-plane orientation; and

[0164]

Embedded image

In the formula, R³²⁴Is H, Cl, alkyl having 1 to 30 carbon atoms, 1 to 30 carbon atoms
Phenylalkyl, phenyl having 1 to 30 carbon atoms or alcohol having 1 to 30 carbon atoms
Represents xy or R³²⁴Is R³²⁵And represents a condensed benzene group;³²⁵Is
, H or methyl, or R³²⁵Is R³²⁴And represents a condensed benzene group; ³²⁶ Is H, an alkyl having 1 to 30 carbon atoms, an alkyl having 1 to 30 carbon atoms.
Alkoxy, Cl, carboalkoxy having 1 to 30 carbon atoms or 1 to 30 carbon atoms
Represents an alkylsulfonyl having a hydrogen atom;³²⁷Is H, Cl, methyl or
Represents methoxy; wherein the compound is in trans-plane orientation or cis-plane orientation,
Preferably has trans plane orientation

Suitable triazoles include 2- (4-styryl-3-sulfophenyl) -2H-naphtho [1,2-d] triazole, commercially available from Ciba Specialty Chemicals and having the trade name Tinopal RBS. (CI fluorescent brightener 46).

Pyrazolines Pyrazolines are a class of compounds having the following basic structure:

[0168]

Embedded image

The pyrazolines useful in the present invention include those having formulas (21)-(23):

[0170]

Embedded image

Wherein R ⁴⁰¹ is H, Cl or N (C ₁ -C ₃₀ -alkyl) ₂ , and R ⁴⁰² is H
_{, Cl, SO 3 M, SO} 2 NH 2, SO 2 NH- ( alkyl C ₁ ~C _30), COO-
C ₁ -C ₃₀ alkyl, SO ₂ —C ₁ -C ₃₀ alkyl, SO ₂ NH (CH ₂ ) _1-4 N ⁺ (
CH _{3) 3} or _{SO 2 (CH 2) 1-4 N} + H (C 1 ~C 30 - alkyl) ₂ An ^- in and, R ⁴⁰³
And R ⁴⁰⁴ are the same or different and are each H, C ₁ -C ₃₀ alkyl or phenyl, and R ⁴⁰⁵ is H or Cl; and An ⁻ and M are as defined above. Preferably, R ⁴⁰¹ is Cl and R ⁴⁰² is SO ₂ CH ₂ CH ₂
N ⁺ H (C ₁ -C ₄ -alkyl) ₂ An ⁻ , wherein An ⁻ is a phosphite,
And R ⁴⁰³ , R ⁴⁰⁴ and R ⁴⁰⁵ are each H; Equations (22) and (23) are shown below.

[0172]

Embedded image

Suitable pyrazolines include 1- (4-amidosulfonylphenyl) -3 with the trade name Blankophore DCB available from Bayer.
-(4-chlorophenyl) -2-pyrazoline (CI fluorescent brightener 121); 1
-[4- (2-Sulfoethylsulfonyl) phenyl] -3- (4-chlorophenyl) -2-pyrazolin, 1- [4- (2-sulfoethylsulfonyl) phenyl]
-3- (3,4-dichloro-6-methylphenyl) -2-pyrazolin, 1- <4
-{N- [3- (N, N, N-trimethylammonio) propyl] amidosulfonyl} phenyl> -3- (4-chlorophenyl) -2-pyrazolinmethyl sulfate and 1- <4- {2- [1-methyl-2- (N, N-dimethylamino) ethoxy] ethylsulfonyldiphenyl> -3- (4-chlorophenyl) -2-pyrazolinmethyl sulfate.

[0174] oxazole oxazole is the class of compounds having the following basic structure.

[0175]

Embedded image

The oxazoles useful in the present invention include those of formulas (24), (25), (26) and (27)
).

[0177]

Embedded image

Wherein R ⁵⁰¹ and R ⁵⁰² are independently H, Cl, C ₁ -C ₃₀ alkyl or SO ₂ -C ₁ -C ₃₀ alkyl, wherein the compound has a trans planar orientation or cis Preferably R ⁵⁰¹ is 4-CH ₃ and R ⁵⁰² is 2-CH ₃ , wherein the compound has a trans-planar orientation;

[0179]

Embedded image

In the formula, R⁵⁰³Are independently H, C (CH_Three)_Three, C (CH_Three)_Two-Phenyl, C₁~ C ₃₀ Alkyl or COO-C₁~ C₃₀Alkyl, preferably H and Q^FourIs -CH
= CH-;

[0181]

Embedded image

Or one group on each ring, R ⁵⁰³ is 2-methyl and the other R ⁵⁰³ is H
And Q ⁴ is —CH ＝ CH—; or one group on each ring, R ⁵⁰³ is 2-C (
CH ₃ ) ₃ and the other R ⁵⁰³ are H; wherein the compound has a trans-plane orientation or a cis-plane orientation, preferably a trans-plane orientation;

[0183]

Embedded image

Wherein R ⁵⁰⁴ is CN, Cl, COO-C ₁ -C ₃₀ alkyl or phenyl;
R ⁵⁰⁵ and R ⁵⁰⁶ are the atoms necessary to form a fused benzene ring or R ⁵⁰⁶ and R ⁵⁰⁸ are independently H or C ₁ -C ₃₀ alkyl; and R ⁵⁰⁷ is H, C ₁ -C ₃ is 0 alkyl or phenyl; that time the compound has a trans-coplanar orientation or cis coplanar orientation; preferably, R ⁵⁰⁴ is a 4-phenyl group, and R ⁵⁰⁵ to R ⁵⁰⁸ Are each H; wherein the compound has a trans-coplanar orientation; and

[0185]

Embedded image

Wherein R ⁵⁰⁹ is H, Cl, alkyl having 1 to 30 carbon atoms, cyclohexyl,
Wherein the alkyl moiety represents phenylalkyl having 1 to 3 carbon atoms, phenyl or alkoxy having 1 to 30 carbon atoms, R ⁵¹⁰ represents H or alkyl having 1 to 30 carbon atoms, and Q ⁵ represents Represents a group;

[0187]

Embedded image

In the formula, R ⁵¹¹ is H, alkyl having 1 to 30 carbon atoms, alkoxy having 1 to 30 carbon atoms, Cl, carboalkoxy having 1 to 30 carbon atoms, 1 to 3 carbon atoms.
Represents unsubstituted sulfamoyl or sulfamoyl mono-substituted or di-substituted by 0 alkyl or hydroxyalkyl, or 1 to 30 carbon atoms
Wherein the compound has a trans-plane orientation or a cis-plane orientation, preferably a trans-plane orientation.

Suitable oxazoles include 4,4′-bis (5-methylbenzoxazole-
2-yl) stilbene and 2- (4-methoxycarbonylstyryl) benzoxazole.

Pyrenes Pyrenes useful in the present invention include those having formulas (28) and (29):

[0191]

Embedded image

Wherein each R ⁶⁰¹ is independently C ₁ -C ₃₀ alkoxy; preferably methoxy; and

[0193]

Embedded image

Wherein each R ⁶⁰² is independently H, OH, or SO ₃ M, where M is a sulfonated phenylamino or anilino as defined above.

Suitable pyrenes include 2,4- having the trade name Fluolite XMF
Dimethoxy-6- (1′-pyrenyl) -1,3,5-triazine (CI fluorescent brightener 179), 8-hydroxy-1,3,6-pyrenetrisulfonic acid (Pharmaceutical and cosmetic green 8) No.) and 3-hydroxy-5,8,10-trisulfanylpyrene.

Porphyrins Porphyrins useful in the present invention include those having formulas (30), (31), and (32):

[0197]

Embedded image

In the formula, R ⁷⁰¹ is CH ₃ or CHO, R ⁷⁰² is H or alkyl of COOC _{1 to} C ₃₀ , and R ⁷⁰³ is H or an alkyl group having 1 to 30 carbons. ;
And

[0199]

Embedded image

Wherein each R ⁷⁰⁴ is independently H, SO ₃ M, COOM, OSO ₃ M, or OPO (O
H) OM, wherein M is a halide, as defined above, or 1-30
Q ⁶ is Cu, Mg, Fe, Cr, Co, or a mixture thereof having a cationic charge. Suitable porphyrins include porphyrins available from Wako Chemicals and copper (II) phthalocyanines available from Wako Chemicals.

Imidazoles Imidazoles are a class of compounds having the following basic structure.

[0202]

Embedded image

The imidazoles useful in the present invention include those of formula (33):

[0204]

Embedded image

Embedded image wherein X ⁻ is as defined above. Suitable imidazoles include C.I. I. One having the trade name of Fluorescent Brightener 352 or Uvtex available from Ciba Specialty Chemicals
AT is included.

UV Absorbers The compositions of the present invention may further comprise a UV (ultraviolet) absorber. UV absorbers
It is particularly useful for the substantially transparent compositions of the present invention. The UV absorbers herein are used at a weight level of the composition, preferably from about 0.01% to about 10%.

The UV absorbers useful herein can be water-soluble or water-insoluble;
p-aminobenzoic acid, salts and derivatives thereof (ethyl, isobutyl, glyceryl ester; p-dimethylaminobenzoic acid); anthranilates (i.e., o-aminobenzoate; methyl, menthyl, phenyl, benzyl, phenyl) Ethyl, linalyl, terpinyl, and cyclohexyl esters); salicylates (amyl, phenyl, benzyl, menthyl, glyceryl, and dipropylene glycol esters); cinnamic acid derivatives (menthyl and benzyl esters, -phenylcinnamonitrile; cinnamoyl butylpyruvate) Trihydroxycinnamic acid derivatives (esculetin, methylesculetin, daphnetin, and glucosides, esculin and daphnin); dibenzalacetone and benzal acetophenone; naphthol sulfonate (2- Futoru-3,6-disulfonic acid and 2-naphthol -6
, 8-disulfonic acid sodium salt); dihydroxy-naphthoic acid and its salts;
o- and p-hydroxybiphenyl disulfonates; quinine salts (bisulfate, sulfate, chloride, oleate, and tannate); quinoline derivatives (8-hydroxyquinoline salt, 2-phenylquinoline); substituted with hydroxy- or methoxy- Benzophenone; uric acid and violuric acid; tannic acid and its derivatives (for example, hexaethyl ether); (butylcarbitol) (6-propylpiperonyl) ether; hydroquinone; benzophenones (oxybenzene,
Slysobenzene, dioxybenzene, benzoresorcinol, 2,2 ', 4,4
'-Tetrahydroxybenzophenone, 2,2'-dihydroxy-4,4'-
Dimethoxybenzophenone, octabenzone; 4-isopropyldibenzoylmethane; butylmethoxydibenzoylmethane; and 4-isopropyl-di-benzoylmethane. Among these, 2-ethylhexyl p-methoxycinnamate, 4,4'-t-butylmethoxydibenzoylmethane, 2-hydroxy-
4-methoxybenzophenone, octyldimethyl p-aminobenzoic acid, digalloyltrioleate, 2,2-dihydroxy-4-methoxybenzophenoneethyl 4- [bis (hydroxypropyl)] aminobenzoate, 2-ethylhexyl 2-
Cyano-3,3-diphenyl acrylate, 2-ethylhexyl salicylate,
Glyceryl p-aminobenzoate, 3,3,5-trimethylcyclohexyl salicylate, methyl anthranilate, p-dimethyl-aminobenzoic acid or aminobenzoate, 2-ethylhexyl p-dimethylaminobenzoic acid, 2-phenylbenzimidazole -5-sulfonic acid, 2- (p-dimethylaminophenyl) -5
Includes sulfonebenzoxazoic acids and mixtures thereof. Preferred sunscreens useful in the compositions of the present invention are 2-ethylhexyl p-cinnamate, butylmethoxydibenzoylmethane, 2-hydroxy-4-methoxybenzophenone, octyldimethyl p-aminobenzoic acid and mixtures thereof. is there.

Herbal Extract The composition of the present invention may further comprise an herbal extract. Useful herbal extracts herein include water-soluble and water-insoluble. Useful herbal extracts according to the present invention include: Tsurukudami extract, Pokkudami extract, Yellowfin bark extract, Chinese elder extract, White dead nettle extract, Licorice root extract, Herb button extract , Soapwort extract, Loofah extract, Quinna peel extract, Crane saxifrage extract, Sophora angustifolia extract, Candock extract,
Chamomile extract, primrose extract, rose extract, pheasant extract, lemon extract, sicon extract, aloe extract, iris root extract, eucalyptus extract, horsetail extract, sage extract, thyme extract, Tea extract, amanori extract, cucumber extract, clove extract, raspberry extract, melissa extract,
Ginseng extract, carrot extract, horse chestnut extract, peach extract, peach leaf extract, mulberry extract, cornflower extract, hamamelis extract,
Placenta extract, thymus extract, silk extract, algae extract, hollyhock extract, hyacinth extract, apple extract, apricot extract, rabbit extract, kawagomugi extract, talus extract, western mint extract, Perilla extract, birch bark extract, daisy bark extract, tea tree extract, burdock root extract, sprouts extract, scutellaria extract, Stephania cepharant (Stephania Ce)
pharantha) extract, daisies extract, chrysanthemum flower extract, Satsuma Mandarin skin extract, Cnidium extract, Coix seed (Coix Seed) extract, Lisianthus extract, Scotch leaf extract, Hawthorn extract, Oenothera oil, Gum beer extract, Ganoderma extract, Gardenia extract, Gardenia extract, Gentian root extract, Geranium extract, Ginkgo extract, Grape leaf extract, Hawthorn extract, Pomfret extract, Honeysuckle extract, Honeysuckle Flower extract, Heelen extract, hop extract, horsetail extract, hydrangea extract, Hypericum extract, isodonis extract, isola ivy extract, rapeseed extract, Japanese cedar extract, Japanese coptis Extract, juniper extract, jujube extract, japonicus extract, la Nda extract, lettuce extract,
Licorice extract, linden extract, purple extract, loquat extract, loofah extract, malloti extract, mallow extract, calendula extract, gourd (moutan) bark extract, mistletoe extract, mukurosi ) Extract,
Artemisia extract, mulberry root extract, nettle extract, nutmeg extract, orange extract, parsley extract, hydrolyzed conchiorin protein, button root extract, peppermint extract, philodendron extract, pine cone extract, Platycodon extract, Mamadokoro extract, Rehmannia
Extract, rice bran extract, rhubarb extract, rosehip extract, rosemary extract, royal jelly extract, safflower extract, saffron crocus extract, elderberry extract, saponaria extract, sassa albo. Marginata (Sas
a albo Marginata extract, Saxifraga extract, Scutellaria root extract, Cortinalus (Lentinus edodes) extract, Shiitake extract, Sophora (Sophora)
Extract, bay extract, shobu root extract, assembly extract, thyme extract, linden extract, tomato extract, turmeric extract, uncaria extract, sphagnum extract, logwood extract, grape extract , White lily extract, wild rose extract, Aedes chinensis extract, witch hazel extract, Achillea millefolium extract, yeast extract, yucca extract, salamander extract and mixtures thereof.

[0209] Commercially available herbal extracts useful in the present invention include water-soluble and institute of occupational medicine (Institute)
of Occupational Medicine, CAPM, China National Light Industry and Maruzen, as well as those listed above available from Maruzen Contains herbal extracts.

Additional Conditioning Agents The compositions of the present invention contain an additional conditioning agent selected from the group consisting of high melting point compounds, high molecular weight ester oils, additional oily compounds, and mixtures thereof. Is also good. The additional conditioning agent is selected according to its compatibility with other components and the desired characteristics of the product. The additional conditioning agent in the present invention preferably comprises from about 0.01% to about 1% by weight of the composition.
Used up to 0%.

High Melting Point Compounds High melting point compounds useful herein are selected from the group consisting of fatty alcohols, fatty acids, fatty alcohol derivatives, fatty acid derivatives, hydrocarbons, steroids and mixtures thereof, having a melting point of at least about 25 ° C. have. One skilled in the art will appreciate that the compounds disclosed in this section of the specification may optionally fall into more than one class, for example, certain fatty alcohol derivatives may also be classified as fatty acid derivatives. ing. However, the classification given is not intended to be a limitation on that particular compound, but is for convenience of classification and nomenclature. Further, it will be understood by those skilled in the art that, depending on the number and position of the double bonds, the length and position of the branches, compounds having certain required carbon atoms may have melting points below about 25 ° C. . Such compounds with low melting points are not intended to be included in this section. Examples of such high melting point compounds are International Cosmetic Ingres Dictionary.
dient Dictionary), 5th edition, 1993 and the CTFA Cosmetic Ingredient Handbook, 2nd edition, 19
Seen during, but not limited to, 1992.

[0212] It is believed that these high melting compounds cover the hair surface and reduce friction, and thereby provide a smooth feel to the hair and thereby facilitate combing.

[0213] Fatty alcohols useful in the present invention are those having about 14 to about 30 carbon atoms, preferably about 16 to about 22 carbon atoms. These fatty alcohols can be straight or branched chain alcohols, and can be saturated or unsaturated. Examples of fatty alcohols include, but are not limited to, cetyl alcohol, stearyl alcohol, behenyl alcohol, and mixtures thereof.

[0214] Fatty acids useful in the present invention contain from about 10 to about 30 carbon atoms, preferably about 1
Those having from 2 to about 22 carbon atoms, and more preferably from about 16 to about 22 carbon atoms. These fatty acids can be straight or branched chain acids, and can be saturated or unsaturated. Also included are diacids, triacids and other polyacids that meet the requirements herein. In the present specification, salts of these fatty acids are also included. Examples of fatty acids include, but are not limited to, lauric acid, palmitic acid, stearic acid, behenic acid, sebacic acid and mixtures thereof.

Fatty alcohol derivatives and fatty acid derivatives useful herein include fatty alcohols
Alkyl ethers, alkoxylated fatty alcohols, alkoxylated fatty alcohols
Cole alkyl ethers, fatty alcohol esters, esterifiable hydrides
Fatty acid esters of compounds having a roxy group, hydroxy-substituted fatty acids, and these
Mixtures. Non-limiting examples of fatty alcohol derivatives and fatty acid derivatives include:
Substances such as methyl stearyl ether; such as ceteth-1 to ceteth-45
In the Ceteth series of compounds, the ethylene glycol
Ethylene glycol ether of cetyl alcohol as a number;
In the steareth series of compounds such as 1 to 10, there is a numerical designation.
Ethylene glycosyl of steareth alcohol, such as the number of tylene glycol moieties
Ether; ceteareth 1 to 10
Aliphatic containing predominantly coal ethers, ie cetyl and stearyl alcohol
In a mixture of alcohols, the number of ethylene glycol moieties, where
Stands for: Ceteth, Steareth, and C of Ceteareth Compounds as Explained ₁ ~ C₃₀Alkyl ethers; polyoxyethylene ethers of behenyl alcohol
E; ethyl stearate, cetyl stearate, cetyl palmitate, steari
Rustearate, myristyl myristate, polyoxyethylene cetyl ether
Stearate, polyoxyethylene stearyl ether stearate, polyoxy
Siethylene lauryl ether stearate, ethylene glycol monostearate
G, polyoxyethylene monostearate, polyoxyethylene distearate
, Propylene glycol monostearate, propylene glycol distearate
G, trimethylolpropane distearate, sorbitan stearate, polyg
Lyceryl stearate, glyceryl monostearate, glyceryl distearate
Glyceryl tristearate and mixtures thereof.

[0216] Hydrocarbons useful herein include compounds having at least about 20 carbons. Steroids useful herein include compounds such as cholesterol. High purity single compound high melting point compounds are preferred. Highly preferred is a single compound of a pure fatty alcohol selected from the group consisting of pure cetyl alcohol, stearyl alcohol and behenyl alcohol. By "pure" herein is meant at least about 90%, preferably at least about 95%, of the compound.
Having the purity of Such a single compound of high purity provides a good rinsing effect when the consumer rinses the composition.

The commercially available high melting compounds useful in the present invention include: KONOL series and NOF (NOF) trade names available from Shin Nippon Rika (Osaka, Japan) (Tokyo, Japan) Cetyl alcohol, stearyl alcohol and behenyl alcohol with NAA series available from Wako (Osaka, Japan); pure behenyl alcohol with the trade name 1-DOCOSANOL available from Wako (Osaka, Japan), Akzo (Illinois, USA) NEO-FAT (trade name), available from Witco Corp. (Chicago). Various fatty acids with HYSTRENE available from (Witco CORP.) (Dublin, Ohio, USA) and DERMA available from Vevy (Genoa, Italy); and from Nikko Available brand name Nikkor Aguasome (NIKKOL
AGUASOME) Contains cholesterol with LA.

High Molecular Weight Ester Oils High molecular weight ester oils are useful in the present invention. The high molecular weight ester oils useful herein are water-insoluble and at least about 500, preferably at least about 800
And a liquid at 25 ° C. Useful high molecular weight ester oils herein include pentaethytriol ester oil, trimethylol ester oil, poly-olefin oil, citrate oil, glyceryl ester oil and mixtures thereof. As used herein, the term “water-insoluble” means that the compound is not substantially soluble in water at 25 ° C .; When mixed with water at a concentration greater than% by weight, the compound temporarily disperses to form an unstable colloid in water, which then rapidly separates from the water into two phases.

The high molecular weight ester oils herein provide conditioning benefits such as moisture, smooth feel and ease of handling when the hair dries, but do not leave a greasy feel on the hair. . It is generally believed that water-insoluble oils can deposit on the hair. While not being bound by theory, it is believed that high molecular weight ester oils, due to their bulkiness, cover the hair surface, and consequently high molecular weight ester oils reduce hair friction and give hair smoothness and manageability . High molecular weight ester oils have some hydrophilic groups that are believed to provide a moisturizing feel, and because they are liquids they do not leave an oily feel on the hair. The high molecular weight ester oil is chemically stable under normal use and storage conditions.

[0220] Pentaerythritol ester oils useful herein include those having the formula:

[0221]

Embedded image

Wherein R ¹ , R ² , R ³ , and R ⁴ are independently branched, linear, saturated, or unsaturated alkyl, aryl, and alkylaryl having 1 to 30 carbons. Group. Preferably, R ¹ , R ² , R ³ and R ⁴ are independently a branched, straight chain, saturated or unsaturated alkyl group having about 8 to about 22 carbons. More preferably,
R ¹ , R ² , R ³ and R ⁴ are defined such that the molecular weight of the compound is from about 800 to about 1200.

The trimethylol ester oils useful herein include those having the following formula:

[0224]

Embedded image

Wherein R ¹¹ is an alkyl group having from 1 to about 30 carbons, and R ¹² , R ¹³ and R ¹⁴ are independently branched, linear, saturated or unsaturated Alkyl, aryl, and alkylaryl groups having 1 to about 30 carbons. Preferably, R ¹¹ is ethyl and R ¹² , R ¹³ and R ¹⁴ are independently a branched, straight-chain, saturated or unsaturated alkyl group having from 8 to about 22 carbons. . More preferably,
R ¹¹ , R ¹² , R ¹³ and R ¹⁴ are defined such that the molecular weight of the compound is from about 800 to about 1200.

The polyalphaolefin oil useful herein has the formula: and from about 1 to about 35
Have a viscosity of up to 2,000 cst, a molecular weight of about 200 to about 60,000 and a polydispersity of about 3 or less;

[0227]

Embedded image

Wherein R ³¹ is alkyl having about 4 to 14 carbons, preferably 4 to 10 carbons. Polyalphaolefin oils having a molecular weight of at least about 800 are useful herein. It is believed that such high molecular weight poly-α-olefin oils provide a long-lasting moist feeling to the hair. Polyalphaolefin oils having a molecular weight of less than about 800 are useful herein. Such low molecular weight poly alpha olefin oils are believed to provide a smooth, light, clean feel to the hair.

Citrate oils useful herein have the formula: at least about 500
It has a molecular weight of:

[0230]

Embedded image

Wherein R ²¹ is OH or CH ₃ COO, and R ²² , R ²³ , and R ²⁴ are independently branched, linear, saturated, or having 1 to about 30 carbons. Unsaturated alkyl, aryl, and alkylaryl groups. Preferably, R ²¹ is OH and R ²² , R ²³ and R ²⁴ are independently a branched chain having from 8 to about 22 carbons,
Straight-chain, saturated or unsaturated alkyl, aryl and alkylaryl groups. More preferably, R ²¹ , R ²² , R ²³ and R ²⁴ are defined such that the molecular weight of said compound is at least about 800.

Glyceryl ester oils useful herein are those having a molecular weight of at least about 500 and having the following formula:

[0233]

Embedded image

Wherein R ⁴¹ , R ⁴² , and R ⁴³ are independently a branched, linear, saturated, or unsaturated alkyl, aryl, and alkylaryl group having 1 to about 30 carbons. is there. Preferably, R ⁴¹ , R ⁴² and R ⁴³ are independently branched, straight chain, saturated or unsaturated alkyl, aryl and alkylaryl groups having from 8 to about 22 carbons. More preferably, R ⁴¹ , R ⁴² and R ⁴³ are defined such that the molecular weight of said compound is at least about 800.

Particularly useful pentaerythritol ester oils and trimethylol ester oils herein are pentaerythritol tetraisostearate, pentaerythritol tetraoleate, trimethylolpropane triisostearate,
Includes trimethylolpropane trioleate and mixtures thereof. Such compounds are available under the trade names KAKPTI, KAKTI and Kokyo Alcohol (Ko
kyo Alcohol) and from Nippon Rika under the trade name PTO, ENUJERUBUTP3SO.

Particularly useful poly-α-olefin oils herein include PURESYN®, a trade name with a multi-average molecular weight of about 500, available from Mobil Chemical Co., and Included is Polydecene having a Pressin 100 having a multi-average molecular weight of about 3000, and Pressin 300 having a number average molecular weight of about 6000.

Particularly useful citrate oils herein include triisocetyl citrate with the trade name Cytomol 316 available from Bernel, trade name available from Phoenix. Pelemol (T)
Includes triisostearyl citrate with ISC, and trioctyldodecyl citrate with tradename Cytomol 320 available from Burnel.

Particularly useful glyceryl ester oils herein include Taiyo Ka (Taiyo Ka)
giso), a triisostearin having the trade name SUN ESPOL G-318, Crowda Surfactants Altidi. (Croda
Surfactants Ltd.) available under the trade name CITHROL GTO, triolein, available from babies under the trade name EFADERMA-
F) or trilinolein, or EFA-GLYCERIDES (trade name) obtained from Brocks.

Additional Oil Compounds Additional oil compounds useful herein include fatty alcohols and their derivatives, fatty acids and their derivatives, and hydrocarbons. Additional oily compounds useful herein may be volatile or non-volatile, and have a melting point no higher than about 25 ° C. Without being limited by theory, it is believed that the additional oily compounds can penetrate the hair and alter the hydroxy bonds of the hair, thereby providing the hair with softness and flexibility. The additional oily compounds in this section should be distinguished from the high melting point compounds described above. Examples of these additional oily compounds are described in International Cosmetic Ingredient Dictionary, 5th edition, 19
1993, and in the CTFA Cosmetic Ingredient Handbook, 2nd Edition, 1992, without limitation.

The fatty alcohols useful herein include from about 10 to about 30 carbon atoms, preferably from about 12 to about 22 carbon atoms, and more preferably about 1 to about 22 carbon atoms.
Includes those having from 6 to about 22 carbon atoms. These fatty alcohols can be straight or branched chain alcohols and can be saturated or unsaturated alcohols, preferably unsaturated alcohols. Examples of these compounds include oleyl alcohol, palmitoleic alcohol, isostearyl alcohol, isocetyl alcohol, undecanol, octyldodecanol, octyldecanol, octyl alcohol, caprylic alcohol, decyl alcohol, and lauryl alcohol. Not limited.

[0241] Fatty acids useful in the present invention include from about 10 to about 30 carbon atoms, preferably from about 12 to about 22 carbon atoms, and more preferably from about 16 to about 22 carbon atoms. Are included. These fatty acids can be straight or branched chain acids, and can be saturated or unsaturated. Suitable fatty acids include, for example, oleic acid, linoleic acid, isostearic acid, linolenic acid, ethyl linolenic acid, ethyl linolenic acid, arachidonic acid and ricinoleic acid.

Fatty acid derivatives and fatty alcohol derivatives are used herein, for example, as esters of fatty alcohols, alkoxylated fatty alcohols, alkyl ethers of fatty alcohols, alkyl ethers of alkoxylated fatty alcohols, and bulky ester oils such as pentaerythritol esters Oil, trimethylol ester oil, citrate ester oil, glyceryl ester oil and mixtures thereof are defined. Non-limiting examples of fatty acid derivatives and aliphatic alcohol derivatives include, for example, methyl linoleate, ethyl linoleate, isopropyl linoleate, isodecyl oleate, isopropyl oleate, ethyl oleate, octyl dodecyl oleate, oleyl oleate, Decyl oleate, butyl oleate, methyl oleate, octyldodecyl stearate, octyldodecyl isostearate,
Octyl dodecyl isopalmitate, octyl isoperargonate, octyl pelargonate, hexyl isostearate, isopropyl isostearate, isodecyl isononanoate, isopropyl stearate, ethyl stearate,
Methyl stearate and Oles-2. Bulk ester oils such as pentaerythritol ester oil, trimethylol ester oil, citrate oil and glyceryl ester useful herein are less than about 800, preferably less than about 50.
It has a molecular weight of less than 0.

[0243] Hydrocarbons useful herein include straight chain, cyclic, and branched chain hydrocarbons that may be saturated or unsaturated as long as they have a melting point below about 25 ° C. Such hydrocarbons have about 12 to about 40 carbon atoms, preferably about 12 to about 30 carbon atoms, and preferably about 12 to about 22 carbon atoms. Also included herein are polymeric hydrocarbons of alkenyl monomers, for example, polymers of C _2-6 alkenyl monomers. These polymers can be linear or branched polymers. These linear polymers are typically relatively short in length and have a total number of carbon atoms as described above. The branched polymer can have a substantially longer chain length. The average number of molecular weights of such materials can vary widely, but is typically up to about 500, preferably from about 200 to
About 400, and more preferably about 300 to about 350. Various grades of mineral oil are also useful herein. Mineral oil is a liquid mixture of hydrocarbons obtained from petroleum. Particular examples of suitable hydrocarbon materials include paraffin oil, mineral oil, dodecane, isododecane, hexadecane, isohexadecane, eicosene, isoeicosene, tridecane, tetradecane, polybutene, polyisobutene and mixtures thereof. For use herein, preferred are mineral oils, polyalpha-olefin oils, such as hydrocarbons selected from the group consisting of isododecane, isohexadecane, polybutene, polyisobutene, and mixtures thereof.

Commercially available aliphatic alcohols and derivatives thereof useful herein include Shin Nippon Rika (
Shin Nippon Rika), trade name UNJECOL 90BH
Oleyl alcohol with R, available from SCHER, various liquid esters having the trade name SCHERCEMOL series, and hexyl isostearate and ZPIS having the trade name HIS, available from Kokyu alcohol Isopropyl isostearate having the formula: Commercially available bulky ester oils useful herein include Mobil Chemical Company
Co., Ltd. under the trade name MOBIL ESTER P43. Commercially available hydrocarbons useful herein include PERMETHYL under the trade name available from Presperse (South Painfield, NJ, USA).
Isododecane, isohexadeance and isoeicosene with 99A, permethyl 101A and permethyl 1082, Amoco Chemicals (
INDOPOL (trade name) available from Illinois, Chicago, and the United States
) Copolymers of isobutene and n-butene with H-100, Witco
Mineral oil with trade name Benol, available from Exxon Chemical Company (Houston, Texas, USA)
Isoparaffin with OPAR).

Other Additional Components A wide variety of other additional components can be formulated in the present compositions. These include: other conditioning agents, such as hydrolyzed collagen with the trade name Peptein 2000 available from Hormel, vitamin E with the trade name Emix-d available from Eisai, Roche Panthenol, available from Roche, panthenyl ethyl ether, available from Roche
Hydrolyzed keratins, proteins, plant extracts and nutrients; hair fixing polymers;
For example, amphoteric fixing polymers, cationic fixing polymers, anionic fixing polymers, nonionic fixing polymers and silicone-grafted copolymers; preservatives such as benzyl alcohol, methylparaben, propylparaben and imidazolidinyl urea; pH regulators such as Citric acid, sodium citrate, succinic acid,
Phosphoric acid, sodium hydroxide, sodium carbonate; generally, salts such as potassium acetate and sodium chloride; coloring agents, for example, food, pharmaceutical and cosmetic or pharmaceutical and cosmetic pigments; hair oxidizing (bleaching) agents, for example, peroxides Hydrogen, perborate and persulfate salts; hair reducing agents such as thioglycolate; fragrances; and sequestering agents such as disodium ethylenediaminetetraacetate; ultraviolet and infrared screens and absorbers such as octyl salicylate, zinc pyrithione. Anti-dandruff agents; and mixtures thereof.

EXAMPLES The following examples further describe and illustrate embodiments within the scope of the present invention. These examples are provided for illustrative purposes only, and numerous modifications of the present invention are possible without departing from the spirit and scope of the present invention and are not limiting. Components are identified by chemical or CTFA name, or otherwise defined below.

[0247]

[Table 1]

Definition of Compounds ^{* 1} Destructible visible particles 1: Unisphere AGE-527 available from Induchem AG ^{* 2} Destructible visible particles 2: Unisphere YE available from Induchem AG
-501 ^{* 3} Destructible visible particles 3: Unicerin C-3 available from Induchem AG
0 ^{* 4} Cetyl hydroxyethylcellulose: POLYSURF 67 available from Herculu ^{* 5} Hydroxyethylcellulose: Natrosol ^{* 6} available from Hercules ^{* 6} Polyquaternium-39: Merquat Plus available from Calgon Plus) 3330 ^{* 7} Polyquaternium-22: Markat 280 ^{* 8} available from Calgon Behenyltrimethylammonium chloride: INCROQUAT TMC-80 ^{* 9} alkyl silicone emulsion available from Croda: obtained from Dow Corning alkyl grafted copolymer silicone emulsion DC2-2845 ^{* 10} dimethicone and dimethiconol: DCQ2-1403 ^{* 11} polyethylene glycidyl available from Dow Corning (Dow Corning) Lumpur 200: Union Carbide (Union Carbide)
Carbowax PEG 200 ^{* 12} 2,4-dimethoxy-6- (1'pyrenyl) -1,3,5-triazine available from:
2,4-Dimethoxy-6- (1 ′) available from Ciba Geigy
Pyrenyl) -1,3,5-triazine ^{* 13} Porphyrin: Porphyrin ^{* 14} available from Wako Chemicals ^{* 14} Benzophenone-4: Uvnul available from Basf (BASF)
) MS-40 ^{* 15} Octylmethoxycinnamate: Parasol MCX available from Roche ^{* 16} Panthenol: Panthenol available from Roche

Preparation Methods Polymeric materials, such as nonionic and amphoteric viscopolymers, when present,
Disperse in water at room temperature and mix by vigorous stirring. If necessary to disperse the polymeric material, a tri-blender can be used. If an inorganic thickener is used, it is mixed in water with vigorous stirring at room temperature. Add the remaining components to this and mix by stirring until uniform.

If a cationic surfactant is included in the formulation, a premix is made by stirring and dissolving the cationic surfactant in boiling water having a temperature greater than 70 ° C., then lower than 40 ° C. Cool. Add the resulting premix to the mixture.

Examples 1-5 are hair conditioning compositions of the present invention that are particularly useful for leave-on applications. These embodiments have many advantages. They are transparent and clearly show destructible visible particles. They can also provide improved conditioning benefits such as smoothness, softness, reduced rubbing, and are easier to apply to hair. The destructible visible particles can be easily broken down on the hand with a small shear force by the finger.

The examples and embodiments described herein are for illustrative purposes only, and in view of these, various modifications or alterations may be made without departing from the spirit and scope of the invention. It is understood that this will be suggested to those skilled in the art.

──────────────────────────────────────────────────続 き Continuation of front page (81) Designated country EP (AT, BE, CH, CY, DE, DK, ES, FI, FR, GB, GR, IE, IT, LU, MC, NL, PT, SE ), OA (BF, BJ, CF, CG, CI, CM, GA, GN, GW, ML, MR, NE, SN, TD, TG), AP (GH, GM, KE, LS, MW, SD, SZ, UG, ZW), EA (AM, AZ, BY, KG, KZ, MD, RU, TJ, TM), AL, AM, AT, AU, AZ, BA, BB, BG, BR, BY, CA, CH, CN, CU, CZ, DE, DK, EE, ES, FI, GB, GD, GE, GH, GM, HR, HU, ID, IL, IN, IS, JP, KE , KG, KP, KR, KZ, LC, LK, LR, LS, LT, LU, LV, MD, MG, MK, MN, MW, MX, NO, NZ, PL, PT, RO, RU, SD, SE, SG, SI, SK, SL, TJ, TM, TR, TT, UA, UG, US, UZ, VN, YU, ZW (72) Inventor Takashi Kosako -3 −202 F term (reference) 4C083 AA111 AB052 AB172 AB222 AB372 AC112 AC172 AC212 AC342 AC482 AC522 AC642 AC692 AC852 AD011 AD042 AD151 AD201 AD211 AD282 BB06 BB46 BB53 CC33 DD01 DD16 EE06 EE07

Claims (7)

[Claims] 1. A hair conditioning composition comprising: (1) a destruction comprising a structural material selected from the group consisting of polysaccharides and derivatives thereof, saccharides and derivatives thereof, oligosaccharides, monosaccharides, and mixtures thereof. (2) an amphoteric viscosifier polymer, a nonionic viscosifier polymer, an inorganic viscosifier, and a mixture thereof, and (3) an aqueous carrier; A hair conditioning composition wherein the composition is transparent. 2. The hair conditioning composition according to claim 1, further comprising a cationic conditioning agent selected from the group consisting of a cationic surfactant, a cationic polymer, and mixtures thereof. 3. The hair conditioning composition according to claim 1, further comprising a silicone compound. 4. The hair conditioning composition according to claim 1, further comprising a wetting agent. 5. The hair conditioning composition according to claim 1, further comprising an optical brightener. 6. The hair conditioning composition according to claim 1, further comprising a UV absorber. 7. The hair conditioning composition according to claim 1, further comprising an herbal extract.