JP2002505658A - Disinfection composition and surface disinfection method - Google Patents
Disinfection composition and surface disinfection methodInfo
- Publication number
- JP2002505658A JP2002505658A JP52535197A JP52535197A JP2002505658A JP 2002505658 A JP2002505658 A JP 2002505658A JP 52535197 A JP52535197 A JP 52535197A JP 52535197 A JP52535197 A JP 52535197A JP 2002505658 A JP2002505658 A JP 2002505658A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- composition
- composition according
- disinfecting
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 210
- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims description 12
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 54
- 230000000249 desinfective effect Effects 0.000 claims abstract description 33
- 230000000845 anti-microbial effect Effects 0.000 claims abstract description 25
- 239000000341 volatile oil Substances 0.000 claims abstract description 20
- 239000004599 antimicrobial Substances 0.000 claims abstract description 8
- 239000002738 chelating agent Substances 0.000 claims description 33
- 239000004094 surface-active agent Substances 0.000 claims description 31
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 23
- 125000000217 alkyl group Chemical group 0.000 claims description 23
- 239000007788 liquid Substances 0.000 claims description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- 239000003921 oil Substances 0.000 claims description 13
- 235000019198 oils Nutrition 0.000 claims description 13
- 239000007921 spray Substances 0.000 claims description 13
- 229960003237 betaine Drugs 0.000 claims description 12
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 claims description 10
- 150000001412 amines Chemical class 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 10
- 229940117986 sulfobetaine Drugs 0.000 claims description 10
- 230000000844 anti-bacterial effect Effects 0.000 claims description 9
- 239000003945 anionic surfactant Substances 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 7
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- 239000000975 dye Substances 0.000 claims description 6
- 239000002736 nonionic surfactant Substances 0.000 claims description 6
- PTMHPRAIXMAOOB-UHFFFAOYSA-L phosphoramidate Chemical compound NP([O-])([O-])=O PTMHPRAIXMAOOB-UHFFFAOYSA-L 0.000 claims description 6
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- 239000002280 amphoteric surfactant Substances 0.000 claims description 5
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- 235000001636 Mentha x rotundifolia Nutrition 0.000 claims description 4
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- 239000003205 fragrance Substances 0.000 claims description 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims description 4
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 claims description 4
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- 239000010678 thyme oil Substances 0.000 claims description 4
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 3
- 240000004760 Pimpinella anisum Species 0.000 claims description 3
- 235000012550 Pimpinella anisum Nutrition 0.000 claims description 3
- 239000012190 activator Substances 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 239000000872 buffer Substances 0.000 claims description 3
- 150000007942 carboxylates Chemical class 0.000 claims description 3
- 239000010630 cinnamon oil Substances 0.000 claims description 3
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- 125000001072 heteroaryl group Chemical group 0.000 claims description 3
- 239000001525 mentha piperita l. herb oil Substances 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
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- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 2
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- 150000008051 alkyl sulfates Chemical class 0.000 claims description 2
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- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 229960001617 ethyl hydroxybenzoate Drugs 0.000 claims description 2
- 235000010228 ethyl p-hydroxybenzoate Nutrition 0.000 claims description 2
- 239000004403 ethyl p-hydroxybenzoate Substances 0.000 claims description 2
- NUVBSKCKDOMJSU-UHFFFAOYSA-N ethylparaben Chemical compound CCOC(=O)C1=CC=C(O)C=C1 NUVBSKCKDOMJSU-UHFFFAOYSA-N 0.000 claims description 2
- 229960000587 glutaral Drugs 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 claims description 2
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 claims description 2
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 claims description 2
- 229960002216 methylparaben Drugs 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 239000010665 pine oil Substances 0.000 claims description 2
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 claims description 2
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 claims description 2
- 229960003415 propylparaben Drugs 0.000 claims description 2
- 239000002689 soil Substances 0.000 claims description 2
- 239000003381 stabilizer Substances 0.000 claims description 2
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims description 2
- 239000000375 suspending agent Substances 0.000 claims description 2
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 2
- 239000001941 cymbopogon citratus dc and cymbopogon flexuosus oil Substances 0.000 claims 2
- 235000019499 Citrus oil Nutrition 0.000 claims 1
- 235000019501 Lemon oil Nutrition 0.000 claims 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims 1
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- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 claims 1
- 150000008052 alkyl sulfonates Chemical class 0.000 claims 1
- 239000010617 anise oil Substances 0.000 claims 1
- 239000007844 bleaching agent Substances 0.000 claims 1
- 239000010624 camphor oil Substances 0.000 claims 1
- 229960000411 camphor oil Drugs 0.000 claims 1
- 239000003093 cationic surfactant Substances 0.000 claims 1
- 239000010627 cedar oil Substances 0.000 claims 1
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- 239000010500 citrus oil Substances 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 claims 1
- 239000010501 lemon oil Substances 0.000 claims 1
- 239000010502 orange oil Substances 0.000 claims 1
- 235000019719 rose oil Nutrition 0.000 claims 1
- 239000010666 rose oil Substances 0.000 claims 1
- 239000010668 rosemary oil Substances 0.000 claims 1
- 229940058206 rosemary oil Drugs 0.000 claims 1
- 239000010671 sandalwood oil Substances 0.000 claims 1
- 239000001384 succinic acid Substances 0.000 claims 1
- 230000002087 whitening effect Effects 0.000 claims 1
- -1 alkali metal cation Chemical class 0.000 description 22
- 239000002253 acid Substances 0.000 description 15
- 239000004744 fabric Substances 0.000 description 13
- 150000003839 salts Chemical class 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 7
- 150000007513 acids Chemical class 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 7
- 230000008901 benefit Effects 0.000 description 6
- 210000004027 cell Anatomy 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000003599 detergent Substances 0.000 description 6
- 238000010790 dilution Methods 0.000 description 6
- 239000012895 dilution Substances 0.000 description 6
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- 230000001580 bacterial effect Effects 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 150000002430 hydrocarbons Chemical group 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
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- 229920005989 resin Polymers 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 241000233866 Fungi Species 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
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- LNFLHXZJCVGTSO-UHFFFAOYSA-N 1-(3-butoxypropoxy)propan-1-ol Chemical compound CCCCOCCCOC(O)CC LNFLHXZJCVGTSO-UHFFFAOYSA-N 0.000 description 2
- KNENSDLFTGIERH-UHFFFAOYSA-N 2,2,4,4-tetramethyl-3-phenylpentan-3-ol Chemical compound CC(C)(C)C(O)(C(C)(C)C)C1=CC=CC=C1 KNENSDLFTGIERH-UHFFFAOYSA-N 0.000 description 2
- IXWOUPGDGMCKGT-UHFFFAOYSA-N 2,3-dihydroxybenzaldehyde Chemical compound OC1=CC=CC(C=O)=C1O IXWOUPGDGMCKGT-UHFFFAOYSA-N 0.000 description 2
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- WXTMDXOMEHJXQO-UHFFFAOYSA-N 2,5-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC(O)=CC=C1O WXTMDXOMEHJXQO-UHFFFAOYSA-N 0.000 description 2
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- XNCSCQSQSGDGES-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]propyl-(carboxymethyl)amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)C(C)CN(CC(O)=O)CC(O)=O XNCSCQSQSGDGES-UHFFFAOYSA-N 0.000 description 2
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- IBGBGRVKPALMCQ-UHFFFAOYSA-N 3,4-dihydroxybenzaldehyde Chemical compound OC1=CC=C(C=O)C=C1O IBGBGRVKPALMCQ-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
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- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/18—Liquid substances or solutions comprising solids or dissolved gases
- A61L2/186—Peroxide solutions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P17/00—Drugs for dermatological disorders
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- A61P31/00—Antiinfectives, i.e. antibiotics, antiseptics, chemotherapeutics
- A61P31/04—Antibacterial agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/046—Insoluble free body dispenser
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/049—Cleaning or scouring pads; Wipes
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
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Abstract
(57)【要約】 本発明は、全組成物の０．１〜１５重量％の過酸化水素、および抗菌精油またはその混合物を含んだ消毒組成物による表面の消毒に関する。 (57) [Summary] The present invention relates to the disinfection of surfaces with a disinfecting composition comprising 0.1-15% by weight of the total composition of hydrogen peroxide, and an antimicrobial essential oil or a mixture thereof.
Description
【発明の詳細な説明】 消毒組成物および表面の消毒方法 技術分野 本発明は、生物表面（例えば、ヒト皮膚、口など）と、限定されないが、壁、 タイル、テーブルトップ、ガラス、浴室表面、キッチン表面、皿のような硬質表 面および布帛、衣類、カーペットなどを含む無生物表面を含めた、様々な表面を 消毒およびクリーニングするために使用できる抗菌組成物に関する。 背景 抗微生物／抗菌組成物は、消毒する能力を有した物質を含有している。消毒物 質は表面上に存在する微生物、例えば細菌をかなり減少させるか、または消失さ えさせることが、一般的に認識されている。例えば、次亜塩素酸類のような含ハ ロゲン化合物または四級化合物をベースにした組成物は、消毒目的に関して当業 界で広く記載されている。過酸を含んだ組成物も消毒組成物として知られている 。 しかしながら、過酸類をベースにしたこのような消毒組成物に伴う欠点は、そ れらが消毒作用を発揮するように接触させた表面にダメージを与えるおそれがあ ることである。確かに、過酸類をベースにしたこのような消毒組成物は、硬質表 面および布帛、特にシルク、ウールなどのようなデリケートな布帛を含めた様々 な表面にとり安全でないと消費者に思われている。 したがって、本発明の目的は、処理された表面に改善された安全性を示しなが ら、高希釈条件下で用いられたときでも上記表面に付与される消毒性能を損わな いような消毒組成物を提供することである。 上記目的は、全組成物の０．１〜１５重量％の過酸化水素、および抗菌精油ま たはその混合物を含んだ組成物を提供することにより達成されることがわかった 。 更に詳しくは、過酸化水素および上記抗菌精油を含んだ本発明の組成物はそれで 処理された表面に改善された安全性を示しながら、高希釈レベルでも、即ち１： １００（組成物：水）の希釈レベルまで、清潔な表面、即ち有機および／または 無機汚れのない表面上で優れた消毒も行うことがわかった。 したがって、本発明による組成物は、生物表面（例えば、オーラル製品または 練歯磨として用いるときには、ヒト皮膚および／または口）と、無生物表面を含 めた、すべてのタイプの表面を消毒するために適している。確かに、この技術は 、硬質表面用と洗濯用に、例えばいわゆる“ソーキングモード”（soaking mode ）、“スルー・ザ・ウォッシュモード”（through the wash mode）で洗濯洗剤 または洗濯添加物として、または“前処理モード”で洗濯前処理物としても、特 に適している。更に詳しくは、本発明による組成物は食品および／またはベビー と接触する表面を含めたデリケートな表面で安全に用いるために適している。確 かに、希釈条件下で本発明による組成物を用いたとき、それで消毒された表面上 に残される化学残留物の量は減少する。このため、本発明の組成物が希釈条件下 で適用された後に、例えば硬質表面をすすぐことは不要かもしれない。 本発明の利点は、グラム陽性およびグラム陰性菌株を含めた広範囲の細菌純株 と真菌のようなより耐性の微生物で優れた消毒が行えることである。 本発明の組成物のもう１つの利点は、付与される消毒性に加えて、良好なクリ ーニングも、特に本組成物が界面活性剤および／または溶媒を更に含んだ本発明 の態様で行えることである。 本発明の組成物の更にもう１つの利点は、それらが異なる形態で、例えば慣用 的な洗剤ボトルに詰められた液体形態、スプレー／フォームディスペンサーに詰 められたスプレーまたはフォームとなりうる形態、このような組成物を取り込ん だふきとり用品の形態、あるいは非液体形態（例えば、ゲル、ペースト形または 固形）で提供されることである。 先行技術の代表例は、四級アンモニウム塩および精油と一緒に、有機酸、ペル ボレート、過酸およびそれらの塩の群から選択される化合物を含んだ液体消毒組 成物について開示している、例えばＷＯ８８／００７９５である。過酸化水素は 、そのレベルはもちろんとして、その消毒組成物で開示されていない。 ＥＰ‐Ｂ‐２８８６８９では、抗菌有効量のパイン油と少くとも１種の油溶性 有機酸を含んだ、硬質表面用の液体について開示している。過酸化水素は開示さ れていない。 ＵＳ５，４０３，５８７は、硬質表面を衛生的に、消毒して、清潔にするため に使用できる水性抗菌組成物を開示している。更に詳しくは、ＵＳ５，４０３， ５８７は、タイム油、ユーカリ油、クローブ油などのような抗菌性効力を示す精 油（０．０２〜５％）と、水キャリア中でその精油の水性溶液または分散液を形 成する上で十分な溶解または分散剤とを含んだ、水性組成物（ｐＨ１〜１２）に ついて開示している。過酸化水素は開示されていない。 発明の要旨 本発明は、全組成物の０．１〜１５重量％の過酸化水素、および抗菌精油また はその混合物を含んだ消毒組成物に関する。 本発明は、本発明による消毒組成物が表面上に適用される、表面を消毒するた めの方法にも更に関する。 発明の具体的な説明 消毒組成物： 本発明による消毒組成物は、全組成物の０．１〜１５重量％の過酸化水素、お よび抗菌精油を含んでいる。 本発明による消毒組成物は、液体または非液体形態（例えば、ゲル、ペースト 形態、あるいは粉末または顆粒形態のような固形）として処方される。組成物が 固形として処方される場合には、それらは使用前に適切な溶媒、典型的には水と ミックスされる。液体組成物は水性組成物でもまたは非水性組成物でもよい。液 体組成物が使用便宜上好ましい。 必須要素として、本発明による組成物は過酸化水素を含んでいる。 本発明の組成物中における過酸化水素の存在はその組成物の消毒性に寄与して いると考えられる。確かに、過酸化水素は微生物細胞の生命維持機能を攻撃し、 例えばそれは微生物細胞の細胞質内にあるリボソーム単位のアセンブリーを阻止 する。しかも、過酸化水素はタンパク質および核酸を攻撃するヒドロキシルフリ ーラジカルを生成する強い酸化剤である。更に、過酸化水素の存在は強いしみ取 り効果を示し、例えば洗濯および硬質表面適用で特に顕著である。 本組成物は、全組成物の０．１〜１５重量％、好ましくは０．５〜１０％、更 に好ましくは１〜８％の過酸化水素を含んでいる。 第二必須成分として、本発明による組成物は抗菌精油またはその混合物を含ん でいる。典型的には、本組成物は全組成物の少くとも０．００３重量％、好まし くは０．００６〜１０％、更に好ましくは０．２〜４％、最も好ましくは０．２ 〜２％の上記抗菌精油またはその混合物を含んでいる。 本組成物で用いられる適切な抗菌精油は抗菌活性を示す精油である。上記抗菌 精油はタンパク質変性剤として作用すると考えられている。上記抗菌油は、表面 を消毒するために用いられたとき、本発明の組成物の安全面に寄与する。上記抗 菌精油の別な利点は、それらが香料を加える必要性なしに本発明の消毒組成物に 快適な匂いを付与することである。確かに、本発明による消毒組成物は、表面に とり安全でありながら、消毒される清潔な表面に優れた消毒性だけでなく、良い 香りも与える。 本発明で用いられる適切な抗菌精油には、タイム、レモングラス、シトラス、 レモン、オレンジ、アニス、クローブ、アニシード、シナモン、ゼラニウム、ロ ーズ、ミント、ペパーミント、ラベンダー、シトロネラ、ユーカリ、ペパーミン ト、カンフル、ビャクダン、シダー、ローズマリー、パイン、バーベイン（verv ain）、フリーグラス（fleagrass）、レモングラス、ラタニア（ratanhiae）お よびそれらの混合物から得られる油があるが、それらに限定されない。本発明で 用いる上で特に好ましいのは、ユーカリ油、タイム油、クローブ油、シナモン油 、ゼラニウム油、ユーカリ油、ペパーミント油、ミント油およびそれらの混合物 である。 ０．１〜１５重量％の過酸化水素と、上記抗菌精油またはそれらの混合物を含 む本発明の組成物は、上記過酸化水素の代わりに過酸を用いた同様の組成物と比 較すると、表面、例えば硬質表面と、シルク、ウールなどのような布帛上で改善 された安全性を示しながら、高度希釈条件下で用いられたときでも清潔な表面で 優れた消毒性能を発揮することがわかった。 本発明に伴う利点は、着色布帛を消毒するために上記組成物を用いたときカラ ーダメージも減少して、高度希釈条件下で用いられたときでも上記布帛に優れた 消毒性能を発揮することである。確かに、過酸化水素と上記抗菌精油またはそれ らの混合物を含んだ本発明による組成物で着色布帛を処理したときに観察される 変色および／または脱色は、上記過酸化水素の代わりに過酸を使うこと以外は同 様の組成物を用いたときに観察される変色および／または脱色と比較して減少し ており、高度希釈条件下で用いられたときでも上記布帛で優れた消毒性能を発揮 する。 表面安全性は、上記布帛の引張強度を測定することにより、布帛のような表面 上で評価される。布帛の引張強度は、引張強度法を用いて測定される。この方法 は上記布帛が破れるまでそれを引き伸ばすことにより所定布帛の引張強度を測定 することからなる。布帛を破るために要するＫｇで表示された力は“極限引張応 力”であり、“応力‐歪インストロン機械”で測定される。 優れた消毒は、高度希釈条件下で用いられたときでも、清潔な表面、即ち有機 および／または無機汚れを実質的に有しない表面上に存在する、Staphylococcus aureusのようなグラム陽性菌およびPseudomonas aeroginosaのようなグラム陰 性菌と、Candida albicansのような真菌を含めた様々な微生物に対して、本発明 の組成物で得られる。 組成物の消毒性はその組成物の殺菌活性により測定される。清潔な表面上で組 成物の殺菌活性を評価するために適した試験法は、European committee for sta ndardisation,Brusselsにより１９９５年１１月付で発行されたEuropean standa rd,prEN 1040,CEN/TC 216 N 78に記載されている。European standard,prEN 104 0,CEN/TC 216 N 78は、消毒組成物の最少殺菌活性に関する試験法および要件を 記載している。細菌コロニー形成単位（ｃｆｕ）が１０7ｃｆｕ（初期レベル） から１０2ｃｆｕ（消毒製品と接触後の最終レベル）に減少するならば試験に合 格であり、即ち生存数の１０5減少が必要である。本発明による組成物は、高度 希釈条件下で用いられたときでも、清潔な条件下でこの試験に合格する。 清潔な表面上で本組成物の殺菌活性を評価するために適したもう１つの試験法 好ましい態様において、本発明による組成物は水性液体クリーニング組成物で ある。上記水性組成物は、好ましくは１２．０以下、更に好ましくは２〜６、最 も好ましくは３〜５のｐＨを有する。組成物のｐＨは、クエン酸、コハク酸、酢 酸、アスパラギン酸、乳酸などのような有機酸、または無機酸、またはアルカリ 剤を用いて調整できる。 本発明の組成物は、ノニオン性、アニオン性、カチオン性、両性および／また は双極性界面活性剤を含めた、当業者に知られる界面活性剤を更に含んでいても よい。上記界面活性剤は、それらが本組成物のクリーニング性能に寄与すること から望ましい。 典型的には、本発明による組成物は全組成物の５０重量％以内、好ましくは ０．０１〜３０％、更に好ましくは０．１〜２５％の界面活性剤またはその混合 物を含んでいる。 このように、本発明の組成物は、好ましくは両性界面活性剤またはその混合物 を含んでいる。本発明で用いられる適切な両性界面活性剤には、ベタインおよび スルホベタイン界面活性剤、それらの誘導体またはその混合物がある。上記のベ タインまたはスルホベタイン界面活性剤は、それらが本組成物の消毒性に寄与す ることから、本発明では好ましい。確かに、それらは細菌細胞壁の透過性を増加 させることにより消毒を助けて、他の活性成分を細胞に侵入させている。 更に、上記ベタインまたはスルホベタイン界面活性剤のマイルドな作用プロフ ィールのために、それらを含んだ本組成物はデリケートな表面、例えば食品およ び／またはベビーと接触するデリケートな洗濯物または硬質表面のクリーニング に特に適している。ベタインおよびスルホベタイン界面活性剤は、皮膚および／ または処理される他の表面に対しても極めてマイルドである。 本発明の組成物で用いられる適切なベタインおよびスルホベタイン界面活性剤 は、分子が内塩を形成する塩基性および酸性双方の基を有して、広範囲のｐＨ値 にわたりカチオン性およびアニオン性双方の親水基を分子に供している、ベタイ ン／スルホベタインおよびベタイン様洗剤である。これら洗剤の一部の一般例は 、参考のため本明細書に組み込まれるＵＳ特許第２，０８２，２７５号、第２， ７０２，２７９号および第２，２５５，０８２号明細書に記載されている。本発 明で好ましいベタインまたはスルホベタイン界面活性剤は、下記式を有するか、 またはその混合物である： 上記式中Ｒ１は１〜２４、好ましくは８〜１８、更に好ましくは１２〜１４の炭 素原子を有するアルキル基であり、Ｒ２およびＲ３は１〜３の炭素原子、好まし くは１つの炭素原子を有しており、ｎは１〜１０、好ましくは１〜６の整数であ り、更に好ましくは１であり、Ｙはカルボキシルおよびスルホニル基からなる群 より選択され、Ｒ１、Ｒ２およびＲ３基の合計は１４〜２４の炭素原子である。 特に適切なベタイン界面活性剤の例には、ココナツベタインのようなＣ１２‐ Ｃ１８アルキルジメチルベタインと、ラウリルベタインのようなＣ１０‐Ｃ１６ アルキルジメチルベタインがある。 本発明で用いられる他の適切な両性界面活性剤には、アミンオキシドまたはそ の混合物がある。アミンオキシドは、それらが本組成物の消毒性に寄与すること から、本発明で好ましい。確かに、それらは細菌の細胞壁／膜を破壊することに より消毒を助け、こうして他の抗菌成分を細胞に侵入させて、例えば細胞の内側 を攻撃させる。 本発明で用いられる適切なアミンオキシドは下記式Ｒ1Ｒ2Ｒ3ＮＯを有してお り、ここでＲ1、Ｒ2およびＲ3は各々独立して１〜３０の炭素原子を有する飽和 直鎖または分岐炭化水素鎖である。本発明に従い用いられる適切なアミンオキシ ドは下記式Ｒ1Ｒ2Ｒ3ＮＯを有するアミンオキシドであり、ここでＲ1は１〜３０ 、好ましくは６〜２０、更に好ましくは６〜１４、最も好ましくは８〜１０の炭 素原子を有する炭化水素鎖であり、Ｒ2およびＲ3は独立して１〜４の炭素原子、 好ましくは１〜３の炭素原子を有する置換または非置換直鎖または分岐炭化水素 鎖であり、更に好ましくはメチル基である。Ｒ1は飽和した直鎖でもまたは分岐 した炭化水素鎖でもよい。 本発明で使用上好ましいアミンオキシドは、例えばナチュラルブレンドＣ８‐ Ｃ１０アミンオキシドと、Hoechstから市販されているＣ１２‐Ｃ１６アミンオ キシドである。 本組成物が硬質表面の消毒に特に適した本発明の好ましい態様において、界面 活性剤は、典型的には、好ましくは２：１〜１００：１、更に好ましくは６：１ 〜１００：１、最も好ましくは１０：１〜５０：１のアミンオキシド対ベタイン またはスルホベタインの重量比でアミンオキシドとベタインまたはスルホベタイ ン界面活性剤を含んだ界面活性剤系である。硬質表面を消毒するために適した本 組成物中でこのような界面活性剤系の使用は、有効なクリーニング性能を示して 、クリーニングされた表面に輝きを与え、即ち上記組成物で処理された清潔な表 面上に残る皮膜／ストリークの量は最少である。 本組成物は、好ましくはアニオン性界面活性剤またはその混合物も含んでいて よい。本発明で用いられる特に適切なアニオン性界面活性剤には、式ＲＯＳＯ3 Ｍの水溶性塩または酸があり、ここでＲは好ましくはＣ6‐Ｃ24ヒドロカルビル 、好ましくはＣ8‐Ｃ20アルキル成分を有するアルキルまたはヒドロキシアルキ ル、更に好ましくはＣ8‐Ｃ16アルキルまたはヒドロキシアルキルであり、Ｍは Ｈまたはカチオン、例えばアルカリ金属カチオン（例えば、ナトリウム、カリウ ム、リチウム）、あるいはアンモニウムまたは置換アンモニウム（例えば、メチ ル‐、ジメチル‐およびトリメチルアンモニウムカチオンと、テトラメチルアン モニウムおよびジメチルピペリジニウムカチオンのような四級アンモニウムカチ オン、エチルアミン、ジエチルアミン、トリエチルアミンのようなアルキルアミ ンから誘導される四級アンモニウムカチオンと、それらの混合物）である。 本発明で用いられる他の適切なアニオン性界面活性剤には、アルキルジフェニ ルエーテルスルホネートおよびアルキルカルボキシレートがある。他のアニオン 性界面活性剤には、石鹸の塩（例えばナトリウム、カリウム、アンモニウムおよ び置換アンモニウム塩、例えばモノ、ジおよびトリエタノールアミン塩がある） 、 Ｃ9‐Ｃ20直鎖アルキルベンゼンスルホネート、Ｃ8‐Ｃ22一級または二級アルカ ンスルホネート、Ｃ8‐Ｃ24オレフィンスルホネート、例えば英国特許明細書第 １，０８２，１７９号明細書に記載されたようにアルカリ土類金属シトレートの 熱分解産物のスルホン化により製造されるスルホン化ポリカルボン酸、Ｃ8‐Ｃ2 4 アルキルポリグリコールエーテルサルフェート（１０モル以内のエチレンオキ シドを含む）、アルキルエステルスルホネート、例えばＣ14‐Ｃ16メチルエステ ルスルホネート、アシルグリセロールスルホネート、脂肪オレイルグリセロール サルフェート、アルキルフェノールエチレンオキシドエーテルサルフェート、パ ラフィンスルホネート、アルキルホスフェート、イセチオネート、例えばアシル イセチオネート、Ｎ‐アシルタウレート、アルキルサクシナメートおよびスルホ サクシネート、スルホサクシネートのモノエステル（特に飽和および不飽和Ｃ12 ‐Ｃ18モノエステル）、スルホサクシネートのジエステル（特に飽和および不飽 和Ｃ6‐Ｃ14ジエステル）、アシルサルコシネート、アルキル多糖のサルフェー ト、例えばアルキルポリグルコシドのサルフェート（ノニオン性非サルフェート 化合物は以下で記載されている）、分岐一級アルキルサルフェート、アルキルポ リエトキシカルボキシレート、例えば式ＲＯ（ＣＨ2ＣＨ2Ｏ）kＣＨ2ＣＯＯ-Ｍ+ （ＲはＣ8‐Ｃ22アルキルであり、ｋは０〜１０の整数であり、Ｍは可溶性塩形 成カチオンである）がある。ロジン、水素付加ロジンと、トール油中に存在する かまたはそれから誘導される樹脂酸および水素付加樹脂酸のような、樹脂酸およ び水素付加樹脂酸も適切である。追加例は”Surface Active Agents and Deterg ents"(Vol.I & II,Schwartz,Perry & Berch)に記載されている。様々なこのよう な界面活性剤は、１９７５年１２月３０日付で発行されたLaughlinらの米国特許 第３，９２９，６７８号明細書の第２３欄５８行目〜第２９欄２３行目でも一般 的に開示されている。 本組成物で使用上好ましいアニオン性界面活性剤は、Ｃ8‐Ｃ16アルキルス ルホネート、Ｃ8‐Ｃ16アルキルサルフェート、Ｃ8‐Ｃ16アルキルアルコキシル 化サルフェート（例えば、Ｃ8‐Ｃ16アルキルエトキシル化サルフェート）およ びそれらの混合物である。このようなアニオン性界面活性剤は、それらが過酸化 水素および／または抗菌精油を含んだ消毒組成物の消毒性に寄与するとわかった ことから、本発明で好ましい。例えば、Ｃ8‐Ｃ16アルキルサルフェートは、細 菌細胞膜を破壊し、酵素活性を阻害し、細胞輸送を妨げ、および／または細胞タ ンパク質を変性させることにより作用する。確かに、アニオン性界面活性剤、特 にＣ8‐Ｃ16アルキルスルホネート、Ｃ8‐Ｃ16アルキルサルフェートおよび／ま たはＣ8‐Ｃ16アルキルアルコキシル化サルフェートの添加に伴い改善された消 毒性能は、例えば本発明の組成物において、細菌に対する上記界面活性剤の多様 な攻撃様式のおかげらしいと推測される。このため、本発明のもう１つの面は、 グラム陰性および／またはグラム陽性菌に対する上記組成物の消毒性を改善する 上で、過酸化水素および／または抗菌精油を含んだ消毒組成物における、アニオ ン性界面活性剤、特にＣ8‐Ｃ16アルキルスルホネート、Ｃ8‐Ｃ16アルキルサル フェートおよび／またはＣ8‐Ｃ16アルキルアルコキシル化サルフェートの使用 である。 本発明で使用に適したノニオン性界面活性剤は、様々な脂肪アルコール鎖長と 様々なエトキシル化度で市販されている脂肪アルコールエトキシレートおよび／ またはプロポキシレートである。確かに、このようなアルコキシル化ノニオン性 界面活性剤のＨＬＢ値は、脂肪アルコールの鎖長、アルコキシル化の性質および アルコキシル化度に本質的に依存している。ノニオン系を含めたいくつかの界面 活性剤をそれらの各ＨＬＢ値と一緒に掲載した界面活性剤カタログが入手できる 。 ノニオン性界面活性剤として本発明で使用に特に適したのは、１６未満、好ま しくは１５未満、更に好ましくは１４未満のＨＬＢ（親水性‐親油性バランス） を有する疎水性ノニオン性界面活性剤である。それらの疎水性ノニオン性界面活 性剤は、良好な油切れ性を示すことがわかった。 本発明による組成物で用いられる好ましい疎水性ノニオン性界面活性剤は、１ ６未満のＨＬＢを有して、式ＲＯ‐（Ｃ2Ｈ4Ｏ）n（Ｃ3Ｈ6Ｏ）mＨで表される界 面活性剤であり、ここでＲはＣ6‐Ｃ22アルキル鎖またはＣ6‐Ｃ28アルキルベン ゼン鎖であり、ｎ＋ｍは０〜２０、ｎは０〜１５およびｍは０〜２０であり、好 ましくはｎ＋ｍは１〜１５、ｎおよびｍは０．５〜１５であり、更に好ましくは ｎ＋ｍは１〜１０、ｎおよびｍは０〜１０である。本発明で使用上好ましいＲ鎖 はＣ8‐Ｃ22アルキル鎖である。したがって、本発明で使用に適した疎水性ノニ オン性界面活性剤は、DubanolR９１‐２．５（ＨＬＢ＝８．１；ＲはＣ9および Ｃ11アルキル鎖の混合であり、ｎは２．５およびｍは０である）、LutensolRＴ Ｏ３（ＨＬＢ＝８；ＲはＣ13アルキル鎖であり、ｎは３およびｍは０である）、 LutensolRＡＯ３（ＨＬＢ＝８；ＲはＣ13およびＲ15アルキル鎖の混合であり、 ｎは３およびｍは０である）、TergitolR２５Ｌ３（ＨＬＢ＝７．７；ＲはＣ12 ‐Ｒ15アルキル鎖長の範囲であり、ｎは３およびｍは０である）、DobanolR２３ ‐３（ＨＬＢ＝８．１；ＲはＣ12およびＣ13アルキル鎖の混合であり、ｎは３お よびｍは０である）、DobanolR２３‐２（ＨＬＢ＝６．２；ＲはＣ12およびＣ13 アルキル鎖の混合であり、ｎは２およびｍは０である）、DobanolR４５‐７（Ｈ ＬＢ＝１１．６；ＲはＣ14およびＲ15アルキル鎖の混合であり、ｎは７およびｍ は０である）、DobanolR２３‐６．５（ＨＬＢ＝１１．９；ＲはＣ12およびＣ13 アルキル鎖の混合であり、ｎは６．５およびｍは０である）、DobanolR２５‐７ （ＨＬＢ＝１２；ＲはＣ12およびＣ15アルキル鎖の混合であり、ｎは７およびｍ は０である）、DobanolR９１‐５（ＨＬＢ＝１１．６；ＲはＣ9およびＣ11アル キル鎖の混合であり、ｎは５およびｍは０である）、DobanolR９１‐６（ＨＬＢ ＝１２．５；ＲはＣ9およびＣ11アルキル鎖の混合であり、ｎは６および ｍは０である）、DobanolR９１‐８（ＨＬＢ＝１３．７；ＲはＣ9およびＣ11ア ルキル鎖の混合であり、ｎは８およびｍは０である）、DobanolR９１‐１０（Ｈ ＬＢ＝１４．２；ＲはＣ9‐Ｃ11アルキル鎖の混合であり、ｎは１０およびｍは ０である）またはそれらの混合物である。本発明で好ましいのは、DobanolR９１ ‐２．５、LutensolRＴＯ３、LutensolRＡＯ３、TergitolR２５Ｌ３、DobanolR ２３‐３、DobanolR２３‐２またはそれらの混合物である。これらのDobanolR界 面活性剤はSHELLから市販されている。これらのLutensolR界面活性剤はＢＡＳＦ から市販され、これらのTergitolR界面活性剤はUNIONCARBIDEから市販されてい る。 他の適切な界面活性剤には、Ｃ6‐Ｃ20慣用的石鹸（Ｃ6‐Ｃ20脂肪酸のアルカ リ金属塩、好ましくはナトリウム塩）も含む。 本発明による組成物は、好ましい任意成分として、本発明の組成物の抗菌活性 に寄与する抗菌成分を更に含んでいてもよい。このような抗菌成分には、エチル パラベン、プロピルパラベン、メチルパラベン、グルタルアルデヒドまたはそれ らの混合物のようなパラベンがある。 本組成物は、好ましい任意成分としてキレート化剤を更に含んでいてもよい。 適切なキレート化剤は、ホスホネートキレート化剤、アミノホスホネートキレー ト化剤、置換ヘテロ芳香族キレート化剤、アミノカルボキシレートキレート化剤 、他のカルボキシレートキレート化剤、多官能性置換芳香族キレート化剤、生分 解性キレート化剤、例えばエチレンジアミンＮ，Ｎ’‐二コハク酸またはそれら の混合物からなる群より選択されるような、当業者に知られるいずれの物質であ ってもよい。 本発明で用いられる適切なホスホネートキレート化剤には、エチドロン酸（１ ‐ヒドロキシエチレンジホスホン酸（ＨＥＤＰ））および／またはアルカリ金属 エタン１‐ヒドロキシジホスホネートがある。 本発明で用いられる適切なアミノホスホネートキレート化剤には、アミノアル キレンポリ（アルキレンホスホネート）、ニトリロトリス（メチレン）トリホス ホネート、エチレンジアミンテトラメチレンホスホネートおよび／またはジエチ レントリアミンペンタメチレンホスホネートがある。本発明で用いられる好まし いアミノホスホネートキレート化剤は、ジエチレントリアミンペンタメチレンホ スホネートである。 これらのホスホネート／アミノホスホネートキレート化剤は、それらの酸形で も、あるいはそれら酸官能基の一部または全部で異なるカチオンの塩として存在 してもよい。このようなホスホネート／アミノホスホネートキレート化剤は、商 本発明で用いられる適切な置換ヘテロ芳香族キレート化剤には、ヒドロキシピ リジン‐Ｎ‐オキシドまたはその誘導体がある。 本発明に従い用いられる適切なヒドロキシピリジン‐Ｎ‐オキシドおよびその 誘導体は、下記式による： 上記式中Ｘは窒素であり、Ｙは下記基酸素、‐ＣＨＯ、‐ＯＨ、‐（ＣＨ2）n‐ ＣＯＯＨ（ｎは０〜２０、好ましくは０〜１０の整数であり、更に好ましくは０ である）のうち１つであり、Ｙは好ましくは酸素である。したがって、本発明で 用いられる特に好ましいヒドロキシピリジン‐Ｎ‐オキシドおよびその誘導体は ２‐ヒドロキシピリジン‐Ｎ‐オキシドである。 ヒドロキシピリジン‐Ｎ‐オキシドおよびその誘導体はSigmaから市販されて いる。 多官能性置換芳香族キレート化剤も本組成物で有用である。１９７４年５月２ １日付で発行されたConnorらのＵＳ特許第３，８１２，０４４号明細書参照。酸 形でこのタイプの好ましい化合物は、１，２‐ジヒドロキシ‐３，５‐ジスルホ ベンゼンのようなジヒドロキシジスルホベンゼンである。 本発明で使用上好ましい生分解性キレート化剤は、エチレンジアミンＮ，Ｎ’ ‐二コハク酸、そのアルカリ金属、アルカリ土類、アンモニウムまたは置換アン モニウム塩、またはそれらの混合物である。エチレンジアミンＮ，Ｎ’‐二コハ ク酸、特に（Ｓ，Ｓ）異性体は、HartmanおよびPerkinsの１９８７年11月３日付 ＵＳ特許第４，７０４，２３３号明細書に詳しく記載されている。エチレンジア ミンＮ，Ｎ’‐二コハク酸は、例えばPalmer Research Laboratoriesから商 が、本発明の組成物に用いる上で特に適している。 本発明で有用な適切なアミノカルボキシレートキレート化剤には、エチレンジ アミン四酢酸、ジエチレントリアミン五酢酸、ジエチレントリアミンペント酢酸 （ＤＴＰＡ）、Ｎ‐ヒドロキシエチルエチレンジアミン三酢酸、ニトリロ三酢酸 、エチレンジアミン四プロピオン酸、トリエチレンテトラアミン六酢酸、エタノ ールジグリシン、プロピレンジアミン四酢酸（ＰＤＴＡ）およびメチルグリシン 二酢酸（ＭＧＤＡ）があり、それらの酸形と、あるいはそれらのアルカリ金属、 アンモニウムおよび置換アンモニウム塩形の双方を含む。本発明で用いる上で特 に適したのは、ジエチレントリアミン五酢酸（ＤＴＰＡ）、例えば商品名Trilon およびメチルグリシン二酢酸（ＭＧＤＡ）である。 本発明で用いられる別なカルボキシレートキレート化剤には、マロン酸、サリ チル酸、グリシン、アスパラギン酸、グルタミン酸またはそれらの混合物がある 。 上記キレート化剤、特にジエチレントリアミンペンタメチレンホスホネートの ようなホスホネートキレート化剤は、それらが過酸化水素の消毒性に更に寄与す ることがわかったため、本発明による組成物で特に好ましい。このため、本発明 のもう１つの面は、グラム陰性および／またはグラム陽性菌に対する上記組成物 の消毒性を改善する上で、過酸化水素を含む消毒組成物における、キレート化剤 、特にジエチレントリアミンペンタメチレンホスホネートのようなホスホネート キレート化剤の使用である。 典型的には、本発明による組成物は、全組成物の５重量％以内、好ましくは０ ．００２〜３重量％、更に好ましくは０．００２〜１．５％のキレート化剤また はその混合物を含んでいる。 本組成物は、好ましい任意成分として、ラジカルスカベンジャーを含んでいて もよい。本発明で使用に適したラジカルスカベンジャーには、周知の置換モノお よびジヒドロキシベンゼンとそれらの誘導体、アルキル‐およびアリールカルボ キシレート、およびそれらの混合物がある。本発明で使用上好ましいラジカルス カベンジャーには、ジ‐tert‐ブチルヒドロキシトルエン（ＢＨＴ）、ｐ‐ヒド ロキシトルエン、ヒドロキノン（ＨＱ）、ジ‐tert‐ブチルヒドロキノン（ＤＴ ＢＨＱ）、モノ‐tert‐ブチルヒドロキノン（ＭＴＢＨＱ）、tert‐ブチルヒド ロキシアニソール（ＢＨＡ）、ｐ‐ヒドロキシアニソール、安息香酸、２，５‐ ジヒドロキシ安息香酸、２，５‐ジヒドロキシテレフタル酸、トルイル酸、カテ コール、ｔ‐ブチルカテコール、４‐アリルカテコール、４‐アセチルカテコー ル、２‐メトキシフェノール、２‐エトキシフェノール、２‐メトキシ‐４‐（ ２‐プロペニル）フェノール、３，４‐ジヒドロキシベンズアルデヒド、２，３ ‐ジヒドロキシベンズアルデヒド、ベンジルアミン、１，１，３‐トリス（２‐ メチル‐４‐ヒドロキシ‐５‐ｔ‐ブチルフェニル）ブタン、tert‐ブチルヒ ドロキシアニリン、ｐ‐ヒドロキシアニリンと没食子酸ｎ‐プロピルがある。本 ているジ‐tert‐ブチルヒドロキシトルエン、および／またはtert‐ブチルヒド ロキシアニソールである。これらのラジカルスカベンジャーは、過酸化水素含有 組成物の安定性に更に寄与する。 典型的には、本発明による組成物は、全組成物の５重量％以内、好ましくは０ ．００１〜１．５重量％、更に好ましくは０．０１〜１％のラジカルスカベンジ ャーまたはその混合物を含んでいる。 本組成物は、好ましい任意成分として、溶媒またはその混合物を含んでいても よい。用いられるとき、溶媒は有利には本組成物に高いクリーニング性を与える 。本発明による組成物で配合に適した溶媒には、プロピレングリコール誘導体、 例えばｎ‐ブトキシプロパノール、またはｎ‐ブトキシプロポキシプロパノール 、溶媒は２‐（２‐アルコキシエトキシ）エタノールクラスの化合物であり、ここ でアルコキシ基はエチル、プロピルまたはブチルから誘導される。好ましい水溶 性カルビトールは、ブチルカルビトールとしても知られる２‐（２‐ブトキシエ エタノールクラスの化合物であり、２‐ブトキシエトキシエタノールが好ましい 。他の適切な溶媒は、ベンジルアルコール、メタノール、エタノール、イソプロ ピルアルコールおよびジオール類、例えば２‐エチル‐１，３‐ヘキサンジオー ルおよび２，２，４‐トリメチル‐１，３‐ペンタンジオールと、それらの混合 物である。本発明で使用上好ましい溶媒は、ｎ‐ブトキシプロポキシプロパノー ル、 である。 溶媒は、典型的には、組成物の１５重量％以内、好ましくは２〜７重量％のレ ベルで、本発明の組成物内に存在している。 本組成物は、緩衝剤（例えば、ホウ酸緩衝剤）、結合剤、安定剤、ブリーチア クチベーター、汚れ懸濁剤、転染剤、増白剤、香料、飛散防止剤、酵素、分散剤 、染料移動阻止剤、顔料、香料および染料のような、様々な他の任意成分を更に 含んでいてもよい。組成物のパッケージング形態： 本組成物は当業者に知られる様々な適切な洗剤パッケージに詰められる。本液 体組成物は、合成有機ポリマープラスチック物質から通常作られる、手動式スプ レー分配容器に詰めることが望ましい。したがって、本発明は、スプレーディス ペンサー、好ましくはトリガースプレーディスペンサーまたはポンプスプレーデ ィスペンサー中に詰められた、過酸化水素および抗菌精油を含んだ液体消毒組成 物にも関する。 確かに、上記スプレータイプディスペンサーは、本発明に従い用いる上で適し た液体消毒組成物を消毒させる表面の比較的大きな面積に均一に適用して、上記 組成物の消毒性に寄与することができる。このようなスプレータイプディスペン サーは垂直表面を消毒する上で特に適している。 本発明に従い用いる上で適したスプレータイプディスペンサーには、例えばSp ecialty Packaging Products,Inc．またはContinental Sprayers,Inc．により販 売されている手動式フォームトリガータイプディスペンサーがある。これらタイ プのディスペンサーは、例えばDurminingらのＵＳ４，７０１，３１１と双方と もFocarracciのＵＳ４，６４６，９７３およびＵＳ４，５３８，７４５に開示さ れている。本発明で使用上特に好ましいのは、Continental Spray イプディスペンサーである。このようなディスペンサーでは、液体組成物は細か な液滴に分散されて、処理される表面上に適用されるスプレーとなる。確かに、 このようなスプレータイプディスペンサーにおいて、そのディスペンサーのボデ ィに含有された組成物は、ユーザーがポンプメカニズムを作動すると、ユーザー によりポンプメカニズムに伝えられたエネルギーによりスプレータイプディスペ ンサーヘッドに向けられる。更に詳しくは、上記スプレータイプディスペンサー ヘッドにおいて、組成物は障害物、例えばグリッドまたはコーンなどに押しやら れて、それにより液体組成物を噴霧するのに役立つ、即ち液滴の形成に役立つシ ョックを与えている。 本発明の組成物はふきとり用品の形態で実施してもよい。“ふきとり用品”と は、本発明による液体組成物で含浸された使い捨てタオルを意味する。したがっ て、本発明は本発明による液体組成物で含浸されたふきとり用品、例えば使い捨 てペーパータオルにも関する。好ましい実施上、上記ふきとり用品は上記液体組 成物で湿潤される。好ましくは、上記ふきとり用品はプラスチックボックスに詰 められる。この実施の利点はユーザーによる消毒組成物のすばやい使用であり、 これは屋外でもそうであり、即ち処理／消毒される表面上に本発明による液体組 成物を注いで、それをクロスで拭いて乾かす必要がないのである。換言すれば、 ふきとり用品はワンステップで表面の消毒を行えるのである。消毒方法： 本発明には、本発明による組成物が表面上に適用される、表面を消毒するため の方法も包含している。 “表面”とは、ヒト皮膚、口、歯のような生物表面と無生物表面を含めたあら ゆる表面を意味する。無生物表面には、キッチン、浴室のような屋内、またはカ ーインテリアで典型的にみられる硬質表面、例えばタイル、壁、フロア、クロム 、ガラス、滑らかなビニール、いずれかのプラスチック、可塑化木材、テーブル ト ップ、シンク、クッカートップ、皿、衛生器具、例えばシンク、シャワー、シャ ワーカーテン、洗面台、ＷＣなどと、衣類、カーテン、ドレープ、ベッドリネン 、バスリネン、テーブルクロス、寝袋、テント、装飾家具などを含めた布帛、お よびカーペットがあるが、それらに限定されない。無生物表面には、冷蔵庫、フ リーザー、洗濯機、自動乾燥機、オーブン、電子レンジ、皿洗機などを含めた家 庭電化製品も含むが、それらに限定されない。 本発明に従い表面を消毒する方法において、上記組成物はそのままの形でまた はその希釈形で消毒される表面に適用される。 “希釈形”とは、本消毒方法で用いられる液体または固形いずれかの組成物が 、典型的にはそれらの重量の１００倍以内の水、好ましくはそれらの重量の８０ 〜３０倍の水、更に好ましくは６０〜４０倍の水でユーザーにより希釈されるこ とを意味する。 上記組成物がその希釈形で消毒される硬質表面に適用される本発明の方法の好 ましい態様において、組成物が適用された後に表面をすすぐ必要性はなく、確か に目に見える残留物は表面上に残らない。 本発明は下記例により更に例示される。例 下記組成物は掲載された割合（他で指摘されないかぎり重量％）で掲載された 成分をミックスすることにより作った。これらの組成物はEuropean committee o f standardisationのprEN 1040試験に合格した。これらの組成物は、そのままで 用いたとき、または例えば１：１００、１：２５、１：５０希釈レベルで希釈さ れたとき、清潔な表面上で優れた消毒を行い、しかも優れた表面安全性および皮 膚マイルド性を発揮する。 DETAILED DESCRIPTION OF THE INVENTION Disinfection composition and surface disinfection method Technical field The present invention relates to biological surfaces (eg, human skin, mouth, etc.) including, but not limited to, walls, Hard tables such as tiles, table tops, glass, bathroom surfaces, kitchen surfaces, dishes Various surfaces, including surfaces and inanimate surfaces including fabrics, clothing, carpets, etc. An antimicrobial composition that can be used for disinfection and cleaning. background The antimicrobial / antimicrobial composition contains a substance capable of disinfecting. Disinfectant The quality significantly reduces or eliminates microorganisms present on the surface, such as bacteria. Is generally recognized. For example, ha containing such as hypochlorous acid Compositions based on logenic or quaternary compounds are known in the art for disinfection purposes. Widely described in the world. Compositions containing peracids are also known as disinfecting compositions . However, disadvantages associated with such disinfecting compositions based on peracids are that. They may damage surfaces that have been brought into contact for disinfection. Is Rukoto. Certainly, such disinfecting compositions based on peracids are hard surfaces. Face and fabric, especially including delicate fabrics such as silk, wool, etc. Consumers believe that the surface is not safe for a particular surface. Accordingly, it is an object of the present invention to provide a treated surface with improved safety. Therefore, even when used under high dilution conditions, the disinfection performance imparted to the surface is not impaired. It is to provide such a disinfecting composition. The aim was to provide 0.1-15% by weight of the total composition of hydrogen peroxide and antimicrobial essential oils. Or by providing a composition comprising the mixture. . More specifically, the composition of the present invention comprising hydrogen peroxide and the essential antimicrobial oil described above Even at high dilution levels, i.e. 1: while exhibiting improved safety on the treated surface Clean surfaces, ie organic and / or organic, up to a dilution level of 100 (composition: water) It has been found that excellent disinfection also occurs on surfaces free of inorganic stains. Accordingly, compositions according to the present invention may be used for biological surfaces (eg, oral products or When used as a toothpaste, it includes human skin and / or mouth) and inanimate surfaces. Suitable for disinfecting all types of surfaces. Indeed, this technology For hard surfaces and for washing, for example the so-called "soaking mode" ), Laundry detergent in "through the wash mode" Or as a laundry additive, or as a pre-laundry in the “pre-treatment mode” Suitable for. More particularly, the composition according to the invention is used for food and / or baby Suitable for safe use on delicate surfaces, including surfaces that come into contact with. Sure When the composition according to the invention is used under dilute conditions, on the surface disinfected therewith The amount of chemical residue left behind is reduced. Therefore, the composition of the present invention may be used under dilution conditions. It may not be necessary, for example, to rinse hard surfaces after being applied. The advantage of the present invention is that a wide range of pure bacterial strains, including Gram-positive and Gram-negative strains And better sterilization with more resistant microorganisms such as fungi. Another advantage of the compositions of the present invention is that, in addition to the disinfection imparted, good cleaning The invention also relates to the invention in which the composition further comprises a surfactant and / or a solvent. Can be performed in the following manner. Yet another advantage of the compositions of the present invention is that they can be used in different forms, such as conventional Liquid form in traditional detergent bottle, spray / foam dispenser In the form of a spray or foam in which the composition is incorporated. In the form of a wipe or in a non-liquid form (eg, gel, paste or (Solid). Representatives of the prior art include organic acids, peroxidic acids, together with quaternary ammonium salts and essential oils. Liquid disinfection kit containing a compound selected from the group of borate, peracid and their salts Disclosed are products, for example WO 88/00795. Hydrogen peroxide , Its level, of course, is not disclosed in its disinfecting composition. In EP-B-288689, an antimicrobial effective amount of pine oil and at least one oil-soluble A liquid for a hard surface containing an organic acid is disclosed. Hydrogen peroxide disclosed Not. US 5,403,587 for sanitizing, sanitizing and cleaning hard surfaces Discloses an aqueous antimicrobial composition that can be used for: For more details, see US 5,403, 587 is a precision antibacterial agent such as thyme oil, eucalyptus oil, clove oil, etc. Oil (0.02-5%) and an aqueous solution or dispersion of the essential oil in a water carrier An aqueous composition (pH 1 to 12) containing a dissolving or dispersing agent sufficient for forming It is disclosed about. Hydrogen peroxide is not disclosed. Summary of the Invention The present invention relates to the use of 0.1 to 15% by weight of the total composition of hydrogen peroxide and an antimicrobial essential oil or Relates to a disinfecting composition comprising the mixture. The present invention relates to a method for disinfecting a surface, wherein the disinfecting composition according to the invention is applied on the surface. The method is also related. Detailed description of the invention Disinfection composition: The disinfecting composition according to the invention comprises 0.1 to 15% by weight of the total composition of hydrogen peroxide, Contains essential antimicrobial oils. The disinfecting composition according to the present invention may be in liquid or non-liquid form (eg, gel, paste). Or solid), such as powder or granule form). Composition If formulated as a solid, they may be mixed with a suitable solvent, typically water, before use. Will be mixed. The liquid composition can be an aqueous composition or a non-aqueous composition. liquid Body compositions are preferred for convenience of use. As an essential element, the composition according to the invention comprises hydrogen peroxide. The presence of hydrogen peroxide in the composition of the invention contributes to the disinfection of the composition It is thought that there is. Indeed, hydrogen peroxide attacks the life-supporting functions of microbial cells, For example, it prevents assembly of ribosome units in the cytoplasm of microbial cells I do. In addition, hydrogen peroxide is a hydroxyl free attack on proteins and nucleic acids. -A strong oxidizing agent that generates radicals. In addition, the presence of hydrogen peroxide is And is particularly noticeable in laundry and hard surface applications, for example. The composition may comprise from 0.1 to 15% by weight of the total composition, preferably from 0.5 to 10%, Preferably contains 1 to 8% hydrogen peroxide. As a second essential ingredient, the composition according to the invention comprises an antimicrobial essential oil or a mixture thereof. In. Typically, the composition will comprise at least 0.003% by weight of the total composition, preferably 0.006 to 10%, more preferably 0.2 to 4%, most preferably 0.2 to 4%. 2% of the antimicrobial essential oil or mixtures thereof. Suitable antimicrobial essential oils for use in the present compositions are those that exhibit antimicrobial activity. Antibacterial above Essential oils are believed to act as protein denaturants. The above antibacterial oil is Contributes to the safety aspects of the compositions of the present invention when used to disinfect Above anti Another advantage of the fungal essential oils is that they provide the antiseptic compositions of the present invention without the need to add perfume. It is to give a comfortable smell. Certainly, the disinfecting composition according to the present invention It is not only safe, but also has good disinfection, Also gives a scent. Suitable antimicrobial essential oils used in the present invention include thyme, lemongrass, citrus, Lemon, orange, anise, clove, aniseed, cinnamon, geranium, b , Mint, peppermint, lavender, citronella, eucalyptus, peppermint , Camphor, sandalwood, cedar, rosemary, pine, barbain (verv ain), freegrass (fleagrass), lemongrass, ratania (ratanhiae) And oils obtained from mixtures thereof, but are not limited thereto. In the present invention Particularly preferred for use are eucalyptus oil, thyme oil, clove oil, and cinnamon oil. , Geranium oil, eucalyptus oil, peppermint oil, mint oil and their mixtures It is. 0.1 to 15% by weight of hydrogen peroxide and the above antibacterial essential oil or a mixture thereof. The composition of the present invention is similar to a similar composition using a peracid in place of the above hydrogen peroxide. In comparison, improved on surfaces, for example hard surfaces, and on fabrics such as silk, wool, etc. Demonstrated safety and clean surface even when used under high dilution conditions It was found that it exhibited excellent disinfection performance. An advantage with the present invention is that when the above composition is used to disinfect a colored fabric, -Reduced damage and superior to the above fabric even when used under highly diluted conditions Demonstrating the disinfection performance. Certainly, hydrogen peroxide and the above antibacterial essential oil or it Observed when treating colored fabrics with the composition according to the invention comprising these mixtures Discoloration and / or bleaching is the same except that a peracid is used instead of hydrogen peroxide. Less than the discoloration and / or bleaching observed when using similar compositions Demonstrates excellent disinfection performance with the above fabric even when used under highly diluted conditions I do. Surface safety can be measured by measuring the tensile strength of Evaluated above. The tensile strength of a fabric is measured using a tensile strength method. This way Measures the tensile strength of a given fabric by stretching it until it breaks It consists of doing. The force required to break the fabric, expressed in Kg, is Force ", measured on a" stress-strain Instron machine ". Good disinfection results in clean surfaces, i.e., organic, even when used under highly diluted conditions. And / or Staphylococcus present on a surface substantially free of inorganic soils. Gram positive bacteria like aureus and gram shade like Pseudomonas aeroginosa The present invention is applied to various microorganisms including fungi and fungi such as Candida albicans. Is obtained. Disinfection of a composition is measured by the bactericidal activity of the composition. Pair on a clean surface A suitable test method for assessing the fungicidal activity of an adult is the European committee for stadium. European standa issued by ndardisation, Brussels on November 1995 rd, prEN 1040, CEN / TC 216 N 78. European standard, prEN 104 0, CEN / TC 216 N 78 specifies test methods and requirements for minimum bactericidal activity of disinfecting compositions. It has been described. 10 bacterial colony forming units (cfu)7cfu (initial level) From 10TwoIf reduced to cfu (final level after contact with disinfecting product) pass the test Case, ie 10 survivingFiveReduction is needed. The composition according to the invention has a high degree of It passes this test under clean conditions, even when used under dilute conditions. Another test method suitable for evaluating the bactericidal activity of the composition on a clean surface In a preferred embodiment, the composition according to the invention is an aqueous liquid cleaning composition is there. The aqueous composition is preferably 12.0 or less, more preferably 2 to 6, most preferably Also preferably have a pH of 3-5. The pH of the composition is citric acid, succinic acid, vinegar Organic or inorganic acids, such as acids, aspartic acid, lactic acid, or alkali It can be adjusted using an agent. The compositions of the present invention may be nonionic, anionic, cationic, amphoteric and / or May further comprise surfactants known to those skilled in the art, including zwitterionic surfactants. Good. The above surfactants contribute to the cleaning performance of the composition. Desirable. Typically, the composition according to the invention is present in an amount of up to 50% by weight of the total composition, preferably 0.01 to 30%, more preferably 0.1 to 25% of a surfactant or a mixture thereof Contains things. Thus, the composition of the present invention preferably comprises an amphoteric surfactant or a mixture thereof. Contains. Suitable amphoteric surfactants used in the present invention include betaine and There are sulfobetaine surfactants, their derivatives or mixtures thereof. Above Tine or sulfobetaine surfactants contribute to the disinfection of the composition. Therefore, it is preferable in the present invention. Indeed, they increase the permeability of bacterial cell walls This helps disinfect and allows other active ingredients to enter the cells. Furthermore, the mild action profile of the above betaine or sulfobetaine surfactants Because of this, the compositions containing them are suitable for delicate surfaces such as food and Cleaning delicate laundry or hard surfaces that come in contact with the baby and / or baby Especially suitable for Betaine and sulfobetaine surfactants are used on the skin and / or Or very mild to other surfaces to be treated. Suitable betaine and sulfobetaine surfactants used in compositions of the invention Has a wide range of pH values, with both basic and acidic groups in which the molecule forms inner salts. Provides both cationic and anionic hydrophilic groups to the molecule for / Sulfobetaine and betaine-like detergents. Some common examples of these detergents are U.S. Pat. Nos. 2,082,275, 2,2, incorporated herein by reference. 702,279 and 2,255,082. Departure A clear and preferred betaine or sulfobetaine surfactant has the formula: Or a mixture thereof: In the above formula, R1 is 1 to 24, preferably 8 to 18, more preferably 12 to 14 carbon atoms. And R2 and R3 are 1 to 3 carbon atoms, preferably Has 1 carbon atom, and n is an integer of 1 to 10, preferably 1 to 6. And more preferably 1, Y is a group consisting of a carboxyl and a sulfonyl group. And the sum of the R1, R2 and R3 groups is from 14 to 24 carbon atoms. Examples of particularly suitable betaine surfactants include C12- such as coconut betaine. C18 alkyl dimethyl betaine and C10-C16 such as lauryl betaine There is alkyl dimethyl betaine. Other suitable amphoteric surfactants for use in the present invention include amine oxides or amine oxides. There is a mixture of Amine oxides contribute to the disinfection of the composition Therefore, it is preferable in the present invention. Indeed, they can destroy bacterial cell walls / membranes. Helps disinfect more, thus allowing other antimicrobial components to penetrate the cells, for example, inside the cells To attack. Suitable amine oxides for use in the present invention have the formula R1RTwoRThreeWith NO Where R1, RTwoAnd RThreeIs independently saturated having from 1 to 30 carbon atoms It is a straight or branched hydrocarbon chain. Suitable amineoxy used according to the invention Is the formula R1RTwoRThreeAmine oxide with NO, where R1Is 1 to 30 , Preferably 6-20, more preferably 6-14, most preferably 8-10 charcoal A hydrocarbon chain having an elemental atom,TwoAnd RThreeIs independently from 1 to 4 carbon atoms, Substituted or unsubstituted linear or branched hydrocarbons having preferably 1 to 3 carbon atoms A chain, and more preferably a methyl group. R1Is saturated straight chain or branched Hydrocarbon chains may be used. Preferred amine oxides for use in the present invention include, for example, natural blend C8- C10 amine oxide and C12-C16 amine oxide available from Hoechst. It is oxide. In a preferred embodiment of the present invention, wherein the composition is particularly suitable for disinfecting hard surfaces, The activator is typically preferably 2: 1 to 100: 1, more preferably 6: 1. ~ 100: 1, most preferably 10: 1 to 50: 1 amine oxide to betaine Or amine oxide and betaine or sulfobetaine in a weight ratio of sulfobetaine It is a surfactant system containing a surfactant. Book suitable for disinfecting hard surfaces The use of such a surfactant system in the composition has shown effective cleaning performance Shines on the cleaned surface, i.e. a clean surface treated with the composition The amount of film / streak remaining on the surface is minimal. The composition also preferably comprises an anionic surfactant or a mixture thereof. Good. Particularly suitable anionic surfactants for use in the present invention include those of the formula ROSOThree There is a water-soluble salt or acid of M, wherein R is preferably C6-Ctwenty fourHydrocarbyl , Preferably C8-C20Alkyl or hydroxyalkyl having an alkyl component , More preferably C8-C16Alkyl or hydroxyalkyl, wherein M is H or a cation, such as an alkali metal cation (eg, sodium, potassium) Ammonium, substituted ammonium (eg, methyl, lithium) Ru-, dimethyl- and trimethylammonium cations and tetramethylan Quaternary ammonium tick such as monium and dimethylpiperidinium cations Alkyl, such as on, ethylamine, diethylamine, triethylamine Quaternary ammonium cations and mixtures thereof). Other suitable anionic surfactants for use in the present invention include alkyl diphenyls. There are ruether sulfonate and alkyl carboxylate. Other anions Surfactants include salts of soaps (eg, sodium, potassium, ammonium and And substituted ammonium salts such as mono, di and triethanolamine salts) , C9-C20Linear alkyl benzene sulfonate, C8-Ctwenty twoPrimary or secondary alka Sulfonate, C8-Ctwenty fourOlefin sulphonates, for example British Patent Specification No. Alkaline earth metal citrates as described in US Pat. Sulfonated polycarboxylic acids produced by sulfonation of pyrolysis products, C8-CTwo Four Alkyl polyglycol ether sulfate (within 10 moles of ethylene oxide ), Alkyl ester sulfonates such as C14-C16Methyl este Rusulfonate, acyl glycerol sulfonate, fatty oleyl glycerol Sulfate, alkylphenol ethylene oxide ether sulfate, Raffin sulfonates, alkyl phosphates, isethionates such as acyl Isethionate, N-acyl taurate, alkyl succinamate and sulfo Succinates, monoesters of sulfosuccinates (especially saturated and unsaturated C12 -C18Monoesters), diesters of sulfosuccinates (especially saturated and unsaturated) Sum C6-C14Diester), acyl sarcosinate, alkyl polysaccharide sulfate For example, alkyl polyglucoside sulfate (nonionic non-sulfate Compounds are described below), branched primary alkyl sulfates, alkyl esters Liethoxycarboxylates, for example of the formula RO (CHTwoCHTwoO)kCHTwoCOO-M+ (R is C8-Ctwenty twoAlkyl, k is an integer from 0 to 10, and M is a soluble salt form Which is a synthetic cation). Rosin, hydrogenated rosin, present in tall oil Resin acids and hydrogenated resin acids or resin acids derived therefrom or derived therefrom. Hydrogenated resin acids are also suitable. An additional example is “Surface Active Agents and Deterg ents "(Vol.I & II, Schwartz, Perry & Berch). Novel surfactants are known from Laughlin et al., U.S. Pat. No. 3,929,678, column 23, line 58 to column 29, line 23 Is disclosed. Preferred anionic surfactants for use in the present composition are C8-C16Alkyls Rufonate, C8-C16Alkyl sulfate, C8-C16Alkyl alkoxyl Sulfate (for example, C8-C16Alkyl ethoxylated sulfate) and And mixtures thereof. Such anionic surfactants can be used to It has been found to contribute to the disinfection of disinfecting compositions containing hydrogen and / or antimicrobial essential oil Therefore, it is preferable in the present invention. For example, C8-C16Alkyl sulfates are fine Disrupts bacterial cell membranes, inhibits enzymatic activity, prevents cell trafficking, and / or It works by denaturing proteins. Certainly, anionic surfactants, especially To C8-C16Alkyl sulfonate, C8-C16Alkyl sulfate and / or Or C8-C16Improved consumption with the addition of alkyl alkoxylated sulfate Toxic performance is determined by the diversity of the surfactants against bacteria, for example in the compositions of the invention. It is presumed that it seems to be due to a different attack style. Thus, another aspect of the present invention is: Improves disinfection of the composition against Gram-negative and / or Gram-positive bacteria Above, in an antiseptic composition comprising hydrogen peroxide and / or antimicrobial essential oil, Surfactants, especially C8-C16Alkyl sulfonate, C8-C16Alkyl monkey Fate and / or C8-C16Use of alkyl alkoxylated sulfates It is. Nonionic surfactants suitable for use in the present invention have various fatty alcohol chain lengths. Fatty alcohol ethoxylates available in various degrees of ethoxylation and / or Or propoxylate. Indeed, such alkoxylated nonionic properties The HLB value of the surfactant depends on the chain length of the fatty alcohol, the nature of the alkoxylation and It is essentially dependent on the degree of alkoxylation. Some interfaces including nonionic systems Surfactant catalogs are available listing surfactants along with their respective HLB values . Particularly suitable for use in the present invention as a nonionic surfactant are less than 16, preferably Or less than 15, more preferably less than 14 HLB (hydrophilic-lipophilic balance) Is a hydrophobic nonionic surfactant having Their hydrophobic nonionic surfactant It was found that the agent exhibited good oil drainage. Preferred hydrophobic nonionic surfactants used in the composition according to the present invention are: Having an HLB of less than 6, the formula RO- (CTwoHFourO)n(CThreeH6O)mThe world represented by H A surfactant where R is C6-Ctwenty twoAlkyl chain or C6-C28Alkylben And n + m is 0 to 20, n is 0 to 15, and m is 0 to 20. Preferably, n + m is 1 to 15, n and m are 0.5 to 15, and more preferably n + m is 1 to 10, and n and m are 0 to 10. R chain preferred for use in the present invention Is C8-Ctwenty twoIs an alkyl chain. Therefore, a hydrophobic non-ionic suitable for use in the present invention. The on-active surfactant is DubanolR91-2.5 (HLB = 8.1; R is C9and C11A mixture of alkyl chains, where n is 2.5 and m is 0), LutensolRT O3 (HLB = 8; R is C13An alkyl chain, n is 3 and m is 0), LutensolRAO3 (HLB = 8; R is C13And R15A mixture of alkyl chains, n is 3 and m is 0), TergitolR25L3 (HLB = 7.7; R is C12 -R15Range of alkyl chain length, n is 3 and m is 0), DobanolR23 -3 (HLB = 8.1; R is C12And C13A mixture of alkyl chains, where n is 3 or And m are 0), DobanolR23-2 (HLB = 6.2; R is C12And C13 A mixture of alkyl chains, n is 2 and m is 0), DobanolR45-7 (H LB = 11.6; R is C14And R15A mixture of alkyl chains, where n is 7 and m Is 0), DobanolR23-6.5 (HLB = 11.9; R is C12And C13 A mixture of alkyl chains, n is 6.5 and m is 0), DobanolR25-7 (HLB = 12; R is C12And C15A mixture of alkyl chains, where n is 7 and m Is 0), DobanolR91-5 (HLB = 11.6; R is C9And C11Al A mixture of kill chains, n is 5 and m is 0), DobanolR91-6 (HLB = 12.5; R is C9And C11A mixture of alkyl chains, where n is 6 and m is 0), DobanolR91-8 (HLB = 13.7; R is C9And C11A A mixture of alkyl chains, n is 8 and m is 0), DobanolR91-10 (H LB = 14.2; R is C9-C11A mixture of alkyl chains, where n is 10 and m is 0) or a mixture thereof. Preferred in the present invention is DobanolR91 -2.5, LutensolRTO3, LutensolRAO3, TergitolR25L3, DobanolR 23-3, DobanolR23-2 or a mixture thereof. These DobanolRWorld Surfactants are commercially available from SHELL. These LutensolRSurfactant is BASF Commercially available from these TergitolRSurfactants are commercially available from UNIONCARBIDE You. Other suitable surfactants include C6-C20Conventional soap (C6-C20Fatty acid arca (Metal salts, preferably sodium salts). The composition according to the present invention comprises, as a preferred optional ingredient, the antimicrobial activity of the composition of the present invention May further contain an antimicrobial component contributing to the following. Such antimicrobial components include ethyl Paraben, propylparaben, methylparaben, glutaraldehyde or it There are parabens like their mixture. The composition may further include a chelating agent as a preferred optional ingredient. Suitable chelators are phosphonate chelators, aminophosphonate chelates Chelating agent, substituted heteroaromatic chelating agent, aminocarboxylate chelating agent , Other carboxylate chelators, polyfunctional substituted aromatic chelators, biomass Decomposable chelating agents such as ethylenediamine N, N'-disuccinic acid or Any substance known to those skilled in the art, such as being selected from the group consisting of mixtures of You may. Suitable phosphonate chelators for use in the present invention include etidronic acid (1 -Hydroxyethylene diphosphonic acid (HEDP)) and / or alkali metal There is ethane 1-hydroxydiphosphonate. Suitable aminophosphonate chelators used in the present invention include aminoal Quirene poly (alkylene phosphonate), nitrilotris (methylene) triphos Phonate, ethylenediaminetetramethylenephosphonate and / or diethyl There is lentriamine pentamethylene phosphonate. Preferred used in the present invention Aminophosphonate chelating agents are diethylenetriaminepentamethylene Shonate. These phosphonate / aminophosphonate chelators are available in their acid form Or salts of different cations in some or all of these acid functional groups May be. Such phosphonate / aminophosphonate chelators are commercially available Suitable substituted heteroaromatic chelators for use in the present invention include hydroxypropyl There is lysine-N-oxide or a derivative thereof. Suitable hydroxypyridine-N-oxides for use according to the invention and their The derivative is according to the formula: In the above formula, X is nitrogen, and Y is the following group oxygen, -CHO, -OH,-(CHTwo)n- COOH (n is an integer of 0 to 20, preferably 0 to 10, and more preferably 0 And Y is preferably oxygen. Therefore, in the present invention Particularly preferred hydroxypyridine-N-oxides and derivatives thereof used are 2-hydroxypyridine-N-oxide. Hydroxypyridine-N-oxide and its derivatives are commercially available from Sigma I have. Polyfunctionally substituted aromatic chelators are also useful in the present compositions. May 2, 1974 See U.S. Pat. No. 3,812,044 issued to Connor et al. acid Preferred compounds of this type in form are 1,2-dihydroxy-3,5-disulfo Dihydroxydisulfobenzene, such as benzene. A preferred biodegradable chelating agent for use in the present invention is ethylenediamine N, N '. -Disuccinic acid, its alkali metal, alkaline earth, ammonium or substituted amino Monium salts or mixtures thereof. Ethylenediamine N, N'-Nichoha Citric acid, especially the (S, S) isomer, was obtained from Hartman and Perkins on Nov. 3, 1987. It is described in detail in US Pat. No. 4,704,233. Ethylenedia Min N, N'-disuccinic acid is commercially available from, for example, Palmer Research Laboratories. Are particularly suitable for use in the compositions of the present invention. Suitable aminocarboxylate chelators useful in the present invention include ethylene di Amine tetraacetic acid, diethylenetriaminepentaacetic acid, diethylenetriaminepentoacetic acid (DTPA), N-hydroxyethylethylenediamine triacetic acid, nitrilotriacetic acid , Ethylenediaminetetrapropionic acid, triethylenetetraamine hexaacetic acid, ethanol Diglycine, propylenediaminetetraacetic acid (PDTA) and methylglycine There are diacetates (MGDA) and their acid forms, or their alkali metals, Includes both ammonium and substituted ammonium salt forms. Special features for use in the present invention Suitable for use are diethylenetriaminepentaacetic acid (DTPA), such as the trade name Trilon And methylglycine diacetate (MGDA). Other carboxylate chelating agents used in the present invention include malonic acid, There is formic acid, glycine, aspartic acid, glutamic acid or a mixture thereof . Of the above chelating agents, especially diethylenetriaminepentamethylenephosphonate Such phosphonate chelators may further contribute to the disinfection of hydrogen peroxide. Are particularly preferred in the compositions according to the invention. Therefore, the present invention Another aspect of the invention relates to the above composition against Gram-negative and / or Gram-positive bacteria Chelating agent in a disinfecting composition containing hydrogen peroxide for improving disinfection of Phosphonates, especially diethylene triamine pentamethylene phosphonate The use of chelating agents. Typically, the composition according to the present invention comprises no more than 5% by weight of the total composition, preferably 0%. . 002 to 3% by weight, more preferably 0.002 to 1.5% of a chelating agent or Contains the mixture. The composition comprises, as a preferred optional ingredient, a radical scavenger. Is also good. Radical scavengers suitable for use in the present invention include well-known substituted mono- and And dihydroxybenzenes and their derivatives, alkyl- and arylcarbo There are xylates, and mixtures thereof. Radicals preferred for use in the present invention Cavengers include di-tert-butylhydroxytoluene (BHT), p-hydrido Roxytoluene, hydroquinone (HQ), di-tert-butylhydroquinone (DT BHQ), mono-tert-butylhydroquinone (MTBHQ), tert-butylhydrido Roxyanisole (BHA), p-hydroxyanisole, benzoic acid, 2,5- Dihydroxybenzoic acid, 2,5-dihydroxyterephthalic acid, toluic acid, Chole, t-butyl catechol, 4-allyl catechol, 4-acetyl catechol 2-methoxyphenol, 2-ethoxyphenol, 2-methoxy-4- ( 2-propenyl) phenol, 3,4-dihydroxybenzaldehyde, 2,3 -Dihydroxybenzaldehyde, benzylamine, 1,1,3-tris (2- Methyl-4-hydroxy-5-tert-butylphenyl) butane, tert-butylamine There are droxyaniline, p-hydroxyaniline and n-propyl gallate. Book Di-tert-butyl hydroxytoluene and / or tert-butyl hydride Roxyanisole. These radical scavengers contain hydrogen peroxide It further contributes to the stability of the composition. Typically, the composition according to the present invention comprises no more than 5% by weight of the total composition, preferably 0%. . 001-1.5% by weight, more preferably 0.01-1% of radical scavenge Or mixtures thereof. The composition may contain a solvent or a mixture thereof as a preferred optional ingredient. Good. When used, the solvent advantageously gives the composition a high cleaning performance . Suitable solvents for formulation in the composition according to the invention include propylene glycol derivatives, For example, n-butoxypropanol, or n-butoxypropoxypropanol ,Solvents are 2- (2-alkoxyethoxy) ethanol class compounds, where Wherein the alkoxy group is derived from ethyl, propyl or butyl. Preferred water-soluble Sex carbitols are known as 2- (2-butoxyethyl), also known as butyl carbitol Ethanol class compound, 2-butoxyethoxyethanol is preferred . Other suitable solvents are benzyl alcohol, methanol, ethanol, Pill alcohols and diols such as 2-ethyl-1,3-hexanediol And 2,2,4-trimethyl-1,3-pentanediol and their mixtures Things. A preferred solvent for use in the present invention is n-butoxypropoxypropanol. Le It is. Solvents typically comprise up to 15% by weight of the composition, preferably 2 to 7% by weight. At the bell, it is present in the composition of the invention. The composition may comprise a buffer (eg, borate buffer), a binder, a stabilizer, a bleacher. Activator, stain suspending agent, dye transfer agent, brightener, fragrance, shatterproofing agent, enzyme, dispersant Various other optional ingredients, such as dye transfer inhibitors, pigments, fragrances and dyes. May be included.Packaging form of the composition: The composition is packaged in various suitable detergent packages known to those skilled in the art. Main solution Body compositions are hand-made spatters, usually made from synthetic organic polymer plastic materials. It is desirable to pack in a laye distribution container. Therefore, the present invention Dispenser, preferably trigger spray dispenser or pump spray dispenser Liquid disinfecting composition containing hydrogen peroxide and antibacterial essential oil packed in dispenser Related to things. Indeed, the above spray type dispensers are suitable for use in accordance with the present invention. The liquid disinfecting composition uniformly applied to a relatively large area of the surface to be disinfected, It can contribute to the disinfection of the composition. Such a spray type dispenser Sir is particularly suitable for disinfecting vertical surfaces. Spray type dispensers suitable for use in accordance with the present invention include, for example, Sp ecialty Packaging Products, Inc. Or Continental Sprayers, Inc. Sold by There are manual form trigger type dispensers that are sold. These thai The dispensers of the pumps are, for example, Durmining et al., US Pat. Are also disclosed in Focarracci US 4,646,973 and US 4,538,745. Have been. Particularly preferred for use in the present invention is Continental Spray Ip dispenser. In such dispensers, the liquid composition is finely divided. Are dispersed into fine droplets, resulting in a spray applied on the surface to be treated. surely, In such a spray type dispenser, the body of the dispenser is used. When the user activates the pump mechanism, the composition contained in the Spray type dispensing by the energy transmitted to the pump mechanism by Pointed at the sensor head. More specifically, the above spray type dispenser At the head, the composition is pushed to an obstacle, such as a grid or cone. To help spray the liquid composition, i.e., help to form droplets. Giving a shock. The composition of the invention may be implemented in the form of a wipe. “Wiping supplies” Means a disposable towel impregnated with the liquid composition according to the invention. Accordingly Thus, the present invention provides a wipe, such as a disposable, impregnated with the liquid composition according to the present invention. Also relates to paper towels. In a preferred embodiment, the wiping article comprises the liquid set Wet with composition. Preferably, the wipe is packed in a plastic box. Can be The advantage of this implementation is the quick use of the disinfecting composition by the user, This is also the case outdoors, i.e. the liquid set according to the invention on the surface to be treated / disinfected. There is no need to pour the product and wipe it dry with a cloth. In other words, The wipes can be disinfected on the surface in one step.Disinfection method: The present invention provides for disinfecting a surface, wherein the composition according to the invention is applied on the surface. Method is also included. “Surface” refers to any surface, including living and inanimate surfaces such as human skin, mouth, and teeth. Means loose surface. Inanimate surfaces may be indoors, such as kitchens, bathrooms, or -Hard surfaces typically found in interiors such as tiles, walls, floors, chrome , Glass, smooth vinyl, any plastic, plasticized wood, table G Cups, sinks, cooker tops, dishes, sanitary fixtures such as sinks, showers, Work curtain, wash basin, WC etc., clothing, curtain, drape, bed linen Fabrics, including bath linen, tablecloths, sleeping bags, tents, decorative furniture, etc. And carpets, but not limited to them. Refrigerators, Homes including risers, washing machines, automatic dryers, ovens, microwaves, dishwashers, etc. Also includes, but is not limited to, garden appliances. In a method of disinfecting a surface according to the present invention, the composition may be used as is or Is applied to the surface to be disinfected in its diluted form. "Diluted form" refers to the liquid or solid composition used in the disinfection method. , Typically within 100 times their weight in water, preferably 80% of their weight It can be diluted by the user with up to 30 times water, more preferably 60 to 40 times water. Means The method of the present invention wherein the composition is applied to a hard surface to be disinfected in its diluted form. In a preferred embodiment, there is no need to rinse the surface after the composition has been applied. No visible residue remains on the surface. The invention is further illustrated by the following examples.An example The following compositions were listed at the listed rates (% by weight unless otherwise indicated) Made by mixing the ingredients. These compositions are from the European committee o Passed the prEN 1040 test of f standardisation. These compositions, as they are When used or diluted eg at 1: 100, 1:25, 1:50 dilution levels Performs excellent disinfection on clean surfaces, and provides excellent surface safety and skin Demonstrate mildness.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ｃ１１Ｄ 3/39 Ｃ１１Ｄ 3/39 3/48 3/48 7/18 7/18 (81)指定国 ＥＰ(ＡＴ，ＢＥ，ＣＨ，ＤＥ， ＤＫ，ＥＳ，ＦＩ，ＦＲ，ＧＢ，ＧＲ，ＩＥ，ＩＴ，Ｌ Ｕ，ＭＣ，ＮＬ，ＰＴ，ＳＥ)，ＯＡ(ＢＦ，ＢＪ，ＣＦ ，ＣＧ，ＣＩ，ＣＭ，ＧＡ，ＧＮ，ＭＬ，ＭＲ，ＮＥ， ＳＮ，ＴＤ，ＴＧ)，ＡＰ(ＫＥ，ＬＳ，ＭＷ，ＳＤ，Ｓ Ｚ，ＵＧ)，ＥＡ(ＡＭ，ＡＺ，ＢＹ，ＫＧ，ＫＺ，ＭＤ ，ＲＵ，ＴＪ，ＴＭ)，ＡＬ，ＡＭ，ＡＴ，ＡＵ，ＡＺ ，ＢＡ，ＢＢ，ＢＧ，ＢＲ，ＢＹ，ＣＡ，ＣＨ，ＣＮ， ＣＵ，ＣＺ，ＤＥ，ＤＫ，ＥＥ，ＥＳ，ＦＩ，ＧＢ，Ｇ Ｅ，ＨＵ，ＩＬ，ＩＳ，ＪＰ，ＫＥ，ＫＧ，ＫＰ，ＫＲ ，ＫＺ，ＬＣ，ＬＫ，ＬＲ，ＬＳ，ＬＴ，ＬＵ，ＬＶ， ＭＤ，ＭＧ，ＭＫ，ＭＮ，ＭＷ，ＭＸ，ＮＯ，ＮＺ，Ｐ Ｌ，ＰＴ，ＲＯ，ＲＵ，ＳＤ，ＳＥ，ＳＧ，ＳＩ，ＳＫ ，ＴＪ，ＴＭ，ＴＲ，ＴＴ，ＵＡ，ＵＧ，ＵＳ，ＵＺ， ＶＮ (72)発明者 ジョバンニ、ミネルビーニ イタリー国ローマ、ビア、フランチェス コ、メンゴッティ、47 (72)発明者 マレーナ、デセット、ブラウン アメリカ合衆国オハイオ州、フェアーフィ ールド、ノース、ティンバー、ホロー、 1528──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) C11D 3/39 C11D 3/39 3/48 3/48 7/18 7/18 (81) Designated country EP ( AT, BE, CH, DE, DK, ES, FI, FR, GB, GR, IE, IT, LU, MC, NL, PT, SE), OA (BF, BJ, CF, CG, CI, CM, GA, GN, ML, MR, NE, SN, TD, TG), AP (KE, LS, MW, SD, SZ, UG), EA (AM, AZ, BY, KG, KZ, MD, RU, TJ) , TM), AL, AM, AT, AU, AZ, BA, BB, BG, BR, BY, CA, CH, CN, CU, CZ, DE, DK, EE, ES, FI, GB, GE, HU , IL, I S, JP, KE, KG, KP, KR, KZ, LC, LK, LR, LS, LT, LU, LV, MD, MG, MK, MN, MW, MX, NO, NZ, PL, PT, RO , RU, SD, SE, SG, SI, SK, TJ, TM, TR, TT, UA, UG, US, UZ, VN (72) Inventor Giovanni, Rome, Minervine Italy, Via, Francesco, Mengotti, 47 (72) Inventor Malena, Desset, Brown, Ohio, USA, Fairfield, North, Timber, Hollow, 1528
Claims (1)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP96870001.3 | 1996-01-12 | ||
| EP96870001A EP0784091A1 (en) | 1996-01-12 | 1996-01-12 | Stable perfumed bleaching composition |
| EP96870017 | 1996-02-23 | ||
| EP96870017.9 | 1996-02-23 | ||
| PCT/US1997/000214 WO1997025404A1 (en) | 1996-01-12 | 1997-01-08 | Disinfecting compositions and processes for disinfecting surfaces |
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| JP2004125841A Division JP2004285071A (en) | 1996-01-12 | 2004-04-21 | Disinfecting compositions and processes for disinfecting surfaces |
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| JP2002505658A true JP2002505658A (en) | 2002-02-19 |
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| JP52535197A Withdrawn JP2002505658A (en) | 1996-01-12 | 1997-01-08 | Disinfection composition and surface disinfection method |
| JP2004125841A Withdrawn JP2004285071A (en) | 1996-01-12 | 2004-04-21 | Disinfecting compositions and processes for disinfecting surfaces |
Family Applications After (1)
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|---|---|---|---|
| JP2004125841A Withdrawn JP2004285071A (en) | 1996-01-12 | 2004-04-21 | Disinfecting compositions and processes for disinfecting surfaces |
Country Status (15)
| Country | Link |
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| EP (1) | EP0904345A4 (en) |
| JP (2) | JP2002505658A (en) |
| KR (1) | KR100321526B1 (en) |
| CN (1) | CN1212723A (en) |
| AU (1) | AU1528997A (en) |
| BR (1) | BR9706949A (en) |
| CA (1) | CA2242411A1 (en) |
| CZ (1) | CZ216898A3 (en) |
| HU (1) | HUP9901053A3 (en) |
| IL (1) | IL125236A0 (en) |
| NZ (1) | NZ326663A (en) |
| PL (1) | PL327658A1 (en) |
| SK (1) | SK94598A3 (en) |
| TR (1) | TR199801320T2 (en) |
| WO (1) | WO1997025404A1 (en) |
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- 1997-01-08 NZ NZ326663A patent/NZ326663A/en unknown
- 1997-01-08 CZ CZ982168A patent/CZ216898A3/en unknown
- 1997-01-08 BR BR9706949A patent/BR9706949A/en not_active Application Discontinuation
- 1997-01-08 CN CN97192739A patent/CN1212723A/en active Pending
- 1997-01-08 KR KR1019980705325A patent/KR100321526B1/en not_active Expired - Fee Related
- 1997-01-08 TR TR1998/01320T patent/TR199801320T2/en unknown
- 1997-01-08 PL PL97327658A patent/PL327658A1/en unknown
- 1997-01-08 AU AU15289/97A patent/AU1528997A/en not_active Abandoned
- 1997-01-08 WO PCT/US1997/000214 patent/WO1997025404A1/en not_active Ceased
- 1997-01-08 JP JP52535197A patent/JP2002505658A/en not_active Withdrawn
- 1997-01-08 EP EP97901377A patent/EP0904345A4/en not_active Withdrawn
- 1997-01-08 CA CA002242411A patent/CA2242411A1/en not_active Abandoned
- 1997-01-08 HU HU9901053A patent/HUP9901053A3/en unknown
- 1997-01-08 IL IL12523697A patent/IL125236A0/en unknown
- 1997-01-08 SK SK945-98A patent/SK94598A3/en unknown
-
2004
- 2004-04-21 JP JP2004125841A patent/JP2004285071A/en not_active Withdrawn
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| JP2004204085A (en) * | 2002-12-26 | 2004-07-22 | Lion Corp | Detergent composition |
| JP2015500369A (en) * | 2011-12-12 | 2015-01-05 | コスメティック ウォリアーズ エルティーディーＣｏｓｍｅｔｉｃ Ｗａｒｒｉｏｒｓ Ｌｔｄ | Solid surfactant composition |
| US9845450B2 (en) | 2011-12-12 | 2017-12-19 | Cosmetic Warriors Limited | Solid surfactant composition |
| JP2019517900A (en) * | 2016-05-26 | 2019-06-27 | マークスベリー ブルー パール エルエルシーＭａｒｋｅｓｂｅｒｙ Ｂｌｕｅ Ｐｅａｒｌ Ｌｌｃ | Method and system for disinfecting |
| JP7202660B2 (en) | 2016-05-26 | 2023-01-12 | マークスベリー ブルー パール エルエルシー | Method and system for disinfection |
| US11679172B2 (en) | 2016-05-26 | 2023-06-20 | Markesbery Blue Pearl LLC | Methods and system for disinfection |
| US11425911B2 (en) | 2017-05-25 | 2022-08-30 | Markesbery Blue Pearl LLC | Method for disinfection of items and spaces |
| JP2021152136A (en) * | 2020-03-18 | 2021-09-30 | シーバイエス株式会社 | Sterilizing detergent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1997025404A1 (en) | 1997-07-17 |
| KR100321526B1 (en) | 2002-03-08 |
| IL125236A0 (en) | 1999-03-12 |
| PL327658A1 (en) | 1998-12-21 |
| HUP9901053A3 (en) | 2000-09-28 |
| AU1528997A (en) | 1997-08-01 |
| JP2004285071A (en) | 2004-10-14 |
| SK94598A3 (en) | 1999-04-13 |
| KR19990077184A (en) | 1999-10-25 |
| TR199801320T2 (en) | 1998-10-21 |
| EP0904345A4 (en) | 1999-07-07 |
| CA2242411A1 (en) | 1997-07-17 |
| NZ326663A (en) | 2000-03-27 |
| CZ216898A3 (en) | 1998-12-16 |
| EP0904345A1 (en) | 1999-03-31 |
| BR9706949A (en) | 1999-04-06 |
| HUP9901053A2 (en) | 1999-08-30 |
| CN1212723A (en) | 1999-03-31 |
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