JP2002272372A - Tea drink using marine deep water and method for producing the same - Google Patents
Tea drink using marine deep water and method for producing the sameInfo
- Publication number
- JP2002272372A JP2002272372A JP2001126714A JP2001126714A JP2002272372A JP 2002272372 A JP2002272372 A JP 2002272372A JP 2001126714 A JP2001126714 A JP 2001126714A JP 2001126714 A JP2001126714 A JP 2001126714A JP 2002272372 A JP2002272372 A JP 2002272372A
- Authority
- JP
- Japan
- Prior art keywords
- tea
- water
- deep water
- bottle
- producing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 59
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 239000003651 drinking water Substances 0.000 claims abstract description 13
- 235000020188 drinking water Nutrition 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 11
- 238000010790 dilution Methods 0.000 claims abstract description 10
- 239000012895 dilution Substances 0.000 claims abstract description 10
- 241001122767 Theaceae Species 0.000 claims abstract 8
- 235000013616 tea Nutrition 0.000 claims description 57
- 235000018553 tannin Nutrition 0.000 claims description 31
- 229920001864 tannin Polymers 0.000 claims description 31
- 239000001648 tannin Substances 0.000 claims description 31
- 239000013535 sea water Substances 0.000 claims description 20
- 235000013353 coffee beverage Nutrition 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims 1
- 235000019606 astringent taste Nutrition 0.000 abstract description 9
- 238000002156 mixing Methods 0.000 abstract description 8
- 230000008569 process Effects 0.000 abstract description 7
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 abstract description 4
- 238000000605 extraction Methods 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 abstract description 2
- 229930003268 Vitamin C Natural products 0.000 abstract description 2
- 239000000498 cooling water Substances 0.000 abstract description 2
- 238000011049 filling Methods 0.000 abstract description 2
- 238000002372 labelling Methods 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000000243 solution Substances 0.000 abstract description 2
- 235000019154 vitamin C Nutrition 0.000 abstract description 2
- 239000011718 vitamin C Substances 0.000 abstract description 2
- 238000005406 washing Methods 0.000 abstract description 2
- 238000007689 inspection Methods 0.000 abstract 2
- 238000003756 stirring Methods 0.000 abstract 2
- 238000009472 formulation Methods 0.000 abstract 1
- 238000010792 warming Methods 0.000 abstract 1
- 235000019640 taste Nutrition 0.000 description 28
- 244000269722 Thea sinensis Species 0.000 description 25
- 229910021645 metal ion Inorganic materials 0.000 description 13
- 229910052500 inorganic mineral Inorganic materials 0.000 description 11
- 239000011707 mineral Substances 0.000 description 11
- ADRVNXBAWSRFAJ-UHFFFAOYSA-N catechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3ccc(O)c(O)c3 ADRVNXBAWSRFAJ-UHFFFAOYSA-N 0.000 description 9
- 235000005487 catechin Nutrition 0.000 description 9
- 150000001765 catechin Chemical class 0.000 description 8
- 230000008859 change Effects 0.000 description 8
- 235000006468 Thea sinensis Nutrition 0.000 description 6
- 235000019658 bitter taste Nutrition 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 235000013824 polyphenols Nutrition 0.000 description 5
- 230000003078 antioxidant effect Effects 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 235000009569 green tea Nutrition 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 235000020279 black tea Nutrition 0.000 description 3
- 230000003749 cleanliness Effects 0.000 description 3
- 238000007865 diluting Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 235000020333 oolong tea Nutrition 0.000 description 3
- 150000008442 polyphenolic compounds Chemical class 0.000 description 3
- 238000001223 reverse osmosis Methods 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- 238000012795 verification Methods 0.000 description 3
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- 235000013361 beverage Nutrition 0.000 description 2
- 230000002328 demineralizing effect Effects 0.000 description 2
- 238000010612 desalination reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229930003935 flavonoid Natural products 0.000 description 2
- 235000017173 flavonoids Nutrition 0.000 description 2
- 150000002215 flavonoids Chemical class 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000008239 natural water Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- -1 polyphenol compounds Chemical class 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 description 1
- WMBWREPUVVBILR-WIYYLYMNSA-N (-)-Epigallocatechin-3-o-gallate Chemical compound O([C@@H]1CC2=C(O)C=C(C=C2O[C@@H]1C=1C=C(O)C(O)=C(O)C=1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 WMBWREPUVVBILR-WIYYLYMNSA-N 0.000 description 1
- LSHVYAFMTMFKBA-TZIWHRDSSA-N (-)-epicatechin-3-O-gallate Chemical compound O([C@@H]1CC2=C(O)C=C(C=C2O[C@@H]1C=1C=C(O)C(O)=CC=1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 LSHVYAFMTMFKBA-TZIWHRDSSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 235000019647 acidic taste Nutrition 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 229950001002 cianidanol Drugs 0.000 description 1
- 235000016213 coffee Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005115 demineralization Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011033 desalting Methods 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000005446 dissolved organic matter Substances 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 235000019600 saltiness Nutrition 0.000 description 1
- 235000019643 salty taste Nutrition 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910021655 trace metal ion Inorganic materials 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Tea And Coffee (AREA)
Abstract
Description
【産業上の利用分野】本発明は、緑茶、紅茶、烏龍茶等
の茶またはコーヒ飲料に関し、特に、マイルドな味を得
ることのできる茶飲料の製造方法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to tea or coffee beverages such as green tea, black tea, and oolong tea, and more particularly to a method for producing a tea beverage capable of obtaining a mild taste.
【従来の技術】一般に茶飲料の味覚成分(渋み成分)
は、主に、タンニン、フラボノイド、カテキンなどのポ
リフェノール化合物に由来すると言われている。ポリフ
ェノール化合物は、抗酸化作用を示す代表的な物質で、
活性酸素・フリーラジカルに分類されるスーパーオキサ
イドやヒドロキシルラジカルの消去物質として、生体内
で作用し、生活習慣病や老化、癌の予防に役立つと言わ
れている。緑茶の研究で、カテキン類はスーパーオキサ
イドやヒドロキシルラジカルを還元消去する過程で酸化
され、キノンラジカル中間体を生成した後、重合体(二
量体以上)を生成することが知られている。カテキン類
の重合反応により茶飲料の味覚成分(渋味)は変化する
ことになる。一方、自然水や天然水と呼ばれる地下水や
湧水でお茶を点てると美味しいとの伝承が、清浄性が高
く、自然環境のよい地域に数多く伝えられている。通
常、美味しいお茶を味わうことのできる水には、多くの
ミネラル成分が含まれているとも言われている。2. Description of the Related Art In general, taste components (astringency components) of tea beverages
Is said to be derived mainly from polyphenol compounds such as tannins, flavonoids and catechins. Polyphenol compounds are representative substances that exhibit antioxidant activity.
It is said to act in vivo as a superoxide and hydroxyl radical scavenger classified as active oxygen and free radicals, and to help prevent lifestyle-related diseases, aging, and cancer. In the study of green tea, it is known that catechins are oxidized in the process of reducing and elimination of superoxide and hydroxyl radicals, generate quinone radical intermediates, and then generate polymers (dimers or more). The taste component (astringency) of the tea beverage changes due to the polymerization reaction of the catechins. On the other hand, it is said that drinking tea from natural water or groundwater or spring water, which is called natural water, is delicious, and it has been reported to many areas with high cleanliness and good natural environment. It is generally said that water that can taste delicious tea contains many mineral components.
【発明が解決しようとする課題】しかしながら、どのよ
うなミネラルが、どのくらいの量あれば、美味しいお茶
を出すことができるのかなどについては、嗜好性が強く
経験的な捉え方が主であり、科学的な検証がされていな
かった。もし、味に関する科学的な検証が行なわれ、理
論が確立すれば、茶飲料をはじめ、各種の飲料を製造す
ることが可能となる。本発明は、上記の点に鑑みてなさ
れたものであり、マイルドで美味しい茶飲料の製造方法
を提供することを目的としている。[Problems to be Solved by the Invention] However, regarding what kind of minerals and how much minerals can be served in a delicious tea, etc., the taste is strong and the empirical approach is mainly used. Has not been verified. If the taste is scientifically verified and the theory is established, it will be possible to produce various beverages including tea beverages. The present invention has been made in view of the above points, and has as its object to provide a method for producing a mild and delicious tea beverage.
【作用】本発明者は、高知県室戸市で採取される深層海
水を使って、お茶やコーヒを出すと、通常の飲料水を使
用した場合とは味が変化し、味がマイルドで飲みやすく
なることを確認していた。しかし、何故味が変化させる
のか、どのような作用機構が関係しているのか、その理
由は何かなど、全く不明であった。深層水を使った場合
の茶飲料の味の変化の原因を突き止めることができれ
ば、深層水の新たな利用法に展望が開けることとなる、
茶飲料の味覚成分は茶ポリフェノール類であって、茶ポ
リフェノールが抗酸化反応することで味が変化する事が
知られている。また本発明者は、海洋深層水原水を利用
して茶を抽出すると茶カテキンの色変化が起こることを
確認し、色の変化の度合いが深層水の濃度に依存してい
ることも確認した。これらの事象から、ポリフェノール
類の構造変化と味の変化の関係を明らかできれば、茶飲
料の味覚に関係する科学的な検証の一助となると考え、
本発明者は、鋭意努力を重ねてきた。そして、本発明者
は、茶成分のカテキン類が示す抗酸化能の研究から、深
層水のもつ味覚成分に与える影響について、以下のよう
な知見を得た。すなわち、その内容は、1)深層水にふ
くまれる主要ミネラル(Na,K,Ca,Mg)が、お
茶における味の変化を引き起こす要因であることを突き
止めた。 さらに、2)清浄性の高い深層水原水を一定
の割合で希釈し用いることで、味がマイルドな茶飲料が
製造できることも発見した。美味しい茶飲料を製造する
方法として、3)深層水は原水を希釈して用いることが
好ましいが、逆浸透膜(RO)を利用して脱塩処理を施
した深層海水を利用することも可能である。逆浸透膜
(RO)を使い脱塩処理した深層海水は主要ミネラルが
原水に比べ0.1%から1.0%程度になっており、原
水との混合(配合率が重要)により、より特徴を持つ茶
飲料の製造が可能となることも分かった。緑茶、紅茶、
烏龍茶などの茶葉を、一定の条件(茶葉量と温度、時
間)で熱水抽出すると、溶出するタンニンが40−60
mg%含まれる茶飲料となる。茶飲料の味覚成分は、構
造の異なるタンニン化合物によって醸成される。本発明
者はこのタンニンと深層水に含まれているミネラル成分
との相互作用によって、味覚成分の変化が引き起こされ
ていることを発見し、実験および科学的な検証を行っ
た。その結果、タンニン量と深層水に含まれる特定のミ
ネラルイオンの量に相関関係が見出され、深層水を使っ
て味がマイルドな茶飲料の製造が可能であることが見出
された。[Function] The present inventor uses deep seawater collected in Muroto City, Kochi Prefecture to produce tea and coffee, and the taste changes from that of ordinary drinking water, and the taste is mild and easy to drink. Had been confirmed. However, it was completely unclear why taste changes, what mechanism of action is involved, and why. If we can identify the cause of the change in the taste of tea beverages when using deep water, we can open up new ways to use deep water.
The taste components of tea beverages are tea polyphenols, and it is known that the taste changes due to the antioxidant reaction of the tea polyphenol. In addition, the present inventor has confirmed that when tea is extracted using deep seawater raw water, the color change of tea catechin occurs, and that the degree of color change is dependent on the concentration of deep water. From these events, if we can clarify the relationship between the structural change of polyphenols and the change in taste, we believe that it will help scientific verification related to the taste of tea beverages,
The inventor has made intensive efforts. The present inventor has obtained the following knowledge on the effect of deep water on the taste component from the study of the antioxidant ability of catechins as a tea component. That is, the content was found to be 1) that the main minerals (Na, K, Ca, Mg) contained in the deep water are factors that cause a change in taste in tea. Furthermore, 2) it was also found that a tea beverage with a mild taste can be produced by diluting deep water raw water having high cleanliness at a certain ratio and using it. As a method for producing a delicious tea beverage, 3) it is preferable to use deep water by diluting raw water, but it is also possible to use deep seawater subjected to desalination treatment using a reverse osmosis membrane (RO). is there. Deep seawater desalinated using a reverse osmosis membrane (RO) contains 0.1% to 1.0% of the main minerals compared to the raw water, and is more distinctive when mixed with the raw water (the mixing ratio is important). It was also found that it was possible to produce tea beverages with Green tea, black tea,
When tea leaves such as oolong tea are extracted with hot water under certain conditions (amount of tea leaves, temperature and time), the tannin eluted is 40-60.
It becomes a tea beverage containing mg%. The taste component of a tea beverage is brewed by tannin compounds having different structures. The present inventor has discovered that the interaction between the tannin and the mineral component contained in the deep water causes a change in the taste component, and has conducted experiments and scientific verification. As a result, a correlation was found between the amount of tannin and the amount of specific mineral ions contained in the deep water, and it was found that a tea beverage with a mild taste can be produced using the deep water.
【発明の実施の形態】以下、本発明の一実施例を図面に
基づいて詳説する。飲料用水とは、水道法による水質基
準に適合した飲用適の水またはそれと同等の水を指して
おり、本実施例では、水道水,表層海水あるいは海洋深
層水に脱塩、脱ミネラル処理をして得た精製飲料用水を
用いる。このような脱塩、脱ミネラル処理は、例えば限
外ろ過膜、逆浸透膜、電気分解装置の3つを適宜組み合
わせた装置を用いて行うことができる。海洋深層水はス
トレーナで濾過したものを用意して、上記飲料用水とと
もに予め設定された配合割合に応じて調合タンクに入
れ、攪拌混合して希釈海洋深層水を得る。上記の海洋深
層水とは、海面下200メートル以上の深海から取水し
た清浄な海水である。図1は本発明を適用した茶飲料の
製造方法の工程例を示す流れ図であり、先ずステップ1
で例えば水道水を用意し、ステップ2において濾過、脱
塩、脱ミネラル処理等により精製飲料用水を得る。な
お、必要に応じて、紫外線照射や超音波照射、微弱電流
の付加による殺菌あるいは除菌処理を加えることが好ま
しいこれと併行してステップ3で海洋深層水を用意し、
ステップ4でストレーナによる濾過を行う。次にステッ
プ5で上記飲料用水と海洋深層水とを予め設定した所定
の配合割合に配合して調合タンク内に入れて充分に攪拌
混合する。この希釈深層水をステップ6で茶の抽出に適
した所定の温度、例えば約90℃にまで加熱し、ステッ
プ7で所定量の茶葉に対して所定量の希釈深層水を注い
で茶を抽出する。必要であれば、ステップ8でビタミン
C等の副原料を添加し、ステップ9で再度攪拌して均質
化された茶飲料とする。一方、ステップ10,11の洗
瓶、温瓶工程によって清浄化された容器(容器はペット
ボトル、金属缶など飲料に適する素材であれば、形状は
問わない)として瓶を用意しておき、ステップ12で充
填器を用いて前記瓶内に均質化された茶飲料を充填し、
ステップ13で約80℃,30分間の脱気及び殺菌を行
い、ステップ14で打栓し、横転させた後、ステップ1
5で冷却水中に浸漬して冷却する。次にステップ16で
瓶の破損や異物の混入有無及び外観の検査を行い、検査
合格品をステップ17でラベラーによるラベリング工程
を行ってからステップ18で包装作業を行って茶飲料の
製品が完成する。飲料用水による海洋深層水の希釈割合
は茶の種類によっても異なるが、通常は海洋深層水が
0.1〜0.9重量%含まれているように希釈するのが
好ましい。本実施例で採用した海洋深層水に関して以下
に説明する。即ち、この海洋深層水は、通常海洋表層で
見られる風波とか表層温度変化に伴う対流,混合も生じ
ない環境下にある海水で、地上で使用されている各種の
油類や化学物質,農薬等の有害物質に起因する海洋汚染
の影響を受けることがない。しかも海水中の溶存有機物
が非常に少なく、かつ、微生物的な観点から極めて清浄
であるという特徴を有している。水温は年間平均で10
℃以下という低温であり、しかも人体が必要とする多く
の天然元素を含んでおり、この海洋深層水は、現在では
世界中の各所で取水されている。常法によって抽出され
た茶飲料に含まれるタンニンの量を1Lに換算すると、
400−600mg/L程度であった。タンニンはカテ
キン、フラボノイドなどの複合体であるので、茶タンニ
ンの平均分子量を600と仮定して、モル濃度に換算す
ると、0.66−1.0mMとなる。カテキン類の重合
反応により、タンニンの平均分子量が2倍となった場合
の濃度は、0.33−0.5mMとなる。一方、深層水
には、表1に示す主要金属のCa,Mg、K,Naと微
量金属のFe,Cu,Mn,Se,Zn,Cr,Moな
どが含まれている。 実験として、先の条件で製造した茶飲料と深層水原水を
等量まぜた結果、茶飲料の示す褐色の色が濃くなり、不
尤物の形成が確認されており、何らかの相互作用をする
ことを示している。深層水を数段階に希釈して実験する
とその現象は収まる方向で色の変化や味の変化を引き起
こし、それらの現象は深層水の濃度に依存していた。深
層水に含まれている成分と色成分との相互作用を研究す
るため、深層水中の金属イオンと茶飲料中のタンニン量
との関係について分析した。これまでの茶カテキンの示
す抗酸化作用の研究で、FeやCuがタンニンと相互作
用することは実験的に証明されている。そこで、深層水
に含まれるFeとCuの濃度とタンニン濃度を比較した
結果、FeとCuの濃度はタンニン濃度の0.1%程度
で、相関しないことがわかった。その結果、深層水に含
まれる主要金属イオンが、味成分と相互作用している可
能性が示唆された。そこで、茶飲料に含まれるタンニン
が金属イオンと複合体を形成したと仮定した場合のタン
ニン濃度を求め、表2とした。 深層水ミネラルイオンが茶飲料のカテキンと相互作用す
ると仮定し、その濃度を求めてみた。これまでの研究か
ら、金属イオンとカテキンとの結合は、1:1あるいは
1:2の割合で起こることが分かっている。そこで、ど
の金属イオンが相互作用しているかを、その濃度関係か
ら調べた。深層水に含まれている主要金属イオンの濃度
とタンニン濃度を等しくする稀釈率として、0.1%の
深層水を含む超純水溶液を作成した。その溶液に含まれ
る主要金属イオンの濃度を表3に示した。 表2と表3の対比より様々な検証を行った。タンニンが
全て金属イオンと結合すると、味覚(渋味、苦味、酸
味)が失われる可能性があることを考慮して、タンニン
量の50%程度が金属イオンと結合すると想定し、さら
に、複合体の1:1であると仮定すると、結合に関与す
るタンニンの濃度を計算すると、0.33−0.5m
M、0.165−0.25mMとなった。表3から、1
000倍希釈した深層水には、Mgが0.062mM、
Caが0.010mM、Kが0.014mM,Naが
0.47mMが含まれる。この計算によって、タンニン
と結合している金属イオンはNaとMgのいずれかであ
ることが分かった。しかし、Naは塩味を示す成分であ
ることから除外された。一方、Mgはそれ自体が苦味を
示すことも知られている。これらの検討結果により、味
覚(渋味、苦味)を変化させる成分としてMgが特定さ
れた。タンニンの量に合わせて深層水を稀釈する場合
は、タンニンの平均分子量が600の時は、深層水の稀
釈率は、0.6%程度、同じく、平均分子量が1200
の時は、0.3%程度が最適であることが計算から導き
出された。実際に、稀釈した深層水で茶飲料を試作し官
能試験した結果では、0.2−0.4%程度が最適であ
った。タンニンによる渋味が金属イオンによって抑制さ
れ、味がマイルドになるとの考えに立てば、Mgの量を
タンニン量の50−80%程度とするのが好ましく、苦
味を増すには、Mgの量をタンニンの量より多くすれば
良い。これらを加味すると、深層水による茶飲料の製造
には、深層水を0.1−0.9%に稀釈して用いること
が最適であることが明かとなった。渋みを抑えたマイル
ドな味の茶飲料の製造法としては、深層水に含まれるミ
ネラルイオンのMgと、味覚成分(渋味、苦味)である
タンニン濃度が一定の割合,1:1あるいは1:2であ
ることが望ましい。深層水の稀釈率を1%以上にする
と、Naによる塩味が顕著になるため、深層水の希釈率
は、0.1−0.9%にすることが望ましい。茶飲料
(緑茶、紅茶、烏龍茶)に溶出するタンニン量は、使用
する原料茶葉と抽出する条件(温度、時間)で異なるた
め、溶出するタンニン量にあわせた希釈率の深層水を使
うことが望ましい。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described below in detail with reference to the drawings. The drinking water refers to drinking water that conforms to the water quality standard of the Water Supply Law or water equivalent thereto. In this embodiment, the water is desalinated and demineralized into tap water, surface seawater, or deep ocean water. Use the purified drinking water obtained. Such desalting and demineralizing treatments can be performed using, for example, an apparatus that appropriately combines three of an ultrafiltration membrane, a reverse osmosis membrane, and an electrolyzer. The deep ocean water is prepared by filtering with a strainer, put into a blending tank together with the drinking water according to a preset mixing ratio, and stirred and mixed to obtain diluted deep ocean water. The above-mentioned deep sea water is clean seawater taken from deep sea 200 meters or more below the sea surface. FIG. 1 is a flowchart showing a process example of a method for producing a tea beverage to which the present invention is applied.
For example, tap water is prepared, and in step 2, purified drinking water is obtained by filtration, desalination, demineralization, or the like. In addition, if necessary, ultraviolet irradiation or ultrasonic irradiation, it is preferable to add sterilization or disinfection treatment by the application of a weak current.
In step 4, filtration by a strainer is performed. Next, in step 5, the drinking water and the deep sea water are blended in a predetermined blending ratio which is set in advance, and is put into a blending tank and sufficiently stirred and mixed. In step 6, the diluted deep water is heated to a predetermined temperature suitable for tea extraction, for example, about 90 ° C., and in step 7, a predetermined amount of diluted deep water is poured into a predetermined amount of tea leaves to extract tea. . If necessary, in step 8, an auxiliary material such as vitamin C is added, and in step 9, the mixture is stirred again to obtain a homogenized tea beverage. On the other hand, the bottles are prepared as containers cleaned by the washing bottle and hot bottle processes of steps 10 and 11 (the containers are not limited as long as they are materials suitable for beverages such as PET bottles and metal cans). Filling the bottle with the homogenized tea beverage using a filler at 12;
In step 13, deaeration and sterilization are performed at about 80 ° C. for 30 minutes.
In 5 immerse in cooling water and cool. Next, at step 16, the bottle is inspected for the presence or absence of foreign matter and the appearance and appearance of the foreign matter. At step 17, the labeling process is performed by a labeler, and then the packaging operation is performed at step 18 to complete a tea beverage product. . Although the dilution ratio of deep sea water with drinking water varies depending on the type of tea, it is usually preferable to dilute the deep sea water so as to contain 0.1 to 0.9% by weight. The deep sea water employed in this embodiment will be described below. In other words, this deep sea water is seawater in an environment where there is no wind wave or convection and mixing caused by changes in surface temperature that are usually found on the surface of the ocean, and various oils, chemical substances, pesticides, etc. used on the ground It is not affected by marine pollution caused by harmful substances. In addition, it has the characteristic that dissolved organic matter in seawater is very small and that it is extremely clean from a microbial point of view. Water temperature is 10 on average annually
It has a low temperature of below ℃ and contains many natural elements required by the human body, and this deep ocean water is now withdrawn throughout the world. When the amount of tannin contained in the tea beverage extracted by the ordinary method is converted into 1 L,
It was about 400-600 mg / L. Since tannin is a complex of catechin, flavonoid, etc., it is 0.66-1.0 mM in terms of molar concentration, assuming that the average molecular weight of tea tannin is 600. When the average molecular weight of tannin is doubled by the polymerization reaction of catechins, the concentration becomes 0.33-0.5 mM. On the other hand, the deep water contains Ca, Mg, K, and Na as main metals and Fe, Cu, Mn, Se, Zn, Cr, and Mo as trace metals shown in Table 1. As an experiment, as a result of mixing the tea beverage produced under the above conditions and the deep water in equal amounts, the brown color of the tea beverage was darkened, and the formation of uncertainties was confirmed. Is shown. In experiments where the deep water was diluted in several steps, the phenomenon caused a change in color and taste in the direction in which it diminished, and those phenomena depended on the concentration of the deep water. In order to study the interaction between the components contained in the deep water and the color components, the relationship between the metal ions in the deep water and the tannin content in the tea beverage was analyzed. Previous studies on the antioxidant action of tea catechins have demonstrated experimentally that Fe and Cu interact with tannins. Then, as a result of comparing the concentrations of Fe and Cu contained in the deep water and the tannin concentration, it was found that the concentrations of Fe and Cu were about 0.1% of the tannin concentration and did not correlate. As a result, it was suggested that main metal ions contained in deep water may interact with taste components. Therefore, the tannin concentration was calculated assuming that tannin contained in the tea beverage formed a complex with the metal ion, and the results are shown in Table 2. Assuming that deep-water mineral ions interact with catechins in tea beverages, we determined their concentrations. Previous studies have shown that binding of metal ions to catechins occurs at a 1: 1 or 1: 2 ratio. Therefore, which metal ions are interacting was examined from the concentration relationship. An ultrapure aqueous solution containing 0.1% of the deep water was prepared as a dilution rate for making the concentration of the main metal ions contained in the deep water equal to the concentration of the tannin. Table 3 shows the concentrations of the main metal ions contained in the solution. Various verifications were made based on the comparison between Table 2 and Table 3. Taking into account that the taste (astringency, bitterness, sourness) may be lost if all of the tannin binds to the metal ion, it is assumed that about 50% of the tannin amount binds to the metal ion. Assuming that the ratio of tannins involved in binding is 1: 1
M, 0.165-0.25 mM. From Table 3, 1
In the deep water diluted 000-fold, Mg is 0.062 mM,
Ca contains 0.010 mM, K contains 0.014 mM, and Na contains 0.47 mM. By this calculation, it was found that the metal ion bound to the tannin was either Na or Mg. However, Na was excluded because it is a salty component. On the other hand, it is also known that Mg itself shows bitterness. As a result of these examinations, Mg was specified as a component that changes the taste (astringency, bitterness). When the deep water is diluted according to the amount of tannin, when the average molecular weight of tannin is 600, the dilution rate of the deep water is about 0.6%, and similarly, the average molecular weight is 1200.
In the case of, it was derived from the calculation that about 0.3% was optimal. Actually, as a result of a trial production of a tea beverage using diluted deep water and a sensory test, about 0.2-0.4% was optimal. Considering that the astringency due to tannin is suppressed by metal ions and the taste becomes mild, it is preferable to set the amount of Mg to about 50-80% of the amount of tannin. It may be more than the amount of tannin. Taking these factors into account, it has become clear that it is optimal to use deep water diluted to 0.1-0.9% for the production of tea beverages using deep water. As a method for producing a mild-tasting tea beverage with reduced astringency, the concentration of Mg, a mineral ion contained in deep water, and the concentration of tannin, which is a taste component (astringency, bitterness), is a fixed ratio, 1: 1 or 1: It is desirably 2. If the dilution rate of the deep water is set to 1% or more, the saltiness due to Na becomes remarkable. Therefore, the dilution rate of the deep water is desirably 0.1 to 0.9%. The amount of tannin eluted in tea beverages (green tea, black tea, oolong tea) differs depending on the raw tea leaves used and the extraction conditions (temperature, time). .
【発明の効果】清浄性の高い深層水は、表層水に含まれ
る有機物や雑菌を取り除く操作が不要であることから、
主要金属イオンや微量金属イオンのミネラルイオンのバ
ランスを一定に保つことができるため、安定かつ安全な
飲料水の製造原料として利用できる。深層水に含まれる
ミネラルイオン(Mg)はタンニンなど味覚成分と相互
作用し、マイルドな味で飲みやすい茶飲料が提供され
る。深層水に含まれるNaイオンの濃度と茶飲料のタン
ニンの濃度が一定の割合1:1あるいは2:1となる
と、食味の塩味と渋味、苦味、酸味のバランスが良くな
ることが分かった。深層水を一定の割合で希釈すること
で、生体に必須である6種の主要金属イオンおよび微量
金属の補給が可能となる。EFFECT OF THE INVENTION Deep water with high cleanliness does not require an operation to remove organic matter and various bacteria contained in surface water.
Since the balance between the main metal ions and the mineral ions of the trace metal ions can be kept constant, it can be used as a stable and safe raw material for producing drinking water. Mineral ions (Mg) contained in deep water interact with taste components such as tannin to provide a tea beverage with a mild taste and easy to drink. It was found that when the concentration of Na ions contained in the deep water and the concentration of tannin in the tea beverage were at a fixed ratio of 1: 1 or 2: 1, the balance between salty taste, astringency, bitterness, and acidity was improved. By diluting deep water at a certain rate, it becomes possible to replenish the six main metal ions and trace metals essential for living organisms.
【図1】本発明を適用した茶飲料の製造方法の工程例を
示す流れ図である。FIG. 1 is a flowchart showing an example of steps of a method for producing a tea beverage to which the present invention is applied.
Claims (6)
深層水を用いて抽出することを特徴とする茶飲料の製造
方法。1. A method for producing a tea beverage, wherein the method is extracted using deep ocean water diluted to 0.1 to 0.9% with drinking water.
タンニンの濃度とほぼ等しいかそれ以下になるように海
洋深層水の希釈率が選定されることを特徴とする請求項
1記載の茶飲料の製造方法。2. The method according to claim 1, wherein the dilution ratio of the deep sea water is selected so that the concentration of Mg in the deep sea water is substantially equal to or less than the concentration of the extracted tannin. Production method of tea beverage.
あることを特徴とする請求項1または2記載の茶飲料の
製造方法。3. The method for producing a tea beverage according to claim 1, wherein the dilution rate of the deep sea water is 0.2 to 0.4%.
釈率が0.1−0.9%となるように添加することを特
徴とする茶飲料の製造方法。4. A method for producing a tea beverage, comprising adding deep-sea water to a tea beverage extracted with drinking water so as to have a dilution ratio of 0.1-0.9%.
タンニンの濃度とほぼ等しいかそれ以下になるように海
洋深層水の希釈率が選定されることを特徴とする請求項
4記載の茶飲料の製造方法。5. The method according to claim 4, wherein the dilution rate of the deep sea water is selected so that the concentration of Mg in the deep sea water is substantially equal to or less than the concentration of the tannin to be extracted. Production method of tea beverage.
が、抽出されるタンニンの濃度とほぼ等しくなるように
天然塩を添加したことを特徴とする茶またはコーヒー飲
料の製造方法。6. A method for producing a tea or coffee beverage, comprising adding a natural salt to a tea beverage extracted with drinking water such that the concentration of Mg is substantially equal to the concentration of tannin to be extracted.
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|---|---|---|---|
| JP2001126714A JP4635370B2 (en) | 2001-03-21 | 2001-03-21 | Tea drink using deep ocean water and method for producing the same |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001126714A JP4635370B2 (en) | 2001-03-21 | 2001-03-21 | Tea drink using deep ocean water and method for producing the same |
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| Publication Number | Publication Date |
|---|---|
| JP2002272372A true JP2002272372A (en) | 2002-09-24 |
| JP4635370B2 JP4635370B2 (en) | 2011-02-23 |
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ID=18975702
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|---|---|---|---|
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100778811B1 (en) | 2006-02-28 | 2007-11-28 | 주식회사 워터비스 | Deep sea water solvent extraction method of functional substances in plants |
| KR100833708B1 (en) | 2006-07-06 | 2008-05-29 | 주식회사 워터비스 | Separation and Extraction Method of Green Tea Polyphenols Functional Materials Using Deep Sea Water Solvent |
| JP2008161188A (en) * | 2006-12-07 | 2008-07-17 | Getto Chaya:Kk | Functional beverage |
| KR100959520B1 (en) | 2007-08-06 | 2010-05-27 | 주식회사 워터비스 | Marine natural organic mineral composition combined with green tea functional ingredients |
| JP2016096729A (en) * | 2014-11-18 | 2016-05-30 | アサヒ飲料株式会社 | Tea beverage |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6283847A (en) * | 1985-10-07 | 1987-04-17 | Tanpei Seiyaku Kk | Healthy tea |
| JPH05219921A (en) * | 1992-02-07 | 1993-08-31 | Kochi Pref Gov | Soft drink using deep ocean water and method for producing the same |
| JPH10150960A (en) * | 1996-07-23 | 1998-06-09 | Hidekazu Itaka | Refreshing drink using deep sea water component |
-
2001
- 2001-03-21 JP JP2001126714A patent/JP4635370B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6283847A (en) * | 1985-10-07 | 1987-04-17 | Tanpei Seiyaku Kk | Healthy tea |
| JPH05219921A (en) * | 1992-02-07 | 1993-08-31 | Kochi Pref Gov | Soft drink using deep ocean water and method for producing the same |
| JPH10150960A (en) * | 1996-07-23 | 1998-06-09 | Hidekazu Itaka | Refreshing drink using deep sea water component |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100778811B1 (en) | 2006-02-28 | 2007-11-28 | 주식회사 워터비스 | Deep sea water solvent extraction method of functional substances in plants |
| KR100833708B1 (en) | 2006-07-06 | 2008-05-29 | 주식회사 워터비스 | Separation and Extraction Method of Green Tea Polyphenols Functional Materials Using Deep Sea Water Solvent |
| JP2008161188A (en) * | 2006-12-07 | 2008-07-17 | Getto Chaya:Kk | Functional beverage |
| KR100959520B1 (en) | 2007-08-06 | 2010-05-27 | 주식회사 워터비스 | Marine natural organic mineral composition combined with green tea functional ingredients |
| JP2016096729A (en) * | 2014-11-18 | 2016-05-30 | アサヒ飲料株式会社 | Tea beverage |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4635370B2 (en) | 2011-02-23 |
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