JP2002160984A - Tile and its manufacturing method - Google Patents
Tile and its manufacturing methodInfo
- Publication number
- JP2002160984A JP2002160984A JP2000359666A JP2000359666A JP2002160984A JP 2002160984 A JP2002160984 A JP 2002160984A JP 2000359666 A JP2000359666 A JP 2000359666A JP 2000359666 A JP2000359666 A JP 2000359666A JP 2002160984 A JP2002160984 A JP 2002160984A
- Authority
- JP
- Japan
- Prior art keywords
- tile
- flux
- water glass
- green body
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 230000004907 flux Effects 0.000 claims abstract description 18
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 14
- 239000007787 solid Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 238000010304 firing Methods 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 8
- 239000003085 diluting agent Substances 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 9
- 239000002904 solvent Substances 0.000 abstract description 5
- 238000005245 sintering Methods 0.000 abstract 2
- 238000010422 painting Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 8
- 239000011148 porous material Substances 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 230000003373 anti-fouling effect Effects 0.000 description 5
- 238000005259 measurement Methods 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052573 porcelain Inorganic materials 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000010433 feldspar Substances 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 208000031872 Body Remains Diseases 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Finishing Walls (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、タイル及びその製
造方法に係り、特に汚れが付きにくく且つ汚れが取れ易
いタイルとその製造方法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a tile and a method of manufacturing the same, and more particularly, to a tile which is hardly stained and easily removed, and a method of manufacturing the same.
【０００２】[0002]
【従来の技術】タイルは、周知の通り、原料を成形して
成形体とし、これを焼成することにより製造される。外
装用タイルは、施釉されないものと施釉されるものがあ
り、内装用タイルは、釉薬が掛けられて焼成される。こ
の釉薬は、焼成後に主としてガラス質となり、素地成形
体の焼結体の表面に釉層として存在する。2. Description of the Related Art As is well known, tiles are manufactured by molding a raw material into a molded body and firing the molded body. Exterior tiles can be unglazed or glazed, while interior tiles are glazed and fired. This glaze mainly becomes glassy after firing, and exists as a glaze layer on the surface of the sintered body of the green body.
【０００３】[0003]
【発明が解決しようとする課題】施釉していないタイル
は、無釉タイル特有の素材の無垢感が生かされ、また滑
りにくいので、外壁だけでなく床用にも好適である。し
かしながら、施釉されていないので、気孔に汚れが入り
込み、汚れ易く、また一旦付いた汚れは除去が難しい。Unglazed tiles are suitable not only for outer walls but also for floors, since they make use of the solid feeling of the material unique to unglazed tiles and are less slippery. However, since it is not glazed, dirt enters pores and is easily stained, and it is difficult to remove dirt once adhered.
【０００４】施釉したタイルは、表面が主にガラス質で
あるから、汚れが付いても簡単に除去することができ
る。しかしながら、このように施釉してあるために滑り
易く、特殊な滑り止めを施さないと床用には用いること
ができない。また、釉による光沢調の美感はあるもの
の、素地成形体の無垢表面が有する特有の素材感は得が
たい。[0004] Glazed tiles can be easily removed even if they are stained because the surface is mainly vitreous. However, it is slippery because it is glazed in this way, and it cannot be used for floors without special anti-slip. In addition, although there is a glossy beauty due to the glaze, it is difficult to obtain a unique texture of the solid surface of the green body.
【０００５】なお、外装用タイルや床タイルの素地組成
をフラックス成分（Ｎａ２Ｏ、Ｋ２Ｏ、Ｂ２Ｏ３等）の
多い組成とすることにより吸水率の低い緻密な焼結体と
し、これにより汚れの付きにくいタイルとすることがあ
るが、焼結体の表面がガラス質に近くなり、上記の無垢
感が乏しくなると共に、全体が焼き締まるためにタイル
の比重も大きなものとなる。[0005] By setting the base composition of the exterior tile and floor tile to a composition containing a large amount of flux components (Na 2 O, K 2 O, B 2 O 3, etc.), a dense sintered body having a low water absorption is obtained. This may make the tile less likely to be stained, but the surface of the sintered body is close to vitreous, and the above-mentioned solid feeling is poor, and the specific gravity of the tile becomes large because the whole is sintered.
【０００６】本発明は、上記実情に鑑みてなされたもの
であり、汚れが付きにくいと共に汚れを除去し易く、素
材の無垢感を有し、滑りにくく、且つ比重も過大となら
ないタイルとその製造方法を提供することを目的とす
る。SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned circumstances, and it is difficult to remove dirt and easily remove dirt. The tile has a solid feeling of material, does not slip easily, and has a specific gravity not too large. The aim is to provide a method.
【０００７】[0007]
【課題を解決するための手段】本発明のタイルは、タイ
ル素地成形体を焼成してなるタイルにおいて、熔融が促
進された緻密層よりなる防汚層を有することを特徴とす
るものである。The tile according to the present invention is characterized in that a tile obtained by firing a tile green body has an antifouling layer composed of a dense layer promoted in melting.
【０００８】本発明のタイルの製造方法は、タイル素地
成形体を焼成するタイルの製造方法において、融剤の溶
液を該タイル素地成形体に塗布してしみ込ませた後、焼
成することを特徴とするものである。[0008] The method for producing a tile of the present invention is characterized in that, in the method for producing a tile for firing a tile green body, a flux solution is applied to the tile green body, impregnated, and then fired. Is what you do.
【０００９】かかる本発明によって提供されるタイル
は、タイル素地成形体の焼結体表面に緻密質な防汚層が
形成されており、汚れが付きにくく、また汚れが付いて
も除去し易い。[0009] In the tile provided by the present invention, a dense antifouling layer is formed on the surface of the sintered body of the tile base molded body, so that the tile is hardly stained and is easily removed even if stained.
【００１０】この緻密な防汚層は焼結体の表面近傍領域
にのみ存在するので、タイルの比重は殆ど増大しない。Since the dense antifouling layer exists only in the region near the surface of the sintered body, the specific gravity of the tile hardly increases.
【００１１】この緻密な層は、焼結体の内部に融剤成分
がしみ込んで熔融することにより形成されるものであ
り、タイル表面は素材の無垢感を有している。[0011] This dense layer is formed by the flux component penetrating into the sintered body and melting, and the tile surface has a solid feeling of the material.
【００１２】[0012]
【発明の実施の形態】以下、本発明について詳細に説明
する。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail.
【００１３】本発明のタイルを製造するには、タイル原
料を成形して素地成形体とし、この素地成形体に融剤溶
液を塗布してしみ込ませ、必要に応じ乾燥した後、焼成
する。In order to manufacture the tile of the present invention, the tile raw material is formed into a green body, and a flux solution is applied to the green body, impregnated, dried if necessary, and then fired.
【００１４】このタイル原料は、長石、陶石、ろう石、
粘土、石灰石、シャモットなど従来からタイル原料とし
て用いられている各種のものを用いることができ、また
これら以外のものでも用いることができる。This tile material is made of feldspar, pottery stone, wax stone,
Various materials conventionally used as tile materials, such as clay, limestone, and chamotte, can be used, and materials other than these can also be used.
【００１５】原料を成形して成形体とする方法は任意で
あり、湿式押出成形や乾式プレス成形など各種方法を採
用することができる。ただし、乾式プレス成形であれ
ば、得られた成形体にそのまま融剤溶液を確実にしみ込
ませることができる。湿式成形した場合には、乾燥させ
た後、融剤溶液を塗布するのが好ましい。The method of forming the raw material into a molded body is arbitrary, and various methods such as wet extrusion molding and dry press molding can be employed. However, in the case of dry press molding, the flux solution can be surely soaked into the obtained molded body. In the case of wet molding, it is preferable to apply a flux solution after drying.
【００１６】なお、成形体の大きさ及び厚さは任意であ
り、タイルとして販売される適宜の大きさとされればよ
い。通常の市販のタイルの厚さは外装用が５〜２５ｍ
ｍ、内装用が３〜１２ｍｍ、床用が７〜２５ｍｍ程度で
ある。The size and thickness of the molded article are arbitrary, and may be any suitable size to be sold as a tile. The thickness of ordinary commercial tiles is 5-25m for exterior
m, about 3 to 12 mm for interior and about 7 to 25 mm for floor.
【００１７】この成形体の表面に融剤溶液を塗布する。
融剤溶液としては水ガラス又はその希釈液が好適である
が、炭酸ナトリウム、ホウ酸、ホウ酸ナトリウム等の水
溶液であってもよい。水ガラスとしては珪酸ナトリウム
のほかにカリやリチウムの水ガラスであってよい。ただ
し、コストの点からして珪酸ナトリウム水ガラスが最も
好適である。A flux solution is applied to the surface of the compact.
As the flux solution, water glass or a diluent thereof is preferable, but an aqueous solution of sodium carbonate, boric acid, sodium borate or the like may be used. The water glass may be potassium or lithium water glass in addition to sodium silicate. However, from the viewpoint of cost, sodium silicate water glass is most preferable.
【００１８】水ガラスは、素地成形体にしみ込み易くす
るために水で２〜１０倍程度に希釈されることが好まし
い。なお、水以外の溶媒や、水に水以外の溶媒を添加し
たものを用いることも可能であるが、コストの点からし
て水を用いるのが最も好ましい。The water glass is preferably diluted about 2 to 10 times with water in order to easily permeate the green body. Note that a solvent other than water or a solvent obtained by adding a solvent other than water to water can be used, but water is most preferably used in terms of cost.
【００１９】水ガラスの場合、固形分量としてタイル表
面に０．５〜５．０ｍｇ／ｃｍ２の割合で塗布するのが
好ましい。この程度の塗布量であると、素地成形体の表
面から０．４〜２ｍｍ程度の範囲までしみ込む。なお、
塗布量は原料の組成や焼成条件を勘案して選定されるの
が好ましい。In the case of water glass, the solid content is preferably applied to the tile surface at a rate of 0.5 to 5.0 mg / cm 2 . With such an amount of application, it penetrates to a range of about 0.4 to 2 mm from the surface of the green body. In addition,
The coating amount is preferably selected in consideration of the composition of the raw materials and the firing conditions.
【００２０】塗布の方法は、スプレー、幕掛け、ロール
コーターなど任意である。The method of application is arbitrary such as spraying, curtaining and roll coater.
【００２１】塗布後、必要に応じて乾燥した後、焼成す
る。この焼成の温度及び時間は、焼結体の吸水率（ただ
し、融剤溶液がしみ込んだ範囲を除く。）が陶器質タイ
ル又はせっ器質タイルと同程度となるように選定するの
が好ましいが、床タイルとして用いる場合には磁器質タ
イルと同程度にまで焼き締めてもよい。After the application, if necessary, drying and firing are performed. The firing temperature and time are preferably selected so that the water absorption of the sintered body (excluding the range in which the flux solution is impregnated) is approximately the same as that of the ceramic tile or the ceramic tile. When used as a floor tile, it may be baked to the same extent as a porcelain tile.
【００２２】なお、ＪＩＳによれば磁器質タイルの吸水
率は１．０％以下、せっ器質タイルの吸水率は５．０％
以下、陶器質タイルの吸水率は２２．０％以下である。According to JIS, the porcelain tile has a water absorption of 1.0% or less, and the porcelain tile has a water absorption of 5.0%.
Hereinafter, the water absorption of the ceramic tile is 22.0% or less.
【００２３】この焼成により、表面に緻密層よりなる防
汚層が形成されたタイルが得られる。このタイルの表面
は、緻密ではあるが、従来の施釉タイルの釉薬層の如き
ガラス質のものではない。By this firing, a tile having a surface formed with an antifouling layer composed of a dense layer is obtained. Although the surface of this tile is dense, it is not glassy like the glaze layer of conventional glazed tiles.
【００２４】本発明のタイルの表面は、通常の無釉タイ
ルの気孔に融剤成分がしみ込んで熔融し、この融剤成分
が気孔を目止めするようになったものであり、タイル表
面層全体がガラス質になったものではない。本発明のタ
イルの表面では素地成形体の焼結体はほぼそのまま残
り、その気孔が融剤がそれ自体で、又は気孔周囲のタイ
ル原料物質と共に熔融して固化した物質で埋められたも
のであり、無釉タイルと同等の又はそれに近い無垢材質
感及び滑りにくさのものとなる。The surface of the tile of the present invention is such that the flux component permeates the pores of a normal unglazed tile and melts, and this flux component blocks the pores. Is not glassy. On the surface of the tile of the present invention, the sintered body of the green body remains almost intact, and its pores are filled with a substance in which the flux is melted and solidified by itself or with the tile raw material around the pores. , A solid texture equivalent to or close to that of an unglazed tile and a difficulty in sliding.
【００２５】このタイルの表面は、気孔が埋められ緻密
であるから、汚れが付きにくく、また付いた汚れも容易
に除去できる。この緻密層は、融剤成分が所定深さにま
でしみ込んで形成されているものであるから、タイル表
面がある程度磨耗してもタイルの防汚特性が維持され
る。Since the surface of the tile is dense and filled with pores, the tile is hardly stained and the stain can be easily removed. Since the dense layer is formed by infiltrating the flux component to a predetermined depth, the antifouling property of the tile is maintained even if the tile surface is worn to some extent.
【００２６】[0026]
【実施例】実施例１ 長石６０重量部、粘土４０重量部の原料を粉砕し、スプ
レードライ法により坏土とし、乾式プレス成形して１０
３×１０３×９ｍｍの大きさの成形体とした。３号水ガ
ラス（珪曹）を水で５倍に希釈した液を１０ｍｇ／ｃｍ
２（固形分に換算すると０．７７ｍｇ／ｃｍ２）の割合
にてスプレーした。これをローラーハースキルンにて１
２５０℃にて焼成してタイルとした。断面をＳＥＭにて
観察したところ、平均して表面から７００μｍの範囲ま
で緻密層であることが認められた。EXAMPLE 1 A raw material of 60 parts by weight of feldspar and 40 parts by weight of clay was pulverized, kneaded by a spray-dry method, and dry-press-molded.
A compact having a size of 3 × 103 × 9 mm was obtained. A solution prepared by diluting No. 3 water glass (silica) five-fold with water is 10 mg / cm.
2 (0.77 mg / cm 2 in terms of solid content). This is Roller Heart Kiln 1
It was fired at 250 ° C. to make a tile. When the cross section was observed by SEM, it was confirmed that it was a dense layer from the surface to a range of 700 μm on average.
【００２７】このタイルについて、滑り特性、汚れ付着
特性及び７５゜鏡面光沢度を測定した。滑り特性はＪＩ
Ｓ Ａ １４５４高分子系張り床材試験方法に準じて測
定した外床ＣＳＲ値である。汚れ付着特性は次の方法に
より測定した。 タイル表面の色度を色彩色度計で計測する。 このタイル表面の全面に墨汁０．５ｃｃを塗り広げ
る。 スポンジローラ（直径６ｃｍ）を水で濡らして固く
絞り、タイルの４方向から１回ずつ合計４回拭き取る。 再度、色度を計測し、最初の色度との差ΔＥを求め
る。 結果を表１に示す。With respect to this tile, slip characteristics, stain adhesion characteristics and 75 ° specular gloss were measured. Sliding characteristics are JI
This is the outer floor CSR value measured according to the SA 1454 polymer-based flooring material test method. Soil adhesion characteristics were measured by the following method. The chromaticity of the tile surface is measured with a colorimeter. Spread 0.5 cc of ink on the entire surface of the tile. A sponge roller (6 cm in diameter) is wetted with water and squeezed tightly, and wiped once from four directions of the tile, a total of four times. The chromaticity is measured again, and a difference ΔE from the first chromaticity is obtained. Table 1 shows the results.
【００２８】実施例２ 水ガラス塗布量（固形分量）を実施例１の２倍としたこ
と以外は同様にしてタイルを製造し、同様の測定を行っ
た。結果を表１に示す。Example 2 A tile was manufactured in the same manner as in Example 1 except that the amount of applied water glass (solid content) was twice that of Example 1, and the same measurement was performed. Table 1 shows the results.
【００２９】実施例３ ３号水ガラスを２倍に希釈し、塗布固形分量は実施例１
と同じとしたこと以外は同様にしてタイルを製造し、同
様の測定を行った。結果を表１に示す。Example 3 No. 3 water glass was diluted twice and the solid content of the coating was determined as in Example 1.
A tile was manufactured in the same manner except that the same was used, and the same measurement was performed. Table 1 shows the results.
【００３０】実施例４ 実施例３において、塗布固形分量を実施例３の２倍とし
たこと以外は同様にしてタイルを製造し、同様の測定を
行った。結果を表１に示す。Example 4 A tile was manufactured in the same manner as in Example 3 except that the amount of the applied solid content was twice that of Example 3, and the same measurement was performed. Table 1 shows the results.
【００３１】比較例１ 水ガラス塗布を行わなかった無垢のタイルについて同様
の測定を行った。結果を表１に示す。Comparative Example 1 The same measurement was carried out on a solid tile to which no water glass was applied. Table 1 shows the results.
【００３２】[0032]
【表１】 [Table 1]
【００３３】表１の通り、本発明のタイルは汚れ（墨
汁）が容易に除去でき、また、実施例１〜４のタイルと
比較例１のタイルの滑りにくさは殆ど同じである。な
お、外観を目視観察したところ、実施例１〜４と比較例
１のものは殆ど変りがなかった。As shown in Table 1, the tiles of the present invention can easily remove dirt (ink), and the tiles of Examples 1 to 4 and the tile of Comparative Example 1 have almost the same slip resistance. In addition, when the external appearance was visually observed, there was almost no difference between Examples 1 to 4 and Comparative Example 1.
【００３４】[0034]
【発明の効果】以上の通り、本発明によると、汚れが付
きにくく、また付いた汚れも除去し易く、しかも滑りに
くく、且つ無釉タイルと同様の無垢材質感を有したタイ
ルが提供される。As described above, according to the present invention, it is possible to provide a tile which is hard to be stained, is easy to remove the stain attached, is hard to slip, and has a solid material feeling similar to that of an unglazed tile. .
───────────────────────────────────────────────────── フロントページの続き (72)発明者 伊奈 麻美 愛知県常滑市鯉江本町５丁目１番地 株式 会社イナックス内 Ｆターム(参考） 2E110 AA65 BA02 BA12 BB07 GA33W GB28W ────────────────────────────────────────────────── ─── Continued on the front page (72) Inventor Asami 5-1-1 Koiehonmachi, Tokoname-shi, Aichi F-term in Inax Co., Ltd. (reference) 2E110 AA65 BA02 BA12 BB07 GA33W GB28W
Claims (4)
において、 熔融が促進された緻密層よりなる防汚層を有することを
特徴とするタイル。1. A tile obtained by firing a molded green body, comprising a stain-proofing layer made of a dense layer in which melting is promoted.
造方法において、融剤の溶液を該タイル素地成形体に塗
布してしみ込ませた後、焼成することを特徴とするタイ
ルの製造方法。2. A tile manufacturing method for firing a tile green body, wherein a flux solution is applied to the tile green body, impregnated, and then fired.
ガラス又はその希釈液であることを特徴とするタイルの
製造方法。3. The method according to claim 2, wherein the flux solution is water glass or a diluent thereof.
釈液を水ガラスの固形分量として０．５〜５．０ｍｇ／
ｃｍ２の割合にてタイル素地成形体の表面に塗布するこ
とを特徴とするタイルの製造方法。4. The method according to claim 3, wherein the water glass or a diluent thereof is used in an amount of 0.5 to 5.0 mg / water as a solid content of the water glass.
A method for producing a tile, wherein the method is applied to a surface of a tile base molded body at a ratio of 2 cm 2 .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000359666A JP2002160984A (en) | 2000-11-27 | 2000-11-27 | Tile and its manufacturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000359666A JP2002160984A (en) | 2000-11-27 | 2000-11-27 | Tile and its manufacturing method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2002160984A true JP2002160984A (en) | 2002-06-04 |
Family
ID=18831401
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000359666A Pending JP2002160984A (en) | 2000-11-27 | 2000-11-27 | Tile and its manufacturing method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2002160984A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010107086A1 (en) * | 2009-03-18 | 2010-09-23 | Toto株式会社 | Photocatalytic tile |
| CN113550526A (en) * | 2021-07-26 | 2021-10-26 | 山东狮子王陶瓷科技有限公司 | A production device for antifouling simulated marble tiles |
| CN118702508A (en) * | 2024-08-29 | 2024-09-27 | 广东大角鹿新材料有限公司 | Anti-slip and anti-fouling tile and production process thereof |
-
2000
- 2000-11-27 JP JP2000359666A patent/JP2002160984A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010107086A1 (en) * | 2009-03-18 | 2010-09-23 | Toto株式会社 | Photocatalytic tile |
| CN113550526A (en) * | 2021-07-26 | 2021-10-26 | 山东狮子王陶瓷科技有限公司 | A production device for antifouling simulated marble tiles |
| CN118702508A (en) * | 2024-08-29 | 2024-09-27 | 广东大角鹿新材料有限公司 | Anti-slip and anti-fouling tile and production process thereof |
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