JP2002020545A - Hydrogenated nbr composition - Google Patents
Hydrogenated nbr compositionInfo
- Publication number
- JP2002020545A JP2002020545A JP2000212085A JP2000212085A JP2002020545A JP 2002020545 A JP2002020545 A JP 2002020545A JP 2000212085 A JP2000212085 A JP 2000212085A JP 2000212085 A JP2000212085 A JP 2000212085A JP 2002020545 A JP2002020545 A JP 2002020545A
- Authority
- JP
- Japan
- Prior art keywords
- hnbr
- organic peroxide
- hydrogenated nbr
- crosslinking
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920006168 hydrated nitrile rubber Polymers 0.000 claims abstract description 12
- 150000001451 organic peroxides Chemical class 0.000 claims abstract description 8
- 229920000459 Nitrile rubber Polymers 0.000 claims description 3
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical class C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 claims 1
- 238000004132 cross linking Methods 0.000 abstract description 5
- 238000000465 moulding Methods 0.000 abstract description 2
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- -1 ketone peroxide Chemical class 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、水素化したアクリロニ
トリルブタジエンラバー（以下、ＨＮＢＲと称す）に関
し、さらに詳しくは、半減期１分の温度が１９０℃以上
である有機過酸化物を用いることにより、耐圧縮永久歪
性、成形加工性を同時に向上させ得ることが可能なＨＮ
ＢＲ組生物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to hydrogenated acrylonitrile butadiene rubber (hereinafter referred to as "HNBR"). HN that can simultaneously improve compression set resistance and molding processability
It relates to a BR-group organism.
【０００２】[0002]
【従来技術の内容】近年、自動車の高性能化に伴い、自
動車部品のゴム製品は使用環境がますます厳しくなって
きている。また、環境的な面からも、省資源、省エネル
ギーが言われているなかでそういったゴム製品に長寿命
化が求められるのは必然である。2. Description of the Related Art In recent years, the use environment of automobile parts rubber products has become more and more severe as automobiles have become more sophisticated. Also, from an environmental point of view, it is inevitable that such rubber products have a longer life in the context of resource saving and energy saving.
【０００３】[0003]
【従来技術の欠点】一般には、耐圧縮永久歪を向上させ
るためには共架橋剤、有機過酸化物などの量を増やすこ
とにより架橋密度を上げる方法がある。Disadvantages of the prior art In general, there is a method of increasing the crosslinking density by increasing the amount of a co-crosslinking agent, an organic peroxide or the like in order to improve the compression set resistance.
【０００４】[0004]
【解決しようとする課題】しかしながら、この方法では
スコーチタイムを早めてしまうことになり成形加工性に
対して悪影響を及ぼす。However, in this method, the scorch time is shortened, which adversely affects the formability.
【０００５】[0005]
【課題を解決するための手段】本発明は、水素化ＮＢＲ
（ＨＮＢＲ）１００部に対して、半減期１分の温度が１
９０℃以上である有機過酸化物０．１〜７重量部を含有
してなるＨＮＢＲ組成物により得られる。SUMMARY OF THE INVENTION The present invention provides a hydrogenated NBR.
(HNBR) For 100 parts, the temperature of half-life 1 minute is 1
It is obtained by a HNBR composition containing 0.1 to 7 parts by weight of an organic peroxide having a temperature of 90 ° C. or higher.
【０００６】本発明に用いられる有機過酸化物は、ケト
ンパーオキサイド、ジアシルパーオキサイド、ハイドロ
パーオキサイド、ジアルキルパーオキサイド、パーオキ
シケタール、アルキルパーエステル、パーカーボネート
類などいずれの分類のものを使用しても良い。The organic peroxide used in the present invention may be of any classification such as ketone peroxide, diacyl peroxide, hydroperoxide, dialkyl peroxide, peroxyketal, alkyl perester, and percarbonate. May be.
【０００７】またその使用量は、０．１〜７重量部、好
ましくは１〜５重量部であり、０．１重量部以下の添加
量では十分な物性を得ることはできず、一方、７重量部
以上の添加量ではスコーチタイムを早めてしまい、ゴム
の流れ不良、ウエルド部分の強度不足などによる不良の
増加につながる恐れがある。The used amount is 0.1 to 7 parts by weight, preferably 1 to 5 parts by weight. If the added amount is 0.1 part by weight or less, sufficient physical properties cannot be obtained. If the addition amount is more than the weight part, the scorch time is shortened, which may lead to an increase in defects due to poor rubber flow, insufficient strength of the weld portion, and the like.
【０００８】組成物の調整は以上の必須成分以外に、架
橋剤、カーボンブラック、可塑剤、その他必要な配合成
分を用いて行われる。The adjustment of the composition is carried out by using a crosslinking agent, carbon black, a plasticizer and other necessary components in addition to the above essential components.
【０００９】[0009]
【実施例】以下にその実施例について本発明を説明す
る。The present invention will be described below with reference to examples.
【表１】 日本ゼオン製品 Ｚｅｔｐｏｌ ２０１０ 注２）日本油脂製品 パーヘキシン２５Ｂ 注３）化薬アクゾ製品 パーカドックス１４ 注４）日本油脂製品 パーヘキサ２５Ｂ 注５）日本油脂製品 パークミルＤ[Table 1] Nippon Zeon products Zetpol 2010 Note 2) Nippon Oil and Fat Products Perhexin 25B Note 3) Kayaku Akzo Products Parkadox 14 Note 4) Nippon Oil and Fat Products Perhexa 25B Note 5) Nippon Oil and Fat Products Parkmill D
【００１０】[0010]
【発明の効果】ＨＮＢＲの有機過酸化物架橋において
は、耐圧縮永久歪、成形加工性の両方を同時に満足させ
ることは困難であったが、半減期１分の温度が１９０℃
以上である有機過酸化物で架橋することによりこの両方
の要求を満足できるＨＮＢＲ組成物が得られる。In the organic peroxide crosslinking of HNBR, it was difficult to simultaneously satisfy both the compression set resistance and the moldability, but the half-life temperature of 1 minute was 190 ° C.
By crosslinking with an organic peroxide as described above, an HNBR composition that satisfies both requirements can be obtained.
Claims (1)
ブタジエンラバー）１００部に対して、半減期１分の温
度が１９０℃以上である有機過酸化物０．１〜７重量部
を含有してなることを特徴とする水素化ＮＢＲ組成物。1. An organic peroxide having a half-life of 1 minute and a temperature of 190 ° C. or more per 100 parts of hydrogenated NBR (hydrogenated acrylonitrile butadiene rubber) is contained in an amount of 0.1 to 7 parts by weight. A hydrogenated NBR composition characterized by the following.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000212085A JP2002020545A (en) | 2000-07-13 | 2000-07-13 | Hydrogenated nbr composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000212085A JP2002020545A (en) | 2000-07-13 | 2000-07-13 | Hydrogenated nbr composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2002020545A true JP2002020545A (en) | 2002-01-23 |
Family
ID=18708049
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000212085A Pending JP2002020545A (en) | 2000-07-13 | 2000-07-13 | Hydrogenated nbr composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2002020545A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006049207A1 (en) * | 2004-11-04 | 2006-05-11 | Eagle Industry Co., Ltd. | Hydrogenated nitrile rubber composition |
-
2000
- 2000-07-13 JP JP2000212085A patent/JP2002020545A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006049207A1 (en) * | 2004-11-04 | 2006-05-11 | Eagle Industry Co., Ltd. | Hydrogenated nitrile rubber composition |
| JP2006131700A (en) * | 2004-11-04 | 2006-05-25 | Eagle Ind Co Ltd | Hydrogenated nitrile rubber composition |
| KR100854944B1 (en) * | 2004-11-04 | 2008-08-28 | 이구루코교 가부시기가이샤 | Hydrogenated Nitrile Rubber Composition |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20040714 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20040727 |
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| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20041124 |