JP2002018392A - Treating method for incineration ash and aging facility - Google Patents
Treating method for incineration ash and aging facilityInfo
- Publication number
- JP2002018392A JP2002018392A JP2000201359A JP2000201359A JP2002018392A JP 2002018392 A JP2002018392 A JP 2002018392A JP 2000201359 A JP2000201359 A JP 2000201359A JP 2000201359 A JP2000201359 A JP 2000201359A JP 2002018392 A JP2002018392 A JP 2002018392A
- Authority
- JP
- Japan
- Prior art keywords
- granular material
- particle size
- incinerated ash
- carbon dioxide
- fine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 230000032683 aging Effects 0.000 title claims abstract description 38
- 238000000034 method Methods 0.000 title claims abstract description 37
- 239000008187 granular material Substances 0.000 claims abstract description 102
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 70
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 47
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 35
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 35
- 239000002245 particle Substances 0.000 claims description 55
- 239000010419 fine particle Substances 0.000 claims description 40
- 238000000227 grinding Methods 0.000 claims description 37
- 239000000463 material Substances 0.000 claims description 25
- 239000000126 substance Substances 0.000 claims description 19
- 238000000926 separation method Methods 0.000 claims description 9
- 239000011800 void material Substances 0.000 claims description 8
- 239000013618 particulate matter Substances 0.000 claims description 4
- 239000011362 coarse particle Substances 0.000 claims description 2
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 43
- 238000010828 elution Methods 0.000 abstract description 20
- 150000002013 dioxins Chemical class 0.000 abstract description 10
- 239000000383 hazardous chemical Substances 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 239000002956 ash Substances 0.000 description 52
- 239000007789 gas Substances 0.000 description 13
- 239000002002 slurry Substances 0.000 description 13
- 238000012545 processing Methods 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000010586 diagram Methods 0.000 description 7
- 239000010881 fly ash Substances 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 238000005498 polishing Methods 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000007667 floating Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 230000035882 stress Effects 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- KVGZZAHHUNAVKZ-UHFFFAOYSA-N 1,4-Dioxin Chemical compound O1C=COC=C1 KVGZZAHHUNAVKZ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 239000011236 particulate material Substances 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 102100032566 Carbonic anhydrase-related protein 10 Human genes 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 101000867836 Homo sapiens Carbonic anhydrase-related protein 10 Proteins 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- -1 chromium hexahydride Chemical compound 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000001784 detoxification Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000010169 landfilling Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Landscapes
- Processing Of Solid Wastes (AREA)
- Combined Means For Separation Of Solids (AREA)
- Crushing And Grinding (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、重金属類を含む焼
却炉の焼却残渣を無害化して再利用可能とする方法と、
重金属類の溶出を防止するためのエージング施設に関す
るものである。[0001] The present invention relates to a method for detoxifying incineration residues of an incinerator containing heavy metals so that the residues can be reused.
The present invention relates to an aging facility for preventing elution of heavy metals.
【0002】[0002]
【従来の技術】従来、リサイクルができない生ゴミ等の
可燃物は、主に、ストーカ式焼却炉あるいは流動床式焼
却炉において焼却され、焼却炉の焼却残渣は焼却灰とし
て廃棄物処分場に搬出されて埋設される。上記焼却残渣
(以下、焼却灰という)には、上記可燃物に混って焼却
された金属屑やガラスあるいは陶器類の欠片や土砂等も
含まれているので、焼却灰の成分としては、各種金属や
シリカ,アルミナ,石灰等が混ざっている。このような
焼却灰は、廃棄量が多いことや、重金属類や焼却過程で
生じたダイオキシン等の有害物質が焼却灰に付着してい
ることから、焼却灰の減量化及び無害化の方法あるいは
再利用の技術の確立が望まれている。2. Description of the Related Art Conventionally, combustible materials such as garbage that cannot be recycled are mainly incinerated in a stoker-type incinerator or a fluidized-bed incinerator, and the incineration residue of the incinerator is discharged to a waste disposal site as incinerated ash. Is buried. Since the incineration residue (hereinafter referred to as incineration ash) contains incinerated metal scraps, pieces of glass or pottery, and earth and sand mixed with the above combustibles, various types of incineration ash Metals, silica, alumina, lime, etc. are mixed. Such incinerated ash has a large amount of waste, and harmful substances such as heavy metals and dioxins generated in the incineration process adhere to the incinerated ash. The establishment of utilization technology is desired.
【0003】[0003]
【発明が解決しようとする課題】ところで、焼却灰は多
くの場合、燃焼時に生じた塩化水素を除去するために消
石灰(Ca(0H)2)が混入されているため、水と接
触するとpHが高くなり、鉛等の重金属類が溶出しやす
くなる。そのため、上記焼却灰を無害化して再利用する
場合には、従来より、屋外堆積(エージング処理)が行
われている。上記エージング処理は、上記焼却灰に適度
の水分を与えつつ数週間、例えば野外のストックヤード
等に静置し、空気中の二酸化炭素と接触させて、中和反
応によるアルカリ度の低下や、CaCO3生成に伴う鉛
取り込み等の化学反応を促進することで、重金属類の溶
出を防止するものである。しかしながら、上記エージン
グ処理が終了するには数週間という膨大な時間がかかる
だけでなく、多量の焼却灰を処理するためには、広大な
ストックヤードを必要としていた。更に、エージング処
理そのものが、自然に進行する化学反応に頼っているた
め、重金属類の溶出防止効果が不安定であるといった問
題点があった。By the way, incinerated ash is often mixed with slaked lime (Ca (0H) 2 ) in order to remove hydrogen chloride generated during combustion. And heavy metals such as lead are easily eluted. Therefore, when the incinerated ash is rendered harmless and reused, outdoor deposition (aging treatment) has conventionally been performed. The above-mentioned aging treatment is carried out for several weeks while giving appropriate moisture to the incinerated ash, for example, by allowing the incinerated ash to stand still in an outdoor stock yard or the like and contacting it with carbon dioxide in the air to reduce alkalinity due to a neutralization reaction, By promoting a chemical reaction such as lead incorporation accompanying the formation of 3 , the elution of heavy metals is prevented. However, the aging process requires an enormous amount of time of several weeks to complete, and requires a large stock yard to process a large amount of incinerated ash. Furthermore, since the aging process itself relies on a chemical reaction that proceeds naturally, there is a problem that the effect of preventing elution of heavy metals is unstable.
【0004】一方、焼却炉で発生し電気集塵器等で回収
された、カドミウム,鉛,六化クロム等の重金属類を多
量に含んだ飛灰に重金属類固形化剤を添加して混練した
後、二酸化炭素を含む気体を接触させて炭酸ガス重金属
類の溶出を防止して埋立等に利用する方法が提案されて
いる(特開平11−188331号公報)。これは、重
金属含有飛灰中のアルカリ分を二酸化炭素と反応させて
中和し、pHを下げて重金属類の溶出を防止するととも
に、上記飛灰中の重金属類を難溶性の炭酸塩にすること
によって、重金属類固形化剤による重金属類の溶出防止
効果を高めるようにしたものである。しかしながら、減
量化あるいは無害化の対象となる焼却炉の焼却残渣は、
上記飛灰とは異なり粒径の大きな粒状体を多く含んでお
り、かつ上記粒状体同士が固着した団粒状になっている
ため、そのままの状態では、重金属類固形化剤や二酸化
炭素との化学反応がなかなか進行せず、重金属類の溶出
を十分に防止することができなかった。そこで、上記焼
却残渣を例えば約100μm以下の粒状体に破砕して、
重金属類固形化剤や二酸化炭素との接触面積を大きくす
るような前処理を行った後、上記飛灰の場合と同様の不
溶化処理を行うことも考えられるが、この方法では、焼
却残渣を減量化することができないだけでなく、焼却灰
の処理効率も低下してしまうという欠点がある。更に
は、破砕処理を行うため、焼却灰中の粒径の大きな粒状
体を、例えば、コンクリート用の骨材などに再利用する
ことができなくなってしまうという問題点がある。On the other hand, a heavy metal solidifying agent is added to a fly ash containing a large amount of heavy metals such as cadmium, lead, and chromium hexahydride, which is generated in an incinerator and collected by an electric dust collector, and kneaded. Thereafter, a method has been proposed in which a gas containing carbon dioxide is brought into contact to prevent elution of carbon dioxide heavy metals and used for landfilling (Japanese Patent Laid-Open No. 11-188331). This is to neutralize the alkali in the heavy metal-containing fly ash by reacting it with carbon dioxide, lower the pH to prevent the elution of the heavy metal, and to convert the heavy metal in the fly ash into a hardly soluble carbonate. Thus, the effect of preventing heavy metals from being dissolved by the heavy metal solidifying agent is enhanced. However, the incineration residues of incinerators subject to weight reduction or detoxification are:
Unlike the fly ash, it contains a large amount of granules having a large particle size and is in the form of aggregates in which the granules are fixed to each other. The reaction did not proceed easily, and the elution of heavy metals could not be sufficiently prevented. Therefore, the above incineration residue is crushed into, for example, a granular material of about 100 μm or less,
After performing a pretreatment to increase the contact area with the heavy metal solidifying agent and carbon dioxide, it is conceivable to perform the same insolubilization treatment as in the case of the fly ash, but in this method, the incineration residue is reduced. In addition to the inability to convert the incineration ash, there is a disadvantage that the efficiency of treating incinerated ash is reduced. Furthermore, since the crushing treatment is performed, there is a problem that the granular material having a large particle diameter in the incineration ash cannot be reused as, for example, aggregate for concrete.
【0005】本発明は、従来の問題点に鑑みてなされた
もので、焼却灰中の粒状体を効率よく無害化して再利用
可能とすることのできる焼却灰の処理方法と重金属類の
溶出防止を効率的にかつ安定して行うことのできるエー
ジング施設を提供することを目的とする。[0005] The present invention has been made in view of the conventional problems, and a method for treating incinerated ash that can efficiently detoxify and reuse the particulate matter in the incinerated ash and prevent elution of heavy metals. It is an object of the present invention to provide an aging facility that can efficiently and stably perform the aging.
【0006】[0006]
【課題を解決するための手段】本発明の請求項1に記載
の焼却灰の処理方法は、焼却灰から所定の粒径以上の粒
状体を抽出し、上記粒状体に適量の水分を与えつつ大気
に触れさせ、上記粒状体を大気中の二酸化炭素に接触さ
せるようにしたことを特徴とする。According to a first aspect of the present invention, there is provided a method for treating incinerated ash, comprising extracting a granular material having a predetermined particle size or more from the incinerated ash and applying an appropriate amount of water to the granular material. The present invention is characterized in that the granular material is brought into contact with the atmosphere and is brought into contact with carbon dioxide in the atmosphere.
【0007】請求項2に記載の焼却灰の処理方法は、焼
却灰から所定の粒径以上の粒状体を抽出し、上記粒状体
に適量の水分を与えつつ二酸化炭素を含む気体を供給
し、上記粒状体を二酸化炭素に接触させるようにしたこ
とを特徴とする。According to a second aspect of the present invention, there is provided a method for treating incinerated ash, comprising extracting a granular material having a predetermined particle size or more from the incinerated ash, supplying a gas containing carbon dioxide while giving an appropriate amount of water to the granular material, The method is characterized in that the granular material is brought into contact with carbon dioxide.
【0008】請求項3に記載の焼却灰の処理方法は、焼
却灰中の粒状体同士を、加水下で擦り合わせて細粒化す
る磨砕処理工程を経た後、この細粒化された粒状体を分
級工程に供給して、所定の粒径以上の粒状体を抽出する
ようにしたことを特徴とする。According to a third aspect of the present invention, there is provided a method for treating incinerated ash, which comprises subjecting the granulated material in the incinerated ash to a grinding treatment step of rubbing together under water to make the granules fine. The body is supplied to a classification step to extract a granular body having a predetermined particle size or more.
【0009】請求項4に記載の焼却灰の処理方法は、上
記磨砕処理工程で細粒化された粒状体を分級工程に供給
して、粒径の大きな粗粒不燃物を分級して抽出した後、
上記粗粒不燃物が除去された残りの粒状体を微粒子分離
装置に供給することにより、粗粒不燃物よりも粒径が小
さく、かつ微粒分が分離された所定の粒径以上の粒状体
を抽出するようにしたものである。According to a fourth aspect of the present invention, there is provided a method for treating incinerated ash, comprising supplying the granular material refined in the grinding step to a classifying step, and classifying and extracting coarse incombustibles having a large particle size. After doing
By supplying the remaining granular material from which the coarse incombustible material has been removed to a fine particle separation device, a granular material having a smaller particle size than the coarse incombustible material and having a predetermined particle size or more from which fine particles are separated can be obtained. It is designed to be extracted.
【0010】請求項5に記載の焼却灰の処理方法は、上
記磨砕処理工程で細粒化された粒状体を微粒子分離装置
に供給して微粒分を分離し、上記微粒分が分離された所
定の粒径以上の粒状体を抽出するようにしたものであ
る。According to a fifth aspect of the present invention, there is provided a method for treating incinerated ash, wherein the fine particles obtained in the grinding step are supplied to a fine particle separation device to separate fine particles, and the fine particles are separated. This is to extract a granular material having a predetermined particle size or more.
【0011】請求項6に記載の焼却灰の処理方法は、上
記微粒子分離装置で微粒分が除去された粒状体から粒径
の大きな粗粒不燃物を除去して、残りの粒状体、すなわ
ち粗粒不燃物よりも粒径が小さく、かつ微粒分が分離さ
れた所定の粒径以上の粒状体を抽出し、この粒状体に二
酸化炭素を接触させるようにしたものである。According to a sixth aspect of the present invention, there is provided a method for treating incinerated ash, comprising removing coarse incombustible materials having a large particle diameter from the granular material from which fine particles have been removed by the fine particle separation apparatus, and removing the remaining granular material, ie, coarse particles. A particulate material having a particle size smaller than that of the incombustible particles and having a predetermined particle size from which fine particles are separated is extracted, and carbon dioxide is brought into contact with the particulate material.
【0012】請求項7に記載のエージング施設は、焼却
灰から抽出された所定の粒径以上の粒状体を搭載するた
めの多数の孔を有する搭載板を有するステージと、上記
ステージの下方に配設された、二酸化炭素を含む気体を
上記粒状体に供給する気体供給管とを備えるとともに、
上記搭載板と気体供給管との間に空隙層を設け、上記粒
状体に適量の水分を与えつつ、上記空隙層を介して、二
酸化炭素を供給し、上記粒状体に二酸化炭素を接触させ
るように構成したものである。An aging facility according to a seventh aspect of the present invention includes a stage having a mounting plate having a large number of holes for mounting a granular material having a predetermined particle size or more extracted from incinerated ash, and a stage below the stage. And a gas supply pipe for supplying a gas containing carbon dioxide to the granular material,
A void layer is provided between the mounting plate and the gas supply pipe, and while giving an appropriate amount of moisture to the granular material, carbon dioxide is supplied through the void layer, and carbon dioxide is brought into contact with the granular material. It is what was constituted.
【0013】請求項8に記載のエージング施設は、上記
空隙層を、粒径の大きな砂礫で構成したものである。[0013] In the aging facility according to the present invention, the void layer is formed of large-grained sand and gravel.
【0014】[0014]
【発明の実施の形態】以下、本発明の実施の形態につい
て、図面に基づき説明する。図1は、本発明の実施の形
態に係わる焼却灰の処理システムの処理フローを示す図
で、この処理システムは、焼却炉の焼却残渣(以下、焼
却灰という)に対して磨砕処理を施し、上記細粒化され
た焼却灰から重金属類やダイオキシン等の有害物質を多
く含む微粒分を分離して所定粒径以上の粒状体を抽出す
るとともに、上記粒状体を二酸化炭素と接触させるため
のエージング施設に送って、重金属類の不溶化処理を行
い、上記粒状体を再利用可能とするものである。同図に
おいて、30は一次磨砕処理装置で、焼却灰に加水し、
上記焼却灰中の粒状体に圧縮応力を作用させ、粒状体同
士が固着している団粒状の粒状体を、上記粒状体を破壊
することなくほぼ独立した粒状体に分離して細粒化する
とともに、上記粒状体相互間の擦り合わせの力を作用さ
せて、粒状体同士の摩擦による相互研磨を行わせ、上記
粒状体の表面に付着している重金属類やダイオキシン等
の有害物質を上記粒状体表面から分離する処理(以下、
磨砕処理という)とを行うもので、この一次磨砕処理装
置30は、後述するように、細粒化を主とした磨砕処理
を行う。40は振動ふるいで、上記磨砕処理装置30で
細粒化された粒状体を含んだスラリーの中から粒径が5
mm以上の粗粒不燃物を選別し分離する。50は、上記
一次磨砕処理装置30と同様に、粒状体の解砕処理と解
膠処理とを行う二次磨砕処理装置で、この二次磨砕処理
装置50は、後述するように、粒状体同士の摩擦による
相互研磨を主体とした磨砕処理を行う。Embodiments of the present invention will be described below with reference to the drawings. FIG. 1 is a diagram showing a processing flow of an incineration ash processing system according to an embodiment of the present invention. This processing system performs attrition processing on incineration residues (hereinafter, referred to as incineration ash) of an incinerator. For separating fine particles containing a large amount of harmful substances such as heavy metals and dioxins from the finely divided incinerated ash to extract granular materials having a predetermined particle size or more, and to contact the granular materials with carbon dioxide. It is sent to an aging facility to perform insolubilization treatment of heavy metals, and the above granular material can be reused. In the figure, reference numeral 30 denotes a primary grinding treatment device, which is added to incinerated ash,
A compressive stress is applied to the granules in the incineration ash to separate the aggregated granules in which the granules adhere to each other into substantially independent granules without breaking the granules, and to refine the granules. At the same time, by applying the force of rubbing between the granules, mutual polishing is performed by friction between the granules, and harmful substances such as heavy metals and dioxins adhering to the surface of the granules are removed by the granules. Treatment to separate from the body surface (hereinafter,
This primary grinding apparatus 30 performs a grinding process mainly for grain refinement, as described later. Numeral 40 denotes a vibrating sieve, which has a particle size of 5 out of the slurry containing the granular material refined by the attrition treatment device 30.
Sort and separate coarse incombustible material of mm or more. Reference numeral 50 denotes a secondary grinding device that performs a crushing process and a deflocculing process of the granular material in the same manner as the primary grinding device 30. As described later, the secondary grinding device 50 includes: A grinding process is performed mainly on mutual polishing by friction between the granular materials.
【0015】60は、上記二次磨砕処理装置50で細粒
化された粒状体を含んだスラリーの中から、粒径が0.
5mm〜5mmの細粒不燃物を分級する振動スクリー
ン、71は上記振動スクリーン60から排出された微粒
分を含むスラリーから脱水ケーキを作製するためのフィ
ルタプレス、72は上記フィルタプレス71の処理水を
浄化する水浄化装置、80は振動スクリーン60で分級
された粒径が0.5mm〜5mmの細粒不燃物中の重金
属類を不溶化処理するためのエージング施設である。ま
た、91は上記振動ふるい40に処理水をジェット流と
して供給するジェットウオータ装置、92は上記振動ス
クリーン60に処理水をジェット流として供給するジェ
ットウオータ装置である。なお、上記水浄化装置72で
浄化された処理水は一次磨砕処理装置30の処理水とし
て使用されるとともに、ジェットウオータ装置91,9
2にも戻され、振動ふるい40及び振動スクリーン60
の処理水としても使用される。Reference numeral 60 denotes a slurry having a particle size of 0.1 from the slurry containing the granular material refined by the secondary grinding apparatus 50.
A vibrating screen for classifying fine incombustible particles of 5 mm to 5 mm, 71 is a filter press for producing a dewatered cake from a slurry containing fine particles discharged from the vibrating screen 60, and 72 is a treated water of the filter press 71. A water purification device 80 for purifying is an aging facility for insolubilizing heavy metals in fine-grained incombustible materials having a particle size of 0.5 mm to 5 mm classified by the vibrating screen 60. Reference numeral 91 denotes a jet water device that supplies treated water to the vibrating sieve 40 as a jet stream, and reference numeral 92 denotes a jet water device that supplies treated water to the vibrating screen 60 as a jet stream. The treated water purified by the water purifying device 72 is used as treated water of the primary attrition treatment device 30 and is also used by the jet water devices 91 and 9.
2, the vibrating screen 40 and the vibrating screen 60
It is also used as treated water.
【0016】次に、焼却灰の処理方法について説明す
る。まず、焼却炉の灰ピット10内に収納された焼却灰
を、受け入れホッパ20を介して、磨砕処理装置30に
投入する。なお、受け入れホッパ20の投入口には、約
20mmの分級用の網21が設けられており、大型の挟
雑物は予め捕獲され除去される。一次磨砕処理装置30
では、上記粒状体に処理水を加水しながら上記焼却灰中
の粒状体同士を擦り合わせ細粒化するとともに、上記粒
状体の表面に付着している重金属類やダイオキシン等の
有害物質を剥離して、処理水中に浮遊あるいは溶解させ
て分離する磨砕処理を行う。なお、上記処理水として
は、後述する水浄化装置72で浄化された処理水を用い
ている。Next, a method of treating incinerated ash will be described. First, the incineration ash stored in the ash pit 10 of the incinerator is introduced into the attrition treatment device 30 via the receiving hopper 20. In addition, a classification net 21 of about 20 mm is provided at the input port of the receiving hopper 20, and large contaminants are captured and removed in advance. Primary grinding device 30
Then, while adding treated water to the granules, the granules in the incineration ash are rubbed with each other to make them finer, and at the same time, harmful substances such as heavy metals and dioxins attached to the surface of the granules are peeled off. Then, a grinding treatment for separating by floating or dissolving in the treated water is performed. Note that, as the treated water, treated water purified by a water purifying device 72 described later is used.
【0017】図2(a)は一次磨砕処理装置30の構成
を示す図で、(b)図はそのA−A断面図である。一次
磨砕処理装置30は、内周面に軸方向に沿って取付けら
れ、中心方向に突出する複数の外羽根31Wを有する円
筒状の回転ドラム31と、外周面に軸方向に沿って取付
けられ、径方向に突出する複数の内羽根32Wを有し、
上記回転ドラム31の内部に偏心して取付けられたロー
タ32とを備え、回転ドラム31の外周に設けられた環
状歯車33をモータ34により駆動し、ロータ32に取
付けられた回転軸35を駆動機構36により駆動して、
回転ドラム31とロータ32とをそれぞれ互いに逆方向
に回転させ、材料投入口37から投入された処理材料で
ある焼却灰に圧縮及びすべり応力を作用させ、塊状とな
った焼却灰を、ほぼ独立した粒状体に分離して細粒化す
るとともに、上記細粒化された粒状体に対して主に粒状
体相互間の擦り合わせの力を作用させて、粒状体同士の
摩擦による相互研磨を行わせ、上記粒状体の表面に付着
している重金属類やダイオキシン等の有害物質を処理水
中に浮遊あるいは溶解させて分離するものである。な
お、振動ふるい40の後段に設けられた二次磨砕処理装
置50は、上記一次磨砕処理装置30と同様の構成であ
る。FIG. 2A is a view showing the structure of the primary grinding apparatus 30, and FIG. 2B is a sectional view taken along line AA. The primary attrition treatment device 30 is attached to the inner peripheral surface along the axial direction, and is attached to the cylindrical rotary drum 31 having a plurality of outer blades 31W protruding toward the center, and attached to the outer peripheral surface along the axial direction. , Having a plurality of inner blades 32W protruding in the radial direction,
A rotor 32 eccentrically mounted inside the rotary drum 31, an annular gear 33 provided on the outer circumference of the rotary drum 31 is driven by a motor 34, and a rotary shaft 35 mounted on the rotor 32 is driven by a drive mechanism 36. Driven by
The rotating drum 31 and the rotor 32 are rotated in directions opposite to each other, and a compressive and sliding stress is applied to the incineration ash, which is the processing material input from the material input port 37, so that the massive incineration ash is substantially independent. Separation into fine particles and fine-graining, and the above-mentioned fine-grained particles are mainly subjected to a rubbing force between the fine particles to cause mutual polishing by friction between the fine particles. In this method, harmful substances such as heavy metals and dioxin adhering to the surface of the granular material are separated by floating or dissolving in treated water. The secondary grinding device 50 provided at the subsequent stage of the vibrating sieve 40 has the same configuration as the primary grinding device 30 described above.
【0018】一次磨砕処理装置30及び二次磨砕処理装
置50において、処理材料に作用する応力の大きさは、
主に、ロータ32の径や偏心度によって決まる、回転ド
ラム31とロータ32との間隔Dと、回転ドラム31と
ロータ32との相対的な回転速度とにより調整される
(図2(b)参照)。本実施の形態においては、一次磨
砕処理装置30では、ロータ32の径及び偏心度を小さ
くすることにより回転ドラム31とロータ32との間隔
Dを比較的広くし、焼却灰に対して細粒化を主体とする
磨砕処理を行う。また、二次磨砕処理装置50では、ロ
ータ32の径と偏心度とを大きくして回転ドラム31と
ロータ32との間隔Dを狭くするとともに、回転ドラム
31とロータ32との相対的な回転速度を上記一次磨砕
処理装置30よりも速くして、粒状体同士の摩擦による
相互研磨を主体とした磨砕処理を行う。In the primary grinding apparatus 30 and the secondary grinding apparatus 50, the magnitude of the stress acting on the processing material is as follows:
It is adjusted mainly by the distance D between the rotary drum 31 and the rotor 32, which is determined by the diameter and the eccentricity of the rotor 32, and the relative rotation speed between the rotary drum 31 and the rotor 32 (see FIG. 2B). ). In the present embodiment, in the primary attrition treatment device 30, the distance D between the rotary drum 31 and the rotor 32 is relatively widened by reducing the diameter and the eccentricity of the rotor 32, so that the fine crushing of the incinerated ash is prevented. Grinding process mainly for liquefaction. In the secondary attrition treatment device 50, the distance D between the rotary drum 31 and the rotor 32 is reduced by increasing the diameter and the eccentricity of the rotor 32, and the relative rotation between the rotary drum 31 and the rotor 32 is increased. The grinding speed is set to be higher than that of the primary grinding device 30 to perform the grinding process mainly based on mutual polishing by friction between the granular materials.
【0019】上記一次磨砕処理装置30で磨砕処理され
た粒状体を含んだスラリーは、振動ふるい40に送られ
る。振動ふるい40では、上記粒状体を含んだスラリー
にジェットウオータ装置91からのジェット水を噴射し
て上記粒状体を洗浄しながら、5〜20mmの主に砂礫
分から成る粗粒不燃物を、上記スラリー中に浮遊あるい
は溶解している有害物質から分離して抽出する。なお、
上記振動ふるい40では、まず、水浄化装置72で浄化
された処理水を用いて上記粒状体を洗浄し、次に、新た
に供給された補助水を用いて洗浄する。上記振動ふるい
40を通過した粒径が5mm以下の粒状体を含んだスラ
リーは、二次磨砕処理装置50に送られ、一次磨砕処理
装置30では剥離できなかった粒状体表面に強く付着し
ている重金属類を粒状体表面から離脱させて処理水中に
浮遊あるいは溶解させる磨砕処理を行い、この磨砕処理
された粒状体を含んだスラリーを、振動スクリーン60
に送る。振動スクリーン60では、上記スラリーにジェ
ットウオータ装置92からのジェット水を噴射して上記
粒状体を洗浄しながら、粒径が0.5mm〜5mmの細
粒不燃物を、上記スラリー中に浮遊あるいは溶解してい
る有害物質から分離して抽出する。なお、振動スクリー
ン60においても、はじめに、水浄化装置72で浄化さ
れた処理水を用いて上記粒状体を洗浄し、次に、新たに
供給された補助水を用いて洗浄する。The slurry containing the granular material ground by the primary grinding device 30 is sent to a vibrating sieve 40. In the vibrating sieve 40, while washing the granular material by jetting jet water from a jet water device 91 to the slurry containing the granular material, coarse incombustible material mainly composed of gravel and having a size of 5 to 20 mm is removed from the slurry. Extract and separate from harmful substances suspended or dissolved in it. In addition,
In the vibrating sieve 40, first, the granular material is washed using the treated water purified by the water purification device 72, and then washed using newly supplied auxiliary water. The slurry containing the granular material having a particle size of 5 mm or less passing through the vibrating sieve 40 is sent to the secondary grinding device 50, and strongly adheres to the surface of the granular material that could not be separated by the primary grinding device 30. A grinding process is performed in which heavy metals are separated from the surface of the granular material and are suspended or dissolved in treated water, and the slurry containing the ground material that has been subjected to the grinding process is applied to the vibrating screen 60.
Send to In the vibrating screen 60, while jetting jet water from a jet water device 92 onto the slurry to wash the granular material, fine incombustible particles having a particle size of 0.5 mm to 5 mm float or dissolve in the slurry. Separate and extract from harmful substances. In the vibrating screen 60 as well, first, the granular material is washed using the treated water purified by the water purification device 72, and then washed using newly supplied auxiliary water.
【0020】上記振動ふるい40で抽出された粒径が5
mmm〜20mmの粗粒不燃物は、重金属類やダイオキ
シン等の有害物質が取り除かれているので、例えば、コ
ンクリート用の骨材などに再利用することができる。し
かしながら、振動スクリーン60で抽出された粒径が
0.5mm〜5mmの細粒不燃物は粒径が小さいため、
水分の吸着量も多く、また、各粒状体の表面、特にその
凹部には重金属類が残留している可能性がある。したが
って、上記細粒不燃物からは重金属類が溶出する可能性
があるので、エージング施設80に送り後述する不溶化
処理を施す。また、振動スクリーン60を通過した、有
害物質の微粒子を多く含むスラリーは、フィルタプレス
71に送って脱水処理を施し、これから脱水ケーキを作
製する。この脱水ケーキは、上記有害物質を多く含んで
いるので、例えば、溶融固化等により無害化した後、廃
棄物処分場に廃棄される。なお、フィルタプレス71の
処理水は、水浄化装置72において、薬剤による重金属
類の不溶化処理を施すなどして浄化されて再利用され
る。The particle size extracted by the vibrating sieve 40 is 5
Since the harmful substances such as heavy metals and dioxins are removed from the coarse incombustible material having a diameter of mm to 20 mm, it can be reused as, for example, aggregate for concrete. However, fine incombustible particles having a particle size of 0.5 mm to 5 mm extracted by the vibrating screen 60 have a small particle size.
A large amount of water is adsorbed, and heavy metals may remain on the surface of each granular material, particularly on its concave portions. Accordingly, heavy metals may be eluted from the fine-grain incombustibles. Therefore, the heavy metals are sent to the aging facility 80 and subjected to insolubilization treatment described later. Further, the slurry containing a large amount of fine particles of harmful substances, which has passed through the vibrating screen 60, is sent to a filter press 71 to be subjected to a dewatering treatment, and a dewatered cake is prepared therefrom. Since this dehydrated cake contains a large amount of the above harmful substances, it is made harmless by, for example, melting and solidifying, and then is discarded at a waste disposal site. The water treated by the filter press 71 is purified and reused in the water purifying device 72 by, for example, subjecting heavy metals to insolubilization treatment with a chemical.
【0021】次に、上記細粒不燃物のエージング処理に
ついて説明する。図3(a)は、本実施の形態に係わる
エージング施設80が設置された細粒不燃物のストック
ヤードの概要を示す平面図である。このストックヤード
の中央には、細粒不燃物80rを野積みするためのステ
ージ81が設置され、上記ステージ81の周囲には、上
記細粒不燃物80rに適度な水分を供給するための散水
機82が設けられている。細粒不燃物80rは、図3
(b)に示すように、ステージの上面を構成する、多数
の孔を有する鉄板から成る搭載板83上に約1m程度の
厚さに搭載されている。ステージ81の底部で上記搭載
板83の下部側には、砂礫84rから成る空隙層84を
隔てて、二酸化炭素を供給するための上記搭載板83方
向に多数の開口部85sを有する気体供給管85が配設
されている。この気体供給管85から送られてきた二酸
化炭素は、上記開口部85sから空隙層84の砂礫84
r内に広がり、搭載板83の多数の孔を通って、細粒不
燃物80r内に吹き込まれる。細粒不燃物80rは、飛
灰や上記振動スクリーン60で分離された微粒分とは異
なり、粒径が0.5mm〜5mmの粒状体であるので、
吹き込まれた二酸化炭素を細粒不燃物80rの表面に十
分に接触させることができるので、重金属類の溶出防止
を効率的に行うことができる。また、砂礫84rからな
る空隙層84を設けて、二酸化炭素が上記細粒不燃物8
0rの搭載面に均一に吹き出すようにしたので、場所に
よる化学反応の進行速度のバラツキをなくすことができ
る。Next, the aging treatment of the fine-grained incombustible material will be described. FIG. 3A is a plan view showing an outline of a stock yard for fine incombustibles in which an aging facility 80 according to the present embodiment is installed. At the center of this stockyard, a stage 81 for stacking fine-grain incombustibles 80r is installed, and around the stage 81, a sprinkler for supplying appropriate moisture to the fine-grained incombustibles 80r. 82 are provided. The fine incombustible material 80r is shown in FIG.
As shown in (b), the stage is mounted on a mounting plate 83 made of an iron plate having a large number of holes and having a thickness of about 1 m, which constitutes the upper surface of the stage. At the bottom of the stage 81 and below the mounting plate 83, a gas supply pipe 85 having a number of openings 85s in the direction of the mounting plate 83 for supplying carbon dioxide, with a gap layer 84 made of gravel 84r therebetween. Are arranged. The carbon dioxide sent from the gas supply pipe 85 passes through the opening 85 s and gravel 84 in the void layer 84.
r, and is blown into the fine incombustibles 80r through many holes of the mounting plate 83. The fine incombustible material 80r is different from fly ash and fine particles separated by the vibrating screen 60, and is a granular material having a particle size of 0.5 mm to 5 mm.
Since the blown carbon dioxide can be brought into sufficient contact with the surface of the fine incombustibles 80r, elution of heavy metals can be efficiently prevented. Further, a void layer 84 made of sand and gravel 84r is provided so that
Since the air is uniformly blown to the mounting surface of 0r, it is possible to eliminate the variation in the progress speed of the chemical reaction depending on the location.
【0022】このように、上記ステージ81に細粒不燃
物80rを搭載し、散水機82により、上記細粒不燃物
80rの表面が乾燥しない程度に水分を供給しながら、
上記細粒不燃物80rを二酸化炭素に接触させ、中和反
応によるアルカリ度の低下や、CaCO3生成に伴う鉛
取り込み等の化学反応を促進することで、重金属類の溶
出防止を短期間で、かつ安定して行うことができる。な
お、1日数回、ホイールローダなどを用いて細粒不燃物
80rの攪拌を行えば、エージング効果を更に促進させ
ることができる。As described above, the fine incombustible material 80r is mounted on the stage 81, and the sprinkler 82 supplies water to such an extent that the surface of the fine incombustible material 80r is not dried.
The fine incombustible material 80r is brought into contact with carbon dioxide to reduce the alkalinity due to the neutralization reaction and promote a chemical reaction such as lead incorporation accompanying CaCO 3 generation, thereby preventing elution of heavy metals in a short time. And it can be performed stably. The aging effect can be further promoted by stirring the fine incombustibles 80r several times a day using a wheel loader or the like.
【0023】図4は、環境基準値を超える鉛の溶出があ
った、粒径が0.5mm〜5mm未満の3種類の細粒物
(A,B,C)の試料を選び出して鉛溶出試験を行うと
ともに、上記試料と同一の試料を、湿潤状態で3〜10
週間静置するエージング処理を行った後に鉛溶出試験を
行った結果を示す図である。同図から明らかなように、
エージング処理した細粒物の鉛の溶出濃度は、A,B,
Cのいずれの試料においても、環境基準値である0.01mg
/lを大きく下回っており、従来の焼却灰全体を静置処理
した場合に比較して短時間で鉛の溶出を防ぐことができ
ることが確認された。また、図5は、上記細粒物(A,
B,C)を、本実施の形態のエージング施設80で空気
及び二酸化炭素をそれぞれ吹き込んでエージング処理し
た結果を示す図である。同図において、□は初期値、●
は1日経過した時点の、▲は3日経過した時点の鉛溶出
試験結果で、同図から明らかなように、供給する気体が
空気であっても二酸化炭素であっても、エージング処理
後に検出された鉛溶出濃度は、1日経過した時点で既に
0.001mg/l以下と検出基準値である0.01mg/lを大きく下
回っており、極めて短時間で鉛の不溶化処理がなされた
ことが確認された。FIG. 4 shows a sample of three kinds of fine particles (A, B, and C) having a particle diameter of 0.5 mm to less than 5 mm in which lead elution exceeding the environmental standard value was selected, and a lead elution test was performed. And the same sample as the above sample is wetted for 3 to 10
It is a figure which shows the result of having performed the lead elution test after performing the aging process of standing still for a week. As is clear from the figure,
The elution concentration of lead in the fine particles subjected to aging treatment is A, B,
In all samples of C, the environmental standard value of 0.01 mg
/ l, which is much lower than that of the conventional incineration ash, and it was confirmed that the elution of lead can be prevented in a shorter time than in the case where the entire incineration ash was left standing. FIG. 5 shows the fine granules (A,
FIG. 6B is a diagram showing the results of aging processing of B and C) by blowing air and carbon dioxide, respectively, in the aging facility 80 of the present embodiment. In the figure, □ is the initial value, ●
Is the lead elution test result after one day, and ▲ is the lead elution test result after three days. As is clear from the figure, whether the supplied gas is air or carbon dioxide is detected after aging treatment. The lead elution concentration that has already been
It was 0.001 mg / l or less, which was much lower than the detection reference value of 0.01 mg / l, and it was confirmed that lead was insolubilized in a very short time.
【0024】このように、本実施の形態によれば、焼却
灰を磨砕処理装置30,50に投入して加水し、粒状体
相互間の擦り合わせの力を作用させて、上記粒状体を細
粒化するとともに、上記粒状体表面から重金属類やダイ
オキシン等の有害物質を多く含む微粒分を分離した後、
振動スクリーン60で上記焼却灰中の細粒不燃物を抽出
し、これをエージング施設80に供給し、上記粒状体に
適量の水分を与えつつ二酸化炭素を供給し、上記粒状体
を二酸化炭素に接触させるようにしたので、短期間でか
つ安定して、重金属類の溶出防止を行うことができ、再
利用可能な粒状体を得ることができる。すなわち、上記
エージングする細粒不燃物は、粒状体表面から重金属類
やダイオキシン等の有害物質を多く含む微粒分の大部分
が既に分離されていること、及び、飛灰や粉砕された焼
却灰などとは異なり、粒径が0.5mm〜5mmの粒状
体であるために、吹き込まれた二酸化炭素と細粒不燃物
80rとの接触がよく反応が促進されやすいことから、
重金属類の溶出防止を確実に行うことができるととも
に、エージング時間を大幅に短縮することができる。し
たがって、廃棄する焼却灰を著しく減量化できるととも
に、予め振動ふるいで分級した粗粒不燃物や上記細粒不
燃物からなる粒状体を、例えば、コンクリート用の骨材
などに再利用することができる。As described above, according to the present embodiment, the incinerated ash is introduced into the attrition treatment devices 30 and 50 to add water thereto, and to apply the force of rubbing between the granular materials, thereby forming the above granular materials. After refinement, after separating fine particles containing a lot of harmful substances such as heavy metals and dioxins from the surface of the granular material,
The fine incombustibles in the incineration ash are extracted by the vibrating screen 60, supplied to the aging facility 80, and supplied with carbon dioxide while giving an appropriate amount of water to the granules, and the granules are brought into contact with carbon dioxide. As a result, heavy metals can be prevented from being eluted in a short period of time and stably, and a reusable granular material can be obtained. In other words, the fine-grained incombustible material to be aged is that most of fine particles containing many harmful substances such as heavy metals and dioxins have already been separated from the surface of the granular material, and fly ash and pulverized incinerated ash Unlike the granular material having a particle size of 0.5 mm to 5 mm, the contact between the injected carbon dioxide and the fine incombustible material 80r is good, and the reaction is easily promoted.
The elution of heavy metals can be reliably prevented, and the aging time can be significantly reduced. Therefore, the amount of incinerated ash to be discarded can be significantly reduced, and the granular material composed of the coarse incombustible material and the fine incombustible material classified in advance by the vibration sieve can be reused as, for example, aggregate for concrete. .
【0025】なお、上記実施の形態では、振動ふるい4
0と振動スクリーン60とを用いて、エージング処理す
る粒径が0.5mm〜5mmの細粒不燃物を抽出した
が、他の方法により、細粒不燃物を抽出してもよい。例
えば、液体供給槽を備えた、液体サイクロン等の微粒子
分離装置を設け、二次磨砕処理装置50からのスラリー
を、上記液体供給槽を介して、上記微粒子分離装置に送
り、例えば、約75μmあるいは50μm未満の微粒分
と、上記磨砕処理装置30,50で分離され処理水中に
浮遊している有害物質の微粒子とを上記細粒かされた粒
状体から分離するとともに、上記微粒分及び微粒子が分
離された粒径の大きな粒状体を、振動ふるいあるいは振
動スクリーンなどの分級手段に供給して細粒不燃物を抽
出するようにしてもよい。これにより、重金属類等の有
害物質を更に確実に分離できるので、エージング施設8
0での細粒不燃物の不溶化処理が容易となり、エージン
グ処理を更に安定して行うことができるとともに、処理
時間を更に短縮することができる。また、上記例では、
2台の磨砕処理装置を用いて、焼却灰の解砕・解膠処理
を行ったが、1台の磨砕処理装置であっても、実用上は
問題がなく、粒状体表面から重金属類やダイオキシン等
の有害物質を十分剥離することができる。In the above embodiment, the vibration sieve 4
Although fine incombustibles having a particle size of 0.5 mm to 5 mm to be subjected to aging were extracted by using 0 and the vibrating screen 60, fine incombustibles may be extracted by another method. For example, a fine particle separation device such as a liquid cyclone provided with a liquid supply tank is provided, and the slurry from the secondary grinding treatment device 50 is sent to the fine particle separation device via the liquid supply tank, for example, about 75 μm Alternatively, the fine particles having a particle size of less than 50 μm and the fine particles of the harmful substance separated in the attrition treatment devices 30 and 50 and floating in the treated water are separated from the fine particles. May be supplied to a classification means such as a vibrating screen or a vibrating screen to extract fine-grained incombustibles. As a result, harmful substances such as heavy metals can be separated more reliably.
At 0, the insolubilization treatment of fine-grained incombustibles becomes easy, the aging treatment can be performed more stably, and the treatment time can be further shortened. In the above example,
The incineration ash was pulverized and peptized using two grinding units. However, even with one grinding unit, there is no problem in practical use. And harmful substances such as dioxin can be sufficiently removed.
【0026】[0026]
【発明の効果】以上説明したように、請求項1に記載の
発明によれば、焼却灰から所定の粒径以上の粒状体を抽
出し、上記粒状体に適量の水分を与えつつ大気中に静置
させるようにしたので、空気中の二酸化炭素との反応が
促進されやすくなり、焼却灰のエージングを効率的にか
つ安定して行うことができる。また、上記粒状体は、重
金属類の不溶化処理がなされているので再利用可能であ
り、また、これにより、廃棄する焼却灰を著しく減量化
することができる。As described above, according to the first aspect of the present invention, a granular material having a predetermined particle size or more is extracted from incinerated ash, and the granular material is exposed to the atmosphere while giving an appropriate amount of moisture. Since it is allowed to stand still, the reaction with carbon dioxide in the air is easily promoted, and the incineration ash can be efficiently and stably aged. Further, since the above-mentioned granular material has been subjected to the insolubilization treatment of heavy metals, it can be reused, and thereby, the amount of incinerated ash to be discarded can be significantly reduced.
【0027】請求項2に記載の発明によれば、上記粒状
体に適量の水分を与えつつ二酸化炭素を含む気体を供給
し、上記粒状体に二酸化炭素を接触させるようにしたの
で、大気中に静置した場合に比べて、処理時間を著しく
短縮することができる。According to the second aspect of the present invention, a gas containing carbon dioxide is supplied while giving an appropriate amount of water to the granules, and carbon dioxide is brought into contact with the granules. The processing time can be significantly reduced as compared with the case where the apparatus is left still.
【0028】請求項3に記載の発明によれば、焼却灰中
の粒状体同士を、加水下で擦り合わせて細粒化する磨砕
処理工程を経た後、この細粒化された粒状体を分級工程
に供給して、所定の粒径以上の粒状体を抽出するように
したので、焼却灰の粒状体表面に付着している重金属類
やダイオキシン等の有害物質を予め分離することができ
る。したがって、エージングが容易となり、重金属類の
不溶化処理を効率よくかつ確実に行うことができる。According to the third aspect of the present invention, the fine particles in the incinerated ash are subjected to a grinding process in which the particles are rubbed together under water to make them fine. Since the particles are supplied to the classification step to extract the particles having a predetermined particle size or more, harmful substances such as heavy metals and dioxins adhered to the surface of the particles of the incinerated ash can be separated in advance. Therefore, aging becomes easy, and the insolubilization treatment of heavy metals can be performed efficiently and reliably.
【0029】請求項4に記載の発明によれば、上記磨砕
処理工程で細粒化された粒状体を分級工程に供給して、
粒径の大きな粗粒不燃物を分級して抽出した後、上記粗
粒不燃物が除去された残りの粒状体を微粒子分離装置に
供給することにより、粗粒不燃物よりも粒径が小さく、
かつ微粒分が分離された所定の粒径以上の粒状体を抽出
し、この粒状体のみをエージングするようにしたので、
処理効率を更に向上させることができる。According to the fourth aspect of the present invention, the granules finely divided in the grinding step are supplied to a classification step,
After classifying and extracting coarse incombustibles having a large particle diameter, the remaining granular material from which the coarse incombustibles have been removed is supplied to a fine particle separator, so that the particle diameter is smaller than that of the coarse incombustibles.
Since the granular material having a predetermined particle size or more in which the fine particles are separated is extracted and only this granular material is aged,
Processing efficiency can be further improved.
【0030】請求項5に記載の発明によれば、上記磨砕
処理工程で細粒化された粒状体を微粒子分離装置に供給
し、重金属類やダイオキシン等の有害物質を多く含む微
粒分を分離し、上記微粒分が分離された所定の粒径以上
の粒状体を抽出するようにしたので、重金属類の不溶化
処理を効率よく行うことができる。According to the fifth aspect of the present invention, the fine particles refined in the grinding step are supplied to a fine particle separation device to separate fine particles containing a large amount of harmful substances such as heavy metals and dioxins. However, since the fine particles having a predetermined particle size or more from which the fine particles are separated are extracted, the insolubilization treatment of heavy metals can be performed efficiently.
【0031】請求項6に記載の発明によれば、上記微粒
子分離装置で微粒分が除去された粒状体から粒径の大き
な粗粒不燃物を抽出して除去して、残りの粒状体、すな
わち粗粒不燃物よりも粒径が小さく、かつ微粒分が分離
された所定の粒径以上の粒状体を抽出し、この粒状体の
みをエージングするようにしたので、処理効率を更に向
上させることができる。According to the sixth aspect of the present invention, coarse incombustibles having a large particle size are extracted and removed from the granular material from which fine particles have been removed by the fine particle separation device, and the remaining granular material, ie, Extracting a granular material having a particle size smaller than that of the coarse incombustible material and a predetermined particle size or more in which fine particles are separated, and aging only the granular material, further improving the processing efficiency. it can.
【0032】また、請求項7に記載の発明によれば、多
数の孔を有する搭載板を有するステージと、上記ステー
ジの下方に配設された、二酸化炭素を含む気体を上記粒
状体に供給する気体供給管とを備えるとともに、上記搭
載板と気体供給管との間に空隙層を設け、焼却灰から抽
出された所定の粒径以上の粒状体に適量の水分を与えつ
つ、上記空隙層を介して、上記粒状体に二酸化炭素を接
触させるようにしたので、上記粒状体に二酸化炭素と効
率よくかつ均一に接触させることができ、エージングを
安定して行うことができるとともに、エージング時間を
大幅に短縮することができる。According to the present invention, a stage having a mounting plate having a large number of holes and a gas containing carbon dioxide disposed below the stage is supplied to the granular material. A gas supply pipe is provided, and a gap layer is provided between the mounting plate and the gas supply pipe, and while giving an appropriate amount of moisture to the granular material having a predetermined particle size or more extracted from the incineration ash, the gap layer is formed. Through the above, the carbon dioxide is brought into contact with the above-mentioned granules, so that the above-mentioned granules can be efficiently and uniformly contacted with the carbon dioxide, and the aging can be performed stably and the aging time is greatly reduced. Can be shortened.
【0033】請求項8に記載の発明によれば、上記空隙
層を、粒径の大きな砂礫で構成したので、簡単な構成で
二酸化炭素の拡散経路を形成することができ、エージン
グを安定して行うことができる。According to the eighth aspect of the present invention, since the above-mentioned void layer is made of large-size sand and gravel, a diffusion path of carbon dioxide can be formed with a simple structure, and aging can be stably performed. It can be carried out.
【図1】 本発明の実施の形態に係わる焼却灰の処理装
置の構成を示す図である。FIG. 1 is a diagram showing a configuration of an incineration ash processing apparatus according to an embodiment of the present invention.
【図2】 本実施の形態に係わる磨砕処理装置の構成を
示す図である。FIG. 2 is a diagram showing a configuration of a grinding processing apparatus according to the present embodiment.
【図3】 本実施の形態に係わるエージング施設の構成
を示す図である。FIG. 3 is a diagram showing a configuration of an aging facility according to the present embodiment.
【図4】 エージング処理による鉛溶出防止効果を示す
図である。FIG. 4 is a diagram showing an effect of preventing lead elution by an aging treatment.
【図5】 エージング促進実験の結果を示す図である。FIG. 5 is a diagram showing the results of an aging promotion experiment.
10 灰ピット、20 受け入れホッパ、30 一次磨
砕処理装置、40 振動ふるい、50 二次磨砕処理装
置、60 振動スクリーン、71 フィルタプレス、7
2 水浄化装置、80 エージング施設、80r 細粒
不燃物、81ステージ、82 散水機、83 搭載板、
84 空隙層、84r 砂礫、85気体供給管、85s
開口部、91,92 ジェットウオータ装置。DESCRIPTION OF SYMBOLS 10 Ash pit, 20 receiving hopper, 30 primary grinding apparatus, 40 vibrating sieve, 50 secondary grinding apparatus, 60 vibrating screen, 71 filter press, 7
2 water purification device, 80 aging facility, 80r fine-grain incombustible material, 81 stage, 82 water sprinkler, 83 mounting plate,
84 void layer, 84r gravel, 85 gas supply pipe, 85s
Openings, 91, 92 Jet water device.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 柴田 浩彦 東京都新宿区津久戸町2番1号 株式会社 熊谷組東京本社内 (72)発明者 前村 辰二 東京都新宿区津久戸町2番1号 株式会社 熊谷組東京本社内 (72)発明者 信太 豊 埼玉県大里郡寄居町桜沢265番地 新六精 機株式会社内 (72)発明者 反後 堯雄 東京都新宿区新宿2丁目3番13号 溶融資 源株式会社内 Fターム(参考) 4D004 AA36 AB03 CA04 CA10 CA34 CB13 CC01 CC03 4D021 AA01 CA07 4D063 EE06 EE11 GA10 GC17 GC40 GD02 GD12 GD19 GD27 ──────────────────────────────────────────────────続 き Continuing on the front page (72) Inventor Hirohiko Shibata 2-1 Tsukudo-cho, Shinjuku-ku, Tokyo Kumagaya Gumi Tokyo head office (72) Inventor Tatsuji Maemura 2-1 Tsukudo-cho, Shinjuku-ku, Tokyo Stock (72) Inventor Shinta Yutaka 265 Sakurazawa, Yorii-cho, Osato-gun, Saitama Prefecture Inside Shinrokuseiki Co., Ltd. (72) Inventor Takao Rego 2-3-13-1 Shinjuku, Shinjuku-ku, Tokyo F-term (Ref.) 4D004 AA36 AB03 CA04 CA10 CA34 CB13 CC01 CC03 4D021 AA01 CA07 4D063 EE06 EE11 GA10 GC17 GC40 GD02 GD12 GD19 GD27
Claims (8)
出し、上記粒状体に適量の水分を与えつつ大気に触れさ
せたことを特徴とする焼却灰の処理方法。1. A method for treating incinerated ash, wherein a granular material having a predetermined particle size or more is extracted from the incinerated ash, and the granular material is exposed to the atmosphere while giving an appropriate amount of moisture.
出し、上記粒状体に適量の水分を与えつつ二酸化炭素を
含む気体を供給し、上記粒状体を二酸化炭素に接触させ
るようにしたことを特徴とする焼却灰の処理方法。2. A method of extracting particulate matter having a predetermined particle size or more from incinerated ash, supplying a gas containing carbon dioxide while giving an appropriate amount of water to the particulate matter, and bringing the particulate matter into contact with carbon dioxide. A method for treating incinerated ash, characterized in that:
合わせて細粒化する磨砕処理工程を経た後、この細粒化
された粒状体を分級工程に供給して、所定の粒径以上の
粒状体を抽出するようにしたことを特徴とする請求項1
または請求項2に記載の焼却灰の処理方法。3. After passing through a grinding treatment step in which the granules in the incinerated ash are rubbed together under water to reduce the size, the finely divided granules are supplied to a classification step, 2. The method according to claim 1, wherein a granular material having a particle size or more is extracted.
Alternatively, the method for treating incinerated ash according to claim 2.
な粗粒不燃物を分離した後、上記粗粒不燃物が除去され
た残りの粒状体を分級工程に供給して、所定の粒径以上
の粒状体を抽出するようにしたことを特徴とする請求項
3に記載の焼却灰の処理方法。4. After separating coarse incombustibles having a large particle diameter from the finely divided granular bodies, the remaining granular bodies from which the coarse incombustible substances have been removed are supplied to a classifying step to be subjected to a predetermined process. 4. The method for treating incinerated ash according to claim 3, wherein a granular material having a particle size or more is extracted.
置に供給して、微粒分を分離して、所定の粒径以上の粒
状体を抽出するようにしたことを特徴とする請求項3に
記載の焼却灰の処理方法。5. The method according to claim 1, wherein said finely divided granular material is supplied to a fine particle separating device, and fine particles are separated to extract a granular material having a predetermined particle size or more. 3. The method for treating incinerated ash according to 3.
状体から粒径の大きな粗粒不燃物を除去して、残りの所
定粒径以上の粒状体を抽出し、この粒状体に二酸化炭素
を接触させるようにしたことを特徴とする請求項5に記
載の焼却灰の処理方法。6. A coarse particle incombustible material having a large particle size is removed from the granular material from which fine particles have been removed by a fine particle separation device, and the remaining granular material having a predetermined particle size or more is extracted. The method for treating incinerated ash according to claim 5, wherein the incineration ash is contacted.
粒状体を搭載するための多数の孔を有する搭載板を有す
るステージと、上記ステージの下方に配設された、二酸
化炭素を含む気体を上記粒状体に供給する気体供給管と
を備え、上記粒状体に適量の水分を与えつつ二酸化炭素
と接触させるエージング処理を行う施設であって、上記
搭載板と気体供給管との間に空隙層を設けたことを特徴
とするエージング施設。7. A stage having a mounting plate having a large number of holes for mounting a granular material having a predetermined particle size or more extracted from incineration ash, and including carbon dioxide disposed below the stage. A gas supply pipe for supplying gas to the granular material, and a facility for performing an aging treatment of contacting carbon dioxide while giving an appropriate amount of moisture to the granular material, between the mounting plate and the gas supply pipe. An aging facility characterized by a gap layer.
したことを特徴とする請求項7に記載のエージング施
設。8. The aging facility according to claim 7, wherein the void layer is made of large-grained gravel.
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|---|---|---|---|
| JP2000201359A JP2002018392A (en) | 2000-07-03 | 2000-07-03 | Treating method for incineration ash and aging facility |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000201359A JP2002018392A (en) | 2000-07-03 | 2000-07-03 | Treating method for incineration ash and aging facility |
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| Publication Number | Publication Date |
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Family
ID=18699065
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011200794A (en) * | 2010-03-25 | 2011-10-13 | Mitsubishi Heavy Industries Environmental & Chemical Engineering Co Ltd | Incineration ash treatment system |
| JP2012166170A (en) * | 2011-02-16 | 2012-09-06 | Mitsubishi Materials Corp | Washing method for incineration ash and method for converting the incineration ash into cement raw material |
| JP2013202593A (en) * | 2012-03-29 | 2013-10-07 | Osaka Gas Co Ltd | Treatment method and treatment apparatus of incineration ash |
| JP2018008195A (en) * | 2016-07-12 | 2018-01-18 | 株式会社フジタ | Waste pretreatment apparatus and pretreatment method |
| JP2022140093A (en) * | 2021-03-12 | 2022-09-26 | 株式会社フジタ | Method for producing humidity control building material and humidity control building material |
-
2000
- 2000-07-03 JP JP2000201359A patent/JP2002018392A/en not_active Withdrawn
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011200794A (en) * | 2010-03-25 | 2011-10-13 | Mitsubishi Heavy Industries Environmental & Chemical Engineering Co Ltd | Incineration ash treatment system |
| JP2012166170A (en) * | 2011-02-16 | 2012-09-06 | Mitsubishi Materials Corp | Washing method for incineration ash and method for converting the incineration ash into cement raw material |
| JP2013202593A (en) * | 2012-03-29 | 2013-10-07 | Osaka Gas Co Ltd | Treatment method and treatment apparatus of incineration ash |
| JP2018008195A (en) * | 2016-07-12 | 2018-01-18 | 株式会社フジタ | Waste pretreatment apparatus and pretreatment method |
| JP2022140093A (en) * | 2021-03-12 | 2022-09-26 | 株式会社フジタ | Method for producing humidity control building material and humidity control building material |
| JP7681412B2 (en) | 2021-03-12 | 2025-05-22 | 株式会社フジタ | Manufacturing method of humidity control building material |
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