JP2002085941A - Fresh water making process and fresh water maker - Google Patents
Fresh water making process and fresh water makerInfo
- Publication number
- JP2002085941A JP2002085941A JP2001207607A JP2001207607A JP2002085941A JP 2002085941 A JP2002085941 A JP 2002085941A JP 2001207607 A JP2001207607 A JP 2001207607A JP 2001207607 A JP2001207607 A JP 2001207607A JP 2002085941 A JP2002085941 A JP 2002085941A
- Authority
- JP
- Japan
- Prior art keywords
- water
- reverse osmosis
- membrane
- osmosis membrane
- pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000013505 freshwater Substances 0.000 title claims abstract description 38
- 238000000034 method Methods 0.000 title claims abstract description 35
- 239000012528 membrane Substances 0.000 claims abstract description 223
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 195
- 238000001223 reverse osmosis Methods 0.000 claims abstract description 120
- 238000011084 recovery Methods 0.000 claims abstract description 30
- 239000008400 supply water Substances 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 238000005259 measurement Methods 0.000 claims description 3
- 239000012466 permeate Substances 0.000 abstract description 10
- 239000013535 sea water Substances 0.000 description 23
- 150000003839 salts Chemical class 0.000 description 9
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 8
- 238000010612 desalination reaction Methods 0.000 description 8
- 239000002131 composite material Substances 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 239000012510 hollow fiber Substances 0.000 description 4
- 229920002301 cellulose acetate Polymers 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000004760 aramid Substances 0.000 description 2
- 229920003235 aromatic polyamide Polymers 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- -1 chlorine ions Chemical class 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- 238000001728 nano-filtration Methods 0.000 description 2
- 230000003204 osmotic effect Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004953 Aliphatic polyamide Substances 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000012905 Brassica oleracea var viridis Nutrition 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920003231 aliphatic polyamide Polymers 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000009530 blood pressure measurement Methods 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000001471 micro-filtration Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 229910021642 ultra pure water Inorganic materials 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Landscapes
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、前処理膜と逆浸透
膜とを用いて海水などの原水を処理して透過水を得るの
に好適に使用できる造水方法および造水装置に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fresh water producing method and a fresh water producing apparatus which can be preferably used for treating raw water such as seawater using a pretreatment membrane and a reverse osmosis membrane to obtain permeated water.
【0002】[0002]
【従来の技術】混合物の分離に関して、溶媒(例えば
水)に溶解した物質(例えば塩類)を除くための技術に
は様々なものがあるが、近年、省エネルギーおよび省資
源のためのプロセスとして膜分離法が利用されてきてい
る。中でも、蒸発のような相変化がなくエネルギー的に
有利であり、さらに運転管理が容易である逆浸透法が普
及してきているが、これによれば、海水や低濃度の塩水
(かん水)などの原水から塩などの不純物を除去して工
業用、農業用または家庭用の水を提供することができ
る。さらに、逆浸透法は、海水、かん水を淡水化して飲
料水を得ることにとどまらず、有害物を含んだ水や廃水
の処理、有価物の回収、工業用超純水の製造などにも用
いることができる。2. Description of the Related Art With respect to separation of a mixture, there are various techniques for removing substances (eg, salts) dissolved in a solvent (eg, water). In recent years, however, membrane separation has been used as a process for saving energy and resources. The law is being used. Above all, the reverse osmosis method, which does not have a phase change such as evaporation and is advantageous in energy and is easy to operate and manage, has become widespread, but according to this method, seawater and low-concentration salt water (brine) are used. It is possible to provide industrial, agricultural or domestic water by removing impurities such as salt from raw water. Further, the reverse osmosis method is used not only for desalinating seawater and brackish water to obtain drinking water, but also for treating harmful water and wastewater, collecting valuable resources, and manufacturing industrial ultrapure water. be able to.
【0003】さて、この逆浸透法を実施するにあたって
は、いかに低コストで造水するかが技術の焦点となるた
め、回収率を高める努力が払われる訳であるが、高回収
率で運転を行うと逆浸透膜の濃縮水側の溶質成分濃度が
高まって、水への溶解度が低いスケール成分が析出し、
膜寿命や透過水品質が低下したりするなどといった問題
を惹起していた。[0003] In implementing this reverse osmosis method, the focus of technology is how to produce water at low cost. Therefore, efforts are made to increase the recovery rate. When doing so, the concentration of solute components on the concentrated water side of the reverse osmosis membrane increases, and scale components with low solubility in water precipitate out,
This has caused problems such as a reduction in membrane life and permeated water quality.
【0004】そこで、逆浸透膜へ供給する原水をあらか
じめ膜により前処理して、スケール成分をある程度まで
取り除いておき、回収率を高める方法が開発されたが、
これについては、装置全体の回収率を高めようとすれ
ば、前処理工程における回収率を高めなければならず、
結局、前処理工程においてスケール成分が析出し、トー
タルでの回収率が高められないといった問題があった。Therefore, a method has been developed in which raw water to be supplied to the reverse osmosis membrane is pretreated with a membrane in advance to remove scale components to a certain extent to increase the recovery rate.
In order to increase the recovery rate of the entire apparatus, the recovery rate in the pretreatment process must be increased.
As a result, there was a problem that scale components were precipitated in the pretreatment step, and the total recovery rate could not be increased.
【0005】[0005]
【発明が解決しようとする課題】本発明の目的は、上記
した従来の問題点を解決し、原水を膜処理して透過水を
得るにあたり、より高い回収率を達成できる造水方法お
よび造水装置を提供することにある。SUMMARY OF THE INVENTION An object of the present invention is to solve the above-mentioned conventional problems and to provide a fresh water producing method and a fresh water producing method capable of achieving a higher recovery rate in membrane treatment of raw water to obtain permeated water. It is to provide a device.
【0006】[0006]
【課題を解決するための手段】上記目的を達成するため
の本発明は、原水を前処理膜に供給して得た処理水を逆
浸透膜に供給して透過水と濃縮水とを得るに際し、原水
の一部を前処理膜をバイパスさせて逆浸透膜に供給する
造水方法を特徴とするものである。SUMMARY OF THE INVENTION The present invention for achieving the above object is directed to a method for supplying treated water obtained by supplying raw water to a pretreatment membrane and supplying the treated water to a reverse osmosis membrane to obtain permeated water and concentrated water. The method is characterized in that a part of raw water is supplied to the reverse osmosis membrane by bypassing the pretreatment membrane.
【0007】ここで、逆浸透膜に供給する処理水の供給
圧力、逆浸透膜に供給する処理水の供給圧力と逆浸透膜
から得られる濃縮水の圧力との差圧、逆浸透膜から得ら
れる透過水の水質、および、逆浸透膜から得られる透過
水の流量からなる群から選ばれる少なくとも1つを測定
し、測定された値があらかじめ定めた範囲を超えた場合
に、前記測定された値に基づいて前処理膜をバイパスさ
せる原水の割合を制御する、上記に記載の造水方法も好
ましい。Here, the supply pressure of the treated water supplied to the reverse osmosis membrane, the pressure difference between the supply pressure of the treated water supplied to the reverse osmosis membrane and the pressure of the concentrated water obtained from the reverse osmosis membrane, The quality of the permeated water to be measured, and at least one selected from the group consisting of the flow rate of the permeated water obtained from the reverse osmosis membrane is measured, and when the measured value exceeds a predetermined range, the measured value is measured. The desalination method described above, in which the ratio of raw water that bypasses the pretreatment membrane is controlled based on the value, is also preferable.
【0008】また、前処理膜をバイパスさせる原水の割
合をXとし、前処理膜における回収率をYとし、逆浸透
膜における回収率をZとしたとき、X、YおよびZが次
式(1)〜(3)を同時に満足するように前処理膜をバ
イパスさせる原水の割合を制御する、上記に記載の造水
方法も好ましい。When the ratio of raw water that bypasses the pretreatment membrane is X, the recovery rate in the pretreatment membrane is Y, and the recovery rate in the reverse osmosis membrane is Z, X, Y and Z are expressed by the following equations (1). The water freshening method described above, in which the ratio of raw water that bypasses the pretreatment film is controlled so as to simultaneously satisfy the requirements (3) to (3), is also preferable.
【0009】 0.6≦Y<1 (1) 0.6<Z≦0.8 (2) 0.6≦(X+(1−X)Y)Z (3) さらに、本発明は、原水を処理するための前処理膜を有
する前処理膜装置と、この前処理膜装置に対して原水を
バイパスさせるバイパス流路と、このバイパス流路に設
けた流量制御手段と、前記前処理膜装置から得られる処
理水を透過水と濃縮水とに分離する、逆浸透膜を有する
逆浸透膜装置と、逆浸透膜装置への供給水圧力を測定す
る圧力測定手段、逆浸透膜装置への供給水圧力と濃縮水
圧力との差圧を測定する差圧測定手段、逆浸透膜装置か
ら得られる透過水の水質を測定する水質測定手段、およ
び、逆浸透膜装置から得られる透過水の流量を測定する
流量測定手段からなる群から選ばれる少なくとも1つの
測定手段と、この測定手段により測定された値に基づい
て前記流量制御手段を制御する制御装置とを備えている
造水装置を特徴としている。0.6 ≦ Y <1 (1) 0.6 <Z ≦ 0.8 (2) 0.6 ≦ (X + (1−X) Y) Z (3) Further, the present invention provides a method for treating raw water A pretreatment membrane device having a pretreatment membrane for processing, a bypass flow path for bypassing raw water to the pretreatment membrane device, a flow control means provided in the bypass flow passage, A reverse osmosis membrane device having a reverse osmosis membrane, which separates the obtained treated water into permeated water and concentrated water, pressure measurement means for measuring the pressure of water supplied to the reverse osmosis membrane device, and water supplied to the reverse osmosis membrane device Differential pressure measuring means for measuring the pressure difference between the pressure and the concentrated water pressure, water quality measuring means for measuring the quality of the permeated water obtained from the reverse osmosis membrane device, and measuring the flow rate of the permeated water obtained from the reverse osmosis membrane device At least one measuring means selected from the group consisting of And a controller for controlling the flow rate control means based on the value measured by the means.
【0010】また、上記に記載の造水方法や造水装置に
より得られた水も好ましい。[0010] Further, water obtained by the above-described fresh water producing method or fresh water producing apparatus is also preferable.
【0011】[0011]
【発明の実施の形態】本発明の一実施態様に係る造水装
置および造水方法について図1に基づいて説明する。図
1において、造水装置1は、海水などの原水の流れ方向
の上流側から順に、取水ポンプ21、送水ポンプ22、
前処理膜モジュール(前処理膜装置)41、高圧ポンプ
23、逆浸透膜モジュール(逆浸透膜処理装置)42が
接続されている。また、取水ポンプ21と送水ポンプ2
2との間の原水流路から、前処理膜モジュールをバイパ
スし処理水流路61と合流するバイパス流路32が設け
られ、このバイパス流路32にはバイパス流量を制御す
るためのバルブ(流量制御手段)81が設けられてい
る。さらに、高圧ポンプ23と濃縮水流路52との間に
は圧力エネルギーを回収するためのタービン70が接続
されている。また、逆浸透膜モジュール42と高圧ポン
プ23との間には圧力計(圧力測定手段)91、逆浸透
膜モジュール42と濃縮水流路52との間には差圧計
(差圧測定手段)92、透過水流路62には水質計(水
質測定手段)93、流量計(流量測定手段)94がそれ
ぞれ設けられ、いずれも電気的に制御装置100と接続
されている。この制御装置100はまた、バルブ81と
電気的に接続されている。DESCRIPTION OF THE PREFERRED EMBODIMENTS A desalination apparatus and desalination method according to one embodiment of the present invention will be described with reference to FIG. In FIG. 1, a fresh water generator 1 includes an intake pump 21, a water pump 22, and an intake pump 21 in order from the upstream side in the flow direction of raw water such as seawater.
A pretreatment membrane module (pretreatment membrane device) 41, a high-pressure pump 23, and a reverse osmosis membrane module (reverse osmosis membrane treatment device) 42 are connected. In addition, the water intake pump 21 and the water supply pump 2
A bypass flow passage 32 is provided from the raw water flow passage between the raw water flow passage 2 and the treatment water flow passage 61 while bypassing the pretreatment membrane module. The bypass flow passage 32 has a valve (flow rate control) for controlling a bypass flow rate. Means) 81 are provided. Further, a turbine 70 for recovering pressure energy is connected between the high-pressure pump 23 and the concentrated water channel 52. A pressure gauge (pressure measuring means) 91 between the reverse osmosis membrane module 42 and the high-pressure pump 23; a differential pressure gauge (differential pressure measuring means) 92 between the reverse osmosis membrane module 42 and the concentrated water channel 52; A water quality meter (water quality measurement means) 93 and a flow meter (flow rate measurement means) 94 are provided in the permeated water flow path 62, and both are electrically connected to the control device 100. The control device 100 is also electrically connected to the valve 81.
【0012】海水などの原水は、取水ポンプ21により
原水流路11を通じて取り入れられ、一部はバイパス流
路32を通じて前処理膜モジュールをバイパスするとと
もに、残りの原水は送水ポンプ22によって前処理膜モ
ジュール41に供給される。前処理膜モジュール41に
供給された水のうち前処理膜を透過しなかった水は非透
過水流路51を通って排出され、一方、前処理膜を透過
した処理水は、処理水流路61を通じて上記のバイパス
流路32を流れる原水と混合され、高圧ポンプ23によ
り逆浸透膜モジュール42に供給水として供される。そ
の供給水は、逆浸透膜モジュール42を通じて透過水と
濃縮水とに分離され、取り出される。このうち濃縮水
は、タービン70により圧力エネルギーが回収されて高
圧ポンプ23の動力として利用された後、排出される。
そして、上記の造水を行う際には、圧力計91や差圧計
92、水質計93、流量計94により、逆浸透膜モジュ
ール42への供給圧力、逆浸透膜差圧、透過水水質、透
過水流量が計測されて制御装置100に計測値が集約さ
れ、その計測値に基づいてバルブ81の弁開度が制御さ
れ、バイパス流量がコントロールされる。Raw water such as seawater is taken in by a water intake pump 21 through a raw water flow path 11, a part of the raw water is bypassed through a pre-treatment membrane module through a bypass flow path 32, and the remaining raw water is supplied to the pre-treatment membrane module by a water supply pump 22. 41. Of the water supplied to the pretreatment membrane module 41, water that has not passed through the pretreatment membrane is discharged through the non-permeate water channel 51, while treated water that has passed through the pretreatment membrane is passed through the treatment water channel 61. The raw water flowing through the bypass passage 32 is mixed with the raw water and supplied to the reverse osmosis membrane module 42 by the high-pressure pump 23 as supply water. The supplied water is separated into permeated water and concentrated water through the reverse osmosis membrane module 42 and is taken out. Among them, the concentrated water is discharged after the pressure energy is recovered by the turbine 70 and used as power for the high-pressure pump 23.
When the above fresh water is produced, the pressure supplied to the reverse osmosis membrane module 42, the reverse osmosis membrane differential pressure, the permeated water quality, the permeated water quality are measured by the pressure gauge 91, the differential pressure gauge 92, the water quality meter 93, and the flow meter 94. The water flow rate is measured, the measured values are collected in the control device 100, the valve opening of the valve 81 is controlled based on the measured value, and the bypass flow rate is controlled.
【0013】さて、海水を膜分離法を用いて真水を得よ
うとする場合において、あらかじめスケール発生の原因
となる特定イオン(硫酸イオンやカルシウムイオン、マ
グネシウムイオンなどの多価イオン)を取り除いた海水
を逆浸透膜分離すれば、スケール発生なしに真水の回収
率を上げることができる。さらに、前処理膜でナトリウ
ムイオンや塩素イオンを除去することは、海水濃度の低
減、すなわち浸透圧を下げることにつながり、より低圧
での運転が可能となる。このことは、逆浸透膜への処理
水の供給に用いる高圧ポンプの小型化や、省力化による
電力費の低減だけでなく、逆浸透膜の圧密化を防止する
ことができ、逆浸透膜の寿命の延長、すなわちエレメン
ト交換比率の低減も可能であることを意味している。し
かし、逆浸透膜に供給する多価イオンの除去を全て前処
理膜処理で行おうとした場合、たとえば、カルシウムイ
オンやマグネシウムイオンといった陽イオンと硫酸イオ
ンなどの陰イオンの除去率がともに高いと、前処理膜内
部でスケールが発生するため前処理膜エレメント自体の
寿命が低下するばかりでなく、スケール防止のために、
結局、低回収率運転となって前処理膜エレメント本数増
加などといったコストアップの原因を引き起こすことに
なり、好ましい状況ではない。そこで、この問題を解決
する手段として、汲み上げた海水の一部のみを前処理膜
に通水する方法を用いると、少量の前処理膜モジュール
を使用することでスケール発生に対して余裕を持った回
収率を設定でき、逆浸透膜への供給水は前処理膜透過水
と前処理膜に通水しない残部の海水とを混合することで
容易に必要量が確保することができる。この際、汲み上
げた海水の分割の割合、すなわち前処理膜をバイパスさ
せる海水の割合は、逆浸透膜に供給する処理水の供給圧
力や逆浸透膜に供給する処理水の供給圧力と逆浸透膜か
ら得られる濃縮水の圧力との差圧、逆浸透膜から得られ
る透過水の水質、逆浸透膜から得られる透過水の流量な
どを計測して決定することが好ましい。In the case where fresh water is to be obtained from the seawater using a membrane separation method, seawater from which specific ions (polyvalent ions such as sulfate ions, calcium ions, and magnesium ions) that cause scale generation have been removed in advance. If the is separated by reverse osmosis membrane, the recovery rate of fresh water can be increased without generating scale. Furthermore, removing sodium ions and chlorine ions with the pretreatment membrane leads to a reduction in the concentration of seawater, that is, a reduction in osmotic pressure, which allows operation at a lower pressure. This not only reduces the size of the high-pressure pump used to supply the treated water to the reverse osmosis membrane and reduces power costs by saving labor, but also prevents the reverse osmosis membrane from becoming more compact. This means that the service life can be extended, that is, the element replacement ratio can be reduced. However, if all removal of polyvalent ions supplied to the reverse osmosis membrane is to be performed by pretreatment membrane treatment, for example, if the removal rate of both cations such as calcium ions and magnesium ions and anions such as sulfate ions is high, Not only does the life of the pretreatment membrane element itself decrease due to the generation of scale inside the pretreatment membrane, but also to prevent scale,
Eventually, a low recovery rate operation results in an increase in cost such as an increase in the number of pretreatment membrane elements, which is not a preferable situation. Therefore, as a means to solve this problem, by using a method of passing only a part of the pumped seawater through the pretreatment membrane, there was a margin for scale generation by using a small amount of pretreatment membrane module. The recovery rate can be set, and the required amount of water supplied to the reverse osmosis membrane can be easily secured by mixing the permeated water of the pretreatment membrane with the remaining seawater that does not pass through the pretreatment membrane. At this time, the division ratio of the pumped seawater, that is, the ratio of the seawater that bypasses the pretreatment membrane, depends on the supply pressure of the treatment water supplied to the reverse osmosis membrane, the supply pressure of the treatment water supplied to the reverse osmosis membrane, and the reverse osmosis membrane. It is preferable to measure and determine the pressure difference from the pressure of the concentrated water obtained from the above, the quality of the permeated water obtained from the reverse osmosis membrane, the flow rate of the permeated water obtained from the reverse osmosis membrane, and the like.
【0014】たとえば、逆浸透膜に供給する処理水の供
給圧力があらかじめ定めた範囲、一例を挙げると、4〜
10MPa±20%を超えた場合などは、バイパス量を
減少させ、前処理膜での処理量を増大させることで、逆
浸透膜へ供給する処理水の溶質濃度を下げるように制御
する。For example, the supply pressure of the treated water to be supplied to the reverse osmosis membrane is in a predetermined range.
When the pressure exceeds 10 MPa ± 20%, for example, the solute concentration in the treated water supplied to the reverse osmosis membrane is controlled to be reduced by decreasing the bypass amount and increasing the throughput in the pretreatment membrane.
【0015】また、逆浸透膜に供給する処理水の供給圧
力と逆浸透膜から得られる濃縮水の圧力との差圧があら
かじめ定めた範囲、一例を挙げると、運転初期の差圧〜
運転初期の差圧×1.5で定められる範囲を超えた場合
などは、上記と同様にバイパス量を減少させる制御を行
う。The pressure difference between the supply pressure of the treated water supplied to the reverse osmosis membrane and the pressure of the concentrated water obtained from the reverse osmosis membrane is within a predetermined range.
When the pressure exceeds the range defined by the differential pressure at the initial stage of operation × 1.5, control is performed to decrease the bypass amount in the same manner as described above.
【0016】さらに、逆浸透膜から得られる透過水の透
過水質、たとえば、全溶質濃度が500mg/l以上に
なった場合などについても、やはり上記と同様にバイパ
ス量を減少させる制御を行えばよい。なお、上記の全溶
質濃度は、たとえば、電気伝導度を測定することにより
得ることができる。Further, also in the case where the permeated water quality of the permeated water obtained from the reverse osmosis membrane, for example, when the total solute concentration becomes 500 mg / l or more, the control for reducing the bypass amount may be performed in the same manner as described above. . The above-mentioned total solute concentration can be obtained, for example, by measuring electric conductivity.
【0017】また、逆浸透膜から得られる透過水の流量
があらかじめ定めた範囲、一例を挙げると、運転初期の
流量×0.8〜運転初期の流量で定められる範囲を下回
った場合などは、バイパス量を増加させ、前処理膜での
処理量を減少させる制御を行う。Further, when the flow rate of the permeated water obtained from the reverse osmosis membrane falls below a predetermined range, for example, the flow rate at the initial operation × 0.8 to the flow rate at the initial operation, for example, Control is performed to increase the bypass amount and decrease the processing amount in the pretreatment film.
【0018】なお、上記のようにある一つの状態の測定
値に基づいてバイパス量を制御してもよいが、もちろ
ん、2つ以上の状態の測定値に基づいて制御することも
できる。たとえば、逆浸透膜から得られる透過水の水質
が悪化、すなわち、全溶質濃度などが一定範囲を超え、
かつ、逆浸透膜から得られる透過水の水量も一定範囲を
超えて増大するような場合などは、バイパス量を減少さ
せ、前処理膜での処理量を増大させることで、逆浸透膜
へ供給する処理水の溶質濃度を下げるように制御するこ
とが好ましい。Although the bypass amount may be controlled based on the measured value in one state as described above, it is needless to say that the bypass amount may be controlled based on the measured values in two or more states. For example, the quality of the permeated water obtained from the reverse osmosis membrane deteriorates, that is, the total solute concentration exceeds a certain range,
In addition, when the amount of permeated water obtained from the reverse osmosis membrane also increases beyond a certain range, supply to the reverse osmosis membrane by reducing the bypass amount and increasing the throughput in the pretreatment membrane It is preferable to control so as to lower the solute concentration of the treated water.
【0019】また、上記した逆浸透膜への供給圧力が上
昇し、差圧が上昇し、透過水質が悪化し、透過水量が低
下した場合などについても同様にバイパス量を減少させ
る制御を行うとよい。ただし、このような場合は、逆浸
透膜の劣化が考えられるため、逆浸透膜エレメントの洗
浄や、新品への交換などを実施することが好ましい場合
がある。Further, when the supply pressure to the reverse osmosis membrane is increased, the differential pressure is increased, the quality of the permeated water is deteriorated, and the amount of the permeated water is decreased, the control for reducing the bypass amount is similarly performed. Good. However, in such a case, since the reverse osmosis membrane may be deteriorated, it may be preferable to wash the reverse osmosis membrane element or replace the element with a new one.
【0020】いずれにしても、上記したようなバイパス
量の制御を行うことにより、造水装置の運転条件を最適
化でき、透過水を高回収率で得ることが可能となる。In any case, by controlling the bypass amount as described above, the operating conditions of the fresh water generator can be optimized, and the permeated water can be obtained at a high recovery rate.
【0021】また、本発明においては、前処理膜をバイ
パスさせる原水の割合をXとし、前処理膜における回収
率をYとし、逆浸透膜における回収率をZとしたとき、
X、YおよびZが次式(1)〜(3)を同時に満足する
ように前処理膜をバイパスさせる原水の割合を制御する
ことが好ましい。In the present invention, when the ratio of raw water that bypasses the pretreatment membrane is X, the recovery rate in the pretreatment membrane is Y, and the recovery rate in the reverse osmosis membrane is Z,
It is preferable to control the ratio of raw water that bypasses the pretreatment film so that X, Y and Z simultaneously satisfy the following expressions (1) to (3).
【0022】 0.6≦Y<1 (1) 0.6<Z≦0.8 (2) 0.6≦(X+(1−X)Y)Z (3) なお、X=(前処理膜をバイパスする原水の容積)/
(全原水の容積) Y=(前処理膜の透過水容積)/(前処理膜の供給水容
積) Z=(逆浸透膜の透過水容積)/(逆浸透膜の供給水容
積) で求められる。0.6 ≦ Y <1 (1) 0.6 <Z ≦ 0.8 (2) 0.6 ≦ (X + (1-X) Y) Z (3) where X = (pretreatment film) Volume of raw water that bypasses
(Volume of all raw water) Y = (permeate water volume of pretreatment membrane) / (supply water volume of pretreatment membrane) Z = (permeate water volume of reverse osmosis membrane) / (supply water volume of reverse osmosis membrane) Can be
【0023】X、YおよびZが上記(1)〜(3)式を
同時に満足していることにより、前処理膜と逆浸透膜と
の負荷の割合を適度な範囲内に抑えつつ、しかも、透過
水の水質を保ったままで透過水量を増大させる、すなわ
ち、回収率を高めることができる。Since X, Y and Z simultaneously satisfy the above expressions (1) to (3), the load ratio between the pretreatment membrane and the reverse osmosis membrane is kept within an appropriate range, and The amount of permeated water can be increased while maintaining the quality of permeated water, that is, the recovery rate can be increased.
【0024】なお、上記の造水装置において、海水の取
水方法としては、表層取水や浸透取水、深層取水など種
々の方法を用いることができる。中でも、海水中の懸濁
物質などをあらかじめある程度まで除去できる、海底の
砂層を浸透した海水を取水する浸透取水法を用いると、
濁質成分が少なくファウリングが発生しにくい点で好ま
しい。In the above fresh water generator, various methods such as surface water intake, permeate water intake, and deep water intake can be used as the seawater intake method. Above all, when using the osmotic water intake method that removes seawater that has penetrated the sand layer on the seabed, which can remove suspended substances in seawater to some extent in advance,
It is preferable because fouling hardly occurs due to a small amount of turbid components.
【0025】また、前処理膜装置は、前処理膜を有す
る、複数個の前処理膜エレメントを圧力容器に納めた前
処理膜モジュールを備えていることが好ましい。It is preferable that the pretreatment membrane device includes a pretreatment membrane module having a pretreatment membrane and containing a plurality of pretreatment membrane elements in a pressure vessel.
【0026】前処理膜としては、限外ろ過膜(MF膜)
や精密ろ過膜(UF膜)、ナノフィルトレーション膜
(NF膜)などを用いることができる。これらの中で
は、イオン成分を除去できる膜を用いることが好まし
く、NF膜を用いると、スケールの発生源である多価イ
オンを選択的に除去することができるため特に好まし
い。また、前処理膜を構成する材質としては、たとえ
ば、酢酸セルロースや芳香族ポリアミド、脂肪族ポリア
ミド、ポリビニルアルコール、ポリエーテルスルホンな
どを用いることができる。また、膜の形態から見ると、
中空糸膜形態や平膜形態を有する膜を用いることがで
き、さらに、非対称膜や複合膜の形態いずれでも使用が
可能である。As the pretreatment membrane, an ultrafiltration membrane (MF membrane)
Or a microfiltration membrane (UF membrane), a nanofiltration membrane (NF membrane), or the like. Among them, it is preferable to use a film capable of removing an ion component, and it is particularly preferable to use an NF film because polyvalent ions that are scale generation sources can be selectively removed. Further, as a material constituting the pretreatment film, for example, cellulose acetate, aromatic polyamide, aliphatic polyamide, polyvinyl alcohol, polyether sulfone, or the like can be used. Also, from the viewpoint of the film form,
A membrane having a hollow fiber membrane form or a flat membrane form can be used, and further, any form of an asymmetric membrane or a composite membrane can be used.
【0027】また、前処理膜エレメントとしては、後述
する逆浸透膜エレメントと同様に、平膜形態の逆浸透膜
を用いる場合は、スパイラル型エレメントや、チューブ
ラー型エレメント、プレートアンドフレーム型エレメン
トを用いることができる。また、中空糸膜形態の逆浸透
膜を用いる場合は、U字状やI字状に束ねて筐体に収納
したエレメントを用いればよい。When a flat membrane type reverse osmosis membrane is used as the pretreatment membrane element, a spiral type element, a tubular type element, or a plate and frame type element is used as in the case of a reverse osmosis membrane element to be described later. Can be used. When a reverse osmosis membrane in the form of a hollow fiber membrane is used, an element bundled in a U-shape or an I-shape and housed in a housing may be used.
【0028】前処理膜モジュールについても、後述する
逆浸透膜モジュールと同様に、上記エレメントを1個ま
たは複数個を圧力容器に収納して用いる。もちろん、こ
のモジュールを並列に複数個配置した前処理膜モジュー
ルユニットとして用いることも可能である。As for the pretreatment membrane module, one or a plurality of the above-mentioned elements are housed in a pressure vessel and used as in the case of a reverse osmosis membrane module described later. Of course, it is also possible to use this module as a pretreatment membrane module unit in which a plurality of modules are arranged in parallel.
【0029】逆浸透膜装置に処理水を供給する高圧ポン
プについては、渦巻ポンプやタービンポンプ、プランジ
ャーポンプなどの種々の形式のポンプを用いることがで
きる。As a high-pressure pump for supplying treated water to the reverse osmosis membrane device, various types of pumps such as a spiral pump, a turbine pump, and a plunger pump can be used.
【0030】逆浸透膜装置は、逆浸透膜を有する、複数
個の逆浸透膜エレメントを圧力容器に納めた逆浸透膜モ
ジュールを備えていることが好ましい。The reverse osmosis membrane device preferably includes a reverse osmosis membrane module having a plurality of reverse osmosis membrane elements having a reverse osmosis membrane and housed in a pressure vessel.
【0031】逆浸透膜としては、酢酸セルロース系ポリ
マーを用いたものや、ポリアミドを用いたものが好まし
く、また、非対称構造を持ったものや複合構造を持った
もの、さらには、中空糸膜形態を有するものや平膜形態
を有するものなど、いずれでも用いることができる。中
でも、非対称構造を有する、酢酸セルロース系ポリマー
を用いた逆浸透膜や、複合構造を有する、ポリアミドを
用いた逆浸透膜を用いると効果が大きく、特に、芳香族
ポリアミド複合膜を用いると非常に効果が大きい。As the reverse osmosis membrane, those using a cellulose acetate polymer or polyamide are preferable, those having an asymmetric structure, those having a composite structure, and those having a hollow fiber membrane form. And those having a flat film form can be used. Above all, a reverse osmosis membrane using a cellulose acetate polymer having an asymmetric structure, or a reverse osmosis membrane using a polyamide having a composite structure has a large effect, and in particular, an aromatic polyamide composite membrane is very effective. Great effect.
【0032】エレメントとは、上記の逆浸透膜を筐体に
納めて使いやすくしたもので、平膜形態の逆浸透膜を用
いる場合は、透過水流路材や原水流路材などとともに構
成された膜ユニットを集水管の周囲に巻回したスパイラ
ル型エレメントや、チューブラー型エレメント、プレー
トアンドフレーム型エレメントなどを用いることができ
る。また、中空糸膜形態の逆浸透膜を用いる場合は、U
字型やI字型に束ねて筐体に納めた形態とすることがで
きる。The element is an element in which the above-described reverse osmosis membrane is housed in a housing for easy use. When a reverse osmosis membrane in the form of a flat membrane is used, the element is constituted together with a permeated water flow path material and a raw water flow path material. A spiral element in which a membrane unit is wound around a water collecting pipe, a tubular element, a plate and frame element, or the like can be used. When a hollow fiber reverse osmosis membrane is used, U
It can be in a form of being bundled in a letter shape or an I shape and housed in a housing.
【0033】逆浸透膜モジュールは、これらのエレメン
トを1本または複数本を圧力容器に納めたものであり、
好ましくは4〜8本のエレメントを収納したものを用い
るとよい。さらに、このモジュールを並列に複数系列配
置したものを逆浸透膜モジュールユニットといい、これ
も逆浸透膜装置として好適に用いることができる。The reverse osmosis membrane module contains one or more of these elements in a pressure vessel.
Preferably, one containing 4 to 8 elements is used. Further, a module in which a plurality of such modules are arranged in parallel is referred to as a reverse osmosis membrane module unit, which can also be suitably used as a reverse osmosis membrane device.
【0034】本発明では、さらに経済的かつ効率的に造
水を行うため、特に、海水から淡水を得る場合には、上
記の逆浸透膜モジュールや逆浸透膜モジュールユニット
を多段に配置して逆浸透膜装置を構成すると好ましい。
たとえば、前後段に2段に配置する場合には、前段で得
られる濃縮水を昇圧して後段への供給水とし、前後段そ
れぞれから透過水(淡水)を得る濃縮水2段法や、前段
の透過水をさらに後段への供給水として高品質な透過水
(淡水)を得る透過水2段法を適用することができる。
もちろん、これらは2段配置に限られることはなく、必
要に応じて3段以上の多段構成とすることもできる。In the present invention, in order to produce water more economically and efficiently, especially when fresh water is obtained from seawater, the above reverse osmosis membrane modules and reverse osmosis membrane module units are arranged in multiple stages to reverse water. It is preferable to configure a permeable membrane device.
For example, in the case of arranging two stages in the front and rear stages, the concentrated water obtained in the front stage is pressurized to supply water to the subsequent stage, and the concentrated water two-stage method in which permeated water (fresh water) is obtained from each of the front and rear stages, A permeate water two-stage method for obtaining high-quality permeate water (fresh water) by further using permeate water as a supply water to the subsequent stage can be applied.
Of course, these are not limited to the two-stage arrangement, and a multi-stage configuration of three or more stages can be used if necessary.
【0035】上記の濃縮水2段法や多段法を用いる場合
は、後段から得られる濃縮水は高い圧力エネルギーを有
しているため、これを昇圧のためのエネルギーとして回
収し利用することが好ましい。これは、たとえば、回収
タービンなどを用いて実現することができる。In the case of using the above-mentioned concentrated water two-stage method or multi-stage method, since the concentrated water obtained from the subsequent stage has high pressure energy, it is preferable to collect and use this as energy for increasing the pressure. . This can be realized using, for example, a recovery turbine.
【0036】[0036]
【実施例】以下の実施例、比較例においては、前処理膜
としてナノフィルトレーション膜(NF膜)を、逆浸透
膜としてポリアミド系複合膜を用いた。 (実施例1)図1に示した造水装置を用いて造水を行っ
た。EXAMPLES In the following examples and comparative examples, a nanofiltration membrane (NF membrane) was used as a pretreatment membrane, and a polyamide-based composite membrane was used as a reverse osmosis membrane. (Example 1) Fresh water was produced using the fresh water producing apparatus shown in FIG.
【0037】まず、原水(塩濃度3.5重量%の海水)
を送水ポンプ22にて2.0MPaに昇圧して前処理膜
モジュール41に供給し、回収率Y=0.7で処理し
た。前処理膜モジュール41の処理水とバイパスさせた
原水(運転開始時のバイパス量の割合X=0.5)とを
混合させた供給水の蒸発残留物濃度は約25,000m
g/lであった。なお、前処理膜モジュール41として
は、500mg/lのNaCl溶液を0.5MPaで運
転したときに脱塩率85%、膜造水量1.20m 3/
(m2・d)の性能を有するNF膜を用いたスパイラル
型エレメントを、6本直列に接続して圧力容器に組み込
んだものを用いた。First, raw water (seawater having a salt concentration of 3.5% by weight)
Is increased to 2.0 MPa by a water supply pump 22 and the pretreatment membrane
Supply to module 41 and process at recovery rate Y = 0.7
Was. The treatment water of the pretreatment membrane module 41 was bypassed.
Raw water (the ratio of bypass amount X = 0.5 at the start of operation)
Evaporation residue concentration of mixed feed water is about 25,000 m
g / l. In addition, as the pretreatment membrane module 41
Operates a 500 mg / l NaCl solution at 0.5 MPa.
Desalination rate 85% when turned, membrane water production 1.20m Three/
(MTwo-Spiral using NF membrane with d) performance
Six mold elements are connected in series and assembled into a pressure vessel
Was used.
【0038】次いで、前処理膜モジュール41の処理水
とバイパスさせた原水とを混合させた供給水を、高圧ポ
ンプにて9.0MPaに昇圧して逆浸透膜モジュール4
2に供給し、回収率Z=0.75にて2,000時間連
続して運転を行い造水を行った。なお、逆浸透膜モジュ
ール42としては、塩濃度3.5重量%の海水を5.5
MPaで運転したときに脱塩率99.85%、膜造水量
0.75m3/(m2・d)の性能を有する逆浸透膜を用
いたスパイラル型逆浸透膜エレメントを、直列に6本接
続して圧力容器に収納したものを用いた。Next, the supply water obtained by mixing the treated water of the pretreatment membrane module 41 and the raw water that has been bypassed is pressurized to 9.0 MPa by a high-pressure pump to increase the reverse osmosis membrane module 4
2 and operated continuously for 2,000 hours at a recovery rate Z = 0.75 to produce fresh water. As the reverse osmosis membrane module 42, seawater having a salt concentration of 3.5% by weight was converted to 5.5.
Six spiral reverse osmosis membrane elements using a reverse osmosis membrane having a desalination rate of 99.85% and a water production of 0.75 m 3 / (m 2 · d) when operated at MPa. One connected and housed in a pressure vessel was used.
【0039】この結果、造水装置全体の回収率は0.6
4に達し、透過水の水質は全溶質濃度が148mg/l
と高品質であった。また、運転中は前処理膜モジュー
ル、逆浸透膜モジュールの濃縮水中に硫酸カルシウムス
ケールの析出は認められず、モジュール内の膜間差圧も
一定範囲内に収まり、バイパス量を変更する必要はなか
った。 (実施例2)図2に示す造水装置を用いて造水を行っ
た。図2において、造水装置2は、逆浸透膜装置として
逆浸透膜モジュール42、43を直列に2段接続し、前
段から得られる濃縮水を後段への供給水とするととも
に、後段から得られる濃縮水の圧力エネルギーをターボ
チャージャにて回収する構成とした。そして、前段に設
けた逆浸透膜モジュール42には、塩濃度3.5重量%
の海水を5.5MPaで運転したときに脱塩率99.8
5%、膜造水量0.7m3/(m2・d)である逆浸透膜
を用い、後段に設けた逆浸透膜モジュール43には、塩
濃度3.5重量%の海水を5.5MPaで運転したとき
に脱塩率99.85%、膜造水量0.75m 3/(m2・
d)の性能を有する逆浸透膜を用いた。その他について
は、図1に示した造水装置と同様とした。As a result, the recovery rate of the whole fresh water generator was 0.6.
4 and the quality of the permeated water is 148 mg / l
And was of high quality. During operation, the pretreatment membrane module
Calcium sulfate in concentrated water of reverse osmosis membrane module
No kale deposition was observed and the transmembrane pressure in the module
It is within a certain range and there is no need to change the bypass amount
Was. (Example 2) Fresh water was produced using the fresh water generator shown in FIG.
Was. In FIG. 2, the fresh water generator 2 is a reverse osmosis membrane device.
Reverse osmosis membrane modules 42 and 43 are connected in two stages in series,
The concentrated water obtained from the stage is used as feed water to the subsequent stage.
The pressure energy of the concentrated water obtained from the latter stage is
It was configured to be collected by a charger. And, set in the previous stage
The reverse osmosis membrane module 42 has a salt concentration of 3.5% by weight.
Desalination rate is 99.8 when the seawater is operated at 5.5 MPa.
5%, membrane water production 0.7mThree/ (MTwoA reverse osmosis membrane which is d)
The reverse osmosis membrane module 43 provided at the subsequent stage
When running 3.5 wt% seawater at 5.5 MPa
Desalination rate 99.85%, membrane water production 0.75m Three/ (MTwo・
A reverse osmosis membrane having the performance of d) was used. About other
Was the same as the fresh water generator shown in FIG.
【0040】まず、原水(塩濃度3.5重量%の海水)
を送水ポンプにて1.8MPaに昇圧して、NF膜を用
いたスパイラル型エレメントを6本直列に接続して圧力
容器に組み込んだ前処理膜モジュール41に供給し、回
収率Y=0.67で処理した。この前処理膜モジュール
41の処理水とバイパスさせた原水(運転開始時のバイ
パス量の割合X=0.7)とを混合させた供給水の蒸発
残留物濃度は約27,000mg/lであった。次い
で、この供給水を高圧ポンプにて5.0MPaに昇圧
し、前段の逆浸透膜モジュール42へ供給した。この前
段での回収率は0.55とした。次に、後段の後段逆浸
透膜モジュール43へ、前段の逆浸透膜モジュール42
で得られた濃縮水を圧力8.5MPaで供給し、回収率
0.45として2,000時間連続運転し、造水を行っ
た。前後段合わせた逆浸透膜モジュール全体の回収率Z
は0.75であった。First, raw water (seawater having a salt concentration of 3.5% by weight)
Is increased to 1.8 MPa by a water pump, and is supplied to a pretreatment membrane module 41 in which six spiral elements using an NF membrane are connected in series and incorporated into a pressure vessel, and a recovery rate Y = 0.67. Processed. The evaporation residue concentration of the supply water obtained by mixing the treated water of the pretreatment membrane module 41 with the bypassed raw water (the ratio of the bypass amount at the start of operation X = 0.7) was about 27,000 mg / l. Was. Next, the pressure of the supplied water was increased to 5.0 MPa by a high-pressure pump, and supplied to the reverse osmosis membrane module 42 in the preceding stage. The recovery rate in the former stage was set to 0.55. Next, the reverse osmosis membrane module 42 of the preceding stage is
Was supplied at a pressure of 8.5 MPa, and was continuously operated for 2,000 hours at a recovery rate of 0.45 to produce fresh water. Recovery rate Z of reverse osmosis membrane module as a whole
Was 0.75.
【0041】造水の結果、装置全体の回収率は0.67
に達し、透過水の水質は全溶質濃度が250mg/lと
高品質であった。また、運転中はいずれのモジュールに
おいても硫酸カルシウムスケールの析出は認められなか
った。 (比較例1)原水(塩濃度3.5重量%の海水)を前処
理膜モジュールに通水せず、高圧ポンプにて9.0MP
aに昇圧して、実施例1と同様の逆浸透膜モジュール4
2に直接供給し、Z=0.65として2,000時間運
転を行った。As a result of desalination, the recovery rate of the entire apparatus was 0.67.
, And the quality of the permeated water was high quality with a total solute concentration of 250 mg / l. During operation, precipitation of calcium sulfate scale was not observed in any of the modules. (Comparative Example 1) Raw water (sea water with a salt concentration of 3.5% by weight) was not passed through the pretreatment membrane module, but was 9.0MP with a high-pressure pump.
a, and the reverse osmosis membrane module 4 similar to that of Example 1
2, and operated for 2,000 hours with Z = 0.65.
【0042】その結果、運転開始から100時間経過後
には、逆浸透膜モジュール42の出口の濃縮水中に硫酸
カルシウムが析出した。さらに、運転開始から500時
間経過後、透過水質が約400mg/lに悪化したた
め、逆浸透膜モジュール中の逆浸透膜エレメントの中心
パイプに管を通し、モジュール中の各エレメントの透過
水質を測定することでエレメントの破損の有無を判断す
る中心パイプ法で検査したところ、逆浸透膜モジュール
42の入口側に配置したエレメントが破損していること
がわかった。このため、入口側の逆浸透膜エレメントを
新品に交換し、運転圧力を8.0MPa、Z=0.55
に下げて運転を再開した。 (比較例2)原水(塩濃度3.5重量%の海水)をバイ
パスさせず(X=0)に前処理膜モジュール41へ全量
供給し、かつ、Z=0.9で運転しようとした以外は、
実施例1と同様に運転を行った。しかしながら、運転開
始直後から徐々に差圧が上昇し、運転開始後200時間
で差圧が運転開始直後の2倍となったため、運転を中止
した。前処理膜モジュール中のNF膜エレメントを解体
し、膜面上の付着物を分析した結果、硫酸カルシウムの
析出が確認できた。As a result, 100 hours after the start of the operation, calcium sulfate was precipitated in the concentrated water at the outlet of the reverse osmosis membrane module 42. Further, 500 hours after the start of operation, the permeated water quality deteriorated to about 400 mg / l. Therefore, the permeated water quality of each element in the reverse osmosis membrane module was measured by passing a pipe through the center pipe of the reverse osmosis membrane element in the reverse osmosis membrane module. Inspection by the central pipe method for judging whether or not the element was damaged revealed that the element disposed on the inlet side of the reverse osmosis membrane module 42 was damaged. For this reason, the reverse osmosis membrane element on the inlet side was replaced with a new one, and the operating pressure was 8.0 MPa and Z = 0.55.
And resumed operation. (Comparative Example 2) Except that the entire amount of raw water (seawater with a salt concentration of 3.5% by weight) was supplied to the pretreatment membrane module 41 without bypassing (X = 0) and the operation was performed at Z = 0.9. Is
The operation was performed in the same manner as in Example 1. However, the differential pressure gradually increased immediately after the start of the operation, and the differential pressure became twice as large as that immediately after the start of the operation 200 hours after the start of the operation, so the operation was stopped. As a result of disassembling the NF membrane element in the pretreatment membrane module and analyzing attached matter on the membrane surface, precipitation of calcium sulfate was confirmed.
【0043】[0043]
【発明の効果】本発明によれば、前処理膜をバイパスさ
せた原水と、前処理膜により処理した処理水とを混合し
て逆浸透膜に供給するので、前処理膜や逆浸透膜に過度
の負担をかけることなく原水の分離を行うことができ、
透過水の水質を高く保ったまま、高回収率で透過水を得
ることができる。According to the present invention, raw water bypassing the pretreatment membrane and treated water treated by the pretreatment membrane are mixed and supplied to the reverse osmosis membrane. Raw water can be separated without imposing excessive burden,
The permeated water can be obtained at a high recovery rate while keeping the quality of the permeated water high.
【0044】また、逆浸透膜に供給する処理水の供給圧
力、逆浸透膜に供給する処理水の供給圧力と逆浸透膜か
ら得られる濃縮水の圧力との差圧、逆浸透膜から得られ
る透過水の水質、および、逆浸透膜から得られる透過水
の流量からなる群から選ばれる少なくとも1つの状態を
測定し、測定された値があらかじめ定めた範囲を超えた
場合に、前記測定された値に基づいて前処理膜をバイパ
スさせる原水の割合を制御すれば、原水の性状に合わせ
た運転条件や膜の劣化状況に合わせた運転条件を設定す
ることができるので、より回収率を高めることができ
る。The supply pressure of the treated water supplied to the reverse osmosis membrane, the pressure difference between the supply pressure of the treated water supplied to the reverse osmosis membrane and the pressure of the concentrated water obtained from the reverse osmosis membrane, and the pressure obtained from the reverse osmosis membrane The quality of the permeated water, and at least one state selected from the group consisting of the flow rate of the permeated water obtained from the reverse osmosis membrane is measured, and when the measured value exceeds a predetermined range, the measured value is measured. By controlling the ratio of raw water that bypasses the pretreatment membrane based on the value, it is possible to set operating conditions that match the properties of the raw water and operating conditions that match the state of deterioration of the membrane, thus further improving the recovery rate. Can be.
【図1】 本発明の一実施態様に係る造水装置を示す概
略図である。FIG. 1 is a schematic diagram showing a fresh water generator according to one embodiment of the present invention.
【図2】 実施例において用いた造水装置を示す概略図
である。FIG. 2 is a schematic diagram showing a fresh water generator used in an example.
1:造水装置 2:造水装置 11:原水流路 21:取水ポンプ 22:送水ポンプ 23:高圧ポンプ 32:バイパス流路 41:前処理膜モジュール(前処理膜装置) 42:逆浸透膜モジュール(逆浸透膜装置) 43:逆浸透膜モジュール(逆浸透膜装置) 51:非透過水流路 52:濃縮水流路 61:処理水流路 62:透過水流路 70:回収タービン 71:ターボチャージャ 81:バルブ(流量制御手段) 91:圧力計(圧力測定手段) 92:差圧計(差圧測定手段) 93:水質計(水質測定手段) 94:流量計(流量測定手段) 100:制御装置 1: fresh water generator 2: fresh water generator 11: raw water flow path 21: water intake pump 22: water supply pump 23: high pressure pump 32: bypass flow path 41: pretreatment membrane module (pretreatment membrane device) 42: reverse osmosis membrane module (Reverse osmosis membrane device) 43: Reverse osmosis membrane module (reverse osmosis membrane device) 51: Non-permeated water channel 52: Concentrated water channel 61: Treated water channel 62: Permeated water channel 70: Recovery turbine 71: Turbocharger 81: Valve (Flow control means) 91: Pressure gauge (pressure measuring means) 92: Differential pressure gauge (Differential pressure measuring means) 93: Water quality meter (Water quality measuring means) 94: Flow meter (Flow rate measuring means) 100: Control device
───────────────────────────────────────────────────── フロントページの続き Fターム(参考) 4D006 GA03 GA07 HA01 HA41 KA52 KA53 KA56 KA57 KE01P KE01Q KE01R KE06P KE06Q KE30P MA01 MA03 MA06 MB07 MC18 MC33 MC54 MC63 PB03 ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 4D006 GA03 GA07 HA01 HA41 KA52 KA53 KA56 KA57 KE01P KE01Q KE01R KE06P KE06Q KE30P MA01 MA03 MA06 MB07 MC18 MC33 MC54 MC63 PB03
Claims (5)
浸透膜に供給して透過水と濃縮水とを得るに際し、原水
の一部を前処理膜をバイパスさせて逆浸透膜に供給する
ことを特徴とする造水方法。When the treated water obtained by supplying raw water to a pretreatment membrane is supplied to a reverse osmosis membrane to obtain permeated water and concentrated water, a part of the raw water is passed through the pretreatment membrane to perform reverse osmosis. A fresh water producing method characterized by supplying to a membrane.
浸透膜に供給する処理水の供給圧力と逆浸透膜から得ら
れる濃縮水の圧力との差圧、逆浸透膜から得られる透過
水の水質、および、逆浸透膜から得られる透過水の流量
からなる群から選ばれる少なくとも1つを測定し、測定
された値があらかじめ定めた範囲を超えた場合に、前記
測定された値に基づいて前処理膜をバイパスさせる原水
の割合を制御する、請求項1に記載の造水方法。2. The supply pressure of the treated water supplied to the reverse osmosis membrane, the pressure difference between the supply pressure of the treated water supplied to the reverse osmosis membrane and the pressure of the concentrated water obtained from the reverse osmosis membrane, and the pressure obtained from the reverse osmosis membrane. The quality of the permeated water, and at least one selected from the group consisting of the flow rate of the permeated water obtained from the reverse osmosis membrane is measured, and when the measured value exceeds a predetermined range, the measured value The fresh water producing method according to claim 1, wherein a ratio of raw water for bypassing the pretreatment membrane is controlled based on the condition.
とし、前処理膜における回収率をYとし、逆浸透膜にお
ける回収率をZとしたとき、X、YおよびZが次式
(1)〜(3)を同時に満足するように前処理膜をバイ
パスさせる原水の割合を制御する、請求項1または2に
記載の造水方法。 0.6≦Y<1 (1) 0.6<Z≦0.8 (2) 0.6≦(X+(1−X)Y)Z (3)3. The ratio of raw water that bypasses the pretreatment membrane is X
When the recovery rate in the pretreatment membrane is Y and the recovery rate in the reverse osmosis membrane is Z, the pretreatment membrane is bypassed so that X, Y and Z simultaneously satisfy the following equations (1) to (3). The fresh water producing method according to claim 1, wherein a ratio of raw water to be produced is controlled. 0.6 ≦ Y <1 (1) 0.6 <Z ≦ 0.8 (2) 0.6 ≦ (X + (1-X) Y) Z (3)
処理膜装置と、この前処理膜装置に対して原水をバイパ
スさせるバイパス流路と、このバイパス流路に設けた流
量制御手段と、前記前処理膜装置から得られる処理水を
透過水と濃縮水とに分離する、逆浸透膜を有する逆浸透
膜装置と、逆浸透膜装置への供給水圧力を測定する圧力
測定手段、逆浸透膜装置への供給水圧力と濃縮水圧力と
の差圧を測定する差圧測定手段、逆浸透膜装置から得ら
れる透過水の水質を測定する水質測定手段、および、逆
浸透膜装置から得られる透過水の流量を測定する流量測
定手段からなる群から選ばれる少なくとも1つの測定手
段と、この測定手段により測定された値に基づいて前記
流量制御手段を制御する制御装置とを備えていることを
特徴とする造水装置。4. A pretreatment membrane device having a pretreatment membrane for treating raw water, a bypass flow passage for bypassing raw water to the pretreatment membrane device, and a flow control means provided in the bypass flow passage. A reverse osmosis membrane device having a reverse osmosis membrane, which separates treated water obtained from the pretreatment membrane device into permeated water and concentrated water, and a pressure measuring means for measuring a pressure of water supplied to the reverse osmosis membrane device; Differential pressure measuring means for measuring the pressure difference between the supply water pressure and the concentrated water pressure to the osmosis membrane device, water quality measurement means for measuring the quality of the permeated water obtained from the reverse osmosis membrane device, and obtained from the reverse osmosis membrane device At least one measuring means selected from the group consisting of flow rate measuring means for measuring the flow rate of permeated water to be supplied, and a control device for controlling the flow rate controlling means based on a value measured by the measuring means. Features of fresh water .
法、または、請求項4に記載の造水装置により得られた
水。5. The water obtained by the method for producing fresh water according to claim 1 or the water producing apparatus according to claim 4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001207607A JP2002085941A (en) | 2000-07-13 | 2001-07-09 | Fresh water making process and fresh water maker |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000212387 | 2000-07-13 | ||
| JP2000-212387 | 2000-07-13 | ||
| JP2001207607A JP2002085941A (en) | 2000-07-13 | 2001-07-09 | Fresh water making process and fresh water maker |
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| Publication Number | Publication Date |
|---|---|
| JP2002085941A true JP2002085941A (en) | 2002-03-26 |
Family
ID=26595940
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001207607A Pending JP2002085941A (en) | 2000-07-13 | 2001-07-09 | Fresh water making process and fresh water maker |
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| Country | Link |
|---|---|
| JP (1) | JP2002085941A (en) |
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