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JP2001305271A - Repair method for in-furnace equipment for nuclear power plants - Google Patents

Repair method for in-furnace equipment for nuclear power plants

Info

Publication number
JP2001305271A
JP2001305271A JP2000122089A JP2000122089A JP2001305271A JP 2001305271 A JP2001305271 A JP 2001305271A JP 2000122089 A JP2000122089 A JP 2000122089A JP 2000122089 A JP2000122089 A JP 2000122089A JP 2001305271 A JP2001305271 A JP 2001305271A
Authority
JP
Japan
Prior art keywords
repair
repaired
nuclear power
heating
furnace equipment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000122089A
Other languages
Japanese (ja)
Inventor
Yuji Yasuda
祐司 安田
Masako Nakabashi
昌子 中橋
Yasuo Morishima
康雄 森島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp filed Critical Toshiba Corp
Priority to JP2000122089A priority Critical patent/JP2001305271A/en
Publication of JP2001305271A publication Critical patent/JP2001305271A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00Energy generation of nuclear origin
    • Y02E30/30Nuclear fission reactors

Landscapes

  • Coating By Spraying Or Casting (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

PROBLEM TO BE SOLVED: To shorten the term of work by repairing a part in the atmosphere on the site without bringing the item to be repaired from the site into factory. SOLUTION: When a part to be repaired such as cracks, defect or the like is detected in an item to be repaired, the inner part of the crack or defect is filled with a brazing filler metal and heated to braze it, and the brazed part is covered with, for example, stainless steel by flame spraying or low heat input welding. This repairing method comprises the following processes: the process (a) of removing the surface deteriorated layer of the part to be repaired, the process b of placing a mixture of an alloy powder and an antioxidant (flux) on the repairing part, the process (c) of melting the alloy powder by heating, the process (d) of filling the molten alloy to the defect part, the process (e) of coagulating the alloy in the defect part, and the process (f) of removing the residue.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、原子炉内機器など
の高耐食性部材を簡便な方法で部分補修することができ
る原子力発電プラント用炉内機器の補修方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for repairing in-core equipment for a nuclear power plant, which can partially repair highly corrosion-resistant members such as in-reactor equipment by a simple method.

【0002】[0002]

【従来の技術】原子力発電プラントの原子炉内機器とし
ては、図4に示すように原子炉圧力容器1内に設置され
たシュラウド2,ジェットポンプ3,制御棒案内管4,
炉心スプレー5等がある。制御棒案内管4は制御棒駆動
機構6の一部を構成している。これらの機器は高温,高
圧水環境下で使用される重要機器であるため、きわめて
高い品質が要求され、高耐食性を有するオーステナイト
系ステンレス鋼が使用されている。
2. Description of the Related Art As equipment in a nuclear power plant, as shown in FIG. 4, a shroud 2 installed in a reactor pressure vessel 1, a jet pump 3, a control rod guide tube 4,
Core spray 5 and the like. The control rod guide tube 4 constitutes a part of the control rod drive mechanism 6. Since these devices are important devices used in a high-temperature, high-pressure water environment, extremely high quality is required, and austenitic stainless steel having high corrosion resistance is used.

【0003】近年、プラントの高経年化が叫ばれてお
り、特に応力腐食割れ(SCC)等による不適合が生じた
場合の低コストでかつ簡易な補修技術を予め確立してお
く必要がある。従来の補修方法は、欠陥部を完全に除去
して再溶接を行うか、またはその欠陥機器,部品の全面
交換により対応しているのが主体である。
In recent years, aging of the plant has been called for, and it is necessary to establish in advance a low-cost and simple repair technique especially when an incompatibility due to stress corrosion cracking (SCC) or the like occurs. The conventional repair method mainly responds by completely removing the defective portion and performing re-welding or by completely replacing the defective device or part.

【0004】[0004]

【発明が解決しようとする課題】上述した従来の補修方
法においては、原子炉圧力容器1内に設置されている炉
内機器であることから、限られた作業空間で、極めて作
業環境が悪く、しかも多大な労力を必要とするなど、作
業性を改善しなければならない課題がある。
In the conventional repair method described above, since the equipment in the reactor is installed in the reactor pressure vessel 1, the working environment is extremely poor in a limited working space. Moreover, there is a problem that the workability must be improved, such as requiring a great deal of labor.

【0005】また、従来ガスタービン高温部品で行われ
ていた、基材をほとんど溶融しない方法であるろう付け
補修方法を適用する場合には、真空または不活性ガス中
での加熱処理が必要であり、取り外しの困難な大型部品
や外部に運び出すことが制約されている機器,部品の現
地補修が困難となる課題がある。
In addition, when a brazing repair method, which is a method that hardly melts a base material, which is conventionally performed on high-temperature components of a gas turbine, is applied, heat treatment in a vacuum or an inert gas is required. In addition, there is a problem that it is difficult to locally repair large components that are difficult to remove and devices and components that are restricted from being carried out.

【0006】本発明は上記課題を解決するためになされ
たものであり、部品を工場に持ち込むことなく、現地で
効率的で容易に欠陥を部分補修することができる原子力
発電プラント用炉内機器の補修方法を提供することを目
的とする。
SUMMARY OF THE INVENTION The present invention has been made to solve the above-mentioned problems, and an object of the present invention is to provide an in-core equipment for a nuclear power plant which can efficiently and easily repair a defect locally without bringing parts into a factory. The purpose is to provide a repair method.

【0007】[0007]

【課題を解決するための手段】上記目的を達成するため
の本発明に係る原子力発電プラント用炉内機器の補修方
法は、補修部の表面層を除去する工程と、前記補修部の
補修面に構造部材より融点の低いろう材合金粉末と酸化
防止剤としてのフラックスの複合体からなる補修材を密
着する混合物密着工程と、前記ろう材合金を加熱溶融し
て前記補修部に充填する合金融液充填工程と、この合金
融液充填後に残余物を除去する残余物除去工程とを有す
ることを特徴とする。
According to the present invention, there is provided a method for repairing an in-core device for a nuclear power plant, comprising the steps of: removing a surface layer of a repair portion; A mixture adhesion step of closely adhering a repair material comprising a composite of a brazing alloy powder having a lower melting point than a structural member and a flux as an antioxidant, and a synthetic liquid for heating and melting the brazing alloy and filling the repair portion. It is characterized by having a filling step and a residue removing step of removing a residue after filling the combined liquid.

【0008】なお、本発明方法においては、補修材密着
の前にフラックスのみを補修面に塗布する工程を含んで
もよく、また、補修後に、補修面を機械的に平滑化する
工程、あるいは、補修面に若干厚さの高耐食層を溶射
法,レーザ溶接法,低入熱TIG溶接法,低入熱PTA法によ
り被覆する工程を加えることもできる。溶射の場合は、
溶射後に、溶射のフレームなどにより加熱して溶射層を
緻密化する工程を加えることもできる。
The method of the present invention may include a step of applying only flux to the repair surface before the repair material adheres, or a step of mechanically smoothing the repair surface after the repair, or It is also possible to add a step of coating a slightly thick highly corrosion-resistant layer on the surface by thermal spraying, laser welding, low heat input TIG welding, or low heat input PTA. In the case of thermal spraying,
After the thermal spraying, a step of heating the thermal spraying frame or the like to densify the thermal sprayed layer may be added.

【0009】補修材は、合金粉末,フラックス,有機バ
インダーが溶剤で混練されたペースト状であってもよ
い。また、該合金粉末は、Au,Pt,Pd,Ag,Ni,Cu,C
o,Fe,Cr,P,Si,B,Mnから選ばれる成分の合金あ
るいはそれらの混合粉末からなる。前記フラックスはほ
う酸,ほう酸塩,フッ化物から選択されたものからな
る。
The repair material may be a paste in which alloy powder, flux, and an organic binder are kneaded with a solvent. The alloy powder is composed of Au, Pt, Pd, Ag, Ni, Cu, C
It is composed of an alloy of components selected from o, Fe, Cr, P, Si, B, and Mn, or a mixed powder thereof. The flux comprises one selected from boric acid, borate and fluoride.

【0010】加熱工程としては、高周波加熱,赤外線集
光加熱,レーザ加熱などによる局部加熱が適している。
加熱雰囲気は特に限定されていないが、大気、あるいは
不活性ガスの吹き付け雰囲気で可能である。
As the heating step, local heating such as high-frequency heating, infrared ray condensing heating, laser heating or the like is suitable.
The heating atmosphere is not particularly limited, but may be air or an inert gas blowing atmosphere.

【0011】本発明の補修方法においては、補修材の合
金粉末を加熱により溶融して、その融液を構造材補修部
の欠陥部に流れ込ませて充填する。すなわち、予め、使
用中に生成した補修部の酸化物層などの変質層を除去す
ることで、補修表面への合金融液の濡れ広がりの阻害が
抑制できる。
In the repair method of the present invention, an alloy powder of the repair material is melted by heating, and the melt flows into a defective portion of the repair portion of the structural material to be filled. In other words, by previously removing the deteriorated layer such as the oxide layer of the repaired portion generated during use, it is possible to suppress the inhibition of the spread of the synthetic liquid on the repaired surface.

【0012】フラックスの作用で、合金の加熱溶融時
に、合金融液の濡れ性を阻害する新たな酸化層形成が防
止され、したがって、良好に欠陥部に合金融液が流れ込
み充填するものである。濡れ性は、例えば合金液滴と基
材との接触角度が、鋭角を示すものを選択することで、
融液が欠陥部に良好に濡れて、自然に浸透ないしは流れ
込み充填する。
By the action of the flux, the formation of a new oxide layer which hinders the wettability of the composite liquid during the heating and melting of the alloy is prevented, and therefore the defective liquid flows and fills the defective portion satisfactorily. The wettability, for example, the contact angle between the alloy droplet and the substrate, by selecting those that show an acute angle,
The melt wets the defect well and naturally penetrates or flows and fills.

【0013】凝固後に耐摩耗部材と良好に接合する必要
があるため、合金は耐摩耗部材と密着性のよい成分から
なる合金から選ばれる必要がある。そのような成分とし
て、例えばAu,Pt,Pd,Ag,Ni,Cu,Co,Fe,Cr,P,
Si,B,Mnなどから主成分が選ばれる合金が挙げられ
る。
[0013] Since it is necessary to bond well with the wear-resistant member after solidification, the alloy must be selected from alloys composed of components having good adhesion to the wear-resistant member. Such components include, for example, Au, Pt, Pd, Ag, Ni, Cu, Co, Fe, Cr, P,
An alloy whose main component is selected from Si, B, Mn, and the like can be given.

【0014】具体的には、例えばPt,Au−Cu,Au−Ni,
Au−Ni−Cr,Au−Pd−Cu,Au−Pd−Ni,Au−Pd−Mn,Pd
−Ni−Mn,Pd−Ag−Cu,Ag−Pd−In,Ag−Al.Pd−Ni,
M−Cr−Si−B,M−Cr−Si,M−Si,M−Si−B,M
−P,M−Si−B(M:Ni,Co,Feのうちから選ばれる
成分)、等を主成分とする合金が挙げられる。
Specifically, for example, Pt, Au-Cu, Au-Ni,
Au-Ni-Cr, Au-Pd-Cu, Au-Pd-Ni, Au-Pd-Mn, Pd
-Ni-Mn, Pd-Ag-Cu, Ag-Pd-In, Ag-Al. Pd-Ni,
M-Cr-Si-B, M-Cr-Si, M-Si, M-Si-B, M
An alloy mainly containing -P, M-Si-B (M: a component selected from Ni, Co, and Fe) and the like can be given.

【0015】合金は、粉末形状であると熱が入り易く、
したがって溶融し易く、また、後述のフラックスとも混
合し易い。粉末粒径は特に問わないが、あまり細かい微
粒子は、表面積が大きく、酸化し易くなるため、数μm
から数10μm、大きくとも100μm台の径が適当であ
る。
[0015] When the alloy is in powder form, it is easy for heat to enter,
Therefore, it is easily melted and easily mixed with a flux described later. Although the particle size of the powder is not particularly limited, very fine particles have a large surface area and are easily oxidized.
A diameter of several tens μm to 100 μm is suitable.

【0016】補修材を補修部に密着する場合、補修材を
加熱時まで仮固定することで、補修材の分散が防止でき
作業性が向上する。そのため、補修材は、合金粉末,フ
ラックス,有機バインダーを溶剤で混練してペースト状
にすることで補修部に良好に固定できる。さらに酸化を
よりよく抑制するために、補修材密着の前にフラックス
をそのまま、または、バインダー、溶剤あるいは溶剤と
バインダーを混練して補修面に塗布する工程を含んでも
よい。
When the repair material is in close contact with the repaired portion, the repair material is temporarily fixed until heating, thereby preventing the dispersion of the repair material and improving the workability. Therefore, the repair material can be satisfactorily fixed to the repair portion by kneading the alloy powder, the flux, and the organic binder with a solvent to form a paste. In order to further suppress oxidation, the method may include a step of applying the flux as it is, or a binder, a solvent, or a mixture of a solvent and a binder and applying the flux to the repair surface before the repair material adheres.

【0017】フラックスは、酸化防止剤として、前記各
合金の融点近傍で効力を発揮する、ほう酸,ほう酸塩,
フッ化物を含むものが挙げられる。合金粉末と酸化防止
剤との混合比率は、適宜決められるが、目安として、合
金粉末に対して容量で数%から100%程度がよい。あま
り少ないと酸化防止効果が少なく、多すぎると合金粉末
の割合が少なくなり、補修能力が低下する。
The flux is effective as an antioxidant near the melting point of each of the above-mentioned alloys.
Those containing fluoride are exemplified. The mixing ratio between the alloy powder and the antioxidant is determined as appropriate, but as a guide, it is preferable that the volume is about several percent to 100% of the alloy powder. If the amount is too small, the antioxidant effect is small, and if the amount is too large, the ratio of the alloy powder is reduced, and the repair ability is reduced.

【0018】有機バインダーとの混合比率は、用いる有
機バインダーの粘性との関連で決められるが、補修材と
して密着する時に、流れすぎず、また固すぎない状態が
得られるように決めることで作業性が良くなる。
The mixing ratio with the organic binder is determined in relation to the viscosity of the organic binder to be used. However, when the adhesive is used as a repair material, it is determined that a state in which it does not flow too much and is not too hard is obtained. Will be better.

【0019】表面層の除去方法は特に限定することはな
いが、脱酸機能の薬品を用いても良いが、それら薬品の
除去が難しい環境である場合、研磨,ブラストなどの機
械的方法によることが薬品の残留がないので有利であ
る。
The method of removing the surface layer is not particularly limited, and a chemical having a deoxidizing function may be used. However, in an environment where it is difficult to remove such a chemical, a mechanical method such as polishing or blasting may be used. Is advantageous because there is no chemical residue.

【0020】加熱工程も特に限定することもないが、耐
摩耗部材を取り外すことに多大な労力を要する部材に対
する現地での作業を考慮すると、小型で簡易的な装置で
加熱の可能な高周波加熱,赤外線集光加熱,レーザ加熱
(特に半導体レーザなど簡易的なもの)による局部加熱
が有利である。
Although there is no particular limitation on the heating process, considering the on-site work on members that require a great deal of labor to remove the wear-resistant members, high-frequency heating, which can be heated by a small and simple device, Local heating by infrared condensing heating and laser heating (especially a simple one such as a semiconductor laser) is advantageous.

【0021】これらの装置は、また、基材に熱影響を与
えず、補修材と補修部近傍を重点的に加熱するために、
局部加熱の可能なエネルギ密度が高く、かつ温度制御性
の良い加熱源が望ましい観点からも有利である。
In addition, these devices do not have a thermal effect on the base material, and mainly heat the repair material and the vicinity of the repair portion.
It is also advantageous from the viewpoint that a heating source with high energy density capable of local heating and good temperature controllability is desirable.

【0022】加熱温度は、補修材の合金が溶融する温度
以上で、通常、該合金の融点の50℃から100℃以上の温
度が好ましい。あまり低いと、欠陥部に十分に充填し難
く、あまり高いと部材の形成されている基材への熱影響
が大きくなる。加熱時間も特に問わないが、基本的に
は、補修材の合金が溶融し、補修面も加熱され合金融液
が補修面を十分流れる時間保持すればよい。
The heating temperature is equal to or higher than the temperature at which the repair material alloy melts, and is usually preferably from 50 ° C. to 100 ° C., which is the melting point of the alloy. If the temperature is too low, it is difficult to sufficiently fill the defective portion, and if the temperature is too high, the thermal influence on the base material on which the member is formed increases. The heating time is not particularly limited, but basically, it is sufficient that the alloy of the repair material is melted, the repair surface is also heated, and a period in which the synthesizing liquid sufficiently flows through the repair surface is maintained.

【0023】具体的には、数分間から長くても数10分間
で十分である。その間、補修部の温度が極端に上下しな
いように一定に保持する必要がある。そのための温度制
御機構を有する装置を備える加熱装置、すなわち温度検
出装置と温度保持装置等を備える装置を用いることが望
ましい。
Specifically, several minutes to at most several tens of minutes is sufficient. During that time, it is necessary to keep the temperature of the repaired part constant so that it does not extremely rise and fall. For this purpose, it is desirable to use a heating device including a device having a temperature control mechanism, that is, a device including a temperature detection device and a temperature holding device.

【0024】補修雰囲気が清浄であることは好ましい
が、完全な雰囲気場を達成することが困難な環境で、大
気中あるいは不活性ガスの吹き付け雰囲気でも、酸化防
止剤の作用により十分効果が得られる。
It is preferable that the repair atmosphere is clean, but in an environment where it is difficult to achieve a perfect atmosphere, even in the air or in a blown atmosphere of an inert gas, a sufficient effect can be obtained by the action of the antioxidant. .

【0025】また、補修部は、その後の使用に耐えるた
め、凝固後に部材と良好に接合される必要がある。した
がって、一般に広く使用されるオーステナイト系ステン
レス鋼と濡れ性が良く接合性に優れる合金として、例え
ばAu,Pt,Pd,Ag,Ni,Cu,Co,Fe,Cr,P,Si,B,
Mnなどから選ばれる合金,合金粉末が挙げられる。
In addition, the repaired portion needs to be properly joined to the member after solidification in order to withstand subsequent use. Therefore, as an alloy having good wettability and excellent bondability with generally widely used austenitic stainless steels, for example, Au, Pt, Pd, Ag, Ni, Cu, Co, Fe, Cr, P, Si, B,
Alloys and alloy powders selected from Mn and the like are listed.

【0026】特に、原子力用途であるため、Au,Pt,P
d,Ni,Co,Cr,P,Siから主成分が選ばれる合金,合
金粉末であることが望ましい。例えばAu−Ni,Au−Ni−
Cr,Au−Pd−Cu,Au−Pd−Ni,Au−Pd−Mn,Pd−Ni,Pd
−Ni−Mn,Pd−Ag−Cu,Ag−Pd−In,Ag−Al,M−Cr−
Si,M−Si,M−P,(M:Ni,Co,Feのうちから選ば
れる成分)などを主成分とする合金が挙げられる。
In particular, for nuclear applications, Au, Pt, P
An alloy or an alloy powder whose main component is selected from d, Ni, Co, Cr, P and Si is desirable. For example, Au-Ni, Au-Ni-
Cr, Au-Pd-Cu, Au-Pd-Ni, Au-Pd-Mn, Pd-Ni, Pd
-Ni-Mn, Pd-Ag-Cu, Ag-Pd-In, Ag-Al, M-Cr-
Alloys containing Si, M-Si, MP, (M: a component selected from Ni, Co and Fe) as a main component are exemplified.

【0027】補修後、欠陥は補修材により強固に充填さ
れ、クラックや減肉部などの欠陥からの流体の漏れなど
もなく、さらなる使用が可能である。また、基材をほと
んど溶融しないため、局部的に残留応力が残ることも少
ない。また、機器,部品を全面的に除去する必要がない
ため、労力が大幅に低減できる。
After the repair, the defect is firmly filled with the repair material, and there is no leakage of fluid from a defect such as a crack or a thinned portion, so that the defect can be further used. Further, since the base material is hardly melted, residual stress is hardly left locally. Further, since it is not necessary to completely remove devices and components, labor can be greatly reduced.

【0028】補修部は、補修状態のままでの使用には差
し支えない。しかしながら、さらに、高耐食性を確保す
るために、補修面にさらに高耐食部材を溶射により被覆
形成してもよい。溶射方法を用いると、基材を溶融する
ことなく、高耐食層を形成することが可能であり、基材
への影響は僅少である。
The repair part may be used in the repair state. However, in order to further secure high corrosion resistance, a high corrosion resistant member may be further formed on the repaired surface by thermal spraying. When a thermal spraying method is used, a high corrosion resistant layer can be formed without melting the base material, and the influence on the base material is small.

【0029】溶射方法としては、雰囲気容器を必要とし
ない方法であれば特に限定しないが、高速ガス炎溶射
(HVOF=High Velocity Oxygen Fuel)法が化合物の
分解が少ないため適しているが、溶射ガンが小型で扱い
易い大気中プラズマ溶射(APS=Atmosphere Plasma S
pray)法も簡便でよい。溶射皮膜の密着性は大きくない
ので、溶射後、ガス炎やプラズマアークを照射,加熱し
て緻密化して、密着性の向上を図ることが望ましい。
The thermal spraying method is not particularly limited as long as it does not require an atmosphere container. A high-speed gas flame thermal spraying (HVOF) method is suitable because the decomposition of the compound is small, but a thermal spray gun is used. Plasma spray (APS = Atmosphere Plasma S)
The pray) method is also simple and convenient. Since the adhesion of the thermal sprayed coating is not large, it is desirable to improve the adhesion by spraying and heating a gas flame or a plasma arc after the thermal spraying to densify the coating.

【0030】溶射する高耐食材料の種類としては、補修
した部材の共材(オーステナイト系ステンレス鋼)や同
等材を被覆すればよい。さらに、補修後にステンレス鋼
の成分偏析などの可能性に対処するため、適切な加熱を
行い、成分の均質化を施し、局部的成分偏析を分散させ
ることにより、使用時の欠陥発生を低減することができ
る。
As the type of the high corrosion resistant material to be sprayed, the repaired member may be coated with a common material (austenitic stainless steel) or an equivalent material. Furthermore, in order to deal with the possibility of component segregation of stainless steel after repair, appropriate heating is applied, components are homogenized, and local component segregation is dispersed to reduce the occurrence of defects during use. Can be.

【0031】溶射法以外は、なるべく入熱を抑えること
の可能な溶接方法により、オーステナイト系ステンレス
鋼等の高耐食部材を被覆形成することも可能である。こ
の場合の溶接方法としては、レーザ溶接,PTA溶接,TIG
溶接等が挙げられる。また、部材が原子力発電プラント
用炉内機器であるため、取り外しの補修は非常に困難で
あり、本発明に係る補修方法は特に有効となる。
Other than the thermal spraying method, it is also possible to coat a highly corrosion-resistant member such as austenitic stainless steel by a welding method capable of suppressing heat input as much as possible. Laser welding, PTA welding, TIG
Welding and the like. Further, since the member is an in-furnace device for a nuclear power plant, repair for removal is very difficult, and the repair method according to the present invention is particularly effective.

【0032】[0032]

【発明の実施の形態】図1及び図2により本発明に係る
原子力発電プラント用炉内機器の補修方法の第1の実施
の形態を説明する。図1は本実施の形態に係る方法の工
程図、図2は本実施の形態による補修後の2例を示す断
面写真図である。本実施の形態は図1に示したように補
修部の表面変質層工程a,補修部に合金粉末と酸化防止
剤(フラックス)の混合物密着工程b,加熱により合金
溶融工程c,欠陥部に合金融液充填工程d,欠陥部に合
金を凝固する工程e及び残余物除去工程fとからなって
いる。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS A first embodiment of a method for repairing in-core equipment for a nuclear power plant according to the present invention will be described with reference to FIGS. FIG. 1 is a process diagram of a method according to the present embodiment, and FIG. 2 is a cross-sectional photograph showing two examples after repair according to the present embodiment. In this embodiment, as shown in FIG. 1, the repaired portion has a surface-altered layer process a, the repaired portion has a process of adhering a mixture of an alloy powder and an antioxidant (flux), the heating process has an alloy melting process c, and the repaired portion has a defective portion. It comprises a finance liquid filling step d, a step e for solidifying the alloy in the defective part, and a residue removal step f.

【0033】すなわち、aの工程では、まず補修を必要
とする補修部の表面をエタノールなどの有機溶剤を用い
て脱脂洗浄した後、表面の変質層を除去する。表面の酸
化物層などの変質層が厚い場合は、グラインダなどを用
いてそれらを研磨,除去し金属面を現出させる。特に、
割れ,欠陥等に対しては、欠陥部分を深さ方向に逆三角
形状に除去すると補修がし易くなる。つぎに、bの工程
に移り、補修部の表面に補修材を例えば載置したり、添
着したり等して密着する。用いる補修材は、表1に示す
ろう材合金などから選ばれる材料とフラックスの複合物
である。それらは、積層体や粉末の混合体などである。
粉末の混合体は、分散し易いので、有機バインダーと溶
剤(有機物系や水系)と混練してペースト状にして用い
ると補修材が飛散し難く施工し易い。
That is, in the step (a), first, the surface of the repaired part requiring repair is degreased and washed using an organic solvent such as ethanol, and then the altered layer on the surface is removed. If the altered layer such as an oxide layer on the surface is thick, it is polished and removed using a grinder or the like to reveal a metal surface. In particular,
For cracks, defects, and the like, repair can be easily performed by removing the defective portion in an inverted triangular shape in the depth direction. Next, the process proceeds to step b, and the repair material is closely attached to the surface of the repair portion by, for example, placing or attaching the repair material. The repair material used is a composite of a material and a flux selected from brazing alloys and the like shown in Table 1. They are laminates, powder mixtures, and the like.
Since the mixture of powders is easily dispersed, if the mixture is kneaded with an organic binder and a solvent (organic or aqueous) and used as a paste, the repair material is less likely to be scattered and is easy to construct.

【0034】つぎに、cの工程に移り、補修材のろう材
合金の融点以上に加熱可能なヒータ、例えば赤外線集光
ヒータ,高周波加熱ヒータ,レーザなどを用いて大気中
で補修面の補修材を加熱,溶融した後、dの工程に移
り、補修部の欠陥部にろう材融液を充填させる。つぎに
eの工程に移り、欠陥部に合金を凝固させ、冷却後、f
の工程に移り、フラックスの残りなどの残余物を、水や
エタノールなどの溶剤により除去する。これにより補修
部の欠陥部の補修は完了する。
Next, the process proceeds to step c, and the repair material for the repair surface is repaired in the atmosphere using a heater capable of heating to a temperature equal to or higher than the melting point of the brazing filler metal alloy as the repair material, for example, an infrared ray condensing heater, a high-frequency heater, or a laser. Is heated and melted, and then the process proceeds to step d, in which the defective portion of the repaired portion is filled with the brazing filler metal melt. Next, the process proceeds to step e, where the alloy is solidified at the defective portion, and after cooling, f
Then, the residue such as the residue of the flux is removed with a solvent such as water or ethanol. Thus, the repair of the defective portion of the repair section is completed.

【0035】[0035]

【表1】 [Table 1]

【0036】つぎに第1の実施の形態の具体的実施例を
説明する。 (実施例1)補修部となるオーステナイト系ステンレス
鋼基材に欠陥部として人工的に設けた幅0.15mm,深さ0.
5mm(例1と記す)及び幅0.02mm,深さ0.3mm(例2と記
す)の2種類の溝状欠陥を用いて本補修方法の有効性を
確認した。補修材として15wt%Cr−11P−残部Niからな
るろう材の粉末、粒径約10μmから44μmの粉末を用い
て、ほう酸を主成分とするフラックスと容積比で3:1
に混合した。
Next, a specific example of the first embodiment will be described. (Example 1) A width of 0.15 mm and a depth of 0.15 mm were artificially provided as defects on an austenitic stainless steel base material to be repaired.
The effectiveness of the repair method was confirmed using two types of groove-like defects having a width of 5 mm (described as Example 1), a width of 0.02 mm, and a depth of 0.3 mm (described as Example 2). As a repair material, a brazing filler metal powder composed of 15 wt% Cr-11P and the balance of Ni, a powder having a particle size of about 10 μm to 44 μm, and a volume ratio of 3: 1 with a flux containing boric acid as a main component.
Was mixed.

【0037】その後、適量の水系溶剤とバインダーとを
混合して、耳たぶ状の硬さに混練して補修材とした。こ
の補修材をパレットを用いて補修面に厚さ約1mmに載置
して密着した。つぎに、ドライヤーにより溶剤を蒸発さ
せ、固化した。その後、本ろう材の融点約880℃より100
℃高い980℃まで赤外線集光ヒータを用いて補修部表面
を加熱した。ろう材は、酸化することなく溶融して補修
部に塗れ広がった。
Thereafter, an appropriate amount of an aqueous solvent and a binder were mixed and kneaded to an earlobe-like hardness to obtain a repair material. The repair material was placed on a repair surface with a thickness of about 1 mm using a pallet and was brought into close contact with the repair surface. Next, the solvent was evaporated by a dryer and solidified. After that, the melting point of the brazing material is about 100
The surface of the repaired part was heated up to 980 ° C, which is higher by ℃, using an infrared focusing heater. The brazing material melted without being oxidized and spread over the repaired part.

【0038】補修後、これらの模擬欠陥の断面を切断研
磨して光学顕微鏡で観察した結果、人工欠陥はいずれも
完全にろう材で充填されており、ボイドなどの欠陥は残
留しておらず良好に補修がなされていることが判明し
た。補修部の断面を写真撮影した断面図を図2に示す。
(a)は例1、(b)は例2の補修後の状態を示してお
り、図2中符号7はステンレス鋼基材で、8は例1の人
工欠陥の充填補修部、9は例2の人工欠陥の充填補修部
である。
After the repair, the cross sections of these simulated defects were cut and polished and observed with an optical microscope. As a result, all of the artificial defects were completely filled with the brazing material, and no defects such as voids remained. It was found that repairs had been made. FIG. 2 is a cross-sectional view showing a photograph of a cross section of the repaired portion.
(A) shows the state after repair of Example 1 and (b) shows the state after repair in Example 2. In FIG. 2, reference numeral 7 is a stainless steel base material, 8 is a filling repair part for artificial defects of Example 1, and 9 is an example. 2 is a filling and repairing section for an artificial defect.

【0039】同様の方法により表1から選択したろう材
を用いて、それぞれのろう材の融点の50℃から100℃程
度高い温度で、赤外線集光ヒータ,高周波加熱ヒータを
用いて加熱したところ、いずれも酸化することなく良好
に模擬欠陥が補修されていることが認められた。
In the same manner, using the brazing material selected from Table 1 at a temperature about 50 ° C. to 100 ° C. higher than the melting point of each brazing material, using an infrared focusing heater and a high-frequency heating heater, In each case, it was confirmed that the simulated defect was satisfactorily repaired without oxidation.

【0040】(実施例2)実施例1と同様に、オーステ
ナイト系ステンレス鋼基材に人工的に設けた幅0.15mm,
深さ0.5mm及び幅0.02mm,深さ0.3mmの2種類の溝状欠陥
を用いて本補修方法の有効性を確認した。補修材として
15wt%Cr−11P−残部Niからなるろう材の粒径約10μm
から44μmの粉末を用いて、ほう酸を主成分とするフラ
ックスと容積比で3:1に混合した。
(Example 2) As in Example 1, an austenitic stainless steel base material having a width of 0.15 mm,
The effectiveness of this repair method was confirmed using two types of groove-like defects with a depth of 0.5 mm, a width of 0.02 mm, and a depth of 0.3 mm. As a repair material
Particle size of brazing filler metal consisting of 15wt% Cr-11P-balance Ni
Was mixed with a flux containing boric acid as a main component at a volume ratio of 3: 1.

【0041】その後、適量の水系溶剤とバインダーとを
混合して、耳たぶ状の硬さに混練した。この補修材をパ
レットを用いて補修面に厚さ約1mmに載置した。つぎ
に、ドライヤーにより溶剤を蒸発させ、固化した。その
後、本ろう材の融点約880℃より100℃高い980℃まで赤
外線集光ヒータを用いて補修部表面を加熱した。ろう材
は、酸化することなく溶融して補修部に濡れ広がった。
Thereafter, an appropriate amount of an aqueous solvent and a binder were mixed and kneaded to an earlobe-like hardness. The repair material was placed on the repair surface to a thickness of about 1 mm using a pallet. Next, the solvent was evaporated by a dryer and solidified. Thereafter, the surface of the repaired part was heated to 980 ° C, which is 100 ° C higher than the melting point of about 880 ° C of the brazing material, using an infrared focusing heater. The brazing material melted without being oxidized and spread over the repaired portion.

【0042】その後、補修部表面を、粒径50メッシュ以
上のアルミナ粉末を用いてブラスと処理して表面をR
a:2〜30μm,Rmax:10〜200μmに粗した後、大気
中プラズマ溶射法により、上記ステンレス鋼の共材(主
成分:18〜200Cr−8〜10Ni−残部Fe)を、厚さ約0.2mm
形成した。溶射条件は、電圧:65V,電流:550A,ア
ルゴン−水素ガス流量:90リットル/分である。
Thereafter, the surface of the repaired part was treated with a brass using alumina powder having a particle size of 50 mesh or more to make the surface R-shaped.
a: 2 to 30 μm, Rmax: 10 to 200 μm, and then the above-mentioned stainless steel common material (main component: 18 to 200 Cr-8 to 10 Ni-remaining Fe) was applied to a thickness of about 0.2 by plasma spraying in air. mm
Formed. Thermal spraying conditions were as follows: voltage: 65 V, current: 550 A, argon-hydrogen gas flow rate: 90 liter / min.

【0043】補修後、模擬欠陥の断面を切断研磨して光
学顕微鏡で観察した結果、2種類の模擬欠陥は、いずれ
も完全にろう材で充填されており、ボイドなどの欠陥は
残留しておらず良好に補修がなされていることが判明し
た。また、溶射層が補修部表面に良好に形成されてお
り、良好に補修がなされていることが判明した。
After the repair, the cross section of the simulated defect was cut and polished and observed with an optical microscope. As a result, the two types of simulated defects were completely filled with the brazing material, and defects such as voids remained. It was found that the repair was done well. Further, it was found that the thermal sprayed layer was formed well on the surface of the repaired portion, and the repair was well performed.

【0044】つぎに図3により本発明に係る第2の実施
の形態を説明する。本実施の形態は図1の第1の実施の
形態に、次の工程を追加したことにある。ろう材合金と
フラックスの複合体である補修材の混合物密着工程bの
前に予め酸化防止剤塗布工程gとして補修面にフラック
スを、水や有機溶剤などの溶剤でペースト化して塗布す
る(バインダーを用いて混練する工程h)。その後、補
修材をその上に密着する。
Next, a second embodiment according to the present invention will be described with reference to FIG. This embodiment is obtained by adding the following steps to the first embodiment shown in FIG. Before the adhesion step b of the mixture of the repair material which is a composite of the brazing alloy and the flux, a flux is applied to the repair surface in advance as an antioxidant application step g by applying a paste with a solvent such as water or an organic solvent. K) using kneading. Thereafter, the repair material is adhered thereon.

【0045】また、補修面の補修材を加熱,溶融し、補
修部の欠陥部にろう材融液を充填させて、さらに残余物
を除去する工程の後、溶射法または溶接法により高耐食
部材の被覆層を形成する溶射による耐食層形成工程iで
ある。溶射法としては、大気中溶射や高速ガス炎溶射な
どが適している。
After the step of heating and melting the repaired material on the repaired surface, filling the defective portion of the repaired portion with the brazing filler metal melt, and further removing the residue, the highly corrosion-resistant member is sprayed or welded. This is a step i of forming a corrosion-resistant layer by thermal spraying for forming a coating layer. As the thermal spraying method, atmospheric thermal spraying, high-speed gas flame thermal spraying, and the like are suitable.

【0046】溶射層の形成の後、溶射フレーム(プラズ
マアークや高温ガス)を用いて溶射層を加熱し(工程
i)、溶射層の緻密化を図る溶射フレームによる溶射層
の加熱工程jである。また、溶接法としては、溶接入熱
を5kJ/cm以下に低くすることの可能なTIG溶接,レー
ザ溶接,PTA溶接等の低入熱溶接による耐食被覆層の形
成工程kを適宜設けており、この場合には溶接のままで
使用可能である。
After the formation of the thermal spray layer, the thermal spray layer is heated using a thermal spray frame (plasma arc or high-temperature gas) (step i), and the thermal spray layer is heated by the thermal spray frame for densification of the thermal spray layer. . In addition, as a welding method, a process k for forming a corrosion-resistant coating layer by low heat input welding such as TIG welding, laser welding, or PTA welding, which can reduce welding heat input to 5 kJ / cm or less, is appropriately provided. In this case, it can be used as welded.

【0047】(実施例3)オーステナイト系ステンレス
鋼基材に人工的に設けた幅0.15mm〜0.3mm,深さ0.3〜1
mm各種溝状模擬欠陥を用いて本補修方法の有効性を確認
した。
(Example 3) A width of 0.15 mm to 0.3 mm and a depth of 0.3 to 1 artificially provided on an austenitic stainless steel base material.
The effectiveness of this repair method was confirmed using various groove-shaped simulated defects.

【0048】補修材として15wt%Cr−30Co−11P−残部
Ni,15wt%Cr−20Ni−3Si−残部Co,80wt%Au−残部N
i,34wt%Pd−30Au−残部Ni,の3種類のろう材の粒径
約1μmから100μmの粉末を用いて、ほう酸、ほうけ
い酸を主成分とするフラックスと容積比で1〜5:1に
混合した。
15% by weight Cr-30Co-11P as a repair material-balance
Ni, 15wt% Cr-20Ni-3Si-balance Co, 80wt% Au-balance N
i, 34 wt% Pd-30Au-balance Ni, using powders of about 1 μm to 100 μm in particle diameter of about 1 μm to 100 μm, and a volume ratio of boric acid and borosilicate to flux of 1 to 5: 1. Was mixed.

【0049】その後、適量の水系溶剤とバインダーと混
合して、耳たぶ状の硬さに混練した補修材を、パレット
を用いて、補修面に厚さ約1mmに密着した。つぎに、ド
ライヤーにより溶剤を蒸発させ、固化した。その後、本
ろう材の融点、それぞれ約880℃,980℃,955℃,1150
℃より100℃高い980℃,1080℃,1055℃,1250℃まで高
周波ヒータあるいはレーザ光を用いて補修部表面を加熱
した。ろう材は、酸化することなく溶融して補修部に濡
れ広がった。
Thereafter, a repair material mixed with an appropriate amount of an aqueous solvent and a binder and kneaded to an earlobe-like hardness was adhered to the repair surface to a thickness of about 1 mm using a pallet. Next, the solvent was evaporated by a dryer and solidified. After that, the melting point of the brazing material was about 880 ° C, 980 ° C, 955 ° C, 1150 ° C, respectively.
The surface of the repaired part was heated to 980 ° C, 1080 ° C, 1055 ° C, and 1250 ° C, which is 100 ° C higher than 100 ° C, using a high-frequency heater or laser light. The brazing material melted without being oxidized and spread over the repaired portion.

【0050】その後、補修部表面を、粒径50メッシュ以
下のアルミナ粉末を用いてブラストして表面をRa:5
〜20μm,Rmax:30〜150μmに粗した後、高速ガス炎
溶射(HVOF)法により、炭素量の少ないSUS304の粒子径
10〜50μmの粉末を用いて、厚さ約0.3mmに形成した。
溶射条件は、流速850m/秒,補修面温度約150〜200℃
である。
Thereafter, the surface of the repaired portion was blasted using alumina powder having a particle size of 50 mesh or less to make the surface Ra: 5.
-20μm, Rmax: After roughening to 30-150μm, the particle size of SUS304 with low carbon content by high-speed gas flame spraying (HVOF) method
It was formed to a thickness of about 0.3 mm using a powder of 10 to 50 μm.
Thermal spraying conditions: flow rate 850m / sec, repair surface temperature about 150-200 ℃
It is.

【0051】溶射後、ガス炎を1〜10分間補修面に当て
て追加熱した。その後、入熱量を低減して、短時間加熱
し、補修部の成分元素を分散させる。最表面を僅かに溶
融させてもよい。
After the thermal spraying, a gas flame was applied to the repaired surface for 1 to 10 minutes to further heat it. Thereafter, the heat input is reduced and heating is performed for a short time to disperse the component elements of the repaired part. The outermost surface may be slightly melted.

【0052】補修完了後、模擬欠陥の断面を切断研磨し
て光学顕微鏡で観察した結果、2種類の模擬欠陥は、い
ずれも完全にろう材で充填されており、ボイドなどの欠
陥は残留しておらず良好に補修がなされていることが判
明した。また、溶射層が補修部表面に良好に形成されて
おり、良好に補修がなされていることが判明した。
After completion of the repair, the cross section of the simulated defect was cut and polished and observed with an optical microscope. As a result, the two types of simulated defects were completely filled with the brazing material, and defects such as voids remained. It was found that the repair was well done. Further, it was found that the thermal sprayed layer was formed well on the surface of the repaired portion, and the repair was well performed.

【0053】さらに、溶射層は緻密化しており、補修面
との密着性も良好であった。溶射に用いる材料として、
炭素量の少ないSUS316あるいはINCONEL182/82相当のNi
基合金を被覆した場合も、同様に良好に補修されている
ことが認められた。
Further, the sprayed layer was dense and had good adhesion to the repaired surface. As a material used for thermal spraying,
SUS316 with low carbon content or Ni equivalent to INCONEL182 / 82
When the base alloy was coated, it was confirmed that the repair was similarly well performed.

【0054】本実施の形態によれば、補修材を用いて、
大気中加熱により、欠陥を良好に充填補修することがで
きる。また、補修面に共材が形成され、補修部の表層が
初期状態と同等の特性を示す。なお、本実施例では、主
成分をCoやNiとする補修材を用いたが、被補修部の主成
分がFeの場合、補修材もFe基材料を用いた方が、より基
材に近い特性の補修部が得られて有効であることは言う
までもない。
According to the present embodiment, using the repair material,
Defects can be satisfactorily filled and repaired by heating in the atmosphere. In addition, a common material is formed on the repaired surface, and the surface layer of the repaired portion shows the same characteristics as the initial state. In the present embodiment, a repair material whose main component is Co or Ni was used.However, when the main component of the repair target portion is Fe, the repair material is also closer to the base material when the repair material also uses an Fe-based material. It goes without saying that a repaired part of the characteristics is obtained and effective.

【0055】[0055]

【発明の効果】本発明によれば、加熱により予め欠陥部
分に塗布した補修材が溶融し、欠陥部に融液が流れ込ん
で充填され、したがって強固に補修される。フラックス
の効果により、大気中加熱でも酸化物生成が抑制され、
良好に合金融液が補修部の欠陥に流れる。
According to the present invention, the repair material previously applied to the defective portion is melted by heating, the melt flows into the defective portion to be filled, and thus the repair is firmly performed. Due to the effect of the flux, the formation of oxides is suppressed even by heating in the air,
The combined liquid flows well to the defect in the repair department.

【0056】また、本発明では、主成分をCoやNiとする
補修材を用いたが、被補修部の主成分がFeの場合、補修
材もFe基材料を用いた方が、より基材に近い特性の補修
部が得られて有効である。
In the present invention, a repair material whose main component is Co or Ni is used. However, when the main component of the repaired portion is Fe, it is more preferable to use an Fe-based material for the repair material. It is effective to obtain a repaired part with characteristics close to.

【0057】さらに、大気中施工が可能となるため、被
補修物を取り外して現地から工場に持ち込むことなく、
現地で直接施工が可能であるとともに、工期短縮化に寄
与でき、しかもコスト削減にも効果的である。
Further, since it is possible to perform the work in the atmosphere, the object to be repaired is not removed and brought to the factory from the site.
The construction can be done directly on site, and it can contribute to shortening the construction period, and it is also effective for cost reduction.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明に係る原子力発電プラント用炉内機器の
補修方法の第1の実施の形態を示す工程図。
FIG. 1 is a process chart showing a first embodiment of a method for repairing in-furnace equipment for a nuclear power plant according to the present invention.

【図2】(a)は第1の実施の形態における例1の補修
部を写真撮影した断面図、(b)は同じく例2を写真撮
影した断面図。
FIG. 2A is a cross-sectional view of a repaired part of Example 1 in the first embodiment photographed, and FIG. 2B is a cross-sectional view of a repaired part of Example 1 in the first embodiment.

【図3】本発明に係る原子力発電プラント用炉内機器の
補修方法の第2の実施の形態を示す工程図。
FIG. 3 is a process diagram showing a second embodiment of the method for repairing in-core equipment for a nuclear power plant according to the present invention.

【図4】原子力発電プラント用炉内機器を説明するため
の縦断面図。
FIG. 4 is a longitudinal sectional view for explaining the in-furnace equipment for a nuclear power plant.

【符号の説明】[Explanation of symbols]

1…原子炉圧力容器、2…シュラウド、3…ジェットポ
ンプ、4…制御棒案内管、5…炉心スプレー、6…制御
棒駆動機構、7…ステンレス鋼基材、8…例1の人工欠
陥の充填補修部、9…例2の人工欠陥の充填補修部、a
…補修部の表面変質層除去工程、b…補修部に合金粉末
と酸化防止剤の混合物密着工程、c…加熱により合金粉
末溶融工程、d…欠陥部に合金融液充填工程、e…欠陥
部に合金凝固工程、f…残余物除去工程、g…酸化防止
剤塗布工程、h…バインダーを用いた混練工程、i…溶
射による耐食層形成工程、j…溶射フレームによる溶射
層の加熱工程、k…低入熱溶接による耐食層形成工程。
DESCRIPTION OF SYMBOLS 1 ... Reactor pressure vessel, 2 ... Shroud, 3 ... Jet pump, 4 ... Control rod guide tube, 5 ... Core spray, 6 ... Control rod drive mechanism, 7 ... Stainless steel base material, 8 ... Filling repair part, 9 ... Filling repair part of the artificial defect of Example 2, a
... removal step of the surface deteriorated layer of the repaired part, b ... adhesion step of the mixture of alloy powder and antioxidant on the repaired part, c ... melting of the alloy powder by heating, d ... filling step of the synthetic liquid with the defective part, e ... defect part Alloy solidification step, f: residue removal step, g: antioxidant application step, h: kneading step using a binder, i: corrosion resistant layer forming step by thermal spraying, j: heating step of thermal sprayed layer by thermal spraying frame, k ... Corrosion resistant layer forming process by low heat input welding.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 森島 康雄 神奈川県横浜市磯子区新杉田町8番地 株 式会社東芝横浜事業所内 Fターム(参考) 4K031 AA04 AA08 AB09 BA01 CB08 CB22 DA01 DA04 FA01 4K044 AA03 AB10 BA02 BA04 BA06 BA08 BA11 BB01 BB04 BC02 CA04 CA11 CA53 CA62  ────────────────────────────────────────────────── ─── Continuing on the front page (72) Inventor Yasuo Morishima 8 Shinsugita-cho, Isogo-ku, Yokohama-shi, Kanagawa Prefecture F-term in Toshiba Yokohama Office 4K031 AA04 AA08 AB09 BA01 CB08 CB22 DA01 DA04 FA01 4K044 AA03 AB10 BA02 BA04 BA06 BA08 BA11 BB01 BB04 BC02 CA04 CA11 CA53 CA62

Claims (12)

【特許請求の範囲】[Claims] 【請求項1】 補修部の表面変質層を除去する工程と、
前記補修部の補修面に構造部材より融点の低いろう材合
金とフラックスの複合体からなる補修材を密着する混合
物密着工程と、前記ろう材合金を加熱溶融して前記補修
部に充填する合金融液充填工程と、この合金融液充填工
程後に残余物を除去する残余物除去工程を有することを
特徴とする原子力発電プラント用炉内機器の補修方法。
A step of removing a surface altered layer of the repaired part;
A mixture adhesion step of closely adhering a repair material composed of a composite of a brazing alloy and a flux having a lower melting point than the structural member to a repair surface of the repair section, and a heat sink for heating and melting the brazing alloy to fill the repair section. A method for repairing in-core equipment for a nuclear power plant, comprising: a liquid filling step; and a residue removing step of removing a residue after the combined liquid filling step.
【請求項2】 前記補修材載置工程の前にフラックスを
前記補修部表面に塗布する工程を含むことを特徴とする
請求項1記載の原子力発電プラント用炉内機器の補修方
法。
2. The method for repairing in-furnace equipment for a nuclear power plant according to claim 1, further comprising a step of applying a flux to the surface of the repair section before the step of placing the repair material.
【請求項3】 前記補修部の補修後、機械加工により表
面を平滑化する工程を含むか、または前記補修部表面に
溶射法により被補修部材と同等、もしくはより耐食性に
優れる高耐食層を形成する工程を含むことを特徴とする
請求項1または2記載の原子力発電プラント用炉内機器
の補修方法。
3. After repairing the repaired portion, a step of smoothing the surface by machining is included, or a high corrosion resistant layer having the same or better corrosion resistance as the repaired member is formed on the surface of the repaired portion by a thermal spraying method. The method for repairing in-furnace equipment for a nuclear power plant according to claim 1 or 2, comprising a step of performing.
【請求項4】 前記残余物除去工程後、溶射法により耐
食層を形成した後、溶射フレームにより溶射層を加熱し
緻密化する工程を含むことを特徴とする請求項3記載の
原子力発電プラント用炉内機器の補修方法。
4. The nuclear power plant according to claim 3, further comprising, after the residue removing step, a step of forming a corrosion-resistant layer by a thermal spraying method, and then heating and densifying the thermal sprayed layer by a thermal spraying frame. How to repair furnace equipment.
【請求項5】 前記残余物除去工程後、前記補修部表面
に入熱5kJ/cm以下のレーザ溶接法、または低入熱TIG
溶接法あるいは低入熱PTA溶接法により被補修部材と同
等、またはより耐食性に優れる高耐食層を形成する工程
を含むことを特徴とする請求項1ないし3記載の原子力
発電プラント用炉内機器の補修方法。
5. A laser welding method with a heat input of 5 kJ / cm or less or a low heat input TIG on the surface of the repaired part after the residue removing step.
4. The in-furnace equipment for a nuclear power plant according to claim 1, further comprising a step of forming a high corrosion resistant layer equivalent to or more excellent in corrosion resistance to the member to be repaired by a welding method or a low heat input PTA welding method. Repair method.
【請求項6】 前記補修部の表面変質層の除去は、研
磨,ブラストなどの機械的方法によることを特徴とする
請求項1記載の原子力発電プラント用炉内機器の補修方
法。
6. The method according to claim 1, wherein the removal of the deteriorated surface layer of the repair part is performed by a mechanical method such as polishing or blasting.
【請求項7】 前記補修材は、ろう材合金粉末,フラッ
クス,有機バインダーと溶剤により混練されたペースト
状であることを特徴とする請求項1ないし4記載の原子
力発電プラント用炉内機器の補修方法。
7. The repair of an in-furnace equipment for a nuclear power plant according to claim 1, wherein the repair material is a paste formed by kneading a brazing alloy powder, a flux, an organic binder and a solvent. Method.
【請求項8】 前記補修材のろう材合金は、Au,Pt,P
d,Ag,Ni,Cu,Co,Fe,Cr,P,Si,B,Mnから選ば
れる少なくとも1種の成分の合金あるいはそれらの混合
物からなることを特徴とする請求項1ないし4記載の原
子力発電プラント用炉内機器の補修方法。
8. The brazing alloy of the repair material is Au, Pt, P
5. Nuclear power according to any one of claims 1 to 4, comprising an alloy of at least one component selected from d, Ag, Ni, Cu, Co, Fe, Cr, P, Si, B and Mn, or a mixture thereof. How to repair furnace equipment for power plants.
【請求項9】 前記フラックスはほう酸,ほう酸塩,フ
ッ化物を含むことを特徴とする請求項1ないし5記載の
原子力発電プラント用炉内機器の補修方法。
9. The method according to claim 1, wherein the flux contains boric acid, borate, and fluoride.
【請求項10】 前記加熱工程は、高周波加熱,赤外線
集光加熱,レーザ加熱などによる局部加熱、または大気
あるいは不活性ガスの吹き付け雰囲気であることを特徴
とする請求項1ないし5記載の原子力発電プラント用炉
内機器の補修方法。
10. The nuclear power generation system according to claim 1, wherein the heating step is performed by local heating such as high-frequency heating, infrared condensing heating, laser heating, or the atmosphere of air or an inert gas. Repair method for furnace equipment for plants.
【請求項11】 前記補修材の合金粉末の主成分は、A
u,Pt,Pd,Ni,Co,Cr,P,Siから選ばれる少なくと
も1種の元素からなることを特徴とする請求項1ないし
5記載の原子力発電プラント用炉内機器の補修方法。
11. The main component of the alloy powder of the repair material is A
6. The method for repairing in-furnace equipment for a nuclear power plant according to claim 1, wherein the method comprises at least one element selected from the group consisting of u, Pt, Pd, Ni, Co, Cr, P, and Si.
【請求項12】 前記補修部を補修後、前記補修部表面
に高耐食オーステナイト系ステンレス鋼を被覆層として
形成することを特徴とする請求項1ないし5記載の原子
力発電プラント用炉内機器の補修方法。
12. The repair of in-furnace equipment for a nuclear power plant according to claim 1, wherein after repairing the repaired portion, a high corrosion resistant austenitic stainless steel is formed as a coating layer on the surface of the repaired portion. Method.
JP2000122089A 2000-04-24 2000-04-24 Repair method for in-furnace equipment for nuclear power plants Pending JP2001305271A (en)

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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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Publication Number Publication Date
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ID=18632613

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JP2005349567A (en) * 2005-08-05 2005-12-22 Tadayuki Nishino Cast iron-made product reproducing method
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US20100116793A1 (en) * 2007-02-13 2010-05-13 Grueger Birgit Welded Repair of Defects Lying on the Inside of Components
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RU2289499C1 (en) * 2005-03-21 2006-12-20 Государственное образовательное учреждение высшего профессионального образования "Тихоокеанский государственный университет" Sliding bearing bush restoring method
JP2005349567A (en) * 2005-08-05 2005-12-22 Tadayuki Nishino Cast iron-made product reproducing method
JP2007191780A (en) * 2006-01-23 2007-08-02 Toshiba Corp Thermal spraying apparatus and method
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US8324526B2 (en) * 2007-02-13 2012-12-04 Siemens Aktiengesellschaft Welded repair of defects lying on the inside of components
US20100116793A1 (en) * 2007-02-13 2010-05-13 Grueger Birgit Welded Repair of Defects Lying on the Inside of Components
US9023423B2 (en) 2009-10-07 2015-05-05 General Electric Company Method of deposition of metallic coatings using atomized spray
JP2011080148A (en) * 2009-10-07 2011-04-21 General Electric Co <Ge> Method of deposition of metallic coating using atomized spray
CN105263667A (en) * 2013-01-31 2016-01-20 西门子能源公司 Selective laser melting / sintering using powdered flux
JP2016511697A (en) * 2013-01-31 2016-04-21 シーメンス エナジー インコーポレイテッド Selective laser melting / sintering using powdered flux
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