JP2001348754A - High-density woven fabric - Google Patents
High-density woven fabricInfo
- Publication number
- JP2001348754A JP2001348754A JP2000397829A JP2000397829A JP2001348754A JP 2001348754 A JP2001348754 A JP 2001348754A JP 2000397829 A JP2000397829 A JP 2000397829A JP 2000397829 A JP2000397829 A JP 2000397829A JP 2001348754 A JP2001348754 A JP 2001348754A
- Authority
- JP
- Japan
- Prior art keywords
- woven fabric
- density
- water
- warp
- weft
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002759 woven fabric Substances 0.000 title claims abstract description 62
- 229920002994 synthetic fiber Polymers 0.000 claims abstract description 11
- 239000012209 synthetic fiber Substances 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 53
- 238000000034 method Methods 0.000 claims description 30
- 239000005871 repellent Substances 0.000 claims description 26
- 239000004744 fabric Substances 0.000 abstract description 31
- 239000000835 fiber Substances 0.000 abstract description 13
- 210000004243 sweat Anatomy 0.000 abstract description 3
- 238000001704 evaporation Methods 0.000 abstract 1
- 238000004078 waterproofing Methods 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 18
- 238000013461 design Methods 0.000 description 18
- 229920000728 polyester Polymers 0.000 description 16
- 230000002940 repellent Effects 0.000 description 14
- 238000010521 absorption reaction Methods 0.000 description 7
- 238000009941 weaving Methods 0.000 description 7
- 238000010586 diagram Methods 0.000 description 6
- 239000006096 absorbing agent Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 238000000576 coating method Methods 0.000 description 4
- 238000007756 gravure coating Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- 239000002250 absorbent Substances 0.000 description 3
- 230000002745 absorbent Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000007730 finishing process Methods 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 2
- 230000000386 athletic effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- -1 polyethylene terephthalate Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- YZTJKOLMWJNVFH-UHFFFAOYSA-N 2-sulfobenzene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1S(O)(=O)=O YZTJKOLMWJNVFH-UHFFFAOYSA-N 0.000 description 1
- 206010016759 Flat affect Diseases 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229920001410 Microfiber Polymers 0.000 description 1
- 229920003189 Nylon 4,6 Polymers 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- WDQNIWFZKXZFAY-UHFFFAOYSA-M fentin acetate Chemical compound CC([O-])=O.C1=CC=CC=C1[Sn+](C=1C=CC=CC=1)C1=CC=CC=C1 WDQNIWFZKXZFAY-UHFFFAOYSA-M 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Woven Fabrics (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、柔軟性及び防水性
に優れた高密度織物、さらには吸汗発散性を兼ね備えた
高密度織物に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a high-density woven fabric excellent in flexibility and waterproofness, and more particularly, to a high-density woven fabric having a sweat-absorbing property.
【０００２】[0002]
【従来の技術】従来から、コート、ブルゾン等のカジュ
アル衣料やスキー、マリン、アスレチック等のスポーツ
衣料には、透湿性、防水性の両方の機能が要求されてい
る。一般にこれらの要求に応えるため、撥水加工された
布帛にポリウレタン系樹脂やポリアミノ酸系樹脂等をコ
ーティング法、ラミネート法等によって微多孔樹脂層を
形成させる方法や、極細繊維を高密度に製織してなる織
物に撥水加工を施す方法がおこなはれている。また高密
度織物に撥水処理を施し、さらに加熱カレンダー等で加
熱加圧処理して織物の目を潰す方法が行われている。し
かしながら、これらの方法で得られる放水布には、風合
いが硬くなるという問題があり、柔軟で着用性の良い布
帛が得られないという問題があった。特公昭６３−５８
９４２号公報には、表裏二重組織を用いて、表面構造を
凹凸構造にすることにより、撥水性を向上させる方法が
提案されているが、経緯二重組織であるため表組織と裏
組織との結節部において、漏水が発生し高い耐水圧を得
ることが難しいという問題があった。2. Description of the Related Art Conventionally, both casual clothes such as coats and blousons and sports clothes such as skis, marine and athletic have been required to have both functions of moisture permeability and waterproofness. In general, in order to meet these demands, a method of forming a microporous resin layer on a water-repellent cloth with a polyurethane resin or a polyamino acid resin by a coating method, a laminating method, or the like, or weaving ultrafine fibers at a high density. A method of applying a water-repellent treatment to a woven fabric is used. Further, a method of subjecting a high-density woven fabric to a water-repellent treatment and further performing a heating and pressurizing treatment with a heating calender or the like to crush the eyes of the woven fabric has been performed. However, the water-dispersing cloth obtained by these methods has a problem that the texture becomes hard, and there is a problem that a flexible and wearable cloth cannot be obtained. Tokiko 63-58
No. 942 proposes a method of improving water repellency by making the surface structure uneven by using a front and back double structure. There was a problem that it was difficult to obtain a high water pressure at the nodal part of the above-mentioned nodule.
【０００３】一方、近年衣料の着用快適性の一つである
吸水発散性能について種々の提案がなされている。例え
ば、特開昭６２−５４８９９号公報には表裏に吸水性の
異なる繊維を使用する方法、実公昭６１−３８９３１号
公報には表裏に吸水性を持たせると共に表面層と裏面層
に導水層を設ける方法が提案されている。これらは主に
スポーツ衣料用として数多く使用されているものの、有
効な吸水発散機能を発現させるには編物でしかできない
という問題があった。織物では、特公平６−４１６５７
号公報に二重織物の裏面に吸水性が優れている天然繊維
からなる短繊維を使用した吸湿性織物が提案されている
が、織物重量が必要以上に重くなるという欠点を有して
いる。特開平７−３９７０５号公報には、経緯二重組織
を用い表組織には凸部を有する扁平断面異繊度繊維を配
して繊維間に微細な間隙を設け、毛細管現象を利用する
ことにより吸汗発散性を得る方法が提案されている。こ
の方法によると優れた吸汗発散性は発現するが、例えば
夏期の雨天時に使用し、織物の表面に水分が付着すると
吸汗発散性が低下し蒸れるという問題を残している。On the other hand, in recent years, various proposals have been made regarding water absorption and diffusion performance, which is one of the wearing comforts of clothing. For example, Japanese Unexamined Patent Publication No. Sho 62-54899 discloses a method of using fibers having different water absorbency on the front and back, and Japanese Utility Model Publication No. 61-38931 discloses a method of imparting water absorbency on the front and back and providing a water guide layer on the front and back layers. Proposed methods have been proposed. Although these are mainly used for sports clothing, there is a problem that only a knitted fabric can exhibit an effective water-absorbing and diffusing function. For textiles, Japanese Patent Publication 6-41657
Japanese Patent Application Laid-Open Publication No. H11-15064 proposes a hygroscopic woven fabric using short fibers made of natural fibers having excellent water absorbency on the back surface of the double woven fabric, but has a drawback that the weight of the woven fabric becomes unnecessarily heavy. Japanese Unexamined Patent Publication No. Hei 7-39705 discloses a double-textured structure, a flat-textured fiber having a flat cross section having a convex portion in the surface structure, a fine gap provided between the fibers, and sweat absorption by utilizing the capillary phenomenon. Methods for obtaining divergence have been proposed. According to this method, excellent sweat-absorbing property is exhibited, but it is used, for example, in the rainy season in summer, and if moisture adheres to the surface of the woven fabric, there is a problem that the sweat-absorbing property is reduced and it becomes stuffy.
【０００４】[0004]
【発明が解決しようとする課題】本発明は、上記の現状
を鑑みてなされたものであり、柔軟性及び防水性に優れ
た高密度織物、さらには吸汗発散性を兼ね備えた高密度
織物を提供することを課題とするものである。SUMMARY OF THE INVENTION The present invention has been made in view of the above situation, and provides a high-density woven fabric excellent in flexibility and waterproofness, and a high-density woven fabric having both sweat-absorbing properties. The task is to do so.
【０００５】[0005]
【課題を解決するための手段】本発明は、このような課
題を解決するものであり、緯二重組織を有する織物であ
って、表組織を構成する糸条は、単糸繊度が１．２デシ
テックス以下である合成繊維であり、表組織部分のカバ
ーファクターが２０００以上、裏組織の緯糸密度が表組
織の緯糸密度の２５〜１００％で、該織物の少なくとも
表面には撥水処理が施されていることを特徴とする高密
度織物、及び経二重組織を有する織物であって、表組織
を構成する糸条は、単糸繊度が１．２デシテックス以下
である合成繊維であり、表組織部分のカバーファクター
が２０００以上、裏組織の経糸密度が表組織の経糸密度
の２５〜１００％で、該織物の少なくとも表面には撥水
処理が施されていることを特徴とする高密度織物、さら
に織物の裏面に吸水加工が施されていることを特徴とす
る上記の高密度織物を要旨とするものである。SUMMARY OF THE INVENTION The present invention solves such a problem, and is a woven fabric having a weft double structure, wherein the yarn constituting the surface structure has a single yarn fineness of 1. A synthetic fiber having a density of 2 decitex or less, a cover factor of the surface structure of 2,000 or more, a weft density of the back structure of 25 to 100% of the weft density of the surface structure, and a water-repellent treatment applied to at least the surface of the woven fabric. A high-density woven fabric characterized by being made, and a woven fabric having a warp double structure, wherein the yarn constituting the surface structure is a synthetic fiber having a single yarn fineness of 1.2 decitex or less; A high-density woven fabric, wherein the cover factor of the woven portion is 2000 or more, the warp density of the back fabric is 25 to 100% of the warp density of the front structure, and at least the surface of the woven fabric is subjected to a water-repellent treatment. To the back of the fabric The high-density woven fabric characterized in that the processing is given it is an gist.
【０００６】[0006]
【発明の実施形態】以下、本発明について詳細に説明す
る。本発明の織物では、織物組織として緯二重組織ある
いは経二重組織を用いる。従来の一重組織の織物では、
肉厚感に欠けるだけでなく、高耐水圧を得るために高密
度に織り上げると、組織点が密となり経緯糸を構成する
糸条の屈曲性が失われ、耐水圧を上げるために仕上加工
工程にて熱カレンダー処理を行うと、さらに風合いが硬
くなり、ペーパーライクな風合いになる。本発明のよう
に緯二重組織あるいは経二重組織を用いると、一重組織
の場合より経糸密度あるいは緯糸密度を大きく設定で
き、肉厚感のある織物を容易に形成できる。また、例え
組織点が密になっても経糸あるいは緯糸が連続して長く
浮く部位が存在するので、その部位の糸条の屈曲性は失
われず、織物としては柔軟な風合いを維持できる。本発
明の具体的な組織としては、高い防水性を得るために表
組織としては平組織が好ましく、裏組織としては、織物
全体に柔軟な風合いを持たせるために連続浮き数が３以
上である綾組織や朱子組織が好ましい。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail. In the woven fabric of the present invention, a weft double structure or a warp double structure is used as the woven structure. In the conventional single-woven fabric,
In addition to lack of feeling of thickness, if weaving at high density to obtain high water resistance, the texture point becomes dense, the flexibility of the yarns constituting the warp yarn is lost, and the finishing process to increase the water pressure When heat calendering is performed at, the texture becomes even harder, giving a paper-like texture. When a weft double structure or a warp double structure is used as in the present invention, the warp density or the weft density can be set higher than in the case of a single structure, and a thick woven fabric can be easily formed. Further, even if the texture points are dense, since there is a portion where the warp or weft continuously floats for a long time, the flexibility of the yarn at that portion is not lost, and the fabric can maintain a soft texture. As a specific structure of the present invention, a flat structure is preferable as a surface structure in order to obtain a high waterproof property, and a continuous floating number is 3 or more as a back structure in order to give a soft texture to the entire woven fabric. Aya structure and satin structure are preferred.
【０００７】本発明では、織物の表面は糸条組織間を蜜
密にし、高密度化を図ることにより耐水性能を向上さ
せ、裏面側は表面より高密度化しないようにして織物に
柔軟性を保持させる。このために本発明では織物の表組
織部分のカバーファクターを２０００以上とする。ここ
で、カバーファクターＫは、次式で定義する。 Ｋ＝Ｄ1/2×Ｍ＋Ｅ1/2×Ｎ Ｄは、緯二重組織においては経糸の繊度（デシテック
ス）、経二重組織においては表組織の経糸の繊度（デシ
テックス）であり、Ｅは、緯二重組織においては表組織
の緯糸の繊度（デシテックス）、経二重組織においては
緯糸の繊度（デシテックス）で、Ｍは、緯二重組織にお
いては経糸の密度（本／2.54cm）、経二重組織において
は表組織の経糸の密度（本／2.54cm）であり、Ｎは、緯
二重組織においては表組織の緯糸の密度（本／2.54c
m）、経二重組織においては緯糸の密度（本／2.54cm）
である。このカバーファクターが２０００未満の場合、
良好な防水性が得られない。カバーファクターの上限
は、表組織の緻密性による硬さが織物全体の風合いの硬
さに影響するようになるので、３０００程度までである
のが好ましい。In the present invention, the surface of the woven fabric is made dense between the yarn structures, the water resistance is improved by increasing the density, and the back side is not densified than the surface, so that the woven fabric has flexibility. Hold. For this reason, in the present invention, the cover factor of the surface texture portion of the woven fabric is set to 2000 or more. Here, the cover factor K is defined by the following equation. K = D 1/2 × M + E 1/2 × ND D is the fineness of the warp (decitex) in the weft double design, the fineness of the warp in the warp double design (decitex), and E is In the weft double design, the weft fineness (decitex) of the surface design, in the warp double design, the fineness of the weft (decitex), M is the density of the warp (book / 2.54 cm) in the weft double design, the warp In the double design, it is the density of the surface warp (book / 2.54 cm). In the weft double design, N is the density of the surface weft (book / 2.54 c).
m), density of wefts in the warp double structure (book / 2.54cm)
It is. If this cover factor is less than 2000,
Good water resistance cannot be obtained. The upper limit of the cover factor is preferably up to about 3000 because the hardness due to the fineness of the surface structure affects the hardness of the texture of the entire woven fabric.
【０００８】また、本発明では、緯二重組織、経糸二重
組織のいずれの場合も裏組織の密度は、表組織の密度の
２５〜１００％とし、表組織の密度より大きくしない。
すなわち緯二重組織の場合、裏組織の緯糸密度は、表組
織の緯糸密度の２５〜１００％とし、経糸二重組織の場
合、裏組織の経糸密度は、表組織の経糸密度の２５〜１
００％とする。裏組織の密度が、表組織の密度の２５％
未満であると、肉厚感に欠ける織物になり、柔軟な風合
いを発現させるのが困難になる。Further, in the present invention, the density of the back fabric is set to 25 to 100% of the density of the front fabric and is not larger than the density of the front fabric in both cases of the weft double structure and the warp double structure.
That is, in the case of the double weft design, the weft density of the back design is 25 to 100% of the weft density of the front design, and in the case of the double warp design, the warp density of the back design is 25 to 1 of the warp density of the front design.
00%. The density of the back tissue is 25% of the density of the front tissue
If it is less than 3, the fabric lacks a feeling of thickness, and it is difficult to develop a soft texture.
【０００９】さらに本発明では、組織内のフィラメント
間の間隙を小さくして耐水性能を向上させるために、表
組織を構成する糸条は、単糸繊度が１．２デシテックス
以下である合成繊維を用いる。製織工程や仕上加工工程
の難易度、防水性能の得やすさ、風合い、コスト等を勘
案すると、単糸繊度が０．４〜０．８デシテックスであ
る合成繊維を用いるのが好ましい。緯二重組織における
裏組織の緯糸及び経二重組織における裏組織の経糸は、
特に限定されることはなく、表組織の糸条と同じ糸条で
もよいし、繊維種類や繊度の異なる糸条であってもよ
い。Further, in the present invention, in order to reduce the gap between the filaments in the structure and improve the water resistance, the yarn constituting the surface structure is made of a synthetic fiber having a single yarn fineness of 1.2 dtex or less. Used. Considering the difficulty of the weaving process and the finishing process, the ease of obtaining waterproof performance, the texture, the cost, etc., it is preferable to use a synthetic fiber having a single fiber fineness of 0.4 to 0.8 decitex. The weft of the back design in the weft double design and the warp of the back design in the warp double design are:
It is not particularly limited, and may be the same yarn as the surface structure yarn, or may be a yarn having a different fiber type or fineness.
【００１０】本発明に用いる合成繊維としては、ポリエ
チレンテレフタレート、ポリブチレンテレフタレート、
あるいはこれらにスルフォイソフタレート、イソフター
ル酸等の第３成分を共重合したポリエステルからなるポ
リエステル系繊維、ナイロン６、ナイロン６６、ナイロ
ン４６等のポリアミド系繊維が挙げられる。また、用途
等の要求に応じて、合成繊維に追撚、合撚、仮撚、エア
ー交絡混繊等の糸加工を施して用いることができる。The synthetic fibers used in the present invention include polyethylene terephthalate, polybutylene terephthalate,
Alternatively, there may be mentioned polyester fibers made of polyester obtained by copolymerizing a third component such as sulfoisophthalate and isophthalic acid, and polyamide fibers such as nylon 6, nylon 66 and nylon 46. In addition, according to the requirements of the use or the like, the synthetic fiber can be used after being subjected to yarn processing such as twisting, ply twisting, false twisting, and air entangled blending.
【００１１】本発明の織物は、一般に行なわれる経糸準
備工程により経糸を準備し、通常の製織工程にて製織し
て得ることができる。経糸準備工程では、経糸が無撚あ
るいは甘撚領域の場合はサイジングをするのが好まし
く、それ以外の場合は糸形状に応じてサイジングの有無
を決定すればよい。製織工程で使用される織機は、ウオ
ータージェットルームやエアージェットルーム等で特に
限定されないが、経二重織物の場合組織によっては、裏
経糸が製織中に弛み生産性を阻害するので、この場合に
は表経糸と裏経糸を別のビームに捲き、二重ビームで製
織するとよい。The woven fabric of the present invention can be obtained by preparing a warp in a generally performed warp preparation step and weaving in a usual weaving step. In the warp preparation step, sizing is preferably performed when the warp is in a non-twisted or sweet-twisted region. In other cases, the presence or absence of sizing may be determined according to the yarn shape. The loom used in the weaving process is not particularly limited to a water jet loom or an air jet loom, but in the case of a warp double woven fabric, the back warp sags during weaving and inhibits productivity, so in this case, It is preferable to wind the front warp and the back warp into different beams and weave them with a double beam.
【００１２】上記のようにして得られた織物には、少な
くともその表面に撥水処理が施されている。撥水処理が
施される前に常法により染色加工が施されていてよいの
はもちろんである。撥水処理に用いられる撥水剤は、シ
リコン系化合物、フッ素系化合物等の公知の撥水剤を使
用すればよいが、ポリエステル系合成繊維の場合には、
撥水剤の洗濯耐久性の面からみてフッ素系撥水剤が好適
に用いられる。さらに洗濯耐久性を高めるために、メラ
ミン系、イミン系、イソシアネート系等の架橋剤を併用
してもよい。また、静電気の発生を押さえるための帯電
防止剤や他の付帯加工による機能性を与えるための各種
の仕上剤を併用してもよい。撥水加工方法としては、パ
ディング法、スプレー法、浸漬法、グラビアコーティン
グ法等にて撥水剤溶液を織物に付与した後に乾燥、熱処
理する従来の方法で行なう。撥水剤を織物の表面のみに
付与する場合には、グラビアコーティング等のコーティ
ング法によるのが好適である。The woven fabric obtained as described above has been subjected to a water-repellent treatment at least on its surface. Needless to say, the dyeing process may be performed by a conventional method before the water-repellent treatment is performed. The water repellent used for the water repellent treatment may be a known water repellent such as a silicon-based compound or a fluorine-based compound, but in the case of a polyester-based synthetic fiber,
From the viewpoint of washing durability of the water repellent, a fluorine-based water repellent is preferably used. In order to further increase the washing durability, a melamine-based, imine-based, isocyanate-based cross-linking agent may be used in combination. Further, an antistatic agent for suppressing the generation of static electricity and various finishing agents for imparting functionality by other auxiliary processing may be used in combination. The water-repellent processing is performed by a conventional method of applying a water-repellent solution to a fabric by a padding method, a spray method, an immersion method, a gravure coating method or the like, followed by drying and heat treatment. When the water repellent is applied only to the surface of the fabric, it is preferable to use a coating method such as gravure coating.
【００１３】吸水発散性能を向上させるために織物の裏
面に吸水加工を施す場合には、表面にグラビアコーティ
ング等のコーティング法によって撥水処理を行なった
後、裏面にグラビアコーティング等のコーティング法に
よって吸水剤を付与するか、パディング法、浸漬法によ
り吸水加工を行う。パディング法や浸漬法により吸水加
工を行っても織物の表面には撥水剤が付与されているの
で吸水剤は付与されず、表面には撥水剤、裏面には吸水
剤が付与された織物となる。使用する吸水剤は、公知の
ものでよく、ポリエステル系繊維にはポリエステル系吸
水剤、ポリアミド系繊維にはポリアミド系吸水剤を用い
るのが好ましい。撥水剤や吸水剤の付着量、乾燥条件、
熱処理条件等は使用する撥水剤、吸水剤の種類、製品の
用途による要求性能により決定されればよい。When the back surface of the woven fabric is subjected to a water absorbing process in order to improve the water absorption and diffusion performance, the surface is subjected to a water repellent treatment by a coating method such as gravure coating, and then the back surface is subjected to a water absorbing process by a coating method such as gravure coating. An agent is applied, or water absorption is performed by a padding method or a dipping method. Even if a water absorbing process is performed by a padding method or an immersion method, the water repellent is applied to the surface of the woven fabric so that the water absorbent is not applied, and the water repellent is applied to the front surface and the water absorbent is applied to the back surface. Becomes The water-absorbing agent to be used may be a known one, and it is preferable to use a polyester-based water-absorbing agent for polyester fibers and a polyamide-based water-absorbing agent for polyamide fibers. The amount of water repellent or water absorbent attached, drying conditions,
The heat treatment conditions and the like may be determined in accordance with the required performance depending on the type of the water repellent and the water absorbing agent to be used and the use of the product.
【００１４】[0014]
【作用】本発明のように、緯二重組織あるいは経二重組
織とすることにより、織物に肉厚感をもたらし、裏糸の
密度を表組織より大きくしないことにより、柔軟性を保
持した織物とすることができ、表組織に単糸繊度１．２
デシテックス以下の合成繊維を用い、カバーファクター
を２０００以上とすることにより、織物の表面の繊維組
織間が密になり、これに撥水加工が施されて高度な耐水
性能を示すようになる。さらに裏面に吸水加工を施した
場合には、吸汗発散性能が付与されることとなり、より
着用時の快適性を向上させることになる。According to the present invention, the fabric has a weft double structure or a warp double structure to give the fabric a thick feeling, and the density of the backing yarn is not larger than that of the surface fabric to maintain flexibility. The surface texture has a single yarn fineness of 1.2
By using a synthetic fiber of decitex or less and having a cover factor of 2000 or more, the space between the fiber structures on the surface of the woven fabric becomes dense, and this is subjected to a water-repellent treatment so as to exhibit high water resistance. Further, when the back surface is subjected to a water absorbing process, sweat permeation performance is imparted, and the comfort at the time of wearing is further improved.
【００１５】[0015]
【実施例】次に本発明を実施例によって具体的に説明す
る。なお、実施例における性能の測定は、次のようにし
て行った。 （１）撥水性 ＪＩＳ Ｌ１０９２のスプレー法にて織物表面を測定し
た。 （２）防水性 ＪＩＳ Ｌ１０１８の耐水圧法に準じて測定した。 （３）吸水性 ＪＩＳ Ｌ１０９６のバイレック法により３分後の織物
裏面の吸水性を測定した。 （４）吸汗発散性 織物の表面を上にして平らな面に置き、ピペットを用い
て０．１ミリリットルの水を０．５cmの高さから滴下
し、６０秒後の表裏の濡れ面積(cm2)を測定し、下式で
表裏の濡れ面積の比率を求め、吸汗発散性とした。この
数値が大きい程吸汗発散性が良好といえる。 吸汗発散性=(裏面の濡れ面積／表面の濡れ面積)×100 （５）厚さ テロック株式会社製厚み計（ＳＭ−１２０１型）にて測
定した。 （６）風合い 織物の柔軟性を触感官能評価により、○：柔軟、△：や
や柔軟、×：硬いの３段階で評価した。Next, the present invention will be described specifically with reference to examples. In addition, the measurement of the performance in an Example was performed as follows. (1) Water repellency The woven fabric surface was measured by the spray method of JIS L1092. (2) Waterproofness Measured according to the water pressure resistance method of JIS L1018. (3) Water Absorption The water absorption of the back surface of the fabric after 3 minutes was measured by the bi-rec method of JIS L1096. (4) Sweat-absorbing property The fabric is placed on a flat surface with the surface facing upward, and 0.1 ml of water is dropped from a height of 0.5 cm using a pipette. 2 ) was measured, and the ratio of the wet area on the front and back sides was determined by the following formula, and the ratio was determined as sweat-absorbing property. It can be said that the larger the value is, the better the sweat-absorbing property is. Sweat-absorbing property = (wet area of back surface / wet area of front surface) × 100 (5) Thickness Measured with a thickness gauge (SM-1201) manufactured by Telok Co., Ltd. (6) Texture The softness of the woven fabric was evaluated by the tactile sensory evaluation in three stages: ：: soft, Δ: slightly soft, and ×: hard.
【００１６】実施例１ 経糸及び表組織の緯糸として、ポリエステルマルチフィ
ラメント糸１００デシテックス／１４４フィラメント
（単糸繊度０．７デシテックス）を用い、裏組織の緯糸
として、ポリエステルマルチフィラメント糸１００デシ
テックス／９６フィラメント（単糸繊度１．０４デシテ
ックス）の仮撚加工糸を用いて、図１に示す組織（表組
織が平織で裏組織が朱子織）にて製織した織物を通常の
方法で精練・染色し、織物の表面に下記処方に示す処理
液をグラビアロールにて６０ｇ／ｍ 2で塗布（固形分付
着量５．４ｇ／ｍ2）し、高圧スチーマーで温度１７０
℃、時間５分の熱処理を行なって撥水処理を施した。 ＜撥水処方＞ アサヒガードＬＳ−３１７ １００質量部 （明成化学工業株式会社製フッ素系撥水剤、固形分３０
％） 尿素 ２０質量部 アルギン酸ナトリウム ４０質量部 水 ８４０質量部 次いで湯洗・乾燥後、高松油脂株式会社製ポリエステル
吸水剤ＳＲ−１０００の５％溶液に浸漬しマングルにて
絞り率６０％で絞液後テンターにて温度１７０℃、時間
１分の熱セットを行なって吸水処理を施し、経糸密度が
１５８本／2.54cm、緯糸密度が１７４本／2.54cm（表裏
共に８７本／2.54cm）で、表組織のカバーファクターが
２４５０である本発明の高密度織物を得た。Example 1 A polyester multifilament was used as a warp and a surface weft.
Lament yarn 100 decitex / 144 filament
(Single yarn fineness 0.7 decitex)
100 polyester polyester multifilament yarn
Tex / 96 filament (single yarn fineness 1.04 d
1) using the false twisted yarn of (x)
Weave is plain weave and back fabric is Suzu weave).
Scouring and dyeing by the method, the treatment shown in the following formula on the surface of the fabric
60g / m with gravure roll Two(With solid content)
5.4 g / mTwo) And pressurize at 170
A water repellent treatment was performed by performing a heat treatment at a temperature of 5 ° C. for 5 minutes. <Water repellent formulation> Asahigard LS-317 100 parts by mass (Fluorine water repellent manufactured by Meisei Chemical Co., Ltd., solid content 30)
%) Urea 20 parts by mass Sodium alginate 40 parts by mass Water 840 parts by mass After washing with hot water and drying, polyester manufactured by Takamatsu Yushi Co., Ltd.
Soak in 5% solution of water-absorbing agent SR-1000 and mangle
After squeezing at a squeezing rate of 60%, the temperature is 170 ° C with a tenter and time
Heat set for 1 minute to perform water absorption, and warp density
158 yarns / 2.54 cm, weft density 174 yarns / 2.54 cm (front and back)
Both are 87 lines / 2.54 cm), and the cover factor of the surface organization is
2450 was obtained.
【００１７】実施例２ 経緯糸を実施例１と同じ糸使いで、組織を図２の組織図
とし、緯糸密度を１４０本／2.54cm、（表緯糸密度１１
２本／2.54cm、裏緯糸密度２８本／2.54cm、裏緯糸密度
は表緯糸密度の２５％）とし、表組織のカバーファクタ
ーを２７００とすること以外は実施例１と同様にして本
発明の高密度織物を得た。Example 2 Using the same weft yarns as in Example 1, the structure is shown in FIG. 2 and the weft density is 140 yarns / 2.54 cm.
2 yarns / 2.54 cm, back weft density 28 yarns / 2.54 cm, back weft density 25% of the surface weft density), and the cover factor of the surface texture was set to 2700. A high density fabric was obtained.
【００１８】比較例１ 経緯糸を実施例１と同じ糸使いで、組織を図３の組織図
とし、緯糸密度を１１９本／2.54cm、（表緯糸密度１０
２本／2.54cm、裏緯糸密度１７本／2.54cm、裏緯糸密度
は表緯糸密度の１７％）とし、表組織のカバーファクタ
ーを２６００とすること以外は実施例１と同様にして比
較例の織物を得た。Comparative Example 1 Using the same weft yarns as in Example 1 and the structure as shown in FIG. 3, the weft density was 119 yarns / 2.54 cm,
2 / 2.54 cm, back weft density 17 / 2.54 cm, back weft density is 17% of the surface weft density), and the cover factor of the surface texture is set to 2600. A woven fabric was obtained.
【００１９】比較例２ 経緯糸としてポリエステルマルチフィラメント糸１００
デシテックス／１４４フィラメント（単糸繊度０．７デ
シテックス）を用い、組織を平組織（一重組織）とし、
緯糸密度を１０３本／2.54cmとして、カバーファクター
を２６１０とすること以外は実施例１と同様にして比較
例の織物を得た。Comparative Example 2 Polyester multifilament yarn 100 as warp yarn
Using decitex / 144 filaments (single yarn fineness: 0.7 decitex), the structure is a flat structure (single structure),
A woven fabric of a comparative example was obtained in the same manner as in Example 1 except that the weft density was 103 yarns / 2.54 cm and the cover factor was 2610.
【００２０】比較例３ 実施例１において、経糸及び表組織の緯糸としてのポリ
エステルマルチフィラメント糸１００デシテックス／１
４４フィラメント（単糸繊度０．７デシテックス）に替
えて、ポリエステルマルチフィラメント糸１００デシテ
ックス／４８フィラメント（単糸繊度２．１デシテック
ス）を用いること以外は実施例１と同様にして比較例の
織物を得た。得られた実施例１〜２及び比較例１〜３の
織物の評価結果を併せて表１に示す。Comparative Example 3 In Example 1, the polyester multifilament yarn as the warp and the weft having the surface texture was 100 dtex / 1.
A woven fabric of a comparative example was prepared in the same manner as in Example 1 except that polyester multifilament yarn 100 dtex / 48 filament (single yarn fineness 2.1 decitex) was used instead of 44 filaments (single yarn fineness 0.7 decitex). Obtained. Table 1 also shows the evaluation results of the obtained woven fabrics of Examples 1 and 2 and Comparative Examples 1 to 3.
【００２１】[0021]
【表１】 [Table 1]
【００２２】表１からも明らかなように、本発明の実施
例１及び実施例２の織物は、肉厚感に富み、柔軟性に優
れたものであり、耐水性能、撥水性能の面で優れてお
り、吸汗発散性といった着用快適性が十分発揮できる織
物であった。これに対して、裏組織の緯糸の比率が小さ
い比較例１、二重組織でない比較例２及び表組織を構成
する糸条の単糸繊度の大きい比較例３は、織物の柔軟性
に劣るものであった。As is clear from Table 1, the woven fabrics of Examples 1 and 2 of the present invention are rich in thickness and excellent in flexibility, and are excellent in water resistance and water repellency. The fabric was excellent and could sufficiently exhibit wearing comfort such as sweat-absorbing properties. On the other hand, Comparative Example 1 in which the ratio of the weft in the back structure is small, Comparative Example 2 in which the structure is not double, and Comparative Example 3 in which the single yarn fineness of the yarn constituting the surface structure is large are inferior in the flexibility of the woven fabric. Met.
【００２３】実施例３ 表経糸として、ポリエステルマルチフィラメント糸１０
０デシテックス／１４４フィラメント（単糸繊度０．７
デシテックス）を用い、緯糸として、ポリエステルマル
チフィラメント糸１００デシテックス／９６フィラメン
ト（単糸繊度１．０４デシテックス）の仮撚加工糸を用
いて、図４に示す組織にて製織した織物に、実施例１と
同様の仕上加工を施して、経糸密度が１９５本／2.54cm
（表組織１５６本／2.54cm、裏組織３９本／2.54cm、裏
経糸密度は表経糸密度の２５％）、緯糸密度が９３本／
2.54cmで、表組織のカバーファクターが２４９０である
本発明の高密度織物を得た。Example 3 As a warp yarn, a polyester multifilament yarn 10 was used.
0 decitex / 144 filament (single yarn fineness 0.7
Using a polyester multifilament yarn of 100 decitex / 96 filaments (single yarn fineness of 1.04 decitex) as a weft and a woven fabric having the structure shown in FIG. The same finishing process as above is applied, and the warp density is 195 yarns / 2.54 cm
(The surface texture is 156 yarns / 2.54 cm, the back texture 39 yarns / 2.54 cm, the back warp density is 25% of the surface warp yarn density), and the weft yarn density is 93 yarns /
A high-density woven fabric of the present invention having a surface factor of 2.54 cm and a cover factor of 2490 was obtained.
【００２４】実施例４ 経緯糸を実施例３と同じ糸使いで、組織を図５の組織図
とし、経糸密度を２６４本／2.54cm（表経糸密度１７６
本／2.54cm、裏経糸密度８８本／2.54cm、裏経糸密度は
表経糸密度の５０％）、緯糸密度を９１本／2.54cmと
し、表組織のカバーファクターを２６７０とすること以
外は実施例３と同様にして本発明の高密度織物を得た。Example 4 Using the same weft yarns as in Example 3 with the structure shown in FIG. 5, the warp density was 264 yarns / 2.54 cm (surface warp density 176).
Example: Except that the warp density was 88 yarns / 2.54 cm, the back warp density was 50% of the surface warp density, the weft density was 91 yarns / 2.54 cm, and the cover factor of the surface structure was 2670. In the same manner as in Example 3, a high-density woven fabric of the present invention was obtained.
【００２５】比較例４ 経緯糸を実施例３と同じ糸使いで、組織を図６の組織図
とし、経糸密度を１９６本／2.54cm（表緯糸密度１６８
本／2.54cm、裏緯糸密度２８本／2.54cm、裏緯糸密度は
表緯糸密度の１７％）、緯糸密度を８０本／2.54cmと
し、表組織のカバーファクターを２４８０とすること以
外は実施例３と同様にして比較例の織物を得た。Comparative Example 4 Using the same weft yarns as in Example 3 and the structure as shown in FIG. 6, the warp density was 196 yarns / 2.54 cm (table weft density 168).
Example: except that the weft density is 80 yarns / 2.54 cm, the weft density is 80 yarns / 2.54 cm, and the cover factor of the surface texture is 2480. In the same manner as in Example 3, a woven fabric of Comparative Example was obtained.
【００２６】比較例５ 実施例３において、経糸をポリエステルマルチフィラメ
ント糸１００デシテックス／１４４フィラメント（単糸
繊度１．０４デシテックス）からポリエステルマルチフ
ィラメント糸１００デシテックス／４８フィラメント
（単糸繊度２．０８デシテックス）に替えること以外は
実施例３と同様にして比較例の織物を得た。得られた実
施例３〜４及び比較例４〜５の織物の評価結果を併せて
表２に示す。Comparative Example 5 In Example 3, the warp was changed from polyester multifilament yarn 100 dtex / 144 filament (single yarn fineness 1.04 dtex) to polyester multifilament yarn 100 dtex / 48 filament (single yarn fineness 2.08 dtex). A woven fabric of a comparative example was obtained in the same manner as in Example 3 except for changing the above. Table 2 also shows the evaluation results of the obtained woven fabrics of Examples 3 to 4 and Comparative Examples 4 to 5.
【００２７】[0027]
【表２】 [Table 2]
【００２８】表２からも明らかなように、本発明の実施
例３及び実施例４の織物は、肉厚感に富み、柔軟性に優
れたものであり、耐水性能、撥水性能の面で優れてお
り、吸汗発散性といった着用快適性が十分発揮できる織
物であった。これに対して、裏組織の緯糸の比率が小さ
い比較例４及び表組織を構成する糸条の単糸繊度の大き
い比較例５は、織物の柔軟性に劣るものであった。As is clear from Table 2, the woven fabrics of Examples 3 and 4 of the present invention are rich in wall thickness and excellent in flexibility, and are excellent in water resistance and water repellency. The fabric was excellent and could sufficiently exhibit wearing comfort such as sweat-absorbing properties. On the other hand, Comparative Example 4 in which the ratio of the weft in the back structure was small and Comparative Example 5 in which the single yarn fineness of the yarn constituting the surface structure was large were inferior in the flexibility of the woven fabric.
【００２９】[0029]
【発明の効果】本発明によれば、柔軟性に優れ肉厚感の
ある風合いを有しながら防水性にも優れた織物であるの
で、コートやブルゾン等のカジュアル衣料やスキーやマ
リン、アスレチック等のスポーツ衣料として好適な素材
を提供できる。さらに裏面に吸水加工を施した場合に
は、優れた吸水発散性を発揮して着用快適性を向上させ
ることができる。According to the present invention, since it is a woven fabric which is excellent in flexibility and excellent in waterproofness while having a thick feeling, it can be used for casual clothing such as coats and blousons, skis, marine, athletic and the like. A suitable material for sports clothing. Further, when the back surface is subjected to a water absorbing process, it is possible to exhibit excellent water absorbing and dispersing properties and to improve wearing comfort.
【図1】本発明に用いることのできる織物組織の例を示
す組織図である。FIG. 1 is a structure diagram showing an example of a woven structure that can be used in the present invention.
【図２】本発明に用いることのできる織物組織の例を示
す組織図である。FIG. 2 is a structure diagram showing an example of a woven structure that can be used in the present invention.
【図３】比較例で用いた織物組織の組織図である。FIG. 3 is a structure diagram of a fabric structure used in a comparative example.
【図４】本発明に用いることのできる織物組織の例を示
す組織図である。FIG. 4 is a structure diagram showing an example of a woven structure that can be used in the present invention.
【図５】本発明に用いることのできる織物組織の例を示
す組織図である。FIG. 5 is a structure diagram showing an example of a woven structure that can be used in the present invention.
【図６】比較例で用いた織物組織の組織図である。FIG. 6 is a structure diagram of a fabric structure used in a comparative example.
───────────────────────────────────────────────────── フロントページの続き Ｆターム(参考） 4L033 AA04 AB05 AC03 AC07 AC15 BA21 CA17 CA25 4L048 AA14 AA19 BA10 BA11 CA00 CA07 CA08 CA15 ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 4L033 AA04 AB05 AC03 AC07 AC15 BA21 CA17 CA25 4L048 AA14 AA19 BA10 BA11 CA00 CA07 CA08 CA15
Claims (3)
織を構成する糸条は、単糸繊度が１．２デシテックス以
下である合成繊維であり、表組織部分のカバーファクタ
ーが２０００以上、裏組織の緯糸密度が表組織の緯糸密
度の２５〜１００％で、該織物の少なくとも表面には撥
水処理が施されていることを特徴とする高密度織物。1. A woven fabric having a weft double structure, wherein the yarn constituting the surface structure is a synthetic fiber having a single yarn fineness of 1.2 decitex or less, and a cover factor of the surface structure portion of 2000 or more. A high-density woven fabric, wherein the weft density of the back structure is 25 to 100% of the weft density of the front structure, and at least the surface of the woven fabric has been subjected to a water-repellent treatment.
織を構成する糸条は、単糸繊度が１．２デシテックス以
下である合成繊維であり、表組織部分のカバーファクタ
ーが２０００以上、裏組織の経糸密度が表組織の経糸密
度の２５〜１００％で、該織物の少なくとも表面には撥
水処理が施されていることを特徴とする高密度織物。2. A woven fabric having a warp double structure, wherein the yarn constituting the surface structure is a synthetic fiber having a single yarn fineness of 1.2 decitex or less, and a cover factor of the surface structure portion of 2000 or more. A high-density woven fabric, wherein the warp density of the back structure is 25 to 100% of the warp density of the front structure, and at least the surface of the woven fabric has been subjected to a water-repellent treatment.
とを特徴とする請求項１または請求項２記載の高密度織
物。3. The high-density woven fabric according to claim 1, wherein the back surface of the woven fabric is subjected to a water absorbing process.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000397829A JP2001348754A (en) | 2000-03-31 | 2000-12-27 | High-density woven fabric |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000-98173 | 2000-03-31 | ||
| JP2000098173 | 2000-03-31 | ||
| JP2000397829A JP2001348754A (en) | 2000-03-31 | 2000-12-27 | High-density woven fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2001348754A true JP2001348754A (en) | 2001-12-21 |
Family
ID=26589175
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000397829A Pending JP2001348754A (en) | 2000-03-31 | 2000-12-27 | High-density woven fabric |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2001348754A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003278050A (en) * | 2002-03-19 | 2003-10-02 | Ventex Co Ltd | Quick moisture-absorbing and drying woven or knitted fabric having waterproof function |
| JP2008231585A (en) * | 2007-03-16 | 2008-10-02 | Teijin Fibers Ltd | Method for producing moisture permeable and waterproof fabric, moisture permeable and waterproof fabric and fibrous product |
| RU2388857C2 (en) * | 2005-09-20 | 2010-05-10 | Джапэн Гор-Текс Инк. | Sealing tape and textile product that uses it |
| JP2016204768A (en) * | 2015-04-16 | 2016-12-08 | 東洋染工株式会社 | Clothing fabric |
| CN107109719A (en) * | 2014-12-23 | 2017-08-29 | 法国欧普泰克公司 | Fabric for manufacturing fireproof clothes |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62276050A (en) * | 1986-05-21 | 1987-11-30 | ユニチカ株式会社 | Double surface functional cloth |
-
2000
- 2000-12-27 JP JP2000397829A patent/JP2001348754A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62276050A (en) * | 1986-05-21 | 1987-11-30 | ユニチカ株式会社 | Double surface functional cloth |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003278050A (en) * | 2002-03-19 | 2003-10-02 | Ventex Co Ltd | Quick moisture-absorbing and drying woven or knitted fabric having waterproof function |
| RU2388857C2 (en) * | 2005-09-20 | 2010-05-10 | Джапэн Гор-Текс Инк. | Sealing tape and textile product that uses it |
| JP2008231585A (en) * | 2007-03-16 | 2008-10-02 | Teijin Fibers Ltd | Method for producing moisture permeable and waterproof fabric, moisture permeable and waterproof fabric and fibrous product |
| CN107109719A (en) * | 2014-12-23 | 2017-08-29 | 法国欧普泰克公司 | Fabric for manufacturing fireproof clothes |
| JP2016204768A (en) * | 2015-04-16 | 2016-12-08 | 東洋染工株式会社 | Clothing fabric |
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