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JP2001220321A - Hair beauty enhancer - Google Patents

Hair beauty enhancer

Info

Publication number
JP2001220321A
JP2001220321A JP2000028306A JP2000028306A JP2001220321A JP 2001220321 A JP2001220321 A JP 2001220321A JP 2000028306 A JP2000028306 A JP 2000028306A JP 2000028306 A JP2000028306 A JP 2000028306A JP 2001220321 A JP2001220321 A JP 2001220321A
Authority
JP
Japan
Prior art keywords
hair
agent
imparting
treatment
depth
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000028306A
Other languages
Japanese (ja)
Inventor
Shinobu Nagase
忍 長瀬
Masato Oshika
正人 大鹿
Takao Shinozaki
孝夫 篠崎
Hiroshi Ikeda
浩 池田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Corp
Original Assignee
Kao Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corp filed Critical Kao Corp
Priority to JP2000028306A priority Critical patent/JP2001220321A/en
Publication of JP2001220321A publication Critical patent/JP2001220321A/en
Pending legal-status Critical Current

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Abstract

(57)【要約】 【解決手段】 毛髪処理前後において、ゴニオフォトメ
ーターにより測定した毛髪の明度減少率を0.02〜
0.90の範囲にする成分を有効成分とする毛髪の立体
感付与剤、透明感付与剤及び深み感付与剤。 【効果】 毛髪に立体感、透明感又は深み感を付与する
効果に優れる。
(57) [Summary] A hair lightness reduction rate measured by a goniophotometer before and after hair treatment is 0.02 to
An agent for imparting a three-dimensional effect to hair, an agent for imparting clarity, and an agent for imparting depth to hair, comprising an active ingredient having a content of 0.90. [Effect] It is excellent in the effect of giving the hair a three-dimensional feeling, transparency or depth.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、毛髪に立体感、透
明感、深み感を付与する毛髪美観向上剤に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an agent for improving the beauty of hair which imparts three-dimensional appearance, transparency and depth to hair.

【0002】[0002]

【従来の技術】従来、毛髪のつや等の光学的性質を改善
するため、種々の毛髪化粧料が使用されている。しか
し、これらの毛髪化粧料は、毛髪表面又は表面近傍のキ
ューティクル(毛小皮)に作用させることを目的とする
ものであり、その効果は一時的なものであったり、十分
なものではなかった。
2. Description of the Related Art Conventionally, various hair cosmetics have been used to improve optical properties such as gloss of hair. However, these hair cosmetics are intended to act on a cuticle (hair cuticle) on or near the surface of the hair, and the effect is temporary or insufficient. .

【0003】[0003]

【発明が解決しようとする課題】本発明の目的は、毛髪
に立体感、透明感又は深み感を付与する効果に優れた剤
を提供することにある。
SUMMARY OF THE INVENTION An object of the present invention is to provide an agent excellent in the effect of imparting three-dimensional feeling, transparency or depth to hair.

【0004】[0004]

【課題を解決するための手段】本発明者らは、毛髪処理
前後の明度の減少率が特定の範囲になる成分を用いれ
ば、毛髪に立体感、透明感又は深み感を付与し、毛髪の
美観を向上できることを見出した。
Means for Solving the Problems The inventors of the present invention provide a hair with a three-dimensional effect, a transparent feeling or a deep feeling by using a component in which the lightness reduction rate before and after the hair treatment is within a specific range, and imparting a sense of depth to the hair. I found that I could improve my aesthetics.

【0005】本発明は、毛髪処理前後において、ゴニオ
フォトメーターにより測定した毛髪の明度減少率を0.
02〜0.90の範囲にする成分を有効成分とする毛髪
の立体感付与剤、透明感付与剤又は深み感付与剤(以
下、これらを総称して「毛髪美観向上剤」ということが
ある)を提供するものである。
According to the present invention, the hair lightness reduction rate measured by a goniophotometer before and after hair treatment is 0.1%.
A three-dimensional effect imparting agent, a transparency imparting agent or a depth imparting agent comprising a component in the range of 02 to 0.90 as an active ingredient (hereinafter, these may be collectively referred to as "hair beauty improving agent"). Is provided.

【0006】本発明において、毛髪の立体感とは、毛髪
外観に関する官能表現であり、毛髪が立体的に奥行きを
持って見える感覚をいう。透明感とは、毛髪外観に関す
る官能表現であり、毛髪自身が透きとおった質感を伴っ
たり、あるいは髪色がくすみなく見える感覚をいう。ま
た、深み感とは、毛髪外観に関する官能表現であり、毛
髪自身に奥行きを感じたり、あるいは見える髪色に深み
や奥行きを感じることをいう。
In the present invention, the three-dimensional appearance of the hair is a sensory expression relating to the appearance of the hair, and refers to a feeling that the hair looks three-dimensionally and deeply. Transparency is a sensory expression related to the appearance of hair, and refers to a feeling that the hair itself has a transparent texture or that the hair color looks dull. In addition, the sense of depth is a sensory expression related to the appearance of the hair, and means that the hair itself feels depth or the depth and depth of the visible hair color.

【0007】[0007]

【発明の実施の形態】本発明の毛髪処理前後における毛
髪の明度減少率は、処理前の標準乾燥状態における毛髪
の明度と処理後の標準乾燥状態における毛髪の明度とを
対比することにより測定できる。ここで、標準乾燥状態
とは、温度20℃、湿度60%RH、無風下で毛髪を釣
り下げて24時間乾燥した状態をいう。また、毛髪処理
は、処理剤の液温度40℃、1時間、浴比(毛髪/処理
剤重量比)1/10で毛髪繊維束を処理後、すすぎ時の
浴比(毛髪/イオン交換水重量比)1/100〜1/1
000で水中に30秒間浸漬し、引き上げ後に乾燥タオ
ルで余剰水分をふきとることにより行う。この処理前及
び処理後において、毛髪の明度を測定する。明度の測定
は、ゴニオフォトメーター(村上色彩技術研究所製、G
CMS−3型)を用い、毛髪繊維束の根元上方から斜め
45°の角度で毛髪に向かって白色光を入射させ、入射
光・毛髪繊維と同じ平面内かつ毛髪に対して入射光と同
じ側の半平面内で毛髪に対し垂直な方向から受光測定し
た時の明度(L値)を測定する(図1)。処理前の明度
をL0、処理後の明度をL0′とし、次式により、明度減
少率を求める。
BEST MODE FOR CARRYING OUT THE INVENTION The lightness reduction rate of hair before and after hair treatment of the present invention can be measured by comparing the lightness of hair in a standard dry state before treatment with the lightness of hair in a standard dry state after treatment. . Here, the standard dry state refers to a state where the hair is hung under a wind of 20 ° C., a humidity of 60% RH, and no wind, and dried for 24 hours. The hair treatment is performed by treating the hair fiber bundle at a bath ratio (hair / treatment agent weight ratio) of 1/10 at a solution temperature of the treatment agent of 40 ° C. for 1 hour, and then rinsing the bath ratio (hair / ion-exchanged water weight). Ratio) 1/100 to 1/1
Immersion in water at 000 for 30 seconds, and after lifting, wipe off excess moisture with a dry towel. Before and after the treatment, the lightness of the hair is measured. The brightness was measured using a goniometer (Murakami Color Research Laboratory, G
Using CMS-3), white light is directed toward the hair at an angle of 45 ° from above the root of the hair fiber bundle, and is in the same plane as the incident light and the hair fibers and on the same side as the incident light with respect to the hair. The lightness (L value) is measured when light is measured from a direction perpendicular to the hair within the half-plane (FIG. 1). The lightness before the processing is L 0 and the lightness after the processing is L 0 ′, and the lightness reduction rate is obtained by the following equation.

【0008】[0008]

【数1】 (Equation 1)

【0009】本発明においては、この明度減少率が0.
02〜0.90、好ましくは0.05〜0.90、特に
好ましくは0.1〜0.9の範囲になることが必要であ
る。
In the present invention, the lightness reduction rate is set to 0.1.
It is necessary to be in the range of 02 to 0.90, preferably 0.05 to 0.90, particularly preferably 0.1 to 0.9.

【0010】明度減少率をこのような範囲にする成分と
しては、例えば分子中にアミノ基、ヒドロキシル基、カ
ルボニル基又はカルボキシル基を有し、分子量が30〜
500である化合物が挙げられる。このような化合物
は、更に前記以外の基、例えばメルカプト基、グアニジ
ノ基等を有していてもよい。
[0010] As a component for controlling the lightness reduction rate within such a range, for example, an amino group, a hydroxyl group, a carbonyl group or a carboxyl group in the molecule and a molecular weight of 30 to
500. Such a compound may further have a group other than the above, for example, a mercapto group, a guanidino group and the like.

【0011】このような化合物としては、例えばα−ヒ
ドロキシ酸、β−ヒドロキシ酸、1,2−ジカルボン
酸、1,3−ジカルボン酸、芳香族カルボン酸、アミノ
酸、ペプチド、N−アシルアミノ酸、尿素、尿素誘導
体、グアニジン、グアニジン誘導体、1級アミン、アル
コール類、芳香族アルコール、ジアルキルケトン、炭酸
アルキレン、アルキレングリコール類、ポリアルキレン
グリコール類及びその誘導体等が挙げられ、特にα−ヒ
ドロキシ酸、β−ヒドロキシ酸、1,2−ジカルボン
酸、1,3−ジカルボン酸、芳香族カルボン酸、アミノ
酸、尿素、グアニジン、芳香族アルコール、ジアルキル
ケトン、炭酸アルキレン、アルキレングリコール類、ポ
リアルキレングリコール類及びその誘導体が好ましい。
Examples of such compounds include α-hydroxy acids, β-hydroxy acids, 1,2-dicarboxylic acids, 1,3-dicarboxylic acids, aromatic carboxylic acids, amino acids, peptides, N-acyl amino acids, ureas , Urea derivatives, guanidine, guanidine derivatives, primary amines, alcohols, aromatic alcohols, dialkyl ketones, alkylene carbonates, alkylene glycols, polyalkylene glycols and derivatives thereof, especially α-hydroxy acids, β- Hydroxy acids, 1,2-dicarboxylic acids, 1,3-dicarboxylic acids, aromatic carboxylic acids, amino acids, ureas, guanidines, aromatic alcohols, dialkyl ketones, alkylene carbonates, alkylene glycols, polyalkylene glycols and derivatives thereof preferable.

【0012】具体的には、例えばリンゴ酸、コハク酸、
マレイン酸、サリチル酸、マロン酸、マンデル酸、乳
酸、グリコール酸、グリシン、尿素、フェニル尿素、シ
トルリン、チオ尿素、グアニジン、フェニルグアニジ
ン、ベンジルグアニジン、3−メトキシ−2−ヒドロキ
シプロピルグアニジン、2−(2−ヒドロキシエトキ
シ)エチルグアニジン、モノエタノールアミン、エタノ
ール、n−プロパノール、ベンジルアルコール、ベンジ
ルオキシエタノール、サリチル酸メチル、サリチル酸エ
チレングリコール、ジエチルケトン、炭酸プロピレン、
ジプロピレングリコール、プロピルプロピレングリコー
ル、エチルカルビトール、N−メチル−2−ピロリドン
等が挙げられる。
Specifically, for example, malic acid, succinic acid,
Maleic acid, salicylic acid, malonic acid, mandelic acid, lactic acid, glycolic acid, glycine, urea, phenylurea, citrulline, thiourea, guanidine, phenylguanidine, benzylguanidine, 3-methoxy-2-hydroxypropylguanidine, 2- (2 -Hydroxyethoxy) ethylguanidine, monoethanolamine, ethanol, n-propanol, benzyl alcohol, benzyloxyethanol, methyl salicylate, ethylene glycol salicylate, diethyl ketone, propylene carbonate,
Examples include dipropylene glycol, propyl propylene glycol, ethyl carbitol, N-methyl-2-pyrrolidone, and the like.

【0013】このような化合物は、1種以上を用いるこ
とができ、毛髪化粧料中に含有させる場合、全組成中に
0.1〜50重量%、特に0.5〜30重量%、更に1
〜20重量%含有させるのが、より穏やかな処理条件で
効果が得られるので好ましい。
One or more of such compounds can be used, and when contained in hair cosmetics, 0.1 to 50% by weight, particularly 0.5 to 30% by weight, and more preferably 1 to 50% by weight in the total composition.
It is preferred that the content be contained in an amount of up to 20% by weight because the effect can be obtained under milder processing conditions.

【0014】本発明の毛髪美観向上剤を毛髪化粧料に含
有させる場合には、前記化合物のほか、通常毛髪化粧料
に用いられる成分、例えばカチオン性界面活性剤、アニ
オン性界面活性剤、ノニオン性界面活性剤、両イオン性
界面活性剤、高級アルコール、酸性染料、酸化染料、シ
リコーン類、カチオン性ポリマー、還元剤、酸化剤、溶
剤等を、本発明の効果を損わない範囲で適宜含有させる
ことができる。
When the hair beauty improving agent of the present invention is contained in hair cosmetics, in addition to the above-mentioned compounds, components usually used in hair cosmetics, such as cationic surfactants, anionic surfactants, and nonionic surfactants Surfactants, amphoteric surfactants, higher alcohols, acid dyes, oxidation dyes, silicones, cationic polymers, reducing agents, oxidizing agents, solvents and the like are appropriately contained within a range not to impair the effects of the present invention. be able to.

【0015】本発明の毛髪美観向上剤を含有する毛髪化
粧料は、各成分を混合することにより製造でき、その形
態は特に制限されず、例えば液状、ゲル状、クリーム
状、エアゾール等とすることができる。
The hair cosmetic containing the hair beauty improving agent of the present invention can be produced by mixing the respective components, and the form thereof is not particularly limited. For example, the composition may be liquid, gel, cream, aerosol, etc. Can be.

【0016】また、本発明の毛髪美観向上剤を配合した
毛髪化粧料は、pH2〜12、特にpH2〜6あるいはpH
8〜10であるのが好ましい。好ましいpHを得るために
は、酸又はアルカリを加えて調整すればよい。
The hair cosmetic containing the hair beauty improver of the present invention has a pH of 2 to 12, especially pH 2 to 6,
It is preferably 8 to 10. In order to obtain a preferable pH, the pH may be adjusted by adding an acid or an alkali.

【0017】[0017]

【発明の効果】本発明の毛髪美観向上剤は、毛髪に立体
感、透明感又は深み感を付与する効果に優れたものであ
る。
The hair beauty improving agent of the present invention is excellent in imparting a three-dimensional effect, transparency or depth to hair.

【0018】実施例1〜14 表1〜3に示す各成分を混合して毛髪美観向上剤を含有
する毛髪化粧料製造し、これを使用したときの毛髪の立
体感、透明感及び深み感を評価した。各評価では、パー
マ処理(2回)及びブリーチ処理(2回)された長さ2
0cm、10gの毛束を用い、表中に示した条件で処理し
た後、評価した。なお、毛束のパーマ処理は1剤〔チオ
グリコール酸アンモニウム8%、水バランス、pH9.
0(強アンモニア水で調整)〕で30℃、15分間処
理、次いで2剤〔臭素酸ナトリウム7%、水バランス、
pH9.0(強アンモニア水で調整)〕で30℃、10
分間処理した。ブリーチ処理は、ブリーチ剤〔過酸化水
素8.5%、水バランス、pH9.5(強アンモニア水
で調整)〕で、30℃、20分間処理した。また、パー
マ剤、ブリーチ剤ともに浴比(毛髪/剤)は1/1とし
た。結果を表1〜3に併せて示す。
Examples 1 to 14 Each of the components shown in Tables 1 to 3 was mixed to produce a hair cosmetic containing a hair beauty improving agent, and the three-dimensional appearance, transparency and depth of the hair when used were evaluated. evaluated. In each evaluation, the length 2 permed (2 times) and bleached (2 times)
A hair bundle of 0 cm and 10 g was treated under the conditions shown in the table and evaluated. In addition, perm treatment of the hair bundle is performed with one agent [ammonium thioglycolate 8%, water balance, pH 9.
0 (adjusted with strong ammonia water)] at 30 ° C. for 15 minutes, then 2 agents [7% sodium bromate, water balance,
pH 9.0 (adjusted with strong ammonia water)] at 30 ° C, 10
Minutes. The bleaching treatment was performed at 30 ° C. for 20 minutes with a bleaching agent [8.5% hydrogen peroxide, water balance, pH 9.5 (adjusted with strong ammonia water)]. The bath ratio (hair / agent) was set to 1/1 for both the permanent agent and the bleaching agent. The results are shown in Tables 1 to 3.

【0019】(評価方法)20cm、10gの毛束を表中
に示した条件で処理し、処理前の毛束と比較して、10
人の専門パネラーにより、以下の基準で官能評価した。
10人の平均点を求め、平均点が3.5以上を◎、2.
5〜3.4を○、1.5〜2.4を△、1.4以下を×
として示した。
(Evaluation method) A hair bundle of 20 cm and 10 g was treated under the conditions shown in the table.
Sensory evaluation was performed by a human expert panelist according to the following criteria.
The average score of 10 people was determined, and the average score was 3.5 or more.
5 to 3.4: ○, 1.5 to 2.4: Δ, 1.4 or less: ×
As shown.

【0020】<毛髪の立体感> 毛髪に立体感を強く感じる ;4点 毛髪に立体感をやや感じる ;3点 どちらとも言えない ;2点 毛髪に立体感を感じない ;1点<Three-dimensional feeling of hair> Strong feeling of three-dimensional effect on hair; 4 points A little feeling of three-dimensional effect on hair; 3 points Neither can be said; 2 points No feeling of three-dimensional effect on hair; 1 point

【0021】<毛髪の透明感> 毛髪や髪色に透明感を強く感じる ;4点 毛髪や髪色に透明感をやや感じる ;3点 どちらとも言えない ;2点 毛髪や髪色に透明感を感じない ;1点<Transparency of hair> Transparency of hair and hair color is strongly felt; 4 points Transparency of hair and hair color is slightly felt; 3 points Neither can be said; 2 points Transparency of hair and hair color I don't feel; 1 point

【0022】<毛髪の深み感> 毛髪や髪色に深み感を強く感じる ;4点 毛髪や髪色に深み感をやや感じる ;3点 どちらとも言えない ;2点 毛髪や髪色に深み感を感じない ;1点<Deepness of Hair> A deep feeling is felt in the hair and hair color; 4 points A deep feeling is felt in the hair and hair color; 3 points Neither can be said; 2 points A deep feeling in the hair and hair color I don't feel; 1 point

【0023】[0023]

【表1】 [Table 1]

【0024】[0024]

【表2】 [Table 2]

【0025】[0025]

【表3】 [Table 3]

【0026】実施例15 表4に示す毛髪美観向上剤を含むシャンプー、リンスを
製造した。これらを用いてシャンプー/リンス処理を常
法により30回繰り返したときの美観向上効果を実施例
1〜14と同様にして評価した。結果を表5に示す。
Example 15 Shampoos and rinses containing the hair beauty improvers shown in Table 4 were produced. Using these, the shampoo / rinsing treatment was repeated 30 times by a conventional method, and the effect of improving the aesthetic appearance was evaluated in the same manner as in Examples 1 to 14. Table 5 shows the results.

【0027】[0027]

【表4】 [Table 4]

【0028】[0028]

【表5】 [Table 5]

【0029】実施例16 表6に示す毛髪美観向上剤を含む染毛剤を製造し、処理
後の美観向上効果を実施例1〜14と同様にして評価し
た。結果を表7に示す。
Example 16 A hair dye containing the hair beauty improving agent shown in Table 6 was produced, and the effect of improving the beauty after treatment was evaluated in the same manner as in Examples 1 to 14. Table 7 shows the results.

【0030】[0030]

【表6】 [Table 6]

【0031】[0031]

【表7】 [Table 7]

【0032】実施例17 表8に示す毛髪美観向上剤を含むパーマ剤を製造し、パ
ーマ1剤処理後、パーマ2剤処理を行い、実施例1〜1
4と同様にして美観向上効果を評価した。結果を表9に
示す。
Example 17 A permanent agent containing a hair beauty improving agent as shown in Table 8 was produced, and after one permanent agent treatment, two permanent agent treatments were performed.
In the same manner as in Example 4, the aesthetic improvement effect was evaluated. Table 9 shows the results.

【0033】[0033]

【表8】 [Table 8]

【0034】[0034]

【表9】 [Table 9]

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明において、毛髪の明度を測定する方法を
示す図である。
FIG. 1 is a diagram showing a method for measuring the lightness of hair in the present invention.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) A61K 7/13 A61K 7/13 (72)発明者 篠崎 孝夫 東京都墨田区文花2−1−3 花王株式会 社研究所内 (72)発明者 池田 浩 東京都墨田区文花2−1−3 花王株式会 社研究所内 Fターム(参考) 4C083 AB032 AC072 AC152 AC172 AC182 AC242 AC292 AC302 AC312 AC342 AC392 AC482 AC542 AC582 AC682 AC692 AC792 AC842 AC852 AD282 BB53 CC32 CC33 CC34 CC36 CC38 CC39 DD08 DD31 DD41 EE25 EE26 EE28 ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 7 Identification Symbol FI Theme Court ゛ (Reference) A61K 7/13 A61K 7/13 (72) Inventor Takao Shinozaki 2-1-3 Bunka, Sumida-ku, Tokyo Kao Hiroshi Ikeda (72) Inventor Hiroshi Ikeda 2-1-3 Bunka, Sumida-ku, Tokyo F-term (reference) 4C083 AB032 AC072 AC152 AC172 AC182 AC242 AC292 AC302 AC312 AC342 AC392 AC482 AC542 AC582 AC682 AC692 AC792 AC842 AC852 AD282 BB53 CC32 CC33 CC34 CC36 CC38 CC39 DD08 DD31 DD41 EE25 EE26 EE28

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 毛髪処理前後において、ゴニオフォトメ
ーターにより測定した毛髪の明度減少率を0.02〜
0.90の範囲にする成分を有効成分とする毛髪の立体
感付与剤。
1. The hair lightness reduction rate measured by a goniophotometer before and after hair treatment is 0.02 to
An agent for imparting a three-dimensional effect to hair, comprising an active ingredient having an ingredient in the range of 0.90.
【請求項2】 毛髪処理前後において、ゴニオフォトメ
ーターにより測定した毛髪の明度減少率を0.02〜
0.90の範囲にする成分を有効成分とする毛髪の透明
感付与剤。
2. The hair lightness reduction rate measured by a goniophotometer before and after the hair treatment is 0.02 to 2.
An agent for imparting clarity to hair, comprising as an active ingredient an ingredient in the range of 0.90.
【請求項3】 毛髪処理前後において、ゴニオフォトメ
ーターにより測定した毛髪の明度減少率を0.02〜
0.90の範囲にする成分を有効成分とする毛髪の深み
感付与剤。
3. A hair lightness reduction rate measured by a goniophotometer before and after hair treatment of 0.02 to
An agent for imparting a sense of depth to hair, comprising an active ingredient having an ingredient in the range of 0.90.
JP2000028306A 2000-02-04 2000-02-04 Hair beauty enhancer Pending JP2001220321A (en)

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Country Link
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WO2004047777A1 (en) * 2002-11-26 2004-06-10 Kao Corporation Cosmetic hair preparation
JP2004189727A (en) * 2002-11-26 2004-07-08 Kao Corp Hair cosmetics
WO2005011623A1 (en) * 2003-08-01 2005-02-10 Kao Corporation Hair grooming preparation
JP2006206585A (en) * 2004-12-28 2006-08-10 Kao Corp How to increase the saturation of hair
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US8518423B2 (en) 2004-12-28 2013-08-27 Kao Corporation Method for enhancing chroma of hair
JP2021521167A (en) * 2018-04-12 2021-08-26 ルブリゾル アドバンスド マテリアルズ, インコーポレイテッド Hair modification composition and its method

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004047777A1 (en) * 2002-11-26 2004-06-10 Kao Corporation Cosmetic hair preparation
JP2004189727A (en) * 2002-11-26 2004-07-08 Kao Corp Hair cosmetics
US7981405B2 (en) 2002-11-26 2011-07-19 Kao Corporation Cosmetic hair preparation
WO2005011623A1 (en) * 2003-08-01 2005-02-10 Kao Corporation Hair grooming preparation
JPWO2005011623A1 (en) * 2003-08-01 2007-10-11 花王株式会社 Hair cosmetics
US8512686B2 (en) 2003-08-01 2013-08-20 Kao Corporation Hair grooming preparation
JP2006206585A (en) * 2004-12-28 2006-08-10 Kao Corp How to increase the saturation of hair
US8518423B2 (en) 2004-12-28 2013-08-27 Kao Corporation Method for enhancing chroma of hair
JP2013056835A (en) * 2011-09-07 2013-03-28 Kao Corp Oxidation type hair dye or bleaching agent composition
JP2021521167A (en) * 2018-04-12 2021-08-26 ルブリゾル アドバンスド マテリアルズ, インコーポレイテッド Hair modification composition and its method
JP7377813B2 (en) 2018-04-12 2023-11-10 ルブリゾル アドバンスド マテリアルズ, インコーポレイテッド Hair modification composition and method thereof

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