JP2001288005A - Heat transpiration insecticidal composition and heat transpiration insecticidal method using the same - Google Patents
Heat transpiration insecticidal composition and heat transpiration insecticidal method using the sameInfo
- Publication number
- JP2001288005A JP2001288005A JP2000098708A JP2000098708A JP2001288005A JP 2001288005 A JP2001288005 A JP 2001288005A JP 2000098708 A JP2000098708 A JP 2000098708A JP 2000098708 A JP2000098708 A JP 2000098708A JP 2001288005 A JP2001288005 A JP 2001288005A
- Authority
- JP
- Japan
- Prior art keywords
- manufactured
- added
- insecticidal composition
- composition
- benzoic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、加熱蒸散用殺虫組
成物及びこれを用いる加熱蒸散殺虫方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an insecticidal composition for heat transpiration and a heat transpiration insecticidal method using the same.
【0002】[0002]
【発明が解決しようとする課題】殺虫組成物中に多孔質
吸液芯の一部を浸漬して、該芯に殺虫組成物を吸液さ
せ、該芯の上部を加熱することにより吸液された殺虫組
成物を蒸散させる加熱蒸散殺虫方法において、長時間に
わたって安定した殺虫組成物の蒸散を行い、安定した殺
虫効果を得ることは困難であった。そこで、安定した殺
虫組成物の蒸散を可能とし、安定した殺虫効果をあげる
ことのできる加熱蒸散用殺虫組成物の開発が望まれてい
た。A part of the porous absorbent core is immersed in the insecticide composition, the insecticide composition is absorbed in the core, and the liquid is absorbed by heating the upper part of the core. In the heat transpiration insecticidal method for evaporating an insecticidal composition, it has been difficult to obtain a stable insecticidal effect by performing stable evaporation of the insecticidal composition for a long time. Therefore, development of an insecticidal composition for heat evaporation that enables a stable insecticidal composition to evaporate and achieves a stable insecticidal effect has been desired.
【0003】[0003]
【課題を解決するための手段】本発明は、上述の課題を
解決するものであり、有機酸を、ピレスロイド化合物及
び沸点範囲を特定した飽和炭化水素とともに用い、かつ
各成分量範囲を特定した加熱蒸散用殺虫組成物により、
殺虫組成物の安定した蒸散及び、長時間にわたる安定し
た殺虫効力の維持が可能なることを見出し本発明に至っ
た。即ち、本発明は(a)ピレスロイド化合物を０．０１
〜２０重量％、(b)有機酸を０．００１〜７重量％及び
(c)沸点が１８０〜３１０℃の飽和炭化水素を７３〜９
９．９８９重量％含有する加熱蒸散用殺虫組成物（以
下、本組成物と記す）及び本組成物を蒸散させることを
特徴とする加熱蒸散殺虫方法（以下、本方法と記す）に
関するものである。SUMMARY OF THE INVENTION The present invention has been made to solve the above-mentioned problems, and uses an organic acid together with a pyrethroid compound and a saturated hydrocarbon having a specified boiling point range, and a heating method having a specified component amount range. By the insecticidal composition for transpiration,
The present inventors have found that stable transpiration of the insecticidal composition and maintenance of stable insecticidal efficacy over a long period of time are possible, and the present invention has been achieved. That is, the present invention relates to (a) a pyrethroid compound in an amount of 0.01
-20% by weight, (b) 0.001-7% by weight of organic acid and
(c) 73-9 saturated hydrocarbons having a boiling point of 180-310 ° C.
The present invention relates to an insecticidal composition for heat evaporation containing 9.989% by weight (hereinafter referred to as the present composition) and a heat-transpiration insecticidal method characterized by evaporating the present composition (hereinafter referred to as the present method). .
【0004】[0004]
【発明の実施の形態】本組成物に用いられるピレスロイ
ド化合物としては、例えば、２−メチル−３−アリル−
４−オキソ−２−シクロペンテン−１−イル ３−（２
−メチル−１−プロペニル）−２，２−ジメチルシクロ
プロパンカルボキシラート、２−メチル−３−プロパル
ギル−４−オキソ−２−シクロペンテン−１−イル ３
−（２−メチル−１−プロペニル）−２，２−ジメチル
シクロプロパンカルボキシラート、５−プロパルギル−
２−フルフリル ３−（２−メチル−１−プロペニル）
−２，２−ジメチルシクロプロパンカルボキシラート、
１−エチニル−２−メチル−２−ペンテニル ３−（２
−メチル−１−プロペニル）−２，２−ジメチルシクロ
プロパンカルボキシラート、２，３，５，６−テトラフ
ルオロベンジル３−（２，２−ジクロロビニル）−２，
２−ジメチルシクロプロパンカルボキシレート、１−エ
チニル−２−メチル−２−ペンテニル ３−（２−クロ
ロ−２−フルオロビニル）−２，２−ジメチルシクロプ
ロパン−１−カルボキシラート、２，３，５，６−テト
ラフルオロ−４−メチルベンジル ３−（２−メチル−
１−プロペニル）−２，２−ジメチルシクロプロパンカ
ルボキシラート、２，３，５，６−テトラフルオロ−４
−メチルベンジル ３−（２−クロロ−２−フルオロビ
ニル）−２，２−ジメチルシクロプロパンカルボキシラ
ート、２，３，５，６−テトラフルオロ−４−メチルベ
ンジル ３−（１−プロペニル）−２，２−ジメチルシ
クロプロパンカルボキシラート、２，３，５，６−テト
ラフルオロ−４−メチルベンジル ３−（２，２−ジク
ロロビニル）−２，２−ジメチルシクロプロパンカルボ
キシレート、２，３，５，６−テトラフルオロ−４−メ
トキシベンジル ３−（２，２−ジクロロビニル）−
２，２−ジメチルシクロプロパンカルボキシレート、
２，３，５，６−テトラフルオロ−４−メトキシベンジ
ル３−メトキシイミノメチル−２，２−ジメチルシクロ
プロパンカルボキシレート、２，３，５，６−テトラフ
ルオロ−４−メトキシメチルベンジル ３−（２−メチ
ル−１−プロペニル）−２，２−ジメチルシクロプロパ
ンカルボキシラート、２−メチル−４−オキソ−３−
（２−プロピニル）−シクロペント−２−エニル ３−
（２、２−ジクロロビニル）−２、２−ジメチルシクロ
プロパンカルボキシレート、２，３，５，６−テトラフ
ルオロ−４−メトキシメチルベンジル３−（１−プロペ
ニル）−２，２−ジメチルシクロプロパンカルボキシラ
ート、２−メチル−３−アリル−４−オキソ−２−シク
ロペンテン−１−イル ３−（２−メチル−１−プロペ
ニル）−２，２，３，３−テトラメチルシクロプロパン
カルボキシラート、天然ピレトリンなどが挙げられる。
その含有量は本組成物に対し、０．０１〜２０重量％で
ある。BEST MODE FOR CARRYING OUT THE INVENTION As the pyrethroid compound used in the present composition, for example, 2-methyl-3-allyl-
4-oxo-2-cyclopenten-1-yl 3- (2
-Methyl-1-propenyl) -2,2-dimethylcyclopropanecarboxylate, 2-methyl-3-propargyl-4-oxo-2-cyclopenten-1-yl 3
-(2-methyl-1-propenyl) -2,2-dimethylcyclopropanecarboxylate, 5-propargyl-
2-furfuryl 3- (2-methyl-1-propenyl)
-2,2-dimethylcyclopropanecarboxylate,
1-ethynyl-2-methyl-2-pentenyl 3- (2
-Methyl-1-propenyl) -2,2-dimethylcyclopropanecarboxylate, 2,3,5,6-tetrafluorobenzyl 3- (2,2-dichlorovinyl) -2,
2-dimethylcyclopropanecarboxylate, 1-ethynyl-2-methyl-2-pentenyl 3- (2-chloro-2-fluorovinyl) -2,2-dimethylcyclopropane-1-carboxylate, 2,3,5 , 6-Tetrafluoro-4-methylbenzyl 3- (2-methyl-
1-propenyl) -2,2-dimethylcyclopropanecarboxylate, 2,3,5,6-tetrafluoro-4
-Methylbenzyl 3- (2-chloro-2-fluorovinyl) -2,2-dimethylcyclopropanecarboxylate, 2,3,5,6-tetrafluoro-4-methylbenzyl 3- (1-propenyl) -2 , 2-Dimethylcyclopropanecarboxylate, 2,3,5,6-tetrafluoro-4-methylbenzyl 3- (2,2-dichlorovinyl) -2,2-dimethylcyclopropanecarboxylate, 2,3,5 , 6-Tetrafluoro-4-methoxybenzyl 3- (2,2-dichlorovinyl)-
2,2-dimethylcyclopropane carboxylate,
2,3,5,6-tetrafluoro-4-methoxybenzyl 3-methoxyiminomethyl-2,2-dimethylcyclopropanecarboxylate, 2,3,5,6-tetrafluoro-4-methoxymethylbenzyl 3- ( 2-methyl-1-propenyl) -2,2-dimethylcyclopropanecarboxylate, 2-methyl-4-oxo-3-
(2-propynyl) -cyclopent-2-enyl 3-
(2,2-dichlorovinyl) -2,2-dimethylcyclopropanecarboxylate, 2,3,5,6-tetrafluoro-4-methoxymethylbenzyl 3- (1-propenyl) -2,2-dimethylcyclopropane Carboxylate, 2-methyl-3-allyl-4-oxo-2-cyclopenten-1-yl 3- (2-methyl-1-propenyl) -2,2,3,3-tetramethylcyclopropanecarboxylate, natural Pyrethrin and the like.
Its content is 0.01 to 20% by weight based on the composition.
【0005】本組成物に用いられる有機酸としては、例え
ば、安息香酸、フェニル酢酸、メチル安息香酸、ジメチ
ル安息香酸、エチル安息香酸などが挙げられる。その含
有量は本組成物に対し、０．００１〜７重量％である。[0005] Examples of the organic acid used in the present composition include benzoic acid, phenylacetic acid, methylbenzoic acid, dimethylbenzoic acid, and ethylbenzoic acid. Its content is 0.001 to 7% by weight based on the composition.
【0006】本組成物に用いられる沸点が１８０〜３１０℃
の飽和炭化水素は、一種単独でも二種以上の混合物であ
ってもよく、例えば、０号ソルベントＨ（日本石油株式
会社製、沸点２４４〜２６２℃）、０号ソルベントＭ、
（日本石油株式会社製、沸点２１９〜２４７℃）、０号
ソルベントＬ（日本石油株式会社製、沸点１８２〜２１
２℃）、ＩＰソルベント2028（出光石油化学株式会社
製、沸点２１３〜２６２℃）、ノルパー１２（エクソン
化学株式会社製、沸点１８８〜２１９℃）、ノルパー１
３（エクソン化学株式会社製、沸点２２６〜２４３
℃）、ノルパー１５（エクソン化学株式会社製、沸点２
５２〜２７６℃）、アイソパーＭ（エクソン化学株式会
社製、沸点２０７〜２５６℃）、アイソパーＬ（エクソ
ン化学株式会社製、沸点１９０〜２０７℃）、アイソパ
ーＶ（エクソン化学株式会社製、沸点２７８〜３０５
℃）、エクソールＤ８０（エクソン化学株式会社製、沸
点２０１〜２４５℃）、エクソールＤ１１０（エクソン
化学株式会社製、沸点２４３〜２５６℃）、エクソール
Ｄ１３０（エクソン化学株式会社製、沸点２８１〜３０
７℃）等を挙げることができる。[0006] The boiling point used in the composition is 180-310 ° C
May be a single kind or a mixture of two or more kinds. For example, No. 0 Solvent H (manufactured by Nippon Oil Co., Ltd., boiling point: 244 to 262 ° C.), No. 0 Solvent M,
No. 0 Solvent L (manufactured by Nippon Oil Co., Ltd., boiling point 182-21)
2 ° C), IP Solvent 2028 (manufactured by Idemitsu Petrochemical Co., Ltd., boiling point: 213 to 262 ° C), Norper 12 (manufactured by Exxon Chemical Co., Ltd., boiling point: 188 to 219 ° C), Norper 1
3 (boiling point: 226 to 243, manufactured by Exxon Chemical Co., Ltd.)
° C), Norpar 15 (manufactured by Exxon Chemical Co., Ltd., boiling point 2)
52 to 276 ° C.), Isopar M (manufactured by Exxon Chemical Co., boiling point 207 to 256 ° C.), Isopar L (manufactured by Exxon Chemical Co., boiling point 190 to 207 ° C.), Isopar V (manufactured by Exxon Chemical Co., Ltd., boiling point 278 to 278 ° C.) 305
C), Exol D80 (manufactured by Exxon Chemical Co., boiling point: 201 to 245C), Exol D110 (manufactured by Exxon Chemical Co., boiling point: 243 to 256C), Exol D130 (manufactured by Exxon Chemical Co., boiling point: 281 to 30)
7 ° C.).
【0007】本組成物には、例えば２−[１−（２−ヒドロ
キシ−３，５−ジ−ｔ−ペンチルフェニル）エチル]−
４，６−ジ−ｔ−ペンチルフェニルアクリレート、２，
６−ジ−ｔ−ブチル−４−メチルフェノール、２，２−
メチレンビス（４−メチル−６−ｔ−ブチルフェノール
等のフェノール系酸化防止剤、ベンゾフェノン系または
ベンゾトリアゾール系等の紫外線吸収剤等を添加しても
よい。[0007] The composition includes, for example, 2- [1- (2-hydroxy-3,5-di-t-pentylphenyl) ethyl]-
4,6-di-t-pentylphenyl acrylate, 2,
6-di-t-butyl-4-methylphenol, 2,2-
A phenolic antioxidant such as methylenebis (4-methyl-6-t-butylphenol) and an ultraviolet absorber such as benzophenone or benzotriazole may be added.
【0008】本方法により防除し得る害虫としては各種の有
害昆虫、ダニ類等の節足動物を挙げることができ、特に
有害飛翔性害虫、すなわち、アカイエカ、コガタアカイ
エカ、ネッタイイエカ、チカイエカ等のイエカ類、ネッ
タイシマカ、ヒトスジシマカ等のヤブカ類、シナハマダ
ラカ等のハマダラカ類、ユスリカ類、イエバエ、オオイ
エバエ、ヒメイエバエ等のイエバエ類、クロバエ類、ニ
クバエ類、ショウジョウバエ類、チョウバエ類、ノミバ
エ類、アブ類、ブユ類、サシバエ類、ヌカカ類等の双し
目害虫が挙げられる。Examples of pests that can be controlled by the present method include various pests, arthropods such as mites, and particularly harmful flying pests, ie, house mosquitoes such as Culex pipiens, Culex pipiens, Aedes pipiens and Culex pipiens. Aedes such as Aedes aegypti and Aedes albopictus, Anopheles such as Aedes albopictus, Anopheles such as midge, house flies, houseflies, house flies such as fly melanogaster, blowflies, flies, flies, flies, flies, and flies And pests of the order Diptera, e.g.
【0009】本方法は、例えば特公平２−２５８８５号公報
等に記載の加熱蒸散型殺虫装置に適用して、優れた効果
をあげることができる。図１は本方法に用いられる装置
の一例を示すものであり、殺虫組成物１中に多孔質吸液
芯３の一部が浸漬されており、該芯に該組成物を吸液さ
せ、該芯の上部を発熱体２で加熱することができるよう
になっている。[0009] The present method can be applied to, for example, a heat-transpiration type insecticidal apparatus described in Japanese Patent Publication No. Hei. FIG. 1 shows an example of an apparatus used in the present method, in which a part of a porous liquid absorbing core 3 is immersed in an insecticidal composition 1 and the core is allowed to absorb the composition. The upper part of the core can be heated by the heating element 2.
【0010】吸液芯の材質である多孔質材としては、例えば
クレー、タルク、カオリン、珪藻土、石膏、パーライ
ト、ベントナイト、酸性白土、グラスファイバー、石綿
等の無機粉末をカルボキシメチルセルロース、澱粉、ア
ラビアガム、ゼラチン、ポリビニルアルコール等の糊剤
にて粘結、成形したものが用いられる。尚、該吸液芯
に、色素、防腐剤、４，４’−メチレンビス（２−メチ
ル−６−ｔ−ブチルフェノール）、ステアリル−β−
（３，５−ジ−ｔ−ブチル−４−ヒドロキシフェニル）
プロピオネート、３，９−ビス[２−〔３−（３−ｔ−
ブチル−４−ヒドロキシ−５−メチルフェニル）プロピ
オニロキシ〕−１，１−ジメチルエチル]−２，４，
８，１０−テトラオキサスピロ〔５，５〕ウンデカン等
の酸化防止剤を適宜含有してもよく、例えば、前記多孔
質材と糊剤との粘結時に混合することにより含有させる
ことができる。[0010] Examples of the porous material as a material of the liquid absorbent core include inorganic powders such as clay, talc, kaolin, diatomaceous earth, gypsum, perlite, bentonite, acid clay, glass fiber, asbestos, etc., carboxymethyl cellulose, starch, gum arabic. What is caulked and molded with a paste such as gelatin, polyvinyl alcohol, etc. is used. In addition, a pigment, a preservative, 4,4′-methylenebis (2-methyl-6-t-butylphenol), stearyl-β-
(3,5-di-t-butyl-4-hydroxyphenyl)
Propionate, 3,9-bis [2- [3- (3-t-
Butyl-4-hydroxy-5-methylphenyl) propionyloxy] -1,1-dimethylethyl] -2,4.
An antioxidant such as 8,10-tetraoxaspiro [5,5] undecane may be appropriately contained. For example, it can be contained by mixing at the time of caking between the porous material and the paste.
【0011】[0011]
【実施例】以下、製造例及び試験例をあげて、本発明を
さらに詳しく説明するが、本発明はこれらの例のみに限
定されるものではない。 製造例１ プラレトリン（住友化学工業株式会社製）０．１８ｇ及
び安息香酸３．４ｍｇに、ネオチオゾール（中央化成株
式会社製）を添加・混合して、３４．５ｇ（４５ｍｌ）
の加熱蒸散用殺虫組成物を得た。EXAMPLES The present invention will be described in more detail with reference to production examples and test examples, but the present invention is not limited to these examples. Production Example 1 Neothiozole (manufactured by Chuo Kasei Co., Ltd.) was added to 0.18 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 3.4 mg of benzoic acid and mixed, and 34.5 g (45 ml) was added.
Was obtained.
【0012】製造例２ プラレトリン（住友化学工業株式会社製）０．３０ｇ及
び安息香酸３．４ｍｇに、ネオチオゾール（中央化成株
式会社製）を添加・混合して、３４．５ｇの加熱蒸散用
殺虫組成物を得る。Production Example 2 Neothiozole (manufactured by Chuo Kasei Co., Ltd.) was added and mixed to 0.30 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 3.4 mg of benzoic acid, and 34.5 g of an insecticidal composition for heat evaporation was added. Get things.
【0013】製造例３ プラレトリン（住友化学工業株式会社製）０．３０ｇ及
び安息香酸１７．０ｍｇに、ネオチオゾール（中央化成
株式会社製）を添加・混合して、３４．５ｇの加熱蒸散
用殺虫組成物を得る。Production Example 3 Neothiozole (manufactured by Chuo Kasei Co., Ltd.) was added and mixed with 0.30 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 17.0 mg of benzoic acid, and 34.5 g of an insecticidal composition for heat evaporation was added. Get things.
【0014】製造例４ プラレトリン（住友化学工業株式会社製）０．３０ｇ及
び安息香酸３４．０ｍｇに、ネオチオゾール（中央化成
株式会社製）を添加・混合して、３４．５ｇの加熱蒸散
用殺虫組成物を得る。Production Example 4 Neothiozole (manufactured by Chuo Kasei Co., Ltd.) was added to and mixed with 0.30 g of prarethrin (manufactured by Sumitomo Chemical Co., Ltd.) and 34.0 mg of benzoic acid, and 34.5 g of an insecticidal composition for heat evaporation was added. Get things.
【0015】製造例５ プラレトリン（住友化学工業株式会社製）０．３０ｇ及
び安息香酸１７０．０ｍｇに、ネオチオゾール（中央化
成株式会社製）を添加・混合して、３４．５ｇの加熱蒸
散用殺虫組成物を得る。Production Example 5 Neothiozole (manufactured by Chuo Kasei Co., Ltd.) was added and mixed with 0.30 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 170.0 mg of benzoic acid, and 34.5 g of an insecticidal composition for heat evaporation was added. Get things.
【0016】製造例６ プラレトリン（住友化学工業株式会社製）０．６０ｇ及
び安息香酸３．４ｍｇに、ネオチオゾール（中央化成株
式会社製）を添加・混合して、３４．５ｇの加熱蒸散用
殺虫組成物を得る。Production Example 6 Neothiozole (manufactured by Chuo Kasei Co., Ltd.) was added and mixed to 0.60 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 3.4 mg of benzoic acid, and 34.5 g of an insecticidal composition for heat evaporation was added. Get things.
【0017】製造例７ プラレトリン（住友化学工業株式会社製）０．６０ｇ及
び安息香酸１７．０ｍｇに、ネオチオゾール（中央化成
株式会社製）を添加・混合して、３４．５ｇの加熱蒸散
用殺虫組成物を得る。Production Example 7 Neothiozole (manufactured by Chuo Kasei Co., Ltd.) was added and mixed to 0.60 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 17.0 mg of benzoic acid, and 34.5 g of an insecticidal composition for heat evaporation was added. Get things.
【0018】製造例８ プラレトリン（住友化学工業株式会社製）０．６０ｇ及
び安息香酸３４．０ｍｇに、ネオチオゾール（中央化成
株式会社製）を添加・混合して、３４．５ｇの加熱蒸散
用殺虫組成物を得る。Production Example 8 Neothiozole (manufactured by Chuo Kasei Co., Ltd.) was added and mixed to 0.60 g of prarethrin (manufactured by Sumitomo Chemical Co., Ltd.) and 34.0 mg of benzoic acid, and 34.5 g of an insecticidal composition for heat evaporation was added. Get things.
【0019】製造例９ プラレトリン（住友化学工業株式会社製）０．６０ｇ及
び安息香酸１７０．０ｍｇに、ネオチオゾール（中央化
成株式会社製）を添加・混合して、３４．５ｇの加熱蒸
散用殺虫組成物を得る。Production Example 9 Neothiozole (manufactured by Chuo Kasei Co., Ltd.) was added and mixed to 0.60 g of prarethrin (manufactured by Sumitomo Chemical Co., Ltd.) and 170.0 mg of benzoic acid, and 34.5 g of an insecticidal composition for heat evaporation was added. Get things.
【0020】製造例１０ プラレトリン（住友化学工業株式会社製）０．９０ｇ及
び安息香酸３．４ｍｇに、ネオチオゾール（中央化成株
式会社製）を添加・混合して、３４．５ｇの加熱蒸散用
殺虫組成物を得る。Production Example 10 Neothiozole (manufactured by Chuo Kasei Co., Ltd.) was added and mixed to 0.90 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 3.4 mg of benzoic acid, and 34.5 g of an insecticidal composition for heat evaporation was added. Get things.
【0021】製造例１１ プラレトリン（住友化学工業株式会社製）０．９０ｇ及
び安息香酸１７．０ｍｇに、ネオチオゾール（中央化成
株式会社製）を添加・混合して、３４．５ｇの加熱蒸散
用殺虫組成物を得る。Production Example 11 Neothiozole (manufactured by Chuo Kasei Co., Ltd.) was added and mixed to 0.90 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 17.0 mg of benzoic acid, and 34.5 g of an insecticidal composition for heat evaporation was added. Get things.
【0022】製造例１２ プラレトリン（住友化学工業株式会社製）０．９０ｇ及
び安息香酸３４．０ｍｇに、ネオチオゾール（中央化成
株式会社製）を添加・混合して、３４．５ｇの加熱蒸散
用殺虫組成物を得る。Production Example 12 Neothiozole (manufactured by Chuo Kasei Co., Ltd.) was added and mixed with 0.90 g of prarethrin (manufactured by Sumitomo Chemical Co., Ltd.) and 34.0 mg of benzoic acid, and 34.5 g of an insecticidal composition for heat evaporation was added. Get things.
【0023】製造例１３ プラレトリン（住友化学工業株式会社製）０．９０ｇ及
び安息香酸１７０．０ｍｇに、ネオチオゾール（中央化
成株式会社製）を添加・混合して、３４．５ｇの加熱蒸
散用殺虫組成物を得る。Production Example 13 Neothiozole (manufactured by Chuo Kasei Co., Ltd.) was added and mixed with 0.90 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 170.0 mg of benzoic acid, and 34.5 g of an insecticidal composition for heat evaporation was added. Get things.
【0024】製造例１４ プラレトリン（住友化学工業株式会社製）１．２０ｇ及
び安息香酸３．４ｍｇに、ネオチオゾール（中央化成株
式会社製）を添加・混合して、３４．５ｇの加熱蒸散用
殺虫組成物を得る。Production Example 14 Neothiozole (manufactured by Chuo Chemical Co., Ltd.) was added and mixed to 1.20 g of prarethrin (manufactured by Sumitomo Chemical Co., Ltd.) and 3.4 mg of benzoic acid, and 34.5 g of an insecticidal composition for heat evaporation was added. Get things.
【0025】製造例１５ プラレトリン（住友化学工業株式会社製）１．２０ｇ及
び安息香酸１７．０ｍｇに、ネオチオゾール（中央化成
株式会社製）を添加・混合して、３４．５ｇの加熱蒸散
用殺虫組成物を得る。Production Example 15 Neothiozole (manufactured by Chuo Kasei Co., Ltd.) was added to 1.20 g of prarethrin (manufactured by Sumitomo Chemical Co., Ltd.) and 17.0 mg of benzoic acid and mixed, and 34.5 g of an insecticidal composition for heat evaporation was added. Get things.
【0026】製造例１６ プラレトリン（住友化学工業株式会社製）１．２０ｇ及
び安息香酸３４．０ｍｇに、ネオチオゾール（中央化成
株式会社製）を添加・混合して、３４．５ｇの加熱蒸散
用殺虫組成物を得る。Production Example 16 Neothiozole (manufactured by Chuo Kasei Co., Ltd.) was added and mixed to 1.20 g of prarethrin (manufactured by Sumitomo Chemical Co., Ltd.) and 34.0 mg of benzoic acid, and 34.5 g of an insecticidal composition for heat evaporation was added. Get things.
【0027】製造例１７ プラレトリン（住友化学工業株式会社製）１．２０ｇ及
び安息香酸１７０．０ｍｇに、ネオチオゾール（中央化
成株式会社製）を添加・混合して、３４．５ｇの加熱蒸
散用殺虫組成物を得る。Production Example 17 Neothiozole (manufactured by Chuo Kasei Co., Ltd.) was added to 1.20 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 170.0 mg of benzoic acid and mixed, and 34.5 g of an insecticidal composition for heat evaporation was added. Get things.
【0028】製造例１８ プラレトリン（住友化学工業株式会社製）１．８０ｇ及
び安息香酸３．４ｍｇに、ネオチオゾール（中央化成株
式会社製）を添加・混合して及び３４．５ｇの加熱蒸散
用殺虫組成物を得る。Production Example 18 Neothiozole (manufactured by Chuo Kasei Co., Ltd.) was added and mixed to 1.80 g of prarethrin (manufactured by Sumitomo Chemical Co., Ltd.) and 3.4 mg of benzoic acid, and 34.5 g of an insecticidal composition for heat evaporation was added. Get things.
【0029】製造例１９ プラレトリン（住友化学工業株式会社製）１．８０ｇ及
び安息香酸１７．０ｍｇに、ネオチオゾール（中央化成
株式会社製）を添加・混合して、３４．５ｇの加熱蒸散
用殺虫組成物を得る。Production Example 19 Neothiozole (manufactured by Chuo Kasei Co., Ltd.) was added and mixed to 1.80 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 17.0 mg of benzoic acid, and 34.5 g of an insecticidal composition for heat evaporation was added. Get things.
【0030】製造例２０ プラレトリン（住友化学工業株式会社製）１．８０ｇ及
び安息香酸３４．０ｍｇに、ネオチオゾール（中央化成
株式会社製）を添加・混合して、３４．５ｇの加熱蒸散
用殺虫組成物を得る。Production Example 20 Neothiozole (manufactured by Chuo Chemical Co., Ltd.) was added to 1.80 g of prarethrin (manufactured by Sumitomo Chemical Co., Ltd.) and 34.0 mg of benzoic acid and mixed, and 34.5 g of an insecticidal composition for heat evaporation was added. Get things.
【0031】製造例２１ プラレトリン（住友化学工業株式会社製）１．２０ｇ及
び安息香酸３．４ｍｇに、ノルパー１３（エクソン化学
株式会社製）を添加・混合して、３５ｇの加熱蒸散用殺
虫組成物を得る。Production Example 21 Norpar 13 (manufactured by Exxon Chemical Co., Ltd.) was added and mixed to 1.20 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 3.4 mg of benzoic acid, and 35 g of an insecticidal composition for heat evaporation was added. Get.
【0032】製造例２２ プラレトリン（住友化学工業株式会社製）１．２０ｇ及
び安息香酸１７．０ｍｇに、ノルパー１３（エクソン化
学株式会社製）を添加・混合して、３５ｇの加熱蒸散用
殺虫組成物を得る。Production Example 22 Norpar 13 (manufactured by Exxon Chemical Co., Ltd.) was added and mixed to 1.20 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 17.0 mg of benzoic acid, and 35 g of an insecticidal composition for heat evaporation was added. Get.
【0033】製造例２３ プラレトリン（住友化学工業株式会社製）１．２０ｇ及
び安息香酸３４．０ｍｇに、ノルパー１３（エクソン化
学株式会社製）を添加・混合して、３５ｇの加熱蒸散用
殺虫組成物を得る。Production Example 23 Norpar 13 (manufactured by Exxon Chemical Co., Ltd.) was added and mixed to 1.20 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 34.0 mg of benzoic acid, and 35 g of an insecticidal composition for heat evaporation was added. Get.
【0034】製造例２４ プラレトリン（住友化学工業株式会社製）１．２０ｇ、
安息香酸１７０．０ｍｇに、ノルパー１３（エクソン化
学株式会社製）を添加・混合して、３５ｇの加熱蒸散用
殺虫組成物を得る。Production Example 24 Pralethrin (manufactured by Sumitomo Chemical Co., Ltd.) 1.20 g,
To 170.0 mg of benzoic acid, Norpar 13 (manufactured by Exxon Chemical Co., Ltd.) is added and mixed to obtain 35 g of an insecticidal composition for heat evaporation.
【0035】製造例２５ プラレトリン（住友化学工業株式会社製）１．８０ｇ、
安息香酸３．４ｍｇに、ノルパー１３（エクソン化学株
式会社製）を添加・混合して、３５ｇの加熱蒸散用殺虫
組成物を得る。Production Example 25 1.80 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.)
To 3.4 mg of benzoic acid, Norpar 13 (manufactured by Exxon Chemical Co., Ltd.) is added and mixed to obtain 35 g of an insecticidal composition for heat evaporation.
【0036】製造例２６ プラレトリン（住友化学工業株式会社製）１．８０ｇ及
び安息香酸１７．０ｍｇに、ノルパー１３（エクソン化
学株式会社製）を添加・混合して、３５ｇの加熱蒸散用
殺虫組成物を得る。Production Example 26 To 1.80 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 17.0 mg of benzoic acid, norpar 13 (manufactured by Exxon Chemical Co., Ltd.) was added and mixed, and 35 g of an insecticidal composition for heat evaporation was added. Get.
【0037】製造例２７ プラレトリン（住友化学工業株式会社製）１．８０ｇ及
び安息香酸３４．０ｍｇに、ノルパー１３（エクソン化
学株式会社製）を添加・混合して、３５ｇの加熱蒸散用
殺虫組成物を得る。Production Example 27 To 1.80 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 34.0 mg of benzoic acid, norpar 13 (manufactured by Exxon Chemical Co., Ltd.) was added and mixed, and 35 g of the insecticidal composition for heat evaporation was added. Get.
【0038】製造例２８ プラレトリン（住友化学工業株式会社製）１．２０ｇ及
び安息香酸３．４ｍｇに、ノルパー１５（エクソン化学
株式会社製）を添加・混合して、３５ｇ加熱蒸散用殺虫
組成物を得る。Production Example 28 To 1.20 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 3.4 mg of benzoic acid, norpar 15 (manufactured by Exxon Chemical Co., Ltd.) was added and mixed, and 35 g of the insecticidal composition for heat evaporation was added. obtain.
【0039】製造例２９ プラレトリン（住友化学工業株式会社製）１．２０ｇ及
び安息香酸１７．０ｍｇに、ノルパー１５（エクソン化
学株式会社製）を添加・混合して、３５ｇの加熱蒸散用
殺虫組成物を得る。Production Example 29 Norpar 15 (manufactured by Exxon Chemical Co., Ltd.) was added and mixed to 1.20 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 17.0 mg of benzoic acid, and 35 g of an insecticidal composition for heat evaporation was added. Get.
【0040】製造例３０ プラレトリン（住友化学工業株式会社製）１．２０ｇ及
び安息香酸３４．０ｍｇに、ノルパー１５（エクソン化
学株式会社製）を添加・混合して、３５ｇの加熱蒸散用
殺虫組成物を得る。Production Example 30 To 1.20 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 34.0 mg of benzoic acid were added and mixed with Norpar 15 (manufactured by Exxon Chemical Co., Ltd.), and 35 g of the insecticidal composition for heat evaporation was added. Get.
【0041】製造例３１ プラレトリン（住友化学工業株式会社製）１．２０ｇ及
び安息香酸１７０．０ｍｇに、ノルパー１５（エクソン
化学株式会社製）を添加・混合して、３５ｇの加熱蒸散
用殺虫組成物を得る。Production Example 31 Norpar 15 (manufactured by Exxon Chemical Co., Ltd.) was added to 1.20 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 170.0 mg of benzoic acid and mixed, and 35 g of an insecticidal composition for heat evaporation was added. Get.
【0042】製造例３２ プラレトリン（住友化学工業株式会社製）１．８０ｇ及
び安息香酸３．４ｍｇに、ノルパー１５（エクソン化学
株式会社製）を添加・混合して、３５ｇの加熱蒸散用殺
虫組成物を得る。Production Example 32 To 1.80 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 3.4 mg of benzoic acid, norpar 15 (manufactured by Exxon Chemical Co., Ltd.) was added and mixed, and 35 g of an insecticidal composition for heat evaporation was added. Get.
【0043】製造例３３ プラレトリン（住友化学工業株式会社製）１．８０ｇ及
び安息香酸１７．０ｍｇに、ノルパー１５（エクソン化
学株式会社製）を添加・混合して、３５ｇの加熱蒸散用
殺虫組成物を得る。Production Example 33 To 1.80 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 17.0 mg of benzoic acid, norpar 15 (manufactured by Exxon Chemical Co., Ltd.) was added and mixed, and 35 g of the insecticidal composition for heat evaporation was added. Get.
【0044】製造例３４ プラレトリン（住友化学工業株式会社製）１．８０ｇ及
び安息香酸３４．０ｍｇに、ノルパー１５（エクソン化
学株式会社製）を添加・混合して、３５ｇの加熱蒸散用
殺虫組成物を得る。Production Example 34 To 1.80 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 34.0 mg of benzoic acid, norpar 15 (manufactured by Exxon Chemical Co., Ltd.) was added and mixed, and 35 g of the insecticidal composition for heat evaporation was added. Get.
【0045】製造例３５ プラレトリン（住友化学工業株式会社製）１．２０ｇ及
び安息香酸３．４ｍｇに、０号ソルベントＨ（日本石油
株式会社製）を添加・混合して、３５ｇの加熱蒸散用殺
虫組成物を得る。Production Example 35 No. 0 Solvent H (manufactured by Nippon Oil Co., Ltd.) was added and mixed to 1.20 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 3.4 mg of benzoic acid, and 35 g of insecticide for heat evaporation was added. Obtain the composition.
【0046】製造例３６ プラレトリン（住友化学工業株式会社製）１．２０ｇ及
び安息香酸１７．０ｍｇに、０号ソルベントＨ（日本石
油株式会社製）を添加・混合して、３５ｇの加熱蒸散用
殺虫組成物を得る。Production Example 36 No. 0 Solvent H (manufactured by Nippon Oil Co., Ltd.) was added and mixed to 1.20 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 17.0 mg of benzoic acid, and 35 g of insecticide for heat evaporation was added. Obtain the composition.
【0047】製造例３７ プラレトリン（住友化学工業株式会社製）１．２０ｇ及
び安息香酸３４．０ｍｇに、０号ソルベントＨ（日本石
油株式会社製）を添加・混合して、３５ｇの加熱蒸散用
殺虫組成物を得る。Production Example 37 To No. 0 solvent H (manufactured by Nippon Oil Co., Ltd.) was added and mixed with 1.20 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 34.0 mg of benzoic acid, and 35 g of insecticide for heat evaporation was added. Obtain the composition.
【0048】製造例３８ プラレトリン（住友化学工業株式会社製）１．２０ｇ及
び安息香酸１７０．０ｍｇに、０号ソルベントＨ（日本
石油株式会社製）を添加・混合して、３５ｇの加熱蒸散
用殺虫組成物を得る。Production Example 38 No. 0 Solvent H (manufactured by Nippon Oil Co., Ltd.) was added and mixed to 1.20 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 170.0 mg of benzoic acid, and 35 g of insecticide for heat evaporation was added. Obtain the composition.
【0049】製造例３９ プラレトリン（住友化学工業株式会社製）１．８０ｇ及
び安息香酸３．４ｍｇに、０号ソルベントＨ（日本石油
株式会社製）を添加・混合して、３５ｇの加熱蒸散用殺
虫組成物を得る。Production Example 39 No. 0 Solvent H (manufactured by Nippon Oil Co., Ltd.) was added and mixed to 1.80 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 3.4 mg of benzoic acid, and 35 g of insecticide for heat evaporation was added. Obtain the composition.
【0050】製造例４０ プラレトリン（住友化学工業株式会社製）１．８０ｇ及
び安息香酸１７．０ｍｇに、０号ソルベントＨ（日本石
油株式会社製）を添加・混合して、３５ｇの加熱蒸散用
殺虫組成物を得る。Production Example 40 No. 0 Solvent H (manufactured by Nippon Oil Co., Ltd.) was added and mixed to 1.80 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 17.0 mg of benzoic acid, and 35 g of insecticide for heat evaporation was added. Obtain the composition.
【0051】製造例４１ プラレトリン（住友化学工業株式会社製）１．８０ｇ及
び安息香酸３４．０ｍｇに、０号ソルベントＨ（日本石
油株式会社製）を添加・混合して、３５ｇの加熱蒸散用
殺虫組成物を得る。Production Example 41 No. 0 Solvent H (manufactured by Nippon Oil Co., Ltd.) was added and mixed to 1.80 g of praletrin (manufactured by Sumitomo Chemical Co., Ltd.) and 34.0 mg of benzoic acid, and 35 g of insecticide for heat evaporation was added. Obtain the composition.
【0052】製造例４２ プラレトリン（住友化学工業株式会社製）１．８０ｇ及
び安息香酸１７０．０ｍｇに、ネオチオゾール（中央化
成株式会社製）を添加・混合して、３４．５ｇの加熱蒸
散用殺虫組成物を得る。Production Example 42 Neothiozole (manufactured by Chuo Kasei Co., Ltd.) was added and mixed to 1.80 g of prarethrin (manufactured by Sumitomo Chemical Co., Ltd.) and 170.0 mg of benzoic acid, and 34.5 g of an insecticidal composition for heat evaporation was added. Get things.
【0053】比較製造例１ プラレトリン（住友化学工業株式会社製）０．１８ｇ
に、ネオチオゾール（中央化成株式会社製）を添加・混
合して、３４．５ｇの比較用加熱蒸散用殺虫組成物を得
た。Comparative Production Example 1 Praletrin (Sumitomo Chemical Co., Ltd.) 0.18 g
Was mixed with Neothiozole (manufactured by Chuo Kasei Co., Ltd.) to obtain 34.5 g of an insecticidal composition for heat evaporation for comparison.
【0054】次に、試験例を記す。 試験例１ 製造例１で得られた加熱蒸散用殺虫組成物および比較用
加熱蒸散用殺虫組成物、おのおの３４．５ｇ（４５ｍ
ｌ）を容器に入れて吸液芯を取り付け、吸液芯付き加熱
蒸散用殺虫組成物入りボトルとした。該ボトルを図1に
示されるような加熱蒸散型殺虫装置を用いて１５８時間
加熱を継続し、該ボトルの重量を測定することにより、
７６〜７８、１５６〜１５８時間の各々２時間に揮散し
た加熱蒸散用殺虫組成物量を測定した。結果を表１に示
す。Next, test examples will be described. Test Example 1 The insecticidal composition for heat evaporation obtained in Production Example 1 and the insecticidal composition for heat evaporation for comparison were each 34.5 g (45 m).
l) was placed in a container, and a liquid-absorbing wick was attached thereto, to give a bottle containing the insecticidal composition for heat evaporation with a liquid-absorbing wick. By heating the bottle for 158 hours using a heat-transpiration type insecticidal apparatus as shown in FIG. 1 and measuring the weight of the bottle,
The amount of the insecticidal composition for heat evaporation which volatilized for 2 hours each from 76 to 78 and 156 to 158 hours was measured. Table 1 shows the results.
【0055】 上表の結果に示されるように、本組成物を用いることに
より、揮散量の減少率は、比較用加熱蒸散用殺虫組成物
を用いた時に比べて１/２以下に改善され、安定して加
熱蒸散用殺虫組成物の揮散を実現させることができた。[0055] As shown in the results of the above table, by using the present composition, the rate of reduction in the amount of volatilization is improved to less than 1/2 compared to when the insecticidal composition for heat evaporation for comparison is used, and stably. The volatilization of the insecticidal composition for heat evaporation could be realized.
【0056】[0056]
【発明の効果】本発明によれば、長時間にわたって安定
して、加熱蒸散用殺虫組成物を揮散させることができ、
安定した殺虫効果を得ることができる。According to the present invention, the insecticidal composition for heat evaporation can be volatilized stably for a long time,
A stable insecticidal effect can be obtained.
【図1】本方法に用いられる装置の一例を示す説明図で
ある。FIG. 1 is an explanatory diagram illustrating an example of an apparatus used in the present method.
１は加熱蒸散用殺虫組成物、２は発熱体、３は吸液芯、
４は薬液を入れた容器を表す。1 is an insecticidal composition for heat evaporation, 2 is a heating element, 3 is an absorbent core,
Reference numeral 4 denotes a container containing a chemical solution.
Claims (6)
量％、(b)有機酸を０．００１〜７重量％及び(c)沸点が
１８０〜３１０℃の飽和炭化水素を７３〜９９．９８９
重量％含有する加熱蒸散用殺虫組成物。(1) 0.01 to 20% by weight of a pyrethroid compound, (b) 0.001 to 7% by weight of an organic acid, and (c) 73 to 99% of a saturated hydrocarbon having a boiling point of 180 to 310 ° C. .989
Insecticidal composition for heat transpiration, which contains by weight.
に記載の加熱蒸散用殺虫組成物。2. The method according to claim 1, wherein the organic acid is an aromatic carboxylic acid.
The insecticidal composition for heat transpiration according to the above.
加熱蒸散用殺虫組成物。3. The insecticidal composition for heat evaporation according to claim 1, wherein the organic acid is benzoic acid.
量％、(b)有機酸を０．００１〜７重量％及び(c)沸点が
１８０〜３１０℃の飽和炭化水素を７３〜９９．９８９
重量％含有する殺虫組成物中に多孔質吸液芯の一部を浸
漬して、該芯に該組成物を吸液させ、該芯の上部を加熱
することにより吸液された該組成物を蒸散させることを
特徴とする加熱蒸散殺虫方法。(4) 0.01 to 20% by weight of (a) a pyrethroid compound, (b) 0.001 to 7% by weight of an organic acid, and (c) 73 to 99% of a saturated hydrocarbon having a boiling point of 180 to 310 ° C. .989
A part of a porous liquid absorbing core is immersed in an insecticidal composition containing a weight percent of the composition, the core absorbs the composition, and the upper part of the core is heated to absorb the liquid. A method for killing insects by heat transpiration, which comprises transpiration.
に記載の方法。5. The organic acid is an aromatic carboxylic acid.
The method described in.
方法。6. The method according to claim 4, wherein the organic acid is benzoic acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000098708A JP4556280B2 (en) | 2000-03-31 | 2000-03-31 | Heat transpiration insecticide composition and heat transpiration insecticide method using the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000098708A JP4556280B2 (en) | 2000-03-31 | 2000-03-31 | Heat transpiration insecticide composition and heat transpiration insecticide method using the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2001288005A true JP2001288005A (en) | 2001-10-16 |
| JP4556280B2 JP4556280B2 (en) | 2010-10-06 |
Family
ID=18613165
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000098708A Expired - Fee Related JP4556280B2 (en) | 2000-03-31 | 2000-03-31 | Heat transpiration insecticide composition and heat transpiration insecticide method using the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4556280B2 (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60161902A (en) * | 1984-01-31 | 1985-08-23 | Earth Chem Corp Ltd | Insecticidal solution composition for core to suck up solution |
-
2000
- 2000-03-31 JP JP2000098708A patent/JP4556280B2/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60161902A (en) * | 1984-01-31 | 1985-08-23 | Earth Chem Corp Ltd | Insecticidal solution composition for core to suck up solution |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4556280B2 (en) | 2010-10-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1071543C (en) | Insecticide-comprising gel formulations for vapor-producing systems | |
| CN87104903A (en) | Method by the heating fumigating desinsection | |
| AU708907B2 (en) | Liquid insecticidal preparation for heat fumigation and method for killing insects by heat fumigation | |
| KR20090024165A (en) | Insecticidal composition comprising tetrafluorobenzyl cyclopropane carboxylate | |
| TWI586274B (en) | Pest control product and pest control method | |
| JP7346570B2 (en) | Insecticidal efficacy enhancer, pest control method, and aqueous insecticide composition for heat transpiration | |
| TWI711374B (en) | Insect pest control product and insect pest control method | |
| CN108601339B (en) | Wick for heat evaporation, method for producing same, and heat evaporation method using same | |
| CN101632379A (en) | Electric heating insecticidal liquid | |
| JP2001288005A (en) | Heat transpiration insecticidal composition and heat transpiration insecticidal method using the same | |
| JP3783251B2 (en) | Heat transpiration insecticide method | |
| TWI664906B (en) | Insect pest control product and insect pest control method | |
| JP4701525B2 (en) | Insecticide for heat evaporation and heat evaporation insecticide method using the same | |
| JP4720244B2 (en) | Pest control solution | |
| JP4972839B2 (en) | Pest control solution for heat transpiration and pest control method | |
| CN101124910B (en) | Controlling pest through heating fumigating | |
| JP4348896B2 (en) | Pest control solution for heat transpiration and pest control method | |
| JPH10182306A (en) | Insecticide for heat evaporation | |
| CN101124909B (en) | Pest control through heat fumigation | |
| JP4288885B2 (en) | Pest control solution for heat evaporation | |
| JPH0768085B2 (en) | Heat transpiration insecticide method | |
| JP3787952B2 (en) | Liquid heated transpiration insecticidal composition and insecticidal method using the same | |
| CN1306747A (en) | Method for prevenltion and elimination of pest by heating fumigation | |
| JP3757061B2 (en) | Absorption core for heat evaporation | |
| CN103392728A (en) | Electric heating insecticide liquid |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070125 |
|
| RD05 | Notification of revocation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7425 Effective date: 20080125 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20100407 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100413 |
|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100607 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20100629 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20100712 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130730 Year of fee payment: 3 |
|
| LAPS | Cancellation because of no payment of annual fees |