JP2001278730A - Powder cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a powder cosmetic having excellent adhesivity and smooth spreadability and extendability, high uniformity of cosmetic film, no crystal precipitation of solid oil and excellent stability with time. SOLUTION: This powder cosmetic comprises a component (a) of a partially crosslinking type organopolysiloxane, a component (b) of a liquid silicone oil, a component (c) of a liquid oil except the component (b), a component (d) of a solid oil and/or a higher alcohol and a component (e) of powder. The powder cosmetic comprises 0.05-3 mass % content of the component (d). The powder cosmetic has the content of the component (b) and the content of the whole oils except the component (d) in the mass ratio of the content of the component (b)/the content of the whole oils except the component (d) of 0.4-0.8 in any of the powder cosmetics. Further the powder cosmetic has the ratio of the content of the component (d) to the total contents of the whole oils in the mass ratio of the content of the component (d)/the contents of the whole oils of 0.01-0.2 in any of the powder cosmetics.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

The present invention relates to a powder cosmetic containing a partially crosslinked organopolysiloxane, liquid silicone oil, liquid oil other than liquid silicone oil, solid oil and / or higher alcohol, and powder. More specifically, the present invention relates to a powder cosmetic having good adhesion and smooth elongation and spreadability, high uniformity of a decorative film, and excellent stability over time without crystal precipitation of solid oil.

[0002]

2. Description of the Related Art Conventionally, powder cosmetics have been used in various oils, polyhydric alcohols, higher alcohols, and the like for the purpose of improving powder adhesion to the skin, adhesion, useability, and cosmetic durability.
Higher fatty acids, surfactants and the like are appropriately selected, added and mixed as an oil agent, or surface-treated on the surface of the powder and blended. Techniques for achieving higher cosmetic durability and adhesion include a method of blending solid oil or a higher alcohol, a method of blending a partially cross-linked organopolysiloxane, a method of blending a surfactant, polybutene or heavy water. There is a method of blending a resin such as ultra-liquid isoparaffin or rosin acid.

[0003]

However, each of the above methods has the following problems. The method of blending solid oils and higher alcohols can not only be obtained by simply blending liquid oil, but can provide a smooth feel at the time of application and a smooth smooth spreadability, but the cosmetic In some cases, crystals were precipitated in the inside, resulting in a poor appearance or a rough foreign substance sensation. The method of blending the partially cross-linked organopolysiloxane can improve the adhesion to the skin, give a smooth feel when applied, and provide a smooth and smooth spreadability, but if it is blended in a large amount, caking occurs. Or
Due to low compatibility with other oils, it was sometimes difficult to uniformly disperse them. In the method of adding a surfactant, the adhesion to the skin is improved, but at the same time, the familiarity with the sebum is increased, so that the persistence of the makeup may be deteriorated. The method of blending a resin such as polybutene, heavy liquid isoparaffin, or rosin acid improves the persistence of makeup due to its excellent adhesion to the skin. The film tended to be non-uniform. For this reason, there has been a demand for the development of a powder cosmetic having good adhesion and smooth elongation and spreadability, high uniformity of the decorative film, and excellent stability over time.

[0004]

Under such circumstances, the present inventors have developed a partially crosslinked organopolysiloxane, liquid silicone oil, liquid oil other than liquid silicone oil, solid oil and / or higher alcohol, and powder. When combined with powder cosmetics, powder cosmetics with good adhesion and smooth extensibility, high uniformity of decorative film, and excellent stability over time without solid oil crystal precipitation Was obtained, and the present invention was completed.

That is, the present invention provides the following components (a) to
(E); component (a) partially crosslinked organopolysiloxane component (b) liquid silicone oil component (c) liquid oil other than component (b) component (d) solid oil and / or higher alcohol component (e) powder And a powder cosmetic containing the same. Also,
The content of the powder cosmetic having the content of the component (d) of 0.05 to 3% by mass, the content of the component (b), and the content of the whole oil excluding the component (d) are represented by mass ratio. , Content of component (b) /
Any of the powder cosmetics described above, wherein the content of the total oil except for the component (d) is 0.4 to 0.8, and further, the ratio of the content of the component (d) to the content of the total oil is The present invention provides any one of the powder cosmetics described above, wherein the content of the component (d) / the content of the total oil is 0.01 to 0.2 in terms of mass ratio.

[0006]

BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail.
The partially crosslinked organopolysiloxane of the component (a) used in the present invention gels a liquid oil such as the component (b) or the component (c).
It is a component that exhibits good adhesion and smooth elongation. Specifically, as a commercial product, KSG-16
(Mixture of 20-30% by mass of crosslinked methylpolysiloxane and 70-80% by mass of dimethylpolysiloxane), KS
G-18 (cross-linked methylphenylpolysiloxane 10
20% by mass and methylphenylpolysiloxane 80 to 90
Mass%), KSG-21 (a mixture of 22 to 32 mass% of crosslinked polyether-modified silicone and 68 to 78 mass% of dimethylpolysiloxane) (all manufactured by Shin-Etsu Chemical Co., Ltd.), and the like. One type or two or more types can be used.

Component (a) in the powder cosmetic of the present invention
Is preferably 0.01 to 5% by mass (hereinafter abbreviated as%), and more preferably 0.05 to 3%. When the content of the component (a) is within the above range, a powder cosmetic having more improved adhesion and smooth spreadability can be obtained.

[0008] The liquid silicone oil of component (b) used in the present invention is a silicone oil which exhibits a liquid state at room temperature.
In the powder cosmetic of the present invention, it is a component that forms a gel with the component (a) to exhibit adhesion and smooth elongation. Specifically, dimethylpolysiloxane, methylhydrogenpolysiloxane, methylphenylpolysiloxane, dimethyldiphenylpolysiloxane, methylphenylmethoxypolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, stear Fluorine modification of roxymethylpolysiloxane, a fluoroalkyl group-containing linear silicone described in JP-A-2-295912 and the like, and a fluoroalkyl group-containing cyclic silicone described in JP-A-9-268110 and the like Silicone and the like can be mentioned, and one or more of these can be used.

Component (b) in the powder cosmetic of the present invention
Is preferably 0.1 to 10%. When the content of the component (b) is in this range, a powder cosmetic having smooth elongation and spreadability and uniformity of the decorative film can be obtained.

[0010] The liquid oil of the component (c) used in the present invention is an oil that exhibits a liquid state at room temperature, and is a component used for dissolving the component (d) in the powder cosmetic of the present invention; It is a liquid oil compatible with component (d). Specifically, liquid paraffin, light isoparaffin, α-
Hydrocarbon oils such as olefins, squalane, isododecane, cetyl 2-ethylhexanoate, propylene glycol dicaprate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, dialkyl carbonate, neopentyl glycol dicaprate, dimalate Ester oils such as isostearyl, neopentyl glycol di-2-ethylhexanoate, 2-ethylhexyl hydroxystearate, 2-ethylhexyl succinate, isotridecyl isononanoate, monoglyceride, glyceryl tri (caprylate / caprylate) acid, triisooctanoic acid Glycerin fatty acid ester oils such as glyceryl, macadamian nut oil, safflower oil, sunflower oil, castor oil, olive oil, jojoba oil, and other vegetable oils Triisostearate polyglyceryl, polyglycerol fatty acid ester oils such as tetra isostearate polyglyceryl, lanolin such as liquid lanolin, p- methoxycinnamic acid 2-ethylhexyl,
UV absorbers such as 2-ethoxyethyl 4-methoxycinnamate and the like, and one or more of these can be used. Among them, ester oils, glycerin fatty acid ester oils, polyglycerin fatty acid ester oils, N-lauroyl-L-glutamic acid di (phytostearyl / 2-octyldodecyl), N-lauroyl-L-glutamic acid di (cholesteryl. Amino acid oils such as octyldodecyl) and p-methoxycinnamic acid-2
Ultraviolet absorbers such as -ethylhexyl and 2-ethoxyethyl 4-methoxycinnamate are particularly preferred from the viewpoint of compatibility with the component (d).

Component (c) in the powder cosmetic of the present invention
Is preferably 0.1 to 15%. When the content of the component (c) is in this range, a powder cosmetic having better adhesion and smooth elongation can be obtained.

The solid oil and / or higher alcohol of the component (d) used in the present invention is an oil agent which exhibits a solid state at room temperature. In the powder cosmetic of the present invention, it improves the adhesion to the skin, It is an ingredient for enhancing the persistence of makeup. Specifically, as solid oils, hydrocarbon waxes such as paraffin wax, ceresin wax, microcrystalline wax, Fischer-Tropsch wax, synthetic waxes such as polyethylene wax, polyethylene polypropylene copolymer, candelilla wax, carnauba wax, beads Wax, mole, gay wax,
Natural and animal and plant waxes such as diwax and montan wax; higher fatty acids such as stearic acid; sucrose fatty acid esters; and bakoundound fatty acid esters can be used. One or more of these can be used. Examples of higher alcohols include stearyl alcohol, isostearyl alcohol, cetyl alcohol, and behenyl alcohol, and one or more of these can be used. Among these, ceresin wax, microcrystalline wax, polyethylene wax, candelilla wax, carnauba wax, stearyl alcohol, cetyl alcohol, behenyl alcohol,
It is more preferable from the viewpoint that good stretchability and a uniform decorative film can be obtained. Furthermore, higher alcohols such as stearyl alcohol, cetyl alcohol, and behenyl alcohol are particularly preferable from the viewpoints of less resistance to the skin upon application, good spreadability and uniformity of the decorative film.

Component (d) in the powder cosmetic of the present invention
Is preferably 0.05 to 3%, and 0.1 to 2%.
Is more preferred. When the content of the component (d) is within this range, a powder cosmetic having better adhesion and smooth smooth spreadability can be obtained.

An oil other than the above (b), (c) and (d), that is, a semi-solid oil, is blended with the powder cosmetic of the present invention for the purpose of enhancing adhesion to the skin and the like. be able to.
Specific examples include petrolatum, lanolin, dipentaerythrit fatty acid ester, polybutene, heavy liquid isobutylene, and the like, and one or more of these can be used.

In the powder cosmetic of the present invention, the component (b)
And the content of all oils except for component (d) (total of component (b), component (c) and other oils)
However, when the content of the component (b) / the content of the total oil excluding the component (d) is 0.4 to 0.8 in terms of mass, the smooth elongation and spreadability is further improved, and the component ( Since the crystal precipitation of d) does not occur, the stability over time is better.

In the powder cosmetic of the present invention, the ratio of the content of the component (d) to the content of the total oil (total of the components (b), (c) and other oils) is determined. , By mass ratio, content of component (d) / content of total oil = 0.01 to
When it is 0.2, smooth elongation and spreadability are further improved,
Since no crystal precipitation of the component (d) occurs, the stability over time is better.

The powder of the component (e) used in the present invention comprises:
In the powder cosmetic of the present invention, a coloring agent, a masking agent, an ultraviolet ray blocking agent, which is used as a make-up effect imparting agent, if it is a powder that is usually used as a cosmetic powder, a spherical, plate Shape, needle shape, fume shape, fine particles,
It is not particularly limited by the particle size such as pigment grade, the particle structure such as porous or non-porous, etc., inorganic powders, glitter powders, organic powders, dye powders, metal powders, Composite powders and the like can be mentioned. Titanium oxide, zinc oxide, cerium oxide, white inorganic pigments such as barium sulfate, iron oxide,
Carbon black, chromium oxide, chromium hydroxide, navy blue,
Colored inorganic pigments such as ultramarine blue, talc, muscovite, phlogopite, mica, biotite, synthetic mica, sericite, synthetic sericite, kaolin, silicon carbide, bentonite, smectite, silicic anhydride, aluminum oxide , Magnesium oxide, zirconium oxide, antimony oxide, diatomaceous earth,
White body powders such as aluminum silicate, magnesium aluminum metasilicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride, titanium oxide-coated mica, titanium oxide-coated bismuth oxychloride , Titanium oxide mica titanium, navy blue treated mica titanium, carmine treated mica titanium, brilliant powder such as bismuth oxychloride, fish scale foil, polyamide resin, polyethylene resin, polyacrylic resin, polyester resin, fluorine resin, Cellulose resin, polystyrene resin, copolymer resin such as styrene-acrylic copolymer resin, organic polymer resin powder such as polypropylene resin, silicone resin, urethane resin, and organic low molecular weight such as zinc stearate and N-acyl lysine Powder, starch, Torque powder, natural organic powders such as cellulose powder, Red No. 201, Red No. 202, Red 205
No. 226, Red No. 228, Orange No. 203, Orange No. 204, Blue No. 404, Yellow No. 401, etc., organic red powder No. 3, Red No. 104, Red No. 106, Orange No. 20
No. 5, Yellow No. 4, Yellow No. 5, Green No. 3, Blue No. 1, etc., organic pigment powders such as zirconium, barium or aluminum lake, metal powders such as aluminum powder, gold powder, silver powder,
Composite powders of fine particle titanium oxide-coated mica titanium, fine particle zinc oxide-coated mica titanium, barium sulfate-coated mica titanium, titanium oxide-containing silicon dioxide, zinc oxide-containing silicon dioxide, and the like, and one or more of these may be used. Can be used. Among these, when a spherical powder is contained as the powder of the component (e), the smooth elongation and spreadability is further improved. These powders may be one or two of fluorine compounds, silicone compounds, metal soaps, lecithin, hydrogenated lecithin, collagen, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, waxes, surfactants and the like. Surface treatment may be performed using the above.

Component (e) in the powder cosmetic of the present invention
Is preferably 70 to 99.5%, more preferably 75 to 99%.
% Is more preferred. When the content of the component (e) is within this range, a powdery cosmetic which has smooth smooth spreadability more excellent can be obtained.

The powder cosmetic of the present invention contains, in addition to the above components,
Components generally used in cosmetics can be blended as long as the effects of the present invention are not impaired. Specifically, a surfactant, an organic silicone resin, an acrylic-silicone graft polymer, a film-forming agent such as a rosin acid derivative, an antioxidant, an ultraviolet absorber other than the component (c), methylcellulose, hydroxymethylcellulose, Carboxyvinyl polymer, alkyl-modified carboxyvinyl polymer,
Xanthan gum, carrageenan, guar gum, agar, water-soluble polymers such as pectin, vitamins A, B6, B12,
Vitamins such as C and E and derivatives thereof, rosemary extract, chamomile extract, carrot extract, assembly extract, catechin, catechin derivative, licorice extract, soybean extract, hop extract and other cosmetic ingredients, collagen, hyaluronic A humectant such as an acid, a hyaluronic acid derivative, trehalose, and aloe extract, a polyhydric alcohol such as ethanol, 1,3-butanediol, propylene glycol, dipropylene glycol, glycerin, and diglycerin, and a fragrance can be blended.

The surfactant which can be blended with the powder cosmetic of the present invention is blended for the purpose of dispersing the powder, improving the durability of the makeup and the like, and is commonly used in cosmetics. Any of them may be used, and examples thereof include nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants. As a nonionic surfactant,
For example, glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, propylene glycol fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct, sorbitol fatty acid ester and its Alkylene glycol adduct, polyalkylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyalkylene alkyl ether, glycerin alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene hydrogenated castor oil, lanolin alkylene glycol adduct, polyoxyalkylene alkyl Co-modified silicone, polyether-modified silicone, and the like. It can be used two or more.
As the anionic surfactant, for example, stearic acid,
Inorganic and organic salts of fatty acids such as lauric acid, alkylbenzene sulfates, alkyl sulfonates, α-olefin sulfonates, dialkyl sulfosuccinates, α-sulfonated fatty acid salts, acylmethyltaurine salts, N-methyl-N -Alkyl taurine salts, polyoxyethylene alkyl ether sulfates, polyoxyethylene alkyl phenyl ether sulfates, alkyl phosphates, polyoxyethylene alkyl ether phosphates, polyoxyethylene alkyl phenyl ether phosphates, N-acyl amino acid salts,
Examples thereof include N-acyl-N-alkylamino acid salts, o-alkyl-substituted malate salts, and alkylsulfosuccinate salts, and one or more of these can be used.
Examples of the cationic surfactant include alkylamine salts, polyamines and alkanolamine fatty acid derivatives,
Examples thereof include an alkyl quaternary ammonium salt and a cyclic quaternary ammonium salt, and one or more of these can be used. Examples of the amphoteric surfactant include amino acid type and betaine type carboxylic acid type, sulfate ester type, sulfonic acid type and phosphate ester type, and those which are safe for human body can be used. For example, N, N-dimethyl-N-alkyl-N-carboxylmethylammonium betaine, N, N-dialkylaminoalkylenecarboxylic acid, N, N, N-trialkyl-N-sulfoalkyleneammonium betaine, N, N- Dialkyl-N, N-bis (polyoxyethylene sulfate) ammonium betaine, 2-alkyl-1-hydroxyethyl-1
-Carboxymethyl imidazolinium betaine, lecithin and the like, and one or more of these can be used. The amount of the surfactant in the powder cosmetic of the present invention varies depending on the purpose of the surfactant, but is generally about 0.01 to 15%.

In the present invention, the powder cosmetic is a cosmetic in which the components (a) to (d) are present between the powders. It is different from cosmetics in which powder is dispersed in oil, so-called oily cosmetics.

The powder cosmetic of the present invention is produced by a generally known method, and specific examples thereof include the following methods. A method in which the components (a) to (d), which are heated and dissolved and uniformly dispersed and mixed, are added to the component (e) which is uniformly mixed and dispersed, mixed and dispersed, and pulverized by a hammer mill or the like. The components (a) to (d) are heated, mixed and dispersed, and mixed with a volatile solvent such as methanol, ethanol, 2-propanol, ethyl acetate, and toluene. A method in which the component (e) is added thereto, mixed and dispersed, the solvent is dried under reduced pressure, and pulverized by a hammer mill or the like. (So-called Method of Surface Treatment of Powder) A method of mixing the above-mentioned pulverized material with another component (e).

The powder cosmetic of the present invention includes body powder, foundation, eyeshadow, blusher, white powder and the like. Among them, foundation, white powder,
Makeup products such as eye shadows are cosmetics in which the effects of the present invention can be more easily exerted. The form of the powder cosmetic of the present invention may be any of powder and solid.
Further, the effect of the present invention is easily exhibited, as a form,
It is solid by press molding or the like.

[0024]

EXAMPLES Next, the present invention will be further described with reference to examples, but the present invention is not limited to these examples.

Examples 1 to 5 and Comparative Examples 1 to 5: Pressed powder foundations Pressed foundations having the compositions shown in Tables 1 and 2 were prepared by the following methods, and were evaluated for "adhesion to skin" and "smooth elongation". Each item of "spreading", "uniformity of the decorative film", and "stability over time" was evaluated by the following evaluation methods, and the results are shown in Tables 1 and 2.

[0026]

[Table 1]

[0027]

[Table 2]

Note 1: Silicon KSG-16 (Shin-Etsu Chemical Co., Ltd.) Note 2: Silicon KSG-18 (Shin-Etsu Chemical Co., Ltd.) Note 3: Silicon KF-96 (20CS) (Shin-Etsu Chemical Co., Ltd.) Note 4 : Silicon KF-56 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method) A: Components 1 to 10 are heated to 80 ° C. and uniformly dispersed. B: Components 11 to 21 are mixed and dispersed by a super mixer. C: A, components 22 to 24 are added to B, mixed and dispersed. D: C was pulverized by a hammer mill and then compression-molded into a metal plate to obtain a pressed foundation.

(Evaluation Method of Usability / Sensory) Forty women with a makeup history of 10 years or more used the pressed foundations of the above Examples and Comparative Examples. Spread and spread "," Uniformity of decorative film "
For each of the above items, the following criteria were used to judge the number of people who felt good.

(Evaluation Method of Stability over Time) The pressed foundations of the above Examples and Comparative Examples were stored at 5 to 40 ° C. cycles, 5 ° C., 15 ° C., 30 ° C., and 50 ° C. constant temperature chambers. The surface condition of the press after one month was observed and judged according to the following criteria.

As is clear from the above results, the pressed foundations of the examples according to the present invention are excellent in all of the items of adhesion, smooth expansion, uniformity of the decorative film, and stability over time without crystal precipitation. I was On the other hand, the pressed foundation of the comparative example did not satisfy all the items.

Example 6: Loose white powder (component) (% by mass) 1. Partially crosslinked organopolysiloxane mixture (Note 1) 0.5 Dimethyl polysiloxane (Note 3) 3 3. 3. 2-ethylhexyl p-methoxycinnamate 24 Stearyl alcohol 15. Organopolysiloxane elastomer (Note 5) 10 6. Talc 40 7. Mica titanium 5 8. 8. Sericite Remaining Red No. 226 0.210. Preservative appropriate amount 11. Appropriate amount of fragrance Note 5: Trefill E505C (Shin-Etsu Chemical Co., Ltd.)

(Production method) A: Components 1 to 4 are heated and dissolved at 60 ° C., and are uniformly dispersed and mixed. B: Components 5 to 10
, A and Component 11 are added and mixed and dispersed. C: B was ground with a hammer mixer and filled in a container to obtain a loose white powder. The loose white powder of Example 6 was excellent in all of the items of adhesion, smooth expansion, uniformity of the decorative film, and stability over time without crystal precipitation.

Example 7: Pressed eye color (component) (% by mass) 1. Partially crosslinked organopolysiloxane mixture (Note 2) 2 Methylphenylpolysiloxane 2 3. 3-ethylhexyl hydroxystearate 5 4. Isostearyl alcohol 15. N-lauroyl-L-glutamic acid di (phytostearyl-2-octyldodecyl) 3 6. Talc 10 7. 7. Bengara coated mica titanium 5 8. Sericite Remaining Red No. 226 0.210. Blue No. 404 0.1 11. Mica black 0.5 12. Preservative appropriate amount 13. Sodium hyaluronate 0.2

(Production Method) A: Components 1 to 5 and 12 are heated and dissolved at 60 ° C., and then uniformly dispersed and mixed. B: A and Component 13 are added to Components 6 to 11, and mixed and dispersed. C: B is ground with a hammer mixer. D: C was compression molded into a container to obtain a pressed eye color. The pressed eye color of Example 7 was excellent in all of the items of adhesion, smooth expansion and spreading, uniformity of the decorative film, and stability over time without crystal precipitation.

Example 8: Loose body powder (component) (% by mass) Partially crosslinked organopolysiloxane mixture (Note 1) 1 2. Dimethylpolysiloxane (Note 3) 1 3. Neopentyl glycol dicaprate 2 4. Microcrystalline wax 15 Talc remaining amount 6. Spherical polystyrene powder (average particle diameter 5 μm) 5 7. 7. Fumed silica 0.5 Preservative 0.3 9. Aloe extract 0.210. Appropriate amount of fragrance

(Production method) A: Components 1 to 4 are heated and dissolved at 80 ° C., and then uniformly dispersed and mixed. B: A and components 9 to 10 are added to components 5 to 8, and mixed and dispersed. C: B was ground with a hammer mixer and filled into a container to obtain a loose body powder. The loose body powder of Example 8 was excellent in all of the items of adhesion, smooth spreading, uniformity of the decorative film, and stability over time without crystal precipitation.

[0039]

As described in detail above, the powder cosmetic of the present invention has good adhesion and smooth elongation and spreadability.
The uniformity of the decorative film was high and the solid oil was excellent in stability over time without crystal precipitation.

──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. ⁷ Identification symbol FI theme coat ゛ (Reference) A61K 7/035 A61K 7/035

Claims (5)

[Claims] 1. Component (a) to (e); component (a) partially crosslinked organopolysiloxane component (b) liquid silicone oil component (c) liquid oil other than component (b) component (d) solid A powder cosmetic comprising an oil and / or a higher alcohol component (e) powder. 2. The powder cosmetic according to claim 1, wherein the content of the component (d) is 0.05 to 3% by mass. 3. The content of the component (b) and the content of the whole oil excluding the component (d) are represented by the ratio of the mass to the content of the component (b) /
3. The powder cosmetic according to claim 1, wherein the content of the total oil excluding the component (d) is from 0.4 to 0.8. 4. The ratio of the content of the component (d) to the content of the whole oil is represented by a mass ratio of the content of the component (d) / the content of the whole oil =
4. The method according to claim 1, wherein the ratio is 0.01 to 0.2.
Powder cosmetic according to any one of the above. 5. The powder cosmetic according to claim 1, wherein the powder cosmetic of the present invention is in a solid form.