JP2001261862A - Preparation process of prepreg, prepreg, metal-laminated laminate and printed circuit board - Google Patents
Preparation process of prepreg, prepreg, metal-laminated laminate and printed circuit boardInfo
- Publication number
- JP2001261862A JP2001261862A JP2000081836A JP2000081836A JP2001261862A JP 2001261862 A JP2001261862 A JP 2001261862A JP 2000081836 A JP2000081836 A JP 2000081836A JP 2000081836 A JP2000081836 A JP 2000081836A JP 2001261862 A JP2001261862 A JP 2001261862A
- Authority
- JP
- Japan
- Prior art keywords
- prepreg
- base material
- thermosetting resin
- resin
- fiber base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title abstract 3
- 229920005989 resin Polymers 0.000 claims abstract description 91
- 239000011347 resin Substances 0.000 claims abstract description 91
- 238000001035 drying Methods 0.000 claims abstract description 73
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract description 49
- 239000000463 material Substances 0.000 claims abstract description 48
- 239000002966 varnish Substances 0.000 claims abstract description 43
- 239000000835 fiber Substances 0.000 claims abstract description 42
- 239000002904 solvent Substances 0.000 claims abstract description 15
- 238000000576 coating method Methods 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 claims description 17
- 239000011888 foil Substances 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000010030 laminating Methods 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 239000002585 base Substances 0.000 description 37
- 239000011521 glass Substances 0.000 description 27
- 239000002759 woven fabric Substances 0.000 description 22
- 239000003822 epoxy resin Substances 0.000 description 19
- 229920000647 polyepoxide Polymers 0.000 description 19
- 229920003986 novolac Polymers 0.000 description 14
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 12
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 8
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 238000005470 impregnation Methods 0.000 description 6
- 230000035699 permeability Effects 0.000 description 6
- -1 diethylenethiamine Chemical compound 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 4
- 229930003836 cresol Natural products 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- LLPKQRMDOFYSGZ-UHFFFAOYSA-N 2,5-dimethyl-1h-imidazole Chemical compound CC1=CN=C(C)N1 LLPKQRMDOFYSGZ-UHFFFAOYSA-N 0.000 description 2
- ULKLGIFJWFIQFF-UHFFFAOYSA-N 5K8XI641G3 Chemical compound CCC1=NC=C(C)N1 ULKLGIFJWFIQFF-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000008065 acid anhydrides Chemical class 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 239000011889 copper foil Substances 0.000 description 2
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- QCTJRYGLPAFRMS-UHFFFAOYSA-N prop-2-enoic acid;1,3,5-triazine-2,4,6-triamine Chemical compound OC(=O)C=C.NC1=NC(N)=NC(N)=N1 QCTJRYGLPAFRMS-UHFFFAOYSA-N 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- LTVUCOSIZFEASK-MPXCPUAZSA-N (3ar,4s,7r,7as)-3a-methyl-3a,4,7,7a-tetrahydro-4,7-methano-2-benzofuran-1,3-dione Chemical compound C([C@H]1C=C2)[C@H]2[C@H]2[C@]1(C)C(=O)OC2=O LTVUCOSIZFEASK-MPXCPUAZSA-N 0.000 description 1
- KNDQHSIWLOJIGP-UMRXKNAASA-N (3ar,4s,7r,7as)-rel-3a,4,7,7a-tetrahydro-4,7-methanoisobenzofuran-1,3-dione Chemical compound O=C1OC(=O)[C@@H]2[C@H]1[C@]1([H])C=C[C@@]2([H])C1 KNDQHSIWLOJIGP-UMRXKNAASA-N 0.000 description 1
- MUTGBJKUEZFXGO-OLQVQODUSA-N (3as,7ar)-3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione Chemical compound C1CCC[C@@H]2C(=O)OC(=O)[C@@H]21 MUTGBJKUEZFXGO-OLQVQODUSA-N 0.000 description 1
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- MTZUIIAIAKMWLI-UHFFFAOYSA-N 1,2-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC=C1N=C=O MTZUIIAIAKMWLI-UHFFFAOYSA-N 0.000 description 1
- ZXHZWRZAWJVPIC-UHFFFAOYSA-N 1,2-diisocyanatonaphthalene Chemical compound C1=CC=CC2=C(N=C=O)C(N=C=O)=CC=C21 ZXHZWRZAWJVPIC-UHFFFAOYSA-N 0.000 description 1
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
- FBHPRUXJQNWTEW-UHFFFAOYSA-N 1-benzyl-2-methylimidazole Chemical compound CC1=NC=CN1CC1=CC=CC=C1 FBHPRUXJQNWTEW-UHFFFAOYSA-N 0.000 description 1
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- PQAMFDRRWURCFQ-UHFFFAOYSA-N 2-ethyl-1h-imidazole Chemical compound CCC1=NC=CN1 PQAMFDRRWURCFQ-UHFFFAOYSA-N 0.000 description 1
- QUPKCFBHJFNUEW-UHFFFAOYSA-N 2-ethyl-4,5-dihydro-1h-imidazole Chemical compound CCC1=NCCN1 QUPKCFBHJFNUEW-UHFFFAOYSA-N 0.000 description 1
- YTWBFUCJVWKCCK-UHFFFAOYSA-N 2-heptadecyl-1h-imidazole Chemical compound CCCCCCCCCCCCCCCCCC1=NC=CN1 YTWBFUCJVWKCCK-UHFFFAOYSA-N 0.000 description 1
- NCVGSSQICKMAIA-UHFFFAOYSA-N 2-heptadecyl-4,5-dihydro-1h-imidazole Chemical compound CCCCCCCCCCCCCCCCCC1=NCCN1 NCVGSSQICKMAIA-UHFFFAOYSA-N 0.000 description 1
- VWSLLSXLURJCDF-UHFFFAOYSA-N 2-methyl-4,5-dihydro-1h-imidazole Chemical compound CC1=NCCN1 VWSLLSXLURJCDF-UHFFFAOYSA-N 0.000 description 1
- ZCUJYXPAKHMBAZ-UHFFFAOYSA-N 2-phenyl-1h-imidazole Chemical compound C1=CNC(C=2C=CC=CC=2)=N1 ZCUJYXPAKHMBAZ-UHFFFAOYSA-N 0.000 description 1
- BKCCAYLNRIRKDJ-UHFFFAOYSA-N 2-phenyl-4,5-dihydro-1h-imidazole Chemical compound N1CCN=C1C1=CC=CC=C1 BKCCAYLNRIRKDJ-UHFFFAOYSA-N 0.000 description 1
- FUOZJYASZOSONT-UHFFFAOYSA-N 2-propan-2-yl-1h-imidazole Chemical compound CC(C)C1=NC=CN1 FUOZJYASZOSONT-UHFFFAOYSA-N 0.000 description 1
- BTYIFQSAIPDZQW-UHFFFAOYSA-N 2-propan-2-yl-4,5-dihydro-1h-imidazole Chemical compound CC(C)C1=NCCN1 BTYIFQSAIPDZQW-UHFFFAOYSA-N 0.000 description 1
- LLEASVZEQBICSN-UHFFFAOYSA-N 2-undecyl-1h-imidazole Chemical compound CCCCCCCCCCCC1=NC=CN1 LLEASVZEQBICSN-UHFFFAOYSA-N 0.000 description 1
- FQHUDZKKDCTQET-UHFFFAOYSA-N 2-undecyl-4,5-dihydro-1h-imidazole Chemical compound CCCCCCCCCCCC1=NCCN1 FQHUDZKKDCTQET-UHFFFAOYSA-N 0.000 description 1
- CMLFRMDBDNHMRA-UHFFFAOYSA-N 2h-1,2-benzoxazine Chemical group C1=CC=C2C=CNOC2=C1 CMLFRMDBDNHMRA-UHFFFAOYSA-N 0.000 description 1
- AERZMMNNWVZSNB-UHFFFAOYSA-N 3-dodec-1-ynyloxolane-2,5-dione Chemical compound CCCCCCCCCCC#CC1CC(=O)OC1=O AERZMMNNWVZSNB-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- CPHGOBGXZQKCKI-UHFFFAOYSA-N 4,5-diphenyl-1h-imidazole Chemical compound N1C=NC(C=2C=CC=CC=2)=C1C1=CC=CC=C1 CPHGOBGXZQKCKI-UHFFFAOYSA-N 0.000 description 1
- TYOXIFXYEIILLY-UHFFFAOYSA-N 5-methyl-2-phenyl-1h-imidazole Chemical compound N1C(C)=CN=C1C1=CC=CC=C1 TYOXIFXYEIILLY-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- MQJKPEGWNLWLTK-UHFFFAOYSA-N Dapsone Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 MQJKPEGWNLWLTK-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 150000001341 alkaline earth metal compounds Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- IMUDHTPIFIBORV-UHFFFAOYSA-N aminoethylpiperazine Chemical compound NCCN1CCNCC1 IMUDHTPIFIBORV-UHFFFAOYSA-N 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 239000004841 bisphenol A epoxy resin Substances 0.000 description 1
- 239000004842 bisphenol F epoxy resin Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000004643 cyanate ester Substances 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- FLBJFXNAEMSXGL-UHFFFAOYSA-N het anhydride Chemical compound O=C1OC(=O)C2C1C1(Cl)C(Cl)=C(Cl)C2(Cl)C1(Cl)Cl FLBJFXNAEMSXGL-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000001841 imino group Chemical group [H]N=* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- VYKXQOYUCMREIS-UHFFFAOYSA-N methylhexahydrophthalic anhydride Chemical compound C1CCCC2C(=O)OC(=O)C21C VYKXQOYUCMREIS-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- QOHMWDJIBGVPIF-UHFFFAOYSA-N n',n'-diethylpropane-1,3-diamine Chemical compound CCN(CC)CCCN QOHMWDJIBGVPIF-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- DIHAURBCYGTGCV-UHFFFAOYSA-N xi-4,5-Dihydro-2,4(5)-dimethyl-1H-imidazole Chemical compound CC1CN=C(C)N1 DIHAURBCYGTGCV-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Reinforced Plastic Materials (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、プリプレグの製造
方法、プリプレグ、金属張り積層板及び印刷配線板に関
する。The present invention relates to a method for producing a prepreg, a prepreg, a metal-clad laminate, and a printed wiring board.
【0002】[0002]
【従来の技術】一般にプリント配線板用に使用されるプ
リプレグは、ガラス織布に熱硬化性樹脂を有機溶剤で希
釈した熱硬化性樹脂ワニスを含浸した後、乾燥炉にて溶
剤を揮発させ熱硬化性樹脂をBステージ状態まで硬化さ
せ製造される。この塗工工程と乾燥工程は、塗工機にお
いて一連の流れになっており、帯状のガラス織布に熱硬
化性樹脂ワニスを含浸させ、含浸させたガラス織布を乾
燥炉で乾燥している。2. Description of the Related Art In general, a prepreg used for a printed wiring board is prepared by impregnating a glass woven fabric with a thermosetting resin varnish obtained by diluting a thermosetting resin with an organic solvent, and then evaporating the solvent in a drying oven. It is manufactured by curing a curable resin to a B-stage state. The coating step and the drying step are a series of flows in a coating machine, in which a band-shaped glass woven cloth is impregnated with a thermosetting resin varnish, and the impregnated glass woven cloth is dried in a drying furnace. .
【0003】ガラス織布に熱硬化性樹脂ワニスを含浸さ
せる塗工工程は、熱硬化性樹脂ワニス中にガラス織布を
浸漬させ、その後、スクイズロール間隙を通過させるこ
とで熱硬化性樹脂ワニスの計量を行っている。[0003] In the coating step of impregnating a glass woven fabric with a thermosetting resin varnish, the glass woven fabric is immersed in the thermosetting resin varnish, and then passed through a gap between squeeze rolls to form the thermosetting resin varnish. Weighing.
【0004】溶剤を揮発させ、樹脂を硬化させる乾燥工
程は、ガラス織布の場合、一般に、縦型乾燥炉が用いら
れており、搬送されてくる基材に熱硬化性樹脂ワニスを
含浸した後、スクイズロール間隙を垂直方向に通過させ
た後、乾燥炉出口の引き出しロールにより縦型乾燥炉内
を垂直方向に引っ張られて移動し、樹脂をBステージ状
態まで硬化させることが一般的に行われている。[0004] In the drying step of volatilizing the solvent and curing the resin, in the case of a glass woven fabric, a vertical drying oven is generally used, and a conveyed substrate is impregnated with a thermosetting resin varnish. After passing vertically through the gap between the squeeze rolls, it is generally performed that the drawer rolls at the outlet of the drying furnace are pulled vertically in the vertical drying furnace to move and harden the resin to the B-stage state. ing.
【0005】しかし、上述した縦型乾燥炉において、熱
硬化性樹脂ワニスを含浸したガラス織布を乾燥する際、
ガラス織布を上方に移動させる必要があり、ガラス織布
を移動させるためには、大きな張力が必要となる。即
ち、縦型乾燥炉では、ガラス織布を重力に抗して上方に
移動させるための張力が必要であり、縦型乾燥炉の出口
に設けた引き出しロールによりガラス織布に張力を作用
させている。この張力が掛かった状態で樹脂が硬化する
ため、張力が歪みとなってプリプレグに残存する。However, when drying the glass woven fabric impregnated with the thermosetting resin varnish in the above-described vertical drying oven,
It is necessary to move the glass woven fabric upward, and a large tension is required to move the glass woven fabric. That is, in the vertical drying oven, tension is required to move the glass woven fabric upward against the gravity, and the tension is applied to the glass woven fabric by the drawer roll provided at the outlet of the vertical drying oven. I have. Since the resin is cured in a state where the tension is applied, the tension is distorted and remains on the prepreg.
【0006】この残存歪みを有するプリプレグを用い
て、金属張り積層板を製造すると、残存歪みが悪影響を
及ぼし,金属張り積層板の寸法安定性やそり特性が低下
する課題がある。また、このプリプレグを多層接着用プ
リプレグとして用いても同様の課題となる。When a metal-clad laminate is manufactured using a prepreg having this residual strain, the residual strain has an adverse effect, and there is a problem that the dimensional stability and warpage characteristics of the metal-clad laminate are reduced. Further, the same problem occurs even when this prepreg is used as a prepreg for multilayer bonding.
【0007】この残存歪みを有するプリプレグを用い
て、金属張り積層板を製造すると、残存歪みが悪影響を
及ぼし,金属張り積層板の寸法安定性やそり特性が低下
する課題がある。また、このプリプレグを多層接着用プ
リプレグとして用いても同様の課題となる。When a metal-clad laminate is manufactured using the prepreg having the residual strain, the residual strain has an adverse effect, and there is a problem that the dimensional stability and warpage characteristics of the metal-clad laminate are reduced. Further, the same problem occurs even when this prepreg is used as a prepreg for multilayer bonding.
【0008】[0008]
【発明が解決しようとする課題】この発明は、上記課題
に鑑みてなされたものであり、残留歪みの小さいプリプ
レグの製造方法、この製造方法により得られるプリプレ
グ並びにこれを用いた高寸法安定性の金属張り積層板及
び印刷配線板の提供を目的とする。SUMMARY OF THE INVENTION The present invention has been made in view of the above problems, and is directed to a method of manufacturing a prepreg having a small residual strain, a prepreg obtained by the method, and a high dimensional stability using the prepreg. It is intended to provide a metal-clad laminate and a printed wiring board.
【0009】[0009]
【課題を解決するための手段】本発明は、次のものに関
する。 1. 繊維基材に熱硬化性樹脂ワニスを含浸する塗工工
程と繊維基材に含浸された熱硬化性樹脂ワニスの溶剤を
揮発させ、樹脂を半硬化させる乾燥工程を含むプリプレ
グの製造方法において、乾燥工程を乾燥炉入口温度を樹
脂の軟化点未満とする横型乾燥炉を用いて行うことを特
徴とするプリプレグの製造方法。 2. 繊維基材に熱硬化性樹脂ワニスを含浸する塗工工
程と繊維基材に含浸された熱硬化性樹脂ワニスの溶剤を
揮発させ、樹脂を半硬化させる乾燥工程を含むプリプレ
グの製造方法において、乾燥工程を上記の熱硬化性樹脂
ワニスによって含浸された繊維基材を水平方向に移動さ
せて行い、しかも、乾燥工程の最初は樹脂の軟化点以下
に加熱することを特徴とするプリプレグの製造方法。 3. 繊維基材が帯状のものである項1又は2記載のプ
リプレグの製造方法。 4. 項1〜3のいずれかに記載の方法により製造した
プリプレグ。 5. 項4に記載のプリプレグ又はその積層体の片面又
は両面に金属箔を積層し、加熱加圧成形してなる金属張
り積層板。 6. 項6に記載の金属張り積層板に回路加工を施して
なる印刷配線板。The present invention relates to the following. 1. In the prepreg manufacturing method including a coating step of impregnating the thermosetting resin varnish on the fiber base material and a drying step of semi-curing the resin by volatilizing the solvent of the thermosetting resin varnish impregnated on the fiber base material. A method for producing a prepreg, wherein the step is performed using a horizontal drying furnace in which the drying furnace inlet temperature is lower than the softening point of the resin. 2. In the prepreg manufacturing method including a coating step of impregnating the thermosetting resin varnish on the fiber base material and a drying step of semi-curing the resin by volatilizing the solvent of the thermosetting resin varnish impregnated on the fiber base material. A process for producing a prepreg, wherein the step is carried out by moving the fiber base material impregnated with the thermosetting resin varnish in the horizontal direction, and heating the resin to a temperature lower than the softening point of the resin at the beginning of the drying step. 3. Item 3. The method for producing a prepreg according to Item 1 or 2, wherein the fibrous base material is a strip. 4. A prepreg produced by the method according to any one of Items 1 to 3. 5. Item 5. A metal-clad laminate obtained by laminating a metal foil on one or both sides of the prepreg or the laminate thereof according to Item 4, and molding by heating and pressing. 6. Item 7. A printed wiring board obtained by subjecting the metal-clad laminate according to Item 6 to circuit processing.
【0010】[0010]
【発明の実施の形態】本発明おいて、乾燥工程では、熱
硬化性樹脂ワニスを含浸した繊維基材を水平方向に移動
させるので、熱硬化性樹脂ワニスを含浸した繊維基材に
かかる引っ張り力が小さくすることができるため、本発
明により得られたプリプレグを用いて製造した金属張り
積層板又は印刷配線板のそり又は寸法変化を小さくする
ことができる。また、本発明おいて、乾燥工程での引っ
張り力は、特に、3.0N/cm以下になるように調整
されることが好ましく、これにより得られたプリプレグ
を用いて製造した金属張り積層板又は印刷配線板のそり
又は寸法変化を小さくすることができる。上記の引っ張
り力は、2.5N/cm以下になるように調整されるこ
とが、さらに好ましい。本発明おいて、乾燥工程では、
熱硬化性樹脂ワニスを含浸した繊維基材に乾燥炉内を移
動させて乾燥されることが特に好ましい。上記の繊維基
材としては、取り扱い安さの点から、帯状のものを使用
することが好ましい。DESCRIPTION OF THE PREFERRED EMBODIMENTS In the present invention, in the drying step, the fiber base material impregnated with the thermosetting resin varnish is moved in the horizontal direction. Therefore, warpage or dimensional change of a metal-clad laminate or printed wiring board manufactured using the prepreg obtained according to the present invention can be reduced. In the present invention, the tensile force in the drying step is particularly preferably adjusted to be 3.0 N / cm or less, and the metal-clad laminate manufactured using the prepreg obtained thereby or Warpage or dimensional change of the printed wiring board can be reduced. More preferably, the above-mentioned tensile force is adjusted to be 2.5 N / cm or less. In the present invention, in the drying step,
It is particularly preferable that the fiber base material impregnated with the thermosetting resin varnish is moved in a drying furnace and dried. As the above-mentioned fiber base material, it is preferable to use a band-like material from the viewpoint of ease of handling.
【0011】乾燥炉の長さは、熱硬化性樹脂を含浸した
繊維基材の移動速度、乾燥炉の温度等により異なるが、
それを通過したときに熱硬化性樹脂が半硬化状態、特に
B−ステージ状態になるように調整される。The length of the drying oven varies depending on the moving speed of the fiber base material impregnated with the thermosetting resin, the temperature of the drying oven, and the like.
The thermosetting resin is adjusted so as to be in a semi-cured state, particularly a B-stage state, when passing therethrough.
【0012】乾燥工程の最初の温度又は乾燥炉の入り口
温度は、樹脂の軟化点未満とされる。また、溶剤の揮発
及び温度安定性を考慮すると50℃以上が好ましい。軟
化点温度未満の温度にて、溶剤が十分揮発除去されるよ
うに、熱硬化性樹脂ワニスを含浸させた繊維基材を滞留
させることが好ましいが、そのためにはこの滞留時間と
しては2〜15秒で十分である。また、熱硬化性樹脂ワ
ニスに使用される溶剤としては、この目的に適合した易
揮発性のものが好ましい。乾燥工程における温度又は乾
燥炉内の温度は、軟化温度以上200℃以下の温度が好
ましく、特に、150〜200℃の温度が好ましく、熱
硬化性樹脂を含浸した繊維基材の乾燥は、この温度雰囲
下に1〜15分曝されるようにして行うことが好まし
い。The temperature at the beginning of the drying step or at the entrance to the drying oven is below the softening point of the resin. Further, considering the volatilization of the solvent and the temperature stability, the temperature is preferably 50 ° C. or higher. At a temperature lower than the softening point temperature, it is preferable to retain the fiber base material impregnated with the thermosetting resin varnish so that the solvent can be sufficiently volatilized and removed. Seconds is enough. The solvent used for the thermosetting resin varnish is preferably a volatile solvent suitable for this purpose. The temperature in the drying step or the temperature in the drying furnace is preferably a temperature not lower than the softening temperature and not higher than 200 ° C, particularly preferably a temperature of 150 to 200 ° C. The drying of the fiber base material impregnated with the thermosetting resin is performed at this temperature. It is preferable that the exposure is performed under an atmosphere for 1 to 15 minutes.
【0013】乾燥工程では、乾燥工程又は乾燥炉(横型
乾燥炉として一般に知られているのものでよい)〕の入
り口付近以前に位置する送りロールと乾燥工程又は乾燥
炉の出口付近以降に位置する引き出しロールとにより繊
維基材を乾燥工程中は又は乾燥内を水平方向に移動させ
ることが好ましい。この目的のために、特別に送りロー
ルを設置してもよいが、スクイズロールにこの役目をさ
せてもよい。引き出しロールについても、この目的のた
めに特別に引き出しロールを設置してもよく、巻き取り
ロールにこの役目をさせてもよい。[0013] In the drying step, a feed roll located before the entrance of the drying step or drying oven (which may be generally known as a horizontal drying oven)] and a feed roll located near the exit of the drying step or the drying oven. It is preferable to move the fiber base material in the drying step or in the drying direction in the horizontal direction using the drawer roll. For this purpose, a special feed roll may be provided, but a squeeze roll may perform this function. As for the drawer roll, a drawer roll may be specially provided for this purpose, and the take-up roll may perform this function.
【0014】送りロールの回転速度と引き出しロールの
回転速度は、乾燥炉内での熱硬化性樹脂を含浸した繊維
基材にかかる引っ張り力をなくすか小さくすることがで
きるように調整される。これにより、繊維基材にかかる
張力を少なくできるので繊維基材に作用する残留歪みを
小さくすることできる。さらに、具体的には、送りロー
ルの回転速度は、引き出しロールの回転速度の95〜1
05%とすることが好ましい。送りロール(特に、スク
イズロールを送りロールとして使用した場合)はワニス
により滑るため、送りロールの回転速度は、引き出しロ
ールの回転速度の100〜105%とすることが特に好
ましい。また、引き出しロールの回転速度と送りロール
の回転速度は、熱硬化性樹脂ワニスを含浸した繊維基材
にかかる引っ張り力が、3.0N/cm以下になるよう
に調整されることが特に好ましい。The rotation speed of the feed roll and the rotation speed of the drawer roll are adjusted so that the tensile force applied to the fiber base material impregnated with the thermosetting resin in the drying furnace can be eliminated or reduced. Thereby, the tension applied to the fiber base material can be reduced, so that the residual strain acting on the fiber base material can be reduced. More specifically, the rotation speed of the feed roll is 95 to 1 of the rotation speed of the pull-out roll.
It is preferably set to 05%. Since the feed roll (especially when a squeeze roll is used as the feed roll) slides with the varnish, the rotation speed of the feed roll is particularly preferably 100 to 105% of the rotation speed of the drawer roll. It is particularly preferable that the rotation speed of the drawer roll and the rotation speed of the feed roll are adjusted so that the tensile force applied to the fiber base material impregnated with the thermosetting resin varnish is 3.0 N / cm or less.
【0015】以下、本発明を図面を参照しながら説明す
る。図1は、本発明のプリプレグの製造に使用される装
置の一例の概略図である。プリプレグ横型製造装置1
は、熱硬化性樹脂ワニス2を入れた含浸槽3、含浸槽3
内の含浸ロール4、送りロールを兼ねるスクイズロール
5、横型乾燥炉6、引き出しロール7とを備えている。
搬送されてくる帯状のガラス織布等の繊維基材8に含浸
槽3で含浸ロール4の下を通過させて熱硬化性樹脂ワニ
ス2を含浸した後、スクイズロール5間隙を通過させ、
横型乾燥炉6中を水平移動して、引き出しロール7によ
り引き出される。横型乾燥炉6では、熱硬化性樹脂をB
ステージ状態まで硬化させプリプレグを製造する。横型
乾燥炉6からでてきたプリプレグは、引き出しロール7
に又は引き出しロール7を通過後に巻き取りロールに巻
き取られるか、引き出しロール7を通過後に所定寸法に
裁断される。横型乾燥炉6内では、繊維基材8を支える
ために、下からエアー等の気体を吹き上げることが好ま
しく、この場合、基材が波打たず安定するように上から
もエアー等の気体を吹き付けるようにすることが好まし
い。また、横型乾燥炉6内では、繊維基材を支えるため
に、ロール等を使用してもよい。乾燥炉内の気体は,繊
維基材を支持するためには,風速5m/分〜15m/分
が好ましい。Hereinafter, the present invention will be described with reference to the drawings. FIG. 1 is a schematic view of an example of an apparatus used for producing the prepreg of the present invention. Pre-preg horizontal manufacturing equipment 1
Are impregnation tank 3 containing thermosetting resin varnish 2, impregnation tank 3
And a squeeze roll 5 also serving as a feed roll, a horizontal drying furnace 6, and a drawer roll 7.
The impregnated tank 3 impregnates the thermosetting resin varnish 2 with the conveyed fiber base material 8 such as a glass woven cloth or the like in the impregnation tank 3, and then passes through the gap of the squeeze roll 5.
It is moved horizontally in the horizontal drying furnace 6 and pulled out by the drawer roll 7. In the horizontal drying furnace 6, the thermosetting resin is
It is cured to a stage state to produce a prepreg. The prepreg coming out of the horizontal drying furnace 6 is supplied to a drawer roll 7.
Or after being passed through a drawer roll 7, it is wound on a take-up roll, or is cut into a predetermined size after passing through the drawer roll 7. In the horizontal drying furnace 6, in order to support the fiber base material 8, it is preferable to blow up gas such as air from below. In this case, gas such as air is also blown from above so that the base material is stable without waving. It is preferable to spray. In the horizontal drying furnace 6, a roll or the like may be used to support the fiber base material. The gas in the drying oven preferably has a wind speed of 5 m / min to 15 m / min in order to support the fiber base material.
【0016】本発明の繊維基材は、ガラス繊維、有機繊
維等の織布又は不織布である。ガラス織布が最も好まし
い。この繊維基材に樹脂の保持力を持たせ、熱硬化性樹
脂を含浸した繊維基材が乾燥炉内を移動する際、繊維基
材に付着した熱硬化性樹脂ワニスが重力により繊維基材
の下側に移行するので、プリプレグ表裏の樹脂付着量を
均一になるように調整するためには、繊維基材の通気度
y(cc/cm2/sec)と厚みx(μm)の相関が
(1)式The fiber substrate of the present invention is a woven or non-woven fabric such as glass fiber and organic fiber. Glass woven fabric is most preferred. When the fiber base material having a resin holding force is imparted to the fiber base material and the thermosetting resin-impregnated fiber base material moves in the drying oven, the thermosetting resin varnish attached to the fiber base material is gravity-adjusted. Since it shifts to the lower side, the correlation between the air permeability y (cc / cm 2 / sec) and the thickness x (μm) of the fiber base material (1 )formula
【数1】 y≦−0.1x+25 (1) を満足するようにされることが好ましい。繊維基材の厚
みは、材質にもよるが、50〜250μmが好ましい。
本発明において、通気度は、JIS R 3420に基
づいて測定したものである。従って、このプリプレグを
用いて製造した金属張り積層板又は印刷配線板は、特
に、そり又は寸法変化が小さい。上記プリプレグを、多
層接着用プリプレグとして使用する場合においても同様
の効果がある。It is preferable that the following formula is satisfied: y ≦ −0.1x + 25 (1) The thickness of the fiber substrate depends on the material, but is preferably 50 to 250 μm.
In the present invention, the air permeability is measured based on JIS R 3420. Therefore, a metal-clad laminate or a printed wiring board manufactured using this prepreg is particularly small in warpage or dimensional change. The same effect can be obtained when the prepreg is used as a prepreg for multilayer bonding.
【0017】本発明に用いられる熱硬化性樹脂として
は、エポキシ樹脂、フェノール樹脂、ポリイミド樹脂、
ポリエステル樹脂、シアネートエステル樹脂、ベンゾオ
キサジン環を有する樹脂、トリアジン環を有する熱硬化
性樹脂が適用できるが、エポキシ樹脂が耐熱性、吸水率
の点から特に好ましい。The thermosetting resin used in the present invention includes epoxy resin, phenol resin, polyimide resin,
A polyester resin, a cyanate ester resin, a resin having a benzoxazine ring, and a thermosetting resin having a triazine ring can be used, and an epoxy resin is particularly preferable in terms of heat resistance and water absorption.
【0018】エポキシ樹脂としては、2官能以上のエポ
キシ樹脂が用いられる。例えば、ビスフェノールA型エ
ポキシ樹脂、ビスフェノールF型エポキシ樹脂、ビスフ
ェノールS型エポキシ樹脂、脂環式エポキシ樹脂、フェ
ノールノボラック型エポキシ樹脂、クレゾールノボラッ
ク型エポキシ樹脂、ビスフェノールAノボラック型エポ
キシ樹脂、多官能フェノールのジグリシジルエーテル化
物、多官能アルコールのジグリシジルエーテル化物、こ
れらの水素添加物などを挙げることができる。これら
は、通常は単独で用いられるが、何種類かを併用するこ
ともできる。As the epoxy resin, a bifunctional or higher functional epoxy resin is used. For example, bisphenol A epoxy resin, bisphenol F epoxy resin, bisphenol S epoxy resin, alicyclic epoxy resin, phenol novolak epoxy resin, cresol novolak epoxy resin, bisphenol A novolak epoxy resin, polyfunctional phenol Glycidyl ether products, diglycidyl ether products of polyfunctional alcohols, hydrogenated products thereof, and the like can be given. These are usually used alone, but several types can be used in combination.
【0019】硬化剤としては、エポキシ樹脂の硬化剤と
して電気絶縁材料用途で用いられているものであれば特
に制限はなく、例えば、アミン類、フェノール類、酸無
水物などを用いることができる。以下に具体的な化合物
を例示する。アミン類としては、ジエチルアミン、ジエ
ツレントチアミン、トリエチレンテトラミン、ジエチル
アミノプロピルアミン、アミノエチルピペラジン、メン
センジアミン、メタキシリレンジアミン、ジシアンジア
ミド、ジアミノジフェニルメタン、ジアミノジフェニル
スルフォン、メチレンジアニリン、メタフェニレンジア
ミンなどを挙げることができる。フェノール類として
は、ビスフェノール、ビスフェノールA、ビスフェノー
ルF、フェノールノボラック樹脂、クレゾールノボラッ
ク樹脂、ビスフェノールAノボラック樹脂、およびこれ
らのアルキル基置換体などを挙げることができる。酸無
水物としては、無水ヘキサヒドロフタル酸、無水テトラ
ヒドロフタル酸、無水ピロメッリト酸、無水クロレンド
酸、無水ナディック酸、無水メチルナディック酸、無水
ドデシニルコハク酸、無水フタル酸、メチルヘキサヒド
ロ無水フタル酸、無水マレイン酸などを挙げることがで
きる。これらは、通常は単独で用いられるが、何種類か
を併用することもできる。The curing agent is not particularly limited as long as it is used as an epoxy resin curing agent for electric insulating materials. For example, amines, phenols, acid anhydrides and the like can be used. Specific compounds are shown below. Examples of amines include diethylamine, diethylenethiamine, triethylenetetramine, diethylaminopropylamine, aminoethylpiperazine, mensendiamine, metaxylylenediamine, dicyandiamide, diaminodiphenylmethane, diaminodiphenylsulfone, methylenedianiline, and metaphenylenediamine. Can be mentioned. Examples of the phenols include bisphenol, bisphenol A, bisphenol F, phenol novolak resin, cresol novolak resin, bisphenol A novolak resin, and alkyl group-substituted products thereof. Examples of the acid anhydride include hexahydrophthalic anhydride, tetrahydrophthalic anhydride, pyromellitic anhydride, chlorendic anhydride, nadic anhydride, methylnadic anhydride, dodecynylsuccinic anhydride, phthalic anhydride, methylhexahydrophthalic anhydride, Maleic anhydride and the like can be mentioned. These are usually used alone, but several types can be used in combination.
【0020】エポキシ樹脂として、ノボラック型エポキ
シ樹脂、例えば、フェノールノボラック型エポキシ樹
脂、クレゾールノボラック型エポキシ樹脂、ビスフェノ
ールAノボラック型エポキシ樹脂などと、また、硬化剤
として、ノボラック型フェノール樹脂、例えば、フェノ
ールノボラック樹脂、クレゾールノボラック樹脂、ビス
フェノールAノボラック樹脂などと組み合わせるのが硬
化物の耐熱性が優れることから好ましい。As the epoxy resin, a novolak type epoxy resin, for example, a phenol novolak type epoxy resin, a cresol novolak type epoxy resin, a bisphenol A novolak type epoxy resin, and the like, and as a curing agent, a novolak type phenol resin, for example, phenol novolak A combination with a resin, a cresol novolak resin, a bisphenol A novolak resin, or the like is preferable because the cured product has excellent heat resistance.
【0021】硬化剤は、エポキシ樹脂のエポキシ基1当
量に対して、硬化剤の官能基が0.8〜1.2当量の範
囲に配合されるのが好ましく、0.85〜1.1当量の
範囲となるように配合されるのがより好ましい。硬化剤
の官能基が0.8当量未満の場合、および1.2当量を
超えるいずれの場合も、ガラス転移温度が低くなり、吸
湿しやすくなるため耐熱性が低下する。The curing agent is preferably used such that the functional group of the curing agent is blended in the range of 0.8 to 1.2 equivalents with respect to 1 equivalent of the epoxy group of the epoxy resin, and 0.85 to 1.1 equivalents. More preferably, it is blended so as to fall within the range. In both cases where the functional group of the curing agent is less than 0.8 equivalent and more than 1.2 equivalent, the glass transition temperature becomes low and moisture is easily absorbed, so that heat resistance is lowered.
【0022】前記エポキシ樹脂及び硬化剤には、必要に
応じてさらに硬化促進剤が併用される。硬化促進剤とし
ては、エポキシ基とフェノール性水酸基のエーテル化反
応を促進させるような触媒機能を持つ化合物であれば制
限無く、例えば、アルカリ金属化合物、アルカリ土類金
属化合物、イミダゾール化合物、有機りん化合物、第二
級アミン、第三級アミン、第四級アンモニウム塩などが
挙げられる。イミノ基がアクリロニトリル、イソシアネ
ート、メラミンアクリレートなどでマスク化されたイミ
ダゾールを用いると、従来の2倍以上の保存安定性を有
するプリプレグを得ることができ好ましい。A curing accelerator may be used in combination with the epoxy resin and the curing agent, if necessary. The curing accelerator is not limited as long as it is a compound having a catalytic function of accelerating an etherification reaction between an epoxy group and a phenolic hydroxyl group, and examples thereof include an alkali metal compound, an alkaline earth metal compound, an imidazole compound, and an organic phosphorus compound. , Secondary amines, tertiary amines, quaternary ammonium salts and the like. It is preferable to use imidazole in which the imino group is masked with acrylonitrile, isocyanate, melamine acrylate, or the like, since a prepreg having storage stability twice or more that of conventional prepregs can be obtained.
【0023】これらの硬化促進剤は何種類かを併用して
もよく、配合量はエポキシ樹脂100重量部に対して
0.01〜5重量部が好ましい。0.01重量部未満で
は促進効果が低下する傾向があり、5重量部を超えると
保存安定性が悪くなる傾向がある。These curing accelerators may be used in combination of several kinds, and the compounding amount is preferably 0.01 to 5 parts by weight based on 100 parts by weight of the epoxy resin. If the amount is less than 0.01 part by weight, the accelerating effect tends to decrease, and if it exceeds 5 parts by weight, the storage stability tends to deteriorate.
【0024】前記イミダゾール化合物としては、イミダ
ゾール、2−エチルイミダゾール、2−エチル−4−メ
チルイミダゾール、2−フェニルイミダゾール、2−ウ
ンデシルイミダゾール、1−ベンジル−2−メチルイミ
ダゾール、2−ヘプタデシルイミダゾール、4,5−ジ
フェニルイミダゾール、2−メチルイミダゾリン、2−
フェニルイミダゾリン、2−ウンデシルイミダゾリン、
2−ヘプタデシルイミダゾリン、2−イソプロピルイミ
ダゾール、2,4−ジメチルイミダゾール、2−フェニ
ル−4−メチルイミダゾール、2−エチルイミダゾリ
ン、2−イソプロピルイミダゾリン、2,4−ジメチル
イミダゾリン、2−フェニル−4−メチルイミダゾリン
などが挙げられ、マスク化剤としては、アクリロニトリ
ル、フェニレンジイソシアネート、トルイジンイソシア
ネート、ナフタレンジイソシアネート、メチレンビスフ
ェニルイソシアネート、メラミンアクリレートなどが挙
げられる。Examples of the imidazole compound include imidazole, 2-ethylimidazole, 2-ethyl-4-methylimidazole, 2-phenylimidazole, 2-undecylimidazole, 1-benzyl-2-methylimidazole, and 2-heptadecylimidazole. , 4,5-diphenylimidazole, 2-methylimidazoline, 2-
Phenylimidazoline, 2-undecylimidazoline,
2-heptadecylimidazoline, 2-isopropylimidazole, 2,4-dimethylimidazole, 2-phenyl-4-methylimidazole, 2-ethylimidazoline, 2-isopropylimidazoline, 2,4-dimethylimidazoline, 2-phenyl-4- Examples of the masking agent include acrylonitrile, phenylene diisocyanate, toluidine isocyanate, naphthalene diisocyanate, methylene bisphenyl isocyanate, and melamine acrylate.
【0025】熱硬化性樹脂には、さらに必要に応じて、
水酸化アルミニウム、クレー等の無機充填材が添加され
る。さらに、必要に応じて本発明の効果を阻害しない範
囲で他の化合物を配合することも可能である。In the thermosetting resin, if necessary,
An inorganic filler such as aluminum hydroxide and clay is added. Further, if necessary, other compounds can be blended as long as the effects of the present invention are not impaired.
【0026】前記熱硬化性樹脂、その他の成分は、溶剤
に溶解または分散させてワニスとして使用される。使用
される溶剤としては,アセトン,メチルエチルケトン,
メチルイソブチルケトンなどのケトン系溶剤,トルエ
ン,キシレンなどの芳香属炭化水素系溶剤,酢酸エチル
などのエステル系溶剤,エチレングリコールモノメチル
エーテルなどのエーテル系溶剤,N,N−ジメチルアセ
トアミドなどのアミド系溶剤,メタノール,エタノール
などのアルコール系溶剤が挙げられ,これらは何種類か
を混合して用いても良い。ワニス中の固形濃度は、50
〜80重量%になるようにするのが好ましい。The thermosetting resin and other components are dissolved or dispersed in a solvent and used as a varnish. Solvents used include acetone, methyl ethyl ketone,
Ketone solvents such as methyl isobutyl ketone; aromatic hydrocarbon solvents such as toluene and xylene; ester solvents such as ethyl acetate; ether solvents such as ethylene glycol monomethyl ether; amide solvents such as N, N-dimethylacetamide , Methanol, ethanol and the like, and some of them may be used as a mixture. The solid concentration in the varnish is 50
It is preferable that the content is about 80% by weight.
【0027】繊維基材への熱硬化性樹脂ワニスの含浸方
法には、特に制限はないが、熱硬化性樹脂ワニスを入れ
た槽内を基材樹脂に通過させることが好ましい。このと
き、繊維基材へのの樹脂付着量は、ワニス固形分と基材
の総量に対して、ワニス固形分が35〜60重量%にな
るようにするのが好ましい。The method of impregnating the fiber base material with the thermosetting resin varnish is not particularly limited, but it is preferable to pass the base resin through a tank containing the thermosetting resin varnish. At this time, the amount of resin adhered to the fiber base material is preferably such that the varnish solid content is 35 to 60% by weight based on the total amount of the varnish solid content and the base material.
【0028】得られたプリプレグは、所定の寸法に裁断
した後、1枚だけでまたは適宜任意枚数を積層してその
片面若しくは両面に金属箔を重ねて加熱加圧成形するこ
とにより金属箔張り積層板とすることができる。このと
きの条件としては、加熱温度が150〜230℃、圧力
が2〜5MPaの条件とすることが好ましく、この条件
に0.5〜2.0時間さらすことが好ましい。The obtained prepreg is cut into a predetermined size, and then laminated singly or in an arbitrary number of layers, and a metal foil is laminated by laminating a metal foil on one or both sides thereof and heating and pressing. It can be a plate. As the conditions at this time, it is preferable that the heating temperature is 150 to 230 ° C. and the pressure is 2 to 5 MPa, and it is preferable that the heating conditions be 0.5 to 2.0 hours.
【0029】上記金属箔としては銅箔、アルミ箔等が使
用される。金属箔の厚さは用途にもよるが5〜100μ
mのものが好適に用いられる。As the above-mentioned metal foil, copper foil, aluminum foil and the like are used. The thickness of the metal foil depends on the application, but is 5-100μ
m are preferably used.
【0030】金属箔張り積層板の金属箔に対して回路加
工を施すことにより印刷配線板とすることができる。回
路加工は、例えば、金属箔表面にレジストパターンを形
成後、エッチングにより不要部分の箔を除去し、レジス
トパターンを剥離後、ドリルにより必要なスルーホール
に導通させるためのメッキを施し、最後にレジストパタ
ーンを剥離することにより行うことができる。このよう
にして得られた印刷積層板の表面にさらに上記の金属箔
張り積層板を前記したのと同様の条件で積層し、さら
に、上記と同様にして加工して多層印刷配線板とするこ
とができる。この場合、必ずしもスルーホールを形成す
る必要はなく、バイアホールを形成してもよく、両方を
形成してもよい。このような多層化は必要な枚数行われ
る。The printed wiring board can be obtained by subjecting the metal foil of the metal foil-clad laminate to circuit processing. For circuit processing, for example, after forming a resist pattern on the surface of the metal foil, the unnecessary portion of the foil is removed by etching, the resist pattern is peeled off, plating is performed to conduct to the necessary through holes by a drill, and finally the resist is This can be performed by peeling the pattern. On the surface of the printed laminate thus obtained, the above-mentioned metal foil-clad laminate is further laminated under the same conditions as described above, and further processed in the same manner as above to obtain a multilayer printed wiring board. Can be. In this case, it is not always necessary to form a through hole, and a via hole may be formed, or both may be formed. Such multilayering is performed for a required number of sheets.
【0031】[0031]
【作用】横型乾燥炉において、熱硬化性樹脂ワニスを含
浸したガラス織布を乾燥する際、乾燥炉入口を樹脂の軟
化点以上の温度に設定すると樹脂が急激に軟化し,ガラ
ス織布表面を容易に移動し,その状態で樹脂が硬化して
しまうため,樹脂付着量が繊維基材の表裏でばらつく恐
れがある。樹脂付着量ばらつきが大きいプリプレグを用
いて、金属張り積層板を製造すると、金属張り積層板の
表面平滑性,板厚精度およびそり特性が低下するという
問題が生じるが、本発明においては、乾燥工程の最初又
は横型乾燥炉の入口温度を樹脂の軟化点以下とすること
で樹脂の粘度低下を抑制し、ガラス織布表面の樹脂流動
を小さくし,その後,樹脂硬化をするので樹脂の付着量
ばらつきが小さくなる。このように、本発明において
は、繊維基材の表裏で樹脂付着量ばらつきの小さいプリ
プレグが得られるので、表面平滑性,板厚精度およびそ
り特性の優れた金属張り積層板及び印刷配線板を製造す
ることができる。[Function] When drying glass woven fabric impregnated with a thermosetting resin varnish in a horizontal drying oven, if the temperature of the drying furnace inlet is set to a temperature higher than the softening point of the resin, the resin rapidly softens, and the surface of the glass woven fabric becomes soft. Since the resin easily moves and the resin hardens in that state, there is a possibility that the resin adhesion amount varies on the front and back of the fiber base material. When a metal-clad laminate is manufactured using a prepreg having a large variation in the amount of adhered resin, there arises a problem that the surface smoothness, plate thickness accuracy, and warpage characteristics of the metal-clad laminate are reduced. The initial or horizontal drying furnace inlet temperature is kept below the softening point of the resin to suppress the decrease in the viscosity of the resin, reduce the flow of the resin on the surface of the glass woven fabric, and then cure the resin. Becomes smaller. As described above, according to the present invention, a prepreg having a small variation in the amount of adhered resin can be obtained on the front and back surfaces of the fiber base material, so that a metal-clad laminate and a printed wiring board having excellent surface smoothness, thickness accuracy and warpage characteristics can be manufactured. can do.
【0032】[0032]
【実施例】次に、本発明の実施例を示す。 実施例1 臭素化ビスフェノールA型エポキシ樹脂(エポキシ当量
480,臭素含有量21.5重量%、軟化温度80℃)
100重量部、ジシアンジアミド2.6重量部及び2−
エチル−4−メチルイミダゾール0.2重量部をメチル
エチルケトンに溶解して固形分65重量%の熱硬化性樹
脂ワニスを作製した。また、図1に示すようなプリプレ
グ横型製造装置を用いた。上記の熱硬化性樹脂ワニスを
含浸槽に入れ、これに、厚み0.20mm、通気度5c
c/cm2/secであって幅1.2mの帯状のガラス
織布を通過させて、熱硬化性樹脂ワニスをガラス織布に
含浸させ、ついで、熱硬化性樹脂ワニスが含浸されたガ
ラス織布を乾燥炉に通して、樹脂分42重量%のプリプ
レグを製造した。Next, examples of the present invention will be described. Example 1 Brominated bisphenol A type epoxy resin (epoxy equivalent: 480, bromine content: 21.5% by weight, softening temperature: 80 ° C.)
100 parts by weight, 2.6 parts by weight of dicyandiamide and 2-
Ethyl-4-methylimidazole (0.2 part by weight) was dissolved in methyl ethyl ketone to prepare a thermosetting resin varnish having a solid content of 65% by weight. Further, a prepreg horizontal manufacturing apparatus as shown in FIG. 1 was used. The above-mentioned thermosetting resin varnish was put in an impregnation tank, and the thickness was 0.20 mm and the air permeability was 5 c.
The glass woven cloth impregnated with the thermosetting resin varnish is passed through a 1.2 m wide band-shaped glass woven cloth having a c / cm2 / sec and then the glass woven cloth impregnated with the thermosetting resin varnish. Was passed through a drying oven to produce a prepreg having a resin content of 42% by weight.
【0033】乾燥炉の仕様は次の通りである。 乾燥炉の長さ;35m 熱硬化性樹脂ワニスが含浸されたガラス織布の乾燥炉内
滞留時間:50秒 乾燥炉内の温度:熱硬化性樹脂ワニスが含浸されたガラ
ス織布が通過する隙間を開けて、乾燥炉を6個の部屋に
区切り、各部屋の温度を一定にした。各部屋の長さと、
温度は次のとおりである。 最初から第1番目の部屋:4.5m、70℃(入り口温
度) 最初から第2番目の部屋:4.5m、100℃ 最初から第3番目の部屋:4.5m、140℃ 最初から第4番目の部屋:4.5m、180℃ 最初から第5番目の部屋:6.0m、180℃ 最初から第6番目の部屋:6.0m、140℃ スライドロールの回転速度:25m/分 引き出しロールの回転速度:25m/分 熱硬化性樹脂ワニスが含浸されたガラス織布にかかる引
っ張り力:2.3N/cm(引き出しロール直前) なお、乾燥炉内では、繊維基材を支えるために、下から
エアーを吹き上げ、また、繊維基材が安定するように上
からもエアーを吹き付けるようにした。The specifications of the drying oven are as follows. Length of drying oven; 35 m Residence time of glass woven fabric impregnated with thermosetting resin varnish in drying oven: 50 seconds Temperature in drying oven: gap through which glass woven fabric impregnated with thermosetting resin varnish passes Was opened, the drying oven was divided into six rooms, and the temperature in each room was kept constant. The length of each room,
The temperatures are as follows: First room from the beginning: 4.5m, 70 ° C (entrance temperature) Second room from the beginning: 4.5m, 100 ° C Third room from the beginning: 4.5m, 140 ° C First from the fourth 5th room from the beginning: 4.5m, 180 ° C Fifth room from the beginning: 6.0m, 180 ° C 6th room from the beginning: 6.0m, 140 ° C Rotation speed of slide roll: 25m / min. Rotational speed: 25 m / min. Tensile force applied to the glass woven fabric impregnated with thermosetting resin varnish: 2.3 N / cm (immediately before the draw roll). Air was blown up, and air was blown from above so that the fiber base material was stabilized.
【0034】実施例2 ガラス織布として、厚み0.10mm、通気度15cc
/cm2/secのガラス織布を使用したこと以外は実
施例1に準じて行い、樹脂分46重量%のプリプレグを
製造した。Example 2 A glass woven fabric having a thickness of 0.10 mm and an air permeability of 15 cc
A prepreg having a resin content of 46% by weight was produced in the same manner as in Example 1 except that a glass woven fabric of / cm2 / sec was used.
【0035】比較例1 乾燥炉として縦型乾燥炉を用いたプリプレグ製造装置を
使用したこと及び0.10mm,通気度5cc/cm2
/secのガラス織布を使用したこと以外は実施例1に
準じて行い、樹脂分46重量%のプリプレグを製造し
た。このプリプレグ製造装置における縦型乾燥炉の大き
さは、高さ17mであり、この中をロールを介して繊維
基材が往復し、長さで34m分が乾燥炉内に存在するよ
うにした。これ以外は図1に示す装置と同様にした。た
だし、 スライドロールの回転速度:25m/分 引き出しロールの回転速度:0.7m/分 とした。繊維基材がはためかないで安定して送られるよ
うにするために、引き出しロールの回転速度をスライド
ロールの回転速度よりも大きくする必要がある。引き出
しロール直前での引っ張り力は,3.4N/cmであっ
た。Comparative Example 1 A prepreg manufacturing apparatus using a vertical drying furnace was used as a drying furnace, and 0.10 mm and a gas permeability of 5 cc / cm 2 were used.
/ Sec, except that a glass woven fabric was used, and a prepreg having a resin content of 46% by weight was produced. The size of the vertical drying furnace in this prepreg manufacturing apparatus was 17 m in height, and the fiber base material reciprocated through a roll in the vertical drying furnace, so that a length of 34 m was present in the drying furnace. Otherwise, the apparatus was the same as the apparatus shown in FIG. However, the rotation speed of the slide roll: 25 m / min The rotation speed of the drawer roll: 0.7 m / min. In order for the fiber base material to be sent stably without flapping, the rotation speed of the drawer roll needs to be higher than the rotation speed of the slide roll. The tensile force immediately before the pull-out roll was 3.4 N / cm.
【0036】比較例2 厚み0.10mm,通気度20cc/cm2/secの
ガラス織布を使用したこと以外は比較例1に準じて行
い、樹脂分46重量%のプリプレグを製造した。引き出
しロール直前での引っ張り力は,3.4N/cmであっ
た。Comparative Example 2 A prepreg having a resin content of 46% by weight was produced in the same manner as in Comparative Example 1 except that a glass woven fabric having a thickness of 0.10 mm and an air permeability of 20 cc / cm 2 / sec was used. The tensile force immediately before the pull-out roll was 3.4 N / cm.
【0037】比較例3 実施例1において、乾燥炉入口温度を150℃とし、し
かも、乾燥炉内温度を150〜185℃に保持したこと
以外は、実施例1に準じて行い、樹脂分42重量%のプ
リプレグを製造した。Comparative Example 3 The procedure of Example 1 was repeated, except that the drying furnace inlet temperature was 150 ° C. and the temperature inside the drying furnace was maintained at 150 to 185 ° C. % Prepreg was produced.
【0038】実施例1、実施例2および比較例1〜3の
プリプレグを所定の大きさに裁断し、この両側に18μ
mの銅箔を配置し,この材料をステンレス製の厚さ1.
8mmの鏡板にはさみ,これら構成品を13回重ねあわ
せ,プレス熱板間に挿入し,多段プレスにて温度185
℃,圧力4Mpaの条件下で85分間成形し,両面銅張
積層板を作製した。得られた両面銅張積層板に常法によ
り回路加工を施し,印刷配線板を作製した。両面銅張積
層板及び印刷配線板の性能を表1に示す。これらの性能
を表1に示す。The prepregs of Example 1, Example 2, and Comparative Examples 1 to 3 were cut to a predetermined size, and 18 μm was cut on both sides.
m of copper foil, and this material is made of stainless steel with a thickness of 1.
Insert these components into an 8 mm end plate, superimpose these components 13 times, insert between press hot plates, and apply a temperature of 185 with a multi-stage press.
Molding was performed for 85 minutes at a temperature of 4 ° C. and a pressure of 4 MPa to produce a double-sided copper-clad laminate. Circuit processing was performed on the obtained double-sided copper-clad laminate by a conventional method to produce a printed wiring board. Table 1 shows the performance of the double-sided copper-clad laminate and the printed wiring board. Table 1 shows these performances.
【0039】[0039]
【表1】 *1;両面銅張積層板の300mm角のサンプルないの
任意の50点での板厚を測定したときの偏差である。 *2;両面銅張積層板の300mm角のサンプルないの
任意の50点での板厚を測定したときの最大値と最小値
の差を示す。 *3;300mm角のサンプルの中央部に標点を記し,
印刷配線板への回路加工による端部のそり(最大)及び
寸法変化をみたものである。[Table 1] * 1: The deviation when measuring the thickness of the double-sided copper-clad laminate at any 50 points without a 300 mm square sample. * 2: The difference between the maximum value and the minimum value when the thickness of the double-sided copper-clad laminate was measured at any 50 points without a 300 mm square sample. * 3: Mark a mark at the center of a 300 mm square sample.
This figure shows the warpage (maximum) and dimensional change of the end due to circuit processing on the printed wiring board.
【0040】実施例1および2と比較例の銅張積層板の
性能は,表1から明らかなように本発明の銅張積層板の
性能は,本発明以外の銅張積層板よりそり,寸法変化が
小さく,且つ多層化接着時のそり,寸法変化も小さいこ
とを確認した。The performance of the copper-clad laminates of Examples 1 and 2 and the comparative example is clear from Table 1. The performance of the copper-clad laminate of the present invention is smaller than that of the copper-clad laminates other than the present invention. It was confirmed that the change was small, and that the warpage and dimensional change during the multi-layer bonding were small.
【0041】[0041]
【発明の効果】本発明より製造したプリプレグは、その
製造時に繊維基材に掛かる張力を低減できているので残
存歪みが生じにくい。これを用いて製造した金属張り積
層板及び印刷配線板は、表面平滑性,板厚精度が優れ、
そり,寸法変化が小さく、。The prepreg produced according to the present invention is less likely to cause residual strain because the tension applied to the fiber base material during the production can be reduced. The metal-clad laminates and printed wiring boards manufactured using them have excellent surface smoothness and plate thickness accuracy,
Small warpage and dimensional change.
【図1】 本発明におけるプリプレグを製造するために
使用されるプリプレグ横型製造装置の一例を示す概略
図。FIG. 1 is a schematic view showing an example of a prepreg horizontal manufacturing apparatus used for manufacturing a prepreg in the present invention.
1 横型塗工機、2 熱硬化性樹脂ワニス、3 含浸
槽、4 含浸ロール、5スクイズロール、6 横型乾燥
炉、7 引き出しロール、8 ガラス織布。1 horizontal coating machine, 2 thermosetting resin varnish, 3 impregnation tank, 4 impregnation roll, 5 squeeze roll, 6 horizontal drying furnace, 7 drawer roll, 8 glass woven fabric.
フロントページの続き (72)発明者 松崎 隆 茨城県下館市大字小川1500番地 日立化成 工業株式会社下館事業所内 Fターム(参考) 4F072 AA07 AB02 AB09 AB28 AB29 AD11 AD13 AD23 AD37 AD45 AG03 AG17 AG19 AH02 AH26 AH31 AH53 AJ04 AJ13 AK02 AL13 Continued on the front page (72) Inventor Takashi Matsuzaki 1500 Ogawa, Shimodate-shi, Ibaraki Pref.Hitachi Chemical Industry Co., Ltd. AJ04 AJ13 AK02 AL13
Claims (6)
る塗工工程と繊維基材に含浸された熱硬化性樹脂ワニス
の溶剤を揮発させ、樹脂を半硬化させる乾燥工程を含む
プリプレグの製造方法において、乾燥工程を乾燥炉入口
温度を樹脂の軟化点未満とする横型乾燥炉を用いて行う
ことを特徴とするプリプレグの製造方法。1. A prepreg comprising a coating step of impregnating a fibrous base material with a thermosetting resin varnish and a drying step of volatilizing a solvent of the thermosetting resin varnish impregnated on the fibrous base material and semi-curing the resin. A method for producing a prepreg, wherein the drying step is performed using a horizontal drying furnace in which the drying furnace inlet temperature is lower than the softening point of the resin.
る塗工工程と繊維基材に含浸された熱硬化性樹脂ワニス
の溶剤を揮発させ、樹脂を半硬化させる乾燥工程を含む
プリプレグの製造方法において、乾燥工程を上記の熱硬
化性樹脂ワニスによって含浸された繊維基材を水平方向
に移動させて行い、しかも、乾燥工程の最初は樹脂の軟
化点以下に加熱することを特徴とするプリプレグの製造
方法。2. A prepreg comprising a coating step of impregnating a thermosetting resin varnish on a fiber base material and a drying step of volatilizing a solvent of the thermosetting resin varnish impregnated on the fiber base material and semi-curing the resin. In the production method, the drying step is performed by moving the fiber base material impregnated with the thermosetting resin varnish in the horizontal direction, and further, the drying step is heated to a temperature equal to or lower than the softening point of the resin. Method for producing prepreg.
は2記載のプリプレグの製造方法。3. The method for producing a prepreg according to claim 1, wherein the fibrous base material is a strip.
より製造したプリプレグ。4. A prepreg produced by the method according to claim 1.
体の片面又は両面に金属箔を積層し、加熱加圧成形して
なる金属張り積層板。5. A metal-clad laminate obtained by laminating a metal foil on one side or both sides of the prepreg or the laminate thereof according to claim 4, and subjecting the laminate to heat and pressure molding.
工を施してなる印刷配線板。6. A printed wiring board obtained by subjecting the metal-clad laminate according to claim 5 to circuit processing.
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000081836A JP2001261862A (en) | 2000-03-17 | 2000-03-17 | Preparation process of prepreg, prepreg, metal-laminated laminate and printed circuit board |
| CNB018049893A CN100382949C (en) | 2000-03-03 | 2001-03-02 | Method for manufacturing prepreg substrate |
| DE60134123T DE60134123D1 (en) | 2000-03-03 | 2001-03-02 | PROCESS FOR PREPARING A PREPREGATION |
| US10/220,426 US6749899B2 (en) | 2000-03-03 | 2001-03-02 | Method for producing prepreg, prepreg, metal clad laminate and printed wiring board |
| TW090104834A TWI236969B (en) | 2000-03-03 | 2001-03-02 | Method for making a prepreg, prepreg, metal clapped laminate, and printed circuit board |
| KR1020027011505A KR100724670B1 (en) | 2000-03-03 | 2001-03-02 | Prepreg manufacturing method, prepreg, metal clad laminate and printed wiring board |
| AT01908259T ATE396025T1 (en) | 2000-03-03 | 2001-03-02 | METHOD FOR PRODUCING A PREPREG |
| ES01908259T ES2305058T3 (en) | 2000-03-03 | 2001-03-02 | PROCEDURE FOR REPAIR OF A PRE-PREPREGNATION. |
| EP01908259A EP1262297B1 (en) | 2000-03-03 | 2001-03-02 | Method of preparing a prepreg |
| PCT/JP2001/001632 WO2001064411A1 (en) | 2000-03-03 | 2001-03-02 | Method for producing prepreg, preprig, metal-clad laminate and printed wiring board |
| CNA2005100039892A CN1628946A (en) | 2000-03-03 | 2001-03-02 | Method for producing prepreg, prepreg, metal-clad laminate and printed wiring board |
| MYPI20010961A MY127196A (en) | 2000-03-03 | 2001-03-02 | Method for producing prepreg, prepreg, metal clad laminate and printed wiring board |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000081836A JP2001261862A (en) | 2000-03-17 | 2000-03-17 | Preparation process of prepreg, prepreg, metal-laminated laminate and printed circuit board |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010126134A Division JP2010248520A (en) | 2010-06-01 | 2010-06-01 | Method for producing prepreg, prepreg, metal-clad laminate, and printed wiring board |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2001261862A true JP2001261862A (en) | 2001-09-26 |
Family
ID=18598711
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000081836A Pending JP2001261862A (en) | 2000-03-03 | 2000-03-17 | Preparation process of prepreg, prepreg, metal-laminated laminate and printed circuit board |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2001261862A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015063040A (en) * | 2013-09-24 | 2015-04-09 | 住友ベークライト株式会社 | Metal-clad laminate, printed wiring board, and semiconductor device |
| JP2015080882A (en) * | 2013-10-22 | 2015-04-27 | 住友ベークライト株式会社 | Metal-clad laminated plate, printed wiring board and semiconductor device |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50139170A (en) * | 1974-04-25 | 1975-11-06 | ||
| JPH01294012A (en) * | 1988-05-23 | 1989-11-28 | Matsushita Electric Works Ltd | Impregnation of base material with varnish |
| JPH09225938A (en) * | 1996-02-23 | 1997-09-02 | Sumitomo Bakelite Co Ltd | Method and device for manufacturing prepreg |
-
2000
- 2000-03-17 JP JP2000081836A patent/JP2001261862A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50139170A (en) * | 1974-04-25 | 1975-11-06 | ||
| JPH01294012A (en) * | 1988-05-23 | 1989-11-28 | Matsushita Electric Works Ltd | Impregnation of base material with varnish |
| JPH09225938A (en) * | 1996-02-23 | 1997-09-02 | Sumitomo Bakelite Co Ltd | Method and device for manufacturing prepreg |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015063040A (en) * | 2013-09-24 | 2015-04-09 | 住友ベークライト株式会社 | Metal-clad laminate, printed wiring board, and semiconductor device |
| JP2015080882A (en) * | 2013-10-22 | 2015-04-27 | 住友ベークライト株式会社 | Metal-clad laminated plate, printed wiring board and semiconductor device |
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