JP2001181606A - Frictional material - Google Patents
Frictional materialInfo
- Publication number
- JP2001181606A JP2001181606A JP36660999A JP36660999A JP2001181606A JP 2001181606 A JP2001181606 A JP 2001181606A JP 36660999 A JP36660999 A JP 36660999A JP 36660999 A JP36660999 A JP 36660999A JP 2001181606 A JP2001181606 A JP 2001181606A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- friction
- fibers
- metal powder
- thermoplastic resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title abstract description 7
- 229910052751 metal Inorganic materials 0.000 claims abstract description 16
- 239000002184 metal Substances 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 14
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 11
- 239000002783 friction material Substances 0.000 claims description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 239000010949 copper Substances 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 239000000835 fiber Substances 0.000 description 14
- 239000000203 mixture Substances 0.000 description 11
- 239000003607 modifier Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229910001369 Brass Inorganic materials 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000010951 brass Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920002972 Acrylic fiber Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229920006231 aramid fiber Polymers 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000011490 mineral wool Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 244000226021 Anacardium occidentale Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229940007424 antimony trisulfide Drugs 0.000 description 1
- NVWBARWTDVQPJD-UHFFFAOYSA-N antimony(3+);trisulfide Chemical compound [S-2].[S-2].[S-2].[Sb+3].[Sb+3] NVWBARWTDVQPJD-UHFFFAOYSA-N 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 235000020226 cashew nut Nutrition 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical class C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
Landscapes
- Braking Arrangements (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、自動車、鉄道車
両、各種産業用機械等の制動に用いられるディスクブレ
ーキパッド、ブレーキライニング等の摩擦材に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to friction materials such as disc brake pads and brake linings used for braking automobiles, railway vehicles, various industrial machines and the like.
【0002】[0002]
【従来の技術】例えば自動車などの制動装置としてディ
スクブレーキが使用されており、その制動部材としてデ
ィスクブレーキパッドがある。現在ディスクブレーキパ
ッドの主流は、特公昭59−4462号公報、特開平6
−184525号公報等に示されるように補強繊維とし
て、スチール繊維、黄銅繊維、銅繊維等の金属繊維、ア
ラミド繊維、アクリル繊維、フェノール繊維等の有機質
繊維、アルミナシリカ繊維、ロックウール、チタン酸カ
リウム繊維、カーボン繊維等の無機質繊維を組み合わせ
たものが使用されている。2. Description of the Related Art Disc brakes are used as braking devices for automobiles, for example, and there are disc brake pads as braking members. At present, the mainstream of disc brake pads is disclosed in Japanese Patent Publication No. 59-4462,
As shown in JP-A-184525, steel fibers, brass fibers, metal fibers such as copper fibers, aramid fibers, organic fibers such as acrylic fibers and phenol fibers, alumina silica fibers, rock wool, potassium titanate are used as reinforcing fibers. A combination of fibers and inorganic fibers such as carbon fibers is used.
【0003】しかしながら上記に示すような従来のディ
スクブレーキパッドは、装着した直後にディスクロータ
とのなじみがないような状態のとき、ブレーキの効きが
低下し、しばしば問題となっていた。[0003] However, the conventional disk brake pads as described above, when in a state where they do not become familiar with the disk rotor immediately after being mounted, have reduced the effectiveness of the brake, and have often been a problem.
【0004】[0004]
【発明が解決しようとする課題】請求項1及び2記載の
発明は、装着した直後にディスクロータとのなじみがな
いような状態のときでもブレーキの効きの低下を大幅に
改善した摩擦材を提供するものである。SUMMARY OF THE INVENTION According to the first and second aspects of the present invention, there is provided a friction material in which a reduction in braking effect is significantly reduced even when the disk rotor is not familiar with the disk rotor immediately after mounting. Is what you do.
【0005】[0005]
【課題を解決するための手段】本発明は、摩擦部材の表
面に、軟質金属粉を1種類以上含有する熱可塑性樹脂を
被覆してなる摩擦材に関する。また、本発明は、軟質金
属粉が、アルミニウム、亜鉛、銅である前記の摩擦材に
関する。SUMMARY OF THE INVENTION The present invention relates to a friction material in which a surface of a friction member is coated with a thermoplastic resin containing at least one kind of soft metal powder. Further, the present invention relates to the friction material, wherein the soft metal powder is aluminum, zinc, or copper.
【0006】[0006]
【発明の実施の形態】本発明において、摩擦部材の表面
に被覆する熱可塑性樹脂としては、アクリル酸エステル
樹脂、アクリル共重合樹脂、酢酸ビニル樹脂、変性エチ
レン一酢酸ビニル樹脂等が挙げられ、また熱可塑性樹脂
に含有される軟質金属粉としては、アルミニウム、亜
鉛、銅等の1種類以上を用いることが好ましいが、軟質
の金属粉であれば特に制限はない。BEST MODE FOR CARRYING OUT THE INVENTION In the present invention, examples of the thermoplastic resin coated on the surface of the friction member include acrylate resin, acrylic copolymer resin, vinyl acetate resin, modified ethylene vinyl acetate resin, and the like. As the soft metal powder contained in the thermoplastic resin, it is preferable to use one or more of aluminum, zinc, copper and the like, but there is no particular limitation as long as it is a soft metal powder.
【0007】軟質金属粉の含有量は、熱可塑性樹脂の固
形分50〜99重量%に対して1〜50重量%とするこ
とが好ましく、熱可塑性樹脂の固形分70〜97重量%
に対して3〜30重量%とすることがさらに好ましい。
軟質金属粉を含有する熱可塑性樹脂の被覆厚さは、10
〜100μmの範囲が好ましく、20〜80μmの範囲
がより好ましく、30〜60μmの範囲がさらに好まし
い。The content of the soft metal powder is preferably 1 to 50% by weight based on 50 to 99% by weight of the solid content of the thermoplastic resin, and 70 to 97% by weight of the solid content of the thermoplastic resin.
More preferably, the content is 3 to 30% by weight.
The coating thickness of the thermoplastic resin containing the soft metal powder is 10
The range is preferably from 100 to 100 µm, more preferably from 20 to 80 µm, even more preferably from 30 to 60 µm.
【0008】本発明において摩擦材の材料は、一般に公
知の材料が用いられ、例えばスチール繊維、黄銅繊維、
アラミド繊維、アクリル繊維、フェノール繊維、セラミ
ック繊維、ロックウール、チタン酸カリウム繊維、カー
ボン繊維等の繊維状物質、フェノール繊維、エポキシ樹
脂、メラミン樹脂、カシュー樹脂等の熱硬化性樹脂やN
BR、SBR等のゴム組成物を含む結合剤、フリクショ
ンダストなどの有機質摩擦調整剤、硫酸バリウム、黒
鉛、三硫化アンチモン等の無機質摩擦調整剤などが用い
られ、さらに必要に応じて真鍮、銅等の金属粉が添加さ
れる。In the present invention, as a material of the friction material, a generally known material is used, for example, steel fiber, brass fiber,
Fibrous substances such as aramid fiber, acrylic fiber, phenol fiber, ceramic fiber, rock wool, potassium titanate fiber, carbon fiber, phenol fiber, thermosetting resin such as epoxy resin, melamine resin, cashew resin and N
Binders including rubber compositions such as BR and SBR, organic friction modifiers such as friction dust, inorganic friction modifiers such as barium sulfate, graphite, antimony trisulfide and the like are used, and if necessary, brass, copper, etc. Of metal powder is added.
【0009】上記における繊維状物質の含有量は摩擦部
材全組成物中に30〜50重量%含有することが好まし
く、35〜45重量%含有することがより好ましい。結
合剤の含有量は摩擦部材全組成物中に8〜18重量%含
有することが好ましく、10〜15重量%含有すること
がより好ましい。有機質摩擦調整剤の含有量は摩擦部材
全組成物中に3〜18重量%含有することが好ましく、
5〜15重量%含有することがより好ましい。また無機
質摩擦調整剤の含有量は摩擦部材全組成物中に25〜4
5重量%含有することが好ましく、30〜40重量%含
有することがより好ましい。これらの成分は、摩擦部材
全組成物が100重量%となるように配合される。なお
必要に応じて添加する金属粉の含有量は、全組成物中に
1〜20重量%とすることが好ましく、3〜15重量%
とすることがより好ましい。これらの成分は、全組成物
が100重量%となるように配合される。The content of the fibrous substance in the above composition is preferably 30 to 50% by weight, more preferably 35 to 45% by weight, in the whole composition of the friction member. The content of the binder is preferably from 8 to 18% by weight, more preferably from 10 to 15% by weight, in the whole composition of the friction member. The content of the organic friction modifier is preferably 3 to 18% by weight in the whole composition of the friction member,
More preferably, the content is 5 to 15% by weight. The content of the inorganic friction modifier is 25 to 4 in the total composition of the friction member.
The content is preferably 5% by weight, more preferably 30 to 40% by weight. These components are blended so that the total composition of the friction member is 100% by weight. The content of the metal powder added as necessary is preferably 1 to 20% by weight in the whole composition, and 3 to 15% by weight.
Is more preferable. These components are blended so that the total composition becomes 100% by weight.
【0010】本発明になる摩擦材は、繊維状物質、結合
剤及び他の摩擦調整剤を含む材料を加えて均一に混合
し、この混合物を予備成形し、次いで金型内に裏金及び
予備成形体(成形後摩擦部材となる)を挿設した後、加
熱加圧成形法で成形し、その後熱処理を行い、冷却後表
面を研磨し、さらに摩擦部材の表面に、軟質金属粉を1
種類以上含有する熱可塑性樹脂を被覆して得られる。な
お成形する際の加熱温度は130〜170℃が好まし
く、140〜160℃がより好ましい。圧力は30〜6
0MPaが好ましく、40〜50MPaがより好ましい。熱処
理温度は100〜300℃が好ましく、150〜250
℃がより好ましい。[0010] The friction material according to the present invention is prepared by adding a material containing a fibrous substance, a binder and other friction modifiers, uniformly mixing the mixture, preforming the mixture, and then forming a back metal and a preform in a mold. After the body (which becomes a friction member after molding) is inserted, it is molded by a heat and pressure molding method, then heat-treated, cooled, and polished.
It is obtained by coating a thermoplastic resin containing more than one kind. The heating temperature at the time of molding is preferably from 130 to 170 ° C, more preferably from 140 to 160 ° C. Pressure is 30-6
0 MPa is preferable, and 40 to 50 MPa is more preferable. The heat treatment temperature is preferably 100 to 300 ° C, and 150 to 250 ° C.
C is more preferred.
【0011】[0011]
【実施例】以下本発明の実施例を説明する。Embodiments of the present invention will be described below.
【0012】実施例1 表1及び表2に示す成分を配合し混合機で均一に混合し
た後、予備成形し、次いで金型内に裏金及び予備成形体
を挿設し、その後152.5±2.5℃、圧力49MPa
の条件で5分間加熱加圧成形し、さらに200℃で5時
間焼成し、冷却後表面を研磨し、次いで摩擦部材の表面
に濃度が40重量%のアクリル酸エステル樹脂水溶液を
95重量%及びアルミニウム粉5重量%を均一に混合し
た混合溶液を塗布し、これを乾燥して厚さが50μmの
軟質金属粉含有熱可塑性樹脂を被覆したディスクブレー
キパッドを得た。Example 1 The components shown in Tables 1 and 2 were blended, uniformly mixed by a mixer, preformed, and then a backing metal and a preformed body were inserted into a mold. 2.5 ° C, pressure 49MPa
Under heat and pressure for 5 minutes, baked at 200 ° C. for 5 hours, polished after cooling, and then 95% by weight of an aqueous acrylate resin solution having a concentration of 40% by weight and aluminum A mixed solution in which 5% by weight of the powder was uniformly mixed was applied and dried to obtain a disc brake pad having a thickness of 50 μm and covered with a thermoplastic resin containing a soft metal powder.
【0013】比較例1 摩擦部材の表面に軟質金属粉含有熱可塑性樹脂を被覆し
ない以外は、実施例1と同様の工程を経てディスクブレ
ーキパッドを得た。Comparative Example 1 A disc brake pad was obtained through the same steps as in Example 1 except that the surface of the friction member was not coated with a thermoplastic resin containing soft metal powder.
【0014】[0014]
【表1】 [Table 1]
【0015】[0015]
【表2】 [Table 2]
【0016】次に、本発明になる実施例1のディスクブ
レーキパッドと比較例1のディスクブレーキパッドにつ
いて、表3に示す条件で第一効力の比較試験を行った。
その結果を表4に示す。Next, a comparison test of the first efficacy was performed under the conditions shown in Table 3 for the disc brake pad of Example 1 and the disc brake pad of Comparative Example 1 according to the present invention.
Table 4 shows the results.
【0017】[0017]
【表3】 [Table 3]
【0018】[0018]
【表4】 [Table 4]
【0019】表4に示すように、本発明になる実施例1
のディスクブレーキパッドは、比較例1のディスクブレ
ーキパッドに比較して、装着した直後のブレーキの効き
が上昇していることが明らかである。As shown in Table 4, Example 1 according to the present invention was used.
It is clear that the brake effect of the disc brake pad immediately after mounting is higher than that of the disc brake pad of Comparative Example 1.
【0020】[0020]
【発明の効果】請求項1及び2記載の摩擦材は、装着し
た直後にディスクロータとのなじみがないような状態の
ときでもブレーキの効きの低下を大幅に改善することが
でき、工業的に極めて好適な摩擦材である。The friction material according to the first and second aspects can greatly reduce the reduction in the braking effect even when the friction material is not familiar with the disk rotor immediately after the friction material is mounted. It is a very suitable friction material.
Claims (2)
以上含有する熱可塑性樹脂を被覆してなる摩擦材。1. A friction material in which a surface of a friction member is coated with a thermoplastic resin containing at least one kind of soft metal powder.
である請求項1記載の摩擦材。2. The friction material according to claim 1, wherein the soft metal powder is aluminum, zinc, or copper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP36660999A JP2001181606A (en) | 1999-12-24 | 1999-12-24 | Frictional material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP36660999A JP2001181606A (en) | 1999-12-24 | 1999-12-24 | Frictional material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2001181606A true JP2001181606A (en) | 2001-07-03 |
Family
ID=18487211
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP36660999A Pending JP2001181606A (en) | 1999-12-24 | 1999-12-24 | Frictional material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2001181606A (en) |
-
1999
- 1999-12-24 JP JP36660999A patent/JP2001181606A/en active Pending
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