JP2001161309A - Method for imparting sweetness and sweetener - Google Patents
Method for imparting sweetness and sweetenerInfo
- Publication number
- JP2001161309A JP2001161309A JP35269999A JP35269999A JP2001161309A JP 2001161309 A JP2001161309 A JP 2001161309A JP 35269999 A JP35269999 A JP 35269999A JP 35269999 A JP35269999 A JP 35269999A JP 2001161309 A JP2001161309 A JP 2001161309A
- Authority
- JP
- Japan
- Prior art keywords
- sweetener
- sweetness
- sugar
- sucralose
- stevia
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003765 sweetening agent Substances 0.000 title claims abstract description 110
- 235000003599 food sweetener Nutrition 0.000 title claims abstract description 108
- 238000000034 method Methods 0.000 title claims abstract description 33
- 235000000346 sugar Nutrition 0.000 claims abstract description 56
- 235000019408 sucralose Nutrition 0.000 claims abstract description 55
- 239000004376 Sucralose Substances 0.000 claims abstract description 53
- BAQAVOSOZGMPRM-QBMZZYIRSA-N sucralose Chemical compound O[C@@H]1[C@@H](O)[C@@H](Cl)[C@@H](CO)O[C@@H]1O[C@@]1(CCl)[C@@H](O)[C@H](O)[C@@H](CCl)O1 BAQAVOSOZGMPRM-QBMZZYIRSA-N 0.000 claims abstract description 53
- -1 α-glucosyl stevia Chemical compound 0.000 claims description 27
- 150000005846 sugar alcohols Chemical class 0.000 claims description 18
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 claims description 15
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 claims description 15
- 239000000811 xylitol Substances 0.000 claims description 15
- 235000010447 xylitol Nutrition 0.000 claims description 15
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 claims description 15
- 229960002675 xylitol Drugs 0.000 claims description 15
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- 239000000832 lactitol Substances 0.000 claims description 6
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- VQHSOMBJVWLPSR-JVCRWLNRSA-N lactitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-JVCRWLNRSA-N 0.000 claims description 6
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- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 claims description 4
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- 239000000845 maltitol Substances 0.000 claims description 4
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- 239000000284 extract Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 235000013615 non-nutritive sweetener Nutrition 0.000 description 9
- 230000001954 sterilising effect Effects 0.000 description 8
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- 235000019202 steviosides Nutrition 0.000 description 6
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 5
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 5
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- 239000008103 glucose Substances 0.000 description 5
- 108010011485 Aspartame Proteins 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000000605 aspartame Substances 0.000 description 4
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- IAOZJIPTCAWIRG-QWRGUYRKSA-N aspartame Chemical compound OC(=O)C[C@H](N)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 IAOZJIPTCAWIRG-QWRGUYRKSA-N 0.000 description 4
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Landscapes
- Seasonings (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、α−グルコシルステビ
ア甘味料にスクラロースと、さらには糖アルコールを配
合した甘味料と、それらを用いることにより、α−グル
コシルステビア甘味料特有の異味や苦味を抑制しつつボ
ディ感を付与し、低カロリー・ノンカロリーでかつ砂糖
に近い良質な甘味を呈し、しかも熱安定性に優れる甘味
の付与を実現する方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a sweetener obtained by blending sucralose and a sugar alcohol with an .alpha.-glucosyl stevia sweetener, and by using these sweeteners, a flavor and bitterness peculiar to the .alpha.-glucosyl stevia sweetener. The present invention relates to a method for imparting a sweetness with low calorie, non-calorie, high-quality sweetness close to that of sugar, and with excellent heat stability, while suppressing body weight while suppressing.
【0002】[0002]
【従来の技術】砂糖、ブドウ糖、フラクトース、マルト
ース、キシロース等に代表される天然甘味料の中でも、
砂糖は最も需要が多く、甘味の質、物性、栄養の面で非
常に優れているが、最近、糖質の過剰摂取による肥満、
肥満に伴う成人病、う蝕の発生等、健康上の観点から、
消費者の健康食品志向が高まりつつある。このような背
景から、砂糖に代わる低カロリー甘味料が種々提案さ
れ、低カロリー甘味料代替による砂糖摂取の低減化が進
行している。2. Description of the Related Art Among natural sweeteners represented by sugar, glucose, fructose, maltose, xylose, etc.,
Sugar is the most demanded and has excellent sweetness, physical properties, and nutrition.
From the viewpoint of health, such as adult diseases associated with obesity and the occurrence of dental caries,
Consumers are increasingly interested in health foods. From such a background, various low-calorie sweeteners have been proposed in place of sugar, and reduction of sugar intake by substituting low-calorie sweeteners has been progressing.
【0003】また従来から、pH4.6以上の弱酸性か
らpH8付近の中性の領域に於いて流通、販売する飲料
を製造する場合には、85℃、30分間以上の加熱殺
菌、120℃、4分間以上の加熱殺菌またはこれらと同
等以上の加熱処理することが必要であり、現実には、レ
トルト殺菌の場合、例えば、120℃、20分間の殺菌
が行われている。上記に例示されるような高温処理を経
た飲食物においては、砂糖、ブドウ糖、果糖等の糖類が
含まれていると色調や品質の変化が起こり、問題となる
ことがある。この問題に対処する手段としても、砂糖等
の糖類に代わる甘味料適用が進んでいる。[0003] Conventionally, when producing beverages to be distributed and sold in a weakly acidic region of pH 4.6 or more to a neutral region near pH 8, heat sterilization at 85 ° C for 30 minutes or more, 120 ° C, It is necessary to perform heat sterilization for 4 minutes or more or heat treatment equivalent to or more than these. In reality, in the case of retort sterilization, for example, sterilization is performed at 120 ° C. for 20 minutes. In foods and drinks that have been subjected to high-temperature treatment as exemplified above, if sugars such as sugar, glucose, and fructose are contained, the color tone and quality may change, which may be a problem. As a means to cope with this problem, sweeteners have been increasingly used in place of sugars such as sugar.
【0004】低カロリー甘味料の中でも、エリスリトー
ルやマルチトール、キシリトールに代表される糖アルコ
ール、およびオリゴ糖などの低甘味度甘味料は、先味が
強くボディ感がある甘味質である。しかし単独では特有
の異味が強く、また十分な甘味を得るために使用量を増
す必要があり、従ってコスト高や大量摂取による緩下作
用が懸念される。[0004] Among the low-calorie sweeteners, low-sweetness sweeteners such as sugar alcohols represented by erythritol, maltitol, and xylitol, and oligosaccharides are sweet substances having a strong initial taste and a body feeling. However, when used alone, it has a strong peculiar off-taste, and it is necessary to increase the amount of use in order to obtain a sufficient sweetness.
【0005】例えばキシリトールは、多くの野菜、果実
もしくは生体内に含まれる糖アルコールで、工業的には
木や樫木のキシラン、ヘミセルロースを原料として得ら
れるキシロースに水素添加して製造される。キシリトー
ルの甘味質は清涼感があり、糖アルコールの中でも甘味
にクセが少なく、低カロリー、抗う蝕作用があることか
ら広く食品に使用できるものである。一方で、キシリト
ールの甘味質は砂糖との比較においては厚みがやや少な
くあっさりしていて砂糖との違いは明らかであり、単独
での砂糖代替は困難である。For example, xylitol is a sugar alcohol contained in many vegetables, fruits or living organisms, and is industrially produced by hydrogenating xylose obtained from xylan or hemicellulose of wood or oak. The sweetness of xylitol has a refreshing sensation, has a low sweetness among sugar alcohols, has a low calorie, and has an anti-cariogenic effect, so that it can be widely used in foods. On the other hand, the sweetness of xylitol is slightly thinner and simpler than that of sugar, and the difference from sugar is clear. Therefore, it is difficult to substitute sugar alone.
【0006】その他の低カロリー甘味料、例えばステビ
ア甘味料、L-アスパルテル-L-フェニルアラニンメチル
エステル(アスパルテーム)、サッカリン、グリチルリ
チン、スクラロース、アセスルファムK等の高甘味度甘
味料は、少量でも十分な甘味を有しているが、特有の異
味や後味があり、また先味と厚みが不足するといった欠
点から嗜好性は高くない。[0006] Other low-calorie sweeteners, for example, stevia sweetener, L-aspartel-L-phenylalanine methyl ester (aspartame), saccharin, glycyrrhizin, sucralose, acesulfame K, and other high-intensity sweeteners, are sufficient even in small amounts. However, it has a peculiar off-taste and aftertaste, and its palatability is not high due to its shortcomings such as lack of first taste and thickness.
【0007】例えばアスパルテームは、上記に示すよう
な味質的欠点に加えて熱に対して非常に不安定で、高温
処理により甘味を消失するため、高温加熱殺菌処理を伴
う飲料に使用しても商品化ができない。[0007] For example, aspartame is extremely unstable to heat in addition to the above-mentioned taste defects and loses its sweetness by high-temperature treatment. Cannot be commercialized.
【0008】スクラロースは、4,1’,6’−トリク
ロロ−4,1’,6’−トリデオキシガラクトスクロー
スまたは1’,6’−ジクロロ−1’,6’−ジデオキ
シ−β−D−フラクトフラノシル−4−クロロ−4−デ
オキシ−α−D−ガラクトピラノシドとして知られてお
り、砂糖の約600倍の甘味度を有する非代謝性のノン
カロリー甘味料である。砂糖に類似した甘味を呈し、溶
解性、熱安定性、非発酵性等の食品加工適性にも優れて
いる。しかし砂糖と比較すると先味とボディ感が不足し
甘味質もさっぱりとし過ぎており、単独では砂糖代替甘
味料として適用し難い。[0008] Sucralose is 4,1 ', 6'-trichloro-4,1', 6'-trideoxygalactosucrose or 1 ', 6'-dichloro-1', 6'-dideoxy-β-D-fructo. Known as furanosyl-4-chloro-4-deoxy-α-D-galactopyranoside, it is a non-metabolic non-caloric sweetener having a sweetness about 600 times that of sugar. It has a sweetness similar to sugar and is excellent in food processing suitability such as solubility, heat stability, and non-fermentability. However, when compared to sugar, the taste and body feel are lacking, and the sweetness is too light, making it difficult to apply as a sugar substitute sweetener by itself.
【0009】ステビア甘味料は、キク科の植物ステビア
レバウディアナベルトニー(Steviarebaudiana BERTON
I)(以後ステビアと略称する)の葉部から抽出精製した
高甘味物質の混合品であり、高甘味を有する天然系の甘
味料として知られている。ステビア高甘味成分は、主成
分であるステビオサイドをはじめ、レバウディオサイド
A、レバウディオサイドC、レバウディオサイドD、レ
バウディオサイドE、ズルコサイドAの6種が知られて
いる。[0009] Stevia sweetener is a plant of the Asteraceae family Steviarebaudiana BERTON (Steviarebaudiana BERTON)
I) A mixture of highly sweet substances extracted and purified from the leaves of stevia (hereinafter abbreviated as stevia), and is known as a natural sweetener having a high sweetness. Six types of stevia high-sweetness components are known, including stevioside as a main component, rebaudioside A, rebaudioside C, rebaudioside D, rebaudioside E, and zurcoside A.
【0010】ステビア抽出品には主成分であるステビオ
サイドの比率の高い通常抽出品、あるいはレバウディオ
サイドAの含有量を多くし味質を改善をした調整品が知
られている。通常抽出品は、蔗糖に対して200〜30
0倍の甘味度があり、使用量も微量で済む点から実質的
にノンカロリーである。また、溶解性、熱安定性、非発
酵性等の食品加工適性にも優れている。As the stevia extract, there is known an ordinary extract having a high ratio of stevioside as a main component, or an adjusted product in which the content of rebaudioside A is increased to improve the taste. Usually, the extract is 200-30 sucrose
It is substantially non-caloric in that it has 0 times the sweetness and uses only a small amount. It is also excellent in food processing suitability such as solubility, heat stability, and non-fermentability.
【0011】また、通常抽出品にα−グルコシル転移酵
素の作用でグルコースを付加する方法(特公昭57−1
8779)によって製造されたα-グルコシルステビア
甘味料、あるいはこれにα−1,4グルコシダーゼを作
用させて糖鎖を短くする方法(特公平5−22498)
によって製造されたα−グルコシルステビア甘味料は、
食品加工適性はそのままで一層味質が改善されている。Also, a method of adding glucose to an extract by the action of α-glucosyltransferase (Japanese Patent Publication No. 57-1)
8779) or a method of shortening the sugar chain by acting α-1,4 glucosidase on the sweetener (Japanese Patent Publication No. 5-22498).
Α-glucosylstevia sweetener manufactured by
Taste quality is further improved while maintaining food processing suitability.
【0012】これらのα−グルコシルステビア甘味料、
その中でも糖鎖を調節されたものについては、通常抽出
品と比較し苦味・渋味・甘味の後引きについては著しく
改良されたものであり、甘味質もよりコクのある、高級
感を保持しているものである。These α-glucosyl stevia sweeteners,
Among them, those with controlled sugar chains are significantly improved in terms of bitterness, astringency, and sweetness after extraction compared to ordinary extracts, and the sweetness is more rich and retains a luxurious feeling. Is what it is.
【0013】以上に示したステビオサイド高含有通常抽
出品、レバウディオサイドA高含有調整品、α−グルコ
シルステビア甘味料はいずれもステビア甘味料として分
類される。The stevioside-rich ordinary extract, the rebaudioside A-rich adjusted product, and the α-glucosylstevia sweetener described above are all classified as stevia sweeteners.
【0014】ステビア甘味料は一般的に、砂糖代替甘味
料として単独で用いられた場合、わずかに感じられる独
特の異味や後味ゆえに嗜好性がやや低く、また甘味の厚
みが不足する、甘味度が高いため甘味の調整が難しいな
どの欠点があることが指摘されており、それに関しては
幾つか改良法が提案されている。例えば、ヘスペリジン
およびその誘導体(特開平8−256725号公報)、
ルチン及び/またはルチン誘導体(特開平10−146
165号公報)、ミョウバンやナリンジン(特開昭52
−90667号公報)、グルタミン酸ナトリウム(特開
昭56−148256号公報)、グリシン、アラニンあ
るいはセリン(特開昭57−63068号公報)、アス
コルビン酸(特開昭58−141760号公報、特開昭
60−114167号公報)、有機酸(特公平5−98
1号公報)、フラボン誘導体(特開平6−335362
号公報)、塩化ナトリウム(特公平6−48966号公
報)を共存せしめ、呈味改良を試みたとの報告が成され
ている。[0014] Stevia sweeteners, when used alone as a sugar substitute sweetener, generally have a slightly lower palatability due to a peculiar off-taste or aftertaste that is perceived slightly, lack a sweetness thickness, and have a low sweetness. It has been pointed out that it is difficult to adjust the sweetness due to its high cost, and several improvements have been proposed for this. For example, hesperidin and its derivatives (JP-A-8-256725),
Rutin and / or rutin derivatives (JP-A-10-146)
165), alum and naringin (Japanese Unexamined Patent Publication No.
-90667), sodium glutamate (JP-A-56-148256), glycine, alanine or serine (JP-A-57-63068), ascorbic acid (JP-A-58-141760, JP-A-58-141760). 60-114167), organic acids (Japanese Patent Publication No. 5-98)
No. 1), flavone derivatives (JP-A-6-335362)
Japanese Patent Application Publication No. 6-48966) and sodium chloride (Japanese Patent Publication No. 6-48966) have been reported to attempt to improve taste.
【0015】しかし、これらの呈味改良素材は、好まし
くない持続的甘味の味質改善効果を有していても、特に
高甘味度甘味料に特有の異味や苦味、厚みのなさ等の改
良に関しては不十分であり、またそれ自体の有する味や
物性で用途が限定されていたり、あるいは比較的高価な
ために、味質改良効果を有していても安定的かつ経済的
に使用できないと行った問題を抱えていた。また、塩化
ナトリウムのように、甘味の厚みを改良するが同時に後
甘味も強調されるという問題もあった。[0015] However, even though these taste-improving materials have an unfavorable effect of improving the taste of a long-lasting sweetness, they are not particularly effective in improving the off-taste, bitterness, and lack of thickness unique to high-intensity sweeteners. Is insufficient and its use is limited due to its own taste and physical properties, or it is relatively expensive, so even if it has a taste-improving effect, it cannot be used stably and economically. Had a problem. Further, there is a problem that the sweetness is improved like sodium chloride, but the post-sweetness is also emphasized at the same time.
【0016】また、他の甘味料と組み合わせることで味
質が改善された甘味を得る方法としては、例えばエリス
リトールを添加する方法(特開昭63−258557号
公報)、ソーマチンを添加する方法(特開昭53−10
4771号公報)、D−キシロースを添加する方法(特
公昭61−12663号公報)、ニゲロオリゴ糖を添加
する方法(特開平10−234331号公報)等が報告
されている。しかし、これらの甘味料は高甘味度甘味料
特有の異味や苦味等の改善効果を有する一方で甘味の質
が砂糖と異なり、また配合割合によってはカロリー増と
なるので、低カロリー、ダイエット甘味料を得るという
本来の目的に反する。さらには大量に摂取すると緩下作
用を引き起こしやすいなどの問題も有している。As a method of obtaining sweetness having improved taste by combining with other sweeteners, for example, a method of adding erythritol (Japanese Patent Application Laid-Open No. 63-258557), a method of adding thaumatin (see 53-10 Kaisho
No. 4771), a method of adding D-xylose (Japanese Patent Publication No. 61-12663), a method of adding a nigerooligosaccharide (Japanese Patent Application Laid-Open No. Hei 10-234331), and the like. However, these sweeteners have the effect of improving the off-taste and bitterness of high-sweetness sweeteners, but the quality of sweetness is different from sugar, and the amount of calories increases depending on the blending ratio. Contradicts the original purpose of obtaining Furthermore, there is also a problem that a large amount of the substance is likely to cause a laxative effect.
【0017】なお、スクラロースを他の高甘味度甘味料
と共存させたときの特性については、例えばサッカリン
やステビオサイド等の苦味を有する甘味料と併用するこ
とによる甘味の相乗効果が報告されている(特公昭63
−61909号公報)。しかし、ステビオサイドはそれ
自体の異味や苦味、甘味の後引きが顕著である点で劣る
ものであり、同様にステビオサイドとスクラロースを配
合してなる甘味組成物においても、異味や苦味の効果的
な抑制という観点では問題があった。As for the characteristics of sucralose when coexisting with other high-intensity sweeteners, a synergistic effect of sweetness when used in combination with a bitter sweetener such as saccharin and stevioside has been reported ( Tokiko Sho 63
-61909). However, stevioside is inferior in that its own off-taste, bitterness, and sweetness are remarkably reduced. Similarly, even in a sweet composition comprising stevioside and sucralose, effective control of off-taste and bitterness is effective. There was a problem from the viewpoint.
【0018】以上に述べたように、飲食物に対して、低
カロリー・ノンカロリーで、糖に近い味質を呈する、し
かも加熱殺菌後も劣化することのない甘味を付与する方
法はこれまでに見いだされていなかった。As described above, a method for imparting a sweetness to foods that is low in calories and non-calories, has a taste similar to that of sugar, and does not deteriorate even after heat sterilization has been used. Had not been found.
【0019】[0019]
【発明が解決しようとする課題】本発明が解決しようと
する課題は、α−グルコシルステビア甘味料とスクラロ
ース両者の欠点である先味、複雑味、ボディ感の不足を
補填し、またα−グルコシルステビア甘味料がわずかに
有する独特の異味や後味を抑制し、飲食物に対して、加
熱殺菌後も劣化することのない砂糖に類似した良質な甘
味料及び甘味付与する方法を提供することである。The problem to be solved by the present invention is to overcome the disadvantages of both α-glucosyl stevia sweetener and sucralose, which are lacking in taste, complex taste and body feeling, and to provide α-glucosyl stevia. An object of the present invention is to provide a high-quality sweetener similar to sugar that does not deteriorate even after heat sterilization, and a method of imparting sweetness to foods and beverages by suppressing the peculiar off-taste and aftertaste of stevia sweetener. .
【0020】[0020]
【課題を解決するための手段】発明者らは、鋭意検討の
結果、α−グルコシルステビア甘味料とスクラロース、
さらに糖アルコールを組み合わせることにより、各々の
甘味料が呈する異味や後味を抑制し、先味、複雑味とボ
ディ感を付与して呈味をより砂糖に近づけ、飲食物に良
質な甘味を付与できることを見いだし、本発明の完成に
至った。本発明により甘味を付与された飲食物は、加熱
殺菌後あるいは長期保存中の甘味度低下を起こすことな
く、安定性に優れるものである。Means for Solving the Problems As a result of intensive studies, the inventors have found that α-glucosylstevia sweetener and sucralose,
In addition, by combining sugar alcohols, it is possible to suppress the off-taste and after-taste of each sweetener, to give a forerunner, complex taste and body feeling, to make the taste more similar to sugar, and to give good sweetness to food and drink. And completed the present invention. The food or drink imparted with sweetness according to the present invention is excellent in stability without causing a reduction in sweetness after heat sterilization or during long-term storage.
【0021】[0021]
【発明の実施の形態】本発明で使用されるα−グルコシ
ルステビア甘味料は、公知の方法(例えば特公昭57−
18779)を用いて、ステビア抽出品にα−グルコシ
ル転移酵素の作用でグルコースを付加することにより製
造されたステビア糖転移品(例えば日本製紙(株)製ス
テビア甘味料、商品名SKスイート)、および/または
公知の方法(例えば特公平5−22498)を用いて、
ステビア糖転移品にα−1,4グルコシダーゼを作用さ
せてα−グルコシル平均付加数を1.0〜2.5に調整
したステビア糖鎖調節品(例えば日本製紙(株)製のス
テビア甘味料、商品名SKスイートFZ)であり、抽出
品と比較して苦味や後引きが大幅に改善された甘味料で
ある。BEST MODE FOR CARRYING OUT THE INVENTION The α-glucosylstevia sweetener used in the present invention can be prepared by a known method (for example,
18779), by adding glucose to the stevia extract by the action of α-glucosyltransferase (for example, Stevia sweetener manufactured by Nippon Paper Co., Ltd., trade name: SK Suite), and / Or using a known method (for example, Japanese Patent Publication 5-22498)
A stevia sugar chain-regulated product (eg, Stevia sweetener manufactured by Nippon Paper Industries Co., Ltd.) in which α-1,4 glucosidase is allowed to act on a stevia sugar-transferred product to adjust the α-glucosyl average addition number to 1.0 to 2.5. SK Sweet FZ), which is a sweetener with significantly improved bitterness and retraction compared to the extract.
【0022】α−グルコシルステビア甘味料には、α−
グルコシル基が1から15〜20個程度付加した甘味成
分が存在し、α−グルコシル平均付加数は特公平5−2
2498号公報や月刊フードケミカル1995年1月
p.36に開示されているように次式で求められる。[0022] α-Glucosylstevia sweetener includes α-
There is a sweet component to which about 1 to 15 glucosyl groups have been added, and the average addition number of α-glucosyl is 5-2.
No. 2498 and monthly food chemicals, January 1995, p. 36, it is determined by the following equation.
【数1】 (Equation 1)
【0023】本発明で使用されるスクラロースは、4,
1’,6’−トリクロロ−4,1’,6’−トリデオキ
シガラクトスクロースまたは1’,6’−ジクロロ−
1’,6’−ジデオキシ−β−D−フラクトフラノシル
−4−クロロ−4−デオキシ−α−D−ガラクトピラノ
シドとして知られており、砂糖に類似した甘味を呈し、
砂糖の約600倍の甘味度を有する非代謝性のノンカロ
リー甘味料である。The sucralose used in the present invention is 4,
1 ', 6'-trichloro-4,1', 6'-trideoxygalactosucrose or 1 ', 6'-dichloro-
Known as 1 ′, 6′-dideoxy-β-D-fructofuranosyl-4-chloro-4-deoxy-α-D-galactopyranoside, it has a sweetness similar to sugar,
It is a non-metabolic non-caloric sweetener having a sweetness about 600 times that of sugar.
【0024】α−グルコシルステビア甘味料とスクラロ
ースはいずれも加熱殺菌による甘味の低下を起こさない
ため、食品加工適性に優れている。だが、それらの味質
に共通する特徴として先味がやや弱くボディ感が不足し
後味が感じられるといった点が指摘されている。Both α-glucosyl stevia sweetener and sucralose do not cause a reduction in sweetness due to heat sterilization, and thus are excellent in food processing suitability. However, it has been pointed out that a common feature of these taste qualities is that the forerunner is somewhat weak, the body feeling is insufficient, and the aftertaste is felt.
【0025】本発明によれば、α−グルコシルステビア
甘味料のうちステビア糖転移品とスクラロースを砂糖換
算重量で10:90〜70:30、好ましくは20:8
0〜60:40の比率で飲食物に添加すると、特有の異
味や後味が感じられない良質な甘味が実現するとともに
甘味の増強効果が認められ、安定性が高く加熱処理によ
り分解されないため優れた加工適性を示す。ただし、α
−グルコシルステビア甘味料の比率(α−グルコシルス
テビア甘味料とスクラロース両者により付与される甘味
においてα−グルコシルステビア甘味料が占める比率)
が提示した範囲未満(10%未満)では厚み付与の効果
が感じられず、範囲を超えると(70%超)α−グルコ
シルステビア甘味料特有の異味や後味が強まってくるた
め好ましくない。According to the present invention, of the α-glucosyl stevia sweetener, a stevia sugar-transferred product and sucralose are 10:90 to 70:30, preferably 20: 8 in terms of sugar weight.
When added to foods and drinks at a ratio of 0 to 60:40, high-quality sweetness with no peculiar off-taste or aftertaste is realized, and the effect of enhancing sweetness is recognized. Shows workability. Where α
-Ratio of glucosyl stevia sweetener (ratio of α-glucosyl stevia sweetener in sweetness imparted by both α-glucosyl stevia sweetener and sucralose)
If it is less than the range (less than 10%), the effect of imparting thickness is not felt, and if it exceeds the range (more than 70%), the unpleasant taste and aftertaste specific to α-glucosyl stevia sweetener increases, which is not preferable.
【0026】また、本発明によれば、α−グルコシルス
テビア甘味料の中でもα−グルコシル平均付加数が1.
0〜2.5に調整されたステビア糖鎖調節品を砂糖換算
重量で10:90〜80:20、特に好ましくは30:
70〜70:30の比率で飲食物に添加すると、ステビ
ア糖転移品以上に優れた効果を示す。すなわち、ステビ
ア糖鎖調節品は、それ自体ステビア糖転移品と比較して
異味や後味の少ない、一層好ましい甘味を呈するもので
あるので、本発明を実施することにより、あらゆる飲食
物、とりわけ飲料やデザートなどの甘味主体の飲食物に
対してステビア特有の苦味や後引きが全く感じられない
良質な甘味を付与することが出来る。ただし、α−グル
コシルステビア甘味料の比率(α−グルコシルステビア
甘味料とスクラロース両者により付与される甘味におい
てα−グルコシルステビア甘味料が占める比率)が提示
した範囲未満(10%未満)では厚み付与の効果が感じ
られず、範囲を超えると(80%超)α−グルコシルス
テビア甘味料特有の異味や後味が強まってくるため好ま
しくない。According to the present invention, among the α-glucosylstevia sweeteners, the average α-glucosyl addition number is 1.
The stevia sugar chain-regulated product adjusted to 0 to 2.5 is 10:90 to 80:20 by weight in terms of sugar, particularly preferably 30:80.
When added to food or drink at a ratio of 70 to 70:30, the effect is superior to that of steviaglycosylated product. That is, the stevia sugar chain-regulated product itself has less off-taste and aftertaste compared to the stevia-glycotransferred product, and exhibits a more preferable sweetness.Therefore, by carrying out the present invention, all foods and drinks, especially beverages and It is possible to impart a high-quality sweetness to a food or beverage mainly containing sweetness, such as dessert, in which the bitterness peculiar to Stevia and the delay are not felt at all. However, if the ratio of the α-glucosyl stevia sweetener (the ratio of the α-glucosyl stevia sweetener to the sweetness provided by both the α-glucosyl stevia sweetener and the sucralose) is less than the suggested range (less than 10%), the thickness is not increased. If the effect is not felt and exceeds the range (more than 80%), the unpleasant taste and aftertaste peculiar to α-glucosylstevia sweetener are undesirably increased.
【0027】また、本発明においては、上記α−グルコ
シルステビア甘味料とスクラロースにさらに糖アルコー
ルを配合することによって、さらに先味とボディ感の点
を改善することができる。In the present invention, further addition of a sugar alcohol to the α-glucosyl stevia sweetener and sucralose can further improve the taste and body feeling.
【0028】本発明で使用される糖アルコールとしては
キシリトール、エリスリトール、マルチトール、ソルビ
トール、マンニトール、パラチニット、ラクチトール及
びこれらの混合物のうち1種または2種以上選択されう
るが、特にキシリトールがα−グルコシルステビア甘味
料とスクラロースとの共存において味質面で相性が良い
という点で優れている。The sugar alcohol used in the present invention may be selected from one or more of xylitol, erythritol, maltitol, sorbitol, mannitol, palatinit, lactitol and mixtures thereof, and particularly, xylitol is α-glucosyl. It is excellent in that coexistence of stevia sweetener and sucralose is compatible with taste.
【0029】α−グルコシルステビア甘味料とスクラロ
ースを合わせたものと糖アルコールとの混合比率は、砂
糖換算重量で20:80〜80:20、好ましくは3
0:70〜70:30が有利である。糖アルコールの比
率が提示した範囲未満(20%未満)ではボディ感付与
効果が少なく、範囲を超えると(80%超)糖アルコー
ル特有の異味が強まり、かつα−グルコシルステビア甘
味料とスクラロースによるカロリー低減効果が期待でき
なくなるため好ましくない。The mixing ratio of α-glucosyl stevia sweetener and sucralose to sugar alcohol is 20:80 to 80:20, preferably 3 in terms of sugar.
0:70 to 70:30 is advantageous. When the ratio of the sugar alcohol is less than the indicated range (less than 20%), the body-feeling effect is small, and when the ratio exceeds the range (more than 80%), the unpleasant taste peculiar to the sugar alcohol is enhanced, and the calories from α-glucosylstevia sweetener and sucralose It is not preferable because a reduction effect cannot be expected.
【0030】本発明の目的達成のためには、α−グルコ
シルステビア甘味料とスクラロースと糖アルコールを上
記の比率で混合する必要があるが、目的達成を阻害しな
い限り、他の糖質が共存していてもよい。他の糖質とし
ては例えば、グルコース、フラクトース、ガラクトース
などの単糖類、マルトール、イソマルトース、ラクトー
ス、パラチノースなどの二糖類、マルトトリオース、エ
ルロース、ラフィノース、ラクトスクロース、ケストー
ス等の三糖類、ソルビトール、マルチトール、ラクチト
ール、マルトトリイトール等の糖アルコールなどが適宜
選択される。これらの使用量の目安としては、砂糖換算
で甘味全体の0〜80%(重量)が適当である。この範
囲を超えると、本発明の目的である、カロリーの低減さ
れた、砂糖に近い甘味を付与する効果が感じられにくく
なるので好ましくない。In order to achieve the object of the present invention, it is necessary to mix the α-glucosyl stevia sweetener, sucralose and sugar alcohol in the above-mentioned ratio. May be. As other saccharides, for example, glucose, fructose, monosaccharides such as galactose, maltol, isomaltose, lactose, disaccharides such as palatinose, maltotriose, erulose, raffinose, lactose sucrose, trisaccharides such as kestose, sorbitol, Sugar alcohols such as maltitol, lactitol, and maltotriitol are appropriately selected. As a standard of these usage amounts, 0 to 80% (weight) of the whole sweetness in terms of sugar is appropriate. Exceeding this range is not preferred because the effect of imparting sweetness close to sugar, which is the object of the present invention, in which calories are reduced, becomes difficult to be felt.
【0031】本発明で提示される方法にて甘味を付与す
ることができる飲食物は、例えば、粉末、顆粒、キュー
ブ、ペースト、液体など種々の形態をもつ甘味料製剤、
果汁入り飲料、野菜飲料、栄養飲料などの酸性飲料、サ
イダー類、コーラ類、ガラナ、ジンジャーエールなどの
炭酸飲料、コーヒー、紅茶、乳飲料、甘酒などの各種飲
料、ゼリー、ムース、アイスクリーム、シャーベット、
プリン、ヨーグルト等のデザート類、チョコレート、ク
ッキー、ケーキ、チューインガム等の菓子類、ハードキ
ャンディ、ソフトキャンディなどのキャンディ類、水産
練り製品、漬物、ドレッシング、醤油、たれなどの塩性
食品および調味料等が挙げられ、いずれの飲食物に対し
ても効果を発揮する。[0031] Foods and drinks to which sweetness can be imparted by the method presented in the present invention include, for example, sweetener preparations having various forms such as powders, granules, cubes, pastes, and liquids;
Acidic drinks such as fruit juice drinks, vegetable drinks and nutritional drinks, carbonated drinks such as ciders, colas, guarana and ginger ale, various drinks such as coffee, tea, milk drinks and amazake, jelly, mousse, ice cream, sherbet ,
Desserts such as pudding and yogurt, confectionery such as chocolate, cookies, cakes and chewing gum, candy such as hard candy and soft candy, seafood paste, salted foods such as pickles, dressings, soy sauce, sauces and seasonings, etc. It is effective for any food or drink.
【0032】[0032]
【実施例】以下、実施例により本発明をさらに具体的に
説明するが、これらは本発明を限定するものではない。
なお、各種甘味料の甘味度およびカロリー値は表1の通
りである。The present invention will be described in more detail with reference to the following examples, which do not limit the present invention.
In addition, the sweetness degree and caloric value of various sweeteners are as shown in Table 1.
【0033】[0033]
【表1】 [Table 1]
【0034】実施例1、2 ステビア甘味料とスクラロース混合水溶液の味質評価を
行った。表2−1、2−2に示す処方に従って、甘味の
合計が砂糖換算5%に相当するように調製し飲料水に溶
解させた。熟練したパネラー15名を用いての官能評価
を下記の基準に従って行い、各パネラーの評価結果の平
均値を算出し表に示した。 評価基準 1:劣る、2:やや劣る、3:普通、4:やや優れる、
5:優れるExamples 1 and 2 The taste of a mixed aqueous solution of stevia sweetener and sucralose was evaluated. According to the prescriptions shown in Tables 2-1 and 2-2, the total sweetness was adjusted to be 5% in terms of sugar and dissolved in drinking water. Sensory evaluation using 15 skilled panelists was performed according to the following criteria, and the average of the evaluation results of each panelist was calculated and shown in the table. Evaluation criteria 1: Inferior 2: Slightly inferior 3: Normal, 4: Slightly superior,
5: Excellent
【0035】[0035]
【表2】 [Table 2]
【0036】[0036]
【表3】 [Table 3]
【0037】[0037]
【表4】 [Table 4]
【0038】実施例3 ステビア甘味料、スクラロース、糖アルコール混合水溶
液における、糖アルコールの種類別味質評価を行った。
表3−1および3−2に示す処方に従って、各甘味料の
配合比は砂糖換算で等量とし、甘味の合計が砂糖換算5
%に相当するように調製し飲料水に溶解させた。熟練し
たパネラー15名を用いての官能評価を下記基準に従っ
て行い、各パネラーの評価結果の平均値を算出し表に示
した。 評価基準 1:劣る、2:やや劣る、3:普通、4:やや優れる、
5:優れるExample 3 The taste quality of sugar alcohols in a mixed aqueous solution of stevia sweetener, sucralose and sugar alcohol was evaluated.
According to the formulations shown in Tables 3-1 and 3-2, the mixing ratio of each sweetener was made equivalent in terms of sugar, and the total sweetness was 5 in terms of sugar.
% And dissolved in drinking water. Sensory evaluation using 15 skilled panelists was performed according to the following criteria, and the average of the evaluation results of each panel was calculated and shown in the table. Evaluation criteria 1: Inferior 2: Slightly inferior 3: Normal, 4: Slightly superior,
5: Excellent
【0039】[0039]
【表5】 [Table 5]
【0040】[0040]
【表6】 [Table 6]
【0041】実施例4、5 ステビア甘味料、スクラロース、キシリトール混合水溶
液の味質評価を行った。表4、5に示す処方に従って、
甘味の合計が砂糖換算5%に相当するように調製し飲料
水に溶解させた。熟練したパネラー15名を用いての官
能評価を下記基準に従って行い、各パネラーの評価結果
の平均値を算出し表に示した。 評価(味質に関して) −2:基準(キシリトール無添加区)より劣る、−1:
やや劣る、±0:同等、+1:やや向上、+2:向上 評価(カロリーに関して) ±0:同等、−1:5kcal/100ml未満、−2:20kcal
/100ml未満Examples 4 and 5 The taste of a mixed aqueous solution of stevia sweetener, sucralose and xylitol was evaluated. According to the formulations shown in Tables 4 and 5,
It was prepared so that the total sweetness was equivalent to 5% in terms of sugar, and dissolved in drinking water. Sensory evaluation using 15 skilled panelists was performed according to the following criteria, and the average of the evaluation results of each panel was calculated and shown in the table. Evaluation (with respect to taste) -2: Inferior to standard (xylitol-free group), -1:
Slightly inferior, ± 0: equivalent, +1: slightly improved, +2: improved Evaluation (in terms of calories) ± 0: equivalent, -1: less than 5kcal / 100ml, -2: 20kcal
Less than / 100ml
【0042】[0042]
【表7】 [Table 7]
【0043】[0043]
【表8】 [Table 8]
【0044】実施例6 ステビア甘味料とスクラロース混合水溶液の耐熱性を調
べた。表6に示す処方に従って、ステビア甘味料、スク
ラロース、アスパルテームを各種比率で混合、甘味の合
計が砂糖換算5%に相当するように調製しイオン交換水
に溶解させた。表6に示す条件にて加熱処理を行ったも
のの甘味残存率を各種濃度の砂糖水溶液と比較し判定し
た。官能評価は熟練したパネラー15名を用いて行い、
各パネラーの評価結果の平均値を算出し表に示した。 数値:甘味残存率(%)Example 6 The heat resistance of a mixed aqueous solution of stevia sweetener and sucralose was examined. According to the formulation shown in Table 6, stevia sweetener, sucralose, and aspartame were mixed at various ratios, prepared so that the total sweetness was equivalent to 5% in terms of sugar, and dissolved in ion-exchanged water. The heat treatment was performed under the conditions shown in Table 6, and the sweetness remaining ratio was determined by comparing with the aqueous sugar solutions having various concentrations. Sensory evaluation was performed using 15 skilled panelists,
The average of the evaluation results of each panel was calculated and shown in the table. Numerical value: sweetness residual rate (%)
【0045】[0045]
【表9】 [Table 9]
【0046】実施例7 ステビア甘味料とスクラロースを混合したときの甘味増
強効果について調べた。表7に示す処方に従って、ステ
ビア甘味料、スクラロース、アスパルテームを砂糖換算
1:1の割合で混合、甘味の合計が砂糖換算5%に相当
するように調製し飲料水に溶解させ、各種濃度の砂糖水
溶液と比較した。官能評価は熟練したパネラー15名を
用いて行い、各パネラーの評価結果の平均値を算出し表
に示した。Example 7 The sweetness enhancing effect when a stevia sweetener and sucralose were mixed was examined. According to the formulation shown in Table 7, stevia sweetener, sucralose, and aspartame were mixed at a ratio of 1: 1 in terms of sugar, prepared so that the total sweetness was equivalent to 5% in terms of sugar, dissolved in drinking water, and dissolved in various concentrations of sugar. Compared to aqueous solution. The sensory evaluation was performed using 15 skilled panelists, and the average of the evaluation results of each panel was calculated and shown in the table.
【0047】[0047]
【表10】 [Table 10]
【0048】実施例8 コーヒーにおけるステビア甘味料とスクラロース併用に
よる甘味質を評価した。市販のインスタントコーヒー1
4gに、表8−1および8−2の配合処方に従って甘味
料を添加(各々の比率は砂糖換算重量比でステビア甘味
料:スクラロース:キシリトール=25:25:50)
し、熱水で1kgに調製した。熟練したパネラー15名
を用いての官能評価を下記の基準に従って行い、各パネ
ラーの評価結果の平均値を算出し表に示した。実施例8
に示されるコーヒーは、各甘味料の単独使用時(比較例
5)と比較して異味が軽減され且つ厚みと複雑味があ
り、良好な甘味を呈した。 評価基準(カロリー以外) 1:劣る、2:やや劣る、3:普通、4:やや優れる、
5:優れる 評価基準(カロリーに関して、単位はkcal/100ml) 0:30以上、1:29〜20、2:19〜15、3:14〜10、
4:9〜5、5:5未満Example 8 The sweetness of coffee in combination with stevia sweetener and sucralose was evaluated. Commercial Instant Coffee 1
To 4 g, a sweetener is added in accordance with the formulation shown in Tables 8-1 and 8-2 (each ratio is stevia sweetener: sucralose: xylitol = 25: 25: 50 by weight in terms of sugar).
Then, it was adjusted to 1 kg with hot water. Sensory evaluation using 15 skilled panelists was performed according to the following criteria, and the average of the evaluation results of each panelist was calculated and shown in the table. Example 8
The coffee shown in Table 2 exhibited good sweetness with reduced off-flavor and thickness and complexity compared to when each sweetener was used alone (Comparative Example 5). Evaluation criteria (other than calories) 1: poor, 2: slightly poor, 3: normal, 4: slightly excellent,
5: Excellent evaluation criteria (calories, kcal / 100ml) 0:30 or more, 1: 29-20, 2: 19-15, 3: 14-10,
4: 9-5, less than 5: 5
【0049】[0049]
【表11】 [Table 11]
【0050】[0050]
【表12】 [Table 12]
【0051】実施例9 紅茶抽出液におけるステビア甘味料とスクラロース併用
による甘味質を評価した。市販の紅茶葉を常法に従って
熱水抽出したものに、表9−1および9−2の配合処方
に従って甘味料を添加し(各々の比率は砂糖換算重量比
でステビア甘味料:スクラロース:キシリトール=2
5:25:50)全量を1kgに調製した。熟練したパ
ネラー15名を用いての官能評価を下記の基準に従って
行い、各パネラーの評価結果の平均値を算出し表に示し
た。実施例9に示される紅茶は、各甘味料の単独使用時
(比較例6)と比較して異味が軽減され且つ厚みと複雑
味があり、良好な甘味を呈した。 評価基準(カロリー以外) 1:劣る、2:やや劣る、3:普通、4:やや優れる、
5:優れる 評価基準(カロリーに関して、単位はkcal/100ml) 0:30以上、1:29〜20、2:19〜15、3:14〜10、
4:9〜5、5:5未満Example 9 The sweetness of a black tea extract was evaluated by using a stevia sweetener and sucralose in combination. A sweetener is added to a commercially available black tea leaf obtained by hot water extraction according to a conventional method, according to the formulation shown in Tables 9-1 and 9-2 (each ratio is expressed in terms of sugar as stevia sweetener: sucralose: xylitol = 2
5:25:50) The total amount was adjusted to 1 kg. Sensory evaluation using 15 skilled panelists was performed according to the following criteria, and the average of the evaluation results of each panelist was calculated and shown in the table. The black tea shown in Example 9 exhibited good sweetness with reduced off-flavor, thickness and complexity compared to when each sweetener was used alone (Comparative Example 6). Evaluation criteria (other than calories) 1: poor, 2: slightly poor, 3: normal, 4: slightly excellent,
5: Excellent evaluation criteria (calories, kcal / 100ml) 0:30 or more, 1: 29-20, 2: 19-15, 3: 14-10,
4: 9-5, less than 5: 5
【0052】[0052]
【表13】 [Table 13]
【0053】[0053]
【表14】 [Table 14]
【0054】実施例10 炭酸飲料におけるステビア甘味料とスクラロース併用に
よる甘味質を評価した。表10−1および10−2の配
合処方に示す甘味料(砂糖換算で7%、各々の甘味料の
比率は砂糖換算重量比でステビア甘味料:スクラロー
ス:キシリトール=25:25:50)、クエン酸0.
7g、リンゴ酸0.3gおよびレモンエッセンス1gに
水を加え全量を1Lとし、孔径0.1μmのメンブラン
フィルターで濾過した後、冷却化炭酸ガスを4.5kg/
cm2で圧入し、透明ガラス瓶に充填打栓したものを6
5℃で15分間加熱殺菌した。官能評価は熟練したパネ
ラー15名を用いて下記の基準に従って行い、各パネラ
ーの評価結果の平均値を算出し表に示した。実施例10
に示される炭酸飲料は、比較例7よりも異味が軽減され
且つ好ましい甘味を呈し、しかもカロリーの低減された
ものだった。 評価基準(カロリー以外) 1:劣る、2:やや劣る、3:普通、4:やや優れる、
5:優れる 評価基準(カロリーに関して、単位はkcal/100ml) 0:30以上、1:29〜20、2:19〜15、3:14〜10、
4:9〜5、5:5未満Example 10 The sweetness of a carbonated beverage was evaluated using a stevia sweetener and sucralose in combination. The sweeteners (7% in terms of sugar, the ratio of each sweetener is Stevia sweetener: sucralose: xylitol = 25: 25: 50 by weight in terms of sugar) shown in the formulation of Tables 10-1 and 10-2, quenched Acid 0.
Water was added to 7 g, 0.3 g of malic acid and 1 g of lemon essence to make the total volume 1 L, and the mixture was filtered through a membrane filter having a pore size of 0.1 μm.
6 cm2 into a transparent glass bottle.
The solution was sterilized by heating at 5 ° C. for 15 minutes. The sensory evaluation was performed according to the following criteria using 15 skilled panelists, and the average of the evaluation results of each panel was calculated and shown in the table. Example 10
The carbonated beverage shown in (1) had less unpleasant taste and a preferable sweetness than Comparative Example 7, and had a reduced calorie. Evaluation criteria (other than calories) 1: poor, 2: slightly poor, 3: normal, 4: slightly excellent,
5: Excellent evaluation criteria (calories, kcal / 100ml) 0:30 or more, 1: 29-20, 2: 19-15, 3: 14-10,
4: 9-5, less than 5: 5
【0055】[0055]
【表15】 [Table 15]
【0056】[0056]
【表16】 [Table 16]
【0057】実施例11 キャンディにおけるステビア甘味料とスクラロース併用
による甘味質を評価した。ラクチトール(東和化成
(株)製)100重量部に、表11の配合処方に示す甘
味料を添加し、常圧下140℃15分間加熱して水分を
5重量%に調整した。ついでポリデキストロース(ファ
イザー(株)製)10重量部、粉末クエン酸10重量部
および香料1重量部と水34重量部を添加し、真空度8
torr、温度50℃で真空乾燥させ水分残存量を1重
量部としてキャンディを製造した。熟練したパネラー1
5名を用いての官能評価を下記の基準に従って行い、各
パネラーの評価結果の平均値を算出し表に示した。実施
例11に示されるキャンディは、比較例8よりも異味が
軽減され好ましい甘味を呈していた。 評価基準 1:劣る、2:やや劣る、3:普通、4:やや優れる、
5:優れるExample 11 The sweetness of candy in combination with stevia sweetener and sucralose was evaluated. To 100 parts by weight of lactitol (manufactured by Towa Kasei Co., Ltd.), the sweetener shown in the formulation in Table 11 was added, and heated at 140 ° C. for 15 minutes under normal pressure to adjust the water content to 5% by weight. Then, 10 parts by weight of polydextrose (manufactured by Pfizer Co., Ltd.), 10 parts by weight of powdered citric acid, 1 part by weight of flavor and 34 parts by weight of water were added, and the degree of vacuum was 8
A candy was manufactured by vacuum drying at 50 ° C. torr and a residual water content of 1 part by weight. Skilled panelist 1
The sensory evaluation using five persons was performed according to the following criteria, and the average value of the evaluation results of each panel was calculated and shown in the table. The candy shown in Example 11 had less off-flavor than Comparative Example 8 and exhibited a preferable sweetness. Evaluation criteria 1: Inferior 2: Slightly inferior 3: Normal, 4: Slightly superior,
5: Excellent
【0058】[0058]
【表17】 [Table 17]
【0059】実施例12 シュガーレスクッキーにおけるステビア甘味料とスクラ
ロース併用による甘味質を評価した。バター65重量部
に還元麦芽糖水飴(林原商事(株)製)22重量部、ラ
クチトール(東和化成(株)製)9重量部および表12
の配合処方に示す甘味料(各々の甘味料の比率は砂糖換
算重量比でステビア甘味料:スクラロース:キシリトー
ル=27:27:46)を添加し良く混合した中に、全
卵25重量部、バニラ香料0.05重量部および薄力粉
100重量部を順次投入し混練、成形したものを170
℃にて15分焼成した。熟練したパネラー15名を用い
ての官能評価を下記の基準に基づいて行い、各パネラー
の評価結果の平均値を算出し表に示した。実施例12に
示されるクッキーは、比較例9よりも異味が軽減され好
ましい甘味を呈していた。 評価基準 1:劣る、2:やや劣る、3:普通、4:やや優れる、
5:優れるExample 12 The sweetness of a sugarless cookie by using a combination of stevia sweetener and sucralose was evaluated. 22 parts by weight of reduced maltose syrup (manufactured by Hayashibara Corporation), 9 parts by weight of lactitol (manufactured by Towa Kasei Co., Ltd.) and 65 parts by weight of butter
(Sweet sweetener: sucralose: xylitol = 27: 27: 46 in terms of sugar), and the mixture was mixed well, and 25 parts by weight of whole egg and vanilla were added. One hundred and fifty parts by weight of the flavor and 100 parts by weight of soft flour were sequentially charged, kneaded, and molded to obtain 170 parts by weight.
Firing at 15 ° C. for 15 minutes. Sensory evaluation using 15 skilled panelists was performed based on the following criteria, and the average of the evaluation results of each panelist was calculated and shown in the table. The cookie shown in Example 12 had less off-flavor than Comparative Example 9 and exhibited a preferable sweetness. Evaluation criteria 1: Inferior 2: Slightly inferior 3: Normal, 4: Slightly superior,
5: Excellent
【0060】[0060]
【表18】 [Table 18]
【0061】[0061]
【発明の効果】本発明に従いα−グルコシルステビア甘
味料とスクラロースを用いて甘味を付与された飲食物
は、(1)α−グルコシルステビア甘味料特有の異味や
後味が感じられず、またスクラロースのあっさりとした
味質に複雑さが加わった、(2)ノンカロリーでかつ先
味とボディ感のある良質な甘味を呈する。またこの発明
にて呈示される方法で飲食物に付与された甘味は(3)
熱に安定で加工適性に優れており、(4)α−グルコシ
ルステビア甘味料およびスクラロースを各々単独で使用
する場合と比較して甘味の増強効果が認められる。さら
に、α−グルコシルステビア甘味料とスクラロース、糖
アルコール(キシリトール)を用いて甘味を付与された
飲食物は、(5)先味とボディ感が一層強く砂糖により
近い好ましい甘味を呈する。EFFECTS OF THE INVENTION A food or drink provided with a sweetener using α-glucosylstevia sweetener and sucralose according to the present invention has the following effects. (1) No off-taste or aftertaste peculiar to α-glucosylstevia sweetener is sensed. (2) Non-calorie, high-quality sweetness with a taste and body sensation in addition to simple taste and complexity. The sweetness imparted to food and drink by the method presented in the present invention is (3)
It is stable to heat and excellent in processability, and (4) an effect of enhancing sweetness is recognized as compared with the case where α-glucosylstevia sweetener and sucralose are used alone. Furthermore, foods and drinks to which sweetness has been imparted using an α-glucosyl stevia sweetener, sucralose, and sugar alcohol (xylitol) exhibit (5) a preferred sweetness that has a stronger initial taste and body feeling and is closer to sugar.
【手続補正書】[Procedure amendment]
【提出日】平成12年2月21日(2000.2.2
1)[Submission date] February 21, 2000 (200.2.2
1)
【手続補正1】[Procedure amendment 1]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】0048[Correction target item name] 0048
【補正方法】変更[Correction method] Change
【補正内容】[Correction contents]
【0048】実施例8 コーヒーにおけるステビア甘味料とスクラロース併用に
よる甘味質を評価した。市販のインスタントコーヒー1
4gに、表8−1および8−2の配合処方に従って甘味
料を添加(各々の比率は砂糖換算重量比でステビア甘味
料:スクラロース=1:1又はステビア甘味料:スクラ
ロース:キシリトール=1:1:1)し、熱水で1kg
に調製した。熟練したパネラー15名を用いての官能評
価を下記の基準に従って行い、各パネラーの評価結果の
平均値を算出し表に示した。実施例8に示されるコーヒ
ーは、各甘味料の単独使用時(比較例5)と比較して異
味が軽減され且つ厚みと複雑味があり、良好な甘味を呈
した。 評価基準(カロリー以外) 1:劣る、2:やや劣る、3:普通、4:やや優れる、
5:優れる 評価基準(カロリーに関して、単位はkcal/100ml) 0:30以上、1:29〜20、2:19〜15、3:14〜10、
4:9〜5、5:5未満Example 8 The sweetness of coffee in combination with stevia sweetener and sucralose was evaluated. Commercial Instant Coffee 1
To 4g, stevia sweetness ratio addition of (respectively sweetener according formulation of Tables 8-1 and 8-2 in sugar-reduced weight ratio
Food: Sucralose = 1: 1 or Stevia sweetener: Sucral
Loose: xylitol = 1: 1: 1 ) and add 1kg with hot water
Was prepared. Sensory evaluation using 15 skilled panelists was performed according to the following criteria, and the average of the evaluation results of each panelist was calculated and shown in the table. The coffee shown in Example 8 exhibited good sweetness with reduced off-flavor, thickness and complexity compared to when each sweetener was used alone (Comparative Example 5). Evaluation criteria (other than calories) 1: poor, 2: slightly poor, 3: normal, 4: slightly excellent,
5: Excellent evaluation criteria (calories, kcal / 100ml) 0:30 or more, 1: 29-20, 2: 19-15, 3: 14-10,
4: 9-5, less than 5: 5
【手続補正2】[Procedure amendment 2]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】0051[Correction target item name] 0051
【補正方法】変更[Correction method] Change
【補正内容】[Correction contents]
【0051】実施例9 紅茶抽出液におけるステビア甘味料とスクラロース併用
による甘味質を評価した。市販の紅茶葉を常法に従って
熱水抽出したものに、表9−1および9−2の配合処方
に従って甘味料を添加し(各々の比率は砂糖換算重量比
でステビア甘味料:スクラロース=1:1又はステビア
甘味料:スクラロース:キシリトール=1:1:1)全
量を1kgに調製した。熟練したパネラー15名を用い
ての官能評価を下記の基準に従って行い、各パネラーの
評価結果の平均値を算出し表に示した。実施例9に示さ
れる紅茶は、各甘味料の単独使用時(比較例6)と比較
して異味が軽減され且つ厚みと複雑味があり、良好な甘
味を呈した。 評価基準(カロリー以外) 1:劣る、2:やや劣る、3:普通、4:やや優れる、
5:優れる 評価基準(カロリーに関して、単位はkcal/100ml) 0:30以上、1:29〜20、2:19〜15、3:14〜10、
4:9〜5、5:5未満Example 9 The sweetness of a black tea extract was evaluated by using a stevia sweetener and sucralose in combination. A sweetener is added to a commercially available black tea leaf obtained by hot-water extraction according to a conventional method, according to the formulation shown in Tables 9-1 and 9-2 (each ratio is a ratio of stevia sweetener to sucralose by weight in terms of sugar : 1: 1). 1 or stevia
Sweetener: sucralose: xylitol = 1: 1: 1 ) The total amount was adjusted to 1 kg. Sensory evaluation using 15 skilled panelists was performed according to the following criteria, and the average of the evaluation results of each panelist was calculated and shown in the table. The black tea shown in Example 9 exhibited good sweetness with reduced off-flavor, thickness and complexity compared to when each sweetener was used alone (Comparative Example 6). Evaluation criteria (other than calories) 1: poor, 2: slightly poor, 3: normal, 4: slightly excellent,
5: Excellent evaluation criteria (calories, kcal / 100ml) 0:30 or more, 1: 29-20, 2: 19-15, 3: 14-10,
4: 9-5, less than 5: 5
【手続補正3】[Procedure amendment 3]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】0054[Correction target item name] 0054
【補正方法】変更[Correction method] Change
【補正内容】[Correction contents]
【0054】実施例10 炭酸飲料におけるステビア甘味料とスクラロース併用に
よる甘味質を評価した。表10−1および10−2の配
合処方に示す甘味料(砂糖換算で7%、各々の甘味料の
比率は砂糖換算重量比でステビア甘味料:スクラロース
=1:1又はステビア甘味料:スクラロース:キシリト
ール=1:1:1)、クエン酸0.7g、リンゴ酸0.
3gおよびレモンエッセンス1gに水を加え全量を1L
とし、孔径0.1μmのメンブランフィルターで濾過し
た後、冷却化炭酸ガスを4.5kg/cm2で圧入し、透
明ガラス瓶に充填打栓したものを65℃で15分間加熱
殺菌した。官能評価は熟練したパネラー15名を用いて
下記の基準に従って行い、各パネラーの評価結果の平均
値を算出し表に示した。実施例10に示される炭酸飲料
は、比較例7よりも異味が軽減され且つ好ましい甘味を
呈し、しかもカロリーの低減されたものだった。 評価基準(カロリー以外) 1:劣る、2:やや劣る、3:普通、4:やや優れる、
5:優れる 評価基準(カロリーに関して、単位はkcal/100ml) 0:30以上、1:29〜20、2:19〜15、3:14〜10、
4:9〜5、5:5未満Example 10 The sweetness of a carbonated beverage was evaluated using a stevia sweetener and sucralose in combination. The sweeteners shown in the formulations of Tables 10-1 and 10-2 (7% in terms of sugar, the ratio of each sweetener is the weight ratio of sugar, Stevia sweetener: sucralose)
= 1: 1 or stevia sweetener: sucralose: xylito
1: 1: 1 ), 0.7 g of citric acid, 0.
Add water to 3g and 1g of lemon essence and add 1L
After filtering through a membrane filter having a pore size of 0.1 μm, cooled carbon dioxide gas was injected under pressure at 4.5 kg / cm 2, and a transparent glass bottle filled and stoppered was heated and sterilized at 65 ° C. for 15 minutes. The sensory evaluation was performed according to the following criteria using 15 skilled panelists, and the average of the evaluation results of each panel was calculated and shown in the table. The carbonated beverage shown in Example 10 had less off-flavor and a preferable sweetness than Comparative Example 7, and had a reduced calorie. Evaluation criteria (other than calories) 1: poor, 2: slightly poor, 3: normal, 4: slightly excellent,
5: Excellent evaluation criteria (calories, kcal / 100ml) 0:30 or more, 1: 29-20, 2: 19-15, 3: 14-10,
4: 9-5, less than 5: 5
【手続補正4】[Procedure amendment 4]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】0059[Correction target item name] 0059
【補正方法】変更[Correction method] Change
【補正内容】[Correction contents]
【0059】実施例12 シュガーレスクッキーにおけるステビア甘味料とスクラ
ロース併用による甘味質を評価した。バター65重量部
に還元麦芽糖水飴(林原商事(株)製)22重量部、ラ
クチトール(東和化成(株)製)9重量部および表12
の配合処方に示す甘味料(各々の甘味料の比率は砂糖換
算重量比でステビア甘味料:スクラロース=1:1)を
添加し良く混合した中に、全卵25重量部、バニラ香料
0.05重量部および薄力粉100重量部を順次投入し
混練、成形したものを170℃にて15分焼成した。熟
練したパネラー15名を用いての官能評価を下記の基準
に基づいて行い、各パネラーの評価結果の平均値を算出
し表に示した。実施例12に示されるクッキーは、比較
例9よりも異味が軽減され好ましい甘味を呈していた。 評価基準 1:劣る、2:やや劣る、3:普通、4:やや優れる、
5:優れるExample 12 The sweetness of a sugarless cookie by using a combination of stevia sweetener and sucralose was evaluated. 22 parts by weight of reduced maltose syrup (manufactured by Hayashibara Corporation), 9 parts by weight of lactitol (manufactured by Towa Kasei Co., Ltd.) and 65 parts by weight of butter
Of sweetener (the ratio of each sweetener is Stevia sweetener: sucralose = 1: 1 in terms of sugar weight ratio) was added and mixed well, and 25 parts by weight of whole egg and 0.05 of vanilla flavor were added. Parts by weight and 100 parts by weight of soft flour were sequentially charged, kneaded, and molded, and baked at 170 ° C. for 15 minutes. Sensory evaluation using 15 skilled panelists was performed based on the following criteria, and the average of the evaluation results of each panelist was calculated and shown in the table. The cookie shown in Example 12 had less off-flavor than Comparative Example 9 and exhibited a preferable sweetness. Evaluation criteria 1: Inferior 2: Slightly inferior 3: Normal, 4: Slightly superior,
5: Excellent
───────────────────────────────────────────────────── フロントページの続き (72)発明者 把田 雅彦 山口県岩国市飯田町2−8−1 日本製紙 株式会社化成品開発研究所内 Fターム(参考) 4B047 LB09 LG21 LG25 LG32 LP02 ──────────────────────────────────────────────────続 き Continuing on the front page (72) Inventor Masahiko Handa 2-8-1 Iida-cho, Iwakuni-shi, Yamaguchi Japan Nippon Paper Industries Co., Ltd. Chemical Development Laboratory F-term (reference) 4B047 LB09 LG21 LG25 LG32 LP02
Claims (8)
ロースを組み合わせることを特徴とする甘味付与方法。1. A method for imparting sweetness, comprising combining an α-glucosylstevia sweetener and sucralose.
−グルコシル基平均付加数が1.0〜2.5のものを用
いる請求項1記載の甘味付与方法。2. An α-glucosylstevia sweetener comprising α
The method for imparting sweetness according to claim 1, wherein the average glucosyl group addition number is 1.0 to 2.5.
ロースを砂糖換算重量で10:90〜70:30の割合
で配合する請求項1記載の甘味付与方法。3. The method according to claim 1, wherein the α-glucosyl stevia sweetener and sucralose are blended in a ratio of 10:90 to 70:30 in terms of sugar.
ロースを砂糖換算重量で10:90〜80:20の割合
で配合する請求項2記載の甘味付与方法。4. The method according to claim 2, wherein the α-glucosyl stevia sweetener and sucralose are blended in a ratio of 10:90 to 80:20 in terms of sugar weight.
クラロースに、さらに糖アルコールを砂糖換算重量で2
0:80〜80:20の割合で配合する請求項1〜4い
ずれか1項記載の甘味付与方法。5. A sugar alcohol is added to the α-glucosyl stevia sweetener and sucralose in a sugar equivalent weight of 2%.
The method for imparting sweetness according to any one of claims 1 to 4, wherein the sweetening agent is blended at a ratio of 0:80 to 80:20.
スリトール、マルチトール、ソルビトール、マンニトー
ル、パラチニット、ラクチトールから1種または2種以
上用いる請求項5記載の甘味付与方法。6. The method according to claim 5, wherein the sugar alcohol is at least one selected from xylitol, erythritol, maltitol, sorbitol, mannitol, palatinit, and lactitol.
ロースを含有してなることを特徴とする甘味料。7. A sweetener comprising an α-glucosylstevia sweetener and sucralose.
クラロースに、さらに糖アルコールを砂糖換算重量で2
0:80〜80:20の割合で配合してなる請求項7記
載の甘味料。8. A sugar alcohol is added to the α-glucosyl stevia sweetener and sucralose in a sugar equivalent weight of 2%.
The sweetener according to claim 7, which is blended at a ratio of 0:80 to 80:20.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP35269999A JP3508127B2 (en) | 1999-12-13 | 1999-12-13 | Sweetening method and sweetener |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP35269999A JP3508127B2 (en) | 1999-12-13 | 1999-12-13 | Sweetening method and sweetener |
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| Publication Number | Publication Date |
|---|---|
| JP2001161309A true JP2001161309A (en) | 2001-06-19 |
| JP3508127B2 JP3508127B2 (en) | 2004-03-22 |
Family
ID=18425837
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP35269999A Expired - Fee Related JP3508127B2 (en) | 1999-12-13 | 1999-12-13 | Sweetening method and sweetener |
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| Country | Link |
|---|---|
| JP (1) | JP3508127B2 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002034501A (en) * | 2000-07-19 | 2002-02-05 | Toyo Seito Kk | Sweetener composition and low-calorie beverage |
| JP2003047453A (en) * | 2001-08-03 | 2003-02-18 | Suntory Ltd | Method for producing low-calorie brewage using malt as raw material |
| JP2006204287A (en) * | 2004-12-27 | 2006-08-10 | Lotte Co Ltd | Collagen-containing food/drink |
| WO2009086049A3 (en) * | 2007-12-27 | 2010-01-28 | Mc Neil Nutritionals, Llc | Synergistic sweetening compositions |
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| JP2011135837A (en) * | 2009-12-28 | 2011-07-14 | Suntory Holdings Ltd | Alcoholic beverage having improved taste |
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