JP2001152169A - Improvement in combustion efficiency of gasoline, gas oil, and fuel oil and purification of exhaust gas - Google Patents

Abstract

PROBLEM TO BE SOLVED: To produce a catalyst which, when mixed into a petroleum fuel, improves the combustion efficiency thereof, enables the fuel consumption of automobiles to be reduced by 10-20%, and can purify a pollutive exhaust gas. SOLUTION: Zeolite impregnated with Aspergillus bacteria and dried is used as the catalyst. The catalyst is impregnated with an aqueous nutrition solution and then immersed in a petroleum fuel for 2-3 weeks to cut and decompose the carbon chains of petroleum hydrocarbons. If necessary, a radiation catalyst and a metal chelate liquid peroxide are immersed together with the catalyst in the petroleum fuel to accelerate the cutting and decomposition of the carbon chains. Such a petroleum fuel containing active bacteria is used as a fuel for automobiles, trains, airplanes, ships, and incineration furnaces, improving fuel consumption and purifying an exhaust gas.

Description

DETAILED DESCRIPTION OF THE INVENTION

When using many BACKGROUND OF THE INVENTION Conventional petroleum fuels scatter always spreaders pollution exhaust gas is large, Therefore hydrocarbons and Nox by incomplete combustion, Sox, many of CO ₂ and free carbon exhaust However, because it was an unsanitary cause of air pollution, it embarked on the regulation of the law and started to reduce the damage, but as a remedy, hybrid electric motors and oil fuel were used. However, today there are many older vehicles, and there is an urgent need to improve the combustion efficiency of unregulated vehicles. Propane gas fuel has become widespread in the taxi industry as one of its purifications, but because of the lack of power as a fuel to go up the slope, development of gasification and development of intermediate products of liquid fuel has been desired. In order to increase combustion efficiency by splitting the carbon chains of hydrocarbon molecules of petroleum fuel, a radiative catalyst was developed, but the cost was high and the intensity of radiation was strong, generally exceeding the regulations of the Science and Technology Agency. But also 1000cc-2
Since the gasoline tank of a 000 cc class car has a narrow inlet, it is impossible for some manufacturers to directly immerse it in gasoline, so it was necessary to cut off the liquid fuel itself. We developed a method to cut off the molecule by continuously adding the new fuel to the certain residual fuel by making the molecular cut work continuously by the propagation of Usus bacteria. This has made it possible to use the petroleum fuel itself as a molecular cutting agent.
It became possible to subdivide and sell this in bottles or cans. However, this petroleum fuel-cut catalyst also had some variation in long-term storage, and it was a problem how to delay the start when traveling when mixed with the new fuel and the catalyst solution. This can be solved by liquid addition,
Silicon, titanium, zirconium, tin,
Hafnium, palladium, copper, nickel, cobalt,
Iron, chrome, platinum, silver, by the organic chelates of gold Add small amount, the result of a combination of method in which deplete the hydrocarbon conversion allowed incomplete combustion into harmless gases N ₂ and the Nox, the high-octane petroleum fuels It is like can travel without the need, de-Nox the development of emulsifier was added 10% water, de-Sox, the purification of the de CO ₂ is carried out exhaust gas came to be performed. The addition of benzoyl peroxide further enhances the effect, and the exhaust gas is introduced into the purifier by a suction pump and purified by sodium silicate aqueous solution to remove NOx.
De Sox, de Co ₂ gas developed a method for detoxifying adsorbed by the adsorbent. This has led to the conviction that it will be applied not only to cars but also to vessels, airplanes, trains and other fuel tanks, and will be effective in preventing the global environment from deteriorating. And it turned out that the sodium peracrylate titanate solution also has a purifying power. The activated Aspergillus is concentrated as a catalyst for petroleum fuel containing the activated Aspergillus, and by adding petroleum fuel to the active Aspergillus, the hydrocarbon chain of the petroleum fuel is decomposed and separated. When the divided fuel is used for combustion, the fuel efficiency is improved by 10 to 20%. Due to the presence of the activated Aspergillus bacteria, the activated Aspergillus bacterium obtained by adding 1 to 10% of the fuel to the fuel tank of the automobile decomposes and breaks the carbon chain of the hydrocarbon of the fuel. Is used to improve fuel efficiency by continuously decomposing and dividing petroleum fuel, which is introduced as a culture of inoculum, and is used not only for automobiles but also for airplanes, ships, and diesel engines. Not only is it used for incinerators and oil stoves, but also has a high level of safety in cracking and breaking down petroleum fuel due to microbial activity without sudden explosion as in other cracking methods. Then, due to the relatively small water content in petroleum fuels does not occur excessively decomposed, the carbon chain number of petroleum fuels is below C ₈ less degradation shedding of carbon chain number are characterized not performed almost primarily It is also used for incinerators and oil stoves because it has the property of decomposing and breaking the carbon chain number between C _{19 and} C ₁₄ , and has the property of sharply decreasing at C ₁₀ and C ₂₁ . However, in the case of heavy oil, C
₁₉ , a large amount of radiation minerals (ZrH
f) When O ₂ is used, its decomposition and fragmentation can exceed the range, so that good results are obtained when used in combination. The provision of an exhaust gas purifier further reduces air pollution which degrades the global environment. In addition, cost reduction due to kerosene conversion of parapines having a large number of carbon atoms is measured. And the marine fuel is saved.

2. Description of the Related Art As a method for improving the fuel efficiency of petroleum fuel, radiating minerals such as radiating monazite, tourmaline stone, and uranium stone are introduced into a fuel tank to partially reduce the carbon chains of carbon and hydrogen molecules of the fuel. The method of increasing the combustion efficiency by cutting has been adopted and used in some cases. However, the regulation of the Science and Technology Agency is less than 4 microcuries per gram, so in this range, the cutting of the carbon chain takes time. This is not practical because of the use of mineral catalysts of 250 microcuries or more per gram. Therefore, a liquid obtained by applying a liquid obtained by mixing the radiating mineral ore powder into the paint is applied to the surface of the fuel tank or the surface of the introduction pipe. However, the power is weaker than the former, and the fuel efficiency is improved by 10% or less. there were. There is a problem in removing Nox, Sox, CO ₂ , and free carbon even with this increase in efficiency, and thus, even if this catalyst is put into petroleum fuel, the effect is exhibited. The effect was not able to be exhibited unless it passed.

SUMMARY OF THE INVENTION Accordingly, the present invention relates to a method for producing a fuel oil containing aspergillus bacterium on a zeolite impregnated with a nutrient for about 2 weeks or more after fitting the oil into a petroleum fuel. Fermentation is used as a feed to decompose and break off the carbon chain of hydrocarbons of petroleum fuel to improve ignitability. Then, the viable bacteria in the petroleum fuel were dispersed and stored in a state of low moisture to perform a continuous catalytic action. The inlets of gasoline tanks of 1000cc to 2000cc class are narrow, and it is difficult to immerse known radiating mineral catalysts in gasoline by physically adjusting the size of the container. The input ports were mixed. In addition, in terms of the dimensions that can be put in, it is necessary to use a catalyst that is higher than the statutory regulation value with a high radiation because it is necessary to make the size extremely small. And it was explosive. Therefore, in order to improve the combustion efficiency of this petroleum fuel, a method of cutting off the carbon chain of the hydrocarbon of the petroleum fuel by Aspergillus was adopted, and at first the concentrated bacteria of Aspergillus was put into a container and converted into petroleum fuel. Soak 3
Leave for a week and wait for the growth of the cells, and replace C ₁₆ -C ₁₉ with C
_The method of dividing into ₆ was adopted, but it took too much time to divide and was effective after 3 weeks. Therefore, as a method for eliminating the time of the first three weeks, as a catalyst, petroleum fuel is put in a separate large tank, and Aspergillus is put in advance and fermented for three weeks. We developed a method to save three weeks of time. And
Adding this catalyst to a gasoline tank after fuel consumption would be costly and time-consuming, so we decided to test its rationalization. Then, they decided to consider how to save fuel immediately when new fuel was put into the tank. Then, de-Nox, de Sox, de-Co _2, the exhaust gas purification allowed to increase the de-free carbon was decided to test by combining a catalyst and other methods. In addition, asparagine oil having a high fluorine point is decomposed and divided by Aspergillus bacteria, and at the same time, the carbon chain of the hydrocarbon is decomposed by the (ZrHf) O ₂ CaCO ₃ catalyst to lower the fluorine point, thereby increasing the general demand. In addition to performing a test for kerosene, it is also investigated whether oil odor generated during ignition and extinguishing can be suppressed by adding a chelating solution of acetylacetone copper titanium.
And, in the purification of exhaust gas and the combustion of cracked fuel, C
Test the addition of benzoyl peroxide to reduce the generation of O and CH gases.

Means for Solving the Problems In the conventional catalyst, the catalyst is put in a stainless steel cylindrical container having a porous metal, sealed, a magnet piece is attached to the bottom, and then put into a gasoline tank.
Although the gasoline hydrocarbons were decomposed by magnetically attaching to the bottom of the tank, it took two to three weeks to break the carbon chains of the gasoline hydrocarbon molecules to facilitate ignition and combustion. But for long haul trucks and cars,
It was necessary to raise fuel efficiency by 10% or more immediately.
It is necessary to gradually reduce the idle time.
There is a 500cc class, and the size of the gasoline tank differs depending on each car company. On the one hand, there are catalyst tanks that can be fitted by adjusting the inlet, and on the other hand, those with a narrow mouth that can not be inserted at all. In some cases, the catalyst container was removed and only the catalyst was taken out and put into a gasoline tank, but crushed stone powder and steel powder were thrown in, resulting in damage to the engine. Also, for diesel engines and incinerators used for trucks and other large cars, trains, ships and airplanes, the size of the catalyst container is not very limited, but light oil or heavy oil is put in the fuel tank. The dimensions could be freely determined by changing the design even when putting it in the tank. However, when the catalyst is put into operation immediately, the carbon chains of the hydrocarbon molecules of the fuel cannot be cut in a short time. Accordingly, the present invention has as its object to develop a method for improving fuel efficiency immediately by using a catalyst itself as a liquid catalyst, which is convenient for small vehicles, large vehicles and diesel engines, and improves fuel efficiency. Then, in order not to cause any trouble when replenishing new fuel, a metal chelate catalyst is separately added in a small amount and developed so as to exhibit the same effect as high-octane oil. Further, an exhaust gas purifier is attached to remove NOx, remove Sox, remove CO
₂ and free carbon, purify the air pollutant gas during city driving of exhaust gas and improve the global environment. Then, the generation of CO and CH gas due to the addition of peroxide is reduced. Moreover, to develop a catalyst for N ₂ the Nox produced when burning gasoline and oil fuels, further petroleum fuels 10
% Of water is added to convert Nox into N ₂ gas, and R & D for removing Sox, removing Co ₂ , and removing free carbon is performed. When parapine oil is used for kerosene, the oil smell is severe and free carbon is likely to be generated,
We will research and develop that if it is inexpensive, it can not be used for kerosene of general petroleum stoves, or if the fluorinated point is reduced by the decomposition and division treatment by Aspergillus bacteria, and if ignition is facilitated, an inexpensive fuel can be obtained. In addition, I was convinced that the change in the indication when the bottle was packed was not changed much as a catalyst using the fuel obtained by decomposing and breaking the carbon number of the hydrocarbon by the growth of Aspergillus bacteria, and furthermore, this was actually used as a fuel tank for automobiles. When two-thirds or less of fresh fuel is added and mixed, active bacteria that reduce fuel efficiency remain forever. Then, the persistence of the sterilized fuel is measured.

[Action] Aspergillus is generally used to degrade gasoline and light oil. In the general gasoline and diesel and fuel oil, the carbon chain of the hydrocarbon C ₁₂ -C ₂₀
Are relatively easy to be fragmented, especially C ₁₆ -C
₁₉ things are easy to be divided. In this degrading bacterium, there are relatively many spore-free yeasts with excellent degradation,
Pichia, Hanrenula,
Zygosacchaonyces, Pebaiyom
ycls, Tichosporon, etc. Other degrading bacteria include Micrococcus, Ceribic
ans and Pseudomonas sp. are generally used,

FIG. 6 shows many of the degraded bacteria. Besides that,
Filamentous fungi include Penicillus, Lilasinium, Cladosporium, Cladosporiodes, Aspergillus,
Behacower and Shigeotrichitium are used. As described above, as a catalytic enzyme that breaks and breaks the carbon chain of hydrocarbon molecules of petroleum fuel, aspergillus bacterium is used to continuously preserve the cells in petroleum fuel and use it as a petroleum fuel liquid for catalyst. Must be concentrated so that the newly added petroleum fuel can be rapidly decomposed.
For this purpose, it is necessary to disperse this inoculum to make a conservative active inoculum, and to make it, cultivate concentrated Aspergillus on a zeolite, apatite or carbon substrate by a conventional method and absorb it. When it is dried and stored at least, it is stored in a nap state for about 3 years. Then, the nutrients are dissolved in water, and this is impregnated into a base material such as the above-mentioned germ-containing zeolite to activate the germ-containing state from a nap state, and then put into petroleum fuel for about 2 weeks or more. When the active bacteria are allowed to stand, they proliferate in the petroleum fuel and decompose and break the carbon chain. Therefore, the base material such as the catalytic zeolite is pulled up and the liquid is filtered and the catalytic petroleum fuel is bottled and stored as a seed fungus. For this preservation property, if an air layer is formed on the upper surface of the bottle, the bacteria will continue to propagate automatically and can be stored for 6 to 12 months. This is because there is moisture generated during fermentation. A precipitate is formed when the water has completely disappeared. If a surfactant is added to the purifier bottle so that free carbon is always precipitated, and bubbles are formed in the aqueous liquid, NOx removal and Sox removal can be efficiently decomposed and removed. And if a lump of carbonated lime is put in the bottle, the absorbing action will be high. This inoculum-containing liquid fuel is also used as a fuel for petroleum stoves and marine fuels. (A) Decomposition of petroleum fuel can be performed in the same way up to heavy oil. In the method of decomposing and breaking carbon chains of (B) heavy oil and (C) heavy oil using a seed catalyst solution, a nutrient solution is impregnated into zeolite grains containing concentrated Aspergillus bacteria at a heating temperature of 40 to 50 ° C. A petroleum fuel containing this seed is used as an inoculum catalyst liquid with an emulsifier in a 10% water solution, and a fuel tank of 30 liters to 60 liters is usually installed in a 1000 cc class passenger car. When the mixture is allowed to spread, the inoculum starts to work and continues to grow to about 3 g / l, so while the car is running, it continues to grow, and if the fuel tank is reduced to one-third, the fuel at this point If the tank is filled by adding additional new fuel, the new fuel mixes with the remaining fuel that has multiplied and continues without stopping the multiplication, so that the automobile can continue running. Therefore, if this pattern is repeated, there will be no change in state for about six months. When doing so, fuel efficiency of 10% is improved when traveling in a city. For a 2000cc class passenger car, adding 250cc of inoculum catalyst solution will give 10
Fuel efficiency can be improved by 10% as in the 00cc class. And this also has no change in proliferation for 6 months. One reason for this is that there is enough room for inoculation of inoculum because the traveling distance of the car is short.
The use of 0 l to 20 l is common, during which the inoculum continues to proliferate. However, the inoculum undergoes generational change and disappears in some generations, so the use was limited to 6 months. However, the same effect is exhibited in 12 months in the long term.
This inoculum catalyst using petroleum fuel generally uses kerosene in diesel vehicles, but the carbon chain of the hydrocarbon in the fuel is C
About _{14 ~C 19} performs the division and degradation growing but, C
Since ₁₂ below and C ₂₀ or more cutting and decomposition decreases rapidly, it is also utilized to gradually kerosene fuel so performed in the C ₁₄ or less from the viewpoint of safety. And in the case of heavy oil, C ₂₀
Since the above increase, the use of the mineral radiation zirconium (ZrHf) O ₂ CaCo ₃ promotes the decomposition of C ₂₀ or more. When used in combination with kerosene or gasoline, monazite, tourmaline stone, and uranium stone may be decomposed and separated, regardless of the carbon chain, so there is a danger of explosion at times. (ZrHf) O ₂ CaCO ₃ has a weak 4 microcurie. It is highly effective because it retains radioactivity and is used within legally regulated values. In the case of light oil, the inoculum catalyst also contains 1 Aspergillus on the zeolite base material.
Using a concentrated bacterium containing 200 million strains per gram, a catalyst impregnated with a nutrient solution was first introduced into kerosene fuel and immersed in the fuel.
After standing for a week, a catalyst solution is prepared for the proliferating bacteria, which is bottled and sealed, and 300 cc for a 60-liter kerosene tank for trucks.
When fuel is added, the fuel efficiency should be 1 after 12 hours.
Driving in the city at 0% rate. 2 for long haul trucks
The improvement is 0%, and the cost is extremely reduced. Nox is in the exhaust gas, Sox is 0.3P in 1m ^3. P. In order to contain M, it is necessary to separate and remove carbon dioxide gas. Then, when connecting the conduits to a plurality of polybottles and using a suction pump to exhaust the exhaust gas through the conduits into the plurality of bottles and exhausting the exhaust gas without reducing the exhaust gas pressure, 5 to 5 parts of the cleaning liquid is previously stored in the bottle. When filling the tank with 10% sodium silicate and 3% sodium peroxide 5% soda water liquid and sucking the exhaust gas into the water liquid with a suction pump, de-NOx, de-Sox, de-CO ₂ and de-carbonization are performed. We, N
80% or more of ox and Sox are removed, and 9% of carbon is removed.
5% is removed and 20% of the CO ₂ gas is removed.
Of course, a surfactant is added. Like the gasoline-powered vehicle, this catalyst seed liquid can continue to proliferate and improve fuel efficiency by adding additional kerosene when the fuel gas containing the seed catalyst is reduced to one third of the fuel tank 60 l when fuel gas is reduced. 10 in driving
% And 20% for long-distance driving. The growth of this bacterium is 3 g / l. When this kerosene is added, unlike the case of gasoline, the breeding usually needs to be left overnight, so when the radiating zirconium or hafnium oxide is used in combination with the CaCO ₃ ore catalyst, the decomposition and fragmentation speed is increased. However, when a strong radiative ore such as monazite, tourmaline or uranium is used as a catalyst, its radioactivity becomes 250 to 2500 microcuries, and there is a danger of explosion sometimes, so that there is a problem in its use. The fuel tank of a general heavy-duty truck is a fuel tank 2 containing 60 l.
Since 300 cc are loaded, 300 cc of liquid catalyst and high-octane organometallic catalyst acetylacetone copper titanium and acetylacetone copper zirconium catalyst are used to reduce free carbon and Nox in exhaust gas, as well as high-octane gasoline and high-octane kerosene. Since it is not necessary to use the fuel and a highly ignitable fuel can be obtained, there is an effect of covering the propagation time of the inoculum in kerosene and immediately assisting running. This organometallic chelate catalyst is prepared by dissolving in an alcohol solution 6
Add 25 cc to 0 l kerosene. This also suppresses polluting exhaust gas by adding 25 cc to gasoline vehicles.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below in detail with reference to embodiments with reference to the drawings.

FIG. 1 shows a process diagram of a liquid fuel catalyst, and a tank (1).
Gasoline is fed through a pipe to the reaction tank (3) by pump (5) and gasoline is sent to the pipe (4).
The gasoline liquid is re-introduced into the tank (1), the gasoline liquid in the tank is sent from the pipe (4 ') to the reaction tank (3) by the pump (5), and the gasoline liquid is supplied to the tank (1) and the reaction tank ( Approximately three weeks after being circulated between 3) and fermented and decomposed, a large number of plastic bottles (6) to which are stood on a sloped stair by pipes (4 ").
The siphon tubes (7) and (7 ') of (6') are absorbed by the capillary absorbing fibers and flow down from the lower bottle (n) to the tank (8). The capillary absorption tube of this bottle is provided with a peacock that comes into contact with air, and air is appropriately introduced. In this reaction, when air enters gasoline, the growth of fermentation bacteria increases, but if there is too much contact with air, gasoline will volatilize into the air and the yield will worsen.
It is good to do it three times. The reaction gasoline liquid stored in the tank (8) is pumped (10) to the turntable filling device (9).
Then, the bottle (11) is filled and sealed, transferred to the conveyor (12), labeled, sealed, sealed tightly in the cardboard box (13), and sealed. Next, the cock (16) of the hopper (15) containing the high octane catalyst (14)
Is opened, the catalyst solution (14) is introduced into the tank (17), and the diluted catalyst solution is diluted with gasoline solution.
The diluted catalyst liquid filled bottles (19) and (19 ') loaded on the conveyor (20) with a large number put in 4) are transferred, sealed and sealed with a label, and fitted and sealed in the cardboard box (21). Light oil or heavy oil catalyst is pumped into tank (22) (2
At the 8th minute after the introduction in 3), stop the pump and seal the valve. The light oil or heavy oil (A) in the tank (22) comes into contact with the pipe (25, 25 ') through the reaction tank (26) into the tank (24) by the pump (24) and is circulated to the tank. A hopper tank (27) is connected to the upper part of the reaction tank (26) by a pipe (28), and the nutrient solution is dropped on the apatite zeolite mass (29) in the reaction tank (26) occasionally to make it wet.
A large number of slanted bottles (30) (30) which were allowed to react sufficiently for 2 weeks in this tank (22) and stood on the stairs
The capillary is moved to n) and stored in the tank (31).
Pumps (32) from these tanks (31) to (31 ')
The catalyst solution (A ') after the reaction of light oil or heavy oil is introduced into the turntable filling device (33), filled in the bottle (34), loaded on the conveyor (35), transferred, and sealed and labeled. Then, it is fitted into a cardboard box and packaged and shipped as described above. In this step, since light oil and heavy oil (A) have fluidity, they can be conveyed by a pump at ordinary temperature, but heavy oil (C) is difficult to flow unless it reacts in a heated state. or,
The catalyst (6B) (6 ′) is contained in many of the inclined bottles (6).
B) is inserted so that the molecules are separated and brought into contact.
The catalyst is also contained in the bottle group (B), and the catalyst (C) is contained in the bottle group (30). This step is

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 shows a process chart for producing a liquid gasoline catalyst (A) in (1) to (13), and (14) to (21).
Until steps are catalysts enhancing the octane number, the allowed to completely decompose the incomplete combustion hydrocarbons caused to reduce carbon, a catalyst for converting Nox, a N _2. This catalyst is used in combination with the gasoline catalyst in the steps (1) to (13) to improve the fuel efficiency by 10 to 20%. next

FIG. 1 shows steps (22) to (35) of a catalyst (C) for light oil, paraffin oil, or heavy oil. This catalyst (C) is also used in truck diesel engines, ships, trains, incinerators and other equipment in combination with the high octane catalyst (A). Kerosene for home heating is divided with Aspergillus bacteria,

FIG. 1 shows that the catalyst treated in the step of catalyst (C) has a small amount of carbon, a small amount of petroleum odor, and an improvement in combustion efficiency of 7%.

FIG. 1 shows the mixing of the catalyst (A) and the high-octane catalyst (B) produced in the steps (1) to (13) with 30 l
Approximately 200 cc of the catalyst (A) is put into a 60 liter gasoline tank, and 15 cc of the catalyst (B) is put in the gasoline fuel. Then, the gasoline fuel is started immediately, and the fuel efficiency is improved by 10% to 20%. 20% improvement over long distances. The catalyst (C) to be added to the fuel such as light oil is 250 cc and the high octane catalyst (B) is 15 cc. This improvement in fuel efficiency was also 10 to 20%. Generally, in order to break the carbon chains of hydrocarbons of petroleum fuel, the number of carbon chains C
_{15 to} C ₂₀ are most easily divided, C ₆ is the slowest to be divided, and C _{8 to} C _{14 which} is 1/10 or less is C.
₁₈ is divided by 80% before and after the division of -C _20. Micrococcus, Serifican and Pseudomonas, and Arginosa were used as the bacteria used for this division.

FIG. 2 shows a side view of a bottle containing a gasoline catalyst (A), in a glass or plastics or metal container (1a).

FIG. 1 shows the gasoline catalyst (A) produced in
The middle cap (3a) is fitted to the upper bottle mouth (5a) by fitting cc to 250cc, and screwed with the upper lid (2a).
(4a) is a label.

FIG. 3 shows a side view of a bottle containing a catalyst for adding high-octane fuel, 15 cc of the high-octane catalyst (B) is fitted into the bottle (1b), and a middle cap (3b) is inserted into the bottle mouth (3'b). Then, the upper lid (2b) is screwed and sealed.

FIG. 4 is a side view of a bottle containing a catalyst for adding truck fuel, in which a light oil catalyst (C) is fitted into a 300 cc bottle (1c), and a middle cap (5′c) is fitted into a bottle mouth (5c). And the upper lid (2c) is screwed together. Truck fuel tanks generally hold two. This fuel tank is 60 liters. For this 60 liters of light oil fuel, 300-500 cc of the catalyst (C) is put in the fuel tank, 15 cc of the high octane catalyst (B) is put, and 50 liters of light oil are put in this and mixed immediately. To run. In the case of a general passenger car, the gasoline catalyst (A) is added to a 1000 cc to 2000 cc class passenger car by adding 150 cc to 250 cc, adding 15 cc of the high octane catalyst, and then introducing and mixing 25 l to 60 gasoline liquid. When the passenger car is driven, the new gasoline is introduced and mixed when the gasoline liquid is reduced to one third after driving, and the operation is started. When driving a passenger car and gasoline is consumed and gasoline is reduced to one-third, additional gasoline is introduced and mixed and repeated at all times. If the gasoline exhibits a catalytic action of about 6 months or more, a new catalyst is usually used after 6 months. A gasoline catalyst and a high octane catalyst are added and operated in the first way, and when this is repeated, 10% to 20%
% Fuel savings. In this catalytic method, the fragmentation of the carbon chain of the hydrocarbon by the bacterial cells decreases with the passage of time. Therefore, when applying zirconium and hafnium (ZrHf) O ₂ + radiation-type calcium carbonate to the tank, 7 to 7 times are always required. A 12% improvement in fuel efficiency is obtained. As the high-octane catalyst, an alcohol xylene solution of copper acetylacetone and a titanium chelate compound is used. A chelating solution of palladium acetylacetone, platinum, gold, silver, nickel, cobalt, and chrome is used. When this catalyst is added, free carbon in the exhaust gas is eliminated, and incompletely combusted hydrocarbons burn. However, old cars require a catalytic cracking catalyst for exhaust gas at the exhaust gas combustion outlet, so when a ceramic porous body is impregnated with this acetylacetone metal chelate catalyst in advance and then dried, it is further attached to the exhaust gas pipe. As a result, free carbon and hydrocarbons are further reduced to purify exhaust gas. However, in this exhaust gas, Nox, Sox, and CO ₂ C gas are also present and contaminate the atmosphere as secondary pollution, so it is necessary to remove these.

FIG. 5 is a side view of an exhaust gas purifier, and the exhaust gas reburned by the porous catalyst ceramic is passed through a pipe (1d) by a block pump (2d) to a gas conduit (3).
d) Suction at (4d) and exhaust from the connected conduit (5d). When sucked by the pump (2d), the exhaust gas passes through the conduit (3d), first passes through the bottle (6d), enters the sodium silicate alkaline water solution, purifies and absorbs the exhaust gas, and removes Nox and Sox gases. Neutralize by trapping in the liquid to precipitate a small amount of free carbon.
The CO ₂ gas is absorbed as Na ₂ CO ₃ and partially precipitates silicic acid. Nox removal in this purification bottle (6d)
Is 2 (NaNO ₃ ) + Hmsion-free Sox is 2 (NaNO ₃ )
₂ Sion) + Hmsion and CO ₂ removal is NaHC
O ₄ → Na ₂ CO ₃ . Sodium silicate solution contains Na
₂ CO ₄ is dissolved to make an alkali oxide solution, and sodium silicate is mixed with the solution to make a 5 to 7% aqueous solution. This bottle (6
The exhaust gas purified in d) enters the bottle (6'd) through the conduit (3d) and is absorbed and washed in an alkali silicate solution or molybdenum tungsten soda solution to remove N2.
conduit (4d) after ox, de-Sox, de-CO ₂
Is absorbed by the pump (2d) and purified and exhausted from the conduit (5d). This absorption pump (4d) facilitates washing in water. Free carbon and silicic acid precipitated in the bottle (6d) are sucked from the water in the pot (6d) through a pump (8d) connected to the conduit (7d) and sent to the filter (9d) to remove carbon and other precipitates. The filtrate is filtered through a conduit (7'd), and the filtrate is bottled (6d).
And circulate. Partition plates (10d) (10'd) are fitted into the bottles (6d) (6'd) to prevent dispersion of the precipitate. And the suction port (11
d) and the suction port (11'd) of the bottle (6'd) prevent backflow by the backflow shielding plates (12d) (12'd). When the exhaust gas is washed with such a soap solution and a sodium silicate percarbonate solution or a sodium peroxide solution, 95% or more of the free carbon in the exhaust gas is removed by the water washing, and Nox 8
0%, 80% Sox, and 20-40% of the CO ₂ is removed. Free carbon and silicic acid hydrate precipitated by this water washing are filtered off by a filter, and the filtrate is reduced and returned to a bottle to be reused for water washing. The water solution in the contaminated bottle is purified and recovered by an electrolytic diaphragm method.
When calcium carbonate lump is put in the bottle (6′d) in advance, Nox and Sox are absorbed and separated by the calcium carbonate lump, and the amount of Nox and Sox in the exhaust gas further decreases. The washing water is partially produced as a hydrogen source for the fuel cell by diaphragm electrolysis and contains Nox and S in the contaminated washing liquid.
A method for concentrating and recovering ox salts has also been put to practical use, and the generated hydrogen gas is used as a hydrogen source for a fuel cell. Also, 10
% Water mixed with an emulsifier such as butyl alcohol 10
0cc methanol 100cc paraformaldehyde powder 60g ultra pin 50g pentane 50cc water 100c
were mixed The mixed emulsion to c diesel or heavy fuel oil 1000 cc, when used after well allowed to stir as engine fuel in Diesel, Nox is harmless as N _2, Sox
Reacts with ultra-pins and is desulfurized and purified.

The cells in FIG. 1 are cultured according to a conventional method, absorbed into zeolite small crushed stones, concentrated and adsorbed to 200 million strains of Aspergillus per 1 g of zeolite, and dried and placed in a porous bag. In addition, put into a petroleum fuel and packaged in a porous mesh, and separately and simultaneously as low radiating minerals, low-permeability magnet powder such as perconium hafnium ore, enenite, uranium stone, monazite, etc. What is sealed in the pack is injected into petroleum fuel to break the carbon chain of hydrocarbon molecules of petroleum. In the case of Aspergillus alone, it takes three weeks to break the carbon chain.
If both are used together, it will be completed in 1-2 weeks. Propagation of Aspergillus in this petroleum requires a cell yield of 1
At 00%, an enzyme amount of 6, 14 (mcl / 100 g) is required. If the air amount is 3.66, the cell yield is 130%, and if the air amount is 2.58, the yield is 150%. As the required amount of the enzyme decreases, the yield of bacterial cells increases. The time of this generation change is 4 to 6 hours. In addition, in order to cut off petroleum fuel without moisture, the splitting speed becomes faster when there is more water, but at least the water which is dispersed in petroleum fuel in fine particles is A good result can be obtained if a small amount of the particles is dispersed and attached to petroleum molecules. The fermentation is performed at a fermentation concentration of about 18 to 30 ° C. After the culture liquid is impregnated with the bacterium containing the zeolite mass, the resultant is immersed in a petroleum liquid and allowed to stand. The cell concentration of 1 g becomes 33 g / l or more in 6 hours. The required amount of this enzyme is 7.14CH ₂ + 6.14O ₂ = 3.92C 65H
1.94O + 3.22CO ₂ + 3.89H ₂ O Accordingly, as can be seen from this equation, carbon dioxide and water are formed in the oil separation, and this water is used for the subsequent propagation.
The heat of combustion of this light oil is 1000-1140 kcal / 1
00 g. The pH in the culture is 6 to 7, and the number of cells increases when the pH is acidic.

FIG. 6 is a list of types of cells that decompose and break hydrocarbon carbon chains of petroleum fuel. Next, an example of the formulation of a nutrient necessary for growing Aspergillus is shown below. A solution obtained by heating this solution and dissolving the solution was placed in a porous case in which 30 g of concentrated Aspergillus zeolite was sealed in a tipak, immersed in a porous casing, immediately withdrawn, and put into petroleum fuel. When allowed to stand, the concentrated bacteria are activated, leave the zeolite and move into the petroleum fuel, and are allowed to stand for two to three weeks due to the growth of the bacteria to break and break the hydrocarbon carbon chains of the petroleum fuel. After 2 to 3 weeks, the concentrated zeolite pack is withdrawn from the liquid, drained, and incinerated. In general, the working unit of Aspergillus bacillus in a 1000 cc gasoline liquid is 30 g, and there are 200 million strains per gram. Accordingly, the cracking and splitting is performed at a rate of 6 billion to 10 billion shares of 1000 cc gasoline. In the case of 60 l, 100 g of a germ-containing zeolite catalyst is used, but in the case of light oil, it is immersed in light oil for 3 weeks to decompose and break the carbon chain of hydrocarbons, then the catalyst is pulled up and the light oil is filtered and bottled. . Since the used catalyst contains residual bacteria, it is charged into a new petroleum fuel gas oil, and 100 g of a new sterilized zeolite catalyst is further added to the waste catalyst.
The bacteria are multiplied by putting them in a 0-liter tank. And the old catalyst is incinerated when the remaining bacteria are gone. The emulsified liquid is mixed, and the bacteria-containing zeolite catalyst impregnated with the nutrient is immersed and circulated to grow the bacteria for 4 weeks. 500 cc per 100 l of this heavy oil as seed oil is added to (B) heavy oil and (C) heavy oil. For this purpose, an activated inoculum can be obtained by using an Aspergillus bacterium which is resistant to 100 ° C. for this growth.

FIG. 7 shows the characteristics of gasoline gas oil, which is impregnated with concentrated Aspergillus bacteria of gas oil and gasoline and then dried,
Further, the nutrient solution is impregnated, put in light oil and gasoline, immersed in the gasoline, and allowed to stand for about 3 weeks. The change characteristic of the fuel efficiency when additional fuel was added when the fuel consumption reached 1/3 was shown. (A) is gasoline,
(B) is light oil. In this running, 15 cc of a metal organic chelate compound of nickel, zirconium and titanium copper dissolved in alcohol was added to obtain a high octane value. From these results, the fuel efficiency of the first gasoline gasoline catalyst containing 250 cc of gasoline catalyst and 30 liters of gasoline, and the fuel efficiency after 6 months, including the case of light oil, are the results of the generation change of bacteria in 4 to 6 hours. descend.
If replenishment of new fuel is performed under favorable conditions, efficiency can be sufficiently improved for one year.

FIG. 8 shows the characteristics of storage of a bottled fuel catalyst by 10
There are no abnormalities in the month. When the cell weight is 3 g / l or more, a precipitate is formed, but if there is a small amount of nutrients and water, the active bacteria are retained for a long time. In the case of light oil, the cell yield is 3 to 3.3 in 4 to 6 hours of generation change time, and the required amount of enzyme is 0.6 to 0.9 g / l hour. The bottled fuel increases the cell yield when the amount of 1 mol / 100 g of Aspergillus bacteria added is small. When (ZrHf) O ₂ (a. Co ₄ ) is added to this sterilized catalyst fuel, 5 to 7
%, But on average 12-15% is a general improvement in fuel economy. In the exhaust gas, CO gas was 2.10 g (km), 3 ql, and CH gas was 0.1 g.
The value of 40 g / km is the regulated value of 2002
To reduce to 3 and 0.12 g / km requires the addition of a benzoyl peroxide solution. When this is added, it decreases to 0.55 and 0.09 g / km. Further, the exhaust gas is passed through a porous tube of silicon manganese ceramics, and CO gas and CH gas are reburned and removed through a chrome oxide or manganese dioxide ceramics porous tube. However, this CH represents a hydrocarbon.

In the process diagram of FIG. 1, the petroleum fuel liquid in the tank (1) passed through the catalyst tank (3) containing the germ-containing zeolite and circulated the petroleum fuel when the contact with air increased. Proliferation increases, but siphon bottles (6) (6 ')
The petroleum fuel liquid flowing down to the tank often comes into contact with the air, so the multiplication is completed in about 2 weeks with only the tank (1). Multiplication is completed in one week. The germ-containing zeolite solution is exchanged at a rate of 60 l 100 g. The high-octane catalyst of this organometallic chelate compound is 2 (CH ₃ C
OCH ₂ COH ₃ CU and 4 (CH ₃ COCH ₂ COC)
H ₃ ) Ti, 4 (CH ₃ COCH ₃ COH ₃ ) ZrH
f, 2 (CH ₃ COCH ₂ COH ₃ ) Ni is used. In this catalyst, copper promotes combustion by absorbing hydrogen and Ti
And (ZrHf) O ₂ decompose water to produce oxygen and hydrogen,
Suppress the generation of Nox. When 15 cc of the alcohol solution of this catalyst is added to petroleum fuel, the metal concentration of CU, Ti or ZrHf is used at 0.0001 to 0.01%. In general, it takes 3 weeks at 25 ° C. for the bacterial cells to reach 3 g / l by putting the germ-containing zeolite catalyst contained in the solid porous container into the fuel tank of the automobile. The bacteria had to be left for 3 weeks to grow to an appropriate concentration. However, when a liquid growing catalyst was used, the fuel efficiency could be improved by 10% or more even if the vehicle was run immediately.
The catalyst containing solid concentrated bacteria has a disadvantage that the efficiency is not improved for 3 weeks. The size of the inlet of the tank differs depending on the manufacturer, and it is inconvenient because the size may not be able to charge the solid catalyst. However, the disadvantage is solved with the liquid catalyst. In terms of preservation, when the bottle is brought into contact with air, the dispersion is stable and the dispersion is small. And
Because the cost is low, it is easy to spread to the general public. In addition, when the decomposed and divided petroleum fuel is burned in an automobile internal combustion engine, CO
Is 0.67 g / km, CH is about 0.17 g / km, and Nox is about 0.10. In order to further reduce CO and CH gas, 100 g of benzoyl peroxide was dissolved in 400 cc of alcohol, then 15 cc to 20 cc of a second catalyst containing 150 cc of xylene was added, and acetylacetone titanium chelate was added to the high octane catalyst. Then, the CO gas can be reduced to 0.5 or less, and the hydrocarbon gas can be reduced to 0.09. When an acetylacetone titanium catalyst is added, CO becomes CO _{2 and} hydrocarbons are easily converted to CO ₂ .

As a method for increasing the combustion efficiency of general petroleum fuel, a relatively high radiating catalyst such as monazite, tourmaline and uranium is immersed in the fuel to decompose the hydrocarbon carbon chain. Although there is a method of dividing, it is difficult to decompose unless the radiating property is high, so there is a disadvantage that decomposition and decomposing is difficult to be performed in a short time with 4 microcuries of radiation within legal regulations,
Since the carbon chain of the hydrocarbon oil fuel is also decomposed cutting takes place intended C ₉ less explosive is strong, particularly in monazite and tourmaline ore and uranium ore using others of 2500-250 microcuries There was a problem with safety. Disruption of the number of carbon chains by the cells of the present invention is mainly caused by C
Since at the range of ₉ -C ₂₀ decomposition divided by bacteria growth is performed, degradation fragmentation of the carbon chain number of C ₈ or less hydrocarbons with explosive is safe because no. However, since the carbon chain number by the bacteria growth C ₂₂ or more the degradation division is delayed, low Radjieshon property as a countermeasure (ZrH
The _f) O 2 CaCO ₃ Mineral catalyst sealed in 10g of tea packs per 60l, but degradation division is 2-7% to _{C 20} or more carbon chains when combined with crimp the tank crimping glue as a sealing agent Fuel efficiency improvement to a certain degree is obtained. When an alcohol solution of acetylacetone copper-titanium or zirconium chelate compound is added to the fermented liquid fuel, a high octane effect is exhibited if the metal content is at least 1 / million. Some features are also used. Therefore, when these three are combined, the fuel efficiency is always 10
% Or more can be stably maintained. Then, free carbon, Nox, and Sox in the exhaust gas are partially adsorbed by the carbon and separated and removed. However, in a city where many used vehicles are used, it is necessary to further remove NOx, remove Sox, remove CO ₂ , and remove carbon in the exhaust gas. Therefore, it is necessary to wash the exhaust gas with a purifier. Since the air resistance further increases in the washing with the liquid, it is necessary to prevent the fuel efficiency from decreasing and returning. If the exhaust gas is sucked using a suction pump and washed with purified water, furthermore,
Since it is possible to remove NOx, remove Sox, remove CO ₂ , and remove carbon, air pollution can be further reduced. The carbon monoxide CO of the exhaust gas of the petroleum fuel which has been cracked and divided is 0.5 g / km, the hydrocarbon is 0.09 g / km and the NOx is 0.1.
04 g / km particles (carbon) are 0.008 g / km. From this result, the government regulation value of 0.63 g CO / km hydrocarbon 0.12 g / km Nox 0.28 mm / km carbon 0.052 was significantly reduced, and when this was washed with the water solution of the purifier, NOx was reduced to 0.1. 001 g / km or less, Sox becomes 0.001 g / km or less, and hydrocarbons become 0.09 m / km. When the exhaust gas is catalytically decomposed at 600 ° C. to 400 ° C. with a metal oxide catalyst, 0.03 g / km and CO become 0.02 g / km or less. In the case of trucks as well, a 30% reduction is achieved. Aspergillus or other petroleum-degrading bacteria enriched in petroleum fuel adsorbed and impregnated on zeolite particles as a catalyst,
This is allowed to stand in petroleum fuel for 2 to 5 weeks to ferment and grow in petroleum fuel, and the liquid obtained by decomposing and breaking down the hydrocarbon chain of petroleum fuel by the growth of bacteria is filtered and the petroleum fuel containing active bacteria is filtered. As a liquid catalyst, a small amount of bottled or canned material was put into a fuel tank, and a liquid fuel using an organometal chelate as a high octane material as a high octane fuel was fitted into the fuel tank, and this was mixed with petroleum fuel and mixed. When the fuel is used as an automobile fuel, the fuel efficiency can be improved even if the vehicle is driven immediately after mixing, and the same effect as that of a known high-octane fuel can be obtained. During driving, the decomposition and fragmentation of the carbon chains of the fuel hydrocarbons are continuously performed. Even if it takes 4 to 6 hours to change the generation of bacteria, the overall balance will be the same, and the generation change will be 6 to 6 hours. It lasts for up to 12 months, but after 6 months, the temperature and the amount of fungi can vary, so practically 6 months is appropriate. In addition, this sterilized petroleum fuel catalyst, that is, a seed petroleum fuel catalyst, is added in an amount corresponding to 0.15% in which 150 cc is added to 30 liters of the fuel tank of a 1000 cc passenger car. 2000
Since the gasoline tank capacity of a 2500 cc class car is a 60 liter tank, if 250 cc of 60 l of a sterilized petroleum fuel catalyst is mixed, the fuel economy can be reduced by 10 to 20%. Therefore, the efficiency increases as the capacity increases. However, in the truck diesel, 60
Since two 1-liter tanks are used, the amount of the catalyst containing light oil is 500 cc to 1000 cc. Even if bottled, the storage period of 6 to 12 months is maintained and fuel efficiency is 10 to 20%
As a result, the carrier can streamline production and save national resources. Oil stoves and ships,
In addition to trains and airplanes, thermal power generation, diesel engines at factories, and incinerators have also improved fuel efficiency by adding seed-containing fuel, resulting in foul odors, free carbon, de-NOx, de-Sox, and de-C.
O ₂ is performed and the fuel consumption is reduced 10% from the top of the overall petroleum fuel with allowed reduce air pollution, a significant savings when viewed overall. In addition, this petroleum fuel is used as a power source for machinery in ships, train airplanes, thermal power plants and factories, and is added to petroleum fuel in incinerators and oil stoves. As a result, it is possible to increase the fuel efficiency by 10% or more, thereby saving petroleum resources and contributing to the purification of air pollution.

[Brief description of the drawings]

FIG. 1 is a process diagram of a liquid fuel catalyst.

Fig. 2 Side view of a bottle containing gasoline catalyst

FIG. 3 is a side view of a bottle containing a catalyst for adding high-octane fuel.

FIG. 4 is a side view of a bottle containing a catalyst for adding truck fuel.

FIG. 5 is a side view of an exhaust gas purifier.

FIG. 6 is a list of types of cells that degrade and break the carbon chains of light oil and gasoline.

FIG. 7: Change characteristics of fuel efficiency

FIG. 8: Storage characteristics of bottled fuel catalyst

Claims (1)

[Claims] As a catalyst, a petroleum fuel impregnated with zeolite granules and impregnated with Aspergillus pre-concentrated on zeolite particles and dried is immersed in a nutrient solution and allowed to stand for 2 to 3 weeks, and then carbonized. Petroleum containing active microbes that breaks down and breaks down the carbon chain of hydrogen, immerses it in a liquid using a radiation catalyst and a metal chelate liquid peroxide as needed, and breaks up the carbon chain more quickly. Use of fuel as fuel for automobiles, trains, airplanes, ships, and incinerators to purify petroleum fuel containing active bacteria and exhaust gas to improve fuel efficiency.