JP2001010930A - Non-aerosol type foam cosmetic for hair - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a non-aerosol type foam cosmetic for hair that has excellent foaming properties with creamy touch of very fine foam and gives the hair smoothness after being applied. SOLUTION: The objective non-aerosol type foam cosmetic for hair is prepared by filling a foam-spraying vessel with a composition comprising a hydroxy group-bearing compound with an IOB value of 1.5-2.25, for example, polyoxypropylene glyceryl ether, a silicone oil, and a surfactant.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

TECHNICAL FIELD The present invention relates to a foam hair cosmetic. In more detail, it has a good feel to the hair, has excellent foaming properties, and the foam is fine and creamy,
The present invention relates to a non-aerosol foam hair cosmetic composition, characterized in that it has good smoothness after being applied to hair.

[0002]

2. Description of the Related Art Conventionally, aerosol foam hair cosmetics using a propellant have been widely used for the purpose of setting hair and giving the hair a smooth feel.

A liquefied petroleum gas is mainly used as a propellant for use in an aerosol for filling foam hair cosmetics. This liquefied petroleum gas emits volatile organic compounds into the atmosphere, causing environmental pollution. In addition, it is flammable under high pressure and is dangerous for use. In recent years, in Europe and the United States, hair cosmetics using containers such as pumps that do not use a propellant have been increasing, and resource saving and recycling of containers have been active. For this reason, non-aerosol foam hair cosmetics which do not use a propellant have been developed.

[0004]

However, the foam quality of non-aerosol foam hair cosmetics is generally rough because no propellant is used.
If a surfactant is added in an amount larger than the usual amount in the aerosol-type foamed hair cosmetic, there is a problem that stickiness occurs and the feel becomes poor.

[0005] In addition, when silicone oil is added to improve the feel, there is a problem that the foam quality of the foam discharged from the container deteriorates due to the defoaming action of the silicone oil.

[0006] In view of the above circumstances, the present inventor has proposed a non-aerosol foam hair cosmetic composition which does not use a propellant.
As a result of intensive studies to solve the above-mentioned problems, a composition obtained by blending a compound having an IOB value of 1.5 to 2.25 and having an OH group, a silicone oil and a surfactant was prepared as a non-aerosol type. Filling the foam discharge container, it was found that a foamy hair cosmetic composition having excellent foaming properties, a fine foam texture, a creamy appearance, and a good smoothness after application to the hair was obtained, and the present invention was completed. Reached.

An object of the present invention is to provide a non-aerosol foam hair cosmetic composition which is excellent in foaming properties, has a fine foam texture, is creamy, and has excellent smoothness after being applied to hair.

[0008]

That is, the present invention provides an I
A non-aerosol type foam, characterized in that a foam discharge container is filled with a composition having a compound having an OB value of 1.5 to 2.25 and having an OH group, a silicone oil and a surfactant. It is intended to provide a hair-like cosmetic.

The present invention also provides the above non-aerosol foam hair cosmetic, wherein the silicone oil is contained in an amount of 0.3 to 50% by weight based on the total amount of the composition. is there.

Further, according to the present invention, the IOB value is 1.5
The non-aerosol foam hair cosmetic according to the above, wherein the compound having a OH group content of at least 2.25 and not more than 0.5 is contained in the composition in an amount of 0.5 to 30% by weight. is there.

[0011] In the present invention, the compound having an IOB value of 1.5 to 2.25 and having an OH group is a polyoxyalkylene (poly) glyceryl ether. It is intended to provide a foamy hair cosmetic.

Further, the present invention provides the above non-aerosol foam hair cosmetic, wherein the polyoxyalkylene (poly) glyceryl ether is polyoxypropylene glyceryl ether or polyoxypropylene diglyceryl ether. To provide.

Further, the present invention provides the above non-aerosol foam hair cosmetic, wherein the silicone oil is methylphenylpolysiloxane.

[0014]

DESCRIPTION OF THE PREFERRED EMBODIMENTS The configuration of the present invention will be described below in detail.

The IOB value used in the present invention is 1.5 or more.
The compound having 25 or less and having an OH group is a compound having a moisturizing action, and diols include 3-methyl 1,
Preferred are 3-butanediol, 1,2-pentanediol, dipropylene glycol, hexylene glycol, and the like. In the case of compounds having a polyalkylene oxide chain, polyoxyalkylene (poly) glyceryl ether is preferred. Glyceryl ether or polyoxypropylene diglyceryl ether is mentioned.

In the foamy hair cosmetic composition of the present invention, this I
The compound having an OB value of 1.5 or more and 2.25 or less and having an OH group is preferably contained in the composition in an amount of from 0.5% by weight to 30% by weight. A fine creamy and soft foam is obtained.

The silicone oil used in the present invention is not particularly limited, and all silicone derivatives such as dimethylpolysiloxane and methylphenylpolysiloxane can be used. However, in terms of smoothness after being applied to hair, methyl silicone is preferred. Phenylpolysiloxane is particularly preferred.

The amount of the silicone oil is usually 0.3 to 50% by weight based on the total amount of the composition in terms of imparting smoothness.
It is.

The surfactant used in the present invention is not particularly limited as long as it can constitute a foamy hair cosmetic, but a cationic surfactant or a nonionic surfactant is preferred.

Examples of the cationic surfactant include alkyltrimethylammonium salts (eg, stearyltrimethylammonium chloride, lauryltrimethylammonium chloride); and alkylpyridinium salts (eg,
Cetylpyridinium chloride, etc.); distearyldimethylammonium dialkyldimethylammonium chloride; poly (N, N'-dimethyl-3,5-methylenepiperidinium chloride);
Alkyl quaternary ammonium salts; alkyl dimethyl benzyl ammonium salts; alkyl isoquinolinium salts; dialkyl morphonium salts; POE-alkylamines; alkyl amine salts; polyamine fatty acid derivatives; amyl alcohol fatty acid derivatives; benzalkonium chloride; benzethonium chloride And the like.

Examples of the lipophilic nonionic surfactant include sorbitan fatty acid esters (eg, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquiole) Ethates, sorbitan trioleate, diglycerol penta-2-ethylhexyl sorbitan, diglycerol sorbitan tetra-2-ethylhexylate, and the like; glycerin polyglycerin fatty acids (for example, glycerin mono-cottonseed oil fatty acid, glycerin monoerucate, glycerin sesquioleate, Glycerin monostearate, α,
α′-oleic acid glycerol pyroglutamate, glyceryl monostearate malic acid, etc.); propylene glycol fatty acid esters (eg, propylene glycol monostearate); hydrogenated castor oil derivatives; glycerin alkyl ether;

Examples of the hydrophilic nonionic surfactant include POE-sorbitan fatty acid esters (eg, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-sorbitan monooleate, etc.). POE sorbit fatty acid esters (eg, POE-sorbit monolaurate, POE-sorbit monooleate, POE-sorbit pentaoleate, POE-sorbit monostearate, etc.); POE-glycerin fatty acid esters (eg, POE -Glycerin monostearate, POE-glycerin monoisostearate, PO
POE-monooleate such as E-glycerin triisostearate, etc.); POE-fatty acid esters (eg, POE-distearate, POE-monodioleate, ethylene glycol distearate, etc.); POE-alkyl ethers (eg, POE-lauryl ether) , POE-oleyl ether, PO
E-stearyl ether, POE-behenyl ether, POE-2-
Octyldodecyl ether, POE-cholestanol ether, etc.); Pluronic type (eg, Pluronic etc.); POE.POP-alkyl ethers (eg, POE.PO)
P-cetyl ether, POE / POP-2-decyltetradecyl ether, POE / POP-monobutyl ether, POE / POP-hydrogenated lanolin, POE / POP-glycerin ether, etc.); Tetra P
OE.tetra-POP-ethylenediamine condensates (eg, tetronic); POE-castor oil-hardened castor oil derivatives (eg, POE-castor oil, POE-hardened castor oil, POE-hardened castor oil monoisostearate, POE) -Hydrogenated castor oil triisostearate, POE-hydrogenated castor oil monopyroglutamic acid monoisostearic acid diester, POE-hydrogenated castor oil maleic acid, etc.); POE-beeswax lanolin derivative (eg, POE-sorbit beeswax, etc.); alkanolamide (For example, coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc.); POE-propylene glycol fatty acid ester; PO
E-alkylamine; POE-fatty acid amide; sucrose fatty acid ester; alkylethoxydimethylamine oxide; trioleyl phosphoric acid and the like.

The amount of the surfactant is usually 0.1 to 3% by weight based on the total amount of the composition, and is appropriately determined according to the formulation. If the amount exceeds 3% by weight, stickiness may occur.

[0024] In addition to the above-mentioned essential components, the composition constituting the foamy hair cosmetic of the present invention may further comprise, if necessary, a quantitative and qualitative range that does not impair the effects of the present invention. Liquid paraffin, squalane, lanolin derivatives, higher alcohols, various ester oils, avocado oil, palm oil, tallow,
Jojoba oil, polyalkylene glycol polyether and its carboxylic acid oligoester compounds, oils such as terpene hydrocarbon oils, humectants such as hyaluronic acid, chondroitin sulfate, pyrrolidone carboxylate, ultraviolet absorbers, ultraviolet scattering agents, acrylics Resins, resins such as polyvinylpyrrolidone, proteins or proteolysates such as soy protein, gelatin, collagen, silk fibroin, elastin,
Preservatives such as ethylparaben and butylparaben, activators such as various amino acids, biotin, and pantothenic acid derivatives;
Oryzanol, dextran sodium sulfate, vitamin E derivatives, blood circulation promoters such as nicotinic acid derivatives, sulfur, antiseborrheic agents such as thianthol, ethanol, isopropanol, diluents such as tetrachlorodifluoroethane, thickeners such as carboxyvinyl polymer, A drug, a fragrance, a coloring agent, and the like are appropriately compounded and manufactured by a conventional method.

The composition comprising the above components is filled in a foam discharge container not using a propellant to obtain the non-aerosol foam hair cosmetic of the present invention. The foam discharge container filled with the foamy hair cosmetic is a foam discharge container other than an aerosol can using a propellant, and is usually used as a pump former container. As the mesh, for example, “2
Pump former containers such as "00 mesh", "150 mesh", and "80 mesh", and commercially available products can be used. The fineness of the mesh is appropriately determined by the prescription, but a fineness close to 200 mesh gives a fine foam close to that of a conventional aerosol foam hair cosmetic (Mousse: registered trademark).

[0026]

The present invention will now be described by way of Examples and Comparative Examples.
This will be described more specifically. The present invention is not limited by these. The compounding amount represents weight%.

"Examples 1 to 6, Comparative Examples 1 and 2""Table1"
The compositions for hair cosmetics of Examples 1 to 6 and Comparative Examples 1 and 2 shown in Table 1 were manufactured and filled into a 150-mesh pump former container, and the feel, gloss, and foam quality were evaluated by the following methods. The results are shown in Table 1 together.

Evaluation method 30 cm / 5 g of Japanese female hazy hair is bundled, and the foamy hair cosmetics of Examples and Comparative Examples are discharged in a foamy form. After about 5 g is applied to the hair, the hair is blown with a comb. An evaluation was performed. <Feeling> 総 合: Very good overall feeling, fine foam, creamy and smooth. ：: Overall good feeling, fine foam, creamy and smooth. Δ: Feel not so good overall. ×: Very bad feeling overall. <Glossy> A: Very glossy. ：: There is gloss. Δ: There is a little gloss. ×: There is no gloss at all. <Foam quality> ：: Very fine. ：: Fine. Δ: Some bubbles are observed. ×: no foam.

[0029]

[Table 1]

According to the results shown in Table 1, a composition containing a compound having an IOB value of 1.5 or more and 2.25 or less and having an OH group, a silicone oil and a surfactant was prepared in a non-aerosol container. It can be seen that even when filled, the foamed hair cosmetic composition is excellent in feel, gloss and foam quality.

[0031]

According to the present invention, it is possible to provide a non-aerosol type foam cosmetic which is excellent in foaming properties, has a fine foam texture, is creamy, and has good smoothness after being applied to hair.

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Claims (6)

[Claims] 1. A foam discharge container is filled with a composition having a compound having an IOB value of 1.5 or more and 2.25 or less and having an OH group, a silicone oil and a surfactant. Non-aerosol foam hair cosmetic. 2. The non-aerosol foam hair cosmetic according to claim 1, wherein the silicone oil is contained in an amount of 0.3 to 50% by weight based on the total amount of the composition. 3. The composition according to claim 1, wherein the compound having an IOB value of 1.5 to 2.25 and having an OH group is contained in an amount of 0.5 to 30% by weight based on the total amount of the composition. Or the non-aerosol foam hair cosmetic according to 2. 4. The compound according to claim 1, wherein said compound having an IOB value of 1.5 or more and 2.25 or less and having an OH group is polyoxyalkylene (poly) glyceryl ether. Non-aerosol foam hair cosmetic. 5. The non-aerosol foam hair cosmetic according to claim 4, wherein the polyoxyalkylene (poly) glyceryl ether is polyoxypropylene glyceryl ether or polyoxypropylene diglyceryl ether. 6. The method according to claim 1, wherein said silicone oil is methylphenylpolysiloxane.
The non-aerosol foam hair cosmetic according to 3, 4 or 5.