JP2001010864A - Highly heat conductive silicon nitride-based sintered compact - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a sintered compact excellent in mechanical strength and having a high heat conductivity without anisotropy in the direction of heat conduction by including silicon nitride as a principal component, including aluminum and oxygen in specific values or below of contents as impurities and respectively regulating the heat conductivity and four-point bending strength at normal temperatures to specified values or above. SOLUTION: This silicon nitride-based sintered compact is obtained by regulating the content of aluminum as an impurity element therein to <=0.2 wt.% and the content of oxygen as an impurity element therein to <=3.0 wt.% and further regulating the heat conductivity to >=70 W/(m.K) and the four-point bending strength to >=600 Pa. The amount of carbon in the sintered compact is preferably <=2.0 wt.% and the total amount of magnesium and a group 3a element of the periodic table contained therein is preferably 0.6-4.0 wt.% The weight ratio (MgO/RExOy) thereof is preferably 1-70. The ratio of β-type silicon nitride grains having >=5 μm minor axis diameter in the sintered compact is preferably <=10 vol.%. When the sintered compact is used as a substrate for a semiconductor element, the thermal shock resistance and heat cycle resistance are improved to thereby provide a substrate material excellent in durability and reliability.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a silicon nitride sintered body having a high strength and a high thermal conductivity. The present invention relates to a member for electronic parts such as a semiconductor substrate, a heat sink for a heating element, and a general machine. It is a silicon nitride sintered body suitable as a structural member such as an appliance member, a molten metal member, a heat engine member, and the like.

[0002]

2. Description of the Related Art Silicon nitride sintered bodies have high-temperature strength characteristics,
In addition to mechanical properties such as abrasion resistance, heat resistance, low thermal expansion,
Since it is excellent in thermal shock resistance and corrosion resistance to metals, it has been conventionally used for various structural members such as members for gas turbines, members for engines, mechanical members for steelmaking, and members for melting molten metal. In addition, it is used as an electrical insulating material by utilizing high insulating properties.

[0003] In recent years, with the development of semiconductor elements having a large amount of heat, such as high-frequency transistors and power ICs, the demand for ceramic substrates having a high thermal conductivity so as to obtain heat dissipation characteristics in addition to electrical insulation has increased. are doing. As such a ceramic substrate, an aluminum nitride substrate is used. However, mechanical strength, fracture toughness, etc. are low, and cracks may occur due to tightening during the assembly process of the substrate unit, or a silicon (Si) semiconductor element may be used. In the mounted circuit board, since the thermal expansion difference between the Si metal and the board is large, there is a problem that cracks and cracks are caused in the aluminum nitride board due to thermal cycling and mounting reliability is reduced.

[0004] Therefore, a substrate made of a high thermal conductive silicon nitride sintered body having a lower thermal conductivity than an aluminum nitride substrate but having a thermal expansion coefficient close to that of Si and having excellent mechanical strength, fracture toughness, and thermal fatigue resistance is used. Attention has been paid to various proposals.

For example, Japanese Patent Application Laid-Open No. 4-175268 discloses that
Aluminum (Al) and oxygen (O), which are substantially composed of silicon nitride and contained as impurities, are both 3.5% by weight or less, have a density of 3.15 g / cm3 or more, and have a power of 40 W / (m · K) A silicon nitride sintered body having a thermal conductivity of not less than K is described.

Japanese Patent Application Laid-Open No. Hei 9-30866 discloses 85
-99% by weight of β-type silicon nitride grains and the remainder consisting of an oxide or oxynitride grain boundary phase, and Mg, C in the grain boundary phase.
a, Sr, Ba, Y, La, Ce, Pr, Nd, Sm,
One or more metal elements selected from Gd, Dy, Ho, Er, and Yb are contained in an amount of 0.5 to 10% by weight, and the content of Al atoms in the grain boundary phase is 1% by weight or less. Yes, the porosity is 5% or less, and the proportion of β-type silicon nitride grains having a minor axis diameter of 5 μm or more is 10 to 60% by volume.
Is described.

[0007] Proceedings of the 1st Annual Meeting of the Ceramic Society of Japan 1996, 1G11 and 1G12;
No. 4842, columnar silicon nitride particles or whiskers are added in advance to the raw material powder, and a molded body in which the particles are two-dimensionally oriented is obtained by using a doctor blade method or an extrusion molding method, and then fired. This describes a silicon nitride sintered body in which heat conduction is imparted with anisotropy to increase heat conductivity in a specific direction.

[0008]

SUMMARY OF THE INVENTION The above-mentioned Japanese Patent Laid-Open No. 4-17 / 1994
In Japanese Patent No. 5268, a thermal conductivity of 40 W / (m · K) or more is obtained, but there is a problem that a material having further improved thermal conductivity and excellent mechanical strength is desired. Also, JP-A-9-30866 and JP-A-10-19
No. 4842, etc., in order to obtain huge columnar particles in a silicon nitride sintered body, a seed crystal or a whisker serving as a growth nucleus is added in advance, and under a nitrogen atmosphere of 2,000 ° C. or more and 100 atm or more. High temperature and high pressure firing is essential. Therefore, there is a problem that special high-temperature and high-pressure equipment such as a hot press or HIP is required, and an economic burden is imposed. Further, since a molding process for obtaining a molded body in which silicon nitride particles are oriented is complicated, there is a problem that productivity and mass productivity are significantly reduced.

SUMMARY OF THE INVENTION The present invention has been made in view of the above problems, and has high cost and high temperature and high pressure at a temperature of 2,000 ° C. or more and 100 atm or more without adding seed crystals or whiskers. It is an object of the present invention to provide a high thermal conductive silicon nitride sintered body which does not require a high heat resistance, has excellent mechanical strength, does not have anisotropy in the direction of heat conduction, and has further improved thermal conductivity.

[0010]

Means for Solving the Problems To achieve the above object, the present inventor has proposed aluminum (Al) and oxygen (O) which are impurity elements in a silicon nitride sintered body and cause a decrease in thermal conductivity. 70W / by carefully selecting the content of
It has been found that a thermal conductivity of (m · K) or more is stably obtained, and sufficient bending strength can be obtained by specifying the properties of the silicon nitride particles in the sintered body. Further, it was confirmed that the content of carbon (C) had an effect on the thermal conductivity, and by optimizing the C content, the sintering aid was further changed to MgO.
As a base, sinterability is improved, and a group 3a element of the periodic table (R
It has been found that the thermal conductivity can be further increased by including the oxide of E) in a specific range, and the present invention has been accomplished.

That is, the high thermal conductive silicon nitride sintered body of the present invention contains silicon nitride as a main component, and contains aluminum (Al) of 0.2 wt% or less and oxygen (O) of 3.0 wt% or less as impurities. The thermal conductivity at room temperature is 7
0W / (m · K) or more, 6-point bending strength at room temperature is 6
It is characterized by being at least 00 MPa.

The high thermal conductive silicon nitride sintered body of the present invention contains silicon nitride as a main component, aluminum (Al) as an impurity of 0.1 wt% or less, and oxygen (O) of 2.5 wt%.
wt% or less, thermal conductivity at room temperature is 100W
/ (M · K) or more, the four-point bending strength at room temperature is 600
Mpa or more.

Further, the high thermal conductive silicon nitride sintered body of the present invention contains silicon nitride as a main component, and contains 0.05 wt% or less of aluminum (Al) and 2.2 wt% or less of oxygen (O) as impurities. The thermal conductivity at room temperature is 1
The four-point bending strength at room temperature is 50 W / (m · K) or more and 600 MPa or more.

It is desirable that the high thermal conductive silicon nitride sintered body of the present invention contains carbon (C) in an amount of 2.0 wt% or less. Further, the ratio of the β-type silicon nitride particles having a minor axis diameter of 5 μm or more in the high thermal conductive silicon nitride-based sintered body is less than 10% by volume, and the aspect ratio of the β-type silicon nitride particles in the sintered body Is desirably 15 or less.

The high thermal conductive silicon nitride sintered body of the present invention is composed of a silicon nitride particle phase and a surrounding grain boundary phase. Oxygen (O) is contained in each of these two phases. The smaller the oxygen content in the silicon nitride particles, the more desirable it is, specifically, 0.6 wt% or less, more desirably 0.3 wt% or less. Is desirable.

Further, magnesium (Mg) is converted to magnesium oxide (MgO), and the element of group 3a (RE) in the periodic table is converted to oxide (RExOy), and the total amount is 0.6 to 7.0 wt. %, And M
It is preferred that the content is contained in a weight ratio of gO / RExOy of 1 to 70. Here, as elements of Group 3a of the periodic table, Y, La, Ce, Nd, Pm, Sm, Eu,
Gd, Dy, Ho, Er, Tm, Yb, Lu and the like can be mentioned.

[0017]

The foreign ions present as impurities in the silicon nitride sintered body, in particular, aluminum (Al) and oxygen (O) serve as phonon scattering sources and reduce the thermal conductivity.

The silicon nitride sintered body is composed of a silicon nitride particle phase and a surrounding grain boundary phase, and aluminum and oxygen are contained in these two phases, respectively. Since aluminum is close to the ionic radius of Si, which is a constituent element of silicon nitride, aluminum easily forms a solid solution in silicon nitride particles. Therefore, the thermal conductivity of the silicon nitride particles themselves is reduced, and as a result, the thermal conductivity of the sintered body is significantly reduced.

Since oxygen mainly adds an oxide as a sintering aid, most of the oxygen exists as a grain boundary phase component.
In order to achieve high thermal conductivity of the sintered body, it is important to reduce the amount of the grain boundary phase having a lower thermal conductivity than the silicon nitride particles of the main phase. The relative density 85%
It is necessary to minimize the amount of the above sintered body and reduce the amount of oxygen. Here, when the sintering aid is based on MgO, the sintering property is better than when other oxides are used, so that the amount of the aid can be further reduced.
In addition, when a silicon nitride powder having a low oxygen content is used as a raw material, the amount of oxygen contained in the grain boundary phase component can be reduced, thereby decreasing the amount of the grain boundary phase and increasing the heat of the sintered body. Conduction is achieved. When a silicon nitride powder having a low oxygen content is used, the amount of SiO ₂ generated in the firing process is reduced and the sintering becomes difficult. Obtainable. In any case, by reducing the amount of oxygen in the sintered body, the amount of the grain boundary phase, which is a low heat conductive phase, can be reduced, and the thermal conductivity can be significantly improved. Therefore 7
In order to obtain a thermal conductivity of 0 W / (m · K) or more, aluminum (Al) in the silicon nitride-based sintered body is 0.2 wt.
% And oxygen (O) are 3.0 wt% or less.

The carbon (C) in the silicon nitride sintered body is
If the content exceeds 2.0% by weight, the density decreases due to sintering inhibition, and partial blackening becomes remarkable, so that a uniform color tone cannot be obtained and the quality of appearance deteriorates. However, the fact that C remains to some extent in the compact is effective in reducing the amount of oxygen in the sintered compact. In other words, a small amount of C remaining reduces oxygen in the silicon nitride raw material and oxygen present as an oxide of the sintering aid in the sintering process to reduce CO2.
This has the effect of removing it as a gas or CO2 gas. As a result, oxygen in the sintered body is reduced, and C itself is consumed in the deoxidation process. Therefore, the content of C and O in the sintered body can be drastically reduced, and the thermal conductivity can be improved.
The C content in the sintered body is preferably 0.5 wt% or less, more preferably 0.3 wt% or less.

When the proportion of the β-type silicon nitride particles having a minor axis diameter of 5 μm or more in the silicon nitride sintered body is 10% by volume or more, the thermal conductivity of the sintered body is improved, but the structure has Since the introduced coarse particles act as a starting point of fracture, the fracture strength is significantly reduced, and a bending strength of 600 MPa or more cannot be obtained. On the other hand, if the aspect ratio of the β-type silicon nitride particles exceeds 15, a bending strength of 600 MPa or more cannot be obtained. The preferred aspect ratio is 10 or less.
The preferred bending strength is 700 MPa or more.

Oxygen contained in the silicon nitride particles causes scattering of phonon, which is a heat conduction medium, at this portion, and lowers the thermal conductivity of the silicon nitride particles themselves, and furthermore, the silicon nitride sintered body. Therefore, it is desirable that the amount of oxygen contained in the particles is as small as possible, specifically, 0.5 wt% or less, more preferably 0.3 wt% or less.

Magnesium and yttrium (Y), an element of Group 3a of the periodic table, are used as a sintering aid and are effective in densifying the raw material powder of silicon nitride. These elements have a low solid solubility in the silicon nitride crystal, which is the first microstructure component constituting the silicon nitride sintered body, so that the silicon nitride crystal, and thus the silicon nitride sintered body, have a high thermal conductivity. Can be kept.

Like yttrium, the element having a low solid solubility in silicon nitride crystal and acting as a sintering aid includes:
La, Ce, Nd, Pm, Sm, Eu, Gd, Dy, H
Rare earth elements such as o, Er, Tm, Yb, and Lu can be mentioned, and among them, La, Ce, Gd, Dy, and Yb are preferable because they can be fired without excessively increasing the temperature and pressure.

When magnesium is converted to magnesium oxide, and the Group 3a element of the periodic table is converted to oxide, if the total amount is less than 0.6 wt%, the densification effect at the time of sintering becomes insufficient, and the relative density increases. Is less than 95%, which is not preferable.
On the other hand, when the content exceeds 7.0 wt%, the amount of the grain boundary phase having a low thermal conductivity, which is the second microstructure component of the silicon nitride sintered body, becomes excessive, and the thermal conductivity of the sintered body becomes 70 W / (m -It is less than K). These oxides have a total amount of 0.6 to 4.0 w.
It is more preferable to contain t%. The Periodic Table 3
One or more of the group a elements can be added.

The weight ratio of magnesium oxide (MgO) to the oxide of the Group 3a element of the periodic table (RExOy) MgO / R
If ExOy is less than 1, the ratio of the rare earth oxide in the grain boundary glass phase increases, so that the liquidus temperature rises in the sintering process, and the sintering becomes difficult, and a dense sintered body cannot be obtained. In addition, MgO /
When RExOy exceeds 70, diffusion of Mg during firing cannot be suppressed, and color unevenness occurs on the surface of the sintered body. M
When gO / RExOy is in the range of 1 to 70, 1650
After pre-firing the compact at a sintering temperature of
When a heat treatment at 850 to 1900 ° C. is added, a material having a high thermal conductivity effect exceeding 120 W / (m · K) is obtained.

The substrate made of the silicon nitride sintered body of the present invention can be made of various substrates such as a substrate for a power semiconductor and a substrate for a multi-chip module by utilizing the characteristics of high strength, high toughness and high thermal conductivity. Alternatively, it is suitable for electronic component members such as a heat transfer plate for a Peltier element and a heat sink for various heating elements.

When the material of the present invention is applied to a substrate for a semiconductor device, cracks are less likely to occur in the substrate due to repeated thermal cycling accompanying the operation of the semiconductor device, and the thermal shock resistance and the thermal cycle resistance are remarkably improved. It is excellent in performance and reliability. Further, even when a semiconductor element for high output and high integration is mounted, deterioration of the thermal resistance characteristics is small and excellent heat radiation characteristics are exhibited.
In addition, the excellent mechanical properties allow not only the function as the original substrate material but also the structure itself to serve as a structural member, so that the structure of the substrate unit itself can be simplified.

The silicon nitride sintered body of the present invention can be widely used for materials requiring heat resistance characteristics such as thermal shock and thermal fatigue, in addition to the above-mentioned electronic component members. Structural members include various heat exchanger parts and heat engine parts, heater tubes used in the field of melting metals such as aluminum and zinc, Stokes, die-cast sleeves, propellers for molten metal stirring, ladles, thermocouple protection tubes, etc. Applicable. In addition, by applying to a sink roll, a support roll, a bearing, a shaft, and the like used in a hot-dip metal plating line of aluminum, zinc, or the like, a member that is hard to be broken by rapid heating or cooling can be obtained. In the field of steel or non-ferrous processing, rolling rolls, squeeze rolls, guide rollers,
When used for wire drawing dies, tool tips, etc., the heat radiation property at the time of contact with the workpiece is good, so that the heat resistance fatigue resistance and thermal shock resistance can be improved, thereby reducing wear and reducing thermal stress cracking. It can hardly occur.

Further, the present invention can be applied to a sputter target member, and is suitable for forming an electric insulating film used for an MR head or a GMR head of a magnetic recording device or a wear-resistant film used for a thermal head of a thermal transfer printer. is there. The film obtained by sputtering has inherently high thermal conductivity, a sufficiently high sputter rate, and a high electric breakdown voltage of the film. For this reason, the MR head and G
Since the electrical insulating film for the MR head has characteristics of high thermal conductivity and high withstand voltage, it is possible to increase the heat generation density of the element and to reduce the thickness of the insulating film. In addition, the wear-resistant coating for a thermal head formed by this sputter target has not only good wear resistance due to the inherent characteristics of silicon nitride, but also high thermal conductivity, so that thermal resistance can be reduced. Can be enhanced.

[0031]

DESCRIPTION OF THE PREFERRED EMBODIMENTS First Embodiment An oxygen content of 0.3 to 1.5 wt% and an average particle size of 0.5
μm silicon nitride (Si3N4) powder, magnesium oxide (MgO) with an average particle size of 0.2 μm as a sintering aid
A predetermined amount of one or two kinds of powders for sintering aids selected from powders and rare earth oxide powders having an average particle diameter of 0.2 to 2.0 μm are added, and an appropriate amount of a dispersant is added thereto, and the mixture is added in ethanol. Crushed and mixed. Then, after vacuum drying, the mixture was granulated through a sieve, and a disc-shaped molded body having a diameter of 20 mm x a thickness of 10 mm and a diameter of 100 mm x a thickness of 15 mm was produced by a press machine. The firing was performed in an atmosphere for 5 hours.

From the obtained silicon nitride sintered body, a diameter of 1
A test piece of 0 mm × thickness 3 mm for measuring thermal conductivity and density and a 4-point bending test piece of 3 mm × 4 mm × 40 mm were collected. The density was determined from the results of dimensional measurement and weight measurement using a micrometer. The thermal conductivity was calculated by measuring the specific heat and the thermal diffusivity at room temperature by a laser flash method. Four-point bending strength is JIS R1 at room temperature
The measurement was performed according to 606.

The volume% of the silicon nitride particles was determined by eluting the grain boundary glass phase with hydrofluoric acid from the sintered body, individually taking out the silicon nitride particles, and observing the particles by SEM. In the present invention, the value of area% was evaluated as volume%. The content of aluminum (Al) in the silicon nitride-based sintered body was determined by induction plasma emission spectrometry (ICP).
And the carbon (C) content was measured by an infrared absorption method.

Tables 1 and 2 show the results according to the present embodiment. The sample No. Sample Nos. 1 to 11 are examples of the present invention. 31 to 36 are comparative examples. In Table 2, “XX” indicates the ratio (volume%) of β-type silicon nitride particles having a minor axis diameter of 5 μm or more in the sintered body.

[0035]

[Table 1]

[0036]

[Table 2]

Samples Nos. 1 to 3 of the present invention shown in Tables 1 and 2 were prepared. 1 to
From the result of No. 11, the aluminum (Al) in the silicon nitride based sintered body was 0.2 wt% or less and the oxygen (O) was 3.0%.
If the content is less than 7 wt%, the thermal conductivity at room temperature is 7%.
0W / (m · K) or more, 6-point bending strength at room temperature is 6
00 MPa or more was obtained. Al is 0.1 wt%
In the case where the content of O is 2.5 wt% or less, a thermal conductivity of 100 W / (m · K) or more was obtained. Further, those containing 0.05 wt% or less of Al and 2.2 wt% or less of O had thermal conductivity of 150 W / (m · K) or more.
Compared to the level of the thermal conductivity of 40 W / (m · K) or more of the prior art, the thermal conductivity could be dramatically increased.

As a sintering aid, magnesium is converted to magnesium oxide (MgO), and the element of Group 3a of the periodic table is converted to oxide (RExOy).
Those containing 6 to 7.0 wt% at a weight ratio of 1 to 70 represented by MgO / RExOy have a thermal conductivity of 70 W.
/ (M · K) or more, a four-point bending strength of 600 MPa or more was obtained.

Further, Comparative Example Sample No. From the results of 31 to 36, those in which the silicon nitride sintered body contains more than 0.2 wt% of Al and more than 3.0 wt% of O have a thermal conductivity of 70 W / (m · K) at room temperature. Less than.
As described above, a four-point bending strength at room temperature of 600 MPa or more was obtained.

The carbon (C) in the silicon nitride sintered body is
If it exceeds 0 wt%, the thermal conductivity becomes less than 70 W / (m · K). Further, when the proportion of β-type silicon nitride particles having a minor axis diameter of 5 μm or more in the silicon nitride sintered body becomes 10% by volume or more, the breaking strength is remarkably reduced.
The material strength became 00 MPa or less.

Further, when the sintering aid component is less than 0.6% by weight, the density of the sintered body is low, so that the thermal conductivity and the bending strength are remarkably reduced. Further, the sintering aid component is 7.0
When the content exceeds wt%, a sufficient glass phase is generated during the firing process, so that the sintered body is densified. However, the thermal conductivity is 60 W / (m · K) or less due to an increase in the low thermal conductive phase. Reduced to

Second Embodiment A mixed powder obtained by adding a predetermined amount of a sintering aid to the silicon nitride powder of the present invention was inserted into a toluene / butanol solution to which a predetermined amount of an amine-based dispersant was added. After wet mixing for 48 hours using a pot and a ball made of silicon nitride,
Add a polyvinyl organic binder and a plasticizer, add 2
The mixture was mixed for 4 hours to obtain a sheet forming slurry. After adjusting the molding slurry, a green sheet was obtained by a doctor blade method. Then, put the green sheet in the air 400
Heating was performed at 600 ° C. for 1 to 2 hours to sufficiently remove the organic binder component added in advance to perform degreasing. The degreased body was fired at 1850 ° C. for 5 hours and 9 atm in a nitrogen atmosphere, and then subjected to a heat treatment at 1900 ° C. in a nitrogen atmosphere for 24 hours at 9 atm to obtain a silicon nitride sintered body sheet.
This was machined to produce a semiconductor device substrate having dimensions of 50 mm × 50 mm × 0.8 mm in thickness.

A circuit board as shown in FIG. 1 was manufactured using the silicon nitride sintered body. In FIG. 1, a circuit board 1 of the present invention is formed by bonding a copper circuit board 3 to a front surface of a silicon nitride sintered body 2 and a copper plate 4 to a back surface by a brazing material 5. This circuit board was evaluated for four-point bending strength and subjected to a heat cycle test.

According to the circuit board made of the silicon nitride sintered body of the present invention, the bending strength is as large as 600 MPa or more, the frequency of occurrence of fastening cracks in the mounting process of the circuit board is suppressed, and the semiconductor using the circuit board is used. It has been demonstrated that the production yield of the device is greatly improved.

In the heat cycle test, the heating / cooling cycle in which cooling at −40 ° C. was 20 minutes, holding at room temperature for 10 minutes, and heating at 180 ° C. for 20 minutes was one cycle, and this cycle was repeated. The number of cycles until cracks and the like occurred in the substrate portion was measured. As a result, even after a lapse of 1000 cycles, there was no cracking of the silicon nitride substrate or peeling of the metal circuit board, and it was confirmed that both the durability and the reliability were excellent. Also, even after 1000 cycles, the withstand voltage characteristics did not decrease.

[0046]

The silicon nitride sintered body of the present invention has high thermal conductivity in addition to its inherent high strength and high toughness. Cracks are less likely to occur in the substrate due to the repetitive thermal cycling involved, and thermal shock resistance and thermal cyclability are significantly improved, resulting in a substrate material having excellent durability and reliability.

[Brief description of the drawings]

FIG. 1 is a cross-sectional view of a circuit board made of a silicon nitride sintered body of an example of the present invention.

[Explanation of symbols]

1 circuit board, 2 board, 3 copper circuit board, 4 copper board, 5 brazing material

 ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 4G001 BA06 BA08 BA09 BA10 BA11 BA32 BA73 BB06 BB08 BB09 BB10 BB11 BB32 BB60 BB71 BB73 BC13 BC54 BD03 BD14 BE03 BE22 BE23 BE32 4K029 BA58 BC02 BC05 BC10 BD11 CA05

Claims (9)

[Claims] 1. A semiconductor comprising silicon nitride as a main component, aluminum (Al) as an impurity of 0.2 wt% or less, and oxygen (O)
Is 3.0 wt% or less, the thermal conductivity at room temperature is 70 W / (m · K) or more, and the four-point bending strength at room temperature is 600 MPa or more. 2. A composition containing silicon nitride as a main component, aluminum (Al) as an impurity of 0.1 wt% or less, and oxygen (O)
Is 2.5 wt% or less, the thermal conductivity at room temperature is 100 W / (m · K) or more, and the four-point bending strength at room temperature is 600 MPa or more. 3. A silicon nitride as a main component, containing aluminum (Al) as an impurity at 0.05 wt% or less and oxygen (O) at 2.2 wt% or less, and having a thermal conductivity of 150 W / (m · K) at room temperature. 3.) A high thermal conductive silicon nitride sintered body characterized in that the four-point bending strength at room temperature is 600 MPa or more. 4. The high thermal conductive silicon nitride sintered body according to claim 1, wherein carbon (C) is contained in an amount of 2.0 wt% or less. 5. The proportion of β-type silicon nitride particles having a minor axis diameter of 5 μm or more in the high thermal conductive silicon nitride-based sintered body is less than 10% by volume.
4. The high thermal conductive silicon nitride sintered body according to any one of 4. 6. The high thermal conductive silicon nitride sintered body according to claim 1, wherein the aspect ratio of the β-type silicon nitride particles in the high thermal conductive silicon nitride sintered body is 15 or less. Union. 7. Magnesium (Mg) is converted to magnesium oxide (MgO) to obtain a Group 3a element (RE) of the periodic table.
In terms of oxide (RExOy), the total amount of which is 0.6 to
The high thermal conductive silicon nitride sintered body according to any one of claims 1 to 6, wherein the sintered body is contained in a proportion of 7.0 wt%. 8. An element (RE) of group 3a of the periodic table, wherein magnesium (Mg) is converted to magnesium oxide (MgO).
In terms of oxide (RExOy), the total amount of which is 0.6 to
7.0 wt%, weight ratio expressed as MgO / RExOy is 1
7. The composition according to claim 1, which is contained at a ratio of from 70 to 70.
A highly thermally conductive silicon nitride-based sintered body according to any one of the above. 9. A high thermal conductive silicon nitride sintered body substrate and a circuit board comprising the high thermal conductive silicon nitride sintered body according to claim 1.