JP2001064117A - Cosmetic for make-up - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a cosmetic for make-up satisfactory in adhesion to skin, excellent in opacifying property, formable a uniform make-up membrane and excellent in durability of the make-up effect. SOLUTION: The cosmetic for make-up comprises component (a) an oil solution treated titanium oxide and component (b) a silicone treated titanium oxide and the weight ratio of the titanium oxide in the component (a) and the titanium oxide in the component (b) is 1:0.05 to 0.2. The cosmetic for make-up includes the component (a) comprising at least one kind of the titanium oxide having particle size 0.1 to 0.5 μm and at least one kind of the titanium oxide having particle size 0.01 to 0.008 μm. The titanium oxide in the above-mentioned component (b) comprises one or more kind titanium oxides having particle size of 0.1 to 0.5 μm, and the formulation is a water in oil type.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a make-up cosmetic, and more particularly, to a make-up cosmetic which has good adhesion to skin, excellent concealing properties, and can form a uniform cosmetic film.
The present invention relates to a makeup cosmetic having a good persistence of makeup.

[0002]

2. Description of the Related Art Conventionally, titanium oxide has been used in makeup cosmetics for the purpose of concealing defects such as skin spots and freckles, and for the purpose of shielding ultraviolet rays. Titanium oxide has been treated with an oil agent to enhance the adhesion to the skin, and has been treated with a water repellent treatment with a silicone compound or the like to increase the durability of the makeup.

[0003]

However, in the makeup cosmetics containing only the titanium oxide treated with an oil agent, if the amount of the makeup cosmetics is increased in order to hide skin defects, the adhesion to the skin becomes too high and the elongation and spread are increased. Poor and could not obtain a uniform decorative film. On the other hand, make-up cosmetics containing only silicone-treated titanium oxide have good cosmetic durability, but sometimes slip on the skin and have poor adhesion. Therefore, there has been a demand for the development of a makeup cosmetic which has good adhesion to the skin, has excellent concealing properties, can form a uniform cosmetic film, and has good makeup persistence.

[0004]

Under these circumstances, the present inventors have conducted intensive studies in order to solve the above-mentioned problems, and as a result, the oil-treated titanium oxide and the silicone-treated titanium oxide are combined in a specific ratio. Thereby, it was found that a good makeup cosmetic having good adhesion to the skin, excellent concealing properties, a uniform makeup film, and a good makeup continuity can be obtained, thereby completing the present invention. Was.

That is, the present invention provides the following components (a) to
(B); (a) an oil agent-treated titanium oxide, (b) a silicone-treated titanium oxide, and the amount of titanium oxide in the component (a) and the amount of titanium oxide in the component (b) are 1 by weight. : 0.05-
The present invention provides a makeup cosmetic characterized by being 0.2. In addition, the titanium oxide in the component (a) has at least one kind of titanium oxide having an average particle size of 0.1 to 0.5 μm and one kind of titanium oxide having an average particle size of 0.01 to 0.08 μm. The makeup cosmetic comprising the above. Further, the makeup cosmetic wherein the titanium oxide in the component (b) is one or more of titanium oxide having an average particle size in a range of 0.1 to 0.5 μm. Still further, the present invention provides the makeup cosmetic, wherein the dosage form is an oil-in-water type.

[0006]

BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail.
The component (a) oil-treated titanium oxide used in the present invention comprises:
Since the titanium oxide particles are adhered to the skin by the oil agent, the adhesion is improved, and as a result, the concealing property is excellent. The titanium oxide surface is obtained by treating the titanium oxide surface with the oil agent. The titanium oxide used for the component (a) is usually used to impart hiding power to makeup cosmetics,
It is used to impart an ultraviolet shielding effect, and its shape may be granular, needle-like, flaky, or the like,
The average particle size is preferably from 0.01 to 0.5 μm. The titanium oxide used for the component (a) has an average particle diameter of 0.1 to
One or more particles in a range of 0.5 μm, and an average particle diameter of 0.01 to
A combination of one or more particles in the range of 0.08 μm is particularly preferable because a more uniform decorative film can be formed on the skin.

The oil agent used for the component (a) is usually used in makeup cosmetics for the purpose of improving adhesion to the skin, imparting an emollient feeling, reducing powderiness, and the like. Vegetable oils, synthetic oils and other sources, solid oils, semi-solid oils, liquid oils, etc., regardless of their properties, such as hydrocarbons, oils and fats, waxes, hardened oils, ester oils, fatty acids, higher alcohols, Oil agents such as lipophilic surfactants, fluorinated oils, and lanolin derivatives are exemplified. Specifically, hydrocarbons such as liquid paraffin, squalane, petrolatum, polyisobutylene, polybutene, paraffin wax, ceresin wax, microcrystalline wax, mokurou, montan wax, fishatrops wax, olive oil, castor oil, jojoba oil, Oils and fats such as mink oil, macadamian nut oil, beeswax,
Lanolin, carnauba wax, candelilla wax, waxes such as gay wax, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate,
Octyldodecyl myristate, glyceryl trioctanoate, diglyceryl diisostearate, diglyceryl triisostearate, glyceryl tribehenate, pentaerythritol rosinate, neopentyl glycol dioctanoate, cholesterol fatty acid ester, N
Esters such as -lauroyl-L-glutamic acid di (cholesteryl behenyl octyldodecyl), fatty acids such as stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid, oleic acid, rosin acid, 12-hydroxystearic acid , Stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, higher alcohols such as behenyl alcohol, glycerin monostearate,
Lipophilic surfactants such as sorbitan tristearate,
Fluorinated oils such as perfluoropolyether, perfluorodecane and perfluorooctane; lanolin derivatives such as lanolin, lanolin acetate, isopropyl lanolin fatty acid, and lanolin alcohol; and the like, and one or more of these may be used. Can be. It is preferable that the oil agent used for the component (a) contains a solid oil or a semi-solid oil at normal temperature, since the adhesion to the skin is further improved.

In the component (a), as a method of treating titanium oxide with an oil agent, a generally known powder treatment method can be used. For example, a method of dissolving or dispersing an oil agent in a solvent such as isopropyl alcohol, adding and mixing titanium oxide thereto, removing the solvent under reduced pressure, treating the oil agent, and pulverizing the oil-treated titanium oxide. Another option is to
Examples of the method include a flushing method using water, a method using a spray-drying apparatus, and a method of mechanochemically treating powdered oil and fat and titanium oxide.

The treatment ratio of the oil agent to titanium oxide in the component (a) is affected by the treatment method, the particle size of the powder, the particle shape, the viscosity of the oil agent, the surface tension, and the like. Oil agent = 99.9: 0.1 to 50:50 is preferable, and 99: 1 to 80:20 is particularly preferable. Within this range, the adhesion to the skin is further enhanced.

The component (b) silicone-treated titanium oxide used in the present invention is a titanium oxide treated with a silicone compound, and is used for enhancing the concealing property and the persistence of makeup when applied to the skin. . The titanium oxide used for the component (b) is the same as the titanium oxide used for the component (a), and is usually used for imparting hiding power to makeup cosmetics or for imparting an ultraviolet shielding effect. The shape may be any of a granular shape, a needle shape, a flake shape and the like, and the average particle size is preferably 0.01 to 0.5 μm. It is particularly preferable that the titanium oxide used in the component (b) is at least one having an average particle diameter in the range of 0.1 to 0.5 μm, because the concealing property for hiding skin defects is further improved.

The silicone compound used in the component (b) is not particularly limited as long as it is generally used as a powdery water-repellent agent. Polysiloxanes, chain silicones such as methylphenylpolysiloxane, amino-modified silicones, alkyl-modified silicones, modified silicones such as alkoxy-modified silicones, silicone resins such as trimethylsiloxysilicic acid and acrylate silicones, silicone rubbers, parts or Examples include fully crosslinked organopolysiloxanes, various silylating agents, and fluorine-modified silicones, and one or more of these can be used.

As the method of treating the titanium oxide with the silicone compound in the component (b), a generally known powder treatment method can be used. For example, after dissolving or dispersing a silicone compound in a solvent such as isopropyl alcohol, adding and mixing titanium oxide thereto, removing the solvent under reduced pressure, baking if necessary, and pulverizing the silicone-treated titanium oxide. how to. Other methods include a flushing method using water, a method using a spray-drying apparatus, a method in which titanium oxide is dispersed in a gas phase, and a silicone compound is spray-coated.

The treatment ratio of the silicone compound to titanium oxide in the component (b) is determined by the treatment method, the particle size of the powder,
Although affected by the particle shape, the viscosity of the oil agent, the surface tension, and the like, the weight ratio is generally about titanium oxide: silicone compound = 99.
9: 0.1 to 50:50 is preferable, and 99: 1 to 80:
20 is particularly preferred. In this range, the water repellency of the titanium oxide is increased, so that the makeup durability is further improved.

The content of the component (a) oil-treated titanium oxide in the makeup cosmetic of the present invention is 5 to 20% by weight.
(Hereinafter, simply abbreviated as “%”). When the content is within this range, the concealing property for hiding skin defects is good, and there is no unnatural whiteness.

The amount of titanium oxide in component (a) and the amount of titanium oxide in component (b) in the makeup cosmetic of the present invention are 1: 0.05 to 1: 0.2 by weight. When the amount of titanium oxide in the component (b) is less than the lower limit of the ratio, the adhesiveness becomes too high when applied to the skin, so that a uniform decorative film cannot be obtained. If the ratio exceeds the upper limit, the material slips on the skin, and the adhesion becomes poor.

The dosage form of the makeup cosmetic of the present invention is not particularly limited, and examples thereof include an emulsion type such as an oil-in-water type and a water-in-oil type, a powder type such as a solid type and a powder type, and an oil type. The dosage form that easily exerts the effect of (1) is an oil-in-water emulsion type. Further, the makeup cosmetic of the present invention may be a liquid foundation, a powder foundation, a blusher,
Applicable to white powder, eye shadow, makeup base, etc.

The makeup cosmetic of the present invention may contain, in addition to the above-mentioned components, oils, powders, water-soluble polymers, surfactants and the like in a quantitative and qualitative range according to the purpose, without impairing the effects of the present invention. Components commonly used in cosmetics such as gelling agents, humectants, ultraviolet absorbers, antioxidants, preservatives, chelating agents, fragrances, and cosmetic ingredients can be blended.

The makeup cosmetic of the present invention is used not only for treating titanium oxide but also for giving an emollient feeling to the skin and for reducing the powderiness when powder is blended. And an oil agent. The oil agent used here is not particularly limited as long as it is an oil agent usually used in cosmetics, and the origin of animal oil, vegetable oil, synthetic oil, etc. and properties of solid oil, semi-solid oil, liquid oil, volatile oil, etc. Regardless, oils such as hydrocarbons, oils and fats, waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorinated oils, and lanolin derivatives are exemplified. Specifically, hydrocarbons such as liquid paraffin, squalane, petrolatum, polyisobutylene, polybutene, paraffin wax, ceresin wax, microcrystalline wax, mokurou, montan wax, fishatrops wax, olive oil, castor oil, jojoba oil, Fats such as mink oil, macadamian nut oil, beeswax, lanolin, carnauba wax, candelilla wax, waxes such as gay wax, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, trioctanoic acid Glyceryl, diglyceryl diisostearate, diglyceryl triisostearate, glyceryl tribehenate, pentaerythritol rosinate, neopentyl glycol dioctanoate Cholesterol fatty acid esters, N- esters such as lauroyl -L- glutamic acid di (cholesteryl behenyl octyldodecyl), stearic acid, lauric acid, myristic acid,
Fatty acids such as behenic acid, isostearic acid, oleic acid, rosin acid, 12-hydroxystearic acid, higher alcohols such as stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol, and low polymerization degree dimethyl poly Silicones such as siloxane, high polymerization degree dimethylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, and fluorine-modified silicone; and fluorine-based materials such as perfluoropolyether, perfluorodecane, and perfluorooctane Oils, lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin derivatives such as lanolin alcohol, and the like. One or more of these may be used. Can. The compounding amount of the oil agent when compounding the oil agent into the makeup cosmetic of the present invention varies depending on the dosage form of the cosmetic, but in the case of an oil-in-water emulsion type,
Generally 0.5 to 30%, in the case of a water-in-oil emulsion type, approximately 3
A range of 0 to 90% is preferred.

The makeup cosmetic of the present invention may contain powders other than titanium oxide as a feel control agent, a coloring agent, a pearl agent, an ultraviolet ray shielding agent and the like. Such powders are not particularly limited by shapes such as spherical, plate-like, and needle-like, fume-like, fine particle, particle size such as pigment grade, and particle structure such as porous and non-porous. Bodies, glitter powders, organic powders, dye powders, composite powders, and the like. Specifically, as a coloring agent, black titanium oxide, konjo, ultramarine blue, red iron oxide, yellow iron oxide, black iron oxide, zinc oxide, aluminum oxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, barium sulfate, chromium oxide , Chromium hydroxide, carbon black, tar dyes, etc., as touch modifiers, silicon oxide, aluminum silicate, magnesium silicate, aluminum magnesium silicate, mica, synthetic mica, synthetic sericite, sericite, talc, silicon carbide , Boron nitride, nylon powder, polymethyl methacrylate, acrylonitrile-methacrylic acid copolymer powder, vinylidene chloride-methacrylic acid copolymer powder, wool powder, silk powder, crystalline cellulose, N-acyl lysine, etc. Oki Bismuth chloride, titanium mica, iron oxide coated mica, iron oxide mica titanium, organic pigment-treated titanium mica, aluminum powder, etc., as ultraviolet ray blocking agents, fine particle titanium oxide, fine particle zinc oxide, fine particle titanium oxide coated mica titanium, fine particle zinc oxide coated Titanium mica,
Composite powders such as barium sulfate-coated mica titanium may be used, and one or more of these may be used.
In addition, these powders, in order to improve the dispersibility and adhesion,
It may be used after surface treatment by a generally known method such as silicones, fluorine compounds, metal soaps, oils and the like.
When blending the powder into the makeup cosmetic of the present invention,
Depends on the purpose of compounding the powder, but generally 1-95%
Is preferable.

[0020]

The present invention will be described in more detail with reference to the following examples. These do not limit the present invention at all.

Production Example 1 Oil-treated titanium oxide 50 g of candelilla wax and 150 g of squalane were dispersed in 1000 ml of isopropyl alcohol, and 800 g of titanium oxide having an average particle size of 0.1 μm was added and mixed. Next, this dispersion was dried under reduced pressure at 100 ° C. under reduced pressure to obtain isopropyl alcohol to obtain oil-treated titanium oxide.

Preparation Example 2: Titanium oxide treated with an oil agent The titanium oxide having an average particle size of 0.1 μm in Preparation Example 1 was replaced with titanium oxide having an average particle size of 0.5 μm to obtain an oil-treated titanium oxide. .

Production Example 3: Titanium oxide treated with an oil agent The titanium oxide having an average particle size of 0.1 μm in Production Example 1 was replaced with titanium oxide having an average particle size of 0.01 μm to obtain an oil-treated titanium oxide. .

Preparation Example 4: Titanium oxide treated with oil agent The titanium oxide having an average particle diameter of 0.1 μm in Preparation Example 1 was replaced with titanium oxide having an average particle size of 0.08 μm, and the same treatment was performed to obtain titanium oxide treated with an oil agent. .

Production Example 5: Silicone-treated titanium oxide 20 g of methyl hydrogen polysiloxane was dispersed in 1000 ml of isopropyl alcohol, and 800 g of titanium oxide having an average particle size of 0.1 μm was added and mixed and dispersed. Next, the dispersion was dried at 100 ° C. under reduced pressure to remove isopropyl alcohol, and then baked at 110 ° C. to obtain silicone-treated titanium oxide.

Production Example 6: Silicone-treated titanium oxide Silicone-treated titanium oxide was obtained in the same manner as in Production Example 5 except that the titanium oxide having an average particle size of 0.1 μm was replaced with titanium oxide having an average particle size of 0.5 μm. .

Production Example 7: Oil-treated titanium oxide 5 g of beeswax and 5 g of petrolatum were dispersed in 1000 ml of isopropyl alcohol, and 990 g of titanium oxide having an average particle size of 0.2 μm was added and mixed. Next, this dispersion was dried under reduced pressure at 100 ° C. under reduced pressure to obtain oil-treated titanium oxide.

Production Example 8: Oil-treated titanium oxide 5 g of carnauba wax and 495 g of liquid paraffin were dispersed in 1000 ml of isopropyl alcohol, and 500 g of titanium oxide having an average particle size of 0.05 μm was added and mixed. Next, this dispersion was dried under reduced pressure at 100 ° C. under reduced pressure to obtain oil-treated titanium oxide.

Production Example 9: Oil-treated titanium oxide 1 g of stearyl alcohol was dispersed in 1000 ml of isopropyl alcohol, and 999 g of titanium oxide having an average particle size of 0.4 μm was added and mixed and dispersed. Next, this dispersion was dried under reduced pressure at 100 ° C. under reduced pressure to obtain oil-treated titanium oxide.

Production Example 10: Silicone-treated titanium oxide 10 g of dimethylpolysiloxane (100CS) was dispersed in 1000 ml of isopropyl alcohol, and 990 g of titanium oxide having an average particle diameter of 0.4 μm was added and mixed. Next, this dispersion was dried under reduced pressure at 100 ° C. under reduced pressure to obtain silicon-treated titanium oxide.

Production Example 11: Silicon-treated titanium oxide In 1000 ml of isopropyl alcohol, amino-modified silicone (aminoethylaminopropylsiloxane) 50
0 g was dispersed therein, and 500 g of titanium oxide having an average particle size of 0.05 μm was added and mixed and dispersed. Next, this dispersion was dried under reduced pressure at 100 ° C. under reduced pressure to obtain silicon-treated titanium oxide.

Production Example 12: Silicone-treated titanium oxide 1 g of stearyl-modified silicone (Note 1) was dispersed in 1000 ml of isopropyl alcohol, and 999 g of titanium oxide having an average particle size of 0.2 μm was added and mixed. Next, this dispersion was dried under reduced pressure at 100 ° C. under reduced pressure to obtain silicon-treated titanium oxide. * Note 1: ABILWAX9800D (Gold Schmidt)

Examples 1 to 7 and Comparative Examples 1 to 4: Oil-in-water emulsified liquid foundation The oil-in-water emulsified liquid foundation was prepared according to the compositions shown in Tables 1 and 2 and by the following method. The following evaluation methods were used to evaluate each of the following items: "property", "adhesion", "uniform makeup film", and "makeup persistence". The results are shown in Tables 1 and 2.

[0034]

[Table 1]

[0035]

[Table 2]

(Production method) A. The components (1) to (4) are heated to 75 ° C. and uniformly mixed and dissolved. B. The components (16) to (19) and (22) are heated to 75 ° C. and uniformly mixed and dissolved. C. The components (5) to (15) are subjected to a dispersion treatment with three rollers. D. Add C to B, mix and disperse, and heat to 75 ° C. E. FIG. Add D to A and emulsify. F. E was cooled, and the components (20) and (21) were added to obtain an oil-in-water emulsified liquid foundation.

(Evaluation Method) An oil-in-water emulsified liquid foundation of the above Examples and Comparative Examples was used by a panel of 10 cosmetics professionals.
Each of the evaluation items of a suitable concealing property when applied to the skin, adhesion to the skin, a uniform makeup film, and makeup continuity was evaluated on a seven-point scale based on the following evaluation criteria. Further, the average score was determined according to the following criteria. Evaluation criteria: [Evaluation]: [Rating] Very good: 6 Good: 5 Somewhat good: 4 Normal: 3 Somewhat bad: 2 Poor: 1 Very bad: 0 Judgment criteria: [Average score]: [ Judgment] 5.5 or more: ◎ 4.5 or more and less than 5.5 points: ○ 2.5 or more and less than 4.5 points: △ Less than 2.5 points: ×

As is clear from the results in Tables 1 and 2,
Oil-in-water emulsified liquid foundation of the present invention,
Compared with the comparative example, the composition had excellent properties in all of a suitable concealing property when applied to the skin, adhesion to the skin, a uniform cosmetic film, and long lasting makeup.

Example 8: Oil-in-water emulsified cosmetic base (component) (% by weight) Cetanol 2 2. Stearic acid 13 Beeswax 0.54. Vaseline 3 5. Glyceryl tri-2-ethylhexanoate 5 6. 6. Oil-treated titanium oxide 2 of Production Example 7 7. Oil-treated titanium oxide of Production Example 1 8. Siliconized titanium oxide of Production Example 11 0.5 Carboxyvinyl polymer 0.1 10. Triethanolamine 0.5 11. Dipropylene glycol 10.0 12. Preservative appropriate amount 13. Appropriate amount of fragrance 14. Purified water balance

(Manufacturing method) The components (1) to (5) are heated to 75 ° C. and uniformly mixed and dissolved. B. Components (6) to (11) and (14) are heated to 75 ° C. and uniformly mixed and dissolved. C. Add B to A and emulsify. D. C was cooled, and the components (12) and (13) were added to obtain an oil-in-water emulsified makeup base. The oil-in-water emulsified makeup base of Example 8 had excellent properties in all of suitable concealing properties when applied to the skin, adhesion to the skin, a uniform makeup film, and long-lasting makeup.

Example 9: Water-in-oil emulsified cream foundation (component) (% by weight) Squalane 10 2. Decamethylcyclopentasiloxane 20 3. Polyoxyethylene-modified dimethylpolysiloxane (Note 1) 5 4. Talc 5 5. Bengara 0.3 6. Iron oxide yellow 17 Black iron oxide 0.18. 8. Oil-treated titanium oxide of Production Example 2 9 10. Oil-treated titanium oxide of Production Example 9 10. Silicone-treated titanium oxide of Production Example 1.7 1.7 Propylene glycol 10 12. Preservative appropriate amount 13. Appropriate amount of fragrance 14. Remaining purified water * Note 1: Silicon KF6017 (Shin-Etsu Chemical Co., Ltd.)

(Manufacturing Method) Components (1) to (10) are uniformly mixed and dispersed. B. The components (11) to (14) are uniformly mixed. C. B was added to A and emulsified to obtain a water-in-oil emulsified cream foundation. The water-in-oil emulsified cream foundation of Example 9 had excellent properties in all of suitable concealing properties when applied to the skin, adhesion to the skin, uniform cosmetic film, and long lasting makeup.

Example 10: Solid powdered powder foundation (component) (% by weight) Talc 10 2. Mica rest 3. Titanium mica 3 4. Bengara 1 5. Yellow iron oxide 1 6. Black iron oxide 0.57. 7. Oil-treated titanium oxide of Production Example 7 8. Siliconized titanium oxide of Production Example 0.6 0.6 Vaseline 1 10. Propylene glycol dicaprate 5 11 Preservative appropriate amount 12. Appropriate amount of fragrance

(Manufacturing Method) Components (1) to (8) are mixed and dispersed. B. The components (9) to (12) are heated to 50 ° C. and uniformly mixed and dissolved. C. Add B to A and mix uniformly. D. C was pulverized and compression molded into a dish to obtain a solid powdery powder foundation. The solid powdered powder foundation of Example 10 was
It had excellent properties in all of suitable concealing properties when applied to the skin, adhesion to the skin, uniform cosmetic film, and long lasting makeup.

Example 11: Solid powdery cake foundation (using water) (Components) (% by weight) Talc 50 2. Mica rest 3. Mica titanium 2 4. Bengara 0.55. Yellow iron oxide 2 6. Black iron oxide 0.8 7. 7. Oil treated titanium oxide of Production Example 1 7 8. Oil-treated titanium oxide of Production Example 8 9. Siliconized titanium oxide of Production Example 12 0.5 10. Polyoxyethylene monooleate (20) sorbitan 1 Glyceryl tri-2-ethylhexanoate 5 12. Preservative appropriate amount 13. Appropriate amount of fragrance

(Manufacturing Method) Components (1) to (9) are mixed and dispersed. B. The components (10) to (13) are heated to 50 ° C. and uniformly mixed and dissolved. C. Add B to A and mix uniformly. D. C was pulverized and compression-molded into a dish to obtain a solid powdery cake foundation. The solid powdered cake foundation of Example 11 had excellent properties in all of a suitable concealing property when applied to the skin, adhesion to the skin, a uniform makeup film, and a long-lasting makeup.

Example 12: Solid oily foundation (component) (% by weight) Talc 10 2. Mica 5 3. Mica titanium 2 4. Bengara 0.55. Yellow iron oxide 2 6. Black iron oxide 0.8 7. 7. Oil-treated titanium oxide of Production Example 1 8. The oil-treated titanium oxide of Production Example 4 9. Siliconized titanium oxide of Production Example 11 9.6 Microcrystalline wax 5 11. Beeswax 2 12. Reduced lanolin 3 13. Liquid paraffin 5 14. 14. Isopropyl palmitate balance Preservative appropriate amount 16. Appropriate amount of fragrance

(Production Method) Components (10) to (14) are uniformly mixed at 85 ° C. B. In A, components (1) to (9) and components (15) to (1)
6) is added and mixed and dispersed. C. B was melted at 85 ° C., poured into a dish, and cooled to obtain a solid oily foundation. The solid oil-based foundation of Example 12 has an appropriate concealing property when applied to the skin, adhesion to the skin, a uniform decorative film,
It had excellent properties in all aspects of long-lasting makeup.

Example 13: Solid powdery white powder (component) (% by weight) Talc 60 2. Mica rest 3. 3. Oil-treated titanium oxide of Production Example 9 4. Siliconized titanium oxide of Production Example 0.3 Squalane 5 6. Preservative appropriate amount

(Manufacturing Method) Components (1) to (4) are uniformly mixed and dispersed. B. The components (5) and (6) are heated to 50 ° C. and uniformly mixed and dissolved. C. B is added to A and mixed and dispersed uniformly. D. C was pulverized and compression-molded into a dish to obtain a solid powdery white powder. The solid powdered white powder of Example 13 had excellent characteristics in all of appropriate concealing properties when applied to the skin, adhesion to the skin, uniform cosmetic film, and long lasting makeup.

Example 14: Powdered blusher (ingredient) (% by weight) Talc 80 2. Mica rest 3. Red No. 202 2 4. 4. Oil-treated titanium oxide of Production Example 2 4 5. Oil-treated titanium oxide of Production Example 3 2.5 6. Siliconized titanium oxide of Production Example 12 Preservative appropriate amount 8. Appropriate amount of fragrance

(Production Method) Components (1) to (8) are uniformly mixed and dispersed. B. A was pulverized and filled in a container to obtain a powdered blusher. The powdered blusher of Example 13 had excellent properties in all of suitable concealing properties when applied to the skin, adhesion to the skin, uniform cosmetic film, and long lasting makeup.

Example 14: Solid powder eye shadow (component) (% by weight) Talc 45 2. Mica rest 3. Colored titanium mica 20 4. 4. Oil-treated titanium oxide of Production Example 7 5. Oil-treated titanium oxide of Production Example 2.6 6. Siliconized titanium oxide of Production Example 6 0.4 7. Dimethylpolysiloxane (20CS) 5 Squalane 5 9. Preservative appropriate amount 10. Appropriate amount of fragrance

(Production Method) Components (1) to (6) are uniformly mixed and dispersed. B. Components (7) to (10) are heated to 50 ° C. and uniformly mixed and dissolved. C. B is added to A and mixed and dispersed uniformly. D. C was pulverized and compression-molded into a dish to obtain a solid powdery eye shadow. The solid powdered eye shadow of Example 14 had excellent characteristics in all of suitable concealing properties when applied to the skin, adhesion to the skin, a uniform makeup film, and long lasting makeup.

[0055]

As described in detail above, the makeup cosmetic of the present invention has good adhesion to the skin, excellent concealing properties, can form a uniform makeup film, and has long lasting makeup. It has excellent quality of being good.

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Claims (5)

[Claims] (1) The following components (a) and (b): (a) an oil agent-treated titanium oxide, (b) a silicone-treated titanium oxide, and the amount of the titanium oxide in the component (a) and the component (b) )) In an amount by weight of 1: 0.05 to
A makeup cosmetic characterized by being 1: 0.2. 2. The composition according to claim 1, wherein the titanium oxide in the component (a) comprises at least one titanium oxide having an average particle size of 0.1 to 0.5 μm.
The makeup cosmetic according to claim 1, comprising at least one kind of titanium oxide having an average particle size of 0.01 to 0.08 µm. 3. The makeup cosmetic according to claim 1, wherein the titanium oxide in the component (b) is at least one kind of titanium oxide having an average particle size in a range of 0.1 to 0.5 μm. . 4. The composition according to claim 1, wherein the total amount of titanium oxide in the component (a) is 5 to 20% by weight.
The makeup cosmetic according to any one of the above. 5. The makeup cosmetic according to claim 1, wherein the dosage form is an oil-in-water type.