JP2000095662A - Cosmetic - Google Patents
CosmeticInfo
- Publication number
- JP2000095662A JP2000095662A JP10269221A JP26922198A JP2000095662A JP 2000095662 A JP2000095662 A JP 2000095662A JP 10269221 A JP10269221 A JP 10269221A JP 26922198 A JP26922198 A JP 26922198A JP 2000095662 A JP2000095662 A JP 2000095662A
- Authority
- JP
- Japan
- Prior art keywords
- cosmetic
- carbonate
- carbonate compound
- cream
- skin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 18
- -1 carbonate compound Chemical class 0.000 claims abstract description 26
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000006071 cream Substances 0.000 abstract description 12
- 239000006210 lotion Substances 0.000 abstract description 8
- 230000003020 moisturizing effect Effects 0.000 abstract description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 6
- 238000004040 coloring Methods 0.000 abstract description 5
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 abstract description 5
- 238000006243 chemical reaction Methods 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000049 pigment Substances 0.000 abstract description 3
- 238000010992 reflux Methods 0.000 abstract description 3
- 239000003963 antioxidant agent Substances 0.000 abstract description 2
- 239000000306 component Substances 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- 239000008213 purified water Substances 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- 239000002562 thickening agent Substances 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 239000004909 Moisturizer Substances 0.000 abstract 1
- 230000002421 anti-septic effect Effects 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 238000002845 discoloration Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical group 0.000 abstract 1
- 230000001333 moisturizer Effects 0.000 abstract 1
- 239000002304 perfume Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 229940124543 ultraviolet light absorber Drugs 0.000 abstract 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 14
- 239000000839 emulsion Substances 0.000 description 7
- 238000003786 synthesis reaction Methods 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 230000001953 sensory effect Effects 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 4
- 235000019645 odor Nutrition 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 206010040880 Skin irritation Diseases 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000036556 skin irritation Effects 0.000 description 3
- 231100000475 skin irritation Toxicity 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- 239000008158 vegetable oil Substances 0.000 description 3
- 150000004703 alkoxides Chemical class 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- JMPVESVJOFYWTB-UHFFFAOYSA-N dipropan-2-yl carbonate Chemical compound CC(C)OC(=O)OC(C)C JMPVESVJOFYWTB-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- QDTDKYHPHANITQ-UHFFFAOYSA-N 7-methyloctan-1-ol Chemical compound CC(C)CCCCCCO QDTDKYHPHANITQ-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004439 Isononyl alcohol Substances 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- UXXXZMDJQLPQPH-UHFFFAOYSA-N bis(2-methylpropyl) carbonate Chemical compound CC(C)COC(=O)OCC(C)C UXXXZMDJQLPQPH-UHFFFAOYSA-N 0.000 description 1
- RCEORVKQNSLBJN-CLFAGFIQSA-N bis[(z)-octadec-9-enyl] carbonate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)OCCCCCCCC\C=C/CCCCCCCC RCEORVKQNSLBJN-CLFAGFIQSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000008294 cold cream Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- GOAUNPQUDWQWCP-UHFFFAOYSA-N didodecyl carbonate Chemical compound CCCCCCCCCCCCOC(=O)OCCCCCCCCCCCC GOAUNPQUDWQWCP-UHFFFAOYSA-N 0.000 description 1
- VUPKGFBOKBGHFZ-UHFFFAOYSA-N dipropyl carbonate Chemical compound CCCOC(=O)OCCC VUPKGFBOKBGHFZ-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000005064 octadecenyl group Chemical group C(=CCCCCCCCCCCCCCCCC)* 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- CUQOHAYJWVTKDE-UHFFFAOYSA-N potassium;butan-1-olate Chemical compound [K+].CCCC[O-] CUQOHAYJWVTKDE-UHFFFAOYSA-N 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 210000002966 serum Anatomy 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、カーボネート化合
物である炭酸ジアルキルを化粧料成分の油性基剤として
配合することを特徴とし、経時的にも安定性に優れ、し
かものびが良く、しっとりした使用感を有する化粧料に
関する。TECHNICAL FIELD The present invention is characterized in that a dialkyl carbonate, which is a carbonate compound, is blended as an oily base of a cosmetic component, which has excellent stability over time, and has good spreadability and moist use. The present invention relates to a cosmetic having a feeling.
【０００２】[0002]
【従来の技術】従来より、植物油はその優れた潤滑作
用、保湿効果および良好な使用感から化粧品の原料とし
て広範囲に利用されている。しかし、植物油配合化粧料
は、硬化植物油を使用した場合を除き、保存安定性は悪
く、製品系において劣化臭や着色を引き起こし、さらに
は過酸化物を生成し皮膚に刺激を与える要因ともなる。
そのため例えば配合量に限度があり機能が充分に発揮で
きなかったり、合成油と併用するなどの方法がとられて
いた。また前記硬化油は、酸化安定性の低下原因となる
不飽和脂肪酸を水素添加により飽和脂肪酸に変えること
で酸化安定性を高めた油脂であるが、融点が高いために
化粧料への配合作業性が著しく低く、またグリース様の
使用感を与えるという欠点がある。2. Description of the Related Art Conventionally, vegetable oils have been widely used as raw materials for cosmetics because of their excellent lubricating action, moisturizing effect and good feeling of use. However, vegetable oil-containing cosmetics have poor storage stability, except when hardened vegetable oils are used, cause deterioration odors and coloring in product systems, and further cause peroxides to be generated and cause irritation to the skin.
For this reason, for example, methods have been employed in which the compounding amount is limited and the function cannot be sufficiently exhibited, or a method is used in combination with a synthetic oil. Further, the hardened oil is an oil or fat whose oxidative stability is enhanced by converting unsaturated fatty acid which causes a decrease in oxidative stability to a saturated fatty acid by hydrogenation. And the drawback is that it gives a grease-like feeling of use.
【０００３】[0003]
【発明が解決しようとする課題】本発明の目的は、熱、
ｐＨなどに対して安定な優れた油性基材として配合し、
臭気、着色、経時安定性、皮膚刺激性などの問題のな
い、のびが良く、さっぱりした使用感を有し、高い保湿
効果および柔軟効果を有する化粧料を提供することにあ
る。SUMMARY OF THE INVENTION An object of the present invention is to provide heat,
Formulated as an excellent oily base material that is stable against pH, etc.
An object of the present invention is to provide a cosmetic composition which has no problems such as odor, coloring, stability with time, and skin irritation, has good spreadability, has a refreshing feeling of use, and has a high moisturizing effect and a softening effect.
【０００４】[0004]
【課題を解決するための手段】前記目的を達成するた
め、本発明者らは鋭意検討の結果、カーボネート化合物
である炭酸ジアルキルを配合することにより、臭気、着
色、経時安定性、皮膚刺激性などの問題のない、のびが
良く、使用感がさっぱりとした良好な機能を持たせた化
粧料ができることを見出し、本発明を完成するに至っ
た。Means for Solving the Problems In order to achieve the above object, the present inventors have made intensive studies and found that by adding dialkyl carbonate, which is a carbonate compound, odor, coloring, stability over time, skin irritation, etc. The present inventors have found that there can be provided a cosmetic composition which does not have the problem described above, has good spreadability, and has a good function with a refreshing feeling of use, and has completed the present invention.
【０００５】[0005]
【発明の実施の形態】本発明は、下記の一般式（１）で
表されるカーボネート化合物を配合してなる化粧料に係
わるものである。BEST MODE FOR CARRYING OUT THE INVENTION The present invention relates to a cosmetic comprising a carbonate compound represented by the following general formula (1).
【化２】 本発明の一般式（１）で表されるカーボネート化合物の
Ｒ1及びＲ2は、同一又は異なる炭化水素基であり、分岐
構造や不飽和結合の有無によらず適宜に選択することが
できる。Embedded image R 1 and R 2 of the carbonate compound represented by the general formula (1) of the present invention are the same or different hydrocarbon groups, and can be appropriately selected regardless of the presence or absence of a branched structure or unsaturated bond.
【０００６】直鎖状炭化水素基の例としてはヘキシル、
オクチル、ノニル、デシル、ウンデシル、ドデシル、ト
リデシル、テトラデシル、ペンタデシル、ヘキサデシ
ル、オクタデシル、イコサニル、ドコサニル等があげら
れる。分岐状炭化水素基の例としてはイソペンチル、イ
ソオクチル、イソノニル、イソデシル、イソドデシル、
イソテトラデシル、イソヘキサデシル、イソオクタデシ
ル、イソエイコサニル、イソドコサニル等があげられ
る。不飽和結合を含む炭化水素基の例としてはヘキサデ
セニル、オクタデセニル等をあげることができる。Examples of linear hydrocarbon groups include hexyl,
Octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, octadecyl, icosanyl, docosanyl and the like can be mentioned. Examples of branched hydrocarbon groups are isopentyl, isooctyl, isononyl, isodecyl, isododecyl,
Isotetradecyl, isohexadecyl, isooctadecyl, isoeicosanyl, isodocosanil and the like. Examples of the hydrocarbon group containing an unsaturated bond include hexadecenyl, octadecenyl and the like.
【０００７】本発明の一般式（１）で表されるカーボネ
ート化合物の合成方法としては、ジアルキルカーボネー
トと前記炭化水素基を有するアルコールとを反応させる
ことにより行われる。かかる合成反応の出発原料である
ジアルキルカーボネートの具体例としては、ジメチルカ
ーボネート、ジエチルカーボネート、ジｎープロピルカ
ーボネート、ジイソプロピルカーボネート、ジイソプロ
ピルカーボネート、ジイソブチルカーボネート等の低沸
点物が好適である。合成反応は90℃から250℃、常圧環
流下、無触媒もしくは触媒を用いて行う。なお触媒を用
いる場合は、アルカリ金属、アルカリ土類金属又はそれ
らのアルコキシド等を反応原料の重量に対し０．００１
〜１．０％加える。触媒の例としては、リチウム、ナト
リウム、カリウム、セシウム、マグネシウム、カルシウ
ム、亜鉛、アルミニウム、チタン、スズ、コバルト、及
びこれらのアルコキシドである。反応終了後、副生する
低級アルコール、未反応物を除去、もしくは蒸留により
本発明のカーボネート化合物を得る。The method for synthesizing the carbonate compound represented by the general formula (1) of the present invention is carried out by reacting a dialkyl carbonate with the alcohol having a hydrocarbon group. As a specific example of the dialkyl carbonate which is a starting material of such a synthesis reaction, a low-boiling substance such as dimethyl carbonate, diethyl carbonate, di-n-propyl carbonate, diisopropyl carbonate, diisopropyl carbonate, diisobutyl carbonate and the like is preferable. The synthesis reaction is carried out at 90 ° C. to 250 ° C. under normal pressure reflux without using a catalyst or a catalyst. When a catalyst is used, an alkali metal, an alkaline earth metal, or an alkoxide thereof is used in an amount of 0.001 to 0.001 wt.
Add ~ 1.0%. Examples of catalysts are lithium, sodium, potassium, cesium, magnesium, calcium, zinc, aluminum, titanium, tin, cobalt and their alkoxides. After the completion of the reaction, the carbonate compound of the present invention is obtained by removing lower alcohol and unreacted substances by-produced or by distillation.
【０００８】かかるカーボネート化合物を化粧料として
配合するに当たっての配合量は、最終組成物の総量に対
し、０．０１重量％以上であり配合の上限は特に限定し
ない。また、本発明の化粧料の種類としては、特に限定
されるものではないが、とりわけ皮膚に対して使用する
公知の各種化粧品を対象とすることが望ましく、例えば
コールドクリーム、バニシングクリーム、クレンジング
クリーム、エモリエントクリーム、サンスクリーンクリ
ーム等の各種クリーム、乳液、化粧水、ファンデーショ
ン、洗顔料、口紅、美容液、パック剤等があげられる。
また、ヘアケア製品についても同様に制限はないが、特
にシャンプー、リンス、ヘアスタイリング剤、染毛剤等
を好適に例示できる。The amount of such a carbonate compound to be compounded as a cosmetic is 0.01% by weight or more based on the total amount of the final composition, and the upper limit of the compounding is not particularly limited. Further, the type of the cosmetic of the present invention is not particularly limited, but it is particularly desirable to target various known cosmetics used for the skin, such as cold cream, burnishing cream, cleansing cream, Various creams such as emollient cream and sunscreen cream, emulsions, lotions, foundations, facial cleansers, lipsticks, serums, packs and the like can be mentioned.
Similarly, there is no limitation on hair care products, but shampoos, rinses, hair styling agents, hair dyes and the like can be particularly preferably exemplified.
【０００９】本発明の化粧料は、前記カーボネート化合
物と他の公知の成分を用いて、常法により調製すること
ができる。すなわち公知の油性成分、水溶性成分、界面
活性剤、保湿剤、増粘剤、防腐剤、顔料、粉体、ｐＨ調
製剤、抗酸化剤、紫外線吸収剤、香料、色素、精製水等
を適宜に配合すればよい。The cosmetic of the present invention can be prepared by a conventional method using the above-mentioned carbonate compound and other known components. That is, known oil components, water-soluble components, surfactants, humectants, thickeners, preservatives, pigments, powders, pH adjusters, antioxidants, ultraviolet absorbers, fragrances, pigments, purified water, etc. May be blended.
【００１０】[0010]
【実施例】以下、実施例および比較例にて本発明を説明
する。実施例中の％は重量％を示す。尚、本発明は、こ
こに挙げた実施例に限定されるものではない。実施例中
の官能試験は下記のごとく実施した。 〔官能試験〕２０人のパネラーによる実用テストを行い
「さっぱりした使用感を感じる」「十分にのびが良い」
「十分に保湿効果がある」「十分に柔軟効果がある」と
答えたパネラーの人数を示した。The present invention will be described below with reference to examples and comparative examples. % In Examples shows% by weight. Note that the present invention is not limited to the embodiments described here. The sensory tests in the examples were performed as follows. [Sensory test] Perform a practical test by 20 panelists, "feel refreshing usability", "good enough spread"
The number of panelists who answered "sufficiently moisturizing effect" and "sufficiently softening effect" was shown.
【００１１】合成例１ ジメチルカーボネート１モルに、ドデシルアルコール２
モルを加え、触媒としてカリウムブトキシドを用いて、
常圧環流下、９０から２００℃で反応させた。反応終了
後、濾過により触媒を除去し、蒸留してジドデシルカー
ボネートを得た。Synthesis Example 1 Dodecyl alcohol 2 was added to 1 mol of dimethyl carbonate.
Mole, and using potassium butoxide as a catalyst,
The reaction was carried out at 90 to 200 ° C. under atmospheric pressure reflux. After completion of the reaction, the catalyst was removed by filtration and distilled to obtain didodecyl carbonate.
【００１２】合成例２ ジメチルカーボネート１モルと、オレイルアルコール２
モルを用い、合成例１と同様の方法でジオレイルカーボ
ネートを得た。Synthesis Example 2 1 mol of dimethyl carbonate and oleyl alcohol 2
Using a mole, dioleyl carbonate was obtained in the same manner as in Synthesis Example 1.
【００１３】合成例３ ジメチルカーボネート１モルに、イソノニルアルコール
２モルを用い、合成例１と同様の方法でジイソノニルカ
ーボネートを得た。Synthesis Example 3 Diisononyl carbonate was obtained in the same manner as in Synthesis Example 1 except that 2 mol of isononyl alcohol was used for 1 mol of dimethyl carbonate.
【００１４】実施例１（クリーム） 表１に示す処方及び、下記の製造方法によりクリームを
調製した。また比較のためのクリームを同様に調製し、
両クリームの官能評価を実施した。その結果を表２に示
す。本発明のクリームは肌に対する伸びがよく、さっぱ
りした使用感や十分な保湿効果、柔軟効果が認められ
た。Example 1 (Cream) A cream was prepared according to the formulation shown in Table 1 and the following production method. Also prepare a cream for comparison in the same way,
Sensory evaluation of both creams was performed. Table 2 shows the results. The cream of the present invention showed good stretch on the skin, and showed a refreshing feeling of use, a sufficient moisturizing effect, and a softening effect.
【００１５】[0015]
【表１】 [Table 1]
【００１６】〔製造方法〕 １〜６、９、10および12を加熱しながら混合し、70〜
80℃に保つ。 13に７、８および11を加えて加熱しながら混合し、70
〜80℃に保つ。 の混合物にの混合物を徐々に加えながら攪拌し、
均一に乳化する。 を水浴に置き、室温になるまで攪拌を続けてクリー
ムを得る。[Manufacturing method] 1 to 6, 9, 10 and 12 are mixed while heating.
Keep at 80 ° C. Add 7, 8 and 11 to 13 and mix while heating.
Keep at ~ 80 ° C. Stir while gradually adding the mixture to the mixture of
Emulsify uniformly. In a water bath and continue to stir to room temperature to obtain a cream.
【００１７】[0017]
【表２】 [Table 2]
【００１８】実施例２（乳液） 表３に示す処方及び、下記の製造方法により乳液を調製
した。また比較のための乳液を同様に調製し、両乳液の
官能評価を実施した。その結果を表４に示す。本発明の
乳液は肌に対する伸びがよく、さっぱりした使用感や十
分な保湿効果、柔軟効果が認められた。Example 2 (Emulsion) An emulsion was prepared according to the formulation shown in Table 3 and the following production method. In addition, emulsions for comparison were prepared in the same manner, and the sensory evaluation of both emulsions was performed. Table 4 shows the results. The emulsion of the present invention showed good stretch on the skin, and showed a refreshing feeling of use, a sufficient moisturizing effect, and a softening effect.
【００１９】[0019]
【表３】 [Table 3]
【００２０】〔製造方法〕 １〜８、11および13を加熱しながら混合し、70〜80℃
に保つ。 14に９、10および12を加えて加熱しながら混合し、70
〜80℃に保つ。 の混合物にの混合物を徐々に加えながら攪拌し、
均一に乳化する。 を水浴に置き、室温になるまで攪拌を続けて乳液を
得る。[Production method] 1-8, 11 and 13 were mixed while heating, and 70-80 ° C.
To keep. Add 9, 10, and 12 to 14 and mix while heating.
Keep at ~ 80 ° C. Stir while gradually adding the mixture to the mixture of
Emulsify uniformly. In a water bath and continue stirring until it reaches room temperature to obtain an emulsion.
【００２１】[0021]
【表４】 [Table 4]
【００２２】実施例３（化粧水） 表５に示す処方及び、下記の製造方法により化粧水を調
製した。また比較のための化粧水を同様に調製し、両化
粧水の官能評価を実施した。その結果を表６に示す。本
発明の化粧水は肌に対する伸びがよく、さっぱりした使
用感や十分な保湿効果が認められた。Example 3 (Lotion) A lotion was prepared according to the formulation shown in Table 5 and the following production method. In addition, a lotion for comparison was prepared in the same manner, and the sensory evaluation of both lotions was performed. Table 6 shows the results. The lotion of the present invention showed good stretch on the skin, and showed a refreshing feeling of use and a sufficient moisturizing effect.
【００２３】[0023]
【表５】 [Table 5]
【００２４】〔製造方法〕 12に１〜３および７〜９を加え、室温下で溶解する。 13に４〜６および10、11を加え、室温下で溶解する。 の混合物にの混合物を徐々に加えながら攪拌し、
均一に乳化する。[Production method] 1 to 3 and 7 to 9 are added to 12 and dissolved at room temperature. 13. Add 4-6 and 10, 11 to 13 and dissolve at room temperature. Stir while gradually adding the mixture to the mixture of
Emulsify uniformly.
【００２５】[0025]
【表６】 [Table 6]
【００２６】[0026]
【発明の効果】本発明によれば、カーボネート化合物で
ある炭酸ジアルキルを油性基剤として配合してなる化粧
料が提供される。本化粧料は臭気、着色、経時安定性、
皮膚刺激性などの問題がなく、加えて伸びが良く、使用
感がさっぱりとし、高い保湿効果、および柔軟効果を奏
する。According to the present invention, there is provided a cosmetic comprising a carbonate compound, dialkyl carbonate, as an oily base. This cosmetic has odor, coloring, stability over time,
There is no problem such as skin irritation, and in addition, it has good elongation, refreshes the feeling of use, and exhibits a high moisturizing effect and a softening effect.
Claims (1)
ト化合物を含有してなる化粧料。 【化１】 （式中Ｒ1及びＲ2は、同一あるいは異なるものであっ
て、炭素数６から３０の直鎖状又は分岐状の炭化水素基
を表す。）1. A cosmetic comprising a carbonate compound represented by the following general formula (1). Embedded image (In the formula, R 1 and R 2 are the same or different and represent a linear or branched hydrocarbon group having 6 to 30 carbon atoms.)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10269221A JP2000095662A (en) | 1998-09-24 | 1998-09-24 | Cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10269221A JP2000095662A (en) | 1998-09-24 | 1998-09-24 | Cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2000095662A true JP2000095662A (en) | 2000-04-04 |
Family
ID=17469361
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10269221A Pending JP2000095662A (en) | 1998-09-24 | 1998-09-24 | Cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2000095662A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004502709A (en) * | 2000-07-07 | 2004-01-29 | コグニス・ドイッチュランド・ゲゼルシヤフト・ミト・ベシュレンクテル・ハフツング・ウント・コンパニー・コマンデイトゲゼルシヤフト | aerosol |
| JP2005075833A (en) * | 2003-09-03 | 2005-03-24 | Cognis Deutschland Gmbh & Co Kg | Emollient mixture for cosmetic and pharmaceutical compositions |
| JP2006516029A (en) * | 2003-01-08 | 2006-06-15 | コグニス・アイピー・マネージメント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | Wax dispersion |
| JP2006517205A (en) * | 2003-01-08 | 2006-07-20 | ジョンソン・アンド・ジョンソン・ゲーエムベーハー | Products containing sheet material and wax dispersion |
| JP2006521410A (en) * | 2003-01-08 | 2006-09-21 | ジョンソン・アンド・ジョンソン・ゲーエムベーハー | Products containing applicators and wax dispersions |
| US7111934B2 (en) | 2003-10-02 | 2006-09-26 | Seiko Epson Corporation | Recording medium feeding apparatus, recording apparatus, liquid ejecting apparatus |
| US20080166431A1 (en) * | 2001-07-13 | 2008-07-10 | Achim Ansmann | Smooth-Feeling Wax-Based Compositions for Personal Care Preparations |
| JP2010511645A (en) * | 2006-12-08 | 2010-04-15 | コグニス・アイピー・マネージメント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | Dialkyl carbonates of branched alcohols and their use |
-
1998
- 1998-09-24 JP JP10269221A patent/JP2000095662A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004502709A (en) * | 2000-07-07 | 2004-01-29 | コグニス・ドイッチュランド・ゲゼルシヤフト・ミト・ベシュレンクテル・ハフツング・ウント・コンパニー・コマンデイトゲゼルシヤフト | aerosol |
| US20080166431A1 (en) * | 2001-07-13 | 2008-07-10 | Achim Ansmann | Smooth-Feeling Wax-Based Compositions for Personal Care Preparations |
| US8716336B2 (en) * | 2001-07-13 | 2014-05-06 | Cognis Ip Management Gmbh | Smooth-feeling wax-based compositions for personal care preparations |
| JP2006516029A (en) * | 2003-01-08 | 2006-06-15 | コグニス・アイピー・マネージメント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | Wax dispersion |
| JP2006517205A (en) * | 2003-01-08 | 2006-07-20 | ジョンソン・アンド・ジョンソン・ゲーエムベーハー | Products containing sheet material and wax dispersion |
| JP2006521410A (en) * | 2003-01-08 | 2006-09-21 | ジョンソン・アンド・ジョンソン・ゲーエムベーハー | Products containing applicators and wax dispersions |
| JP2005075833A (en) * | 2003-09-03 | 2005-03-24 | Cognis Deutschland Gmbh & Co Kg | Emollient mixture for cosmetic and pharmaceutical compositions |
| US7111934B2 (en) | 2003-10-02 | 2006-09-26 | Seiko Epson Corporation | Recording medium feeding apparatus, recording apparatus, liquid ejecting apparatus |
| JP2010511645A (en) * | 2006-12-08 | 2010-04-15 | コグニス・アイピー・マネージメント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | Dialkyl carbonates of branched alcohols and their use |
| KR101485203B1 (en) * | 2006-12-08 | 2015-01-26 | 코그니스 아이피 매니지먼트 게엠베하 | Dialkyl carbonates of branched alcohols and their uses |
| US10544086B2 (en) | 2006-12-08 | 2020-01-28 | Cognis Ip Management Gmbh | Dialkyl carbonates of branched alcohols and their use |
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