IT1271622B - Processo di (co) polimerizzazione in sospensione per la preparazione ddi fluoropolimeri termoplastici contenenti idrogeno - Google Patents
Processo di (co) polimerizzazione in sospensione per la preparazione ddi fluoropolimeri termoplastici contenenti idrogenoInfo
- Publication number
- IT1271622B IT1271622B ITMI940521A ITMI940521A IT1271622B IT 1271622 B IT1271622 B IT 1271622B IT MI940521 A ITMI940521 A IT MI940521A IT MI940521 A ITMI940521 A IT MI940521A IT 1271622 B IT1271622 B IT 1271622B
- Authority
- IT
- Italy
- Prior art keywords
- suspension
- preparation
- containing hydrogen
- polymerization process
- thermoplastic fluoropolymers
- Prior art date
Links
- 229920002313 fluoropolymer Polymers 0.000 title abstract 2
- 239000004811 fluoropolymer Substances 0.000 title abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 2
- 239000001257 hydrogen Substances 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 239000000725 suspension Substances 0.000 title abstract 2
- 229920001169 thermoplastic Polymers 0.000 title abstract 2
- 239000004416 thermosoftening plastic Substances 0.000 title abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title 1
- 229920001577 copolymer Polymers 0.000 abstract 2
- YFZCNXJOYHYIGC-UHFFFAOYSA-N (2,2,2-trichloroacetyl) 2,2,2-trichloroethaneperoxoate Chemical compound ClC(Cl)(Cl)C(=O)OOC(=O)C(Cl)(Cl)Cl YFZCNXJOYHYIGC-UHFFFAOYSA-N 0.000 abstract 1
- MSTZXMFWGUDAOI-UHFFFAOYSA-N (2,2-dichloro-2-fluoroacetyl) 2,2-dichloro-2-fluoroethaneperoxoate Chemical compound FC(Cl)(Cl)C(=O)OOC(=O)C(F)(Cl)Cl MSTZXMFWGUDAOI-UHFFFAOYSA-N 0.000 abstract 1
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 101000597193 Homo sapiens Telethonin Proteins 0.000 abstract 1
- 102100035155 Telethonin Human genes 0.000 abstract 1
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 abstract 1
- -1 for example Chemical class 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000003505 polymerization initiator Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
- C08F4/34—Per-compounds with one peroxy-radical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/18—Monomers containing fluorine
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
Abstract
L'invenzione si riferisce ad un processo di (co) polimerizzazione in sospensione per la preparazione di fluoropolimeri termoplastici contenenti idrogeno, quali ad esempio i copolimeri etilene/clorotrifluoroetilene od etileneltetra-fluoroetilene, oppure gli omopolimeri o copolimerl del vinilidenfluoruro, in cui si impiega come iniziatore di polimerizzazione il bis-diclorofluoroacetil perossido (CFCl2-CO-O)2 (DCFAP). Da tale processo si ottengono prodotti dotati di elevata stabilità termica, significativamente maggiore di quella ottenibile utilizzando il bis-tricloroacetilperossido (TCAP).
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI940521A IT1271622B (it) | 1994-03-21 | 1994-03-21 | Processo di (co) polimerizzazione in sospensione per la preparazione ddi fluoropolimeri termoplastici contenenti idrogeno |
| AT95103468T ATE157995T1 (de) | 1994-03-21 | 1995-03-10 | Suspensions(co)polymerisationsverfahren zur herstellung von wasserstofhältigen thermoplastischen fluorpolymeren |
| EP95103468A EP0673951B1 (en) | 1994-03-21 | 1995-03-10 | (Co)polymerization process in suspension for preparing hydrogen containing thermoplastic fluoropolymers |
| DE69500667T DE69500667T2 (de) | 1994-03-21 | 1995-03-10 | Suspensions(co)polymerisationsverfahren zur Herstellung von wasserstoffhältigen thermoplastischen Fluorpolymeren |
| ES95103468T ES2108503T3 (es) | 1994-03-21 | 1995-03-10 | Procedimiento de (co)polimerizacion en suspension para preparar fluorpolimeros termoplasticos que contienen hidrogeno. |
| US08/405,811 US5569728A (en) | 1994-03-21 | 1995-03-16 | (co)polymerization process in suspension for preparing hydrogen containing thermoplastic fluoropolymers |
| CA002144891A CA2144891A1 (en) | 1994-03-21 | 1995-03-17 | (co)polymerization process in suspension for preparing hydrogen containing thermoplastic fluoropolymers |
| RU95103971A RU2139890C1 (ru) | 1994-03-21 | 1995-03-20 | Способ получения водородсодержащих термопластичных фторполимеров |
| KR1019950005877A KR100355792B1 (ko) | 1994-03-21 | 1995-03-20 | 열가소성수소-함유플루오르중합체를생성하기위한서스펜션내에서의(공)중합방법 |
| CN95114811A CN1050848C (zh) | 1994-03-21 | 1995-03-21 | 制备含氢热塑性氟聚合物的悬浮(共)聚合方法 |
| JP06321995A JP3989975B2 (ja) | 1994-03-21 | 1995-03-22 | 水素含有熱可塑性フッ化ポリマーの製造のための懸濁重合方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI940521A IT1271622B (it) | 1994-03-21 | 1994-03-21 | Processo di (co) polimerizzazione in sospensione per la preparazione ddi fluoropolimeri termoplastici contenenti idrogeno |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| ITMI940521A0 ITMI940521A0 (it) | 1994-03-21 |
| ITMI940521A1 ITMI940521A1 (it) | 1995-09-21 |
| IT1271622B true IT1271622B (it) | 1997-06-04 |
Family
ID=11368276
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ITMI940521A IT1271622B (it) | 1994-03-21 | 1994-03-21 | Processo di (co) polimerizzazione in sospensione per la preparazione ddi fluoropolimeri termoplastici contenenti idrogeno |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5569728A (it) |
| EP (1) | EP0673951B1 (it) |
| JP (1) | JP3989975B2 (it) |
| KR (1) | KR100355792B1 (it) |
| CN (1) | CN1050848C (it) |
| AT (1) | ATE157995T1 (it) |
| CA (1) | CA2144891A1 (it) |
| DE (1) | DE69500667T2 (it) |
| ES (1) | ES2108503T3 (it) |
| IT (1) | IT1271622B (it) |
| RU (1) | RU2139890C1 (it) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1284112B1 (it) * | 1996-07-05 | 1998-05-08 | Ausimont Spa | Copolimeri fluorurati dell'etilene |
| IT1286028B1 (it) * | 1996-07-09 | 1998-07-07 | Ausimont Spa | Processo di polimerizzazione in sospensione di monomeri fluorurati |
| IT1290426B1 (it) * | 1997-03-21 | 1998-12-03 | Ausimont Spa | Polimeri fluorurati termoprocessabili |
| IT1298091B1 (it) * | 1998-01-09 | 1999-12-20 | Ausimont Spa | Processo per la preparazione degli alogenuri di diclorofluoroacetile |
| IT1301451B1 (it) | 1998-06-04 | 2000-06-13 | Ausimont Spa | Copolimeri del clorotrifluoroetilene |
| WO2001032726A1 (en) * | 1999-11-03 | 2001-05-10 | Atofina Chemicals, Inc. | Low crystallinity vinylidene fluoride hexafluoropropylene copolymers |
| IT1317833B1 (it) | 2000-02-15 | 2003-07-15 | Ausimont Spa | Polimeri fluorurati termoprocessabili. |
| IT1317834B1 (it) | 2000-02-15 | 2003-07-15 | Ausimont Spa | Fluoropolimeri termoplastici. |
| US6919497B2 (en) * | 2002-09-10 | 2005-07-19 | First Line Seeds Ltd. | Soybean cultivar SN83544 |
| ITMI20030642A1 (it) * | 2003-04-01 | 2004-10-02 | Solvay Solexis Spa | Composizioni termoprocessabili a base di ctfe |
| EP1743921A1 (en) | 2005-07-13 | 2007-01-17 | Solvay Solexis S.p.A. | Thermoplastic halopolymer composition |
| EP1743920A1 (en) | 2005-07-13 | 2007-01-17 | Solvay Solexis S.p.A. | Thermoplastic fluoropolymer composition |
| CN101195669B (zh) * | 2006-12-04 | 2011-11-16 | 上海三爱富新材料股份有限公司 | 一种偏氟乙烯聚合物的制备方法 |
| CN103304712A (zh) * | 2013-05-07 | 2013-09-18 | 山东森福新材料有限公司 | 一种珠粒状聚三氟氯乙烯树脂的制造方法 |
| CN104356267A (zh) * | 2013-10-30 | 2015-02-18 | 东莞市长安东阳光铝业研发有限公司 | 一种聚三氟氯乙烯树脂的制备方法 |
| WO2017033689A1 (ja) * | 2015-08-27 | 2017-03-02 | 旭硝子株式会社 | 含フッ素重合体用開始剤組成物および含フッ素重合体の製造法 |
| CN113260639A (zh) | 2018-12-20 | 2021-08-13 | 索尔维特殊聚合物意大利有限公司 | 用于制备全卤酰基过氧化物的方法 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2580358A (en) * | 1948-05-17 | 1951-12-25 | William T Miller | Method for storing perhaloacetyl peroxide and stabilized perhaloacetyl peroxide |
| US2559630A (en) * | 1950-03-04 | 1951-07-10 | Du Pont | Fluorinated acyl peroxides |
| US3053820A (en) * | 1958-09-03 | 1962-09-11 | Borden Co | Aqueous suspension polymerization in the presence of alkane hydrocarbons |
| US3642742A (en) * | 1969-04-22 | 1972-02-15 | Du Pont | Tough stable tetrafluoroethylene-fluoroalkyl perfluorovinyl ether copolymers |
| US3624250A (en) * | 1970-01-20 | 1971-11-30 | Du Pont | Copolymers of ethylene/tetrafluoroethylene and of ethylene/chlorotrifluoroethylene |
| US3865845A (en) * | 1971-02-24 | 1975-02-11 | Paul Raphael Resnick | Fluorinated dioxoles |
| US3978030A (en) * | 1973-08-01 | 1976-08-31 | E. I. Du Pont De Nemours And Company | Polymers of fluorinated dioxoles |
| JPS52887A (en) * | 1975-06-23 | 1977-01-06 | Daikin Ind Ltd | Preparation of tetrafluoroethylene-hexafluoropropylene copolymer |
| JPS5838707A (ja) * | 1981-08-20 | 1983-03-07 | イ−・アイ・デユポン・デ・ニモアス・アンド・カンパニ− | パ−フルオロ−2,2−ジメチル−1,3−ジオキソ−ルの無定形共重合体 |
| US4429143A (en) * | 1981-09-28 | 1984-01-31 | E. I. Du Pont De Nemours & Co. | Cyclic monomers derived from trifluoropyruvate esters |
| US4399264A (en) * | 1981-11-19 | 1983-08-16 | E. I. Du Pont De Nemours & Co. | Perfluorodioxole and its polymers |
| JPS58189210A (ja) * | 1982-04-30 | 1983-11-04 | Daikin Ind Ltd | テトラフルオロエチレン/フルオロ(アルキルビニルエ−テル)共重合体の製法 |
| JPS59147007A (ja) * | 1983-02-12 | 1984-08-23 | Daikin Ind Ltd | テトラフルオロエチレン/エチレン系共重合体の製造法 |
| FR2542319B1 (fr) * | 1983-03-10 | 1985-07-19 | Solvay | Procede pour la polymerisation dans un milieu aqueux de mise en suspension du fluorure de vinylidene |
| JPS59197411A (ja) * | 1983-04-25 | 1984-11-09 | Daikin Ind Ltd | エチレン−テトラフルオロエチレンまたはクロロトリフルオロエチレン系共重合体 |
| DE3584930D1 (de) * | 1984-09-24 | 1992-01-30 | Ausimont Spa | Verfahren zur herstellung von vinylidenfluorid, homo- und copolymeren. |
| EP0185242A3 (en) * | 1984-12-20 | 1986-11-05 | Ausimont, U.S.A. | Copolymers of chlorotrifluoroethylene, ethylene and perfluoroalkylethylenes |
| JPS6323907A (ja) * | 1986-07-16 | 1988-02-01 | Nippon Mektron Ltd | パ−オキサイド加硫可能な含フツ素エラストマ−の製造方法 |
| EP0526216B1 (en) * | 1991-08-01 | 1995-12-27 | Kureha Chemical Industry Co., Ltd. | Method of making vinylidene fluoride polymer |
| US5182342A (en) * | 1992-02-28 | 1993-01-26 | E. I. Du Pont De Nemours And Company | Hydrofluorocarbon solvents for fluoromonomer polymerization |
| US5399643A (en) * | 1992-04-22 | 1995-03-21 | Diakin Industries Ltd. | Method for preparation of tetrafluoroethylene/hexafluoropropylene copolymer |
| IT1263955B (it) * | 1993-02-23 | 1996-09-05 | Ausimont Spa | Processo di (co) polimerizzazione radicalica di monomeri olefinici fluorurati |
-
1994
- 1994-03-21 IT ITMI940521A patent/IT1271622B/it active IP Right Grant
-
1995
- 1995-03-10 DE DE69500667T patent/DE69500667T2/de not_active Expired - Fee Related
- 1995-03-10 AT AT95103468T patent/ATE157995T1/de active
- 1995-03-10 EP EP95103468A patent/EP0673951B1/en not_active Expired - Lifetime
- 1995-03-10 ES ES95103468T patent/ES2108503T3/es not_active Expired - Lifetime
- 1995-03-16 US US08/405,811 patent/US5569728A/en not_active Expired - Lifetime
- 1995-03-17 CA CA002144891A patent/CA2144891A1/en not_active Abandoned
- 1995-03-20 RU RU95103971A patent/RU2139890C1/ru active
- 1995-03-20 KR KR1019950005877A patent/KR100355792B1/ko not_active Expired - Fee Related
- 1995-03-21 CN CN95114811A patent/CN1050848C/zh not_active Expired - Fee Related
- 1995-03-22 JP JP06321995A patent/JP3989975B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CA2144891A1 (en) | 1995-09-22 |
| ITMI940521A1 (it) | 1995-09-21 |
| EP0673951B1 (en) | 1997-09-10 |
| US5569728A (en) | 1996-10-29 |
| KR950032317A (ko) | 1995-12-20 |
| JPH07304809A (ja) | 1995-11-21 |
| DE69500667T2 (de) | 1998-01-22 |
| EP0673951A1 (en) | 1995-09-27 |
| KR100355792B1 (ko) | 2002-12-11 |
| JP3989975B2 (ja) | 2007-10-10 |
| ES2108503T3 (es) | 1997-12-16 |
| ATE157995T1 (de) | 1997-09-15 |
| RU2139890C1 (ru) | 1999-10-20 |
| DE69500667D1 (de) | 1997-10-16 |
| RU95103971A (ru) | 1997-03-20 |
| CN1112567A (zh) | 1995-11-29 |
| ITMI940521A0 (it) | 1994-03-21 |
| CN1050848C (zh) | 2000-03-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 0001 | Granted | ||
| TA | Fee payment date (situation as of event date), data collected since 19931001 |
Effective date: 19970324 |