IT1251461B - Procedimento per la produzione di vanadio bis-areni da ossicloruro di vanadio - Google Patents
Procedimento per la produzione di vanadio bis-areni da ossicloruro di vanadioInfo
- Publication number
- IT1251461B IT1251461B ITMI911934A IT1251461B IT 1251461 B IT1251461 B IT 1251461B IT MI911934 A ITMI911934 A IT MI911934A IT 1251461 B IT1251461 B IT 1251461B
- Authority
- IT
- Italy
- Prior art keywords
- arene
- chloride
- vanadium
- aluminium
- oxy
- Prior art date
Links
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 title abstract 6
- 150000004945 aromatic hydrocarbons Chemical class 0.000 title abstract 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 title abstract 4
- 229910052720 vanadium Inorganic materials 0.000 title abstract 4
- 229910052782 aluminium Inorganic materials 0.000 title abstract 3
- 229910052751 metal Inorganic materials 0.000 title abstract 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 title abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 title 2
- 239000004411 aluminium Substances 0.000 abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 2
- ZHXZNKNQUHUIGN-UHFFFAOYSA-N chloro hypochlorite;vanadium Chemical compound [V].ClOCl ZHXZNKNQUHUIGN-UHFFFAOYSA-N 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 125000002015 acyclic group Chemical group 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Viene descritto un procedimento per la preparazione di un vanadio bis-arene, [V(arene)2], a partire da ossicloruro di vanadio, alluminio metallico, tricloruro di alluminio ed un arene, in cui:- (a) vengono posti a contatto, in un primo stadio di reazione, vanadio ossicloruro (VOCl3), alluminio metallico attivo e alluminio tricloruro, in un arene liquido, per trasformare l'ossicloruro di vanadio in un cloruro di vanadio in stato di ossidazione (III);- (b) viene aggiunto ulteriore alluminio metallico alla miscela di reazione dello stadio (a) per formare il complesso [V(arene)2] + [AlC14] -;- (c) viene aggiunto un etere ciclico o aliciclico liquido al prodotto della reazione dello stadio (b) per ridurre [V(arene)2] + in [V(arene)2]; e - (d) si recupera il vanadio bis-arene [V(arene)2] dal prodotto della reazione dello stadio (c).I vanadio bis-areni così ottenuti sono utili nella preparazione di catalizzatori di polimerizzazione delle olefine.
Priority Applications (23)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT91MI1934 IT1251461B (it) | 1991-07-12 | 1991-07-12 | Procedimento per la produzione di vanadio bis-areni da ossicloruro di vanadio |
| AU19483/92A AU647296B2 (en) | 1991-07-12 | 1992-07-07 | Procedure for the producing of vanadium bis-arenes from vanadium oxychloride |
| DZ920088A DZ1598A1 (fr) | 1991-07-12 | 1992-07-08 | Procédé de production de vanadium-bis arènes à partir d'exychlorure de vanadium. |
| EP92202086A EP0525857B1 (en) | 1991-07-12 | 1992-07-08 | Procedure for the producing of vanadium bis-arenes from vanadium oxychloride |
| FI923151A FI104900B (fi) | 1991-07-12 | 1992-07-08 | Menetelmä vanadiini-bis-areenien valmistamiseksi vanadiinioksikloridista |
| DE69213605T DE69213605T2 (de) | 1991-07-12 | 1992-07-08 | Verfahren zur Herstellung von Vanadium-bisarenen aus Vanadiumoxychlorid |
| DK92202086.2T DK0525857T3 (it) | 1991-07-12 | 1992-07-08 | |
| ES92202086T ES2092012T3 (es) | 1991-07-12 | 1992-07-08 | Procedimiento para la produccion de bis-arenos de vanadio a partir de oxicloruro de vanadio. |
| AT92202086T ATE142633T1 (de) | 1991-07-12 | 1992-07-08 | Verfahren zur herstellung von vanadium-bisarenen aus vanadiumoxychlorid |
| NO922709A NO303286B1 (no) | 1991-07-12 | 1992-07-09 | FremgangsmÕte for fremstilling av vanadium-bis-arener |
| US07/911,286 US5210244A (en) | 1991-07-12 | 1992-07-09 | Procedure for the production of vanadium bis-arenes from vanadium oxychloride |
| SU925052317A RU2083582C1 (ru) | 1991-07-12 | 1992-07-10 | Способ получения бис-ареновых производных ванадия из оксихлорида ванадия |
| MX9204064A MX9204064A (es) | 1991-07-12 | 1992-07-10 | Procedimiento para la produccion de bis-arenos de vanadio a partir de oxicloruro de vanadio. |
| TNTNSN92061A TNSN92061A1 (fr) | 1991-07-12 | 1992-07-10 | Procede de production de vanadium-bis-arenes a partir d'oxychlorure de vanadium |
| CA002073634A CA2073634C (en) | 1991-07-12 | 1992-07-10 | Process for the production of vanadium bis-arenes from vanadium oxychloride |
| EG37992A EG21012A (en) | 1991-07-12 | 1992-07-11 | Procedure for the producing of vanadium bis-arenes from vanadium oxychloride |
| KR1019920012375A KR950006545B1 (ko) | 1991-07-12 | 1992-07-11 | 바나듐 옥시클로라이드로부터의 바나듐 비스-아렌 제조방법 |
| CN92105624A CN1031712C (zh) | 1991-07-12 | 1992-07-11 | 用氯氧化钒生产钒二芳烃的方法 |
| JP4185409A JPH05194556A (ja) | 1991-07-12 | 1992-07-13 | オキシ塩化バナジウムからビスアレーンバナジウムを製造する方法 |
| BR929202662A BR9202662A (pt) | 1991-07-12 | 1992-07-13 | Processo para preparacao de um vanadio bis-areno /v(areno)2/ |
| AR92322727A AR247745A1 (es) | 1991-07-12 | 1992-07-13 | Procedimiento para la preparacion de un bis-areno de vanadio ¡v(areno)2¿, partiendo de oxicloruro de vanadio, metal de aluminio, tricloruro de aluminio y un areno. |
| SA92130177A SA92130177B1 (ar) | 1991-07-12 | 1992-10-17 | طريقة لانتاج ارينات فانيديوم مزدوجة من أكسي كلوريد فانيديوم |
| GR960402686T GR3021323T3 (en) | 1991-07-12 | 1996-10-10 | Procedure for the producing of vanadium bis-arenes from vanadium oxychloride |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT91MI1934 IT1251461B (it) | 1991-07-12 | 1991-07-12 | Procedimento per la produzione di vanadio bis-areni da ossicloruro di vanadio |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| ITMI911934A0 ITMI911934A0 (it) | 1991-07-12 |
| ITMI911934A1 ITMI911934A1 (it) | 1993-01-12 |
| IT1251461B true IT1251461B (it) | 1995-05-15 |
Family
ID=11360337
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IT91MI1934 IT1251461B (it) | 1991-07-12 | 1991-07-12 | Procedimento per la produzione di vanadio bis-areni da ossicloruro di vanadio |
Country Status (2)
| Country | Link |
|---|---|
| IT (1) | IT1251461B (it) |
| SA (1) | SA92130177B1 (it) |
-
1991
- 1991-07-12 IT IT91MI1934 patent/IT1251461B/it active IP Right Grant
-
1992
- 1992-10-17 SA SA92130177A patent/SA92130177B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ITMI911934A1 (it) | 1993-01-12 |
| ITMI911934A0 (it) | 1991-07-12 |
| SA92130177B1 (ar) | 2004-05-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 0001 | Granted | ||
| TA | Fee payment date (situation as of event date), data collected since 19931001 |
Effective date: 19970710 |