IT1161225B - Prodn. of 2,3-di:hydro-2,2-di:methyl -7-benzo-furanol - Google Patents
Prodn. of 2,3-di:hydro-2,2-di:methyl -7-benzo-furanolInfo
- Publication number
- IT1161225B IT1161225B IT20739/83A IT2073983A IT1161225B IT 1161225 B IT1161225 B IT 1161225B IT 20739/83 A IT20739/83 A IT 20739/83A IT 2073983 A IT2073983 A IT 2073983A IT 1161225 B IT1161225 B IT 1161225B
- Authority
- IT
- Italy
- Prior art keywords
- prodn
- furanol
- benzo
- hydro
- methyl
- Prior art date
Links
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 title 1
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 abstract 3
- JIGUICYYOYEXFS-UHFFFAOYSA-N 3-tert-butylbenzene-1,2-diol Chemical compound CC(C)(C)C1=CC=CC(O)=C1O JIGUICYYOYEXFS-UHFFFAOYSA-N 0.000 abstract 2
- AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical compound CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 abstract 2
- WJGPNUBJBMCRQH-UHFFFAOYSA-N 2,2-dimethyl-2,3-dihydro-1-benzofuran-7-ol Chemical compound C1=CC(O)=C2OC(C)(C)CC2=C1 WJGPNUBJBMCRQH-UHFFFAOYSA-N 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 150000007942 carboxylates Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 230000008707 rearrangement Effects 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
Landscapes
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Prodn. of 2,3-dihydro-2,2-dimethyl -7-benzofuranol of formula (I) comprises (1) reaction of t-butyl catechol (II) or catechol (III) with isobutyraldehyde (IV) in presence of an oxide, hydroxide, alcoholate or carboxylate of a metal of Gps. IA, IIA, IIB or VIIB of the Periodic System; (2) rearrangement of the prods., opt. after removal of low boiling components, by contact with an acidic cpd., followed by recovery of (I), opt. after further treatment.
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT20739/83A IT1161225B (en) | 1983-04-22 | 1983-04-22 | Prodn. of 2,3-di:hydro-2,2-di:methyl -7-benzo-furanol |
| EP84200540A EP0123357A3 (en) | 1983-04-22 | 1984-04-16 | Process for the preparation of 2,3-bihydro-2,2-dimethyl-7-benzofuranol |
| NO841531A NO841531L (en) | 1983-04-22 | 1984-04-17 | PROCEDURE FOR PREPARING 2,3-BIHYDRO-2,2-DIMETHYL-7,7-BENZOFURANOL. |
| ES532167A ES8602736A1 (en) | 1983-04-22 | 1984-04-18 | Process for the preparation of 2,3-bihydro-2,2-dimethyl-7-benzofuranol. |
| AU27059/84A AU2705984A (en) | 1983-04-22 | 1984-04-18 | Process for the preparation of 2,3-dihydro-2,2-dimethyl-7- benzofuranol |
| DK200784A DK200784A (en) | 1983-04-22 | 1984-04-18 | METHOD FOR PREPARING 2,3-DIHYDRO-2,2-DIMETHYL-7-BENZOFURANOL |
| US06/602,214 US4562266A (en) | 1983-04-22 | 1984-04-19 | Process for the preparation of 2,3-dihydro-2,2-dimethyl-7-benzofuranol |
| IL71591A IL71591A (en) | 1983-04-22 | 1984-04-19 | Process for the preparation of 2,3-dihydro-2,2-dimethyl-7-benzofuranol |
| CA000452373A CA1212682A (en) | 1983-04-22 | 1984-04-19 | Process for the preparation of 2,3-bihydro-2,2- dimethyl-7-benzofuranol |
| SU843732808A SU1355129A3 (en) | 1983-04-22 | 1984-04-20 | Method of producing 2.3-dihydro-2.2-dimethyl- 7 - benzofuranol |
| SU853853839A SU1376945A3 (en) | 1983-04-22 | 1985-02-11 | Method of producing 2.3-dihydro-2.2-dimethyl-7-benzofuranole |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT20739/83A IT1161225B (en) | 1983-04-22 | 1983-04-22 | Prodn. of 2,3-di:hydro-2,2-di:methyl -7-benzo-furanol |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IT8320739A0 IT8320739A0 (en) | 1983-04-22 |
| IT1161225B true IT1161225B (en) | 1987-03-18 |
Family
ID=11171324
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IT20739/83A IT1161225B (en) | 1983-04-22 | 1983-04-22 | Prodn. of 2,3-di:hydro-2,2-di:methyl -7-benzo-furanol |
Country Status (1)
| Country | Link |
|---|---|
| IT (1) | IT1161225B (en) |
-
1983
- 1983-04-22 IT IT20739/83A patent/IT1161225B/en active
Also Published As
| Publication number | Publication date |
|---|---|
| IT8320739A0 (en) | 1983-04-22 |
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