IL43425A - Continuous process for removing nitrates from wastewaters by extraction - Google Patents
Continuous process for removing nitrates from wastewaters by extractionInfo
- Publication number
- IL43425A IL43425A IL43425A IL4342573A IL43425A IL 43425 A IL43425 A IL 43425A IL 43425 A IL43425 A IL 43425A IL 4342573 A IL4342573 A IL 4342573A IL 43425 A IL43425 A IL 43425A
- Authority
- IL
- Israel
- Prior art keywords
- solvent
- process according
- stripping
- water
- waste water
- Prior art date
Links
- 239000002351 wastewater Substances 0.000 title claims 8
- 150000002823 nitrates Chemical class 0.000 title claims 5
- 238000000605 extraction Methods 0.000 title claims 4
- 238000010924 continuous production Methods 0.000 title claims 2
- 239000002904 solvent Substances 0.000 claims 10
- 238000000034 method Methods 0.000 claims 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 6
- 239000000126 substance Substances 0.000 claims 5
- 239000003960 organic solvent Substances 0.000 claims 4
- 230000008929 regeneration Effects 0.000 claims 3
- 238000011069 regeneration method Methods 0.000 claims 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 2
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims 2
- -1 sulphate ions Chemical class 0.000 claims 2
- 150000003512 tertiary amines Chemical class 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 229910002651 NO3 Inorganic materials 0.000 claims 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims 1
- 239000003513 alkali Substances 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 150000004982 aromatic amines Chemical class 0.000 claims 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 1
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims 1
- 239000003085 diluting agent Substances 0.000 claims 1
- 239000006185 dispersion Substances 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims 1
- 229910000027 potassium carbonate Inorganic materials 0.000 claims 1
- 150000003141 primary amines Chemical class 0.000 claims 1
- 230000001172 regenerating effect Effects 0.000 claims 1
- 150000003335 secondary amines Chemical class 0.000 claims 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims 1
- 229910000029 sodium carbonate Inorganic materials 0.000 claims 1
- CMXPERZAMAQXSF-UHFFFAOYSA-M sodium;1,4-bis(2-ethylhexoxy)-1,4-dioxobutane-2-sulfonate;1,8-dihydroxyanthracene-9,10-dione Chemical compound [Na+].O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=CC=C2O.CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC CMXPERZAMAQXSF-UHFFFAOYSA-M 0.000 claims 1
- 229910021653 sulphate ion Inorganic materials 0.000 claims 1
- 239000001117 sulphuric acid Substances 0.000 claims 1
- 235000011149 sulphuric acid Nutrition 0.000 claims 1
- 239000002699 waste material Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/26—Treatment of water, waste water, or sewage by extraction
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physical Water Treatments (AREA)
Claims (8)
1. A continuous process for removing nitrates from waste waters with the ' minimum possible solvent losses, in which case the nitrate-containing waste water is extracted with a primary, secondary, or tertiary, aliphatic and/or aromatic amine which is substantially water insoluble or which can be made water insoluble by using, as a diluent, aliphatic and/or aromatic hydrocarbons and/or other organic solvents which are either liquid under normal pressure or which have been liquefied from solvents gaseous- under normal pressure, whereafter the waste water essentia ly devoid of nitrates is directed, after phase separationf into the watercourse, and the organic solvent phase is fed into a stripping stage where the nitrates are separated with a strippin chemical, which reacts alkalically, in a usable water solution form, and the solvent phase is returned to the regeneration stage, characterized in that the dispersion composed of the regenerated solvent and the regeneration agent is fed directly into the extraction stage without first separating the phases, and after the stripping stage, the stripping chemical is fed into a return wash carried out with water in order to return the stripping chemical to the stripping stage.
2. A process according to Claim 1, c h a r a c t e r i z e d i n that sulphate ions, e.g., sulphuric acid, are used for regenerating the solvent.
3. A process according to one of the above claims, c ha r a c t e r i z e d i n that the stripping chemical used is an alkali hydroxide, an earth alkali hydroxide, ammonia, or .v/ater solutions of these in different strengths, or organic primary, secondary or tertiary amines with such a carbon chain length that their water solubility is greater than their solubility in an organic solvent. 43425/2
4. A process according to one of the above claims, c h a r a c t e r i z e d i n that the pH of the purified waste water emerging from the extraction is controlled at about 5-10, preferably about 7-9, in order to minimize the solubility of the solvent in the purified waste water*
5. A process according to Claim 4, c h a r a c t e r i z e d •i n that the alkali used for the pH control is an environmentall non-harmful sodium, potassium, or calcium carbonate.
6. A process according to Claim 4 or 5f c h a r a c t e r i z e d i n that the solvent remaining in the purified waste water is v/ashed av/ay in the' solvent circulation with pure solvent taken before ' the regeneration stage in order _to return the' solven remaining in the purified waste water to the circulation.
7. A pjrocess according to Claim 6, c h a r a c t e r i z e d i n that the said solvent wash is carried out in a contact apparatus, through which the purified v/aste water with a controll pH and the organic solvent phase coming from. the return wash of the stripping chemical and effecting the wash are directed.
8. A process according to one of the above claims, c h a r a c t e r i z e d i n that the return wash of th^ stripping chemic is carried out with a byflow of the purified waste water0 : . ·. . :. ·!
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI2850/72A FI56160C (en) | 1972-10-16 | 1972-10-16 | KONTINUERLIGT FOERFARANDE FOER AVLAEGSNANDE AV NITRATER UR AVFALLSVATTEN GENOM EXTRAKTION OCH MED MOEJLIGAST SMAO EXTRAKTIONSMEDELSFOERLUSTER |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL43425A0 IL43425A0 (en) | 1974-01-14 |
| IL43425A true IL43425A (en) | 1976-08-31 |
Family
ID=8507681
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL43425A IL43425A (en) | 1972-10-16 | 1973-10-15 | Continuous process for removing nitrates from wastewaters by extraction |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE2350962A1 (en) |
| FI (1) | FI56160C (en) |
| IL (1) | IL43425A (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2391953A1 (en) * | 1976-11-02 | 1978-12-22 | Ugine Kuhlmann | NITRIC EFFLUENT TREATMENT PROCESS |
| US4372932A (en) * | 1978-05-18 | 1983-02-08 | Union Oil Company Of California | Process for removing SOx and NOx compounds from gas streams |
| US4597954A (en) * | 1980-05-21 | 1986-07-01 | Union Oil Company Of California | Process for removing sox and nox compounds from gas streams |
| US4804522A (en) * | 1980-05-21 | 1989-02-14 | Union Oil Company Of California | Process for removing SOx and NOx compounds from gas streams |
| US4675169A (en) * | 1980-05-21 | 1987-06-23 | Union Oil Company Of California | Process for removing sox and nox compounds from gas streams |
| US4448899A (en) * | 1980-05-21 | 1984-05-15 | Union Oil Company Of California | Process for removing SOx and NOx compounds from gas streams |
| US4347227A (en) * | 1981-03-11 | 1982-08-31 | Union Oil Company Of California | Process for removing SOx and NOx compounds from gas streams |
| GB8607034D0 (en) * | 1986-03-21 | 1986-04-30 | Rohm & Haas | Removal of no3 from salt solutions |
| EP0396790B1 (en) * | 1989-05-09 | 1992-12-23 | Bayer Antwerpen N.V. | Process for the removal of nitrate and organic pollutants from effluents |
| DE19732074A1 (en) * | 1997-07-25 | 1999-01-28 | Bayer Ag | Process for the purification of waste water containing organic and possibly inorganic sulfur compounds |
-
1972
- 1972-10-16 FI FI2850/72A patent/FI56160C/en active
-
1973
- 1973-10-11 DE DE19732350962 patent/DE2350962A1/en active Pending
- 1973-10-15 IL IL43425A patent/IL43425A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FI56160C (en) | 1979-12-10 |
| FI56160B (en) | 1979-08-31 |
| DE2350962A1 (en) | 1974-04-25 |
| IL43425A0 (en) | 1974-01-14 |
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