IL310179B2

IL310179B2 - Self-lubricating compositions and uses thereof; and polymers within said compositions

Info

Publication number: IL310179B2
Application number: IL310179A
Authority: IL
Inventors: AGBARIA Mahmood
Original assignee: Slibio Labs Ltd; AGBARIA Mahmood
Priority date: 2024-01-16
Filing date: 2024-01-16
Publication date: 2025-04-01
Also published as: IL310179B1; IL310179A

Description

P-622096-IL 1 SELF-LUBRICATING COMPOSITIONS AND USES THEREOF; AND POLYMERS WITHIN SAID COMPOSITIONS FIELD OF THE INVENTION id="p-1" id="p-1" id="p-1" id="p-1" id="p-1" id="p-1" id="p-1"

[001] This invention provides a self-lubricating composition and its use in a method of preventing arthropods climbing on a climbable surface. This invention also provides polymers used within said composition. BACKGROUND OF THE INVENTION id="p-2" id="p-2" id="p-2" id="p-2" id="p-2" id="p-2" id="p-2"

[002] Every year, insects destroy plants worth more than 77 billion dollars and they are the main reason for the spread of contagious diseases around the world along with ecological damages. The current method of treatment for such insects/pests is chemical pesticide which leads to ecological damages and endangers human lives either directly or indirectly. [003] Thus, there is a crucial need to deal with insects/pests in a modern method that is different from other conventional methods. This invention provides green and non-toxic methods and compositions used within, to prevent and/or inhibit insects/pests from climbing climbable surfaces, e.g. tree trunks, fences etc.

SUMMARY OF THE INVENTION id="p-4" id="p-4" id="p-4" id="p-4" id="p-4" id="p-4" id="p-4"

[004] In one embodiment, this invention is directed to a self-lubricating composition comprising capsules, wherein the capsules comprise a core comprising a first mixture of oils and fats having multiplicity of molecular weights; a shell; and a first surfactant. [005] In one further embodiment, this invention is directed to a method of preventing arthropods climbing on a climbable surface, comprising application of a self-lubricating composition on the climbable surface, wherein the composition comprises capsules; and wherein the capsules comprise a core comprising a first mixture of oils and fats having multiplicity of molecular weights; a shell; and a first surfactant. [006] In one further embodiment, this invention is directed to a copolymer of polymethylhydrosiloxane-polyethylene glycol (PMHS-g-PEG).

BRIEF DESCRIPTION OF THE DRAWINGS P-622096-IL 2 id="p-7" id="p-7" id="p-7" id="p-7" id="p-7" id="p-7" id="p-7"

[007] The subject matter regarded as the invention is particularly pointed out and distinctly claimed in the concluding portion of the specification. The invention, however, both as to organization and method of operation, together with objects, features, and advantages thereof, may best be understood by reference to the following detailed description when read with the accompanying drawings in which: [008] Figures 1A-1B depict ATR FTIR spectra of PMHS and PEG mixture before and after the reaction between both of them (see Examples 1-2). The bottom curve (having a peak at 21cm-1) is the ATR absorption of the mixture of PEG and PMHS 1:1 before the reaction. The top curve is the ATR absorption of the PMHS-g-PEG after the reaction. Figure 1A: ATR FTIR spectra of PMHS and PEG mixture before and after the reaction – full scale; and Figure 1B: ATR FTIR spectra of PMHS and PEG mixture before and after the reaction – focus on ~400 - ~1400 cm-1. [009] Figures 2A-2D depict experimental setups to assess the ability of ants to climb wood coated with the compositions of this invention. Figure 2A: wood stick glued on a plastics lid; Figure 2B: coated wood stick on it (the coating is White / Transparent).; Figure 2C: sticky tape with 100 μl of 50% Sucrose solution; and Figure 2D: 10 -15 Componotus ants added to the plastic container.

DETAILED DESCRIPTION OF THE PRESENT INVENTION id="p-10" id="p-10" id="p-10" id="p-10" id="p-10" id="p-10" id="p-10"

[0010] In the following detailed description, numerous specific details are set forth in order to provide a thorough understanding of the invention. However, it will be understood by those skilled in the art that this invention may be practiced without these specific details. In other instances, well-known methods, procedures, and components have not been described in detail so as not to obscure this invention. Method of preventing arthropods climbing on a climbable surface id="p-11" id="p-11" id="p-11" id="p-11" id="p-11" id="p-11" id="p-11"

[0011] In some embodiments, this invention provides a method of preventing arthropods climbing on a climbable surface, comprising application of a self-lubricating composition on the climbable surface, wherein the composition comprises capsules; and wherein the capsules comprise a core comprising a first mixture of oils and fats having multiplicity of molecular weights; a shell; and a first surfactant. In one embodiment, the prevention of arthropods climbing on a climbable surface comprises disruption of the Van der Waals interaction between the arthropods‘ legs (via hairy pads thereof) and the climbable surface.

P-622096-IL 3 In one embodiment, the method of this invention is sustainable, green, ecological and/or non-lethal, due to the utilization of the green and ecological, self lubricating composition, as described hereinbelow. In one embodiment, the method disrupts the Van der Waals interaction between the arthropods‘ legs (via hairy pads thereof) and the climbable surface, thus preventing the arthropods from climbing; and therefore this method does not harm and/or does not kill the arthropods. Each possibility represents a separate embodiment of this invention. [0012] In one embodiment, the climbable surface is any surface that can be coated; and which arthropods can climb on (said surface). In one other embodiment, the climbable surface is a tree trunk, an internal or external wall, a fence or a greenhouse. In another embodiment, the climbable surface is a tree trunk. In other embodiment, the species of the tree is Avocado, Citrus, Mango, Cacao, Coffee or any ornamental plant species or fruit tree species. In another embodiment, any tree trunk is suitable in the context of this invention as long as no "internal pathways" are present in said trunk so the arthropod would not have any chance to "bypass" the coated climbable surface in order to climb the trunk from e.g. the inside of it (for example in a case where the tree has a hole around the ground so the arthropod can get inside the tree and climb from there).. In another embodiment, the tree trunk is in a height of 5-100 cm, 10-15 cm, 20-50 cm, 30-40 cm, 30-cm, 10-80 cm or 50-100 cm. In another embodiment, the climbable surface is an internal wall. In another embodiment, the climbable surface is an external wall. In another embodiment, the climbable surface is a fence. In another embodiment, the climbable surface is a greenhouse. In another embodiment, Each possibility represents a separate embodiment of this invention. [0013] In one embodiment, the application of the self lubricating composition comprises coating of the climbable surface with the self lubricating composition. [0014] In one embodiment, the coating of the self lubricating composition comprises spraying or brushing of the climbable surface with the self lubricating composition. [0015] In one embodiment, the arthropods are selected from the non-limiting group consisting of: insects, ants, mealybugs, mites, snails or spiders. [0016] In one embodiment, the prevention was at least 90% efficient for 3 months. In another embodiment, the prevention was 90-99.99% efficient for 3 months. In another embodiment, the prevention was 90-99.99% efficient for 2-4 months. In another embodiment, the prevention was 90-95% efficient for 2-4 months. In another embodiment, the prevention was 90-99.99% efficient for 1-6 months. In another embodiment, the prevention was 90-95% efficient for 1-6 months. In some embodiments, said "efficiency" of the prevention is measured via various methods, for P-622096-IL 4 example the one described in Example 5 ("Success rate (%)"). Each possibility represents a separate embodiment of this invention. [0017] In some embodiments, the self lubricating composition layer found on top of the climbable surface, or the self lubricating coating on top of the climbable surface has a thickness of 5-200 m (micron). In one embodiment, the thickness is 5-150 m. In another embodiment, the thickness is 5-100m. In another embodiment, the thickness is 5-50m. In another embodiment, the thickness is 5-20m. In another embodiment, the thickness is 20-200m. In another embodiment, the thickness is 20-150. In another embodiment, the thickness is 20-100m. In another embodiment, the thickness is 20-50m. In another embodiment, the thickness is 50-200m. In another embodiment, the thickness is 50-150m. In another embodiment, the thickness is 50-100m. In another embodiment, the thickness is 100-200m. In another embodiment, the thickness is 100-150m. In another embodiment, the thickness is 150-200m. In another embodiment, the thickness is 100m. Each possibility represents a separate embodiment of this invention. Self-lubricating composition and capsule [0018] In some embodiments, this invention provides a self-lubricating composition comprising capsules, wherein the capsules comprise a core comprising a first mixture of oils and fats having multiplicity of molecular weights; a shell; and a first surfactant. In one embodiment, the composition is an emulsion. In one other embodiment, the core of the capsule is an emulsion. In another embodiment, the emulsion of the composition and/or capsule is an oil in water or water in oil emulsion. In some embodiments, it is noted herein that the molecular weights are proportional to viscosities, thus said multiplicity of molecular weights comprise of and can be characterized by multiplicity of viscosities. Each possibility represents a separate embodiment of this invention. [0019] In one embodiment, the shell comprises polyvinyl alcohol, Polycaprolactone, Fatty alcohol, biodegradable polyesters, poly(furfuryl alcohol) bioresin, Cellulose, lignin, biobased wax, paraffin wax, or any combination thereof. In another embodiment, the biobased wax comprises carnauba wax, bees wax, shellfish wax, lanolin, candelilla wax, jojoba oil, soy wax or any combination thereof. In another embodiment, the shell comprises at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 0-3 : 0-3 : 0-3. In another embodiment, the shell comprises at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 0-2 : 0-2 : 0-2. In another embodiment, the shell comprises at least one of polyvinyl P-622096-IL alcohol, carnauba wax and bees wax in a weight ratio of 0-1 : 0-1 : 0-1. Each possibility represents a separate embodiment of this invention. [0020] In one embodiment, the first mixture of oils and fats having multiplicity of molecular weights comprises a first mixture of silicone oils; and at least one of first almond oil; first vegetable oil; and fatty acid amide. In another embodiment, the first mixture of silicone oils comprises a first silicone oil having a viscosity of between 100-1,000 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp. In another embodiment, the first silicone oil has a viscosity of between 100-500 cp. In another embodiment, the first silicone oil has between 100-250 cp. In another embodiment, the first silicone oil has a viscosity of between 250-1000 cp. In another embodiment, the first silicone oil has a viscosity of between 250-500 cp. In another embodiment, the first silicone oil has a viscosity of 350 cp. In another embodiment, the first silicone oil has a viscosity of between 500-1000 cp. In another embodiment, the second silicone oil has a viscosity of between 40,000 – 70,000 cp. In another embodiment, the second silicone oil has a viscosity of between 40,000 – 50,000 cp. In another embodiment, the second silicone oil has a viscosity of between 50,000 – 80,000 cp. In another embodiment, the second silicone oil has a viscosity of between 50,000 – 70,000 cp. In another embodiment, the second silicone oil has a viscosity of between 70,000 – 80,000 cp. In another embodiment, the second silicone oil has a viscosity of 60,000 cp. In another embodiment, the first mixture of silicone oils comprises a first silicone oil having a viscosity of 350 cp and a second silicone oil having a viscosity of 60,000 cp. In another embodiment, the first to second silicon oil weight ratio is 1-: 0-1. In another embodiment, the first to second silicon oil weight ratio is 1-2 : 0-1. In another embodiment, the first to second silicon oil weight ratio is 0.5-5 : 0-2. In another embodiment, the first silicone oil and the second silicone oil have a weight ratio of 3:1, respectively. In another embodiment, the first almond oil has a viscosity of 35-45 cp. In another embodiment, the first vegetable oil has a viscosity of 5-80 cp. In another embodiment, the first vegetable oil has a viscosity of 10-70 cp. In another embodiment, the first vegetable oil has a viscosity of 20-60 cp. In another embodiment, the first vegetable oil has a viscosity of 30-50 cp. In another embodiment, the first vegetable oil has a viscosity of 40-60 cp. Each possibility represents a separate embodiment of this invention. [0021] In one embodiment, the fatty acid amide comprises erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, oleyl palmitamide or any combination thereof. In another embodiment, the fatty acid amide comprises a mixture of erucamide, oleamide, ethylene bis- P-622096-IL 6 oleamide, stearyl erucamide and oleyl palmitamide. Each possibility represents a separate embodiment of this invention. [0022] In one embodiment, the capsules further comprise water. In other embodiment, the water are distilled water. [0023] In some other embodiments, the composition further comprises a second surfactant and a second mixture of oils and fats having multiplicity of molecular weights. In one embodiment, the second mixture of oils and fats comprises a second mixture of silicone oils; and at least one of second almond oil; and second vegetable oil. In another embodiment, the second mixture of silicone oils comprise a third silicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp. In another embodiment, the third silicone oil has a viscosity of between 100-500 cp. In another embodiment, the third silicone oil has a viscosity of between 100-250 cp. In another embodiment, the third silicone oil has a viscosity of between 250-1000 cp. In another embodiment, the third silicone oil has a viscosity of between 250-500 cp. In another embodiment, the third silicone oil has a viscosity of 350 cp. In another embodiment, the third silicone oil has a viscosity of between 500-1000 cp. In another embodiment, the fourth silicone oil has a viscosity of between 40,000 – 70,000 cp. In another embodiment, the fourth silicone oil has a viscosity of between 40,000 – 50,000 cp. In another embodiment, the fourth silicone oil has a viscosity of between 50,000 – 80,000 cp. In another embodiment, the fourth silicone oil has a viscosity of between 50,000 – 70,000 cp. In another embodiment, the fourth silicone oil has a viscosity of between 70,000 – 80,000 cp. In another embodiment, the fourth silicone oil has a viscosity of 60,000 cp. In another embodiment, the second mixture of silicone oils comprises a third silicone oil having a viscosity of 350 cp and a fourth silicone oil having a viscosity of 60,000 cp. In another embodiment, the third to fourth silicon oil weight ratio is 1-3 : 0-1. In another embodiment, the third to fourth silicon oil weight ratio is 1-2 : 0-1. In another embodiment, the third to fourth silicon oil weight ratio is 0.5-5 : 0-2. In another embodiment, the third silicone oil and the fourth silicone oil have a weight ratio of 3:1, respectively. In another embodiment, the second almond oil has a viscosity of 35-45 cp. In another embodiment, the second vegetable oil has a viscosity of 5-80 cp. In another embodiment, the second vegetable oil has a viscosity of 10-70 cp. In another embodiment, the second vegetable oil has a viscosity of 20-60 cp. In another embodiment, the second vegetable oil has a viscosity of 30-50 cp. In another embodiment, the second vegetable oil has a viscosity of 40-60 cp. Each possibility represents a separate embodiment of this invention.

P-622096-IL 7 id="p-24" id="p-24" id="p-24" id="p-24" id="p-24" id="p-24" id="p-24"

[0024] In one embodiment, the composition (including, inter-alia, or excluding the capsules within) further comprises water. [0025] In some embodiments, the first and the second surfactants are identical or different. In one embodiment, the first and second surfactants are different. In one other embodiment, the first and second surfactants are each independently polymethylhydrosiloxane-polyethylene glycol copolymer (PMHS-g-PEG), PMHS, PEG, Dow corning 5225c, Dow corning 5200, RITASIL sw 3050, ABIL care 85, Agrimer AL 10LC, Agrimer AL 22, Cyclopentasiloxane (and) PEG/PPG-18/18 Dimethicone, LAURYL PEG/PPG-18/18 METHICONE, Cetyl PEG-PPG–10/Dimethicone, Bis-PEG/PPG-16/16 PEG/PPG-16/16 Dimethicone (and) Caprylic/Capric Triglyceride, 1-Butene-N-vinylpyrrolidone copolymer, 1-hexadecnyl-N-vinylpyrrolidone copolymer, or any combination thereof. In one other embodiment, the first and second surfactants are each independently a polymethylhydrosiloxane-polyethylene glycol copolymer (PMHS-g-PEG). In one other embodiment, the first and second surfactants are each independently polymethylhydrosiloxane-polyethylene glycol copolymer (PMHS-g-PEG), PMHS, PEG or any combination thereof. In one other embodiment, the first and second surfactants are each independently a combination of PMHS and PEG. In one other embodiment, the first and second surfactants are each independently a combination of polymethylhydrosiloxane-polyethylene glycol copolymer (PMHS-g-PEG), PMHS and PEG. In yet one further embodiment, the first and second surfactants are each independently a combination of polymethylhydrosiloxane-polyethylene glycol copolymer (PMHS-g-PEG), PMHS and PEG, wherein the polymethylhydrosiloxane-polyethylene glycol copolymer (PMHS-g-PEG) is 10-100, 10-50, 50-100, 10-20, 20-30, 30-40, 40-50, 50-60, 60-70, 70-80, 80-90 or 90-100% w/w of the whole combination. In yet other embodiment, the first and second surfactants are each independently Dow corning 5225c, Dow corning 5200, RITASIL sw 3050, ABIL care 85, Agrimer AL 10LC, Agrimer AL 22, Cyclopentasiloxane (and) PEG/PPG-18/18 Dimethicone, LAURYL PEG/PPG-18/18 METHICONE, Cetyl PEG-PPG–10/1 Dimethicone, Bis-PEG/PPG-16/16 PEG/PPG-16/Dimethicone (and) Caprylic/Capric Triglyceride, 1-Butene-N-vinylpyrrolidone copolymer, 1-hexadecnyl-N-vinylpyrrolidone copolymer, or any combination thereof. In other embodiment, the first and the second surfactants are useful in preventing emulsion, dispersion or suspension to break/collapse, i.e. they keep the stability of the composition and/or the capsules of this inventions. Each possibility represents a separate embodiment of this invention. [0026] In some embodiments, the first and the second mixtures of oils and fats having multiplicity of molecular weights are identical or different. In one embodiment, the first and the P-622096-IL 8 second mixtures of oils and fats having multiplicity of molecular weights are different. In one other embodiment, the first and the second mixtures of oils and fats having multiplicity of molecular weights are identical. In yet other embodiment, each of the first and the second mixtures of oils and fats having multiplicity of molecular weights independently comprise two, three, four, five or more fatty/oily ingredients with specific (different) molecular weights and/or viscosities (proportional to molecular weights). In another embodiment, the first and/or the second mixtures of oils and fats having multiplicity of molecular weights comprise two fatty/oily ingredients with specific (different) molecular weights and/or viscosities. In another embodiment, the first and/or the second mixtures of oils and fats having multiplicity of molecular weights comprise three fatty/oily ingredients with specific (different) molecular weights and/or viscosities. In another embodiment, the first and/or the second mixtures of oils and fats having multiplicity of molecular weights comprise four fatty/oily ingredients with specific (different) molecular weights and/or viscosities. In another embodiment, the first and/or the second mixtures of oils and fats having multiplicity of molecular weights comprise five fatty/oily ingredients with specific (different) molecular weights and/or viscosities. In another embodiment, each ingredient within the multiple fatty/oily ingredients can be part of the same or a different family of oils/fats. In one another embodiment, non-limiting examples of oils/fats families consist essentially of: silicone oils, almond oils, vegetable oils, fatty acid amides, synthetic oils and fatty acids. Each possibility represents a separate embodiment of this invention. [0027] In some embodiments, the first and the second almond oil are each independently selected from a bitter and a sweet almond oil and any combination thereof. In one embodiment, the first and/or second almond oil has each independently a viscosity of 35-45 cp. Each possibility represents a separate embodiment of this invention. [0028] In some embodiments, the first and the second vegetable oil are each independently selected from olive oil, canola oil, corn oil, cotton seed oil, soya oil, coconut oil, and any combination thereof. In another embodiment, the first and/or second vegetable oil has each independently a viscosity of 5-80 cp. In another embodiment, the first and/or second vegetable oil has each independently a viscosity of 10-70 cp. In another embodiment, the first and/or second vegetable oil has each independently a viscosity of 20-60 cp. In another embodiment, the first and/or second vegetable oil has each independently a viscosity of 30-50 cp. In another embodiment, the first and/or second vegetable oil has a viscosity of 40-60 cp. In another embodiment, the olive oil has a viscosity of 40-60 cp. In another embodiment, the olive oil has a viscosity of 45-55 cp. Each possibility represents a separate embodiment of this invention.

P-622096-IL 9 id="p-29" id="p-29" id="p-29" id="p-29" id="p-29" id="p-29" id="p-29"

[0029] In one embodiment, the capsule further comprises first synthetic oil and/or first fatty acid. In another embodiment, the first synthetic oil comprises polyalphaolefin (PAO) base oils, paraffin oil, polyalkylene glycol or any combination thereof. In another embodiment, the first synthetic oil replaces the first mixture of silicone oils. In yet another embodiment, the first synthetic oil is provided in addition to the first mixture of silicone oils. In another embodiment, the first fatty acid comprise palmitic acid, stearic acid, oleic acid, linoleic acid, N-acylethanolamine, oleamide, stearamide, erucamide or any combination thereof. In another embodiment, the first fatty acid replace the fatty acid amide. In yet another embodiment, the first fatty acid is provided in addition to the fatty acid amide. In one other embodiment, the first mixture of oils and fats having multiplicity of molecular weights of the capsule comprises the first mixture of silicone oils, first almond oil, first vegetable oil, fatty acid amide, first synthetic oil, first fatty acid or any combination thereof. Each possibility represents a separate embodiment of this invention. [0030] In one embodiment, the composition further comprises second synthetic oil and/or second fatty acid. In another embodiment, the second synthetic oil comprises polyalphaolefin (PAO) base oils, paraffin oil, polyalkylene glycol or any combination thereof. In another embodiment, the second synthetic oil replaces the second mixture of silicone oils. In yet another embodiment, the second synthetic oil is provided in addition to the second mixture of silicone oils. In another embodiment, the second fatty acid comprise palmitic acid, stearic acid, oleic acid, linoleic acid, N-acylethanolamine, oleamide, stearamide, erucamide or any combination thereof. In one other embodiment, the second mixture of oils and fats having multiplicity of molecular weights of the composition comprises the second mixture of silicone oils, second almond oil, second vegetable oil, fatty acid amide, second synthetic oil, second fatty acid or any combination thereof. Each possibility represents a separate embodiment of this invention. [0031] In some embodiments, the capsules comprise shell, first mixture of oils and fats having multiplicity of molecular weights, first surfactant and water. In one embodiment, the first mixture of oils and fats having multiplicity of molecular weights comprises a first mixture of silicone oils; and at least one of first almond oil; first vegetable oil; and fatty acid amide. In some embodiments, the capsules comprise shell, first mixture of silicone oils, first almond oil; first vegetable oil or mixture thereof; fatty acid amide; first surfactant and water. In some other embodiment, the capsules comprise 30-50% w/w of shell, 5-40% of w/w first mixture of silicone oils, 0-10% w/w of first almond oil; first vegetable oil or mixture thereof; 0-5% w/w of fatty acid amide; 1-5% w/w of first surfactant and 5-30% w/w water. In another embodiment, the P-622096-IL shell is in a weight of 30-50% w/w, 30-40% w/w or 40-50% w/w. In another embodiment, the first mixture of silicone oils is in a weight of 5-40% w/w, 5-10% w/w, 10-20% w/w, 20-30% w/w or 30-40% w/w. In another embodiment, the first almond oil; first vegetable oil or mixture thereof is in a weight of 5-10% w/w, 0-5% w/w or 5-10% w/w. In another embodiment, the water is in a weight of 5-30% w/w, 5-10% w/w, 10-20% w/w or 20-30% w/w. In one embodiment, the capsules comprise at least one of polyvinyl alcohol, carnauba wax and bees wax, a first mixture of first silicone oil having a viscosity of between 100-1,000 cp and a second silicone oil having between a viscosity of 40,000 – 80,000 cp, mixture of first almond oil and first vegetable oil; erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; PMHS-g-PEG, PMHS, PEG or any combination thereof; and water. In one other embodiment, the capsules comprise at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 0-3 : 0-3 : 0-3, a first mixture of first silicone oil having between 100-1,000 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, mixture of first almond oil and first vegetable oil; erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; PMHS-g-PEG, PMHS, PEG or any combination thereof; and water. In one embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 0-3 : 0-3 : 0-3, 5-40% w/w of a first mixture of first silicone oil having a viscosity of between 100-1,000 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the shell is in a 40% w/w; and the first mixture of silicone oils comprises a first silicone oil having a viscosity of 350 cp and a second silicone oil having a viscosity of 60,000 cp. Each possibility represents a separate embodiment of this invention. [0032] In some embodiments, the composition comprises capsules, a second surfactant, a second mixture of oils and fats having multiplicity of molecular weights and water. In one embodiment, the second mixture of oils and fats having multiplicity of molecular weights comprises a second mixture of silicone oils; and at least one of second almond oil; and second vegetable oil. In some embodiments, the composition comprises capsules, second mixture of silicone oils, mixture of second almond oil and second vegetable oil, second surfactant and water. In some other embodiments, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of silicone oils, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w P-622096-IL 11 of second surfactant and 10-50% w/w water. In one embodiment, the capsules are in a weight of 5-30% w/w, 5-10% w/w, 10-20% w/w or 20-30% w/w. In another embodiment, the second mixture of silicone oils is in a weight of 5-40% w/w, 5-10% w/w, 10-20% w/w 20-30% w/w or 30-40% w/w. In another embodiment, the mixture of second almond oil and second vegetable oil is in a weight of 0-15% w/w, 5-10% w/w or 10-15% w/w. In another embodiment, the water is in a weight of 0-50% w/w, 0-10% w/w, 10-20% w/w, 20-30% w/w, 30-40% w/w or 40-50% w/w. In one embodiment, the composition comprises capsules, second mixture of thirdsilicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, mixture of second almond oil and second vegetable oil; PMHS-g-PEG, PMHS, PEG or any combination thereof; and water. In one other embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having a viscosity of 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. Each possibility represents a separate embodiment of this invention. [0033] In some embodiments, the capsules are excluded from the composition of this invention. In one embodiment, the composition comprises a second surfactant and a second mixture of oils and fats having multiplicity of molecular weights, as indicated and detailed throughout this subject application; and said composition does not comprise the capsules as described throughout said subject application. In some other embodiments, the composition comprises a second surfactant, a second mixture of oils and fats having multiplicity of molecular weights and water. In one embodiment, the second mixture of oils and fats having multiplicity of molecular weights comprises a second mixture of silicone oils; and at least one of second almond oil; and second vegetable oil. In some other embodiments, the composition comprises second mixture of silicone oils, mixture of second almond oil and second vegetable oil, second surfactant and water. In some other embodiments, the composition comprises 15-50% w/w second mixture of silicone oils, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, the second mixture of silicone oils is in a weight of 15-50% w/w, 15-20% w/w, 20-30% w/w, 30-40% w/w or 40-50% w/w. In another P-622096-IL 12 embodiment, the mixture of second almond oil and second vegetable oil is in a weight of 0-25% w/w, 0-5% w/w, 5-10% w/w, 10-15% w/w, 15-20% w/w or 20-25% w/w. In another embodiment, the water is in a weight of 0-50% w/w, 0-10% w/w, 10-20% w/w, 20-30% w/w, 30-40% w/w or 40-50% w/w. In one embodiment, the composition comprise second mixture of third silicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, mixture of second almond oil and second vegetable oil; PMHS-g-PEG, PMHS, PEG or any combination thereof; and water. In one other embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,0– 80,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. Each possibility represents a separate embodiment of this invention. [0034] In some embodiments, the compositions that do include said capsules provide lower viscosity compared to compositions with the capsules absent, thus such capsules-including compositions are easier to spray on the climbable surface. [0035] In some other embodiments, the capsule is a microcapsule. In one embodiment, the size of the microcapsule is 1-1000 m (micron). In another embodiment, the size of the microcapsule is 1-500 m. In another embodiment, the size of the microcapsule is 1-100 m. In another embodiment, the size of the microcapsule is 1-50 m. In another embodiment, the size of the microcapsule is 1-10 m. In another embodiment, the size of the microcapsule is 1-5 m. In another embodiment, the size of the microcapsule is 10-1000 m. In another embodiment, the size of the microcapsule is 10-500 m. In another embodiment, the size of the microcapsule is 10-100 m. In another embodiment, the size of the microcapsule is 10-50 m. In another embodiment, the size of the microcapsule is 50-1000 m. In another embodiment, the size of the microcapsule is 50-500 m. In another embodiment, the size of the microcapsule is 50-100 m. In another embodiment, the size of the microcapsule is 100-1000 m. In another embodiment, the size of the microcapsule is 100-500 m. In another embodiment, the size of the microcapsule is 500-1000 m. Each possibility represents a separate embodiment of this invention.

P-622096-IL 13 id="p-36" id="p-36" id="p-36" id="p-36" id="p-36" id="p-36" id="p-36"

[0036] In one embodiment, the capsule is provided as detailed hereinabove in all embodiments and limitations, however in this specific embodiment the capsule is provided as a separate, distinct and independent embodiment/entity (not as a part of- , or within the- composition of this invention). [0037] In some embodiments, the self lubricating composition provides constant lubrication to the (climbable) surface upon which it is found or coated on, due to the multiplicity of the molecular weights (or viscosities, which are proportional to the molecular weights) of the oils and the fats which are released/diffused from said coating in a rate directly proportional to their weight/viscosity. Thus, multiple molecular weights provide multiple release/diffusion rates so the coating has lubrication for short range (of time; with low molecular weight oil/fat), medium and long range (with medium/high molecular weight oil/fat). The higher the multiplicity, the better the efficiency and/or the time said coating will stay efficient on the surface, though at least two molecular weights at the extremes (high and low) are sufficient as well. In one embodiment, the first mixture of oils within the capsule comprises a first mixture of silicone oils; comprising silicone oil of 100-1000 cp and another silicone oil of 40,000 – 80,000 cp; at least one of first almond oil of 35-45cp; first vegetable oil of 5-80 cp; and a fatty acid amide (usually a solid fatty substance), and said first mixture of oils provides good lubrication and efficiency over time – 90% over 3 months. In one embodiment, the second mixture of oils within the compositions comprises a second mixture of silicone oils; comprising silicone oil of 100-1000 cp and another silicone oil of 40,000 – 80,000 cp; and at least one of second almond oil of 35-45cp; and second vegetable oil of 5-80 cp, and said second mixture of oils provides good lubrication and efficiency over time – 90% over 3 months. In another embodiment, the first and second mixtures of oils provide together good lubrication and efficiency over time – 90% over 3 months. In another embodiment, silicone oils mixture (e.g. as found within the first and/or second mixture of oils), for example, comprising silicone oil of 350 cp and another silicone oil of 60,000 cp – provides good lubrication and efficiency over time – 90% over 3 months. In some other embodiments, the oils mixtures (e.g. first or second) provide fats/oils having a multiplicity of molecular weights or viscosities, for example three types such as low (around tens cp), medium (around hundreds cp) and high (around tens of thousands cp) viscosities, all together giving good lubrication and efficiency over time as described herein. In some further embodiments, each of the viscosity range/type (low, medium and high) comprises one or more type of oil or fat. In yet other embodiments, solid fats (e.g. fatty acid amide)/oils/waxes enhance said lubrication and efficiency over time, in addition to the oils mixtures having multiplicity of viscosities. In some other P-622096-IL 14 embodiments, the term "around" in the context of "around N cp" where N is e.g. "tens" (or "hundreds" or "thousands") is defined as the numerical range of (10-99) ± 5% (that is, the actual range of 10-99, and 10 - 5% (="ten minus 5% of ten") and also 99 + 5% (="99 plus 5% of 99")). Each possibility represents a separate embodiment of this invention. [0038] In some embodiments, the composition is sustainable, green, ecological and/or non-lethal due to the ingredients involved within, as described hereinabove. In one embodiment, the method of this invention is also sustainable, green, ecological and/or non-lethal, due to the utilization of said composition. In one embodiment, the method disrupts the Van der Waals interaction between the arthropods‘ legs (via hairy pads thereof) and the climbable surface, thus preventing the arthropods climbing; and therefore this method does not harm and/or does not kill the arthropods. Each possibility represents a separate embodiment of this invention. [0039] In some embodiments, the compositions as described herein, throughout all this subject application, and capsules within, and any embodiment and limitation associated therewith – can be used in the methods of this invention, as described hereinabove. Each such possibility, limitation or alternative of the composition is a separate embodiment of the composition and/or method of this invention. [0040] In some embodiments, this invention provides a method of preparing the capsules, comprising: - stirring all ingredients to obtain the capsules; and - subjecting the capsule in a cold temperature to afford the capsules of the invention. [0041] In some embodiments, this invention provides a method of preparing the compositions, comprising: - optionally, filtering the capsules of this invention (depending on whether capsules are used or not in the compositions); and - stirring all ingredients to obtain the compositions. [0042] In one embodiment, the obtained capsules are microcapsules as described hereinabove. [0043] In one embodiment, the stirring is performed for a duration of 0.1-10 hr. In another embodiment, the duration is 0.1-1 hr. In another embodiment, the duration is 0.1-2 hr. In another embodiment, the duration is 0.1-5 hr. In another embodiment, the duration is 1-2 hr. In another embodiment, the duration is 1-5 hr. In another embodiment, the duration is 1-10 hr. In another embodiment, the duration is 2-5 hr. In another embodiment, the duration is 5-10 hr. Each possibility represents a separate embodiment of this invention.

P-622096-IL id="p-44" id="p-44" id="p-44" id="p-44" id="p-44" id="p-44" id="p-44"

[0044] In one embodiment, the stirring is performed at 50-100C. In another embodiment, the stirring is performed at 50-75C. In another embodiment, the stirring is performed at 75-100C. In another embodiment, the stirring is performed at 85C. Each possibility represents a separate embodiment of this invention. [0045] In one embodiment, the stirring is done in a high shear mixer (homogenizer). [0046] In one embodiment, the emulsion is subjected to "cold temperature", herein defined as -15C – 5C. In another embodiment, the cold temperature is 0C. [0047] In one embodiment, the size of capsules does not change once they are subjected to the "cold temperature" as defined hereinabove. [0048] In some embodiments, the obtained capsules contain an emulsion, encapsulated by a shell. PMHS -PEG copolymer [0049] In some embodiments, this invention provides a copolymer of polymethylhydrosiloxane-polyethylene glycol (PMHS-g-PEG). In one embodiment, the copolymer is represented by Formula (I): (I) wherein P-622096-IL 16 m is an integer between 2 – 2000; and n is an integer between 10 – 120. [0050] In one embodiment, m is an integer between 2-2000. In another embodiment, m is between 2-20. In another embodiment, m is between 2-50. In another embodiment, m is between 2-100. In another embodiment, m is between 2-200. In another embodiment, m is between 2-500. In another embodiment, m is between 2-1000. In another embodiment, m is between 2-2000. In another embodiment, m is between 20-50. In another embodiment, m is between 20-100. In another embodiment, m is between 20-200. In another embodiment, m is between 20-500. In another embodiment, m is between 20-1000. In another embodiment, m is between 20-2000. In another embodiment, m is between 50-100. In another embodiment, m is between 50-200. In another embodiment, m is between 50-500. In another embodiment, m is between 50-1000. In another embodiment, m is between 50-2000. In another embodiment, m is between 100-200. In another embodiment, m is between 100-500. In another embodiment, m is between 100-1000. In another embodiment, m is between 100-2000. In another embodiment, m is between 200-500. In another embodiment, m is between 200-1000. In another embodiment, m is between 200-2000. In another embodiment, m is between 500-1000. In another embodiment, m is between 500-2000. In another embodiment, m is between 1000-2000. Each possibility represents a separate embodiment of this invention. [0051] In one embodiment, n is an integer between 10-120. In another embodiment, n is between 10-20. In another embodiment, n is between 10-50. In another embodiment, n is between 10-100. In another embodiment, n is between 20-50. In another embodiment, n is between 20-100. In another embodiment, n is between 20-120. In another embodiment, n is between 50-100. In another embodiment, n is between 50-120. In another embodiment, n is between 100-120. Each possibility represents a separate embodiment of this invention. [0052] In some embodiments, the PMHS-g-PEG copolymer is used as a surfactant. In one embodiment, the PMHS-g-PEG copolymer is used as a surfactant in the compositions and capsules of this invention as described hereinabove. [0053] In some embodiments, this invention provides a method of preparing PMHS-g-PEG copolymer, comprising: - Dissolving a base in water; - Adding PMHS (polymethylhydrosiloxane) and water to the dissolved base until full dissolution; - Adding PEG (poly(ethylene glycol), affording the PMHS-g-PEG copolymer.

P-622096-IL 17 id="p-54" id="p-54" id="p-54" id="p-54" id="p-54" id="p-54" id="p-54"

[0054] In some embodiments, the obtained PMHS-g-PEG copolymer is not pure and may include reactants such as PEG and/or PMHS. In one embodiment, the PMHS-g-PEG is 10-100, 10-50, 50-100, 10-20, 20-30, 30-40, 40-50, 50-60, 60-70, 70-80, 80-90 or 90-100% w/w of the whole combination (PMHS-g-PEG and reactants). [0055] In one embodiment, the base is KOH, NaOH . [0056] In one embodiment, the non-limiting examples of PEG consist of PEG 400 , PEG 6000, PEG 8000, and PEG 35000. [0057] In one embodiment, the Base : PMHS : PEG w/w/v ratio is 50-150 : 80-120 : 85-130. In another embodiment, the ratio is 120-130 : 90-110 : 105-115. In another embodiment, the ratio is 125 : 100 : 110. Each possibility represents a separate embodiment of this invention. [0058] In one embodiment, the water is distilled water. [0059] In one embodiment, the temperature within the method of preparing the copolymer is "room temperature", defined herein as 15-40C. In another embodiment, the temperature is 20-0C. [0060] In one embodiment, the duration of each step within the method of preparing the copolymer is 0.2-48 hr. In another embodiment, the duration is 0.2-1 hr. In another embodiment, the duration is 0.2-2 hr. In another embodiment, the duration is 0.2-5 hr. In another embodiment, the duration is 0.2-10 hr. In another embodiment, the duration is 0.2-24 hr. In another embodiment, the duration is 0.2-48 hr. In another embodiment, the duration is 1-2 hr. In another embodiment, the duration is 1-5 hr. In another embodiment, the duration is 1-10 hr. In another embodiment, the duration is 1-24 hr. In another embodiment, the duration is 1-48 hr. In another embodiment, the duration is 2-5 hr. In another embodiment, the duration is 2-10 hr. In another embodiment, the duration is 2-24 hr. In another embodiment, the duration is 2-48 hr. In another embodiment, the duration is 5-10 hr. In another embodiment, the duration is 5-24 hr. In another embodiment, the duration is 5-48 hr. In another embodiment, the duration is 10-24 hr. In another embodiment, the duration is 10-48 hr. In another embodiment, the duration is 24-48 hr. Each possibility represents a separate embodiment of this invention. Specific capsules and compositions [0061] In some embodiments, the capsules comprise 30-50% w/w of shell, 5-40% of w/w first mixture of silicone oils, 0-10% w/w of first almond oil; first vegetable oil or mixture thereof; 0-5% w/w of fatty acid amide; 1-5% w/w of first surfactant and 5-30% w/w water. In one embodiment, the capsules comprise 30-40% w/w of shell, 5-40% of w/w first mixture of silicone P-622096-IL 18 oils, 0-10% w/w of first almond oil; first vegetable oil or mixture thereof; 0-5% w/w of fatty acid amide; 1-5% w/w of first surfactant and 5-30% w/w water. In another embodiment, the capsules comprise 40-50% w/w of shell, 5-40% of w/w first mixture of silicone oils, 0-10% w/w of first almond oil; first vegetable oil or mixture thereof; 0-5% w/w of fatty acid amide; 1-5% w/w of first surfactant and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of shell, 5-10% of w/w first mixture of silicone oils, 0-10% w/w of first almond oil; first vegetable oil or mixture thereof; 0-5% w/w of fatty acid amide; 1-5% w/w of first surfactant and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of shell, 10-20% of w/w first mixture of silicone oils, 0-10% w/w of first almond oil; first vegetable oil or mixture thereof; 0-5% w/w of fatty acid amide; 1-5% w/w of first surfactant and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of shell, 20-30% of w/w first mixture of silicone oils, 0-10% w/w of first almond oil; first vegetable oil or mixture thereof; 0-5% w/w of fatty acid amide; 1-5% w/w of first surfactant and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of shell, 30-40% of w/w first mixture of silicone oils, 0-10% w/w of first almond oil; first vegetable oil or mixture thereof; 0-5% w/w of fatty acid amide; 1-5% w/w of first surfactant and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of shell, 5-40% of w/w first mixture of silicone oils, 0-5% w/w of first almond oil; first vegetable oil or mixture thereof; 0-5% w/w of fatty acid amide; 1-5% w/w of first surfactant and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of shell, 5-40% of w/w first mixture of silicone oils, 5-10% w/w of first almond oil; first vegetable oil or mixture thereof; 0-5% w/w of fatty acid amide; 1-5% w/w of first surfactant and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of shell, 5-40% of w/w first mixture of silicone oils, 0-10% w/w of first almond oil; first vegetable oil or mixture thereof; 0-5% w/w of fatty acid amide; 1-5% w/w of first surfactant and 5-10% w/w water. In another embodiment, the capsules comprise 30-50% w/w of shell, 5-40% of w/w first mixture of silicone oils, 0-10% w/w of first almond oil; first vegetable oil or mixture thereof; 0-5% w/w of fatty acid amide; 1-5% w/w of first surfactant and 10-20% w/w water. In another embodiment, the capsules comprise 30-50% w/w of shell, 5-40% of w/w first mixture of silicone oils, 0-10% w/w of first almond oil; first vegetable oil or mixture thereof; 0-5% w/w of fatty acid amide; 1-5% w/w of first surfactant and 20-30% w/w water. In some other embodiments, in any one of the capsules described above the first almond oil has a viscosity of 35-45 cp. In some other embodiments, in any one of the capsules described above the first vegetable oil has a viscosity of 5-80 cp. Each possibility represents a separate embodiment of this invention.

P-622096-IL 19 id="p-62" id="p-62" id="p-62" id="p-62" id="p-62" id="p-62" id="p-62"

[0062] In some embodiments, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax, 5-40% w/w of a first mixture of first silicone oil having a viscosity of between 100-1,000 cp and a second silicone oil having a viscosity of between 40,0– 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In one embodiment, the capsules comprise 30-40% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax, 5-40% w/w of a first mixture of first silicone oil having a viscosity of between 100-1,000 cp and a second silicone oil having a viscosity of between 40,000 – 80,0cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 40-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax, 5-40% w/w of a first mixture of first silicone oil having between 100-1,000 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax, 5-10% w/w of a first mixture of first silicone oil having a viscosity of between 100-1,000 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax, 10-20% w/w of a first mixture of first silicone oil having between 100-1,000 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax, 20-30% w/w of a first mixture of first silicone oil having between 100-1,000 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, P-622096-IL ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax, 30-40% w/w of a first mixture of first silicone oil having a viscosity of between 100-1,0cp and a second silicone oil having between 40,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax, 5-40% w/w of a first mixture of first silicone oil having between 100-200 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax, 5-40% w/w of a first mixture of first silicone oil having a viscosity of between 200-500 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax, 5-40% w/w of a first mixture of first silicone oil having a viscosity of between 500-800 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax, 5-40% w/w of a first mixture of first silicone oil having between 800-1,000 cp and a second silicone oil having a viscosity of between 40,0– 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax, 5-40% w/w of a first mixture of first silicone oil having between P-622096-IL 21 100-1,000 cp and a second silicone oil having a viscosity of between 40,000 – 50,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax, 5-40% w/w of a first mixture of first silicone oil having between 100-1,000 cp and a second silicone oil having a viscosity of between 50,000 – 70,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax, 5-40% w/w of a first mixture of first silicone oil having a viscosity of between 100-1,000 cp and a second silicone oil having between 70,000 – 80,000 cp, 0-5% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax, 5-40% w/w of a first mixture of first silicone oil having a viscosity of between 100-1,000 cp and a second silicone oil having a viscosity of between 50,000 – 70,000 cp, 5-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax, 5-40% w/w of a first mixture of first silicone oil having a viscosity of between 100-1,000 cp and a second silicone oil having a viscosity of between 50,000 – 70,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-10% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax, 5-40% w/w of a first mixture of first silicone oil having between 100-1,000 cp and a second silicone oil having a viscosity of between 50,0– 70,000 cp, 10-20% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 20-30% w/w water. In P-622096-IL 22 another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax, 5-40% w/w of a first mixture of first silicone oil having between 100-1,000 cp and a second silicone oil having a viscosity of between 50,000 – 70,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In some other embodiments, in any one of the capsules described above the first almond oil has a viscosity of 35-45 cp. In some other embodiments, in any one of the capsules described above the first vegetable oil has a viscosity of 5-80 cp.Each possibility represents a separate embodiment of this invention. [0063] In some embodiments, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 0-3 : 0-3 : 0-3, 5-40% w/w of a first mixture of first silicone oil having a viscosity of between 100-1,000 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In one embodiment, the capsules comprise 30-40% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 0-3 : 0-3 : 0-3, 5-40% w/w of a first mixture of first silicone oil having a viscosity of between 100-1,000 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 40-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 0-: 0-3 : 0-3, 5-40% w/w of a first mixture of first silicone oil having between 100-1,000 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 0-1 : 0-1 : 0-1, 5-40% w/w of a first mixture of first silicone oil having between 100-1,000 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, P-622096-IL 23 PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 1-3 : 1-3 : 1-3, 5-40% w/w of a first mixture of first silicone oil having a viscosity of between 100-1,000 cp and a second silicone oil having a viscosity of between 40,0– 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 2-3 : 2-3 : 2-3, 5-40% w/w of a first mixture of first silicone oil having between 100-1,000 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 0-3 : 0-3 : 0-3, 5-40% w/w of a first mixture of first silicone oil having between 100-200 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 0-3 : 0-3 : 0-3, 5-40% w/w of a first mixture of first silicone oil having a viscosity of between 200-500 cp and a second silicone oil having between 40,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 0-3 : 0-3 : 0-3, 5-40% w/w of a first mixture of first silicone oil having a viscosity of between 500-800 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 0- P-622096-IL 24 3 : 0-3 : 0-3, 5-40% w/w of a first mixture of first silicone oil having a viscosity of between 800-1,000 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 0-3 : 0-3 : 0-3, 5-40% w/w of a first mixture of first silicone oil having between 100-1,000 cp and a second silicone oil having a viscosity of between 40,000 – 50,0cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 0-3 : 0-3 : 0-3, 5-40% w/w of a first mixture of first silicone oil having a viscosity of between 100-1,000 cp and a second silicone oil having a viscosity of between 50,000 – 70,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 0-3 : 0-3 : 0-3, 5-40% w/w of a first mixture of first silicone oil having between 100-1,000 cp and a second silicone oil having a viscosity of between 70,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 0-3 : 0-3 : 0-3, 5-40% w/w of a first mixture of first silicone oil having a viscosity of between 100-1,000 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-5% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 0-: 0-3 : 0-3, 5-40% w/w of a first mixture of first silicone oil having a viscosity of between 100-1,000 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, 5-10% P-622096-IL w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-30% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 0-3 : 0-3 : 0-3, 5-40% w/w of a first mixture of first silicone oil having a viscosity of between 100-1,000 cp and a second silicone oil having a viscosity of between 40,0– 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 5-10% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 0-3 : 0-3 : 0-3, 5-40% w/w of a first mixture of first silicone oil having between 100-1,000 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-20% w/w water. In another embodiment, the capsules comprise 30-50% w/w of at least one of polyvinyl alcohol, carnauba wax and bees wax in a weight ratio of 0-3 : 0-3 : 0-3, 5-40% w/w of a first mixture of first silicone oil having a viscosity of between 100-1,000 cp and a second silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-10% w/w of mixture of first almond oil and first vegetable oil; 0-5% w/w of erucamide, oleamide, ethylene bis-oleamide, stearyl erucamide, and oleyl palmitamide; 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 20-30% w/w water. In some other embodiments, in any one of the capsules described above the first almond oil has a viscosity of 35-45 cp. In some other embodiments, in any one of the capsules described above the first vegetable oil has a viscosity of 5-80 cp. Each possibility represents a separate embodiment of this invention. [0064] In some embodiments, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of silicone oils, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In one embodiment, the composition comprises 5-10% w/w capsules, 5-40% w/w second mixture of silicone oils, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, the composition comprises 10-20% w/w capsules, 5-40% w/w second mixture of silicone oils, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, P-622096-IL 26 the composition comprises 20-30% w/w capsules, 5-40% w/w second mixture of silicone oils, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-10% w/w second mixture of silicone oils, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 10-20% w/w second mixture of silicone oils, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 20-30% w/w second mixture of silicone oils, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 30-40% w/w second mixture of silicone oils, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of silicone oils, 0-5% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of silicone oils, 5-10% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of silicone oils, 10-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of silicone oils, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-20% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of silicone oils, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 20-30% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of silicone oils, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 30-40% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of silicone oils, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 40-50% w/w water. In some other embodiments, in any one of the compositions described above the second almond oil has a viscosity of 35-45 cp. In some other embodiments, in any one of the compositions described P-622096-IL 27 above the second vegetable oil has a viscosity of 5-80 cp. Each possibility represents a separate embodiment of this invention. [0065] In some embodiments, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In one embodiment, the composition comprises 5-10% w/w capsules, 5-40% w/w second mixture of third silicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 10-20% w/w capsules, 5-40% w/w second mixture of third silicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 20-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-10% w/w second mixture of thirdsilicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 10-20% w/w second mixture of thirdsilicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,0cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 20-30% w/w second mixture of thirdsilicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 30-40% P-622096-IL 28 w/w second mixture of thirdsilicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having a viscosity of between 100-200 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having a viscosity of between 200-500 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having a viscosity of between 500-800 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having a viscosity of between 800-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 50,0cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 50,000 – 70,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 70,000 – 80,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any P-622096-IL 29 combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,0cp, 0-5% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 5-10% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 10-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-20% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,0cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 20-30% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 30-40% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 40-50% w/w water. In some other embodiments, in any one of the compositions described above the second almond oil has a viscosity of 35-45 cp. In some other embodiments, in any one of the P-622096-IL compositions described above the second vegetable oil has a viscosity of 5-80 cp. Each possibility represents a separate embodiment of this invention. [0066] In some embodiments, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having 350 cp and a second silicone oil having a viscosity of 60,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In one embodiment, the composition comprises 5-10% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 10-20% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having 350 cp and a second silicone oil having a viscosity of 60,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 20-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-10% w/w second mixture of thirdsilicone oil having 350 cp and a second silicone oil having a viscosity of 60,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 10-20% w/w second mixture of thirdsilicone oil having 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 20-30% w/w second mixture of thirdsilicone oil having 350 cp and a second silicone oil having a viscosity of 60,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 30-40% w/w second mixture of thirdsilicone oil having 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition P-622096-IL 31 comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 0-5% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 5-10% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 10-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-20% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 20-30% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 30-40% w/w water. In another embodiment, the composition comprises 5-30% w/w capsules, 5-40% w/w second mixture of thirdsilicone oil having 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 0-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 40-50% w/w water. In some other embodiments, in any one of the compositions described above the second almond oil has a viscosity of 35-45 cp. In some other embodiments, in any one of the compositions described above the second vegetable oil has a viscosity of 5-80 cp. Each possibility represents a separate embodiment of this invention. [0067] In some embodiments, the composition comprises 15-50% w/w second mixture of silicone oils, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, the composition comprises P-622096-IL 32 -20% w/w second mixture of silicone oils, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, the composition comprises 20-30% w/w second mixture of silicone oils, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, the composition comprises 30-40% w/w second mixture of silicone oils, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, the composition comprises 40-50% w/w second mixture of silicone oils, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of silicone oils, 0-5% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of silicone oils, 5-10% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of silicone oils, 10-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of silicone oils, 15-20% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of silicone oils, 20-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of silicone oils, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 10-20% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of silicone oils, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 20-30% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of silicone oils, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 30-40% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of silicone oils, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of second surfactant and 40-50% w/w water. In some other embodiments, in any one of the compositions described above the second almond oil has a viscosity of 35-45 cp. In some other P-622096-IL 33 embodiments, in any one of the compositions described above the second vegetable oil has a viscosity of 5-80 cp. Each possibility represents a separate embodiment of this invention. [0068] In some embodiments, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 15-20% w/w second mixture of third silicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 20-30% w/w second mixture of third silicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 30-40% w/w second mixture of third silicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 40-50% w/w second mixture of third silicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of between 100-200 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having between 200-500 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having between 500-800 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable P-622096-IL 34 oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of between 800-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 50,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 50,000 – 70,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 70,000 – 80,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-5% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. a viscosity of In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having between 40,000 – 80,000 cp, 10-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 15-20% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 20-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and P-622096-IL -50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-20% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 20-30% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 30-40% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of between 100-1,000 cp and a fourth silicone oil having a viscosity of between 40,000 – 80,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 40-50% w/w water. In some other embodiments, in any one of the compositions described above the second almond oil has a viscosity of 35-45 cp. In some other embodiments, in any one of the compositions described above the second vegetable oil has a viscosity of 5-80 cp. Each possibility represents a separate embodiment of this invention. [0069] In some embodiments, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 15-20% w/w second mixture of third silicone oil having a viscosity of 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 20-30% w/w second mixture of third silicone oil having a viscosity of 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 30-40% w/w second mixture of third silicone oil having a viscosity of 350 cp and a fourth silicone oil having a P-622096-IL 36 viscosity of 60,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 40-50% w/w second mixture of third silicone oil having a viscosity of 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 0-5% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 5-10% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 10-15% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 15-20% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 20-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-50% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 10-20% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 20-30% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone P-622096-IL 37 oil having a viscosity of 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 30-40% w/w water. In another embodiment, the composition comprises 15-50% w/w second mixture of third silicone oil having a viscosity of 350 cp and a fourth silicone oil having a viscosity of 60,000 cp, 0-25% w/w of mixture of second almond oil and second vegetable oil, 1-5% w/w of PMHS-g-PEG, PMHS, PEG or any combination thereof; and 40-50% w/w water. Each possibility represents a separate embodiment of this invention. First and second compositions and kits thereof [0070] In some embodiments, this invention provides a kit, comprising a first composition, a second composition, and instructions to use in a method of preventing arthropods from climbing on a climbable surface. In one embodiment, the first and second compositions are kept in separate containers which form part of the kit. [0071] In some embodiments, this invention provides a first composition. [0072] In some embodiments, this invention provides a second composition. [0073] In some embodiments, the first composition serves as a mechanical barrier between the climbable surface and the second composition serves as the active layer in preventing arthropods from climbing. In one other embodiment, each of the compositions as described hereinabove (prior to "First and second compositions and kits thereof" section) can be used as the first or second composition. In another embodiment, the first composition comprises the shell as described hereinabove; the first silicone oil as described hereinabove, having a viscosity of between 100-1000 cp; the first surfactant as described hereinabove and water. In another embodiment, the first composition comprises the shell as described hereinabove, at 5-20% w/w; the first silicone oil as described hereinabove, having a viscosity of between 100-1000 cp, at 10-30% w/w; the first surfactant as described hereinabove, at 0.5-10% w/w; and water, at 30-80% w/w. In one other embodiment, the first composition comprises polyvinylalcohol, first silicone oil of 350 cp; PMHS-g-PEG, PMHS, PEG or any combination thereof; and water. In one other embodiment, the first composition comprises polyvinylalcohol at 5-20% w/w, first silicone oil of 350 cp at 10-30% w/w; PMHS-g-PEG, PMHS, PEG or any combination thereof at 0.5-10% w/w and water, at 30-80% w/w. In one other embodiment, the first composition comprises polyvinylalcohol at 12% w/w, first silicone oil of 350 cp at 20% w/w; PMHS-g-PEG, PMHS, PEG or any combination thereof at 4% w/w and water, at 64% w/w. Each possibility represents P-622096-IL 38 a separate embodiment of this invention. Each possibility (e.g. identity of components; and concentrations thereof and ranges of the same) and combination of the same, as described hereinabove (non-limiting examples are found for example in the "Specific capsules and compositions" section, however any possibility as found throughout this document is plausible) – represent a separate embodiment of this invention. [0074] In another embodiment, the second composition comprises an aqueous phase and an oily phase. In another embodiment, the aqueous phase comprises the shell as described hereinabove and water. In another embodiment, the aqueous phase comprises the shell as described hereinabove, at 0.5-10% w/w; and water at 90-99.5% w/w. In another embodiment, the aqueous phase comprises polyvinylalcohol and water. In another embodiment, the aqueous phase comprises polyvinylalcohol at 0.5-10% w/w; and water at 90-99.5% w/w. In another embodiment, the aqueous phase comprises polyvinylalcohol at 5% w/w; and water at 95% w/w. Each possibility represents a separate embodiment of this invention. Each possibility (e.g. identity of components; and concentrations thereof and ranges of the same) and combination of the same, as described hereinabove (non-limiting examples are found for example in the "Specific capsules and compositions" section, however any possibility as found throughout this document is plausible) – represent a separate embodiment of this invention. [0075] In another embodiment, the oily phase comprises the third silicone oil as described hereinabove, having a viscosity of between 100-1000 cp; the fourth silicone oil as described hereinabove, having a viscosity of between 40,000-80,000 cp; the first almond oil as described hereianbove; the first vegetable oil as described hereinabove ; and the second surfactant as described hereinabove. In another embodiment, the oily phase comprises the third silicone oil as described hereinabove, having a viscosity of between 100-1000 cp, at 40-70% w/w; the fourth silicone oil as described hereinabove, having a viscosity of between 40,000-80,000 cp, at 10-30% w/w; the first almond oil as described hereinabove, at 1-15% w/w; the first vegetable oil as described hereinabove, at 1-15% w/w; and the second surfactant as described hereinabove, at 0.5-10% w/w. In another embodiment, the oily phase comprises the third silicone oil, having a viscosity of 350 cp; the fourth silicone oil, having a viscosity of between 60,000 cp; the first almond oil having molecular weight of 300gr/mol; the first vegetable oil, having a molecular weight of 1520 gr/mol; and PMHS-g-PEG, PMHS, PEG or any combination thereof. In another embodiment, the oily phase comprises the third silicone oil, having a viscosity of 350 cp, at 40-70% w/w; the fourth silicone oil, having a viscosity of between 60,000 cp, at 10-30% w/w; the first almond oil having molecular weight of 300gr/mol, at 1-15% w/w; the first vegetable oil, P-622096-IL 39 having a molecular weight of 1520 gr/mol, at 1-15% w/w; and PMHS-g-PEG, PMHS, PEG or any combination thereof, at 0.5-10% w/w. In another embodiment, the oily phase comprises the third silicone oil, having a viscosity of 350 cp, at 55% w/w; the fourth silicone oil, having a viscosity of between 60,000 cp, at 20% w/w; the first almond oil having molecular weight of 300gr/mol, at 10% w/w; the first vegetable oil, having a molecular weight of 1520 gr/mol, at 10% w/w; and PMHS-g-PEG, PMHS, PEG or any combination thereof, at 5% w/w. In one embodiment, the vegetable oil is an olive oil. Each possibility represents a separate embodiment of this invention. Each possibility (e.g. identity of components; and concentrations thereof and ranges of the same) and combination of the same, as described hereinabove (non-limiting examples are found for example in the "Specific capsules and compositions" section, however any possibility as found throughout this document is plausible) – represent a separate embodiment of this invention. [0076] In one further embodiment, this invention provides methods of preparing the first and second compositions of the kit. In one embodiment, the first composition is prepared in a method comprising mixing (between 1-240 minutes, e.g. 1, 2, 10, 20, 60, 120 or 240 minutes) and heating (to between 40-90C, e/g/ 40,50, 60, 70, 80, 85 or 90C), optionally via homogenizer of the corresponding ingredients, which are detailed hereinabove. The aqueous and oily phase of the second compositions are prepared in a similar method to the first composition, each independently can be prepared by unique combination of heating temperature and time (of the corresponding ingredients). In one embodiment, the second composition is prepared by a method comprising mixing and heating together (as described hereinabove) the oily and aqueous phases. In another embodiment, the ratio of oily to aqueous phase is between 4:1 to 1:4; or 1:1; or 3:2; or 2:3. Each possibility represents a separate embodiment of this invention. [0077] In some embodiments, this invention provides method of preventing arthropods climbing on a climbable surface, comprising application of the first composition of the kit on the climbable surface, wherein the climbable surface is as described hereinabove; followed by application of the second composition in the same. In some other embodiment, the obtained thickness of the layers/films is as the same as described hereinabove in the "Self-lubricating composition and capsule" section. In one embodiment, there should be between 30-120, 5-10, 20-30, 10-30, 30-60, 60-90 or 90-120 minutes between the applications of the first and second compositions. Each possibility represents a separate embodiment of this invention. [0078] In some embodiments, the term "polymethylhydrosiloxane-polyethylene glycol copolymer (PMHS-g-PEG), PMHS, PEG or any combination thereof" or "PMHS-g-PEG, P-622096-IL 40 PMHS, PEG or any combination thereof", as found throughout this whole document, is defined as only PMHS, only PEG, only PMHS-PEG or any possible combination between the triad, including e.g. PMHS-g-PEG, PMHS and PEG as one combination; and PMHS and PEG as other combination, amongst other combinations. In one other embodiment, the combination is PMHS-g-PEG, PMHS and PEG, wherein the PMHS-g-PEG is 10-100, 10-50, 50-100, 10-20, 20-30, 30-40, 40-50, 50-60, 60-70, 70-80, 80-90 or 90-100% w/w of the whole combination. Each possibility represents a separate embodiment of this invention. [0079] In some embodiments, when a ratio of "X : 0" (reading, "X : zero", wherein X is an integer) is indicated in any one of this document’s embodiments – the zero means a value of "around zero", i.e. very close to zero (for example, milli (10-3), micro (10-6), nano (10-9), etc.). The following examples are presented in order to more fully illustrate the preferred embodiments of this invention. They should in no way, however, be construed as limiting the broad scope of this invention. EXAMPLES Example Preparation of PMHS-g-PEG id="p-80" id="p-80" id="p-80" id="p-80" id="p-80" id="p-80" id="p-80"

[0080] 125gr KOH was dissolved in 50 ml distilled water, and to the mixture was dripped 1gr PMHS cautiously and slowly. While adding PMHS, were added 350 ml of distilled water in portions, 100 ml each time, while maintaining the prevention of the exothermic reaction. After adding all the reagents, the mixture kept stirring overnight, all the solid phase was dissolved, and at room temp were added 110 ml of PEG 400, the reaction was carried out slowly and the color of the solution changed from colorless to yellow-orange. The obtained material was isolated in one of the following ways: a) the crude solution was dried until provision of a dried solid; or b) an acid was added to the crude solution to arrive at pH=7, where precipitation occurred and the precipitate was isolated and dried. Example Characterization of the PMHS-g-PEG copolymer via ATR-FTIR id="p-81" id="p-81" id="p-81" id="p-81" id="p-81" id="p-81" id="p-81"

[0081] The PMHS-g-PEG prepared in Example 1 was characterized via ATR-FTIR. The bottom curve (having a peak at 2161 cm-1) is the ATR absorption of the mixture of PEG and PMHS 1:before the reaction. The top curve is the ATR absorption of the PMHS-g-PEG after the reaction.

P-622096-IL 41 Figures 1A-1B show that the PMHS-g-PEG is characterized by different features with respect to the mixture before the reaction (PEG: PMHS 1: 1). The main differences are shown at 2161 cm- and 944 cm-1. Most of the Si-H groups (2161 cm-1) are consumed in PMHS-g-PEG, which is further confirmed by the Hydrogen that evolved during the reaction process. A new sharp peak at 944 cm-1 is observed in PMHS-g-PEG that doesn’t exist in the mixture before the reaction and it is characteristic to Si-O-Alcohol (Si-O-PEG). Example Capsules for self lubricating composition comprising PMHS-g-PEG as surfactant id="p-82" id="p-82" id="p-82" id="p-82" id="p-82" id="p-82" id="p-82"

[0082] Ingredients within the capsule (% are w/w): - 40% polyvinylalcohol + Carnauba wax + Bee wax (0-3 : 0-3 : 0-3) - - 5-40% a mixture of Silicone oils (350 cp and 60000 cp) 1-3 : 0-1 - 0-10% almond oil/ vegetable oils (<100 cp) - 0-5% mixture of Fatty acid amides; - Erucamide, Oleamide, Ethylene bis-oleamide (EBO), Stearyl erucamide (SE), Oleyl palmitamide (OP) - 1-5% surfactant (PMHS-g-PEG) - 5-30% distilled water [0083] All ingredients were stirred in a high-shear mixer (homogenizer) for 10 min at 85˚C. When a homogeneous and uniform emulsion was obtained, the emulsion was placed into an ice bowl to freeze the size of the capsules. Microcapsules were obtained. Example Self lubricating composition comprising PMHS-g-PEG as surfactant id="p-84" id="p-84" id="p-84" id="p-84" id="p-84" id="p-84" id="p-84"

[0084] Ingredients within the composition (% are w/w): - 5-30% Microcapsules of Example 3 - 5-40% a mixture of Silicone oils (350 cp and 60000 cp) 3:1 - 0-15% almond oil/ vegetable oils (<100 cp) - 1-5% surfactant (PMHS-g-PEG) - 10-50% distilled water P-622096-IL 42 id="p-85" id="p-85" id="p-85" id="p-85" id="p-85" id="p-85" id="p-85"

[0085] The microcapsules of Example 3 were filtered and added to an emulsion composition having the above ingredients in the concentration as indicated hereinabove. All ingredients were stirred in a high-shear mixer (homogenizer) for 10 min at room temperature.

Example Inhibition of ants climbing on a wood coated with the self lubricating compositions of this invention Experimental research is conducted to examine the success rate of the different self lubricating compositions to prevent the Componotus Ants from climbing the wood. [0086] Ants consume honeydew which is produced by homopterans (Aphids). By exploiting hemipteran honeydew, ants provide a sanitary service to the pests and protect them from parasitoids and other enemies. Ants also transport these hemipterans to safer sites where they can flourish. Thus, the relationship between sap-sucking homopterans and attending ants is mutually beneficial, but may be detrimental to the host plants, as expanding hemipteran colonies take more of their nutrients. (Martinez, JJ.I., Cohen, M. & Mgocheki, N. The response of an aphid tending ant to artificial extra-floral nectaries on different host plants. Arthropod-Plant Interactions 5, 185–192 (2011). https://doi.org/10.1007/s11829-011-9127-6). Materials and Equipment 1. Componotus Ants 2. Wood sticks 10cm x 1cm x 0.2 cm 3. 100 ml transparent rounded plastic containers + lid 4. Yellow sticky insects tape 5. Sugar syrup concentration of 50% 6. self lubricating compositions, e.g. Example 4. Test method [0087] The experimental system consists of one common ant species, Componotus (Hymenoptera: Formicidae). The ants are collected from e.g. Al Qassimi college campus garden and maintained in big plastic containers with soil from their nest. Success rate of ants climbing on the coated wood is measured by counting the number of ants that get stuck on a sticky trap on top of the wood stick, which was coated with the compositions beforehand. Rounded transparent plastic containers (100 ml) are used for each coating material.

P-622096-IL 43 A wood stick (7.5 cm) is glued to each plastic container lid (Figure 2A) to mimic a tree trunk. Every wood stick is sprayed with said compositions, e.g. Example 4, and remains on the table for 15-20 minutes to get dry (Figure 2B). Small piece of sticky tape (0.75 cm * 1 cm) is placed on top of each wood stick with a drop of 100 μl of 50% sucrose solution to mimic the honeydew that the aphids produce to attract ants (Figure 2C). Ten to fifteen Componotus ants that were subjected to a diet without food or water for 3 days prior to the experiment are placed in each plastic container (Figure 2D). Each ant is not used more than one time to avoid any adaptive or learning effects. The experiment is replicated at least 6 times with each different composition and ant. The experiment is done in hours light / 12 hours dark rounds, 22-0C for 72 hours. After 72 hours, the number of stuck ants is collected. [0088] The coating success rate is calculated as follows: u0003u0004u0005u0005u0006u0007u0007 u0003u0004u0005u0005u0006u0007u0007 u0003u0004u0005u0005u0006u0007u0007 u0003u0004u0005u0005u0006u0007u0007 btu0006 btu0006 btu0006 btu0006 (%)=100 −( u000bfru000eu000fu0010 u0011u0012 u0013fu0014u0014u000fu0013u0013u0012fu0015 u0016u000bu0017u0013u000bfru000eu000fu0010 u0011u0012 u0017u000fu0013u0017u000fu0018 u0016u000bu0017u0013 ×100) The insect is considered "successful" if it did pass the coating material and did reach the edge of the wood stick and got stuck on the yellow sticker. Success rates for the compositions of this invention are found to be high. Results [0089] Coating of vertical wood surfaces with the self lubricating compositions of this invention (e.g. Example 4) results in failure of the Componotus ants to adhere to- and to climb on said vertical wood surfaces, thus their climbing on said surfaces is inhibited and/or prevented by these compositions. Example Preparing the two layers/compositions of the kit of this invention id="p-90" id="p-90" id="p-90" id="p-90" id="p-90" id="p-90" id="p-90"

[0090] First layer/composition ingredients (w/w): - 64% water - 12% polyvinylalcohol - 20% Silicone oil 350 cp - 4% PMHS-g-PEG P-622096-IL 44 id="p-91" id="p-91" id="p-91" id="p-91" id="p-91" id="p-91" id="p-91"

[0091] All ingredients were put in one vessel and then mixed (in a homogenizer) while heated to 85C, for 10 minutes. [0092] Second layer/composition: [0093] Aqueous phase ingredients (w/w): - 95% water - 5% polyvinylalcohol [0094] The materials were dissolved and mixed at 85C. [0095] Oily phase ingredients (w/w): - 55% silicone oli 350 cp - 20% Silicone oil 60,000 cp - 10% almond oil (300gr/mol) - 10% olive oil (1520 gr/mol) - 5% PMHS-g-PEG [0096] The oily phase was heated to 85C, then it was added to the aqueous phase in a ratio of 3:2 (oily : aqueous), and finally all phases were mixed together at homogenizer for 10 minutes. Example Coating with two layers/compositions kit id="p-97" id="p-97" id="p-97" id="p-97" id="p-97" id="p-97" id="p-97"

[0097] The kit included both first and second compositions in separate containers. The first composition of Example 6 is applied on a tree trunk at 10-15 cm height, providing a 100 micron thickness layer. Following 10-30 minutes from application of first layer, the second composition is applied on top of the first, providing 100 micron thickness of a second layer (same height as first layer). Then prevention of ants from climbing on said tree trunk is tested as detailed in e.g. Example 5. The test shows that the kit of said compositions is successful in inhibiting ants from climbing the tree trunk. [0098] While certain features of this invention have been illustrated and described herein, many modifications, substitutions, changes, and equivalents will now occur to those of ordinary skill in the art. It is, therefore, to be understood that the appended claims are intended to cover all such modifications and changes as fall within the true spirit of this invention.

Claims

310179/ What is claimed is:

1. A surfactant comprising polymethylhydrosiloxane (PMHS) and polyethylene glycol (PEG).

2. The surfactant according to claim 1, being a copolymer of PMHS and PEG.

3. The surfactant according to claim 1 or 2, for use in forming a self-lubricating formulation.

4. The surfactant according to claim 3, wherein the self-lubricating composition comprises capsules, each of said capsules formed of a core comprising a mixture of oils and fats of different molecular weights; and a shell.

5. The surfactant according to claim 4, wherein the shell comprises polyvinyl alcohol, Polycaprolactone, Fatty alcohol, biodegradable polyesters, poly(furfuryl alcohol) bioresin, Cellulose, lignin, biobased wax, paraffin wax or any combination thereof.

6. The surfactant according to claim 4, being contained in the core of said capsules.

7. The surfactant according to claim 4, being contained outside of said capsules.

8. A method of preventing arthropods climbing on a climbable surface, the method comprising applying a surfactant according to any one of clams 1 to 7 or a formulation comprising same on the climbable surface.

9. The method according to claim 8, wherein the formulation is a self-lubricating formulation comprises a plurality of capsules, each having a core comprising a mixture of oils and fats of different molecular weights; and a shell.

10. The method according to claim 9, wherein the prevention of arthropods climbing on a climbable surface comprises disruption of Van der Waals interaction between the arthropods legs and the climbable surface. 310179/

11. The method according to claim 9 or 10, wherein the climbable surface is a tree trunk, an internal or external wall, a fence or a greenhouse.

12. The method according to any one of claims 9 to 11, wherein the self-lubricating composition is applied by a method comprises spraying or brushing of the climbable surface with the self-lubricating composition.

13. The method according to any one of claims 8 to 12, wherein the formulation is a self-lubricating formulation comprising (a) a plurality of core/shell capsules, wherein the core of said capsules comprising a first mixture of oils and fats having a multiplicity of molecular weights; (b) a second mixture of oils and fats having a multiplicity of molecular weight and being external to said core/shell capsules; (c) a first surfactant, and optionally second surfactant, wherein the first mixture and the second mixture are same or different and wherein one or both of said first surfactant and the second surfactant is the surfactant of any one of claims 1 to 7.

14. A formulation comprising a surfactant according to any one of clams 1 to 7.

15. The formulation according to claim 14, comprising the surfactant in a minimum amount between 1 and 5 wt%.

16. The formulation according to claim 14 or 15 being a water-based formulation.

17. The formulation according to any one of claims 14 to 16, for use in a method of coating a surface.

18. The formulation according to any one of claims 14 to 17, wherein the formulation is a self-lubricating formulation comprising (a) a plurality of core/shell capsules, wherein the core of said capsules comprising a first mixture of oils and fats having a multiplicity of molecular weights; (b) a second mixture of oils and fats having a multiplicity of molecular weight and being external to said core/shell capsules; (c) a first surfactant, and optionally second surfactant, wherein the first mixture and the second mixture are same or different and wherein one or both of said first surfactant and the second surfactant is the surfactant of any one of claims 1 to 7. 310179/

19. The surfactant according to any one of claims 1 to 7 being a compound represented by Formula (I) : (I) wherein m is an integer between 2 – 2000; and n is an integer between 10 – 1

20. 20. The formulation according to claim 14, wherein the surfactant is the compound of Formula (I) of claim 19.