IE50814B1 - Hair waving or straightening process that simultaneously conditions hair and hair waving composition for this process - Google Patents
Hair waving or straightening process that simultaneously conditions hair and hair waving composition for this processInfo
- Publication number
- IE50814B1 IE50814B1 IE112/81A IE11281A IE50814B1 IE 50814 B1 IE50814 B1 IE 50814B1 IE 112/81 A IE112/81 A IE 112/81A IE 11281 A IE11281 A IE 11281A IE 50814 B1 IE50814 B1 IE 50814B1
- Authority
- IE
- Ireland
- Prior art keywords
- approximately
- hair
- weight
- waving
- polymers
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title claims abstract description 14
- 230000003472 neutralizing effect Effects 0.000 claims abstract description 17
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 14
- 239000003599 detergent Substances 0.000 claims abstract description 12
- 229920006317 cationic polymer Polymers 0.000 claims abstract description 11
- 239000007800 oxidant agent Substances 0.000 claims abstract description 8
- 230000001143 conditioned effect Effects 0.000 claims abstract description 4
- 125000000129 anionic group Chemical group 0.000 claims abstract description 3
- 230000003750 conditioning effect Effects 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 4
- -1 alkali metal salts Chemical class 0.000 claims description 3
- 229920002717 polyvinylpyridine Polymers 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical group OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 2
- 239000000470 constituent Substances 0.000 claims 2
- XWNSFEAWWGGSKJ-UHFFFAOYSA-N 4-acetyl-4-methylheptanedinitrile Chemical compound N#CCCC(C)(C(=O)C)CCC#N XWNSFEAWWGGSKJ-UHFFFAOYSA-N 0.000 claims 1
- 239000004153 Potassium bromate Substances 0.000 claims 1
- BOUCRWJEKAGKKG-UHFFFAOYSA-N n-[3-(diethylaminomethyl)-4-hydroxyphenyl]acetamide Chemical compound CCN(CC)CC1=CC(NC(C)=O)=CC=C1O BOUCRWJEKAGKKG-UHFFFAOYSA-N 0.000 claims 1
- 229940094037 potassium bromate Drugs 0.000 claims 1
- 235000019396 potassium bromate Nutrition 0.000 claims 1
- 239000006210 lotion Substances 0.000 description 25
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- PMNLUUOXGOOLSP-UHFFFAOYSA-N 2-mercaptopropanoic acid Chemical compound CC(S)C(O)=O PMNLUUOXGOOLSP-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 239000008135 aqueous vehicle Substances 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000008406 cosmetic ingredient Substances 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 2
- 239000003981 vehicle Substances 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- HLNJFEXZDGURGZ-UHFFFAOYSA-M 1-methylpyridin-1-ium;iodide Chemical compound [I-].C[N+]1=CC=CC=C1 HLNJFEXZDGURGZ-UHFFFAOYSA-M 0.000 description 1
- CKFRJFUTYHQHCA-UHFFFAOYSA-N 2-phosphanylethanol Chemical compound OCCP CKFRJFUTYHQHCA-UHFFFAOYSA-N 0.000 description 1
- AEDQNOLIADXSBB-UHFFFAOYSA-N 3-(dodecylazaniumyl)propanoate Chemical compound CCCCCCCCCCCCNCCC(O)=O AEDQNOLIADXSBB-UHFFFAOYSA-N 0.000 description 1
- XYYUAOIALFMRGY-UHFFFAOYSA-N 3-[2-carboxyethyl(dodecyl)amino]propanoic acid Chemical compound CCCCCCCCCCCCN(CCC(O)=O)CCC(O)=O XYYUAOIALFMRGY-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical class [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 230000003113 alkalizing effect Effects 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 1
- 235000018417 cysteine Nutrition 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- JZKFHQMONDVVNF-UHFFFAOYSA-N dodecyl sulfate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOS(O)(=O)=O JZKFHQMONDVVNF-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- QUPVIPDFFMWKDW-UHFFFAOYSA-L potassium;sodium;dibromate Chemical class [Na+].[K+].[O-]Br(=O)=O.[O-]Br(=O)=O QUPVIPDFFMWKDW-UHFFFAOYSA-L 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 230000003655 tactile properties Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/04—Preparations for permanent waving or straightening the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
A process for waving or straightening hair that leaves the hair in conditioned form which comprises treating the hair with a novel hair waving composition containing a reducing agent and certain cationic polymers followed by treating said hair with a "neutralizing" composition containing an oxidizing agent and an anionic or amphoteric detergent.
Description
This invention relates to compositions for waving or straightening hair, and especially human hair, and to processes for effecting the same. More particularly, it concerns compositions and methods of the aforesaid character which leaves the hair in a conditioned or improved manner.
Waving or straightening of hair with reducing agents such as mercaptans, sulfites or phosphines is almost invariably accompanied by deterioration of tactile properties of hair, increased tangling and difficult combing.
This is true for all types of hair and particularly bothersome for hair which, prior to waving, had been exposed to bleaching, coloring or prolonged weathering. The conventional way to ameliorate this situation is to treat the waved hair with conditioning agents such as alkyl-dimethyl benzyl halides, emulsions of mineral oil, lanolin, etc. Conditioning agents of this type are usually incorporated in the neutralizing step of the waving or the straightening process. While these conditioning compounds improve the feel of hair and allow for easier combing, their beneficial effects are only transitory and are entirely lost when the hair is shampooed.
It has now been found that durable conditioning of hair during a hair waving or a hair straightening operation that is superior in its effects to conventional techniques can be obtained by first treating the hair with a reducing composition containing certain specific cationic-polymers defined in more detail below followed by the treatment of the hair with a neutralizing formulation containing an anionic or an amphoteric surfactant. As a result of the
-3sequence of the waving (or straightening) and neutralizing steps and a unique combination of ingredients, a conditioning complex,· stable to repeated shampooings, is formed in the hair.
It is accordingly an object of this invention to provide a process for waving or straightening hair which leaves the hair in a conditioned fashion which resists repeated shampooings.
It is also an object of the present invention to pro10 vide compositions which are useful in carrying out the aforesaid process.
Other and more detailed objects of this invention will be apparent from the following description and claims.
The cationic polymers that are useful for the purpose 15 of the present invention are from relatively narrow
S Q 8 1 4
-4classes.
One class of cationic polymers that may be employed in the present invention are polymers and copolymers 5 of ouaternized polyvinylamine. These can be described by the generalized formula:
CH2 —CH (II) where R^, R2 and R^ are either the same or different radicals and represent alkyl group having up to 20 carbon atoms and X- is an anion such as halide (e.g. iodide or chloride) sulfate or carboxylate. These ordinarily will have a molecular weight in the range of from about 5000 to about 100,000. By way of example, mention may be made of trimethyl polyvinyl ammonium sulfate which may be described by the 15. formula:
CH.
(III)
- CH |+
CH.-N 3 I
CH.
CH.
CH.— CH
CH.-N - CH. 3 I 3 CH.
SO,
Average M.W. about 50,000
A second class of useful cationic materials are polymers and copolymers of cuatemized polyvinylpyridine.
These are described by the general formula:
-550814
Where R is an alkyl radical of C^-C^q and the X is an anion such as a halide, sulfate or carboxylate. These also will have a molecular weight in the range of from about 5000 to about 100,000.
As an example of the cationic polymer of this group, the following may be mentioned:
polyvinyl methyl pyridinium iodide
Average M.W. 50,000
As mentioned above, the particular cationic polymers described will be contained in the waving lotion employed in the present invention. The quantity of cationic polymer that will be present in these waving lotions may vary somewhat depending on the results that are desired. Ordinarily, this will constitute between about .2% to about 10% by weight based on the total weight of the waving lotion with the optimal range being between about 1% to about 5% by weight of the waving lotion.
In addition to the cationic polymer, the waving lotion employed in this invention may also contain other conventional ingredients commonly employed in such waving lotion.
S Ο 8 1 4
Thus, the vehicle for the lotion will be an aqueous vehicle which will have incorporated therein one or more reducing agents. A variety of reducing agents are known in the prior art which are useful in waving or straightening hair. By way of example, we might mention: thioglycollic acid, cysteine, thiolactic acid, sodium-, potassium-, and ammonium sulfites and bisulfites, tris(hydroxyethyl phosphine). In the preferred form of this invention, the reducing agents that will be employed are thioglycollic acid and alkali metal salts e.g. sodium salts of sulfurous acid (e.g. sulfites and bisulfites).
The quantity of reducing agent contained in the waving lotion will also vary somewhat depending on the agent selected and the results desired. Usually, however, the waving lotion will contain from about 0.5% to about 20% by weight of reducing agent based on the total weight of the waving lotion. Optimal results are obtained when the reducing agent comprises from about 2% to about 10% by weight based on the total weight of the lotion.
In addition, the waving lotion may also contain fragrances, alkalizing agents and other conventional waving lotion ingredients. Moreover, it will also generally have a pH in the range of from about 5 to about 10.
The second essential component of the present conditioning system are amphoteric or anionic detergents which will ordinarily constitute part of the neutralizing lotion. There are a number of amphoteric detergents that are suitable for use in the present invention. However, two classes of detergents have been found to be especially effective.
The first class can be defined by the formula:
CH-COONa 1+
N CH2CH2OCH2COO
CH,
CH2
-7in which R is a long chain fatty radical containing from 10 to 18 carbon atoms. A typical example of such a compound or compounds is the case in which R represents coconut fatty radicals. A material·.of this character is sold under the trade name MIRANOL (Trade Mark) C2MSF and is described in the CTFA Cosmetic Ingredient Dictionary (1973) under the name AMPHOTERIC-2,
A second class of amphoteric detergents that is particularly effective for the purposes of the present invention can be defined by the formula:
R—NH-CHj—CHj-COOH wherein R is a long chain fatty alkyl group having from 10 to 18 carbon atoms. An example of such .a detergent is marketed under the trade name DERIPHAT (Trade Mark) 170 C in which the R in the formula is a mixture of lauryl and myristyl fatty alkyl groups. This material is described in the CTFA Cosmetic Ingredient Dictionary (1973) as Lauraminopropionic Acid.
All anionic detergents tested have been found useful in-this invention; thus, salts of alkyl sulfonates, alkyl sulfates, sulfonated and sulfated alkyl ethers as well as long chain carboxylic acid (where the chain length is at least C1Q) exhibit formation of conditioning complexes.
By way of specifically illustrating the anionic detergents that are useful herein, the following may be mentioned: sodium lauryl sulfate, sodium lauryl ether (laureth) sulfate, TEA lauryl sulfate, sodium stearate, etc.
The quantity of amphoteric or anionic detergent which will be contained in the neutralizing lotion of this invention will vary somewhat again depending on the economics and the results sought. However, usually this will be in the range of from about 0.2 to about 50% by weight and ideally, in the range of from about 0.5% to about 20% by s Ο 8 1 4
-8weight based on the total weight of the neutalizing lotion.
The neutralizing lotion may also contain other ingredients usually employed in such neutralizing lotions that are utilized in hair waving or hair straightening procedures
Again, the vehicle will ordinarily be an aqueous vehicle which will contain an oxidizing agent that will serve to neutralize the action of the reducing agent contained in the reducing agent contained in the waving lotion after the latter has been applied to the head. A number of oxidizing agents are known to those skilled in this art which will accomplish this purpose. These include hydrogen peroxide, sodium- and potassium- bromates, sodium perborate, etc.
The quantity of oxidizing agent that will be contained.
in the neutralizing lotion may also vary somewhat; again, depending on the agent selected and the results desired.
For the most part,' this will comprise between about 0.2% to about 20% by weight of the neutralizing lotion based on the total weight of said neutralizing lotion. In a preferred form of the invention, the oxidizing agent will constitute about 1% to about 10% by weight based on the total weight of the neutralizing lotion.
In addition to the above, among the other ingredients that may be contained in the neutralizing lotion, mention may be made of such materials as organic and inorganic acids (e.g. phosphoric, citric acid, etc.). The pH of the neutralizing lotion will usually be in the range of from about 2 to about 9.
Claims (6)
1. A process for waving o.r straightening hair which leaves the hair in a conditioned form which conditioning persists through repeated shampooings which comprises: . treating said hair with an aqueous waving composition containing an effective amount of a reducing agent and a polymer constituent, the latter consisting of a cationic polymer selected from i. polymers and copolymers of quaternized polyvinyl-amine having a molecular weight in the range of approximately 5000 to approximately 100,000; and ii. polymers and copolymers of quaternized polyvinyl pyridine having a molecular weight in the range of approximately 5000 to approximately 100,000; and then treating said hair with an aqueous neutralizing composition containing: iii. an oxidizing agent; and iv. an anionic or amphoteric detergent.
2. A process according to claim 1 in which the waving composition contains, based on the weight of said waving composition, approximately 0.5% to approximately 20% by weight of said reducing agent and approximately 0.2% to approximately 10% by weight of said cationic polymer, and said neutralizing composition contains, based on the weight of said neutralizing composition, approximately 0.2% to approximately 20% by weight of oxidizing agent and approximately 0.2% to approximately 50% by weight of said detergent.
3. A process according to claim 2 in which said reducing agent is selected from thioglycollic acid and alkali metal salts of sulfurous acid. -104. A process according to claim 2 or 3 in which said oxidizing agent is sodium or potassium bromate.
4. 5. A process according to claim 2, 3 or 4 in which said detergent is sodium or ammonium laureth sulfate. 5 6. An aqueous hair waving composition useful in the waving or straightening of hair containing, based on the weight of the waving composition: (a) approximately 0.5% to approximately 20% by weight of a reducing agent; and
5. 10 (b) approximately 0.2% to.approximately 10% by weight of a polymer constituent, the latter consisting of a cationic polymer selected from i. polymers and copolymers of quaternized-polyvinylamine having a molecular weight in the range of
6. 15 approximately 5000 to approximately 100,000; and ii. polymers and copolymers of quaternized polyvinylpyridine having a molecular weight in the range of approximately 5000 to approximately 100,000.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11447980A | 1980-01-23 | 1980-01-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE810112L IE810112L (en) | 1981-07-23 |
| IE50814B1 true IE50814B1 (en) | 1986-07-23 |
Family
ID=22355472
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE112/81A IE50814B1 (en) | 1980-01-23 | 1981-01-22 | Hair waving or straightening process that simultaneously conditions hair and hair waving composition for this process |
Country Status (18)
| Country | Link |
|---|---|
| JP (1) | JPS56150009A (en) |
| AU (1) | AU540290B2 (en) |
| BE (1) | BE887219A (en) |
| BR (1) | BR8100183A (en) |
| CA (1) | CA1138341A (en) |
| CH (1) | CH646039A5 (en) |
| DE (1) | DE3100737A1 (en) |
| DK (1) | DK29481A (en) |
| FR (1) | FR2473883B1 (en) |
| GB (1) | GB2068031B (en) |
| GR (1) | GR73514B (en) |
| IE (1) | IE50814B1 (en) |
| IT (1) | IT1170644B (en) |
| NL (1) | NL8100258A (en) |
| NZ (1) | NZ195964A (en) |
| PH (1) | PH18975A (en) |
| SE (1) | SE456475B (en) |
| ZA (1) | ZA81198B (en) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4948579A (en) * | 1974-05-16 | 1990-08-14 | Societe Anonyme Dite: L'oreal | Quaternized polymer for use as a cosmetic agent in cosmetic compositions for the hair and skin |
| US5196189A (en) * | 1974-05-16 | 1993-03-23 | Societe Anonyme Dite: L'oreal | Quaternized polymer for use as a cosmetic agent in cosmetic compositions for the hair and skin |
| AT365448B (en) * | 1975-07-04 | 1982-01-11 | Oreal | COSMETIC PREPARATION |
| FR2495931A2 (en) * | 1980-12-12 | 1982-06-18 | Oreal | METHOD FOR HAIR STRAIGHTENING, AND COMPOSITION FOR CARRYING OUT SAID METHOD |
| US4416297A (en) * | 1980-01-23 | 1983-11-22 | Clairol Incorporated | Hair waving or straightening process and product |
| US4407791A (en) * | 1981-09-28 | 1983-10-04 | Alcon Laboratories, Inc. | Ophthalmic solutions |
| NZ203095A (en) * | 1982-02-08 | 1986-10-08 | Bristol Myers Co | Aqueous hair waving compositions and packages containing them |
| CA1196576A (en) * | 1982-02-22 | 1985-11-12 | Stanley H. Pohl | Composition and process for the dyeing of hair |
| US4656043A (en) * | 1985-09-13 | 1987-04-07 | Richardson-Vicks Inc. | Peroxide-containing conditioning shampoo |
| EP0356508A4 (en) * | 1988-02-19 | 1990-10-03 | Amethyst Investment Group, Inc. | Permanent wave process and compositions |
| US4996997A (en) * | 1988-02-19 | 1991-03-05 | Amethyst Investment Group, Inc. | Permanent waving process and compositions |
| US5415856A (en) * | 1990-05-08 | 1995-05-16 | Preemptive Advertising Inc. | Hair treatment compositions containing disaccharides |
| FR2795316B1 (en) * | 1999-06-28 | 2004-12-24 | Oreal | PERMANENT PROCESS COMPRISING THE PRELIMINARY APPLICATION OF A COMPOSITION COMPRISING AT LEAST ONE ANIONIC POLYMER |
| US6805136B2 (en) | 2001-11-02 | 2004-10-19 | Kenra, Llc | Hair relaxer |
| US6723308B2 (en) | 2001-11-02 | 2004-04-20 | Kenra, Llc | Hair clarifying treatment |
| FR3004643B1 (en) * | 2013-04-19 | 2015-07-03 | Oreal | METHOD FOR LOOP RETENTION AND / OR KERATIN FIBER SMOOTHING USING A REDUCING COMPOSITION AND A NEUTRALIZING COMPOSITION, AND A CLEANING KIT |
| FR3004642B1 (en) * | 2013-04-19 | 2015-05-22 | Oreal | COSMETIC HAIR RELAXATION AND / OR VOLUME REDUCTION CAPILLARY COMPOSITION AND COSMETIC TREATMENT METHOD USING THE SAME |
| BR112015026185A2 (en) * | 2013-04-19 | 2017-07-25 | Oreal | cosmetic composition for the treatment of hair for curl relaxation and / or volume reduction, and cosmetic treatment process using said composition |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1113816A (en) * | 1965-11-24 | 1968-05-15 | Hercules Inc | Improvements in or relating to process and composition for the waving of hair |
| IT1035032B (en) * | 1970-02-25 | 1979-10-20 | Gillette Co | COSMETIC COMPOSITION AND PACKAGING THAT CONTAINS IT |
| DE2213671A1 (en) * | 1972-03-21 | 1973-10-04 | Cosmital Sa | METHODS AND MEANS FOR THE PERMANENT DEFORMING OF HAIR. |
| DE2347832C2 (en) * | 1973-09-22 | 1982-07-29 | Wella Ag, 6100 Darmstadt | Process for the permanent deformation of hair |
| FR2368508A2 (en) * | 1977-03-02 | 1978-05-19 | Oreal | HAIR CONDITIONING COMPOSITION |
| AU512531B2 (en) * | 1975-11-13 | 1980-10-16 | L'oreal | Process and composition for dyeing hair |
| JPS5261237A (en) * | 1975-11-13 | 1977-05-20 | Oreal | New cosmetic compound on basis of quaternarized polymer |
| LU76955A1 (en) * | 1977-03-15 | 1978-10-18 | ||
| LU78153A1 (en) * | 1977-09-20 | 1979-05-25 | Oreal | COSMETIC COMPOSITIONS BASED ON QUATERNARY POLYAMMONIUM POLYMERS AND PREPARATION PROCESS |
| FR2472382A1 (en) * | 1979-12-28 | 1981-07-03 | Oreal | PERMANENT HAIR DEFORMATION PROCESS |
-
1980
- 1980-03-26 CA CA000348455A patent/CA1138341A/en not_active Expired
-
1981
- 1981-01-06 AU AU66019/81A patent/AU540290B2/en not_active Ceased
- 1981-01-06 NZ NZ195964A patent/NZ195964A/en unknown
- 1981-01-09 FR FR8100273A patent/FR2473883B1/en not_active Expired
- 1981-01-13 BR BR8100183A patent/BR8100183A/en unknown
- 1981-01-13 ZA ZA00810198A patent/ZA81198B/en unknown
- 1981-01-13 DE DE19813100737 patent/DE3100737A1/en not_active Ceased
- 1981-01-20 NL NL8100258A patent/NL8100258A/en not_active Application Discontinuation
- 1981-01-21 PH PH25111A patent/PH18975A/en unknown
- 1981-01-21 GR GR63932A patent/GR73514B/el unknown
- 1981-01-21 SE SE8100340A patent/SE456475B/en not_active IP Right Cessation
- 1981-01-22 IT IT47616/81A patent/IT1170644B/en active
- 1981-01-22 GB GB8101959A patent/GB2068031B/en not_active Expired
- 1981-01-22 DK DK29481A patent/DK29481A/en not_active Application Discontinuation
- 1981-01-22 IE IE112/81A patent/IE50814B1/en unknown
- 1981-01-23 JP JP804381A patent/JPS56150009A/en active Pending
- 1981-01-23 BE BE0/203589A patent/BE887219A/en not_active IP Right Cessation
- 1981-01-23 CH CH45381A patent/CH646039A5/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| AU6601981A (en) | 1981-07-30 |
| SE8100340L (en) | 1981-07-24 |
| IT8147616A0 (en) | 1981-01-22 |
| PH18975A (en) | 1985-11-26 |
| GR73514B (en) | 1984-03-08 |
| SE456475B (en) | 1988-10-10 |
| IE810112L (en) | 1981-07-23 |
| NZ195964A (en) | 1984-07-06 |
| BE887219A (en) | 1981-07-23 |
| FR2473883B1 (en) | 1986-06-27 |
| IT8147616A1 (en) | 1982-07-22 |
| BR8100183A (en) | 1981-07-28 |
| FR2473883A1 (en) | 1981-07-24 |
| NL8100258A (en) | 1981-08-17 |
| ZA81198B (en) | 1983-02-23 |
| GB2068031B (en) | 1983-09-01 |
| AU540290B2 (en) | 1984-11-08 |
| DK29481A (en) | 1981-07-24 |
| GB2068031A (en) | 1981-08-05 |
| IT1170644B (en) | 1987-06-03 |
| JPS56150009A (en) | 1981-11-20 |
| CA1138341A (en) | 1982-12-28 |
| DE3100737A1 (en) | 1982-01-28 |
| CH646039A5 (en) | 1984-11-15 |
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