IE39619B1 - Method for removing sulfur and nitrogen in petroleum oils - Google Patents
Method for removing sulfur and nitrogen in petroleum oilsInfo
- Publication number
- IE39619B1 IE39619B1 IE1506/74A IE150674A IE39619B1 IE 39619 B1 IE39619 B1 IE 39619B1 IE 1506/74 A IE1506/74 A IE 1506/74A IE 150674 A IE150674 A IE 150674A IE 39619 B1 IE39619 B1 IE 39619B1
- Authority
- IE
- Ireland
- Prior art keywords
- nitrogen
- sulfur
- oil
- compounds
- oxidized
- Prior art date
Links
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 title abstract 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title abstract 8
- 239000011593 sulfur Substances 0.000 title abstract 8
- 229910052717 sulfur Inorganic materials 0.000 title abstract 8
- 239000003921 oil Substances 0.000 title abstract 7
- 229910052757 nitrogen Inorganic materials 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 3
- 239000003208 petroleum Substances 0.000 title abstract 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- 229910017464 nitrogen compound Inorganic materials 0.000 abstract 3
- 150000002830 nitrogen compounds Chemical class 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 230000005484 gravity Effects 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- 229910052920 inorganic sulfate Inorganic materials 0.000 abstract 1
- 150000002826 nitrites Chemical class 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 238000007086 side reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
- C10G27/12—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with oxygen-generating compounds, e.g. per-compounds, chromic acid, chromates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
- C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
- C10G53/14—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one oxidation step
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
A method for the removal of sulfur and nitrogen components from petroleum oils is disclosed. The unwanted sulfur and nitrogen is oxidized to the extent that the resultant compounds exhibit preferential solubility characteristics in some solvent with respect to the oil. The oxidation step involves reacting the sulfur and nitrogen compounds present with an oxide of nitrogen. In particular instances, pretreatment of the oil to remove active groups which cause undesirable side reactions or removal of low sulfur fractions prior to the oxidation step will increase the efficiency of the process. The oil containing the oxidized forms of sulfur and nitrogen is then mixed with a selective solvent, which is immiscible in the oil and in which the sulfur and nitrogen compounds will dissolve. Methanol is the presently preferred solvent. Separation of the oil from the methanol-oxidized compound solution may be effected in a gravity separator. The oxidant gas may be regenerated by the addition of oxygen and recirculated. The oxidized sulfur and nitrogen compounds may be decomposed in a hydrolysis reaction with a dilute base to separate inorganic sulfate and sulfite, and nitrate and nitrite compounds from the hydrocarbon parts of the compounds.
[US3847800A]
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US00385894A US3847800A (en) | 1973-08-06 | 1973-08-06 | Method for removing sulfur and nitrogen in petroleum oils |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE39619L IE39619L (en) | 1975-03-06 |
| IE39619B1 true IE39619B1 (en) | 1978-11-22 |
Family
ID=23523298
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE1506/74A IE39619B1 (en) | 1973-08-06 | 1974-07-16 | Method for removing sulfur and nitrogen in petroleum oils |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US3847800A (en) |
| JP (1) | JPS5337081B2 (en) |
| BE (1) | BE818350A (en) |
| BR (1) | BR7406369D0 (en) |
| CA (1) | CA1046004A (en) |
| DE (1) | DE2424274C3 (en) |
| FR (1) | FR2240280B1 (en) |
| GB (1) | GB1437569A (en) |
| IE (1) | IE39619B1 (en) |
| IN (1) | IN141762B (en) |
| IT (1) | IT1017927B (en) |
| NL (1) | NL7407257A (en) |
| SU (1) | SU508220A3 (en) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3919402A (en) * | 1973-08-06 | 1975-11-11 | Kvb Inc | Petroleum oil desulfurization process |
| US4382855A (en) * | 1981-10-28 | 1983-05-10 | Ashland Oil, Inc. | Process for removal of hydroxy- and/or mercapto-substituted hydrocarbons from coal liquids |
| US4485007A (en) * | 1982-06-15 | 1984-11-27 | Environmental Research And Technology Inc. | Process for purifying hydrocarbonaceous oils |
| LU86141A1 (en) * | 1985-10-24 | 1987-06-02 | Labofina Sa | PROCESS FOR REMOVING BASIC NITROGEN COMPOUNDS FROM GASOILS |
| US4711713A (en) * | 1986-02-24 | 1987-12-08 | Rei Technologies, Inc. | Process for enhancing the cetane number and color of diesel fuel |
| US4746420A (en) * | 1986-02-24 | 1988-05-24 | Rei Technologies, Inc. | Process for upgrading diesel oils |
| US4643820A (en) * | 1986-02-24 | 1987-02-17 | Oxiprocessing | Process for enhancing the cetane number of diesel fuel |
| FR2657620B1 (en) * | 1990-01-30 | 1992-04-17 | Elf France | PROCESS FOR THE STABILIZATION OF GAS OILS DERIVED FROM CATALYTIC CRACKING, GAS OIL OBTAINED THEREBY AND COMPOSITIONS CONTAINING SAID GAS OIL. |
| CN1062294C (en) * | 1995-09-05 | 2001-02-21 | 新疆石油管理局克拉玛依炼油厂 | A kind of petroleum distillate oil amino alcohol deacidification process |
| FR2753717B1 (en) * | 1996-09-24 | 1998-10-30 | PROCESS AND PLANT FOR THE PRODUCTION OF LOW SULFUR CATALYTIC CRACKING ESSENCES | |
| US6251289B1 (en) | 1999-06-03 | 2001-06-26 | Grt, Inc. | Treatment of contaminated liquids with oxidizing gases and liquids |
| US6368495B1 (en) * | 1999-06-07 | 2002-04-09 | Uop Llc | Removal of sulfur-containing compounds from liquid hydrocarbon streams |
| ES2179753B1 (en) | 2000-10-11 | 2005-02-16 | Universidad Politecnica De Valencia | PROCESS AND CATALYSTS FOR THE ELIMINATION OF SULFUR COMPOUNDS FROM THE GASOLINE FRACTION. |
| US6872231B2 (en) * | 2001-02-08 | 2005-03-29 | Bp Corporation North America Inc. | Transportation fuels |
| US6881325B2 (en) * | 2001-02-08 | 2005-04-19 | Bp Corporation North America Inc. | Preparation of components for transportation fuels |
| US20020148754A1 (en) * | 2001-02-08 | 2002-10-17 | Gong William H. | Integrated preparation of blending components for refinery transportation fuels |
| US6673230B2 (en) | 2001-02-08 | 2004-01-06 | Bp Corporation North America Inc. | Process for oxygenation of components for refinery blending of transportation fuels |
| US6544409B2 (en) | 2001-05-16 | 2003-04-08 | Petroleo Brasileiro S.A. - Petrobras | Process for the catalytic oxidation of sulfur, nitrogen and unsaturated compounds from hydrocarbon streams |
| US7153414B2 (en) * | 2002-12-10 | 2006-12-26 | Petroleo Brasileiro S.A.-Petrobras | Process for the upgrading of raw hydrocarbon streams |
| US7175755B2 (en) * | 2003-05-06 | 2007-02-13 | Petroleo Brasileiro S.A.-Petrobras | Process for the extractive oxidation of contaminants from raw hydrocarbon streams |
| EP1765959A4 (en) * | 2004-05-31 | 2010-07-28 | Agency Science Tech & Res | NOVEL PROCESS FOR OBSERVING FUEL SULFUR |
| US8016999B2 (en) * | 2004-05-31 | 2011-09-13 | Agency For Science, Technology And Research | Process for removing sulfur from fuels |
| BRPI0405847B1 (en) * | 2004-12-21 | 2015-04-22 | Petroleo Brasileiro Sa | Process for the extractive oxidation of contaminants present in crude oxide catalyzed fuel streams |
| JP4397432B1 (en) | 2009-06-19 | 2010-01-13 | 有限会社中部エンザイム | Fuel production method and fuel production apparatus |
| US9023120B2 (en) * | 2009-06-19 | 2015-05-05 | Cyuba Enzyme Ltd. | Fuel production method, fuel production apparatus, and fuel oil |
| US20110220550A1 (en) * | 2010-03-15 | 2011-09-15 | Abdennour Bourane | Mild hydrodesulfurization integrating targeted oxidative desulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds |
| US9296960B2 (en) * | 2010-03-15 | 2016-03-29 | Saudi Arabian Oil Company | Targeted desulfurization process and apparatus integrating oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds |
| US8658027B2 (en) | 2010-03-29 | 2014-02-25 | Saudi Arabian Oil Company | Integrated hydrotreating and oxidative desulfurization process |
| WO2012027820A1 (en) | 2010-09-03 | 2012-03-08 | Her Majesty The Queen In Right Of Canada As Represented By The Minister Of Natural Resources Canada | Production of high-cetane diesel product |
| BR112014009803B1 (en) | 2011-10-24 | 2021-07-06 | Aditya Birla Nuvo Limited | process to produce a surface-modified carbon black |
| US8906227B2 (en) | 2012-02-02 | 2014-12-09 | Suadi Arabian Oil Company | Mild hydrodesulfurization integrating gas phase catalytic oxidation to produce fuels having an ultra-low level of organosulfur compounds |
| HUE045169T2 (en) | 2012-03-30 | 2019-12-30 | Aditya Birla Science And Tech Company Limited | A process for obtaining carbon black powder with reduced sulfur content |
| JP6144352B2 (en) * | 2012-11-09 | 2017-06-07 | サウジ アラビアン オイル カンパニー | Oxidative desulfurization process and system using gaseous oxidant enriched feed |
| US8920635B2 (en) | 2013-01-14 | 2014-12-30 | Saudi Arabian Oil Company | Targeted desulfurization process and apparatus integrating gas phase oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds |
| CN108239556B (en) * | 2016-12-23 | 2020-08-07 | 中国石油天然气股份有限公司 | A method for separating and enriching basic and non-basic nitrogen compounds in coking wax oil |
| CN108795483B (en) * | 2017-05-02 | 2020-07-14 | 中国石油天然气股份有限公司 | A method for separating and refining non-basic nitrogen-containing compounds in petroleum fractions |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1935207A (en) * | 1930-03-27 | 1933-11-14 | Ig Farbenindustrie Ag | Process for the purification of a crude hydrocarbon |
| US1968842A (en) * | 1930-11-03 | 1934-08-07 | Atiantic Refining Company | Treatment of hydrocarbons |
| US2581050A (en) * | 1944-07-18 | 1952-01-01 | Centrallaboratorium Ab | Method for the production of dimethyl sulfoxide |
| US2556836A (en) * | 1949-03-11 | 1951-06-12 | Standard Oil Dev Co | Method of treating sour petroleum distillates |
| US2702824A (en) * | 1952-08-18 | 1955-02-22 | Nitroglycerin Ab | Liquid-vapor phase method for producing lower dialkyl sulfoxides |
| US2925442A (en) * | 1958-07-16 | 1960-02-16 | Crown Zellerbach Corp | Process for the oxidation of organic sulfides |
| US2976229A (en) * | 1959-04-24 | 1961-03-21 | Universal Oil Prod Co | Purification of acid oils |
| US3135078A (en) * | 1961-05-31 | 1964-06-02 | Phillips Petroleum Co | Package wrapping |
| US3267027A (en) * | 1961-07-17 | 1966-08-16 | Union Oil Co | Process of desulfurization employing alkali and nitrogen dioxide |
| US3135680A (en) * | 1961-09-11 | 1964-06-02 | Pure Oil Co | Process of refining diesel fuel with nitrogen dioxide |
| BE625074A (en) * | 1961-11-24 | |||
| US3164546A (en) * | 1961-12-22 | 1965-01-05 | Pure Oil Co | Two stage process of refining diesel fuel |
| US3294677A (en) * | 1964-02-05 | 1966-12-27 | Howe Baker Eng | Desulfurizing petroleum fractions with nitrogen dioxide and sulfuric acid |
| GB1051515A (en) * | 1964-04-22 |
-
1973
- 1973-08-06 US US00385894A patent/US3847800A/en not_active Expired - Lifetime
-
1974
- 1974-05-15 GB GB2156674A patent/GB1437569A/en not_active Expired
- 1974-05-18 DE DE2424274A patent/DE2424274C3/en not_active Expired
- 1974-05-24 CA CA200,763A patent/CA1046004A/en not_active Expired
- 1974-05-30 NL NL7407257A patent/NL7407257A/en not_active Application Discontinuation
- 1974-06-20 IN IN1365/CAL/74A patent/IN141762B/en unknown
- 1974-07-09 JP JP7863974A patent/JPS5337081B2/ja not_active Expired
- 1974-07-16 IE IE1506/74A patent/IE39619B1/en unknown
- 1974-07-25 FR FR7425960A patent/FR2240280B1/fr not_active Expired
- 1974-07-26 SU SU2049070A patent/SU508220A3/en active
- 1974-07-31 BE BE147170A patent/BE818350A/en unknown
- 1974-08-02 BR BR6369/74A patent/BR7406369D0/en unknown
- 1974-08-06 IT IT26012/74A patent/IT1017927B/en active
Also Published As
| Publication number | Publication date |
|---|---|
| BE818350A (en) | 1974-11-18 |
| BR7406369D0 (en) | 1975-05-27 |
| JPS5337081B2 (en) | 1978-10-06 |
| US3847800A (en) | 1974-11-12 |
| JPS5039704A (en) | 1975-04-12 |
| DE2424274C3 (en) | 1979-10-18 |
| IN141762B (en) | 1977-04-16 |
| AU7150974A (en) | 1976-01-22 |
| DE2424274A1 (en) | 1975-03-13 |
| FR2240280A1 (en) | 1975-03-07 |
| NL7407257A (en) | 1975-02-10 |
| SU508220A3 (en) | 1976-03-25 |
| GB1437569A (en) | 1976-05-26 |
| CA1046004A (en) | 1979-01-09 |
| DE2424274B2 (en) | 1979-03-01 |
| IE39619L (en) | 1975-03-06 |
| IT1017927B (en) | 1977-08-10 |
| FR2240280B1 (en) | 1979-02-16 |
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