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HK40070310B - Lid component for packages and package manufacturing method - Google Patents

Lid component for packages and package manufacturing method

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Publication number
HK40070310B
HK40070310B HK42022058880.0A HK42022058880A HK40070310B HK 40070310 B HK40070310 B HK 40070310B HK 42022058880 A HK42022058880 A HK 42022058880A HK 40070310 B HK40070310 B HK 40070310B
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HK
Hong Kong
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layer
width
encapsulation
corners
component
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HK42022058880.0A
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Chinese (zh)
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HK40070310A (en
Inventor
大道悟
宇野浩规
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三菱综合材料株式会社
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Publication of HK40070310A publication Critical patent/HK40070310A/en
Publication of HK40070310B publication Critical patent/HK40070310B/en

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Description

封装用盖部件及封装体的制造方法Method for manufacturing the cover component and package body for packaging

本申请是针对申请日为2019年10月9日、申请号为201980059130.3、发明名称为“封装用盖部件及封装体”的发明专利申请的分案申请。This application is a divisional application of the invention patent application filed on October 9, 2019, with application number 201980059130.3 and entitled "Cover component and encapsulation body for encapsulation".

技术领域Technical Field

本发明涉及一种接合于封装基板的封装用盖部件及封装体。The present invention relates to a cover component and a package body for bonding to a packaging substrate.

本申请主张基于2018年10月15日在日本申请的专利申请2018-194535号及2019年10月7日在日本申请的专利申请2019-184287号的优先权,并将其内容援用于此。This application claims priority based on Japanese Patent Application No. 2018-194535, filed on October 15, 2018, and Japanese Patent Application No. 2019-184287, filed on October 7, 2019, the contents of which are incorporated herein by reference.

背景技术Background Technology

以往,已知有为了从外部环境保护半导体激光器(LD)或LED等发光元件而密封在封装体内的半导体装置及发光装置(例如,参考专利文献1及2)。Previously, semiconductor devices and light-emitting devices were known to be sealed within a package to protect light-emitting elements such as semiconductor lasers (LDs) or LEDs from the external environment (see, for example, Patent Documents 1 and 2).

专利文献1中记载的半导体装置具备:封装基板,具有上部开口的凹部;半导体元件,容纳于凹部;窗部件(封装用盖部件),配置成覆盖凹部的开口;及密封结构,密封封装基板与窗部件之间。该密封结构具有:第一金属层,以框状设置于封装基板的上表面;第二金属层,以框状设置于窗部件的内表面;及金属接合层,设置于第一金属层与第二金属层之间,所述密封结构构成为第一金属层及第二金属层中的其中一个整体位于设置有第一金属层及第二金属层中的另一个的区域内。Patent Document 1 describes a semiconductor device comprising: a packaging substrate having a recess with an upper opening; a semiconductor element housed in the recess; a window member (a cover member for packaging) configured to cover the opening of the recess; and a sealing structure sealing the space between the packaging substrate and the window member. The sealing structure comprises: a first metal layer disposed in a frame shape on the upper surface of the packaging substrate; a second metal layer disposed in a frame shape on the inner surface of the window member; and a metal bonding layer disposed between the first metal layer and the second metal layer. The sealing structure is configured such that one of the first metal layer and the second metal layer is integrally located within the region where the other of the first metal layer and the second metal layer are disposed.

专利文献2中记载的发光装置具备:安装基板;紫外线发光元件,安装于安装基板;及盖(封装用盖部件),形成有配置于安装基板上的凹部,在所述凹部内容纳紫外线发光元件。安装基板具备支承体、被支承体支承的第一导体部、第二导体部及第一接合用金属层。盖具备:盖主体,在背面形成有凹部;及第二接合用金属层,在凹部的周部与第一接合用金属层对置而配置。各第一导体部、第二导体部及第一接合用金属层中离支承体最远的最上层由Au形成,这些第一接合用金属层和第二接合用金属层通过Au-Sn接合。Patent Document 2 describes a light-emitting device comprising: a mounting substrate; an ultraviolet light-emitting element mounted on the mounting substrate; and a cover (encapsulation cover component) having a recess formed on the mounting substrate, wherein the ultraviolet light-emitting element is housed within the recess. The mounting substrate comprises a support body, a first conductor portion supported by the support body, a second conductor portion, and a first bonding metal layer. The cover comprises: a cover body having a recess formed on its back side; and a second bonding metal layer disposed opposite to the first bonding metal layer at the periphery of the recess. The uppermost layer of each of the first conductor portion, second conductor portion, and first bonding metal layer, which is furthest from the support body, is formed of Au, and these first and second bonding metal layers are bonded by Au-Sn.

专利文献1中记载的金属接合部由Au-Sn合金构成。专利文献2中,第一接合用金属层和第二接合用金属层也通过Au-Sn合金接合。即,专利文献1及2的任一结构中,在封装用盖部件都形成有由Au-Sn合金构成的Au-Sn层。Au-Sn层例如通过在上述部位涂布Au-Sn浆料并进行回流焊而形成。The metal bonding portion described in Patent Document 1 is made of an Au-Sn alloy. In Patent Document 2, the first bonding metal layer and the second bonding metal layer are also bonded by an Au-Sn alloy. That is, in either Patent Document 1 or 2, an Au-Sn layer made of an Au-Sn alloy is formed in the encapsulation cover component. The Au-Sn layer is formed, for example, by applying Au-Sn paste to the above-mentioned area and performing reflow soldering.

若将Au-Sn浆料涂布于玻璃板材并进行回流焊,则有时Au-Sn层被从玻璃板材剥落或玻璃板材的一部分被剥离,封装用盖部件有可能破损。If Au-Sn paste is applied to a glass substrate and reflow soldered, the Au-Sn layer may sometimes peel off from the glass substrate or a portion of the glass substrate may be detached, potentially damaging the encapsulation cover component.

专利文献1:日本专利第6294417号公报Patent Document 1: Japanese Patent No. 6294417

专利文献2:日本专利第6260919号公报Patent Document 2: Japanese Patent No. 6260919

发明内容Summary of the Invention

本发明是鉴于这种情况而完成的,其目的在于提供一种能够抑制Au-Sn层的剥离及封装用盖部件的破损的封装用盖部件及封装体。The present invention was made in view of this situation, and its object is to provide a packaging cover component and a package body capable of suppressing the peeling of the Au-Sn layer and the breakage of the packaging cover component.

本发明的一方式所涉及的封装用盖部件为接合于封装基板的封装用盖部件,其具有:玻璃部件,具有设置成平面框状的接合部及设置于所述接合部的内侧的光透射部;一层以上的金属化层,以框状形成于所述玻璃部件的所述接合部;及一层以上的Au-Sn层,设置于所述金属化层上且具有宽度为250μm以下的框形状。One aspect of the present invention relates to a packaging cover component that is bonded to a packaging substrate, comprising: a glass component having a bonding portion configured as a planar frame and a light-transmitting portion disposed inside the bonding portion; one or more metallization layers formed in a frame shape on the bonding portion of the glass component; and one or more Au-Sn layers disposed on the metallization layers and having a frame shape with a width of 250 μm or less.

Au-Sn层的线膨胀系数和玻璃部件的线膨胀系数不同。通过回流焊形成Au-Sn层时,冷却时的Au-Sn层的收缩率大于玻璃部件的收缩率。由此,Au-Sn层的冷却时的收缩引起的应力作用于玻璃部件,导致Au-Sn层从玻璃部件剥落,或玻璃部件的一部分被剥离。The coefficient of linear expansion of the Au-Sn layer differs from that of the glass component. When the Au-Sn layer is formed by reflow soldering, the shrinkage rate of the Au-Sn layer during cooling is greater than that of the glass component. Consequently, the stress caused by the shrinkage of the Au-Sn layer during cooling acts on the glass component, leading to the Au-Sn layer peeling off from the glass component, or a portion of the glass component being detached.

相对于此,Au-Sn层的宽度为250μm以下,因此Au-Sn层的收缩引起的相对于玻璃部件的应力较小,能够抑制Au-Sn层的收缩引起的玻璃部件的剥离及破损。In contrast, the width of the Au-Sn layer is less than 250 μm. Therefore, the stress caused by the shrinkage of the Au-Sn layer relative to the glass component is relatively small, which can suppress the peeling and breakage of the glass component caused by the shrinkage of the Au-Sn layer.

作为本发明的封装用盖部件的优选方式,可以为如下,即,一层以上的所述Au-Sn层的所述框形状具有一个以上的角部,所述角部的最大宽度小于所述Au-Sn层的除了所述角部以外的部位的所述框形状的所述宽度。As a preferred embodiment of the cover component for packaging according to the present invention, it can be as follows: the frame shape of one or more Au-Sn layers has one or more corners, and the maximum width of the corners is less than the width of the frame shape of the Au-Sn layer excluding the corners.

角部的最大宽度表示与框形状的周向交叉的方向的最大尺寸。上述方式中,角部的最大宽度小于除了角部以外的部位的宽度,因此能够可靠地减小上述角部中的玻璃部件中的应力。The maximum width of the corner represents the maximum dimension in the direction intersecting the circumferential shape of the frame. In the above manner, the maximum width of the corner is smaller than the width of the parts other than the corner, thus reliably reducing the stress in the glass components at the corner.

作为本发明的封装用盖部件的优选方式,可以为如下,即,所述角部被倒角。As a preferred embodiment of the cover component for packaging according to the present invention, the corners are chamfered.

例如,Au-Sn层的框形状为矩形时,两条直线部在角部以90°相交,4个角部中的最大宽度大于角部以外的部分的宽度,Au-Sn层的冷却时的收缩引起的应力容易集中。相对于此,通过角部被倒角而角部的最大宽度小于除了角部以外的部位的宽度,能够更加减小相对于玻璃部件的应力。For example, when the frame shape of the Au-Sn layer is rectangular, the two straight sections intersect at 90° at the corners, and the maximum width of the four corners is greater than the width of the parts other than the corners. This makes it easy for stress caused by the shrinkage of the Au-Sn layer during cooling to concentrate. In contrast, by chamfering the corners so that the maximum width of the corners is smaller than the width of the parts other than the corners, the stress relative to the glass component can be further reduced.

作为本发明的封装用盖部件的优选方式,可以为如下,即,一层以上的所述Au-Sn层具有第一Au-Sn层及第二Au-Sn层,所述第二Au-Sn层在所述第一Au-Sn层的内侧隔开间隙而设置。As a preferred embodiment of the encapsulation cover component of the present invention, it can be as follows: one or more Au-Sn layers have a first Au-Sn layer and a second Au-Sn layer, wherein the second Au-Sn layer is disposed with a gap separating it from the inner side of the first Au-Sn layer.

上述方式中,Au-Sn层具有第一Au-Sn层及第二Au-Sn层,因此能够提高封装用盖部件接合于封装基板时的接合强度。而且,在第一Au-Sn层的内侧隔开间隙而设置第二Au-Sn层,第一Au-Sn层的宽度及第二Au-Sn层的宽度均为250μm以下,因此Au-Sn层的收缩引起的玻璃部件中的应力较小,能够抑制Au-Sn层从玻璃部件剥离或封装用盖部件的破损。In the above-described manner, the Au-Sn layer comprises a first Au-Sn layer and a second Au-Sn layer, thereby improving the bonding strength when the cover component of the encapsulation is bonded to the encapsulation substrate. Furthermore, the second Au-Sn layer is disposed with a gap separating it from the inner side of the first Au-Sn layer. Since the widths of both the first and second Au-Sn layers are 250 μm or less, the stress in the glass component caused by the shrinkage of the Au-Sn layer is relatively small, thus suppressing the peeling of the Au-Sn layer from the glass component or damage to the cover component of the encapsulation.

作为本发明的封装用盖部件的优选方式,所述玻璃部件的厚度可以是50μm以上且3000μm以下。As a preferred embodiment of the cover component for packaging according to the present invention, the thickness of the glass component may be 50 μm or more and 3000 μm or less.

所述Au-Sn层的所述宽度可以是50μm以上。The width of the Au-Sn layer can be 50 μm or more.

所述Au-Sn层的所述宽度可以是230μm以下。The width of the Au-Sn layer can be less than 230 μm.

所述角部的所述最大宽度可以是30μm以上且130μm以下。The maximum width of the corner can be greater than 30 μm and less than 130 μm.

所述玻璃部件可以是平板状。The glass component can be flat.

所述玻璃部件可以是箱状。The glass component can be box-shaped.

本发明的一方式所涉及的封装体具备至少一个以上的封装基板及本发明的一方式所涉及的所述封装用盖部件,所述封装用盖部件和所述封装基板通过接合层接合,所述接合层通过将所述Au-Sn层熔融并固化而成。The package according to one aspect of the present invention includes at least one packaging substrate and the packaging cover member according to one aspect of the present invention, wherein the packaging cover member and the packaging substrate are joined by a bonding layer, which is formed by melting and solidifying the Au-Sn layer.

本发明的一方式所涉及的封装体中,封装基板和封装用盖部件可靠地被接合,且能够抑制Au-Sn层的收缩引起的应力所导致的封装基板的剥离及破损。In one aspect of the present invention, the encapsulation substrate and the encapsulation cover component are reliably joined, and the peeling and breakage of the encapsulation substrate caused by the stress caused by the shrinkage of the Au-Sn layer can be suppressed.

本发明的一方式中,能够抑制形成于玻璃部件上的Au-Sn层的剥离及封装用盖部件的破损。In one aspect of the present invention, peeling of the Au-Sn layer formed on the glass component and breakage of the encapsulation cover component can be suppressed.

附图说明Attached Figure Description

图1是表示构成第一实施方式所涉及的封装体的封装用盖部件及封装基板的立体图。Figure 1 is a perspective view showing the encapsulation cover component and the encapsulation substrate constituting the encapsulation body according to the first embodiment.

图2是表示第一实施方式的封装用盖部件中与封装基板接合的面的俯视图。Figure 2 is a top view showing the surface of the cover component for packaging that is joined to the packaging substrate in the first embodiment.

图3是沿着图2所示的A1-A1线的封装用盖部件的向视剖视图。Figure 3 is a cross-sectional view of the cover component for packaging along line A1-A1 shown in Figure 2.

图4是表示第二实施方式的封装用盖部件中与封装基板接合的面的俯视图。Figure 4 is a top view showing the surface of the cover component for packaging that is joined to the packaging substrate in the second embodiment.

图5是表示第三实施方式的封装用盖部件中与封装基板接合的面的俯视图。Figure 5 is a top view showing the surface of the cover component for packaging that is joined to the packaging substrate in the third embodiment.

图6是表示第四实施方式的封装用盖部件中与封装基板接合的面的俯视图。Figure 6 is a top view showing the surface of the cover component for packaging that is joined to the packaging substrate in the fourth embodiment.

图7是表示第五实施方式的封装用盖部件中与封装基板接合的面的俯视图。Figure 7 is a top view showing the surface of the cover component for packaging that is joined to the packaging substrate in the fifth embodiment.

图8是表示第六实施方式的封装用盖部件中与封装基板接合的面的俯视图。Figure 8 is a top view showing the surface of the cover component for packaging that is joined to the packaging substrate in the sixth embodiment.

图9是表示第一实施方式所涉及的封装体的剖视图。Figure 9 is a cross-sectional view of the package according to the first embodiment.

图10是表示第七实施方式所涉及的封装体的剖视图。Figure 10 is a cross-sectional view showing the package according to the seventh embodiment.

图11是表示第八实施方式的封装用盖部件中与封装基板接合的面的俯视图。Figure 11 is a top view showing the surface of the cover member for packaging that is joined to the packaging substrate in the eighth embodiment.

具体实施方式Detailed Implementation

以下,利用附图对本发明所涉及的封装用盖部件及封装体的各实施方式进行说明。图1是表示本实施方式的封装基板2及封装用盖部件3的立体图。图2是封装用盖部件3的俯视图。图3是沿着图2的A1-A1线的封装用盖部件3的向视剖视图。图9是接合封装基板2和封装用盖部件3而成的封装体1的剖视图。Hereinafter, various embodiments of the encapsulation cover member and encapsulation body according to the present invention will be described with reference to the accompanying drawings. FIG1 is a perspective view showing the encapsulation substrate 2 and the encapsulation cover member 3 of this embodiment. FIG2 is a top view of the encapsulation cover member 3. FIG3 is a cross-sectional view of the encapsulation cover member 3 along line A1-A1 in FIG2. FIG9 is a cross-sectional view of the encapsulation body 1 formed by joining the encapsulation substrate 2 and the encapsulation cover member 3.

[封装体的概略结构][Simple Overview of the Package Structure]

如图1及图9所示,封装体1具备:封装基板2,具有上部开口的凹部21;及平板状的封装用盖部件3,接合于封装基板2而堵塞凹部21。在封装体1内容纳LD(激光二极管,LaserDiode)或LED(发光二极管,Light Emitting Diode)等发光元件等(未图示)。As shown in Figures 1 and 9, the package 1 includes: a package substrate 2 with a recess 21 having an upper opening; and a flat package cover member 3, which is joined to the package substrate 2 to block the recess 21. The package 1 contains light-emitting elements such as LD (Laser Diode) or LED (Light Emitting Diode) (not shown).

[封装基板的结构][Structure of the packaging substrate]

如图1及图9所示,封装基板2具有上部开口的凹部21及设置于凹部21的周围的接合面22。例如,封装基板2由AlN(氮化铝)等形成为矩形箱状。凹部21通过封装用盖部件3接合于接合面22而被堵塞,形成容纳发光元件等的空间。As shown in Figures 1 and 9, the encapsulation substrate 2 has a recess 21 with an upper opening and a mating surface 22 disposed around the recess 21. For example, the encapsulation substrate 2 is formed into a rectangular box shape from AlN (aluminum nitride) or the like. The recess 21 is blocked by the encapsulation cover member 3, which is joined to the mating surface 22, forming a space for accommodating light-emitting elements, etc.

[封装用盖部件的结构][Structure of the cover component for packaging]

如图1至图3所示,封装用盖部件3具有:矩形板状的玻璃部件30,具有设置成平面框状的接合部33及设置于接合部33的内侧的光透射部34;金属化层4,以框状形成于接合部33;及框状的Au-Sn层5,形成于金属化层4上。As shown in Figures 1 to 3, the encapsulation cover component 3 has: a rectangular plate-shaped glass component 30, having a joint portion 33 configured as a planar frame and a light-transmitting portion 34 disposed inside the joint portion 33; a metallization layer 4 formed in a frame shape on the joint portion 33; and a frame-shaped Au-Sn layer 5 formed on the metallization layer 4.

接合部33还被称为包围包括玻璃部件30的大致中央部的光透射部34的周围的框线。通过接合部33划定光透射部34的轮廓和区域。金属化层4及Au-Sn层5也被称为包围光透射部34的周围的框线。接合部33、金属化层4及Au-Sn层5还被称为具有框形状。The joint 33 is also referred to as the frame line surrounding the light-transmitting portion 34, which includes the glass component 30 at approximately the center. The joint 33 defines the outline and area of the light-transmitting portion 34. The metallization layer 4 and the Au-Sn layer 5 are also referred to as the frame line surrounding the light-transmitting portion 34. The joint 33, the metallization layer 4, and the Au-Sn layer 5 are also referred to as having a frame shape.

玻璃部件30具有成为封装体1的顶面的上表面31、及包含接合于封装基板2的接合面22的接合部33的下表面32。例如,玻璃部件30利用硼硅酸玻璃、石英玻璃等,形成为边长为2mm~30mm、厚度为50μm~3000μm的矩形板状。The glass component 30 has an upper surface 31 that forms the top surface of the package 1 and a lower surface 32 that includes a joint portion 33 that is bonded to the joint surface 22 of the package substrate 2. For example, the glass component 30 is formed into a rectangular plate shape with a side length of 2 mm to 30 mm and a thickness of 50 μm to 3000 μm using borosilicate glass, quartz glass, etc.

如图1至图3所示,在下表面32的接合部33形成有由Au、Ti、Ni等构成的矩形框状的金属化层4。在金属化层4上形成有与金属化层4相同的矩形框形状的Au-Sn层5。As shown in Figures 1 to 3, a rectangular frame-shaped metallization layer 4 composed of Au, Ti, Ni, etc., is formed at the joint 33 on the lower surface 32. An Au-Sn layer 5 with the same rectangular frame shape as the metallization layer 4 is formed on the metallization layer 4.

金属化层4大于封装基板2的凹部21,形成为包围凹部21而与接合面22抵接。Au-Sn层5的宽度与金属化层4的宽度相同,或比金属化层4的宽度窄,设定为250μm以下。The metallization layer 4 is larger than the recess 21 of the packaging substrate 2, and is formed to surround the recess 21 and abut against the bonding surface 22. The width of the Au-Sn layer 5 is the same as or narrower than the width of the metallization layer 4, and is set to 250 μm or less.

即,被金属化层4的框(框线)包围的区域大于封装基板2的凹部21的上部的开口区域。Au-Sn层5的框(框线)的线宽与金属化层4的框(框线)的线宽相同,或比金属化层4的框(框线)的线宽窄。在本实施方式中,Au-Sn层5的线宽设定为250μm以下。That is, the area surrounded by the frame (frame line) of the metallization layer 4 is larger than the opening area at the top of the recess 21 of the packaging substrate 2. The linewidth of the frame (frame line) of the Au-Sn layer 5 is the same as or narrower than the linewidth of the frame (frame line) of the metallization layer 4. In this embodiment, the linewidth of the Au-Sn layer 5 is set to 250 μm or less.

具体而言,如图2所示,在Au-Sn层5中,矩形的两条边在角部51以90°相交,4个角部51中的最大宽度(最大线宽)L2(Au-Sn层5的轮廓的外侧的两条边的交点与内侧的两条边的交点之间的距离,即,沿框形状的周向交叉的方向的最大尺寸)大于除了4个角部51以外的部位的宽度(线宽)L1。Specifically, as shown in Figure 2, in the Au-Sn layer 5, the two sides of the rectangle intersect at 90° at the corners 51. The maximum width (maximum line width) L2 (the distance between the intersection of the two outer sides and the two inner sides of the outline of the Au-Sn layer 5, i.e., the maximum dimension in the direction of circumferential intersection along the frame shape) of the four corners 51 is greater than the width (line width) L1 of the parts other than the four corners 51.

然而,宽度L1及最大宽度L2均为250μm以下。宽度L1及最大宽度L2超过250μm时,在使Au-Sn层5熔融的回流焊之后的冷却时,Au-Sn层5与玻璃部件的线膨胀系数之差导致的应力变大,导致Au-Sn层5从玻璃部件剥离或玻璃部件破损。However, both the width L1 and the maximum width L2 are less than 250 μm. When the width L1 and the maximum width L2 exceed 250 μm, the stress caused by the difference in the coefficients of linear expansion between the Au-Sn layer 5 and the glass component increases during cooling after reflow soldering when the Au-Sn layer 5 is melted, leading to the Au-Sn layer 5 peeling off from the glass component or the glass component breaking.

并且,宽度L1及最大宽度L2优选为50μm以上。此时,在接合封装用盖部件3和封装基板2而成的封装体1中,封装用盖部件3和封装基板2的接合变得牢固,因此封装用盖部件3不会从封装基板2脱落。Furthermore, the width L1 and the maximum width L2 are preferably 50 μm or more. At this time, in the package 1 formed by joining the encapsulation cover member 3 and the encapsulation substrate 2, the joining of the encapsulation cover member 3 and the encapsulation substrate 2 becomes firm, so the encapsulation cover member 3 will not fall off the encapsulation substrate 2.

更优选如下,即,Au-Sn层5的除了角部51以外的部位(直线部)的宽度L1可以设定为50μm以上且230μm以下,4个角部51的最大宽度L2可以设定为70μm以上且250μm以下。More preferably, the width L1 of the Au-Sn layer 5, excluding the corners 51 (straight sections), can be set to 50 μm or more and 230 μm or less, and the maximum width L2 of the four corners 51 can be set to 70 μm or more and 250 μm or less.

Au-Sn层5的高度(厚度)例如可以设定为1μm以上且100μm以下。The height (thickness) of the Au-Sn layer 5 can be set to, for example, above 1 μm and below 100 μm.

在以上说明的封装基板2的凹部21内容纳发光元件。接着,使封装用盖部件3的下表面32的Au-Sn层5抵接于封装基板2的接合面22上。在Au-Sn层5抵接于接合面22的状态下,对封装基板2及封装用盖部件3进行回流焊(加热)。由此,形成由Au-Sn层5熔融而成的Au-Sn焊料(接合层6)。通过该Au-Sn焊料(接合层6)接合封装基板2和封装用盖部件3,如图9所示那样形成封装体1。The light-emitting element is housed in the recess 21 of the encapsulation substrate 2 described above. Next, the Au-Sn layer 5 of the lower surface 32 of the encapsulation cover member 3 is brought into contact with the bonding surface 22 of the encapsulation substrate 2. With the Au-Sn layer 5 in contact with the bonding surface 22, the encapsulation substrate 2 and the encapsulation cover member 3 are reflow soldered (heated). As a result, Au-Sn solder (bonding layer 6) formed by melting the Au-Sn layer 5 is formed. The encapsulation substrate 2 and the encapsulation cover member 3 are bonded together by the Au-Sn solder (bonding layer 6), and the encapsulation body 1 is formed as shown in FIG9.

[封装用盖部件的制造方法][Manufacturing method for the cover component for packaging]

例如,按如以下那样制造封装用盖部件3。在1张玻璃部件30(在本实施方式中,为20mm×20mm大小的板材)的表面,通过溅射或镀敷等形成由Au、Ti、Ni等构成的多个金属化层4(例如,形成25个外形为长宽3mm的正方形框)。接着,以在各金属化层4上形成矩形框(例如,形成25个外形为长宽3mm的正方形框)的方式涂布Au-Sn浆料。For example, the encapsulation cover component 3 is manufactured as follows. Multiple metallization layers 4 composed of Au, Ti, Ni, etc., are formed on the surface of a glass component 30 (in this embodiment, a 20mm x 20mm sheet) by sputtering or plating (e.g., forming 25 square frames with dimensions of 3mm x 3mm). Next, Au-Sn paste is applied to each metallization layer 4 in such a way that rectangular frames (e.g., forming 25 square frames with dimensions of 3mm x 3mm) are formed on each metallization layer 4.

即,在玻璃部件30的表面形成具有矩形(正方形)的框形状的多个金属化层4。接着,在各金属化层4上形成具有矩形(正方形)的框形状的Au-Sn层。Au-Sn层通过涂布Au-Sn浆料来形成。That is, multiple metallization layers 4 with rectangular (square) frame shapes are formed on the surface of the glass component 30. Next, an Au-Sn layer with a rectangular (square) frame shape is formed on each metallization layer 4. The Au-Sn layer is formed by coating Au-Sn paste.

金属化层4优选通过Au镀敷形成。金属化层4形成为与Au-Sn层5相同的矩形框状。The metallization layer 4 is preferably formed by Au plating. The metallization layer 4 is formed in the same rectangular frame shape as the Au-Sn layer 5.

形成Au-Sn层5的Au-Sn浆料例如为如下浆料,即,将Au-Sn浆料设为100质量%时,以助熔剂的比例成为10质量%以上且90质量%以下的方式混合Au-Sn合金粉末和助熔剂而成。所述Au-Sn合金粉末例如以21质量%以上且23质量%以下的量含有Sn,剩余部分为Au及不可避免的杂质。作为助熔剂,并无特别限定,能够使用通常的焊料用助熔剂。例如,能够使用RA类型、RMA类型、无卤素类型的助熔剂、MSN类型、AS1类型、AS2类型等。The Au-Sn slurry forming the Au-Sn layer 5 is, for example, a slurry in which Au-Sn alloy powder and flux are mixed in a manner where the Au-Sn slurry is set to 100% by mass. The Au-Sn alloy powder contains, for example, Sn in an amount of 21% by mass to 23% by mass, with the remainder being Au and unavoidable impurities. There are no particular limitations on the flux used; conventional solder fluxes can be used. For example, RA type, RMA type, halogen-free type fluxes, MSN type, AS1 type, AS2 type, etc., can be used.

在金属化层4上,以成为宽度为50μm以上且250μm以下、厚度为1μm以上且100μm以下的涂膜的方式,印刷涂布Au-Sn浆料。另外,Au-Sn浆料也可以通过点胶机等喷出供给来涂布。Au-Sn paste is printed onto the metallization layer 4 to form a coating with a width of 50 μm or more and 250 μm or less, and a thickness of 1 μm or more and 100 μm or less. Alternatively, the Au-Sn paste can also be applied by spraying from a dispensing machine or similar means.

接着,对印刷涂布有Au-Sn浆料的玻璃部件30进行加热(回流焊)。在该回流焊工序中,例如在N2气氛下等非氧化性气氛下对Au-Sn浆料的涂膜进行加热。作为加热温度,设为280℃~350℃的范围内即可,优选设为280℃~330℃的范围内,更优选设为280℃~300℃的范围内。关于加热时间,在加热温度下保持10秒~120秒的范围内即可。加热时间优选设为20秒~90秒的范围内,更优选设为30秒至60秒的范围内。作为适当条件的一例,是在300℃下加热1分钟的条件。Next, the glass component 30 coated with Au-Sn paste is heated (reflow soldering). In this reflow soldering process, the Au-Sn paste coating is heated in a non-oxidizing atmosphere, such as N₂ . The heating temperature is preferably set within the range of 280°C to 350°C, more preferably within the range of 280°C to 330°C, and even more preferably within the range of 280°C to 300°C. The heating time is preferably maintained at the heating temperature for 10 to 120 seconds. The heating time is preferably set within the range of 20 to 90 seconds, and even more preferably within the range of 30 to 60 seconds. As an example of suitable conditions, heating at 300°C for 1 minute is preferred.

由此,Au-Sn浆料熔融。所熔融的Au-Sn停留在金属化层4上,并在该状态下被冷却,由此形成与金属化层4相同宽度的Au-Sn层5。另外,所形成的Au-Sn层5包含金属化层4,因此其组成与Au-Sn浆料略有不同,由具有Sn:19wt%~23wt%、剩余部分:Au及不可避免的杂质的组成的Au-Sn合金构成。Thus, the Au-Sn slurry melts. The molten Au-Sn remains on the metallization layer 4 and is cooled in this state, thereby forming an Au-Sn layer 5 with the same width as the metallization layer 4. Furthermore, the formed Au-Sn layer 5 includes the metallization layer 4, and therefore its composition differs slightly from the Au-Sn slurry, consisting of an Au-Sn alloy having Sn: 19wt%–23wt%, the remainder being Au, and unavoidable impurities.

在此,通过回流焊形成的Au-Sn层5的线膨胀系数和玻璃部件30的线膨胀系数不同。即,冷却引起的Au-Sn层5的收缩率大于玻璃部件的收缩率。由此,若由于Au-Sn层5的冷却时的收缩而作用于玻璃部件30的应力较大,则有可能导致Au-Sn层5从玻璃部件30剥落或玻璃部件30的一部分被剥离。Here, the coefficient of linear expansion of the Au-Sn layer 5 formed by reflow soldering is different from that of the glass component 30. That is, the shrinkage rate of the Au-Sn layer 5 due to cooling is greater than that of the glass component. Therefore, if the stress acting on the glass component 30 due to the shrinkage of the Au-Sn layer 5 during cooling is large, it may cause the Au-Sn layer 5 to peel off from the glass component 30 or a part of the glass component 30 to be detached.

相对于此,在本实施方式中,Au-Sn层5的宽度为250μm以下,因此由于冷却时的Au-Sn层5的收缩而作用于玻璃部件30的应力较小。由此,抑制Au-Sn层5从玻璃部件30剥离或玻璃部件30破损。In contrast, in this embodiment, the width of the Au-Sn layer 5 is less than 250 μm, thus the stress acting on the glass component 30 due to the contraction of the Au-Sn layer 5 during cooling is relatively small. This suppresses the peeling of the Au-Sn layer 5 from the glass component 30 or the breakage of the glass component 30.

通过按每个Au-Sn层5分割如此形成有多个矩形的Au-Sn层5的玻璃部件30,成为图2~3所示的封装用盖部件3。如此制造的封装用盖部件3如上述那样接合于封装基板2,从而形成封装体1。By dividing the glass component 30, which has multiple rectangular Au-Sn layers 5, into sections for each Au-Sn layer 5, a cover component 3 for encapsulation as shown in Figures 2 and 3 is formed. The cover component 3 for encapsulation thus manufactured is bonded to the encapsulation substrate 2 as described above, thereby forming the encapsulation body 1.

通过利用这种封装用盖部件3,能够通过封装用盖部件3可靠地密封封装基板2的凹部21,且还能够抑制Au-Sn层5的收缩引起的应力所导致的封装基板2的剥离及破损。By utilizing this encapsulation cover component 3, the recess 21 of the encapsulation substrate 2 can be reliably sealed, and the peeling and breakage of the encapsulation substrate 2 caused by the stress caused by the shrinkage of the Au-Sn layer 5 can also be suppressed.

图9表示封装体1。Au-Sn层5熔融接着固化而成为接合层6。在封装体1中,通过接合层6无间隙地接合封装基板2和封装用盖部件3。Figure 9 shows the package 1. The Au-Sn layer 5 is melted and then solidified to form the bonding layer 6. In the package 1, the package substrate 2 and the package cover component 3 are bonded together without gaps through the bonding layer 6.

另外,本发明并不限定于上述实施方式,能够在不脱离本发明的要素的范围内加以各种变更。以下,对第二实施方式~第八实施方式进行说明,但对与第一实施方式相同的特征省略说明。并且,金属化层及Au-Sn层的宽度为其框(框线)或框形状的线宽。Furthermore, the present invention is not limited to the above embodiments, and various modifications can be made without departing from the elements of the present invention. Hereinafter, the second to eighth embodiments will be described, but features identical to those in the first embodiment will be omitted from the description. Furthermore, the width of the metallization layer and the Au-Sn layer is the line width of its frame (frame line) or frame shape.

图4是表示第二实施方式所涉及的封装用盖部件103的俯视图。在第二实施方式中,代替Au-Sn层5设置有Au-Sn层5A。Au-Sn层5A中,矩形框状的角部51A分别被倒角。因此,4个角部51A的最大宽度L3(构成Au-Sn层5A的框的角部中的沿周向交叉的方向的最大尺寸)小于除了4个角部51A以外的部位的宽度L1。即,Au-Sn层5A的任一部位的宽度均为250μm以下。Figure 4 is a top view showing the encapsulation cover member 103 according to the second embodiment. In the second embodiment, an Au-Sn layer 5A is provided instead of the Au-Sn layer 5. In the Au-Sn layer 5A, the rectangular frame-shaped corners 51A are chamfered. Therefore, the maximum width L3 of the four corners 51A (the maximum dimension in the circumferential direction of the corners constituting the frame of the Au-Sn layer 5A) is smaller than the width L1 of the parts other than the four corners 51A. That is, the width of any part of the Au-Sn layer 5A is 250 μm or less.

例如,在Au-Sn层5A中,除了角部51A以外的部位(直线部)的宽度L1设定为50μm以上且250μm以下,4个角部51A的最大宽度L3设定为30μm以上且130μm以下。这种形状的Au-Sn层5A也可以通过以下方法形成。For example, in the Au-Sn layer 5A, the width L1 of the portion other than the corner 51A (the straight portion) is set to be 50 μm or more and 250 μm or less, and the maximum width L3 of the four corner 51A is set to be 30 μm or more and 130 μm or less. This shape of Au-Sn layer 5A can also be formed by the following method.

也可以形成与Au-Sn层5A形状相同的角部被倒角的金属化层4,在其上同样地以角部被倒角的形状涂布Au-Sn浆料并进行回流焊,由此形成Au-Sn层5A。并且,还可以在形成为没有倒角的矩形框状的金属化层4上同样地以没有倒角的矩形框状形成Au-Sn层,接着对Au-Sn层的角部51A进行倒角来形成Au-Sn层5A。Alternatively, a metallization layer 4 with chamfered corners, identical in shape to the Au-Sn layer 5A, can be formed. Au-Sn paste is then applied to this metallization layer with chamfered corners and reflow soldered to form the Au-Sn layer 5A. Furthermore, an Au-Sn layer can also be formed on a metallization layer 4 that is formed in a rectangular frame shape without chamfers, and then the corners 51A of the Au-Sn layer are chamfered to form the Au-Sn layer 5A.

由于Au-Sn层5A的冷却时的收缩,应力容易集中在Au-Sn层5A的角部51A。在第二实施方式中,Au-Sn层5A的冷却时的收缩引起的应力容易集中的Au-Sn层5A的角部51A被倒角,因此能够更加减小相对于封装用盖部件103的应力。并且,Au-Sn层5A中的角部51A的最大宽度L3小于Au-Sn层5A的除了角部51A以外的部位的宽度L1,因此能够可靠地减小角部51A中的相对于封装用盖部件3的应力。Due to the shrinkage of the Au-Sn layer 5A during cooling, stress tends to concentrate at the corners 51A of the Au-Sn layer 5A. In the second embodiment, the corners 51A of the Au-Sn layer 5A, where stress tends to concentrate due to the shrinkage during cooling, are chamfered, thereby further reducing the stress relative to the encapsulation cover member 103. Furthermore, the maximum width L3 of the corners 51A in the Au-Sn layer 5A is smaller than the width L1 of the Au-Sn layer 5A excluding the corners 51A, thus reliably reducing the stress relative to the encapsulation cover member 3 in the corners 51A.

图5是表示第三实施方式所涉及的封装用盖部件203的俯视图。在第三实施方式中,代替Au-Sn层5设置有Au-Sn层5B。在Au-Sn层5B中,矩形框状的4个角部51B为内侧被切成圆形状的形状。因此,4个角部51B的最大宽度L4小于除了4个角部51B以外的部位的宽度L1。即,Au-Sn层5B的任一部位的宽度均为250μm以下。Figure 5 is a top view showing the encapsulation cover member 203 according to the third embodiment. In the third embodiment, an Au-Sn layer 5B is provided instead of the Au-Sn layer 5. In the Au-Sn layer 5B, the four rectangular corner portions 51B are rounded on the inside. Therefore, the maximum width L4 of the four corner portions 51B is smaller than the width L1 of the portions other than the four corner portions 51B. That is, the width of any portion of the Au-Sn layer 5B is 250 μm or less.

例如,Au-Sn层5B的除了角部51B以外的部位(直线部)的宽度L1设定为50μm以上且230μm以下,4个角部51B的最大宽度L4设定为30μm以上且130μm以下。For example, the width L1 of the Au-Sn layer 5B, excluding the corners 51B (straight sections), is set to be 50 μm or more and 230 μm or less, and the maximum width L4 of the four corners 51B is set to be 30 μm or more and 130 μm or less.

这种形状的Au-Sn层5B也可以通过以下方法形成。也可以形成与Au-Sn层5B形状相同的具有缺口的金属化层4,在其上同样地以具有缺口的形状涂布Au-Sn浆料并进行回流焊,由此形成Au-Sn层5B。并且,还可以在形成为没有缺口的矩形框状的金属化层4上同样地以没有缺口的矩形框状形成Au-Sn层,接着将Au-Sn层的角部51B的内侧切成圆形状来形成Au-Sn层5B。This type of Au-Sn layer 5B can also be formed by the following methods. A metallization layer 4 with a notch, having the same shape as the Au-Sn layer 5B, can be formed. Au-Sn paste is then applied to this metallization layer with the same notch shape and reflow soldered to form the Au-Sn layer 5B. Alternatively, an Au-Sn layer can be formed on a metallization layer 4 that is formed in a rectangular frame shape without notches, and then the inner sides of the corners 51B of the Au-Sn layer are rounded to form the Au-Sn layer 5B.

图6是表示第四实施方式所涉及的封装用盖部件303的俯视图。在第四实施方式中,代替Au-Sn层5设置有Au-Sn层5C。在Au-Sn层5C中,在角部51C相交的两条边的最大宽度L5设为Au-Sn层5C的除了角部51C以外的部位(直线部)的宽度L1的大致一半的宽度。因此,在角部51C相交的两条边上,设置有宽度设为直线部的宽度L1的大致一半的区域(部位)。考虑到接合性的降低,在角部51C相交的两条边中的一条边上,宽度设为直线部的宽度L1的大致一半的区域的距离L6设定为40μm以上且125μm以下的范围内。Figure 6 is a top view showing the encapsulation cover member 303 according to the fourth embodiment. In the fourth embodiment, an Au-Sn layer 5C is provided instead of the Au-Sn layer 5. In the Au-Sn layer 5C, the maximum width L5 of the two sides intersecting at the corner 51C is set to approximately half the width L1 of the portion (straight section) of the Au-Sn layer 5C excluding the corner 51C. Therefore, on the two sides intersecting at the corner 51C, a region (part) with a width set to approximately half the width L1 of the straight section is provided. Considering the reduction in adhesion, the distance L6 of the region with a width set to approximately half the width L1 of the straight section on one of the two sides intersecting at the corner 51C is set to a range of 40 μm or more and 125 μm or less.

因此,Au-Sn层5C的4个角部51C的最大宽度L5小于Au-Sn层5C的直线部的宽度L1。即,Au-Sn层5C的任一部位的宽度均为250μm以下。Therefore, the maximum width L5 of the four corner portions 51C of the Au-Sn layer 5C is smaller than the width L1 of the straight portion of the Au-Sn layer 5C. That is, the width of any part of the Au-Sn layer 5C is less than 250 μm.

例如,在Au-Sn层5C中,直线部的宽度L1设定为50μm以上且250μm以下,4个角部51C的最大宽度L5设定为30μm以上且130μm以下。For example, in the Au-Sn layer 5C, the width L1 of the straight section is set to be 50 μm or more and 250 μm or less, and the maximum width L5 of the four corner sections 51C is set to be 30 μm or more and 130 μm or less.

图7是表示第五实施方式所涉及的封装用盖部件403的俯视图。第五实施方式中,代替Au-Sn层5,具有框状的第一Au-Sn层5D及在第一Au-Sn层5D的内侧隔开间隙而形成的框状的第二Au-Sn层5E。第一Au-Sn层5D的宽度L1和角部51中的最大宽度(最大线宽)L2、及第二Au-Sn层5E的宽度L7和角部51E中的最大宽度(最大线宽)L8设定为250μm以下。Figure 7 is a top view showing the encapsulation cover member 403 according to the fifth embodiment. In the fifth embodiment, instead of the Au-Sn layer 5, a frame-shaped first Au-Sn layer 5D and a frame-shaped second Au-Sn layer 5E formed by a gap separating the inner side of the first Au-Sn layer 5D are provided. The width L1 of the first Au-Sn layer 5D and the maximum width (maximum line width) L2 of the corner portion 51, and the width L7 of the second Au-Sn layer 5E and the maximum width (maximum line width) L8 of the corner portion 51E are set to 250 μm or less.

第一Au-Sn层5D与第一实施方式的Au-Sn层5相同。在第二Au-Sn层5E中,直线部的宽度L7设定为50μm以上且250μm以下,4个角部51E的最大宽度L8设定为70μm以上且250μm以下。第一Au-Sn层5D与第二Au-Sn层5E之间的间隙的距离L9设定为10μm以上且500μm以下。The first Au-Sn layer 5D is the same as the Au-Sn layer 5 in the first embodiment. In the second Au-Sn layer 5E, the width L7 of the straight portion is set to be 50 μm or more and 250 μm or less, and the maximum width L8 of the four corner portions 51E is set to be 70 μm or more and 250 μm or less. The distance L9 between the first Au-Sn layer 5D and the second Au-Sn layer 5E is set to be 10 μm or more and 500 μm or less.

通过将该间隙的距离L9设为上述范围内,在分别制造Au-Sn层5D、5E时,能够抑制由于所熔融的Au-Sn的收缩而Au-Sn层5D、5E从封装用盖部件403剥离的情况等。在Au-Sn层5D、5E形成为双重的第五实施方式中,与第一~第四实施方式的封装用盖部件相比,能够扩大基于Au-Sn层的接合范围,因此能够提高通过封装用盖部件403密封封装基板2时的接合强度。By setting the distance L9 of the gap within the aforementioned range, when manufacturing the Au-Sn layers 5D and 5E respectively, it is possible to suppress situations where the Au-Sn layers 5D and 5E peel off from the encapsulation cover member 403 due to the shrinkage of the molten Au-Sn. In the fifth embodiment where the Au-Sn layers 5D and 5E are formed in a double configuration, compared to the encapsulation cover member of the first to fourth embodiments, the bonding range based on the Au-Sn layers can be expanded, thereby improving the bonding strength when the encapsulation cover member 403 seals the encapsulation substrate 2.

在上述各实施方式中,将各Au-Sn层形成为矩形框状,但并不限于此。例如,框状的Au-Sn层可以是三角形形状或六边形形状,也可以是没有角部的圆形形状。In the above embodiments, each Au-Sn layer is formed into a rectangular frame shape, but it is not limited to this. For example, the frame-shaped Au-Sn layer can be triangular or hexagonal, or it can be a circular shape without corners.

图8是表示第六实施方式所涉及的封装用盖部件503的俯视图。在第六实施方式中,封装用盖部件503代替矩形的玻璃部件30具有圆形的玻璃部件3F,代替矩形框状的金属化层4及Au-Sn层5具有圆形框状的金属化层(未图示)及圆形框状的Au-Sn层5F。玻璃部件3F具有中央的光透射部534及包围光透射部534的圆形框状的接合部533。在玻璃部件3F的下表面32F上,Au-Sn层5F形成为在接合部533没有角部的圆形状。Au-Sn层5F的宽度L10为250μm以下。例如,Au-Sn层5F的宽度L10设定为50μm以上且250μm以下。Figure 8 is a top view showing the encapsulation cover member 503 according to the sixth embodiment. In the sixth embodiment, the encapsulation cover member 503 has a circular glass member 3F instead of a rectangular glass member 30, and has a circular frame-shaped metallization layer (not shown) and a circular frame-shaped Au-Sn layer 5F instead of a rectangular frame-shaped metallization layer 4 and an Au-Sn layer 5F. The glass member 3F has a central light-transmitting portion 534 and a circular frame-shaped joint portion 533 surrounding the light-transmitting portion 534. On the lower surface 32F of the glass member 3F, the Au-Sn layer 5F is formed into a round shape without corners in the joint portion 533. The width L10 of the Au-Sn layer 5F is 250 μm or less. For example, the width L10 of the Au-Sn layer 5F is set to be 50 μm or more and 250 μm or less.

图10是表示第七实施方式所涉及的封装体701的剖视图。在封装体701中,凹部731设置于封装用盖部件703的玻璃部件730而不是封装基板702。封装用盖部件703具有玻璃部件730、形成于玻璃部件730上的框状的金属化层704及形成于金属化层704上的框状的Au-Sn层。通过接合层706,封装用盖部件703与平板状的封装基板702接合,从而形成封装体701,所述接合层706通过将Au-Sn层熔融并固化而成。Figure 10 is a cross-sectional view showing the package 701 according to the seventh embodiment. In the package 701, a recess 731 is provided in the glass component 730 of the package cover member 703 instead of the package substrate 702. The package cover member 703 has a glass component 730, a frame-shaped metallization layer 704 formed on the glass component 730, and a frame-shaped Au-Sn layer formed on the metallization layer 704. The package cover member 703 is bonded to the flat package substrate 702 by a bonding layer 706, thereby forming the package 701. The bonding layer 706 is formed by melting and solidifying the Au-Sn layer.

图11是表示第八实施方式所涉及的封装用盖部件803的俯视图。在第八实施方式中,代替金属化层4设置有具有圆弧状角部的金属化层4G,代替Au-Sn层5设置有具有圆弧状角部51G的Au-Sn层5G。Au-Sn层5G中,包括角部51G在内的整体形成为相同(恒定)的宽度L8。Figure 11 is a top view showing the encapsulation cover member 803 according to the eighth embodiment. In the eighth embodiment, a metallization layer 4G with rounded corners is provided instead of the metallization layer 4, and an Au-Sn layer 5G with rounded corners 51G is provided instead of the Au-Sn layer 5. In the Au-Sn layer 5G, the entire Au-Sn layer, including the corners 51G, is formed with the same (constant) width L8.

实施例Example

实施例1、2及比较例1所涉及的封装用盖部件中,在板状的玻璃部件上形成了不同宽度的Au-Sn层。对这些实施例1、2及比较例1所涉及的封装用盖部件进行说明。将各例中的Au-Sn层的宽度示于表1。In the encapsulation cover components of Examples 1, 2, and Comparative Example 1, Au-Sn layers of different widths are formed on the plate-shaped glass component. These encapsulation cover components of Examples 1, 2, and Comparative Example 1 will be described. The widths of the Au-Sn layers in each example are shown in Table 1.

在实施例1、2及比较例1中,分别在20mm×20mm的矩形玻璃部件的表面实施Au镀敷来形成了25个样品的金属化层。金属化层具有与表1中记载的Au-Sn层相同尺寸的矩形框形状,厚度为0.1μm。In Examples 1, 2, and Comparative Example 1, Au plating was performed on the surface of a 20mm × 20mm rectangular glass component to form a metallization layer for 25 samples. The metallization layer had a rectangular frame shape with the same dimensions as the Au-Sn layer described in Table 1, and a thickness of 0.1μm.

在各金属化层上,以与金属化层相同的矩形框形状涂布了Au-Sn浆料。以助熔剂比率10质量%混合Au-Sn合金粉末和助熔剂而获得了Au-Sn浆料。Au-Sn合金粉末(Au-22质量%Sn合金粉末)包含22质量%的Sn,剩余部分为Au和不可避免的杂质。助熔剂使用了RA类型。Au-Sn slurry was applied to each metallization layer in the same rectangular frame shape as the metallization layer. The Au-Sn slurry was obtained by mixing Au-Sn alloy powder and flux at a flux ratio of 10% by mass. The Au-Sn alloy powder (Au-22% by mass Sn alloy powder) contained 22% by mass Sn, with the remainder being Au and unavoidable impurities. The flux used was of type RA.

详细而言,对于实施例1及比较例,为了以图11所示的第八实施方式的形状形成表1所示的各尺寸的封装体尺寸3030(长3.0mm×宽3.0mm)的Au-Sn层,利用厚度为30μm的印刷用网眼掩模,在玻璃部件上将Au-Sn浆料进行丝网印刷来涂布。In detail, for Example 1 and the comparative example, in order to form an Au-Sn layer of package size 3030 (3.0 mm long × 3.0 mm wide) of each size shown in Table 1 in the shape of the eighth embodiment shown in FIG11, Au-Sn paste was screen printed on the glass component using a printing mesh mask with a thickness of 30 μm.

对于实施例2,为了以图4所示的第二实施方式的形状形成表1所示的尺寸的封装体尺寸3030(长3.0mm×宽3.0mm)的Au-Sn层,利用厚度为30μm的印刷用网眼掩模,在玻璃部件上将Au-Sn浆料进行丝网印刷来涂布。For Example 2, in order to form an Au-Sn layer with package size 3030 (3.0 mm long × 3.0 mm wide) as shown in Table 1 in the shape of the second embodiment shown in FIG4, Au-Sn paste is screen-printed onto the glass component using a printing mesh mask with a thickness of 30 μm.

并且,对涂布有Au-Sn浆料的玻璃部件进行回流焊,从而在玻璃部件上形成了25个框状的Au-Sn层。该回流焊中,在N2气氛下以300℃对Au-Sn浆料的涂膜进行了1分钟的加热。在如此形成的各Au-Sn层中,除了角部以外的部位(直线部)的宽度及角部的最大宽度为表1所示的值,Au-Sn层的厚度为4.7μm。Furthermore, the glass component coated with Au-Sn paste was reflow soldered to form 25 frame-shaped Au-Sn layers on the glass component. During this reflow soldering, the Au-Sn paste coating was heated to 300°C for 1 minute under a N2 atmosphere. The width of each Au-Sn layer formed in this way, excluding the corners (straight sections) and the maximum width of the corners, are the values shown in Table 1. The thickness of the Au-Sn layer is 4.7 μm.

对于实施例1、2及比较例1,分别观察如此获得的各25个样品的Au-Sn层,根据Au-Sn层的内外贯通率评价了自玻璃部件的剥离。For Examples 1, 2 and Comparative Example 1, the Au-Sn layers of each of the 25 samples thus obtained were observed, and the peeling from the glass component was evaluated based on the internal and external penetration rate of the Au-Sn layers.

(剥离评价:Au-Sn层的内外贯通率)(Stripping evaluation: Internal and external continuity rate of the Au-Sn layer)

利用光学显微镜(10倍)从上表面观察了形成于金属化层上的Au-Sn层。将存在从Au-Sn层的外侧至Au-Sn层的内侧连续剥离的部分的样品判定为不合格。将不存在剥离的部分的样品判定为良好。并且,在形成于玻璃部件上的25个样品的Au-Sn层中,计算判定为良好的样品数量的比例,并将其值示于表1的项目“剥离评价(%)”。The Au-Sn layer formed on the metallization layer was observed from the top surface using an optical microscope (10x). Samples with continuous peeling from the outer side to the inner side of the Au-Sn layer were deemed unacceptable. Samples without peeling were deemed acceptable. Furthermore, the percentage of samples deemed acceptable was calculated out of the 25 Au-Sn layers formed on the glass component, and the value is shown in Table 1 under the item "Peeling Evaluation (%)".

[表1][Table 1]

Au-Sn层的宽度为250μm以下的实施例1及2的剥离评价为92%以上。尤其,在角部的宽度为100μm且与直线部相等或小于直线部的实施例2中,剥离评价为96%,剥离评价尤其高。另一方面,比较例1中,Au-Sn层的宽度较大,为425μm,因此大致一半的Au-Sn层剥离,剥离评价较低,为48%。In Examples 1 and 2, where the width of the Au-Sn layer was 250 μm or less, the peeling evaluation was 92% or higher. In particular, in Example 2, where the corner width was 100 μm and equal to or smaller than the straight portion, the peeling evaluation was 96%, which was especially high. On the other hand, in Comparative Example 1, the width of the Au-Sn layer was larger at 425 μm, resulting in approximately half of the Au-Sn layer peeling off, and a lower peeling evaluation of 48%.

因此,得知若Au-Sn层的宽度为250μm以下,则能够抑制Au-Sn层的剥离。并且,可知若角部的宽度小于直线部的宽度,能够更加抑制Au-Sn层的剥离。Therefore, it is known that if the width of the Au-Sn layer is less than 250 μm, the peeling of the Au-Sn layer can be suppressed. Furthermore, it is known that if the width of the corner is smaller than the width of the straight section, the peeling of the Au-Sn layer can be further suppressed.

产业上的可利用性Industrial availability

根据本实施方式,抑制接合于封装基板的玻璃制封装用盖部件的破损及设置于封装用盖部件的Au-Sn层的剥离。因此,本实施方式的封装用盖部件及封装体能够适当地适用于在封装体内密封有半导体激光器(LD)或LED等发光元件的半导体装置及发光装置。According to this embodiment, damage to the glass encapsulation cover member bonded to the encapsulation substrate and peeling of the Au-Sn layer disposed on the encapsulation cover member are suppressed. Therefore, the encapsulation cover member and encapsulation body of this embodiment can be appropriately applied to semiconductor devices and light-emitting devices that seal light-emitting elements such as semiconductor lasers (LDs) or LEDs within the encapsulation body.

符号说明Symbol Explanation

1、701-封装体,2、702-封装基板,6、706-接合层,21、721、731-凹部,22-接合面,3、103、203、303、403、503、703、803-封装用盖部件,4、4G、704-金属化层,5、5A、5B、5C、5F、5G-Au-Sn层,51、51A、51B、51C、51E、51G-角部,5D-第一Au-Sn层,5E-第二Au-Sn层,30、3F、730-玻璃部件,31-上表面,32、32F-下表面,33、533-接合部,34、534-光透射部。1. 701 - Package body; 2. 702 - Package substrate; 6. 706 - Bonding layer; 21. 721. 731 - Recess; 22 - Bonding surface; 3. 103. 203. 303. 403. 503. 703. 803 - Cover component for packaging; 4. 4G. 704 - Metallization layer; 5. 5A. 5B. 5C. 5F. 5G - Au-Sn layer; 51. 51A. 51B. 51C. 51E. 51G - Corner; 5D - First Au-Sn layer; 5E - Second Au-Sn layer; 30. 3F. 730 - Glass component; 31 - Upper surface; 32. 32F - Lower surface; 33. 533 - Bonding portion; 34. 534 - Light transmission portion.

Claims (10)

1.一种封装用盖部件,其特征在于,1. A cover component for packaging, characterized in that, 具备玻璃部件,所述玻璃部件具有设置成平面框状的接合部及设置于所述接合部的内侧的光透射部;The device includes a glass component, which has a joint portion configured as a planar frame and a light-transmitting portion disposed inside the joint portion. 所述接合部具有:The joint has: 一层以上的金属化层,以框状形成于所述玻璃部件的所述接合部;及One or more metallization layers are formed in a frame shape at the joint of the glass component; and 一层以上的回流焊后的状态的Au-Sn层,设置于所述金属化层上且具有宽度为250μm以下的框形状,One or more Au-Sn layers in the post-reflow soldering state are disposed on the metallization layer and have a frame shape with a width of less than 250 μm. 所述金属化层的宽度与所述Au-Sn层的宽度相同、或比所述Au-Sn层的宽度宽,The width of the metallization layer is the same as or wider than the width of the Au-Sn layer. 一层以上的所述Au-Sn层的所述框形状具有一个以上的角部,所述角部的最大宽度小于所述Au-Sn层的除了所述角部以外的部位的所述框形状的所述宽度。The frame shape of the Au-Sn layer with one or more layers has one or more corners, and the maximum width of the corners is less than the width of the frame shape of the Au-Sn layer excluding the corners. 2.根据权利要求1所述的封装用盖部件,其特征在于,2. The sealing cap component according to claim 1, characterized in that, 所述角部被倒角。The corners are chamfered. 3.根据权利要求1或2所述的封装用盖部件,其特征在于,3. The sealing cap component according to claim 1 or 2, characterized in that, 一层以上的所述Au-Sn层具有第一Au-Sn层及第二Au-Sn层,所述第二Au-Sn层在所述第一Au-Sn层的内侧隔开间隙而设置。The Au-Sn layer with one or more layers has a first Au-Sn layer and a second Au-Sn layer, wherein the second Au-Sn layer is disposed with a gap separating it from the inner side of the first Au-Sn layer. 4.根据权利要求1或2所述的封装用盖部件,其特征在于,4. The sealing cap component according to claim 1 or 2, characterized in that, 所述玻璃部件的厚度为50μm以上且3000μm以下。The thickness of the glass component is greater than 50 μm and less than 3000 μm. 5.根据权利要求1或2所述的封装用盖部件,其特征在于,5. The sealing cap component according to claim 1 or 2, characterized in that, 所述Au-Sn层的所述宽度为50μm以上。The width of the Au-Sn layer is 50 μm or more. 6.根据权利要求1或2所述的封装用盖部件,其特征在于,6. The sealing cap component according to claim 1 or 2, characterized in that, 所述Au-Sn层的所述宽度为230μm以下。The width of the Au-Sn layer is less than 230 μm. 7.根据权利要求1或2所述的封装用盖部件,其特征在于,7. The sealing cap component according to claim 1 or 2, characterized in that, 所述角部的所述最大宽度为30μm以上且130μm以下。The maximum width of the corner is more than 30 μm and less than 130 μm. 8.根据权利要求1或2所述的封装用盖部件,其特征在于,8. The sealing cap component according to claim 1 or 2, characterized in that, 所述玻璃部件为平板状。The glass component is flat. 9.根据权利要求1或2所述的封装用盖部件,其特征在于,9. The sealing cap component according to claim 1 or 2, characterized in that, 所述玻璃部件为箱状。The glass component is box-shaped. 10.一种封装体的制造方法,其特征在于,10. A method for manufacturing a package, characterized in that, 准备至少一个以上的封装基板及权利要求1至9中任一项所述的所述封装用盖部件,Prepare at least one packaging substrate and the packaging cover component as described in any one of claims 1 to 9. 将所述封装用盖部件的所述Au-Sn层抵接于所述封装基板,并将所述Au-Sn层熔融固化,由此将所述封装用盖部件和所述封装基板接合。The Au-Sn layer of the encapsulation cover component is abutted against the encapsulation substrate, and the Au-Sn layer is melted and solidified, thereby bonding the encapsulation cover component and the encapsulation substrate.
HK42022058880.0A 2018-10-15 2022-08-23 Lid component for packages and package manufacturing method HK40070310B (en)

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