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HK1238194B - Intelligent fluid filtration management system - Google Patents

Intelligent fluid filtration management system Download PDF

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Publication number
HK1238194B
HK1238194B HK17112177.1A HK17112177A HK1238194B HK 1238194 B HK1238194 B HK 1238194B HK 17112177 A HK17112177 A HK 17112177A HK 1238194 B HK1238194 B HK 1238194B
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filtration
flux
pressure
membrane
filtrate
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HK17112177.1A
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HK1238194A1 (en
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埃里克M.V.霍克
苏比尔.巴塔查尔吉
吉尔.赫维茨
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沃特普兰尼特公司
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Description

智能流体过滤管理系统Intelligent fluid filtration management system

相关申请的交叉引用CROSS-REFERENCE TO RELATED APPLICATIONS

本申请要求2014年8月12日提交的标题为“用于交叉流动膜系统的智能通量管理系统”的美国临时申请序号62/036,344和2015年4月10日提交的标题为“智能流体过滤管理系统”的美国临时申请序号62/145,793的优先权,各申请的内容以引用方式特此并入。This application claims priority to U.S. Provisional Application Serial No. 62/036,344, filed on August 12, 2014, entitled “Smart Flux Management System for Cross-Flow Membrane Systems,” and U.S. Provisional Application Serial No. 62/145,793, filed on April 10, 2015, entitled “Smart Fluid Filtration Management System,” the contents of each of which are hereby incorporated by reference.

背景技术Background Art

在实践中,过滤可宽泛地分为六个分离类别:固-气、固-液、固-固、液-液、气-液和气-气。过滤技术用来在广泛的工艺应用中分离污染物和增值材料,所述工艺应用诸如汽车和航空航天燃料和空气过滤、家庭和工业空气过滤、食品和饮料浓缩和灭菌、药物分子隔离和纯化、医疗如肾脏透析和血液氧合、饮用水处理、工业工艺用水纯化以及废物处理和环境整治。例如,过滤是最重要和广泛使用的水纯化方法,因为它能够通过尺寸排阻、优先吸附和大规模扩散来完全地和连续地过滤杂质(Howe and G.Tchobanoglous,WaterTreatment:Principles and Design,John Wiley&Sons,Inc.,Hoboken,New Jersey,第2版,2005)。几乎所有的市政和工业水和废水处理设施、大多数地下水处理设施以及大型和小型脱盐设施采用一些形式的过滤以去除有问题的物质,诸如微生物、粘土、沉积物、油和其他有机和无机溶质(Crittenden,J.,等(2012)Water Treatment:Principles andDesign,MWH,Hoboken,NJ,USA)。In practice, filtration can be broadly divided into six separation categories: solid-gas, solid-liquid, solid-solid, liquid-liquid, gas-liquid, and gas-gas. Filtration technology is used to separate pollutants and value-added materials in a wide range of process applications, such as automotive and aerospace fuel and air filtration, household and industrial air filtration, food and beverage concentration and sterilization, pharmaceutical molecule isolation and purification, medical applications such as kidney dialysis and blood oxygenation, drinking water treatment, industrial process water purification, and waste treatment and environmental remediation. For example, filtration is the most important and widely used water purification method because it can completely and continuously filter impurities through size exclusion, preferential adsorption, and large-scale diffusion (Howe and G. Tchobanoglous, Water Treatment: Principles and Design, John Wiley & Sons, Inc., Hoboken, New Jersey, 2nd edition, 2005). Virtually all municipal and industrial water and wastewater treatment facilities, most groundwater treatment facilities, and large and small desalination facilities employ some form of filtration to remove problematic materials such as microorganisms, clays, sediments, oils, and other organic and inorganic solutes (Crittenden, J., et al. (2012) Water Treatment: Principles and Design, MWH, Hoboken, NJ, USA).

通常,流体过滤构成了通过穿过分离介质的相对速率从水中分离和除去目标悬浮和溶解的固体。流体过滤系统最常见地包括以下处理技术:颗粒介质过滤(例如,砂、无烟煤、石榴石、坚果壳、非织造织物和其他非反应性废生物质)、离子交换介质过滤、吸附介质过滤(例如,颗粒活性炭或GAC、沸石、聚合物和有机粘土)、反应介质过滤(例如,绿砂和氧化过滤、生物砂过滤、生物GAC过滤)、低压膜过滤(例如,微滤和超滤),以及高压膜过滤(例如,纳滤和反渗透)。In general, fluid filtration consists of separating and removing targeted suspended and dissolved solids from water by the relative velocity of the solids passing through the separation media. Fluid filtration systems most commonly include the following treatment technologies: granular media filtration (e.g., sand, anthracite, garnet, nut shells, nonwoven fabrics, and other non-reactive waste biomass), ion exchange media filtration, adsorption media filtration (e.g., granular activated carbon or GAC, zeolites, polymers, and organoclays), reactive media filtration (e.g., greensand and oxidation filtration, biosand filtration, bioGAC filtration), low-pressure membrane filtration (e.g., microfiltration and ultrafiltration), and high-pressure membrane filtration (e.g., nanofiltration and reverse osmosis).

大多数过滤工艺受去除材料在过滤介质上或过滤介质中的累积限制。例如,当膜用来从水样品中过滤杂质时,随着膜变得被无机颗粒、有机物质和/或生物微生物堵塞或“结垢”,通量将随时间逐渐减少。膜结垢通常导致严重的通量或通过量下降,影响工艺效率和所产生的水的质量。事实上,由于对滤液质量、维持目标过滤通过量、能量效率和过滤器损坏的剧烈影响,过滤器堵塞及其减轻仍然是过滤技术的主要操作挑战。Most filtration processes are limited by the accumulation of removed material on or in the filter media. For example, when a membrane is used to filter impurities from a water sample, the flux will gradually decrease over time as the membrane becomes clogged or "fouled" with inorganic particles, organic matter, and/or biological microorganisms. Membrane fouling often results in a significant drop in flux or throughput, impacting process efficiency and the quality of the water produced. Indeed, filter clogging and its mitigation remain a major operational challenge in filtration technology due to its dramatic impact on filtrate quality, maintaining target filtration throughput, energy efficiency, and filter damage.

过滤器堵塞是在过滤期间发生的不可避免的现象,但是可在需要完全更换之前通过日常维护策略来减轻。具体地,通量维持技术可定义为通过去除过滤器上或内的可逆污物和沉积物和/或抑制它们的未来沉积来执行以恢复滤液通量的系统工艺。常见的维护策略包括各种形式的机械和化学清洗,诸如滤液反洗和原位化学清洗(例如,腐蚀剂、氧化剂/消毒剂、酸、螯合剂和表面活性剂)(Liu,C.,等(2006)Membrane Chemical Cleaning:FromArt to Science,Pall Corporation,Port Washington,NY 11050,USA)。然而,每个维护响应可通过增加系统停机时间、消耗商品化的滤液产物、消耗昂贵的清洗化学品和通过苛刻的清洗方法损坏过滤器来负面地影响工艺的效率。当前,这些过滤器维护技术使用预定的设计标准—频率、强度和持续时间来实施—并且不能实时适应给定过滤工艺内的空间和时间变化。因此,需要用于操作基于过滤的工艺的适应性工艺控制技术,以便优化维护响应并且使过滤器污染对操作能量需求和寿命循环性能的影响最小化。Filter clogging is the inevitable phenomenon that occurs during filtration, but can be alleviated by routine maintenance strategy before needing to change completely.Specifically, flux maintenance technology can be defined as by removing the reversible dirt and sediment on or in the filter and/or suppressing their future deposition to carry out the system process to recover filtrate flux.Common maintenance strategy includes various forms of mechanical and chemical cleaning, such as filtrate backwashing and original position chemical cleaning (for example, corrosive agent, oxidant/disinfectant, acid, chelating agent and surfactant) (Liu, C., etc. (2006) Membrane Chemical Cleaning:FromArt to Science, Pall Corporation, Port Washington, NY 11050, USA).However, each maintenance response can negatively affect the efficiency of process by increasing system downtime, consuming commercial filtrate product, consuming expensive cleaning chemicals and damaging filter by harsh cleaning method.Currently, these filter maintenance technologies use predetermined design standard--frequency, intensity and duration to implement--and can not adapt to the space and time variation in given filtration process in real time. Therefore, there is a need for adaptive process control techniques for operating filtration-based processes in order to optimize maintenance response and minimize the impact of filter fouling on operating energy requirements and life cycle performance.

相当大的努力与响应于过期过滤器的拆卸和更换相关,并且可产生显著的系统停机时间和成本。过滤器模块、过滤介质、离子交换树脂或颗粒活性炭的使用寿命基于用于给定处理目的的独特环境条件和水质是位置特异性的。因此,最大化工厂效率需要基于与给定应用中的模块的具体性能直接相关的信息来预测所述模块的使用寿命。在本公开中解决了这些和其他缺点。Considerable effort is associated with removing and replacing expired filters, and this can result in significant system downtime and costs. The useful life of filter modules, filter media, ion exchange resins, or granular activated carbon is location-specific, based on the unique environmental conditions and water quality used for a given treatment purpose. Maximizing plant efficiency, therefore, requires predicting the useful life of the modules based on information directly related to their specific performance in a given application. These and other shortcomings are addressed in the present disclosure.

发明概要Summary of the Invention

应理解,如所要求的,以下概述和以下具体实施方式都仅仅是示例性和说明性的而不是限制性的。提供了用于智能流体过滤管理的方法和系统。所述方法和系统可监测与过滤系统的一个或多个膜相关的一个或多个参数。一个或多个过滤器的条件可基于监测到的过滤系统的一个或多个参数来确定。所述条件可包括即将到来的过滤器熟化或过滤准备状态、检测到的过滤器熟化或过滤准备状态、即将到来的完整性破坏、检测到的完整性破坏、即将到来的渗透性损失、检测到的渗透性损失中的一个或多个、其组合等。一个或多个维护程序可基于确定的条件来执行。一个或多个维护程序可包括过滤器清洗程序、过滤器隔离程序、过滤器修理程序、过滤器更换程序和过滤器钉扎程序中的一个或多个。It should be understood that, as required, both the following overview and the following detailed description are merely exemplary and illustrative and not restrictive. Methods and systems for intelligent fluid filtration management are provided. The methods and systems can monitor one or more parameters associated with one or more membranes of a filtration system. Conditions of one or more filters can be determined based on the one or more monitored parameters of the filtration system. The conditions can include one or more of an impending filter maturation or filtration readiness, a detected filter maturation or filtration readiness, an impending integrity breach, a detected integrity breach, an impending permeability loss, a detected permeability loss, combinations thereof, and the like. One or more maintenance procedures can be performed based on the determined conditions. The one or more maintenance procedures can include one or more of a filter cleaning procedure, a filter isolation procedure, a filter repair procedure, a filter replacement procedure, and a filter pinning procedure.

在一方面,过滤管理系统可监测恒定压力操作期间的流体滤液通过量变化和恒定滤液通过量操作期间的压力变化中的至少一个。结垢机制可基于滤液通过量的变化和压力的变化中的至少一个来确定。结垢机制可通过根据一个或多个预定结垢模型执行滤液流量变化或压力变化的数学分析来确定。一个或多个预定结垢模型可包括Hermia氏模型、改进Hermia氏模型和串联阻力模型中的一个或多个。可基于所确定的结垢机制来选择清洗方案。清洗方案可包括选择清洗方法和与清洗方法相关的一个或多个参数In one aspect, the filtration management system may monitor at least one of a change in fluid filtrate throughput during constant pressure operation and a change in pressure during constant filtrate throughput operation. A fouling mechanism may be determined based on at least one of a change in filtrate throughput and a change in pressure. The fouling mechanism may be determined by performing a mathematical analysis of the filtrate flow change or pressure change according to one or more predetermined fouling models. The one or more predetermined fouling models may include one or more of a Hermia model, a modified Hermia model, and a series resistance model. A cleaning regimen may be selected based on the determined fouling mechanism. The cleaning regimen may include selecting a cleaning method and one or more parameters associated with the cleaning method.

在一方面,过滤系统可以包括压力泵,所述压力泵被配置来在流动于第一室与第二室之间的流体上施加压力。所述过滤系统还可包括流量传感器,所述流量传感器被配置来测定与流过在所述第一室与所述第二室之间沉积的膜的流体相关的至少一个参数。过滤系统可以包括压力传感器,所述压力传感器被配置来测定从第一室流到第二室的流体的压力读数。此外,过滤系统可以包括过滤管理系统,所述过滤管理系统被配置来基于压力读数引起压力泵在从第一室到第二室流过膜的流体上施加恒定压力持续第一预定时间。过滤管理系统可被进一步配置来基于至少一个参数引起压力泵使穿过膜的流体流反转持续第二预定时间。In one aspect, the filtration system can include a pressure pump configured to apply pressure to a fluid flowing between a first chamber and a second chamber. The filtration system can also include a flow sensor configured to measure at least one parameter associated with the fluid flowing through a membrane deposited between the first chamber and the second chamber. The filtration system can include a pressure sensor configured to measure a pressure reading of the fluid flowing from the first chamber to the second chamber. Additionally, the filtration system can include a filtration management system configured to cause the pressure pump to apply a constant pressure to the fluid flowing through the membrane from the first chamber to the second chamber for a first predetermined time based on the pressure reading. The filtration management system can be further configured to cause the pressure pump to reverse the flow of the fluid through the membrane for a second predetermined time based on the at least one parameter.

另外的优势将在下面的描述中部分地阐述或者可通过实践来学习。所述优势将借助在所附权利要求书中具体指出的要素和组合来实现和达到。应理解,如所要求的,前述概述和以下具体实施方式都仅仅是示例性和说明性的而不是限制性的。Additional advantages will be partially set forth in the following description or may be learned through practice. Said advantages will be realized and attained by means of the elements and combinations specifically pointed out in the appended claims. It should be understood that, as required, the foregoing summary and the following detailed description are merely exemplary and illustrative and not restrictive.

附图简述BRIEF DESCRIPTION OF THE DRAWINGS

并入本说明书并且构成本说明书的一部分的附图说明实施方案,并且连同描述一起用来解释方法和系统的原理:The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate embodiments and, together with the description, serve to explain the principles of the methods and systems:

图1示出膜工艺的恒定通过量可变进料压力操作的代表性示意图;FIG1 shows a representative schematic diagram of a membrane process with constant throughput and variable feed pressure operation;

图2示出膜工艺的恒定压力可变通量操作的代表性示意图;FIG2 shows a representative schematic diagram of a constant pressure variable flux operation of a membrane process;

图3示出过滤管理系统的代表图;FIG3 shows a representative diagram of a filtration management system;

图4示出在正向过滤之后接着反洗期间的代表性通量分布;FIG4 shows a representative flux distribution during forward filtration followed by backwash;

图5示出了说明用于在训练模式下操作过滤管理系统的示例性方法的流程图;FIG5 shows a flow chart illustrating an exemplary method for operating a filter management system in a training mode;

图6示出过滤管理系统的代表性流程图;FIG6 shows a representative flow chart of a filtration management system;

图7示出了说明用于在控制模式下操作过滤管理系统的示例性方法的流程图;FIG7 shows a flow chart illustrating an exemplary method for operating a filtration management system in a control mode;

图8示出过滤管理系统的控制模式操作的代表性流程图;FIG8 illustrates a representative flow chart of the control mode operation of the filtration management system;

图9示出了说明用于响应于通量的阶跃变化来操作过滤管理系统的示例性方法的流程图;FIG9 shows a flow chart illustrating an exemplary method for operating a filtration management system in response to a step change in flux;

图10示出了说明用于响应于通量的脉冲变化来操作过滤管理系统的示例性方法的流程图;FIG10 shows a flow chart illustrating an exemplary method for operating a filtration management system in response to pulsed changes in flux;

图11示出了过滤管理系统对持续时间tp的脉冲事件的响应的代表性示意图;FIG11 shows a representative schematic diagram of the response of the filtration management system to a pulse event of duration t p ;

图12示出了说明用于操作过滤管理系统的示例性方法的流程图;FIG12 shows a flow chart illustrating an exemplary method for operating a filtration management system;

图13示出了进行拟合测试以确定具体观察到的颗粒结垢机制的不同结垢机制和通量对时间曲线的解决方案;FIG13 shows solutions for different fouling mechanisms and flux versus time curves for which fitting tests were performed to determine the specific observed particle fouling mechanism;

图14示出了说明用于操作过滤管理系统的示例性方法的另一个流程图;FIG14 shows another flow chart illustrating an exemplary method for operating a filtration management system;

图15示出利用过滤管理系统的实验结果;FIG15 shows the experimental results using a filtration management system;

图16示出利用过滤管理系统的实验结果;并且FIG16 shows the experimental results using a filter management system; and

图17示出了可操作所公开的方法和系统的示例性计算设备。FIG. 17 illustrates an exemplary computing device on which the disclosed methods and systems may operate.

本公开的另外的优势将部分阐述在以下描述中,并且部分将从所述描述中看出或者可通过实践本公开来得知。本公开的优势将借助所附权利要求书中具体指出的元件和组合来实现并达到。应当理解,如所要求的,以上概述和以下具体实施方式都仅是示例性和解释性的,并且不限制所述方法和系统。Additional advantages of the present disclosure will be set forth in part in the following description and in part will be apparent from the description or may be learned by practicing the present disclosure. The advantages of the present disclosure will be realized and achieved by means of the elements and combinations specifically pointed out in the appended claims. It should be understood that, as required, the above summary and the following detailed description are merely exemplary and illustrative and do not limit the methods and systems.

具体实施方式DETAILED DESCRIPTION

通过参考以下方法和系统的具体实施方式和其中包括的实施例可以更容易理解本公开。The present disclosure may be understood more readily by reference to the following detailed description of methods and systems and the Examples included therein.

在公开并描述本发明的化合物、组合物、制品、系统、设备和/或方法之前,应理解,除非另外说明规定,否则它们不限于特定的合成方法,或者除非另外规定,否则它们不限于特定的试剂,因此它们当然可以改变。还应理解,本文所使用的术语仅出于描述特定方面的目的,且并不旨在加以限制。尽管在实施或测试本公开中可使用与本文所述的那些方法和材料类似或等效的任何方法和材料,但是现在描述示例性方法和材料。Before disclosing and describing the compounds, compositions, articles, systems, devices and/or methods of the present invention, it should be understood that, unless otherwise specified, they are not limited to specific synthetic methods, or unless otherwise specified, they are not limited to specific reagents, and therefore they can certainly vary. It should also be understood that the terms used herein are only for the purpose of describing specific aspects and are not intended to be limiting. Although any methods and materials similar or equivalent to those described herein can be used in implementing or testing the present disclosure, exemplary methods and materials are now described.

为了公开和描述公布在引用时所涉及的方法和/或材料,本文中提到的所有公布均以引用方式并入本文。提供本文中讨论的公布仅仅是针对它们在本申请的提交日期之前的公开。本文中的任何内容都不应解释为承认本公开内容由于先前的公开而无权早于所述公布。此外,本文中提供的公布日期可能不同于实际的公布日期,它们可能需要单独确认。In order to disclose and describe the method and/or material involved in being published when quoting, all publications mentioned herein are incorporated herein by reference.Providing the publication discussed herein is only for the disclosure before the filing date of the present application.Any content herein should not be construed as admitting that the present disclosure has no right to be earlier than described publication due to previous disclosure.In addition, the publication date provided herein may be different from the actual publication date, and they may need to be confirmed separately.

如在说明书和所述权利要求中所使用,除上下文另外明确规定之外,单数形式“一个(a)”、“一种(an)”和“所述(the)”包括复数指示物。因此,例如,对“膜”、“阀”或“传感器”的提及包括两个或更多个所述膜、阀或传感器等的混合物。As used in the specification and the appended claims, the singular forms "a," "an," and "the" include plural referents unless the context clearly dictates otherwise. Thus, for example, reference to "a membrane," "a valve," or "a sensor" includes a mixture of two or more such membranes, valves, or sensors, etc.

在本文中,范围可表达为从“约”一个具体值和/或到“约”另一个具体值。当表示这样一个范围时,另外的方面包括从一个具体值和/或至另一个具体值。类似地,当通过使用先行词“约”将值表达为近似值时,将理解的是特定值形成了另外方面。应进一步理解,该范围的每个端点相对于另一个端点以及独立于另一个端点都是有意义的。还应理解,本文公开了多个值,并且在本文中每个值除所述值本身之外也公开为“约”所述特定值。例如,如果公开了值“10”,那么也公开了“约10”。还理解的是还公开了两个具体单位之间的每个单位。例如,如果公开了10和15,则还公开了11、12、13和14。In this article, ranges can be expressed as from "about" one specific value and/or to "about" another specific value. When such a range is expressed, additional aspects include from a specific value and/or to another specific value. Similarly, when a value is expressed as an approximation by using the antecedent "about", it will be understood that the specific value forms an additional aspect. It should be further understood that each endpoint of the range is meaningful relative to the other endpoint and independently of the other endpoint. It should also be understood that multiple values are disclosed herein, and each value is also disclosed as "about" the specific value in addition to the value itself. For example, if the value "10" is disclosed, then "about 10" is also disclosed. It is also understood that every unit between two specific units is also disclosed. For example, if 10 and 15 are disclosed, then 11, 12, 13, and 14 are also disclosed.

如本文使用的术语“任选的”或“任选地”意指随后描述的事件或情况可以发生或可以不发生,并且这种描述包括其中所述事件或情况发生的实例和其中不发生的情况。As used herein, the terms "optional" or "optionally" mean that the subsequently described event or circumstance may or may not occur, and that the description includes instances where said event or circumstance occurs and instances where it does not.

如本文所用,“流体”是指在施加的剪切应力下连续变形或流动的任何物质。流体包括但不限于液体、气体和等离子体。As used herein, "fluid" refers to any substance that continuously deforms or flows under applied shear stress. Fluids include, but are not limited to, liquids, gases, and plasmas.

如本文所用,“过滤器”是指用于从流体中除去杂质的任何半透屏障或多孔设备。流体过滤器可包括但不限于膜或筛、填充介质床、流化介质床、膜生物反应器和离子交换系统。过滤分离机制包括但不限于尺寸排阻、吸附、优先溶解/扩散、电磁吸引/排斥、静电吸引/排斥、化学反应或其组合。As used herein, "filter" refers to any semipermeable barrier or porous device used to remove impurities from a fluid. Fluid filters may include, but are not limited to, membranes or sieves, packed media beds, fluidized media beds, membrane bioreactors, and ion exchange systems. Filter separation mechanisms include, but are not limited to, size exclusion, adsorption, preferential dissolution/diffusion, electromagnetic attraction/repulsion, electrostatic attraction/repulsion, chemical reaction, or a combination thereof.

如本文所用,“结垢”是指有机和无机物质在过滤器表面上或在过滤器孔和空隙空间内的沉积。结垢包括但不限于无机颗粒(例如,粘土、矿物质、金属等)、不互混的烃(例如,油和油脂)、溶解和沉淀的有机分子和细菌或藻类在本文所述的流体过滤系统过滤器上的沉积或吸附。As used herein, "fouling" refers to the deposition of organic and inorganic matter on the filter surface or within the filter pores and interstitial spaces. Fouling includes, but is not limited to, the deposition or adsorption of inorganic particles (e.g., clays, minerals, metals, etc.), immiscible hydrocarbons (e.g., oils and greases), dissolved and precipitated organic molecules, and bacteria or algae on the filters of the fluid filtration systems described herein.

如本文所用,“进料流”是指包含可过滤的溶质和/或颗粒物质的任何水性或非水性流体。As used herein, "feed stream" refers to any aqueous or non-aqueous fluid containing filterable solutes and/or particulate matter.

如本文所用,“渗透物流”是指已经通过压力驱动或重量过滤装置引导通过过滤器的进料流的任何部分。As used herein, "permeate stream" refers to any portion of a feed stream that has been directed through a filter by a pressure driven or gravimetric filtration device.

如本文所用,“通量”是指穿过过滤器的单位面积的流体流量。通量可为但不限于渗透物通量或拉伸通量。As used herein, "flux" refers to the flow rate of fluid per unit area through a filter. Flux can be, but is not limited to, permeate flux or tensile flux.

除非另外明确说明,否则决不旨在将本文阐述的任何方法解释为要求以特定顺序执行其步骤。因此,在方法权利要求项没有实际叙述其步骤所遵循的顺序或在权利要求书或描述中没有另外具体陈述各步骤将限于特定顺序的情况下,决不旨在在任何方面推断顺序。这适用于任何可能的用于解释的非表达基础,包括:相对于步骤安排或操作流程的逻辑事项;从语法组织或标点符号得到的清晰含义;以及在本说明书中描述的实施方案的数量或类型。Unless otherwise expressly stated, it is not intended that any method described herein be construed as requiring that its steps be performed in a specific order. Therefore, in the absence of a method claim actually reciting the order in which its steps are to be followed or otherwise specifically stating in the claims or description that the steps are to be limited to a specific order, no order is intended to be inferred in any respect. This applies to any possible non-express basis for interpretation, including: matters of logic with respect to arrangement of steps or operational flow; clear meaning derived from grammatical organization or punctuation; and the number or type of embodiments described in this specification.

应理解,本文公开的组合物具有某些功能。本文公开了用于执行所公开功能的某些结构需求,且应理解存在可执行与所公开结构有关的同一功能的多种结构,且这些结构通常实现相同结果。It is understood that the compositions disclosed herein have certain functions. Certain structural requirements are disclosed herein for performing the disclosed functions, and it is understood that there are multiple structures that can perform the same function related to the disclosed structures, and these structures generally achieve the same results.

A.半透膜A. Semipermeable membrane

在一方面,本公开的方法和系统涉及使用膜作为分离屏障以从溶液或液体悬浮液中除去溶质和悬浮颗粒的压力驱动的过滤工艺。在一方面,膜可以是半透膜。In one aspect, the methods and systems of the present disclosure relate to a pressure-driven filtration process using a membrane as a separation barrier to remove solutes and suspended particles from a solution or liquid suspension. In one aspect, the membrane can be a semipermeable membrane.

半透膜可用于从进料流中分离溶解的或分散的材料。分离过程可以涉及使进料溶液与半透膜的一个表面在压力下接触,以便影响溶剂相渗透通过半透膜,同时防止溶解或分散的材料的渗透。Semipermeable membranes can be used to separate dissolved or dispersed materials from a feed stream. The separation process can involve contacting the feed solution with one surface of the semipermeable membrane under pressure to affect permeation of the solvent phase through the semipermeable membrane while preventing permeation of the dissolved or dispersed material.

半透膜可以由聚合物、陶瓷或金属制成。这些聚合物、陶瓷或金属膜可包装成具有许多可能的组合(形状因素)的元件和模块,诸如平板模块、板框模块、螺旋卷绕模块、管状模块、中空纤维模块、其组合等。此外,这些半透膜都可经合成以显示宽的选择性和渗透性范围,范围基本上为微滤(MF)和超滤(UF)至纳滤(NF)和反渗透(RO)。Semipermeable membranes can be made of polymers, ceramics or metals. These polymers, ceramics or metal membranes can be packaged into elements and modules with many possible combinations (form factors), such as flat-plate modules, plate-and-frame modules, spiral-wound modules, tubular modules, hollow fiber modules, combinations thereof, and the like. In addition, these semipermeable membranes can all be synthesized to exhibit a wide range of selectivities and permeabilities, ranging essentially from microfiltration (MF) and ultrafiltration (UF) to nanofiltration (NF) and reverse osmosis (RO).

RO膜和NF膜均可以包括统称为“复合膜”的固定到多孔载体上的薄膜识别层。MF和UF膜还可以包括复合布置。多孔载体可提供物理强度,但是多孔载体可由于其多孔性而提供很小的流动阻力。另一方面,薄膜识别层可以是较少多孔的,并且可以提供溶解或分散的材料的主要分离手段。因此,薄膜识别层可以主要造成给定膜的“拒斥率”—所拒斥的特定溶解或分散的材料(例如,溶质)的百分比,以及“通量”—溶剂穿过膜的每单位面积的流速。Both RO membranes and NF membranes can include a thin film discriminating layer fixed to a porous support, collectively referred to as a "composite membrane". MF and UF membranes can also include a composite arrangement. The porous support can provide physical strength, but the porous support can provide little flow resistance due to its porosity. On the other hand, the thin film discriminating layer can be less porous and can provide the primary means of separation of dissolved or dispersed materials. Therefore, the thin film discriminating layer can be primarily responsible for the "rejection" of a given membrane - the percentage of a particular dissolved or dispersed material (e.g., solute) that is rejected, and the "flux" - the flow rate per unit area of the solvent through the membrane.

半透膜相对于其对不同离子以及有机和无机化合物的渗透度而变化。例如,“扩散膜”(例如,NF和RO)对于实际上所有离子(包括钠和氯化物)以及分子量高于约200道尔顿的不带电的溶质是相对不可渗透的。因此,RO膜广泛用于咸水或海水的脱盐以提供用于工业、商业或家庭用途的高纯化水,因为RO膜的钠和氯离子的拒斥率通常大于约90%。相反,“低压膜”(例如,MF和UF)可以是相对多孔的,并且因此用于去除胶体和颗粒物质(例如,对于MF为约0.1μm至约10μm,对于UF为0.01μm至0.1μm)。MF和UF可在用于颗粒和病原体去除的市政和工业处理应用、NF/RO预处理、化学合成纯化等中使用。Semipermeable membranes vary with respect to their permeability to different ions and organic and inorganic compounds. For example, " diffusion membranes " (e.g., NF and RO) are relatively impermeable to virtually all ions (including sodium and chloride) and uncharged solutes with a molecular weight higher than about 200 daltons. Therefore, RO membranes are widely used in the desalination of salt water or seawater to provide highly purified water for industrial, commercial or domestic use, because the rejection of the sodium and chloride ions of RO membranes is generally greater than about 90%. On the contrary, " low-pressure membranes " (e.g., MF and UF) can be relatively porous, and are therefore used to remove colloids and particulate matter (e.g., about 0.1 μm to about 10 μm for MF, 0.01 μm to 0.1 μm for UF). MF and UF can be used in municipal and industrial treatment applications, NF/RO pretreatment, chemical synthesis purification, etc. for particle and pathogen removal.

MF和UF膜可由几何形状范围内的无机或聚合材料组成。膜可被配制成各种模块构造,例如像管状构造、板框构造、螺旋卷绕构造、中空纤维构造、其组合等。聚合MF和UF膜可由各种聚合物(例如像醋酸纤维素、聚偏二氟乙烯、聚丙烯腈、聚丙烯、聚砜和聚醚砜)构成。聚合膜可相对经济地制造成具有各种形状因素,但是可限于相对于适度的pH、温度和化学耐受性的窄操作范围。由诸如氧化铝、氧化锆和二氧化钛的材料制成的陶瓷膜可用于条件要求高温下的操作或可能需要苛刻清洗化学品的应用中。MF and UF membranes can be composed of inorganic or polymeric materials in a range of geometric shapes. The membranes can be formulated into various modular configurations, such as tubular configurations, plate-and-frame configurations, spiral wound configurations, hollow fiber configurations, combinations thereof, and the like. Polymeric MF and UF membranes can be composed of various polymers (such as cellulose acetate, polyvinylidene fluoride, polyacrylonitrile, polypropylene, polysulfone, and polyethersulfone). Polymeric membranes can be manufactured relatively economically to have various form factors, but can be limited to narrow operating ranges relative to moderate pH, temperature, and chemical tolerances. Ceramic membranes made of materials such as alumina, zirconium oxide, and titanium dioxide can be used in applications where conditions require operation at high temperatures or where harsh cleaning chemicals may be required.

MF和UF膜可构造成具有对称的孔结构,以允许通过反洗或反冲洗进行的原位结垢控制。如本文所用,“反洗”或“反冲洗”是指通过施加比正向过滤跨膜压力大的压力差来反转渗透物流的流向,其可以是机械和/或渗透驱动的。反洗包括但不限于通过添加补充化学品诸如酸、腐蚀剂和/或氧化剂来使用渗透物液体、纯化水或化学增强的渗透物液体。MF and UF membranes can be constructed with a symmetrical pore structure to allow for in-situ scaling control by backwashing or backflushing. As used herein, "backwashing" or "backflushing" refers to reversing the direction of permeate flow by applying a pressure differential greater than the forward filtration transmembrane pressure, which can be mechanically and/or osmotically driven. Backwashing includes, but is not limited to, using permeate liquid, purified water, or chemically enhanced permeate liquid by adding supplemental chemicals such as acids, caustics, and/or oxidants.

在另一方面,智能流体过滤管理工艺可与MF膜、UF膜、NF膜、RO膜、正向渗透膜和没有薄膜涂层的压力延迟渗透膜的使用一起采用。此外,智能流体过滤管理工艺可与陶瓷膜和聚合膜的使用一起采用。在又一方面,半透膜以管状构造、板框构造、螺旋卷绕构造、中空纤维构造或膜生物反应器构造采用。In another aspect, the intelligent fluid filtration management process can be employed with the use of MF membranes, UF membranes, NF membranes, RO membranes, forward osmosis membranes, and pressure-retarded osmosis membranes without film coatings. Furthermore, the intelligent fluid filtration management process can be employed with the use of ceramic membranes and polymeric membranes. In yet another aspect, the semipermeable membrane is employed in a tubular configuration, a plate-and-frame configuration, a spiral-wound configuration, a hollow fiber configuration, or a membrane bioreactor configuration.

在又一方面,智能流体过滤管理工艺可与非基于膜的过滤、离子交换和活性炭系统诸如砂过滤混合介质过滤、离子交换、颗粒活性炭和临界滤筒以及螺旋卷绕过滤系统的使用一起采用,因为过滤和过滤器维持的机制反映本文描述的基于膜的方面的那些机制。In yet another aspect, the intelligent fluid filtration management process can be employed in conjunction with the use of non-membrane based filtration, ion exchange and activated carbon systems such as sand filtration mixed media filtration, ion exchange, granular activated carbon and critical cartridges and spiral wound filtration systems, as the mechanisms of filtration and filter maintenance mirror those of the membrane based aspects described herein.

B.流体过滤管理系统B. Fluid Filtration Management System

图1示出过滤管理系统105管理的示例性过滤系统100。在一方面,本公开涉及过滤系统100,过滤系统100包括被配置用于在第一室115和第二室120之间流动的流体上施加压力的压力泵110。过滤系统100还可包括流量传感器125,流量传感器125被配置来测定与流过在第一室115与第二室120之间沉积的膜130的流体相关的至少一个参数。过滤系统100还可包括压力传感器135,压力传感器135耦接到压力泵110和流量传感器125并被配置来测定从第一室115流到第二室120的流体的压力读数。此外,过滤系统100可包括与压力泵110、流量传感器125和压力传感器135连通的过滤管理系统105。滤管理系统105可被配置来基于来自压力传感器135的压力读数引起压力泵在从第一室115流到第二室120的流体上施加恒定压力持续第一预定时间。过滤管理系统105可以基于至少一个参数引起压力泵110使穿过膜130的流体流在恒定压力下反转持续第二预定时间。FIG1 illustrates an exemplary filtration system 100 managed by a filtration management system 105. In one aspect, the present disclosure relates to filtration system 100, which includes a pressure pump 110 configured to apply pressure to a fluid flowing between a first chamber 115 and a second chamber 120. Filtration system 100 may also include a flow sensor 125 configured to measure at least one parameter associated with the fluid flowing through a membrane 130 deposited between first chamber 115 and second chamber 120. Filtration system 100 may also include a pressure sensor 135 coupled to pressure pump 110 and flow sensor 125 and configured to measure a pressure reading of the fluid flowing from first chamber 115 to second chamber 120. Furthermore, filtration system 100 may include filtration management system 105 in communication with pressure pump 110, flow sensor 125, and pressure sensor 135. Filtration management system 105 may be configured to cause the pressure pump to apply a constant pressure to the fluid flowing from first chamber 115 to second chamber 120 for a first predetermined time based on the pressure reading from pressure sensor 135. Filtration management system 105 may cause pressure pump 110 to reverse the flow of fluid through membrane 130 at a constant pressure for a second predetermined time based on the at least one parameter.

压力驱动的膜过滤工艺,诸如微滤(MF)、超滤(UF)、纳滤(NF)和反渗透(RO),使用半透膜作为分离屏障以从溶液或液体悬浮液中除去溶质和悬浮颗粒。跨膜压(TMP)差的施加引起溶剂流过膜,同时保留进料中的溶质或颗粒。Pressure-driven membrane filtration processes, such as microfiltration (MF), ultrafiltration (UF), nanofiltration (NF), and reverse osmosis (RO), use a semipermeable membrane as a separation barrier to remove solutes and suspended particles from a solution or liquid suspension. The application of a transmembrane pressure (TMP) differential causes the solvent to flow through the membrane while retaining the solutes or particles in the feed.

穿过膜的清洗溶剂流速(或通量)可以受制于达西方程,所述达西方程表示通量(膜的每单位横截面积的体积流速)与施加的压差成线性比例:The cleaning solvent flow rate (or flux) through the membrane can be governed by Darcy's equation, which states that the flux (volume flow rate per unit cross-sectional area of the membrane) is linearly proportional to the applied pressure differential:

在过滤工艺期间,被膜保留的溶质和颗粒可累积在膜表面处。膜表面处的溶质浓度累积的机制可称为浓度极化。膜表面处溶质浓度的增加可导致对穿过膜的溶剂流量的额外阻力。这些阻力可减少滤液或渗透物通量。表1总结了几种阻力增加和随后的通量下降的相关机制。During the filtration process, solutes and particles retained by the membrane can accumulate at the membrane surface. The mechanism of solute concentration accumulation at the membrane surface can be called concentration polarization. The increase in solute concentration at the membrane surface can lead to additional resistance to solvent flow through the membrane. These resistances can reduce the filtrate or permeate flux. Table 1 summarizes several related mechanisms of increased resistance and subsequent flux reduction.

表1.Table 1.

通量下降机制的多样性可导致不同类型的膜元件、模块和膜过滤系统的渗透物通量的不同类型的时空变化。表1中描述的每种机制可以导致通量下降行为的不同类型的时间依赖性。随着时间的推移,更多溶质可以累积到膜上。溶质的累积可以增加穿过膜的溶剂流量的总阻力,并且随时间推移而引起滤液通量的减少。在许多类型的商业规模的切向流膜元件和模块(诸如管状模块、板框模块、螺旋卷绕模块、中空纤维模块或膜生物反应器模块)中,溶质沉积到膜上的程度也可在空间上变化。因此,连同通量的时间依赖性变化,沿着每种类型的膜模块或元件的通量也可存在局部空间变化。例如,NF和RO膜的通量损失分布可说明铅元素的有机结垢。铅元素的有机结垢的特征可在于通过滤饼形成进行的逐渐通量损失。此外,NF和RO膜的通量损失分布可说明尾部元件上的无机结垢,所述无机结垢的特征可在于通过无机沉淀和完全孔阻塞进行的剧烈和突然的通量损失。The diversity of flux decline mechanism can cause different types of spatiotemporal variation of the permeate flux of different types of membrane elements, modules and membrane filtration systems. Each mechanism described in Table 1 can cause different types of time dependence of flux decline behavior. Over time, more solutes can be accumulated on the membrane. The accumulation of solutes can increase the total resistance of the solvent flow through the membrane, and over time cause the reduction of filtrate flux. In the tangential flow membrane elements and modules (such as tubular modules, plate and frame modules, spiral wound modules, hollow fiber modules or membrane bioreactor modules) of the commercial scale of many types, the degree of solute deposition on the membrane can also vary spatially. Therefore, together with the time dependence of flux, there can also be local spatial variation in the flux of each type of membrane module or element. For example, the flux loss distribution of NF and RO membranes can illustrate the organic fouling of lead element. The feature of the organic fouling of lead element can be the gradual flux loss carried out by filter cake formation. Furthermore, the flux loss distributions of NF and RO membranes may account for inorganic fouling on the tailing element, which may be characterized by drastic and sudden flux losses through inorganic precipitation and complete pore blocking.

不同的通量下降机制,各种类型的模块和元件几何形状以及膜工艺的商业应用中的复杂进料化学和组成可能使得开发通量下降和膜结垢的一般机械模型成为挑战,所述通量下降和膜结垢可作为操作和工艺控制算法实施。膜过滤系统的工艺控制可涉及维持来自膜过滤系统的恒定体积通过量。换句话说,可在工艺期间监测来自膜模块的平均渗透物通量。如果通过量有任何下降,则控制算法可以增加驱动力(诸如施加的TMP)以将通量保持在所需设定点处。这种操作原理完全忽略了任何通量下降机制,并且用于范围为微滤至反渗透和膜类型(陶瓷膜或聚合膜)的所有类型的压力驱动膜分离工艺。Different flux decline mechanisms, various types of modules and element geometries, and the complex feed chemistry and composition in the commercial application of membrane processes may make it challenging to develop a general mechanistic model of flux decline and membrane fouling that can be implemented as an operation and process control algorithm. The process control of a membrane filtration system may involve maintaining a constant volume throughput from the membrane filtration system. In other words, the average permeate flux from the membrane modules can be monitored during the process. If there is any decline in throughput, the control algorithm can increase the driving force (such as the TMP applied) to maintain flux at the desired set point. This operating principle completely ignores any flux decline mechanism and is used for all types of pressure-driven membrane separation processes ranging from microfiltration to reverse osmosis and membrane types (ceramic membranes or polymeric membranes).

图2示意性地示出了膜元件的进料侧上的施加压力相对于时间的变化。增加施加的压力以维持通过膜元件的恒定渗透物通量。增加施加的压力以维持通过膜元件的恒定渗透物通量。施加的压力连续增加,因为在过滤期间不同的结垢机制降低了总体膜渗透性。当施加的压力达到最大阈值Pmax时,在过滤循环、tf期间,停止过滤并且启动膜清洗机制。在一些应用中,过滤循环处于固定的定时器上,而tf在连续循环之间是恒定的。在所述情况下,最大施加压力Pmax可在过滤循环之间改变。清洗机制可以根据膜元件的类型以及膜工艺而不同,并且范围可为反洗(BW)、化学增强反洗(CEB)、渗透物弛豫(PR)、压力脉冲(PP)、空气冲刷(AS)、化学脉冲(CP)、进料流反转(FFR)、原位清洗(CIP)、其组合等。在执行清洗机制之后,部分地恢复膜元件的渗透性。恢复的渗透性部分归因于在过滤循环期间膜元件的可逆结垢,并且未恢复的渗透性部分是由于不可逆的结垢。在恒定通过量操作模式中,膜元件的不可逆渗透性损失的一部分还可通过由操作期间的高压所引起的膜元件的压缩引起。此外,过滤工艺的能量需求是时间依赖性的,因为压力增加需要待增加的过滤系统的功率汲取。FIG2 schematically illustrates the change in applied pressure on the feed side of a membrane element relative to time. The applied pressure is increased to maintain a constant permeate flux through the membrane element. The applied pressure is increased to maintain a constant permeate flux through the membrane element. The applied pressure is continuously increased because different fouling mechanisms reduce overall membrane permeability during filtration. When the applied pressure reaches a maximum threshold value P max , during the filtration cycle, t f , filtration is stopped and a membrane cleaning mechanism is started. In some applications, the filtration cycle is on a fixed timer, and t f is constant between successive cycles. In such cases, the maximum applied pressure P max can be changed between filtration cycles. The cleaning mechanism can be different depending on the type of membrane element and the membrane process, and can range from backwash (BW), chemically enhanced backwash (CEB), permeate relaxation (PR), pressure pulse (PP), air scour (AS), chemical pulse (CP), feed flow reversal (FFR), cleaning in place (CIP), combinations thereof, etc. After executing the cleaning mechanism, the permeability of the membrane element is partially restored. The restored permeability is partially due to reversible fouling of the membrane elements during the filtration cycle, while the unrecovered permeability is partially due to irreversible fouling. In constant throughput mode of operation, some of the irreversible permeability loss of the membrane elements can also be caused by compression of the membrane elements due to the high pressures during operation. Furthermore, the energy requirements of the filtration process are time-dependent, as increasing pressure requires an increase in the power draw of the filtration system.

在恒定压力可变通过量操作模式中,可初始地设置TMP,并且由于各种通量下降机制,渗透物通量在过滤循环期间随时间推移而减少。两种操作模式可以是可能的:(i)固定过滤时间模式,其中正向过滤时间tf是恒定的;以及(ii)固定通量下降模式,其中在触发清洗机制之前允许通量达到最小值Jf。在清洗之后,由于不可逆的膜结垢,通量恢复通常是不完全的。In a constant pressure variable throughput mode of operation, the TMP can be initially set, and the permeate flux decreases over time during the filtration cycle due to various flux decay mechanisms. Two modes of operation may be possible: (i) a fixed filtration time mode, in which the forward filtration time tf is constant; and (ii) a fixed flux decay mode, in which the flux is allowed to reach a minimum value Jf before the cleaning mechanism is triggered. After cleaning, flux recovery is typically incomplete due to irreversible membrane fouling.

图3示出了描绘膜工艺的恒定压力可变通量操作的代表性图。纵轴描述通量。阴影区域表示不可逆的通透性损失。操作过滤系统的模式可以是恒定通过量(CT)可变跨膜压力(TMP)模式,其中压力逐渐增加以维持穿过膜的恒定渗透物通过量。此工艺控制的实施可能需要流速测量设备以记录通过量,以及用于调节进料压力的压力控制机制。这种类型的工艺控制可能具有比例积分微分(PID)控制回路的问题;即,工艺控制可以是反应性的(反馈控制机制),可以是基于恒定参数,不是基于膜通量下降的实际机制,并且不提供最佳或适应性控制。FIG3 shows a representative diagram of a constant pressure variable flux operation depicting a membrane process. The vertical axis describes flux. The shaded area represents irreversible permeability loss. The mode of operating the filtration system can be a constant throughput (CT) variable transmembrane pressure (TMP) mode, in which pressure is gradually increased to maintain a constant permeate throughput through the membrane. The implementation of this process control may require a flow rate measurement device to record throughput, and a pressure control mechanism for regulating feed pressure. This type of process control may have problems with a proportional-integral-differential (PID) control loop; that is, process control can be reactive (feedback control mechanism), can be based on constant parameters, is not based on the actual mechanism of membrane flux decline, and does not provide optimal or adaptive control.

从膜工艺观点来看,以上PID控制回路的问题在于确定通量设定点。如果通量设定点是初始通量J0,则在过滤的初始阶段期间压力可能增加太急剧,因为在这些阶段期间通量下降可能相当快。压力的这种增加可以相当剧烈地压缩膜。From a membrane process perspective, the problem with the above PID control loop is determining the flux set point. If the flux set point is the initial flux, J 0 , then the pressure may increase too sharply during the initial stages of filtration, since the flux may drop quite quickly during these stages. This increase in pressure can compress the membrane quite severely.

CT操作模式中的PID控制回路的第二个问题与进料中的污物浓度的突然激增有关。当这种激增击打膜时,通量突然下降。响应于这种突然的通量下降,PID控制回路可以尝试增加压力以使通量保持恒定。在以质量传递控制方式操作的膜工艺中,通量可能不会随着施加的压力线性地响应。因此,压力可显著增加以实现相对小的通量增强。此外,这种通量增加可以降低的通过膜的渗透性为代价,因为较高的渗透阻力迫使更多的溶质朝向膜表面或嵌入膜孔中,从而更主动地使膜结垢。在一些情况下,增加的进料压力可通过增加轴向压降来增强膜的质量传递,这引起交叉流增加。因此,响应于进料溶质浓度的突然升高而增加压力不是膜工艺中通量控制的谨慎方法。The second problem with the PID control loop in the CT operating mode is related to a sudden surge in the contaminant concentration in the feed. When this surge hits the membrane, the flux drops suddenly. In response to this sudden drop in flux, the PID control loop can try to increase the pressure to keep the flux constant. In a membrane process operated in a mass transfer controlled manner, the flux may not respond linearly with the applied pressure. Therefore, the pressure can be increased significantly to achieve a relatively small flux enhancement. In addition, this flux increase can be at the expense of reduced permeability through the membrane, because the higher permeation resistance forces more solutes toward the membrane surface or embedded in the membrane pores, thereby more actively fouling the membrane. In some cases, increased feed pressure can enhance the mass transfer of the membrane by increasing the axial pressure drop, which causes an increase in crossflow. Therefore, increasing pressure in response to a sudden increase in feed solute concentration is not a prudent approach to flux control in a membrane process.

膜元件的通量下降可以是在过滤工艺期间发生的结垢的显现。通量下降可被认为是膜结垢和性能损失的直接和明确的指标。如果可在大规模商业过滤操作期间追踪通量下降,则这种信息可适于开发用于膜工艺的控制和操作架构,所述膜工艺可智能地:a)评估过滤工艺期间结垢的主要机制;b)学习一旦观察到结垢和通量下降的临界水平就自动触发清洗机制;c)适应给定给水质量和工艺配置的最经济的操作方式;d)动态地响应给水质量的突然波动,甚至在给水污物水平的有害和灾难性激增期间关闭工艺;e)降低能耗;f)在各种模式的系统维护(如反洗和原位清洗)之间自动循环;g)延长膜的使用寿命并优化水处理的成本;其组合等。Flux decline in a membrane element can be a sign of fouling occurring during a filtration process. Flux decline can be considered a direct and unambiguous indicator of membrane fouling and performance loss. If flux decline can be tracked during large-scale commercial filtration operations, this information can be used to develop a control and operating architecture for a membrane process that can intelligently: a) assess the primary mechanism of fouling during a filtration process; b) learn to automatically trigger a cleaning mechanism once critical levels of fouling and flux decline are observed; c) adapt to the most economical operating mode for a given feedwater quality and process configuration; d) dynamically respond to sudden fluctuations in feedwater quality, even shutting down the process during harmful and catastrophic surges in feedwater contaminant levels; e) reduce energy consumption; f) automatically cycle between various modes of system maintenance (such as backwashing and in-place cleaning); g) extend the useful life of the membrane and optimize the cost of water treatment; combinations thereof, etc.

渗透物通量由膜过滤期间施加的压力(驱动力)产生。换句话说,施加的压力是原因,并且通量是影响。在恒定压力(CP)操作模式中,驱动力保持恒定,并且随后的通量变化仅仅是不同结垢阻力如何随时间推移而累积的显现,导致固定驱动力的影响下的所述通量下降。然而,在恒定通过量(CT)操作模式中,驱动力本身响应于通量的变化而改变。驱动力的变化可将工艺动力学改变为可在不同操作压力下调用附加机制的方式。结垢机制的这种改变的常见实例为一些类型的蛋白质和聚合物过滤期间高于临界TMP差异的渗透压控制和凝胶层控制之间的转变。低于阈值压力,聚合物溶液不胶化,并且浓度极化的主要机制是渗透压累积。然而,如果达到凝胶浓度的临界压力,则通量下降的主要机制变为凝胶层的生长。Permeate flux is generated by the pressure (driving force) applied during membrane filtration. In other words, the pressure applied is the cause, and flux is the effect. In the constant pressure (CP) operating mode, the driving force remains constant, and the subsequent flux change is simply a manifestation of how different fouling resistances accumulate over time, resulting in a decrease in the flux under the influence of a fixed driving force. However, in the constant throughput (CT) operating mode, the driving force itself changes in response to changes in flux. The change in driving force can change the process dynamics to a way that additional mechanisms can be called under different operating pressures. A common example of this change in fouling mechanism is the transition between osmotic pressure control and gel layer control above the critical TMP difference during filtration of some types of proteins and polymers. Below the threshold pressure, the polymer solution does not gel, and the main mechanism of concentration polarization is osmotic pressure accumulation. However, if the critical pressure of the gel concentration is reached, the main mechanism of flux decline becomes the growth of the gel layer.

恒定压力(CP)操作模式可用于依赖于通量下降作为关键信号的工艺控制架构中。恒定压力模式可以防止压力和通量之间的因果关系的改变。The constant pressure (CP) operating mode can be used in process control architectures that rely on flux drop as a key signal. Constant pressure mode prevents changes in the causal relationship between pressure and flux.

在本文中,公开了所提出的智能过滤管理系统的一个方面,所述智能过滤管理系统在恒定压力操作模式下在包括膜的过滤系统中触发反洗。本文的公开证明如何遵循通量下降模式可允许收集关于给定驱动力(TMP)和进料条件下的过滤系统行为的相关信息,如何利用所述信息来调整过滤系统的性能,响应于通过量的突然变化触发反洗或CIP,以及将CP操作模式与CT操作模式区分开来。然而,设想了其他过滤系统。Herein, one aspect of a proposed intelligent filtration management system is disclosed, which triggers backwashing in a filtration system comprising a membrane in a constant pressure operating mode. This disclosure demonstrates how following a flux decline pattern can allow for the collection of relevant information about the behavior of the filtration system under given driving force (TMP) and feed conditions, how this information can be used to adjust the performance of the filtration system, trigger backwashing or CIP in response to sudden changes in throughput, and distinguish between CP and CT operating modes. However, other filtration systems are contemplated.

假设膜过滤系统以对应于ΔP0的初始TMP的J0的初始通量开始操作。在正向过滤循环期间,通量随时间推移而变化,并且所述变化以Δt的固定时间间隔记录。在tf的正向过滤时间之后,启动反洗循环。在反洗期间,过滤循环期间收集的一部分渗透物被迫通过膜从渗透物返回到进料侧。反洗通量JBW可大于正向过滤通量,但是反洗持续时间tBW可远小于正向过滤时间。这种条件移动沉积的固体从膜的表面并将它们带到再循环进料中。这种类型的反洗可在基于陶瓷膜的过滤操作期间采用。Assume that the membrane filtration system begins operation with an initial flux of J 0 corresponding to an initial TMP of ΔP 0. During the forward filtration cycle, the flux changes over time, and the changes are recorded at fixed time intervals of Δt. After a forward filtration time of t f , a backwash cycle is initiated. During the backwash, a portion of the permeate collected during the filtration cycle is forced through the membrane from the permeate back to the feed side. The backwash flux, J BW , can be greater than the forward filtration flux, but the backwash duration, t BW , can be much less than the forward filtration time. This condition removes deposited solids from the membrane surface and carries them to the recirculating feed. This type of backwash can be employed during filtration operations based on ceramic membranes.

图4示意性地描绘了具有中间反洗的两个连续过滤循环期间的通量对时间分布。通量随时间推移而减少,并且过滤循环期间渗透物(或滤液)的累积产生为Figure 4 schematically depicts the flux versus time distribution during two consecutive filtration cycles with intermediate backwashing. The flux decreases over time, and the accumulation of permeate (or filtrate) during the filtration cycle produces

其中Am是膜面积,并且最终表达是基于在固定时间间隔(存在N个间隔)处使用梯形法则积分的通量的离散测量值。where Am is the membrane area, and the final expression is based on discrete measurements of the flux integrated at fixed time intervals (there are N intervals) using the trapezoidal rule.

在反洗过程中消耗的渗透物的总体积为The total volume of permeate consumed during the backwash process is

QBW=AmJBWtBW (2)Q BW =A m J BW t BW (2)

反洗比然后被定义为The backwash ratio is then defined as

对于具有反洗的过滤操作,期望具有尽可能小的反洗比,典型的目标为rBW<0.2。来自膜装置的净产物水通过量为For filtration operations with backwash, it is desirable to have the smallest possible backwash ratio, with a typical target of r BW < 0.2. The net product water throughput from the membrane unit is

过滤循环期间的通量下降的速率由下式给出The rate of flux decline during the filtration cycle is given by

如果流量测量设备以规则的间隔记录通量,则通量下降的速率可在每个瞬间时刻ti(瞬时下降)表示为If the flow measurement device records the flux at regular intervals, the rate of flux decline at each instant ti (instantaneous decline) can be expressed as

方程(1)和(6)分别表示相同时间依赖性渗透物通量顺序的积分和导数。Equations (1) and (6) represent the integral and derivative, respectively, of the same time-dependent permeate flux order.

可以尝试使用这些通量测量来构造比例积分微分(PID)类型控制算法,而不进一步详细审查。这种方法可能需要设定点的定义,所述设定点可为所需通量并基于给定通量测量值与设定点的偏差,将调节控制变量(通常为施加的压力),这将使通量与设定值的偏差最小化。这是以前称为恒定通过量(CT)可变压力模型的方法。Without further scrutiny, one could attempt to use these flux measurements to construct a proportional-integral-derivative (PID) type control algorithm. This approach would require the definition of a set point, which could be the desired flux, and based on the deviation of a given flux measurement from the set point, the controlled variable (typically the applied pressure) would be adjusted to minimize the flux deviation from the set point. This is an approach formerly known as the constant throughput (CT) variable pressure model.

如本文以上所述,PID控制机制遭受两个主要问题。首先,确定通量设定点。如果设定点是初始通量J0,则在过滤的初始阶段期间压力将增加太急剧,因为在这些阶段期间通量下降相当快。压力的这种增加可以相当剧烈地压缩膜。第二个担忧与进料中污物浓度的突然激增有关,引起通量突然下降。在PID过滤管理系统中,压力需要显著增加以实现相对小的通量增强。这进而可能导致由于结垢增加所引起的渗透性降低,所述结垢增加是由更高的渗透阻力迫使更多溶质朝向膜表面引起。As described above, the PID control mechanism suffers from two major problems. First, the flux set point is determined. If the set point is the initial flux J 0 , the pressure will increase too sharply during the initial stage of filtration because the flux drops quite quickly during these stages. This increase in pressure can compress the membrane quite violently. The second concern is related to the sudden surge in dirt concentration in the feed, causing a sudden drop in flux. In a PID filter management system, the pressure needs to be significantly increased to achieve a relatively small flux enhancement. This in turn may lead to a decrease in permeability caused by an increase in scaling, which is caused by forcing more solutes toward the membrane surface due to a higher permeation resistance.

1.恒定压力可变通过量操作模式1. Constant pressure variable throughput operation mode

如果考虑这两种类型的操作期间的工艺的功率消耗,恒定压力可变通过量操作模式在范围方面与恒定通过量可变压力操作模式稍微不同。给定工艺的功率消耗可与由下式给出的水马力相关If the power consumption of the process during both types of operation is considered, the constant pressure variable throughput mode of operation is slightly different in scope from the constant throughput variable pressure mode of operation. The power consumption of a given process can be related to the water horsepower given by

对于恒定压力操作,J=J(t),而对于恒定通过量操作,TMP差是时间的函数。在两种模式下操作的过滤系统的功率输出的关键差异在于,对于恒定压力操作,当过滤循环期间通量减少时,功率消耗不增加(它保持恒定或减小);而对于恒定通过量操作,功率消耗在过滤循环期间增加。在CT操作期间功率消耗的增加与附加驱动力的产生有关,来以恒定速率推动渗透物通过较低渗透性的过滤屏障。For constant pressure operation, J = J(t), while for constant throughput operation, the TMP difference is a function of time. The key difference in the power output of filtration systems operating in the two modes is that, for constant pressure operation, power consumption does not increase (it remains constant or decreases) as flux decreases during a filtration cycle; whereas, for constant throughput operation, power consumption increases during a filtration cycle. The increase in power consumption during CT operation is related to the generation of additional driving force to push permeate through the lower permeability filtration barrier at a constant rate.

在大多数商业膜元件和模块中,浓度极化、结垢和颗粒沉积的程度沿着模块的长度轴向地变化。此类变化在模块或元件的不同位置处引起不同程度的通量下降。来自模块的通过量表示沿着模块的空间平均渗透物通量乘以膜面积。模块中的局部渗透物通量根据结垢机制而变化。在大多数应用中,结垢在模块的下游位置处更严重,导致来自这些位置的较低通量。在这些模块中的许多中,采用切向流来限制结垢的程度。在一些应用中,进料流反转(FFR)可用来防止模块一端的过度不对称结垢。In most commercial membrane elements and modules, the degree of concentration polarization, scaling and particle deposition varies axially along the length of the module. Such changes cause different degrees of flux decline at different positions of the module or element. The throughput from the module represents the spatial average permeate flux along the module multiplied by the membrane area. The local permeate flux in the module varies according to the scaling mechanism. In most applications, scaling is more serious at the downstream position of the module, resulting in lower flux from these positions. In many of these modules, tangential flow is used to limit the degree of scaling. In some applications, feed flow reversal (FFR) can be used to prevent excessive asymmetric scaling at one end of the module.

不考虑商业模块中膜结垢的机制,大多数模块和元件被不对称地结垢,并且通常元件在其仅仅一部分在很大程度上变得不可逆地结垢时需要更换。膜元件的不对称结垢是切向流过滤系统的质量传递特征的结果。感兴趣的是探索如何操作采用恒定压力可变通过量和恒定通过量可变压力模式的商业规模膜元件可导致元件的不同程度的不对称结垢。Regardless of the mechanism of membrane fouling in commercial modules, most modules and elements scale asymmetrically, and typically require replacement when only a portion of the element becomes largely and irreversibly fouled. Asymmetrical fouling of membrane elements is a consequence of the mass transfer characteristics of tangential flow filtration systems. It was of interest to explore how operating commercial-scale membrane elements in constant-pressure, variable-throughput, and constant-throughput, variable-pressure modes can result in varying degrees of asymmetrical fouling of the elements.

结垢在膜的下游端启动,引起膜的这些区域中的渗透性损失。来自这些区域的滤液恢复减少。在恒定压力操作中,较低渗透增加了稳态工艺期间的体积切向流。随着交叉流速度增加,轴向摩擦损失也增加。虽然增加的交叉流对于质量传递是有益的,并且导致在一些类型的膜工艺中去除结垢层,但是较高的交叉流通常与模块中较高的轴向压降相关。这种工艺在恒定通过量操作模式期间加重,因为在膜的一部分损失渗透性时增加总驱动压力更主动地增加轴向流组分。因此,尽管在这种类型的操作中,来自模块的滤液或渗透物的产生保持恒定,但是生产主要是由于来自元件前缘处的膜的未结垢区域的渗透增加。来自这些位置的较高渗透增强了渗透阻力,并因此增强了污物在膜的这些部分上的累积。最终,当膜被阻塞但是较高的驱动压力施加在进料上时,轴向流增加,从而增加沿着模块的摩擦压降。此总体结果是当在恒定通过量可变压力模式下操作时膜工艺的操作成本较高。Fouling initiates at the downstream end of the membrane, causing permeability loss in these regions of the membrane. Filtrate recovery from these regions is reduced. In constant-pressure operation, lower permeability increases the volumetric tangential flow during the steady-state process. As crossflow velocity increases, axial friction losses also increase. While increased crossflow is beneficial for mass transfer and leads to the removal of the fouling layer in some membrane processes, higher crossflow is typically associated with higher axial pressure drop across the module. This process is exacerbated during constant-throughput operation because increasing the total driving pressure when a portion of the membrane loses permeability more actively increases the axial flow component. Therefore, while filtrate or permeate production from the module remains constant in this type of operation, production is primarily due to increased permeation from unfouled regions of the membrane at the leading edge of the element. Higher permeability from these locations increases permeation resistance and, therefore, foulant accumulation in these portions of the membrane. Ultimately, when the membrane becomes blocked but higher driving pressure is applied to the feed, axial flow increases, thereby increasing the frictional pressure drop across the module. The overall result is higher operating costs for membrane processes operating in constant-throughput, variable-pressure mode.

在另一方面,基于至少一个参数引起压力泵将恒定压力反转包括将所确定的至少一个参数与至少一个阈值进行比较。在又一方面,至少一个参数是流体流速、流体流速的变化率、持续预定义时间周期通过膜的流体体积渗透物中的一个或多个。In another aspect, causing the pressure pump to reverse the constant pressure based on at least one parameter comprises comparing the determined at least one parameter to at least one threshold value. In yet another aspect, the at least one parameter is one or more of a fluid flow rate, a rate of change of the fluid flow rate, and a volume of fluid permeate passing through the membrane for a predefined time period.

在另一方面,过滤系统还可包括计时器,所述计时器被配置用于调节施加恒定压力的时间和调节反转恒定压力的时间中的至少一个。In another aspect, the filtration system may further include a timer configured to adjust at least one of a time for applying the constant pressure and a time for reversing the constant pressure.

在另一方面,第一预定时间和第二预定时间中的一个或多个是恒定值。在又一方面,第一预定时间和第二预定时间中的一个或多个基于预定义公式来确定。In another aspect, one or more of the first predetermined time and the second predetermined time is a constant value. In yet another aspect, one or more of the first predetermined time and the second predetermined time is determined based on a predefined formula.

在另一方面,反转压力是恒定压力。On the other hand, the reverse pressure is a constant pressure.

2.压力泵2. Pressure pump

在不同方面,过滤系统包括压力泵,所述压力泵被配置来在流动于第一室与第二室之间的流体上施加压力。即使当膜拒斥杂质通过所述膜时,压力泵也提供推动流体通过所述膜所需的压力。微滤和超滤可在约3psi至约50psi的范围内操作,这显著低于纳滤和反渗透膜(约200psi至约1,200psi)。In various aspects, the filtration system includes a pressure pump configured to apply pressure to the fluid flowing between the first chamber and the second chamber. The pressure pump provides the pressure required to push the fluid through the membrane even when the membrane is rejecting impurities from passing through the membrane. Microfiltration and ultrafiltration can operate in a range of about 3 psi to about 50 psi, which is significantly lower than nanofiltration and reverse osmosis membranes (about 200 psi to about 1,200 psi).

3.流量传感器3. Flow sensor

在不同方面,过滤系统包括流量传感器,所述流量传感器被配置用于测定与流过在第一室与第二室之间沉积的膜的流体相关的至少一个参数。流体流量传感器可被设计来指示由过滤系统记录的瞬时和平均通量。时间通量测量值然后可用来计算控制工艺所需的积分和导数通量项。In various aspects, a filtration system includes a flow sensor configured to measure at least one parameter associated with a fluid flowing through a membrane deposited between a first chamber and a second chamber. The fluid flow sensor can be designed to indicate both instantaneous and average fluxes recorded by the filtration system. The time flux measurements can then be used to calculate integral and derivative flux terms required for process control.

4.压力传感器4. Pressure sensor

在不同方面,过滤系统包括压力传感器。压力传感器可被配置来测定穿过将第一室与第二室隔开的膜的流体流量的压力读数。压力传感器可以不保留待测量的流体的这种方式配置。在另一方面,压力传感器包括膜和压力感测部分,所述压力感测部分感测膜内流动的流体的压力。在又一方面,压力传感器与膜是不同的和/或隔开的。In various aspects, a filtration system includes a pressure sensor. The pressure sensor can be configured to measure the pressure of a fluid flowing through a membrane separating a first chamber from a second chamber. The pressure sensor can be configured in such a manner that the fluid to be measured is not retained. In another aspect, the pressure sensor includes a membrane and a pressure sensing portion that senses the pressure of the fluid flowing within the membrane. In yet another aspect, the pressure sensor is distinct from and/or separate from the membrane.

5.过滤管理系统5. Filtration management system

在一方面,过滤系统可包括过滤管理系统。在一方面,过滤管理系统与压力泵、流量传感器和压力传感器连通。过滤管理系统可被配置来基于压力读数引起压力泵在从第一室流到第二室的流体上施加恒定压力持续第一预定时间。此外,过滤管理系统可以基于至少一个参数引起压力泵使恒定压力反转持续第二预定时间。反转压力可引起流体的流动在反转方向上移动穿过第一室与第二室之间的膜。反转压力还可以是恒定压力。In one aspect, a filtration system may include a filtration management system. In one aspect, the filtration management system is in communication with a pressure pump, a flow sensor, and a pressure sensor. The filtration management system may be configured to cause the pressure pump to apply a constant pressure to fluid flowing from a first chamber to a second chamber for a first predetermined time based on a pressure reading. Furthermore, the filtration management system may cause the pressure pump to reverse the constant pressure for a second predetermined time based on at least one parameter. The reversed pressure may cause the fluid flow to move in a reversed direction across a membrane between the first and second chambers. The reversed pressure may also be a constant pressure.

C.用于在训练模式下操作流体过滤管理系统的方法C. Method for Operating a Fluid Filtration Management System in Training Mode

图5示出了过滤管理系统的方法500。在步骤501中,恒定压力可施加于从第一室流到第二室的流体上。在一方面,恒定压力可由压力泵施加。在一方面,膜可沉积在第一室与第二室之间,以允许流体从第一室渗透所述膜到第二室。FIG5 illustrates a method 500 for managing a filtration system. In step 501, a constant pressure may be applied to a fluid flowing from a first chamber to a second chamber. In one aspect, the constant pressure may be applied by a pressure pump. In one aspect, a membrane may be deposited between the first chamber and the second chamber to allow the fluid to permeate the membrane from the first chamber to the second chamber.

在步骤502中,可以确定与从第一室穿过膜到第二室的流体流量相关的至少一个参数。在一方面,流量传感器可以测定至少一个参数。在一方面,至少一个参数可以是流体流速、流体流速的变化率、持续预定义时间周期通过膜的流体体积渗透物、膜上形成的结垢中的一个或多个。在一方面,膜上形成的结垢可通过测量膜的电导率来确定。在另一方面,膜上形成的结垢可通过膜表面的原位目测检查来确定。In step 502, at least one parameter related to the flow of fluid from the first chamber through the membrane to the second chamber can be determined. In one aspect, a flow sensor can measure the at least one parameter. In one aspect, the at least one parameter can be one or more of the fluid flow rate, the rate of change of the fluid flow rate, the volume of fluid permeate passing through the membrane for a predefined time period, and scale formation on the membrane. In one aspect, scale formation on the membrane can be determined by measuring the conductivity of the membrane. In another aspect, scale formation on the membrane can be determined by in-situ visual inspection of the membrane surface.

在步骤503中,可基于所测定的至少一个参数与至少一个阈值的比较来反转恒定压力。在一方面,当满足阈值时,过滤管理系统可引起压力泵反转恒定压力。在一方面,反转压力可以恒定水平施加并且可基于预定义公式来确定。在一方面,反转压力可施加持续预定义时间周期。预定义时间周期可基于至少一个测量因素。测量因素可以是在每个循环中在膜上累积的结垢量。在反转压力已经施加到流体持续预定义的时间周期之后,恒定压力可在从第一室到第二室的流体流量的原始方向上重新施加。In step 503, the constant pressure may be reversed based on a comparison of the at least one measured parameter with at least one threshold value. In one aspect, when the threshold value is met, the filtration management system may cause the pressure pump to reverse the constant pressure. In one aspect, the reverse pressure may be applied at a constant level and may be determined based on a predefined formula. In one aspect, the reverse pressure may be applied for a predefined time period. The predefined time period may be based on at least one measured factor. The measured factor may be the amount of scale accumulated on the membrane during each cycle. After the reverse pressure has been applied to the fluid for the predefined time period, the constant pressure may be reapplied in the original direction of fluid flow from the first chamber to the second chamber.

通过过滤管理系统进行的智能工艺控制可涉及过滤系统对给定刺激(驱动力)的响应的一些初始学习。在膜工艺中,这可在最初的几个过滤循环期间通过在固定的TMP下操作过滤系统并观察随后的通量下降行为来容易地实现。在调试过滤系统时,给水与过滤系统的最初几次相互作用可提供给水如何使膜结垢以及过滤和反洗循环需要如何适应具体给水的优异指标。应用预设的TMP将导致过滤系统中的某些通量下降行为,所述某些通量下降行为可在触发反洗之前在预设的过滤时间内记录。Intelligent process control through a filtration management system can involve some initial learning of the filtration system's response to a given stimulus (driving force). In membrane processes, this can be readily accomplished during the first few filtration cycles by operating the filtration system at a fixed TMP and observing the subsequent flux decline behavior. When commissioning a filtration system, the first few interactions of the feedwater with the filtration system can provide excellent indicators of how the water will foul the membranes and how the filtration and backwash cycles need to be adapted to the specific feedwater. Applying a preset TMP will result in some flux decline behavior in the filtration system, which can be recorded over a preset filtration time before backwash is triggered.

考虑实施具有以下四个预设条件的过滤管理系统:初始TMP,其给出初始通量J0;正向过滤时间tfini;最大允许通量比JN/Jf;以及反洗比rBW。如果此初始预设正向过滤时间期间的通量下降产生比预设通量比大的通量比,并且在随后的反洗步骤之后通量再次完全恢复以达到初始通量J0,则预设条件保持为足以用于当前操作。然而,如果通量比在tf,ini之前达到低于预设比率JN/Jf的值,则正向过滤循环较早停止,并且新的过滤时间tf<tf,ini被选择用于下一个过滤循环。Consider implementing a filtration management system with the following four preset conditions: an initial TMP, which gives an initial flux, J 0 ; a forward filtration time, t f , ini ; a maximum permissible flux ratio, J N /J f ; and a backwash ratio, r BW . If the flux drop during this initial preset forward filtration time results in a flux ratio greater than the preset flux ratio, and after a subsequent backwash step, the flux is fully restored again to reach the initial flux, J 0 , then the preset conditions remain sufficient for the current operation. However, if the flux ratio reaches a value below the preset ratio, J N /J f , before t f, ini , the forward filtration cycle is stopped early, and a new filtration time, t f < t f, ini , is selected for the next filtration cycle.

当过滤时间缩短时,在过滤循环期间滤液的产生将较低。因此,反洗比将变得更高。如果反洗比大于预设极限,则所述方法将不太经济,因为所述方法在一个循环内产生较少量的水。为调节反洗比,存在几个选项,所述几个选项可包括修改反洗时间和反洗通量。然后可改变反洗通量并使用来自第一循环的改进参数运行由正向过滤和反洗步骤组成的第二循环。When the filtration time is shortened, the filtrate produced during the filtration cycle will be lower. Therefore, the backwash ratio will become higher. If the backwash ratio is greater than a preset limit, the process will be less economical because it produces less water within a cycle. To adjust the backwash ratio, there are several options, which may include modifying the backwash time and backwash flux. The backwash flux can then be changed and a second cycle consisting of a forward filtration and backwash step can be run using the modified parameters from the first cycle.

图6描绘了学习过程流程图。学习模块是数据获取模块和比较器,所述比较器实时测量通量并将其与预设值(或在先前的训练步骤中获取的值)进行比较。在给定过滤循环期间存储的预设值是初始通量(J0,ini,其取决于TMP设定点)、过滤时间(tf,ini)和先前过滤循环的通量比(r通量=JN/J0)。铰孔预设值是反洗参数、即反洗时间、反洗通量和反洗比。学习模块记录通量对时间的数据,并在模块内实时执行以下计算:Figure 6 depicts a flow chart of the learning process. The learning module is a data acquisition module and a comparator that measures flux in real time and compares it to preset values (or values acquired in a previous training step). The preset values stored during a given filtration cycle are the initial flux (J 0,ini , which depends on the TMP setpoint), the filtration time (tf,ini ), and the flux ratio of the previous filtration cycle (r flux = J N /J 0 ). The reaming preset values are the backwash parameters, namely, backwash time, backwash flux, and backwash ratio. The learning module records the flux versus time data and performs the following calculations in real time within the module:

1.根据方程(1)的通量的积分1. Integration of the flux according to equation (1)

2.根据方程(6)的通量的导数2. The derivative of the flux according to equation (6)

3.误差估计评估为:3. The error estimate is evaluated as:

其中Kp、Ki和Kd分别是比例、积分和微分增益。误差估计用来控制用于下一个过滤运行的过滤时间和TMP设置。应当注意,方程(7)中的各项提供了膜过滤工艺中通量下降机制的更现实的表示。比例项描绘了局部通量如何与先前循环的平均通量进行比较,积分项描绘了从当前过滤循环直到时间ti的累积产量如何与来自先前循环的总产量进行比较,并且微分项描绘了本过滤循环中的瞬时通量下降速率如何与先前过滤循环中的总通量下降速率进行比较。Where Kp , Ki , and Kd are the proportional, integral, and differential gains, respectively. The error estimate is used to control the filtration time and TMP setting for the next filtration run. It should be noted that the terms in Equation (7) provide a more realistic representation of the flux decline mechanism in a membrane filtration process. The proportional term describes how the local flux compares to the average flux of the previous cycle, the integral term describes how the cumulative yield from the current filtration cycle until time ti compares to the total yield from the previous cycle, and the differential term describes how the instantaneous flux decline rate in the current filtration cycle compares to the total flux decline rate in the previous filtration cycle.

方程(7)是用于控制过滤系统的性能的一般PID控制算法,并且可被修改来充当工艺控制的比例、积分和微分模式的任何组合。例如,将积分增益设置为零,所述工艺可以定义为PD控制器。还值得注意的是,以在每个过滤循环之后更新设定点的这种方式定义工艺控制算法以反映结垢机制的学习特征。此外,学习过程可涉及调节所应用的TMP或调节过滤时间或其组合以微调过滤循环。在许多情况下,在具有膜的过滤系统的设计期间选择初始TMP设定点,使得结垢不严重。在这方面,可以使用学习过程来增加TMP设定点。当调节TMP设定点时,考虑导数输入可能更有用,因为所施加的压力直接影响通量下降速率。更高的TMP导致更快的通量下降速率。另一方面,当调节过滤时间时,权重应该归因于所有三个误差,即瞬时通量、通量的积分(给出通过量)和通量的导数。Equation (7) is a general PID control algorithm for controlling the performance of a filtration system and can be modified to act as any combination of proportional, integral, and derivative modes of process control. For example, by setting the integral gain to zero, the process can be defined as a PD controller. It is also worth noting that the process control algorithm is defined in such a way that the set point is updated after each filtration cycle to reflect the learning characteristics of the fouling mechanism. In addition, the learning process may involve adjusting the applied TMP or adjusting the filtration time or a combination thereof to fine-tune the filtration cycle. In many cases, the initial TMP set point is selected during the design of the filtration system with the membrane so that fouling is not severe. In this regard, the learning process can be used to increase the TMP set point. When adjusting the TMP set point, it may be more useful to consider the derivative input because the applied pressure directly affects the flux drop rate. A higher TMP results in a faster flux drop rate. On the other hand, when adjusting the filtration time, weight should be attributed to all three errors, i.e., the instantaneous flux, the integral of the flux (giving the amount passed), and the derivative of the flux.

学习过程的总体目标是确定固定给水组成的通量下降动力学,从而将所有其他操作条件保持固定。经改变以调整工艺控制机制的唯一参数是所应用的TMP和过滤时间。在一些情况下,还可调节反洗通量和反洗时间。The overall goal of the learning process was to determine the flux reduction kinetics for a fixed feedwater composition, keeping all other operating conditions fixed. The only parameters that were varied to adjust the process control mechanism were the applied TMP and filtration time. In some cases, the backwash flux and backwash time were also adjusted.

D.用于在控制模式下操作流体过滤管理系统的方法D. Method for Operating a Fluid Filtration Management System in Control Mode

图7示出了根据不同方面的过滤管理系统的方法700。在步骤701中,恒定压力可施加于从第一室流到第二室的流体上持续第一预定时间。膜可沉积在第一室与第二室之间,以允许流体从第一室渗透所述膜到第二室。在一方面,第一预定义时间可以是恒定值。在一方面,第一预定义时间可以是基于预定义公式的值。FIG7 illustrates a method 700 for a filtration management system according to various aspects. In step 701, a constant pressure may be applied to a fluid flowing from a first chamber to a second chamber for a first predetermined time. A membrane may be deposited between the first chamber and the second chamber to allow the fluid to permeate the membrane from the first chamber to the second chamber. In one aspect, the first predetermined time may be a constant value. In another aspect, the first predetermined time may be a value based on a predefined formula.

在步骤702中,恒定压力可反转持续第二预定时间。在一方面,第二预定义时间可以是恒定值。在一方面,第二预定义时间可以基于预定义公式。在步骤703中,恒定压力可以重新施加持续第一预定义时间。In step 702, the constant pressure may be reversed and continued for a second predetermined time. In one aspect, the second predefined time may be a constant value. In one aspect, the second predefined time may be based on a predefined formula. In step 703, the constant pressure may be reapplied and continued for the first predefined time.

控制模式操作涉及响应操作期间过滤系统中通量的突然或预期的变化,以及以必要的间隔执行反洗或CIP。一旦建立工艺TMP、正向过滤时间和反洗参数,就在几个训练循环后启动控制模式。这种情况下的控制PID方程可写为Control mode operation involves responding to sudden or expected changes in the flux in the filtration system during operation, as well as performing backwashing or CIP at necessary intervals. Once the process TMP, forward filtration time, and backwash parameters are established, control mode is initiated after several training cycles. The control PID equation in this case can be written as

其中,in,

JAv,0是来自先前时间步长的平均通量,Qf,0是来自先前过滤步骤的累积过滤体积(通量的积分),J Av,0 is the average flux from the previous time step, Q f,0 is the cumulative filtered volume (integral of the flux) from the previous filtration step,

以及as well as

是先前过滤步骤的开始与结束之间的线性化通量下降速率。is the linearized flux decline rate between the start and end of the previous filtration step.

图8描绘了正常操作模式。在控制模式操作期间,过滤管理系统将以规则的时间间隔记录通量。还假定一旦TMP在训练周期期间建立,其在正常操作期间就不进一步改变。在正常操作期间,通量将按照由过滤管理系统学习的相同模式随着时间推移而减小,并且在一定时间间隔之后,过滤循环将停止,反洗启动,然后过滤循环在反洗之后重新开始。控制过滤时间和反洗顺序的工艺涉及将使用流量监测设备测量的瞬时通量、导数和积分通量(产量)分别与先前过滤步骤期间由过滤管理系统记录的平均通量、通量下降的线性化速率和累积产量进行比较。控制器测量比例、微分和积分分量的误差,并确定必要的动作。例如,当本过滤循环期间的累积产量变得与来自先前循环的累积产量相同并且当前循环的平均通量下降速率变得与先前循环相同时,过滤管理系统触发反洗。这是不存在过滤系统的任何其他输入或扰动的变化时的正常操作模式。Figure 8 depicts the normal operating mode. During control mode operation, the filtration management system will record flux at regular intervals. It is also assumed that once the TMP is established during the training period, it will not change further during normal operation. During normal operation, the flux will decrease over time according to the same pattern learned by the filtration management system, and after a certain time interval, the filtration cycle will stop, backwash will be initiated, and the filtration cycle will then restart after the backwash. The process of controlling the filtration time and backwash sequence involves comparing the instantaneous flux, derivative, and integrated flux (yield) measured using a flow monitoring device with the average flux, linearized rate of flux decline, and cumulative yield recorded by the filtration management system during the previous filtration step, respectively. The controller measures the errors in the proportional, differential, and integral components and determines the necessary actions. For example, when the cumulative yield during the current filtration cycle becomes the same as the cumulative yield from the previous cycle and the average flux decline rate of the current cycle becomes the same as the previous cycle, the filtration management system triggers backwash. This is the normal operating mode when there are no other changes in the filtration system's inputs or disturbances.

E.用于响应于滤液流量的阶跃变化来操作流体过滤管理系统的方法E. Method for Operating a Fluid Filtration Management System in Response to a Step Change in Filtrate Flow

图9示出了用于响应于滤液流量的阶跃变化来操作流体过滤管理系统的方法900。在步骤901中,恒定压力可施加于从第一室流到第二室的流体上。在一方面,膜沉积在第一室与第二室之间,以允许流体从第一室渗透所述膜到第二室。FIG9 illustrates a method 900 for operating a fluid filtration management system in response to a step change in filtrate flow. In step 901, a constant pressure may be applied to a fluid flowing from a first chamber to a second chamber. In one aspect, a membrane is deposited between the first chamber and the second chamber to allow the fluid to permeate the membrane from the first chamber to the second chamber.

在步骤902中,可确定过滤系统上待超过的阈值。在一方面,阈值可以是基于参数的阈值,所述参数诸如但不限于流体流速、流体流速的变化率、持续预定义时间周期通过膜的流体体积渗透物、膜上形成的结垢、其组合等中的一个或多个。In step 902, a threshold to be exceeded on the filtration system can be determined. In one aspect, the threshold can be a threshold based on parameters such as, but not limited to, one or more of a fluid flow rate, a rate of change of a fluid flow rate, a volume of fluid permeate passing through a membrane for a predefined time period, scale formed on the membrane, combinations thereof, and the like.

在步骤903中,可响应于确定阈值已经超过的值来启动回流工艺。在一方面,回流工艺可施加持续预定义时间周期。在一方面,回流工艺可以包括反转恒定压力。在一方面,反转压力可以是恒定值。在一方面,可基于预定义公式确定反转压力。In step 903, a reflow process may be initiated in response to determining that the threshold value has been exceeded. In one aspect, the reflow process may be applied for a predefined time period. In one aspect, the reflow process may include reversing a constant pressure. In one aspect, the reversing pressure may be a constant value. In one aspect, the reversing pressure may be determined based on a predefined formula.

如果在操作期间,污物块附着到膜上并突然减少其通量,则导致渗透物通量的阶跃下降。测量的瞬时通量和通量下降速率将立即改变为响应于这种阶跃变化。积分响应(累积体积)将不立即显而易见,但将在几个后续测量中显现。过滤管理系统现在将具有多个选项以响应阶跃变化,而在决策过程结束时的动作是停止过滤工艺并触发反洗。在比例模式中,过滤管理系统将继续记录通量并执行时间平均,并且一旦时间平均值下降到先前循环的平均通量以下,将触发反洗。If, during operation, a foulant adheres to the membrane and suddenly reduces its flux, this results in a step drop in permeate flux. The measured instantaneous flux and the rate of flux drop will immediately change in response to this step change. The integrated response (cumulative volume) will not be immediately apparent but will become apparent over several subsequent measurements. The filtration management system will now have multiple options for responding to the step change, with the action at the end of the decision-making process being to stop the filtration process and trigger a backwash. In proportional mode, the filtration management system will continue to record flux and perform time averaging, and once the time average drops below the average flux of the previous cycle, a backwash will be triggered.

在导数模式中,过滤管理系统将记录表示为方程(10)的瞬时导数和平均线性化导数。可以辨别,瞬时导数响应(通量下降速率)将指示大误差(对于阶跃函数是无穷大的),并且仅基于瞬时导数误差的控制响应将是太唐突的。然而,如方程(10)中的线性化导数将提供更适度的导数误差。如果此线性化导数变得比来自先前过滤循环的线性导数陡峭,则所述工艺可以触发反洗。In derivative mode, the filtration management system will record the instantaneous derivative and the average linearized derivative, expressed as Equation (10). It can be seen that the instantaneous derivative response (the rate of flux drop) will indicate a large error (infinite for a step function), and a control response based solely on the instantaneous derivative error will be too abrupt. However, the linearized derivative as in Equation (10) will provide a more moderate derivative error. If this linearized derivative becomes steeper than the linear derivative from the previous filtration cycle, the process can trigger a backwash.

在积分模式中,过滤管理系统将通过积分瞬时通量继续计算累积产量。然而,积分响应将不用于触发反洗。此响应用于计算反洗体积比,并确定反洗是否有效,或者是否应调用CIP。In integrating mode, the filtration management system will continue to calculate the cumulative throughput by integrating the instantaneous flux. However, the integrated response will not be used to trigger a backwash. This response is used to calculate the backwash volume ratio and determine whether the backwash is effective or if a CIP should be called.

过滤管理系统将通过较早地停止过滤工艺,使反洗更频繁,并在持续的不利条件(例如,如果反洗不能增加回流)下响应,以触发CIP。The filtration management system will respond to ongoing adverse conditions (for example, if backwashing fails to increase reflux) by stopping the filtration process earlier, enabling more frequent backwashing, and triggering CIP.

应当注意,过滤管理系统可以不涉及使用PID误差估计来修改过滤循环中的TMP或任何其他参数。它仅仅继续累积平均通量、平均导数和累积通量,并将这些与先前过滤步骤中获得的值进行比较。一旦平均通量变得等于先前循环中的平均通量,或者通量下降速率变得比先前步骤中的平均通量下降速率大一些预定倍数,则所述工艺然后停止过滤。通量管理的这种被动模式允许膜通过改变反洗循环的频率来从任何结垢事件中恢复。它未通过增加TMP以恢复通量来加重结垢。工艺控制方法通过在较早时间处停止过滤工艺、更频繁地清洗膜以及(如果不利条件持续)停止过滤并触发CIP来响应于通量的任何扰动。It should be noted that the filtration management system does not involve the use of PID error estimation to modify the TMP or any other parameters in the filtration cycle. It only continues to accumulate the average flux, average derivative and cumulative flux, and compares these with the values obtained in the previous filtration step. Once the average flux becomes equal to the average flux in the previous cycle, or the flux decline rate becomes some predetermined multiple greater than the average flux decline rate in the previous step, the process then stops filtering. This passive mode of flux management allows the membrane to recover from any fouling event by changing the frequency of the backwash cycle. It does not increase fouling by increasing TMP to restore flux. The process control method responds to any disturbance in flux by stopping the filtration process at an earlier time, cleaning the membrane more frequently, and (if unfavorable conditions persist) stopping filtration and triggering CIP.

F.用于响应于滤液流量的脉冲变化来操作流体过滤管理系统的方法F. Method for Operating a Fluid Filtration Management System in Response to Pulsed Changes in Filtrate Flow

图10示出了用于响应于过滤流量的脉冲变化来操作过滤管理系统的方法1000。在步骤1001中,恒定压力可施加在从第一室流到第二室的流体上,其中膜沉积在第一室与第二室之间,以允许流体从第一室渗透所述膜到第二室。Figure 10 shows a method 1000 for operating a filtration management system in response to pulsed changes in filtration flow. In step 1001, a constant pressure may be applied to a fluid flowing from a first chamber to a second chamber, wherein a membrane is deposited between the first chamber and the second chamber to allow the fluid to permeate the membrane from the first chamber to the second chamber.

在步骤1002中,可以确定与从第一室穿过膜到第二室的流体流量相关的至少一个参数。In step 1002, at least one parameter related to the flow of a fluid from a first chamber through a membrane to a second chamber may be determined.

在步骤1003中,可基于所测定的至少一个参数与至少一个阈值的比较来启动去垢工艺。在一方面,去垢工艺包括反洗工艺。在一方面,去垢工艺包括化学清洗工艺。在一方面,去垢工艺包括压力脉冲工艺。在一方面,去垢工艺包括空气冲刷工艺。在一方面,去垢工艺包括化学脉冲工艺。在一方面,去垢工艺包括进料流反转工艺。在一方面,去垢工艺包括原位清洗工艺。In step 1003, a descaling process may be initiated based on a comparison of the at least one measured parameter with at least one threshold value. In one aspect, the descaling process comprises a backwash process. In one aspect, the descaling process comprises a chemical cleaning process. In one aspect, the descaling process comprises a pressure pulse process. In one aspect, the descaling process comprises an air flush process. In one aspect, the descaling process comprises a chemical pulse process. In one aspect, the descaling process comprises a feed flow reversal process. In one aspect, the descaling process comprises a cleaning in place process.

如果通量突然减小然后在一段时间后恢复(脉冲函数),则过滤系统的响应应该是增加反洗的频率,从而降低脉冲期间的过滤时间,然后在恢复原始操作条件之后逐渐恢复到较低的频率反洗和较长的过滤步骤。这种条件可由诸如短持续时间内进料溶质浓度增加的事件触发,并且常规通量控制机制在这些事件期间通过响应于通量下降增加TMP并使结垢过程加重来使膜结垢加剧。在本发明方法中,恒定压力操作不改变驱动力以使结垢加重。If the flux suddenly decreases and then recovers after a period of time (a pulse function), the response of the filtration system should be to increase the frequency of backwashing, thereby reducing the filtration time during the pulse, and then gradually return to a lower frequency backwash and longer filtration step after the original operating conditions are restored. Such conditions can be triggered by events such as an increase in feed solute concentration for a short duration, and conventional flux control mechanisms during these events increase membrane fouling by increasing the TMP in response to the flux drop and exacerbating the fouling process. In the present method, constant pressure operation does not change the driving force to exacerbate fouling.

图11描绘了触发更尖锐通量下降的脉冲事件期间的典型过滤循环顺序。所述图绘制纵轴上的通量针对时间。为清楚地说明情况并解释通量下降行为的智能管理概念,假定通量下降行为是线性的。此外,通量在每个过滤循环中,在初始通量J0和最终通量JN之间在每个过滤循环内变化,而反洗在每个循环之后将通量恢复到初始通量。对于不同的应用,可以放宽这些简化的假设。例如,在反洗后,通量恢复可能不完全。此外,通量下降行为可能不是线性的。每个过滤循环期间的平均通量由圆圈表示,并且具有固定值JAvFIG11 depicts a typical filtration cycle sequence during a pulse event that triggers a sharper flux drop. The figure plots flux against time on the vertical axis. To clearly illustrate the situation and explain the concept of intelligent management of flux drop behavior, it is assumed that the flux drop behavior is linear. In addition, the flux varies within each filtration cycle between an initial flux J 0 and a final flux J N , while backwashing restores the flux to the initial flux after each cycle. For different applications, these simplifying assumptions can be relaxed. For example, after backwashing, flux recovery may not be complete. In addition, the flux drop behavior may not be linear. The average flux during each filtration cycle is represented by a circle and has a fixed value J Av .

假设脉冲事件在第三过滤循环期间的某一时刻处改变通量下降的速率。由于此脉冲事件所引起的较快通量下降速率使得通量对时间曲线的斜率更陡。在这种不同的通量下降速率下,最小通量JN在此循环期间较早达到。虽然较早到达平均值,但是此循环的平均通量仍为JAv。这意味着过滤循环时间tf,3<tf,2。在此循环中,过滤的累积产量也较低。一旦达到JN,反洗就开始,并且在反洗之后达到第四循环的初始通量J0。然而,在第四循环中,通量下降的速率较大,并且因此与先前循环相比较早达到平均通量和JN。换句话说,tf,4小于tf,3。此外,滤液的累积产量与过滤循环4相比也较低。由于脉冲事件所引起的加速结垢引起过滤循环的持续时间减少,并且引起反洗循环的频率增加。Assume that a pulse event changes the rate of flux decline at some point during the third filtration cycle. The faster rate of flux decline caused by this pulse event results in a steeper slope in the flux versus time curve. Given this different rate of flux decline, the minimum flux, J N , is reached earlier during this cycle. Although the average value is reached earlier, the average flux for this cycle remains J Av . This means that the filtration cycle time, t f,3 , < t f,2 , is t f,3 . The cumulative filtration yield is also lower during this cycle. Once J N is reached, backwashing begins, and the initial flux, J 0 , for the fourth cycle is reached after backwashing. However, in the fourth cycle, the rate of flux decline is greater, and therefore the average flux and J N are reached earlier than in the previous cycle. In other words, t f,4 is less than t f,3 . Furthermore, the cumulative filtrate yield is also lower compared to filtration cycle 4. The accelerated fouling caused by the pulse event reduces the duration of the filtration cycle and increases the frequency of backwash cycles.

在循环5中,脉冲事件消退,并且通量下降的原始速率恢复。与循环4相比,这立即增加了过滤时间。在循环6中,第一过滤循环的原始参数恢复。因此,触发加速通量下降的脉冲事件减少了过滤循环的持续时间,并且增加了反洗循环的频率。虽然作为对引起膜结垢的任何类型的扰动的响应,这降低了滤液的产生,但是所述机制防止膜不可逆地或主动地结垢。In cycle 5, the pulse event subsides, and the original rate of flux decline is restored. This immediately increases filtration time compared to cycle 4. In cycle 6, the original parameters of the first filtration cycle are restored. Thus, the pulse event that triggers the accelerated flux decline reduces the duration of the filtration cycle and increases the frequency of backwash cycles. While this reduces filtrate production in response to any type of perturbation that causes membrane fouling, the mechanism prevents the membrane from irreversibly or actively fouling.

图12示出了过滤管理系统的方法1200。在步骤1201中,可监测恒定压力操作期间的流体滤液通过量变化和恒定滤液通过量操作期间的压力变化中的至少一个。在一方面,监测流体滤液通过量的变化可包括测量在预定义的时间周期内穿过膜的通量。作为实例,通量的变化可以通过流量传感器来测量。在一方面,监测压力变化可包括测量预定义的时间周期内的压力。作为实例,压力的变化可以通过压力传感器来测量。FIG12 illustrates a method 1200 for a filtration management system. In step 1201, at least one of a change in fluid filtrate throughput during constant pressure operation and a change in pressure during constant filtrate throughput operation may be monitored. In one aspect, monitoring the change in fluid filtrate throughput may include measuring flux through a membrane over a predefined time period. For example, the change in flux may be measured using a flow sensor. In another aspect, monitoring the change in pressure may include measuring pressure over a predefined time period. For example, the change in pressure may be measured using a pressure sensor.

在步骤1202中,结垢机制可基于滤液通过量的变化和压力的变化中的至少一个来确定。在一方面,确定结垢机制可包括根据一个或多个预定结垢模型执行通量变化和/或压力变化的数学分析。作为实例,一个或多个预定结垢模型可包括Hermia氏模型、改进Hermia氏模型或串联阻力模型。在一方面,确定结垢机制可包括根据一个或多个预定结垢模型执行通量变化和/或压力变化的数学分析。作为实例,一个或多个预定结垢模型可包括Hermia氏模型、改进Hermia氏模型或串联阻力模型。在一方面,结垢机制可包括浓度极化、化学活性分子的有机吸附、由于盐和氢氧化物的沉淀所引起的结垢、由于大悬浮颗粒或小胶体颗粒的沉积所引起的滤饼和孔阻塞、由于惰性大分子的沉积所引起的凝胶形成、由于生物活性有机体的沉积和生长所引起的生物结垢等。In step 1202, the scaling mechanism may be determined based on at least one of a change in filtrate throughput and a change in pressure. In one aspect, determining the scaling mechanism may include performing a mathematical analysis of the flux change and/or pressure change according to one or more predetermined scaling models. As an example, the one or more predetermined scaling models may include a Hermia model, a modified Hermia model, or a series resistance model. In one aspect, determining the scaling mechanism may include performing a mathematical analysis of the flux change and/or pressure change according to one or more predetermined scaling models. As an example, the one or more predetermined scaling models may include a Hermia model, a modified Hermia model, or a series resistance model. In one aspect, the scaling mechanism may include concentration polarization, organic adsorption of chemically active molecules, scaling due to precipitation of salts and hydroxides, filter cake and pore blockage due to deposition of large suspended particles or small colloidal particles, gel formation due to deposition of inert macromolecules, biofouling due to deposition and growth of biologically active organisms, and the like.

方程12描述了随着阻碍给定驱动力的流动的阻力的累积膜结垢对通量下降的影响:Equation 12 describes the effect of membrane fouling on flux degradation as a function of the resistance to flow for a given driving force:

其中J是通过膜的渗透物通量,ΔP是跨膜压力驱动力,μ是流体粘度,Rtot是总水力阻力,Rm是固有膜阻力,Rcp是由浓度极化引起的阻力,Ra是由溶质吸附引起的阻力,Rp是由孔阻塞和滤饼形成引起的阻力,并且Rg是由表面凝胶形成引起的阻力。where J is the permeate flux through the membrane, ΔP is the transmembrane pressure driving force, μ is the fluid viscosity, Rtot is the total hydraulic resistance, Rm is the intrinsic membrane resistance, Rcp is the resistance due to concentration polarization, Ra is the resistance due to solute adsorption, Rp is the resistance due to pore blocking and cake formation, and Rg is the resistance due to surface gel formation.

在一方面,当没有发生结垢时,通量-压力曲线可以是均匀线性的,因为只有固有膜阻力是一个因素。然而,结垢的开始可根据结垢的具体机制及其对增加的渗透物流量的总阻力的影响而反映在不同程度的斜率变化中。例如,可以通过将通量对时间曲线拟合为一系列预先存在的结垢模型,根据以下方程13和14的解来确定颗粒结垢的具体机制:In one aspect, when scaling is not occurring, the flux-pressure curve can be uniformly linear, as only intrinsic membrane resistance is a factor. However, the onset of scaling can be reflected in varying degrees of slope change, depending on the specific mechanism of scaling and its impact on the overall resistance to increased permeate flow. For example, the specific mechanism of particle scaling can be determined by fitting the flux-time curve to a series of pre-existing scaling models, based on the solutions of the following equations 13 and 14:

其中t是过滤时间,k和n是表征过滤工艺的常数,并且U是分别取决于恒定压力或恒定通量操作的变化的渗透物体积V或跨膜压力ΔP。因此,通过针对dt/dU绘制d2t/dU2并确定阻塞指数n的值,可以从单个图中识别不同的阻塞机制。图13示出了进行拟合测试以确定特定观察到的颗粒结垢机制的不同结垢机制和单个通量对时间曲线的解决方案(Maiti,Sadrezadeh等2012)。此外,可使用通过修改Hermia经验模型得出的用于交叉流过滤的一般方程:where t is the filtration time, k and n are constants that characterize the filtration process, and U is the permeate volume V or transmembrane pressure ΔP that varies depending on constant pressure or constant flux operation, respectively. Thus, by plotting d²t / dU² against dt/dU² and determining the value of the blocking index n, different blocking mechanisms can be identified from a single plot. FIG13 shows a solution to different fouling mechanisms and a single flux versus time curve that were fitted to a specific observed particle fouling mechanism (Maiti, Sadrezadeh et al. 2012). Furthermore, the general equation for cross-flow filtration, derived by modifying the Hermia empirical model, can be used:

其中Jp是渗透物通量(m/s),t是过滤时间(s),KCF是取决于特定结垢机制的现象系数,Jpss是稳态渗透物通量(m/s),并且n再次为阻塞指数,其中完全孔阻塞、中间孔收缩、标准孔阻塞和滤饼过滤/凝胶形成的n分别=2、1.5、1和0。使用这些模型来评估膜结垢的实例还见于(Chang,Yang等"Assessing the fouling mechanisms of high-pressurenanofiltration membrane using the modified Hermia model and the resistance-in-series model”Separation and Purification Technology 79(2011)329-336)中。因此,智能学习过程可对以经验方式产生的通量/压力对时间曲线执行实时数据分析,以确定什么结垢机制是有效的,以及什么最有效和最经济的清洗工艺有待采用。Where Jp is the permeate flux (m/s), t is the filtration time (s), KCF is a phenomenon coefficient that depends on the specific fouling mechanism, Jpss is the steady-state permeate flux (m/s), and n is again the blocking index, where n = 2, 1.5, 1, and 0 for complete pore blocking, intermediate pore shrinkage, standard pore blocking, and cake filtration/gel formation, respectively. Examples of using these models to assess membrane fouling are also found in (Chang, Yang et al. "Assessing the fouling mechanisms of high-pressure nanofiltration membrane using the modified Hermia model and the resistance-in-series model" Separation and Purification Technology 79 (2011) 329-336). Therefore, an intelligent learning process can perform real-time data analysis on empirically generated flux/pressure versus time curves to determine what fouling mechanisms are active and what the most effective and economical cleaning process to adopt.

在步骤1203中,可以基于所确定的结垢机制来选择清洗方案。在一方面,确定清洗方案可包括选择清洗方法和与清洗方法相关的一个或多个参数。作为实例,清洗方法可以包括反冲洗方法。作为实例,一个或多个参数可以包括压力、持续时间、流速、温度、具体化学添加剂和具体化学添加剂的剂量中的一个或多个。在一方面,具体化学添加剂可以包括酸、碱、氧化剂、螯合剂等中的一种或多种。In step 1203, a cleaning regimen may be selected based on the determined fouling mechanism. In one aspect, determining the cleaning regimen may include selecting a cleaning method and one or more parameters associated with the cleaning method. As an example, the cleaning method may include a backwash method. As an example, the one or more parameters may include one or more of pressure, duration, flow rate, temperature, a specific chemical additive, and a dosage of the specific chemical additive. In one aspect, the specific chemical additive may include one or more of an acid, a base, an oxidizer, a chelating agent, and the like.

不同类型的清洗方案可用于结垢控制;然而,给定的清洗方案的功效可高度依赖于待去除的污物。表2将各种类型的膜污物与最有效的清洗技术配对:Different types of cleaning schemes can be used for fouling control; however, the efficacy of a given cleaning scheme can be highly dependent on the foulant to be removed. Table 2 pairs various types of membrane foulants with the most effective cleaning techniques:

表2Table 2

在一方面,选择的过滤系统(诸如NF和RO)遭受异质和空间依赖的结垢,所述异质和空间依赖的结垢的影响不能通过监测全规模系统数据来有效地捕获。在这些应用中,智能过滤管理系统的实施方案将包括与沿着全规模过滤系统的策略性部署的独立结垢监测器的连通。监测结垢监测器的性能数据将为智能过滤管理系统提供更高的灵敏度,以响应于早期的结垢和通量下降迹象。On the one hand, selected filtration systems (such as NF and RO) suffer from heterogeneous and spatially dependent fouling, the effects of which cannot be effectively captured by monitoring full-scale system data. In these applications, embodiments of the intelligent filtration management system will include communication with independent fouling monitors strategically deployed along the full-scale filtration system. Monitoring the performance data of the fouling monitors will provide the intelligent filtration management system with greater sensitivity to respond to early signs of fouling and flux degradation.

在一方面,对过滤器性能和完整性的辛勤监测和测试在开发对过滤器的剩余使用寿命的清楚理解和确定何时需要更换方面可以是至关重要的。例如,用于即时故障响应的膜完整性测试的手段可以包括靶向完整性测试期间的目测监测。视频捕获可用于实时监测一个或多个膜元件,从而检测可疑膜元件的任何完整性破坏。On the one hand, diligent monitoring and testing of filter performance and integrity can be crucial in developing a clear understanding of the remaining useful life of the filter and determining when replacement is necessary. For example, a means of membrane integrity testing for immediate failure response can include targeted visual monitoring during integrity testing. Video capture can be used to monitor one or more membrane elements in real time, thereby detecting any integrity breaches of suspected membrane elements.

在具体方面,过滤管理系统可连续监测一个或多个膜元件的渗透物质量。当具体膜的完整性变得成问题时,过滤管理系统可以隔离用于原位泡沫完整性测试的一个或多个元件。一旦检测到完整性破坏,过滤管理系统就可发送适当的警报并隔离一个或多个有缺陷的膜以进行维护,从而使修理速度最大化,并且使对总体过滤系统性能的影响最小化。这些公开的系统和方法还可扩展以并入用于在由于设备故障、泄漏等所引起的过滤系统故障的事件中的实时系统诊断和维护响应的其他系统度量。In a specific aspect, the filtration management system can continuously monitor the permeate quality of one or more membrane elements. When the integrity of a specific membrane becomes problematic, the filtration management system can isolate one or more elements for in-situ foam integrity testing. Once an integrity breach is detected, the filtration management system can issue appropriate alerts and isolate the defective membrane or membranes for maintenance, thereby maximizing the speed of repair and minimizing the impact on overall filtration system performance. The disclosed systems and methods can also be expanded to incorporate other system metrics for real-time system diagnostics and maintenance response in the event of filtration system failure due to equipment failure, leaks, etc.

在一方面,所述方法和系统可以执行一个或多个所测量的性能度量的实时趋势分析。所述方法和系统可以监测给定设备的操作诊断,诸如过滤器的剩余寿命和预期更换日期。例如,可通过分析渗透水质量趋势以确定是否和/或何时发生系统完整性破坏来实现实时趋势分析。在一方面,当达到给定过滤系统的预定最小渗透性时,可使用过滤和回归分析来外推。一旦确定已经发生了合理的完整性破坏,瞬时和自动响应就可开始以使系统停机时间最小化并防止总体系统故障。在一方面,所公开的系统和方法可适用于任何过滤系统,而不管是否在恒定通量或恒定压力下操作。In one aspect, the methods and systems can perform real-time trend analysis of one or more measured performance metrics. The methods and systems can monitor operational diagnostics for a given device, such as the remaining life of a filter and the expected replacement date. For example, real-time trend analysis can be achieved by analyzing permeate water quality trends to determine if and/or when a system integrity breach has occurred. In one aspect, filtration and regression analysis can be used to extrapolate when a predetermined minimum permeability for a given filtration system has been reached. Once it is determined that a reasonable integrity breach has occurred, an instantaneous and automated response can be initiated to minimize system downtime and prevent total system failure. In one aspect, the disclosed systems and methods are applicable to any filtration system, regardless of whether it is operating at constant flux or constant pressure.

图14示出了过滤管理系统的方法1400。在步骤1401中,可监测与过滤系统的一个或多个过滤器相关的一个或多个参数。在一方面,一个或多个参数可包括变压器过滤器压力、渗透物通量、渗透物浊度、渗透物盐度、渗透物pH、渗透物盐度、渗透物颜色、渗透物硬度、渗透物总有机浓度、一种或多种预定义的渗透离子的浓度、一种或多种预定义的有机分子的浓度。这些参数中的许多可以原位测量,诸如pH、盐度、颜色和浊度;然而,一些可能需要定期取样和非原位测量,诸如目标无机和有机分子的浓度。例如,可通过使用集成探针追踪穿过渗透物或进料溶液的光的量来以分光光度法的方式测量颜色和浊度。而无机和有机组分的目标浓度可使用独立的仪器来测量,所述独立的仪器诸如电感耦合等离子体发射光谱仪、气相色谱-质谱仪等。FIG14 illustrates a method 1400 for managing a filtration system. In step 1401, one or more parameters associated with one or more filters of a filtration system may be monitored. In one aspect, the one or more parameters may include transformer filter pressure, permeate flux, permeate turbidity, permeate salinity, permeate pH, permeate salinity, permeate color, permeate hardness, permeate total organic concentration, concentrations of one or more predefined permeate ions, and concentrations of one or more predefined organic molecules. Many of these parameters can be measured in situ, such as pH, salinity, color, and turbidity; however, some may require periodic sampling and ex situ measurement, such as the concentrations of target inorganic and organic molecules. For example, color and turbidity can be measured spectrophotometrically using integrated probes to track the amount of light passing through the permeate or feed solution. Target concentrations of inorganic and organic components can be measured using separate instruments, such as inductively coupled plasma optical emission spectrometers, gas chromatography-mass spectrometers, and the like.

在步骤1402中,可基于所监测的一个或多个参数来确定一个或多个过滤器的条件。在一方面,当基于所监测的一个或多个参数确定一个或多个过滤器的条件时,可以基于所监测的一个或多个参数来执行统计分析。在一方面,统计分析可包括过滤和平滑分析、回归和趋势分析。作为实例,过滤和平滑分析可包括维纳分析、卡尔曼分析、巴特沃斯分析、切比雪夫分析、椭圆分析、贝塞尔分析、高斯分析、移动平均分析和Savitsky-Golay分析。作为实例,回归和趋势分析可包括线性回归分析、多元回归分析、阶乘回归分析、多项式回归分析、响应面回归、混合面回归、单向方差分析(ANOVA)、主效应ANOVA分析、阶乘ANOVA分析、协方差分析、斜率均匀性分析、线性拟合分析、最小二乘拟合分析、Kendell检验分析、森氏斜率检验分析、Wilcoxon-Mann-Whitney步长趋势分析、遗传和神经网络分析、其组合等。In step 1402, the conditions of one or more filters can be determined based on the one or more parameters monitored. On the one hand, when determining the conditions of one or more filters based on the one or more parameters monitored, statistical analysis can be performed based on the one or more parameters monitored. On the one hand, statistical analysis can include filtering and smoothing analysis, regression and trend analysis. As an example, filtering and smoothing analysis can include Wiener analysis, Kalman analysis, Butterworth analysis, Chebyshev analysis, elliptic analysis, Bessel analysis, Gaussian analysis, moving average analysis and Savitsky-Golay analysis. As an example, regression and trend analysis can include linear regression analysis, multiple regression analysis, factorial regression analysis, polynomial regression analysis, response surface regression, mixed surface regression, one-way analysis of variance (ANOVA), main effect ANOVA analysis, factorial ANOVA analysis, covariance analysis, slope uniformity analysis, linear fit analysis, least squares fit analysis, Kendell test analysis, Sen's slope test analysis, Wilcoxon-Mann-Whitney step trend analysis, genetic and neural network analysis, its combination etc.

在一方面,确定一个或多个过滤器的条件可以包括估计一个或多个过滤器的寿命。在一方面,如果估计的寿命低于预定义阈值(例如,两天),则可以发送通知。作为实例,通知可以包括一个或多个过滤器的估计更换日期。可相对于具体过滤器特性,诸如渗透性(例如,变压器过滤器压力和滤液流速)、不可逆结垢的程度和完整性测试来监测过滤器条件。还可相对于操作参数和性能度量,诸如施加的压力、通量维持(例如,机械和化学维持、原位清洗维持)和滤液质量(例如,浊度)来监测过滤器条件。将实时记录的这些度量的值与预定阈值进行比较以计算模块的剩余寿命。渗透性测量可实时记录并且用于统计模型中以外推所随着时间推移的预测的渗透性趋势。由当前过滤器的模型预测的实现阈值渗透性的时间量是剩余的模块寿命。当寿命剩余值达到预定阈值时,则可以更换过滤器。In one aspect, determining the condition of one or more filters can include estimating the lifespan of the one or more filters. In one aspect, if the estimated lifespan falls below a predefined threshold (e.g., two days), a notification can be sent. As an example, the notification can include an estimated replacement date for one or more filters. Filter condition can be monitored relative to specific filter characteristics, such as permeability (e.g., transformer filter pressure and filtrate flow rate), the degree of irreversible fouling, and integrity testing. Filter condition can also be monitored relative to operating parameters and performance metrics, such as applied pressure, flux maintenance (e.g., mechanical and chemical maintenance, in-situ cleaning maintenance), and filtrate quality (e.g., turbidity). The values of these metrics, recorded in real time, are compared to predetermined thresholds to calculate the remaining lifespan of the module. Permeability measurements can be recorded in real time and used in a statistical model to extrapolate predicted permeability trends over time. The amount of time predicted by the model for the current filter to achieve the threshold permeability is the remaining module lifespan. When the remaining lifespan value reaches the predetermined threshold, the filter can be replaced.

在一方面,确定一个或多个过滤器的条件可以包括确定一个或多个过滤器的类型。作为实例,一个或多个过滤器的类型包括管状聚合膜、中空纤维膜、螺旋卷绕膜、管状陶瓷膜、其组合等。In one aspect, determining the condition of the one or more filters can include determining the type of the one or more filters. As examples, the one or more filter types include tubular polymeric membranes, hollow fiber membranes, spiral wound membranes, tubular ceramic membranes, combinations thereof, and the like.

在一方面,一个或多个过滤器的条件可包括即将到来的完整性破坏、检测到的完整性破坏、即将到来的渗透性损失和检测到的渗透性损失。In one aspect, the condition of the one or more filters may include an impending integrity breach, a detected integrity breach, an impending permeability loss, and a detected permeability loss.

在步骤1403中,一个或多个维护程序可基于确定的条件来执行。一个或多个维护程序可根据所述条件来使用。在一方面,一个或多个维护程序可包括过滤器隔离程序、过滤器修理程序、过滤器更换程序、过滤器钉扎程序、其组合等。In step 1403, one or more maintenance procedures may be performed based on the determined conditions. The one or more maintenance procedures may be used according to the conditions. In one aspect, the one or more maintenance procedures may include a filter isolation procedure, a filter repair procedure, a filter replacement procedure, a filter pinning procedure, a combination thereof, or the like.

在一方面,无论是否由完整性破坏还是渗透性损失所引起的对具体过滤器条件的响应均可根据系统所用的过滤器的类型而改变。例如,当发生中空纤维膜的纤维故障时,故障的纤维膜可通过在断裂纤维的端部插入小针或环氧树脂来隔离,或者可从使用中永久地移除。作为另一个实例,螺旋卷绕纳滤和反渗透膜可以在故障后更换。考虑到与过滤器故障和更换相关的高频率和成本,故障的早期检测和适当准备可在经济上有效的更换实践中是非常有价值的。On the one hand, the response to a specific filter condition, whether caused by integrity damage or permeability loss, can be varied depending on the type of filter used in the system. For example, when a fiber failure of a hollow fiber membrane occurs, the failed fiber membrane can be isolated by inserting a small needle or epoxy resin at the end of the broken fiber, or can be permanently removed from use. As another example, spirally wound nanofiltration and reverse osmosis membranes can be replaced after a failure. Considering the high frequency and cost associated with filter failure and replacement, early detection of failures and appropriate preparation can be very valuable in economically efficient replacement practices.

图15和图16示出了使用本文所述的过滤管理系统和方法的实验结果。可编程逻辑控制器被编程来在恒定的施加压力下操作过滤系统。允许过滤系统的通量自然衰减,直到达到预先计算的最小值,然后该最小值将触发维护程序,例如如图15所示的滤液反洗。与利用预定义的维护程序频率的常规过滤工艺不同,过滤管理系统可以通过允许过滤系统性能要求适当的维护程序诸如清洗方案来适应环境条件。图16示出了过滤管理系统如何因此能够适应环境条件(诸如给水质量和温度)的剧烈变化性。具体地,油浓度和水温的剧烈摆动可能在初始启动阶段导致显著的通量损失。作为响应,过滤管理系统可以增加反洗的频率以及化学清洗的数量,各自被表示为“原位清洗”(CIP)。过滤管理系统在约24小时的操作之后最终稳定了膜的性能,这导致最小化的通量下降和CIP频率。Figures 15 and 16 show experimental results using the filtration management system and method described herein. A programmable logic controller is programmed to operate the filtration system under constant applied pressure. The flux of the filtration system is allowed to decay naturally until it reaches a pre-calculated minimum value, which then triggers a maintenance program, such as filtrate backwashing as shown in Figure 15. Unlike conventional filtration processes that utilize predefined maintenance program frequencies, the filtration management system can adapt to environmental conditions by allowing the filtration system performance to require appropriate maintenance programs such as cleaning solutions. Figure 16 shows how the filtration management system can therefore adapt to the dramatic variability of environmental conditions (such as feed water quality and temperature). Specifically, dramatic swings in oil concentration and water temperature may result in significant flux loss during the initial startup phase. In response, the filtration management system can increase the frequency of backwashing and the number of chemical cleanings, each denoted as "cleaning in place" (CIP). The filtration management system ultimately stabilized the performance of the membrane after approximately 24 hours of operation, which resulted in minimized flux decline and CIP frequency.

在示例性方面,方法和系统可在如图17所示的和如下所述的计算机1701上实施。类似地,所公开的方法和系统可利用一个或多个计算机来在一个或多个位置中执行一个或多个功能。图17是示出用于执行所公开的方法的示例性操作环境的框图。此示例性操作环境仅是操作环境的一个实例,并且不旨在对操作环境架构的使用或功能性的范围提出任何限制。也不应将操作环境解释为具有与示例性操作环境中所示的部件中的任一个或组合有关的任何依赖性或要求。In an exemplary aspect, the methods and systems may be implemented on a computer 1701 as shown in FIG. 17 and described below. Similarly, the disclosed methods and systems may utilize one or more computers to perform one or more functions in one or more locations. FIG. 17 is a block diagram illustrating an exemplary operating environment for performing the disclosed methods. This exemplary operating environment is merely an example of an operating environment and is not intended to limit the scope of use or functionality of the operating environment architecture. Neither should the operating environment be interpreted as having any dependency or requirement relating to any one or combination of components illustrated in the exemplary operating environment.

本发明方法和系统可以与许多其他通用或专用计算系统环境或配置一起操作。可适于与所述系统和方法一起使用的公知计算系统、环境和/或配置的实例包括但不限于个人计算机、服务器计算机、膝上型设备和多处理器系统。另外实例包括机顶盒、可编程消费电子产品、网络PC、小型计算机、大型计算机、包括以上系统或设备中的任一个的分布式计算环境等。The method and system of the present invention can operate with many other general or special computing system environments or configurations. Examples of known computing systems, environments, and/or configurations suitable for use with the system and method include, but are not limited to, personal computers, server computers, laptops, and multiprocessor systems. Additional examples include set-top boxes, programmable consumer electronics, network PCs, minicomputers, mainframe computers, distributed computing environments including any of the above systems or devices, and the like.

所公开的方法和系统的处理可由软件部件来执行。所公开的系统和方法可在由一个或多个计算机或其他设备执行的计算机可执行指令诸如程序模块的一般上下文中描述。通常,程序模块包括用来执行特定任务或实施特定抽象数据类型的计算机代码、例程、程序、对象、部件、数据结构等。所公开的方法还可在基于网格的和分布式计算环境中实践,在所述环境中任务由通过通信网络链接的远程处理设备来执行。在分布式计算环境中,程序模块可定位在包括内存存储装置的本地和/或远程计算机存储介质中。The processing of the disclosed methods and systems can be performed by software components. The disclosed systems and methods can be described in the general context of computer-executable instructions, such as program modules, executed by one or more computers or other devices. Generally, program modules include computer code, routines, programs, objects, components, data structures, etc., that are used to perform specific tasks or implement specific abstract data types. The disclosed methods can also be practiced in grid-based and distributed computing environments, in which tasks are performed by remote processing devices linked through a communication network. In a distributed computing environment, program modules can be located in local and/or remote computer storage media, including memory storage devices.

此外,本领域技术人员将理解,本文所公开的系统和方法可通过呈计算机1701形式的通用计算设备来实施。计算机1701可以包括一个或多个部件,诸如一个或多个处理器1703、系统存储器1712,以及将包括一个或多个处理器1703的计算机1701的不同部件耦接到系统存储器1712的总线1713。在多处理器1703的情况下,系统可以利用并行计算。Furthermore, those skilled in the art will appreciate that the systems and methods disclosed herein may be implemented by a general purpose computing device in the form of a computer 1701. The computer 1701 may include one or more components, such as one or more processors 1703, a system memory 1712, and a bus 1713 that couples the various components of the computer 1701, including the one or more processors 1703, to the system memory 1712. In the case of multiple processors 1703, the system may utilize parallel computing.

总线1713可以包括几个可能类型的总线结构中的一个或多个,诸如存储器总线、存储器控制器、外围总线、加速图形端口以及使用各种总线架构中的任一种的处理器或局部总线。例如,所述架构可以包括工业标准架构(ISA)总线、微通道架构(MCA)总线、增强型ISA(EISA)总线、视频电子标准协会(VESA)局部总线、加速图形端口(AGP)总线,以及外围部件互连(PCI)、PCI-Express总线、个人计算机存储卡工业协会(PCMCIA)、通用串行总线(USB)等。总线1713和本说明书中指定的所有总线还可以通过有线或无线网络连接来实施,并且计算机1701的部件中的一个或多个,诸如一个或多个处理器1703、大容量存储设备1704、操作系统1705、数据处理软件1706、通量数据1707、网络适配器1708、系统存储器1712、输入/输出界面1710、显示适配器1709、显示设备1711和人机界面1702可以包含在物理上分离的位置处的一个或多个远程计算设备1714a、b、c内,通过这种形式的总线连接,从而实际上实施完全分布式系统。The bus 1713 may include one or more of several possible types of bus structures, such as a memory bus, a memory controller, a peripheral bus, an accelerated graphics port, and a processor or local bus using any of a variety of bus architectures. For example, the architecture may include an Industry Standard Architecture (ISA) bus, a Micro Channel Architecture (MCA) bus, an Enhanced ISA (EISA) bus, a Video Electronics Standards Association (VESA) local bus, an Accelerated Graphics Port (AGP) bus, as well as a Peripheral Component Interconnect (PCI), PCI-Express bus, a Personal Computer Memory Card Industry Association (PCMCIA), a Universal Serial Bus (USB), and the like. The bus 1713 and all buses specified in this specification can also be implemented through a wired or wireless network connection, and one or more of the components of the computer 1701, such as one or more processors 1703, mass storage device 1704, operating system 1705, data processing software 1706, flux data 1707, network adapter 1708, system memory 1712, input/output interface 1710, display adapter 1709, display device 1711 and human-computer interface 1702 can be included in one or more remote computing devices 1714a, b, c at physically separate locations, connected through this form of bus, thereby actually implementing a fully distributed system.

计算机1701通常包括各种计算机可读介质。示例性可读介质可以是可由计算机1701访问的任何可用介质,并且包括(例如但不意在限制)易失性和非易失性介质、可移动和不可移动介质。系统存储器1712可包括成以下形式的计算机可读介质:易失性存储器,诸如随机访问存储器(RAM)和/或非易失性存储器,诸如只读存储器(ROM)。系统存储器1712通常可包括诸如通量数据1707的数据,和/或诸如可由一个或多个处理器1703访问和/或操作的操作系统1705和数据处理软件1706的程序模块。The computer 1701 typically includes a variety of computer-readable media. Exemplary computer-readable media can be any available media that can be accessed by the computer 1701, and include, for example, but not intended to be limiting, volatile and non-volatile media, removable and non-removable media. The system memory 1712 may include computer-readable media in the form of volatile memory, such as random access memory (RAM), and/or non-volatile memory, such as read-only memory (ROM). The system memory 1712 may typically include data, such as flux data 1707, and/or program modules, such as an operating system 1705 and data processing software 1706, that can be accessed and/or operated by one or more processors 1703.

在另一方面,计算机1701还可以包括其他可移动/不可移动、易失性/非易失性计算机存储介质。大容量存储设备1704可以提供用于计算机1701的计算机代码、计算机可读指令、数据结构、程序模块和其他数据的非易失性存储。例如,大容量存储设备1704可以是硬盘、可移动磁盘、可移动光盘、磁性盒或其他磁存储设备、闪存卡、CD-ROM、数字通用光盘(DVD)或其他光存储器、随机访问存储器(RAM)、只读存储器(ROM)、电可擦除可编程只读存储器(EEPROM)等。In another aspect, the computer 1701 may also include other removable/non-removable, volatile/non-volatile computer storage media. The mass storage device 1704 may provide non-volatile storage for computer code, computer-readable instructions, data structures, program modules, and other data for the computer 1701. For example, the mass storage device 1704 may be a hard disk, a removable magnetic disk, a removable optical disk, a magnetic cassette or other magnetic storage device, a flash memory card, a CD-ROM, a digital versatile disk (DVD) or other optical storage, a random access memory (RAM), a read-only memory (ROM), an electrically erasable programmable read-only memory (EEPROM), etc.

任选地,任何数量的程序模块可以存储在大容量存储设备1704(包括例如操作系统1705和数据处理软件1706)上。操作系统1705和数据处理软件1706(或其某种组合)中的一个或多个可以包括编程和数据处理软件1706的元件。通量数据1707也可存储在大容量存储设备1704上。通量数据1707可存储在本领域中已知的一个或多个数据库中的任一个中。所述数据库的实例包括Access、SQL Server、mySQL、PostgreSQL等。数据库可以是集中式的或跨过网络1715内的多个位置分布。Optionally, any number of program modules can be stored on the mass storage device 1704 (including, for example, an operating system 1705 and data processing software 1706). One or more of the operating system 1705 and the data processing software 1706 (or some combination thereof) can include elements of the programming and data processing software 1706. Flux data 1707 can also be stored on the mass storage device 1704. Flux data 1707 can be stored in any of one or more databases known in the art. Examples of such databases include Access, SQL Server, mySQL, PostgreSQL, etc. The database can be centralized or distributed across multiple locations within the network 1715.

在一方面,用户可通过输入设备(未示出)将命令和信息输入到计算机1701中。所述输入设备的实例包括但不限于键盘、指向设备(例如,计算机鼠标、遥控器)、麦克风、操纵杆、扫描仪、触觉输入设备诸如手套,以及其他身体覆盖物、运动传感器等。这些和其他输入设备可以通过耦接到总线1713的人机界面1702连接到一个或多个处理器1703,但是可以通过其他界面和总线结构来连接,所述其他界面和总线结构诸如并行端口、游戏端口、IEEE1394端口(也称为火线端口)、串行端口、网络适配器1708和/或通用串行总线(USB)。In one aspect, a user can enter commands and information into the computer 1701 through input devices (not shown). Examples of such input devices include, but are not limited to, keyboards, pointing devices (e.g., a computer mouse, a remote control), microphones, joysticks, scanners, tactile input devices such as gloves and other body coverings, motion sensors, etc. These and other input devices can be connected to the one or more processors 1703 through a human-machine interface 1702 coupled to the bus 1713, but can be connected through other interfaces and bus structures, such as a parallel port, a game port, an IEEE 1394 port (also known as a FireWire port), a serial port, a network adapter 1708, and/or a universal serial bus (USB).

在又一方面,显示设备1711还可以通过诸如显示适配器1709的界面连接到总线1713。可以设想,计算机1701可具有多于一个的显示适配器1709,并且计算机1701可以具有多于一个的显示设备1711。例如,显示设备1711可以是监测器、LCD(液晶显示器)、发光二极管(LED)显示器、电视、智能透镜、智能玻璃和/或投影仪。除了显示设备1711之外,其他输出外围设备还可包括诸如可通过输入/输出界面1710连接到计算机1701的扬声器(未示出)和打印机(未示出)的部件。方法的任何步骤和/或结果可以任何形式输出到输出设备。所述输出可以是任何形式的视觉表示,包括但不限于文本表示、图形表示、动画表示、音频表示、触觉表示等。显示器1711和计算机1701可以是一个设备或单独设备的一部分。In another aspect, the display device 1711 can also be connected to the bus 1713 via an interface such as a display adapter 1709. It is contemplated that the computer 1701 may have more than one display adapter 1709, and the computer 1701 may have more than one display device 1711. For example, the display device 1711 can be a monitor, an LCD (liquid crystal display), a light emitting diode (LED) display, a television, a smart lens, smart glass, and/or a projector. In addition to the display device 1711, other output peripherals may also include components such as speakers (not shown) and printers (not shown) that can be connected to the computer 1701 via an input/output interface 1710. Any steps and/or results of the method can be output to an output device in any form. The output can be any form of visual representation, including but not limited to textual representation, graphical representation, animated representation, audio representation, tactile representation, etc. The display 1711 and the computer 1701 can be part of one device or separate devices.

计算机1701可在联网环境中使用与一个或多个远程计算设备1714a、b、c的逻辑连接操作。例如,远程计算设备1714a、b、c可以是个人计算机、计算站(例如工作站)、便携式计算机(例如膝上型、移动电话、平板设备)、智能设备(例如智能电话、智能手表、活动追踪器、智能服装、智能配件)、安全和/或监测设备、服务器、路由器、网络计算机、对等设备、边缘设备或其他公共网络节点等。计算机1701与远程计算设备1714a、b、c之间的逻辑连接可以通过网络1715诸如局域网(LAN)和/或通用广域网(WAN)来进行。所述网络连接可以通过网络适配器1708进行。网络适配器1708可在有线和无线环境中实施。所述网络环境在住宅、办公室、企业范围计算机网络、内联网和因特网中是常规和常见的。Computer 1701 can operate in a networked environment using logical connections to one or more remote computing devices 1714a, b, c. For example, remote computing devices 1714a, b, c can be personal computers, computing stations (e.g., workstations), portable computers (e.g., laptops, mobile phones, tablet devices), smart devices (e.g., smartphones, smart watches, activity trackers, smart clothing, smart accessories), security and/or monitoring equipment, servers, routers, network computers, peer devices, edge devices, or other public network nodes. The logical connection between computer 1701 and remote computing devices 1714a, b, c can be made via a network 1715, such as a local area network (LAN) and/or a general wide area network (WAN). The network connection can be made via a network adapter 1708. Network adapter 1708 can be implemented in both wired and wireless environments. Such networking environments are conventional and common in homes, offices, enterprise-wide computer networks, intranets, and the Internet.

出于说明的目的,应用程序和其他可执行程序部件诸如操作系统1705在本文说明为离散块,但是认识到所述程序和部件可以在不同时间处驻留在计算设备1701的不同存储部件中,并且由计算机1701的一个或多个处理器1703执行。数据处理软件1706的实施可存储在某种形式的计算机可读介质上或传输出穿过某种形式的计算机可读介质。所公开方法中的任一个可由体现在计算机可读介质上的计算机可读指令来执行。计算机可读介质可以是可由计算机访问的任何可用介质。例如但不意在限制,计算机可读介质可以包括“计算机存储介质”和“通信介质”。“计算机存储介质”可包括以任何方法或技术实施的用于存储信息诸如计算机可读指令、数据结构、程序模块或其他数据的易失的和非易失的、可移动和不可移动的介质。示例性计算机存储介质可包括RAM、ROM、EEPROM、闪存或其他存储器技术、CD-ROM、数字通用光盘(DVD)或其他光学存储器、磁性盒、磁带、磁盘存储器或其他磁存储设备或可用于存储所需信息并可由计算机访问的任何其他介质。For purposes of illustration, application programs and other executable program components, such as an operating system 1705, are described herein as discrete blocks, but it is recognized that the programs and components may reside at different times in different storage components of the computing device 1701 and be executed by one or more processors 1703 of the computer 1701. An implementation of the data processing software 1706 may be stored on or transmitted across some form of computer-readable media. Any of the disclosed methods may be performed by computer-readable instructions embodied on a computer-readable medium. A computer-readable medium may be any available medium that can be accessed by a computer. By way of example, and not limitation, computer-readable media may include "computer storage media" and "communication media." "Computer storage media" may include volatile and nonvolatile, removable and non-removable media implemented in any method or technology for storage of information, such as computer-readable instructions, data structures, program modules, or other data. Exemplary computer storage media may include RAM, ROM, EEPROM, flash memory or other memory technology, CD-ROM, digital versatile disks (DVD) or other optical storage, magnetic cassettes, magnetic tape, magnetic disk storage or other magnetic storage devices, or any other medium which can be used to store the desired information and which can be accessed by the computer.

所述方法和系统可以采用人工智能(AI)技术,诸如机器学习和迭代学习。所述技术的实例包括但不限于专家系统、基于案例的推理、贝叶斯网络、基于行为的AI、神经网络、模糊系统、进化计算(例如遗传算法)、群体智能(例如蚂蚁算法),以及混合智能系统(例如通过神经网络生成的专家推理规则或来自统计学习的生产规则)。The methods and systems can employ artificial intelligence (AI) techniques such as machine learning and iterative learning. Examples of such techniques include, but are not limited to, expert systems, case-based reasoning, Bayesian networks, behavior-based AI, neural networks, fuzzy systems, evolutionary computation (e.g., genetic algorithms), swarm intelligence (e.g., ant algorithms), and hybrid intelligent systems (e.g., expert inference rules generated by neural networks or production rules from statistical learning).

虽然已经结合优选实施方案和具体实施例描述了方法和系统,但是并不旨在将范围限于所阐述的特定实施方案,因为本文的实施方案在所有方面均旨在说明而非限制。While the methods and systems have been described in conjunction with preferred embodiments and specific examples, it is not intended to be limited in scope to the particular embodiments set forth, as the embodiments herein are intended in all respects to be illustrative rather than restrictive.

虽然可以用特定的法定类别(如系统法定类别)对本公开的方面进行描述和要求保护,但这仅是为了方便,并且本领域技术人员将理解到可以用任何的法定类别对本公开的各方面进行描述和要求保护。除非另外明确说明,否则决不旨在将本文阐述的任何方法或方面解释为要求以特定顺序执行其步骤。因此,在权利要求书或说明书中,当方法权利要求没有确切地说明步骤是限于特定顺序时,在任何方面决非旨在推断顺序。这适用于任何可能的用于解释的非表达基础,包括相对于步骤安排或操作流程的逻辑事项、从语法组织或标点符号得到的清晰含义、或者在说明书中描述的方面的数量或类型。Although aspects of the present disclosure may be described and claimed using specific statutory categories (such as the system statutory category), this is for convenience only, and those skilled in the art will understand that aspects of the present disclosure may be described and claimed using any statutory category. Unless expressly stated otherwise, it is in no way intended that any method or aspect set forth herein be construed as requiring that its steps be performed in a particular order. Therefore, in the claims or specification, when a method claim does not specifically state that the steps are limited to a particular order, it is in no way intended that an order be inferred. This applies to any possible non-express basis for interpretation, including matters of logic with respect to the arrangement of steps or operational flow, clear meaning derived from grammatical organization or punctuation, or the number or type of aspects described in the specification.

本领域技术人员显而易知可产生本公开的各种修改和变化而不背离本公开的范围或精神。从本文所公开的方法和/或系统的说明书和实践的考虑,本公开的其他实施方案对本领域技术人员而言将为显而易见的。预期说明书和实施例仅被视为示例性的,其中本公开的真实范围和精神由所附权利要求书指示。It will be apparent to those skilled in the art that various modifications and variations of the present disclosure may be made without departing from the scope or spirit of the present disclosure. Other embodiments of the present disclosure will be apparent to those skilled in the art from consideration of the description and practice of the methods and/or systems disclosed herein. It is intended that the description and examples be regarded as exemplary only, with the true scope and spirit of the present disclosure being indicated by the appended claims.

Claims (20)

1.一种方法,其包括:1. A method comprising: 在当前过滤循环期间监测与过滤系统的一个或多个膜相关的一个或多个参数;Monitor one or more parameters related to one or more membranes in the filtration system during the current filtration cycle; 在当前过滤循环期间基于监测到的一个或多个参数确定当前过滤循环的通量下降速率大于先前过滤循环的通量下降速率;以及During the current filtration cycle, based on one or more monitored parameters, it is determined that the flux decline rate of the current filtration cycle is greater than the flux decline rate of the previous filtration cycle; and 基于对当前过滤循环的通量下降速率大于先前过滤循环的通量下降速率的确定,执行一个或多个维护程序。Based on the determination that the flux decline rate of the current filtration cycle is greater than the flux decline rate of the previous filtration cycle, one or more maintenance procedures are executed. 2.如权利要求1所述的方法,其中监测作为所述过滤系统的平均值或通过监测所述过滤系统内的局部性能参数来执行,以检测所述一个或多个膜中至少一个膜的单独结垢的空间变化性。2. The method of claim 1, wherein monitoring is performed as an average value of the filtration system or by monitoring local performance parameters within the filtration system to detect the spatial variability of individual fouling of at least one of the one or more membranes. 3.如权利要求1所述的方法,其中所述一个或多个参数包括以下中的一个或多个:变压器过滤器压降、滤液流速、滤液浊度、滤液盐度、滤液pH、滤液颜色、滤液硬度、滤液总有机浓度、滤液微生物计数、进料微生物计数、一种或多种预定义滤液、进料或浓缩物离子的浓度,或者一种或多种预定义滤液、进料或浓缩物非离子分子的浓度。3. The method of claim 1, wherein the one or more parameters include one or more of the following: transformer filter pressure drop, filtrate flow rate, filtrate turbidity, filtrate salinity, filtrate pH, filtrate color, filtrate hardness, total organic concentration of filtrate, microbial count of filtrate, microbial count of feed, concentration of one or more predefined ions in filtrate, feed or concentrate, or concentration of one or more predefined nonionic molecules in filtrate, feed or concentrate. 4.如权利要求3所述的方法,其中在前端位置(流入物)、后端位置(浓缩物或拒斥物)和滤液端位置(或渗透物)处监测被监测的所述一个或多个参数中的至少一个参数,并且其中所述一个或多个参数中的所述至少一个参数在所述前端位置、所述后端位置或所述滤液端位置中的一个或多个处被监测。4. The method of claim 3, wherein at least one of the monitored parameters is monitored at a front-end position (inflow material), a rear-end position (concentrate or repellent), and a filtrate end position (or permeate material), and wherein the at least one of the monitored parameters is monitored at one or more of the front-end position, the rear-end position, or the filtrate end position. 5.如权利要求1所述的方法,其中基于所述监测到的一个或多个参数确定所述一个或多个膜的条件包括基于所述监测到的一个或多个参数执行统计分析。5. The method of claim 1, wherein determining the conditions of the one or more membranes based on the monitored one or more parameters includes performing statistical analysis based on the monitored one or more parameters. 6.如权利要求1所述的方法,其中所述一个或多个膜的条件包括即将到来的过滤器熟化或过滤准备状态、检测到的过滤器熟化或过滤准备状态、即将到来的完整性破坏、检测到的完整性破坏、即将到来的渗透性损失或检测到的渗透性损失中的一个或多个。6. The method of claim 1, wherein the conditions of the one or more membranes include one or more of the following: upcoming filter curing or filter preparation state, detected filter curing or filter preparation state, upcoming integrity failure, detected integrity failure, upcoming permeability loss, or detected permeability loss. 7.如权利要求1所述的方法,其中所述一个或多个维护程序包括过滤器清洗程序、过滤器隔离程序、过滤器修理程序、过滤器更换程序或过滤器钉扎程序中的一个或多个。7. The method of claim 1, wherein the one or more maintenance procedures include one or more of a filter cleaning procedure, a filter isolation procedure, a filter repair procedure, a filter replacement procedure, or a filter pinning procedure. 8.一种方法,其包括:8. A method comprising: 在当前过滤循环期间监测恒定压力操作期间的流体滤液通过量的变化或恒定滤液通过量操作期间的压力的变化中的至少一个;Monitor at least one of the changes in fluid filtrate throughput during constant pressure operation or the changes in pressure during constant filtrate throughput operation during the current filtration cycle. 当确定当前过滤循环的滤液通过量的变化大于先前过滤循环的滤液通过量的变化,或者确定当前过滤循环的压力变化大于先前过滤循环的压力变化时,对结构机制进行确定;The structural mechanism is determined when it is determined that the change in the filtrate throughput of the current filtration cycle is greater than the change in the filtrate throughput of the previous filtration cycle, or when it is determined that the change in the pressure of the current filtration cycle is greater than the change in the pressure of the previous filtration cycle. 基于确定的结垢机制选择清洗方案;以及Select a cleaning scheme based on the identified scaling mechanism; and 根据所选择的清洗方案执行清洗程序。Perform the cleaning procedure according to the selected cleaning plan. 9.如权利要求8所述的方法,还包括:9. The method of claim 8, further comprising: 捕获一个或多个膜元件的视频。Capture video of one or more membrane elements. 10.如权利要求8所述的方法,其中监测滤液通过量的变化包括测量预定义的时间周期内的滤液流量,并且其中监测压力的变化包括测量预定义的时间周期内的压力。10. The method of claim 8, wherein monitoring changes in filtrate flow rate comprises measuring filtrate flow rate over a predefined time period, and wherein monitoring changes in pressure comprises measuring pressure over a predefined time period. 11.如权利要求8所述的方法,其中确定结垢机制包括根据一个或多个预定结垢模型执行滤液流量的变化或压力的变化的数学分析。11. The method of claim 8, wherein determining the scaling mechanism comprises performing mathematical analysis of changes in filtrate flow rate or pressure based on one or more predetermined scaling models. 12.如权利要求8所述的方法,其中所述结垢机制包括浓度极化、化学活性分子的有机吸附、由于盐和氢氧化物的沉淀所引起的结垢、由于大悬浮颗粒或小胶体颗粒的沉积所引起的滤饼和孔阻塞、由于惰性大分子的沉积所引起的凝胶形成,或者由于生物活性有机体的沉积和生长所引起的生物结垢中的一种或多种。12. The method of claim 8, wherein the scaling mechanism comprises one or more of the following: concentration polarization, organic adsorption of chemically active molecules, scaling due to precipitation of salts and hydroxides, filter cake and pore blockage due to deposition of large suspended particles or small colloidal particles, gel formation due to deposition of inert macromolecules, or bioscale due to deposition and growth of bioactive organisms. 13.如权利要求11所述的方法,其中所述一个或多个预定结垢模型包括Hermia氏模型、改进Hermia氏模型和串联阻力模型中的一个或多个。13. The method of claim 11, wherein the one or more predetermined scaling models include one or more of the Hermia model, the modified Hermia model, and the series resistance model. 14.如权利要求8所述的方法,其中选择所述清洗方案包括选择清洗方法和与所述清洗方法相关的一个或多个参数。14. The method of claim 8, wherein selecting the cleaning scheme includes selecting a cleaning method and one or more parameters associated with the cleaning method. 15.一种系统,其包括:15. A system comprising: 压力泵,其被配置来在当前过滤循环期间在流动于第一室与第二室之间的流体上施加压力;A pressure pump is configured to apply pressure to the fluid flowing between the first and second chambers during the current filtration cycle; 流量传感器,其被配置来在当前过滤循环期间测定与流过在所述第一室与第二室之间沉积的膜的流体相关的至少一个参数;A flow sensor configured to measure at least one parameter relating to the fluid flowing through a membrane deposited between the first and second chambers during the current filtration cycle; 压力传感器,其被配置来在当前过滤循环期间测定从所述第一室流到所述第二室的所述流体的压力读数;以及A pressure sensor is configured to measure the pressure reading of the fluid flowing from the first chamber to the second chamber during the current filtration cycle; and 过滤管理系统,其被配置来:The filter management system is configured to: 基于所述压力读数引起所述压力泵在从所述第一室到所述第二室流过所述膜的流体上施加恒定压力持续第一预定时间;所述过滤管理系统还被配置来:Based on the pressure reading, the pressure pump applies a constant pressure to the fluid flowing through the membrane from the first chamber to the second chamber for a first predetermined time; the filtration management system is also configured to: 在所述第一预定时间期间,至少基于所述至少一个参数确定当前过滤循环的线性化通量下降速率大于先前过滤循环的线性化通量下降速率,并且基于对当前过滤循环的线性化通量下降速率大于先前过滤循环的线性化通量下降速率的确定,引起所述压力泵使穿过所述膜的所述流体流反转持续第二预定时间;或During the first predetermined time period, it is determined, based at least one parameter, that the linearized flux decrease rate of the current filtration cycle is greater than the linearized flux decrease rate of the previous filtration cycle, and based on the determination that the linearized flux decrease rate of the current filtration cycle is greater than the linearized flux decrease rate of the previous filtration cycle, the pressure pump is caused to reverse the fluid flow through the membrane for a second predetermined time; or 在所述第一预定时间之后,引起所述压力泵使穿过所述膜的所述流体流反转持续第二预定时间。After the first predetermined time, the pressure pump is activated to reverse the flow of fluid through the membrane for a second predetermined time. 16.如权利要求15所述的系统,其中至少基于所述至少一个参数确定当前过滤循环的线性化通量下降速率大于先前过滤循环的线性化通量下降速率包括将所述至少一个参数与至少一个阈值进行比较。16. The system of claim 15, wherein determining that the linearized flux decline rate of the current filtering cycle is greater than the linearized flux decline rate of the previous filtering cycle based at least on the at least one parameter comprises comparing the at least one parameter with at least one threshold. 17.如权利要求16所述的系统,其还包括计时器,所述计时器被配置用于调节施加所述恒定压力的时间或调节使所述恒定压力反转的时间中的至少一个。17. The system of claim 16, further comprising a timer configured to adjust at least one of the time for applying the constant pressure or adjusting the time for reversing the constant pressure. 18.如权利要求16所述的系统,其中所述至少一个参数是流体流速、流体流速的变化率、或持续预定义时间周期通过所述膜的流体体积渗透物中的一个或多个。18. The system of claim 16, wherein the at least one parameter is one or more of fluid flow rate, rate of change of fluid flow rate, or fluid volume permeate passing through the membrane for a predefined time period. 19.如权利要求16所述的系统,其中所述第一预定时间或所述第二预定时间中的一个或多个是恒定值。19. The system of claim 16, wherein one or more of the first predetermined time or the second predetermined time is a constant value. 20.如权利要求16所述的系统,其中所述第一预定时间或所述第二预定时间中的一个或多个基于预定义公式确定。20. The system of claim 16, wherein one or more of the first predetermined time or the second predetermined time are determined based on a predefined formula.
HK17112177.1A 2014-08-12 2015-08-12 Intelligent fluid filtration management system HK1238194B (en)

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