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HK1220945B - Process for producing a multilayer pipe having a metallurgical bond by drawing, and multilayer pipe produced by this process - Google Patents

Process for producing a multilayer pipe having a metallurgical bond by drawing, and multilayer pipe produced by this process Download PDF

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Publication number
HK1220945B
HK1220945B HK16109048.5A HK16109048A HK1220945B HK 1220945 B HK1220945 B HK 1220945B HK 16109048 A HK16109048 A HK 16109048A HK 1220945 B HK1220945 B HK 1220945B
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Hong Kong
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tube
tubular element
outer tube
inner tube
multilayer
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HK16109048.5A
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Chinese (zh)
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HK1220945A1 (en
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Júlio Márcio SILVEIRA E SILVA
Timo EBELING
Hezick DA SILVA PERDIGÃO
Danielle GRANHA GIORGINI
Antônio Wagner DA SILVA PENNA
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Vallourec Tubos Do Brasil S.A.
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Priority claimed from BR102013021664-0A external-priority patent/BR102013021664B1/en
Application filed by Vallourec Tubos Do Brasil S.A. filed Critical Vallourec Tubos Do Brasil S.A.
Publication of HK1220945A1 publication Critical patent/HK1220945A1/en
Publication of HK1220945B publication Critical patent/HK1220945B/en

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Description

用于由拉拔生产具有冶金结合的多层管的方法和通过该方法 生产的多层管Method for producing a multilayer tube having a metallurgical bond by drawing and a multilayer tube produced by the method

技术领域Technical Field

本发明涉及一种用于通过至少一个热机械成型步骤而由至少一个内管和一个外管来生产具有冶金结合(metallurgical bond,冶金接合)的多层管的方法。通过该方法生产的管通常具有耐腐蚀层,这使它们能够在高度腐蚀的环境中使用,并且能够使管具有高机械强度。The present invention relates to a method for producing a multilayer tube having a metallurgical bond from at least one inner tube and one outer tube by means of at least one thermomechanical forming step. The tubes produced by this method generally have a corrosion-resistant layer, which enables them to be used in highly corrosive environments and gives them high mechanical strength.

背景技术Background Art

多层管,诸如具有冶金结合(也被称为“复合管(clad pipe,包覆管)”)的管和具有机械结合(也被称为“衬里管(lined pipes)”)的管,以及它们的制造方法是当前工业发展的目标,上述涂层管主要用于石油工业,其中,可能有强机械应力和高腐蚀环境。内部循环流体可促进对管的化学侵蚀,需要使用耐腐蚀合金。Multilayer pipes, such as those with metallurgical bonds (also known as "clad pipes") and mechanical bonds (also known as "lined pipes"), and their production methods are currently the subject of industrial development. These coated pipes are primarily used in the oil industry, where they can be subject to high mechanical stresses and highly corrosive environments. Internally circulating fluids can promote chemical attack on the pipes, necessitating the use of corrosion-resistant alloys.

根据在标准DNV-OS-F101和API 5LD中提供的定义,复合管包括具有耐腐蚀内层的外管,在此在这些材料之间的结合是冶金性的。根据在DNV OS F101和API 5LD中提供的定义,衬里管包括具有耐腐蚀内层的外管,在此在这些材料之间的结合是机械性的。According to the definitions provided in standards DNV-OS-F101 and API 5LD, composite pipe includes an outer pipe with a corrosion-resistant inner layer, where the bond between these materials is metallurgical. According to the definitions provided in DNV OS F101 and API 5LD, lined pipe includes an outer pipe with a corrosion-resistant inner layer, where the bond between these materials is mechanical.

现有技术包含用于制造复合管的几个过程,一般包括:材料预备步骤、可选层步骤和包覆步骤。在大批次生产的工业规模中使用的两个众所周知的过程是通过轧制的包覆和堆焊。The prior art comprises several processes for manufacturing composite pipes, generally comprising: a material preparation step, an optional layer step and a cladding step. Two well-known processes used on an industrial scale for large batch production are cladding by rolling and overlay welding.

在通过板材轧制的包覆过程中,同时进行两种不同材料的板材轧制,上述过程形成一个单一的包覆板材。然后该板材被处理、成型和纵向焊接而形成接缝复合管。In the cladding process by plate rolling, two sheets of different materials are rolled simultaneously to form a single clad sheet. This sheet is then processed, formed and longitudinally welded to form a seamed composite pipe.

在通过堆焊的包覆过程中,材料通过在整个内管表面的角焊缝的沉积物而结合。在角焊缝中使用的材料通常是耐腐蚀合金。焊接沉积过程能够在复合管的内部材料与外部材料之间形成冶金结合。During the cladding process with weld overlay, the materials are bonded together by depositing fillet welds across the entire inner tube surface. The material used in the fillet welds is typically a corrosion-resistant alloy. The weld deposition process creates a metallurgical bond between the inner and outer materials of the composite tube.

文献GB2085330披露了一种生产复合管的方法,该方法包括第一冷拉拔以在内管与外管之间获得良好的机械结合。然后,中间产物在炉子中经历加热步骤,在此两个管结合在一起。随后,中间产物经历热加工步骤以用于通过压制或轧制来成形最终产品。在该文献中,复合管的制造过程进一步包括对在冷拉拔中待接触的表面进行准备的步骤。该步骤包括通过抛光清洁待接触的表面。可替代地,该步骤可包括对接触表面进行喷丸而不是抛光。GB2085330 discloses a method for producing a composite tube. The method includes a first cold drawing step to achieve a good mechanical bond between the inner and outer tubes. The intermediate product then undergoes a heating step in a furnace, where the two tubes are bonded together. Subsequently, the intermediate product undergoes a hot working step to form the final product by pressing or rolling. In this document, the composite tube manufacturing process further includes a step of preparing the surfaces to be contacted during the cold drawing step. This step includes cleaning the surfaces to be contacted by polishing. Alternatively, this step may include shot peening the contact surfaces instead of polishing.

同样根据文献GB2085330,在此在内管与外管之间的热膨胀系数中的差异是大的,结合管的端部被焊接,以防止空气入侵到形成结合管的材料之间,由于空气入侵可影响管的品质。通常,在冷成型和热成型之后,也需要轧制的最后步骤。Also according to document GB2085330, where the difference in thermal expansion coefficient between the inner and outer tubes is large, the ends of the joined tubes are welded to prevent air from entering between the materials forming the joined tubes, which could affect the quality of the tubes. Typically, a final step of rolling is also required after cold forming and hot forming.

文献US3598156披露了一种生产具有接合金属的双金属管件的方法,其在内管与外管之间实现冶金结合。在上述文献描述的过程中,内管的冷膨胀使用渐缩的心轴执行,确保在三个金属层之间的稳固结合。然后,管通过电磁线圈加热,引起内管较高的膨胀系数以比外管扩张更多,在接合中间层上施加大的压力。在没有熔化内管和外管的情况下,该接合层熔化,并且随后它再次凝固,在内管与外管之间形成冶金结合。该文献没有提出后续的热拉拔步骤。US Pat. No. 3,598,156 discloses a method for producing bimetallic pipe fittings with a joining metal that creates a metallurgical bond between the inner and outer tubes. In the process described in this document, cold expansion of the inner tube is performed using a tapered mandrel, ensuring a secure bond between the three metal layers. The tubes are then heated by electromagnetic coils, causing the inner tube's higher coefficient of expansion to expand more than the outer tube, exerting significant pressure on the joining intermediate layer. Without melting the inner and outer tubes, this joining layer melts and subsequently solidifies again, forming a metallurgical bond between the inner and outer tubes. This document does not mention a subsequent hot drawing step.

此外,该文献也披露了在冷拉拔之前,进行了内管的外表面和外管的内表面的化学处理和/或抛光。然而,它没有提出喷丸处理(blasting)这些表面以提高表面的粗糙度和接触力。由于它是复合管,即,两个管以冶金方式结合在一起,不需要增加管之间的结合的机械强度和表面粗糙度,这对衬里管将是重要的。然而,利用该处理也可获得复合产品的改善。Furthermore, this document discloses chemical treatment and/or polishing of the outer and inner surfaces of the inner and outer tubes prior to cold drawing. However, it does not mention shot peening these surfaces to improve surface roughness and contact force. Since this is a composite tube, i.e., two tubes metallurgically bonded together, there is no need to increase the mechanical strength and surface roughness of the bond between the tubes, which would be important for lined tubes. However, improvements in the composite product can be achieved using this treatment.

在现有技术中呈现的复合同心管的方法一直包括预备步骤、成型或沉积焊接材料的步骤(该步骤在管之间形成冶金结合)以及抛光步骤,其一般地是在层压、压制、轧制、挤压或冷拉拔之间的步骤。Methods of composite concentric tubes presented in the prior art have always included preparation steps, steps of forming or depositing the weld material (which forms the metallurgical bond between the tubes), and polishing steps, which are generally between lamination, pressing, rolling, extrusion or cold drawing steps.

现有技术方法没有披露仅在一个成形步骤中生产复合管,而没有抛光步骤。另外,现有技术的方法均没有提出在单一生产线上执行所有步骤而无需将管在步骤之间从一个工作台移动到另一个或将加热的管从炉子内部移动到生产线的可能性,它负担生产的过程和速度以及劳动。现有技术文献均没有披露具有冶金结合的无缝多层管。None of the prior art methods discloses producing composite tubes in a single forming step, without a polishing step. Furthermore, none of the prior art methods suggests the possibility of performing all steps on a single production line without moving the tube from one workstation to another between steps or moving the heated tube from inside the furnace to the production line, which burdens the production process, speed, and labor. None of the prior art documents disclose seamless multi-layer tubes with metallurgical bonds.

发明内容Summary of the Invention

本发明的目的是通过用于由管状元件生产具有冶金结合的多层管的方法来实现,管状元件包括至少一个金属材料的其他管和布置在外管之内的一个金属材料的内管,外管的内表面机械地结合到内管的外表面,该方法包括以下步骤:The object of the present invention is achieved by a method for producing a multilayer tube with metallurgical bonding from a tubular element comprising at least one other tube of metallic material and an inner tube of metallic material arranged inside the outer tube, the inner surface of the outer tube being mechanically bonded to the outer surface of the inner tube, the method comprising the following steps:

在生产线上,管状元件被同时加热和拉拔,其中,管状元件的每个部分经受通过感应的加热,并且然后经受热拉拔,并且其中管状元件利用位于它内部的心轴而被拉拔。On a production line, the tubular element is heated and drawn simultaneously, wherein each portion of the tubular element is subjected to heating by induction and then to hot drawing, and wherein the tubular element is drawn with a mandrel located inside it.

外管包括碳锰钢合金,并且内管包括耐腐蚀合金。The outer tube comprises a carbon-manganese steel alloy, and the inner tube comprises a corrosion-resistant alloy.

优选地,当与电磁线圈交叉时,布置在生产线上的管状元件的每个区段在至少900℃的温度下被加热。同样优选地,在加热和拉拔的步骤中,管状元件被拉而穿过至少一个电磁线圈的内部,在此它被加热到950°与1050℃之间的温度,并且被拉而穿过连续地(sequentially,顺序地)布置在电磁线圈的输出端中的拉拔模,其中,心轴设置在管状元件内并与拉拔模开口对准。Preferably, each section of the tubular element arranged on the production line is heated at a temperature of at least 900° C. when crossing the electromagnetic coil. Also preferably, in the heating and drawing steps, the tubular element is drawn through the interior of at least one electromagnetic coil, where it is heated to a temperature between 950° C. and 1050° C., and is drawn through drawing dies sequentially arranged in the output of the electromagnetic coil, wherein a mandrel is arranged inside the tubular element and aligned with the drawing die opening.

拉拔步骤可包括通过在拉拔模与心轴之间的管状元件的压缩来减小管状元件的壁厚。The drawing step may include reducing the wall thickness of the tubular element by compression of the tubular element between the drawing die and the mandrel.

该方法可在拉拔步骤之后进一步包括至少一个热处理步骤,其中,管状元件经受冷却。也可实施冷拉拔的步骤,内管的内表面和外管的外表面的预先润滑是可选择的,以便提高几何公差和表面光洁度。此外,在拉拔之后可执行管状元件的弯曲的另外的步骤。The method may further include at least one heat treatment step after the drawing step, in which the tubular element is cooled. A cold drawing step may also be performed, with the optional prior lubrication of the inner surface of the inner tube and the outer surface of the outer tube to improve geometric tolerances and surface finish. Furthermore, a further step of bending the tubular element may be performed after the drawing step.

本发明的目的通过具有由在本文中描述的方法生产的冶金结合的多层管实现,多层管包括至少一个金属材料的外管和布置在外管之内的一个金属材料的内管,外管的内表面冶金(metallurgically)结合到内管的外表面,外管由碳锰钢构成,并且内管由耐腐蚀合金构成。The objects of the present invention are achieved by a metallurgically bonded multilayer tube produced by the method described herein, the multilayer tube comprising at least one outer tube of a metallic material and an inner tube of a metallic material arranged within the outer tube, the inner surface of the outer tube being metallurgically bonded to the outer surface of the inner tube, the outer tube being composed of carbon-manganese steel and the inner tube being composed of a corrosion-resistant alloy.

金属材料的内管可由包括碳钢、低合金钢、高合金钢、不锈钢、镍基合金、钛基合金、钴基合金、铜基合金、锡基合金和锆基合金中的至少一种的材料制成。外管和内管优选地是无缝管。The inner tube of the metal material may be made of at least one of carbon steel, low alloy steel, high alloy steel, stainless steel, nickel-based alloy, titanium-based alloy, cobalt-based alloy, copper-based alloy, tin-based alloy and zirconium-based alloy. The outer tube and the inner tube are preferably seamless tubes.

多层管可包括布置在外管与内管之间的至少一个金属材料的中间层。中间层的熔点可低于外管和内管的熔点。中间层可包括镍(Ni)或锆(Zn)。多层管可包括布置到外管的外部的另外的外层,外层由具有内直径大于外管的外直径的第二外管制成,并且冶金结合到外管。外层优选地由耐腐蚀合金、耐磨损合金和耐疲劳合金形成。在多层管中,在外管与内管之间可能达到100%的冶金结合。The multilayer tube may include at least one intermediate layer of a metallic material disposed between the outer tube and the inner tube. The intermediate layer may have a lower melting point than both the outer and inner tubes. The intermediate layer may include nickel (Ni) or zirconium (Zn). The multilayer tube may include an additional outer layer disposed externally of the outer tube, the outer layer being formed from a second outer tube having an inner diameter greater than the outer diameter of the outer tube and metallurgically bonded to the outer tube. The outer layer is preferably formed from a corrosion-resistant alloy, a wear-resistant alloy, and a fatigue-resistant alloy. In the multilayer tube, a 100% metallurgical bond may be achieved between the outer tube and the inner tube.

附图说明BRIEF DESCRIPTION OF THE DRAWINGS

将基于在附图中所示的执行的一实例进一步更详细地描述本发明。附图示出了:The present invention will be further described in more detail based on an example of implementation shown in the accompanying drawings. The drawings show:

图1是用于生产本发明的多层管的方法的热拉拔步骤的第一实施方式的示意图;1 is a schematic diagram of a first embodiment of a hot drawing step of a method for producing a multilayer tube of the present invention;

图2是根据本发明的步骤的框图;FIG2 is a block diagram of the steps according to the present invention;

图3是用于生产本发明的多层管的方法的热拉拔步骤的第二实施方式的示意图;3 is a schematic diagram of a second embodiment of the hot drawing step of the method for producing a multilayer tube of the present invention;

图4是通过本发明的方法生产的机械结合管之间的界面的图片,结合了在管之间的界面中的铁元素和镍元素的浓度的图表;以及FIG4 is a photograph of the interface between mechanically bonded tubes produced by the method of the present invention, combined with a graph of the concentrations of iron and nickel elements in the interface between the tubes; and

图5是通过本发明的方法生产的具有冶金结合的拉拔多层管的实施方式的管之间的界面的图片,结合了管之间的界面中的铁元素和镍元素的浓度的图表。5 is a photograph of the interface between tubes of an embodiment of a metallurgically bonded drawn multilayer tube produced by the method of the present invention, combined with a graph of the concentrations of iron and nickel elements in the interface between the tubes.

具体实施方式DETAILED DESCRIPTION

如可在图1到图5中看出,本发明涉及一种用于从管状元件生产具有冶金结合的多层管1的方法,管状元件包括至少一个金属材料的外管10和一个金属材料20的内管,使得由该方法生产的管是如下的多层管:包括至少一个由外管10制成的外层,外层至少部分地以冶金方式结合到由内管20制成的内层。管状元件可以替代地最初包括多于两个管,形成具有至少部分地以冶金方式结合至彼此的多层的一个管1。As can be seen in Figures 1 to 5, the present invention relates to a method for producing a multilayer tube 1 with metallurgical bonding from a tubular element comprising at least one outer tube 10 of a metallic material and one inner tube of a metallic material 20, such that the tube produced by the method is a multilayer tube comprising at least one outer layer made of the outer tube 10, which is at least partially metallurgically bonded to an inner layer made of the inner tube 20. The tubular element may alternatively initially comprise more than two tubes, forming one tube 1 with multiple layers at least partially metallurgically bonded to one another.

通过该方法生产的多层管可以是复合管,当利用本发明的方法所生产的多层管所包含的多层之间的结合满足标准ASTM A578和API 5LD的最低要求时,即,在管的表面上的任何非包覆区域在以不连续的显示为中心的225mm乘225mm的正方形扫描区域内可不超过25mm的直径。此外,管在距离管的端部的100mm的距离内不应当有任何非包覆区域。根据本发明,复合管可通过根据本发明的方法制造,在外管10与内管20之间的包覆达到100%。The multilayer pipe produced by this method can be a composite pipe when the bonding between the layers of the multilayer pipe produced using the method of the present invention meets the minimum requirements of standards ASTM A578 and API 5LD, namely, any unclad area on the surface of the pipe may not exceed a diameter of 25 mm within a 225 mm by 225 mm square scanned area centered on the discontinuity. Furthermore, the pipe should not have any unclad area within a distance of 100 mm from the end of the pipe. According to the present invention, a composite pipe can be produced using the method of the present invention with 100% cladding between the outer pipe 10 and the inner pipe 20.

构成管状元件的管优选地是无缝管。在这种情况下,通过根据本发明的方法生产的多层管也是无缝的。在本发明的可替代的实施方式中,外管10可以是无缝管,并且内管20可以是焊缝管。The tubes constituting the tubular element are preferably seamless tubes. In this case, the multilayer tube produced by the method according to the invention is also seamless. In an alternative embodiment of the invention, the outer tube 10 can be a seamless tube and the inner tube 20 can be a welded tube.

内管20优选地由耐腐蚀合金(CRA)制成,并且最初布置在外管10内,形成一种用于后者的涂层。内管也可由耐磨损合金(WRA)或耐疲劳合金制成。通常,外管10负责提供最终的多层管机械强度。同样重要的是,外管10的内表面机械地结合到内管20的外表面,使得在两个管之间没有氧气。在管之间的界面处存在氧气可导致氧化物的产生,其形成腐蚀并且可阻碍管之间的良好包覆。包括机械地结合在一起的管的管状元件可被称作衬里管。The inner tube 20 is preferably made of a corrosion-resistant alloy (CRA) and is initially placed inside the outer tube 10, forming a coating for the latter. The inner tube can also be made of a wear-resistant alloy (WRA) or a fatigue-resistant alloy. Generally, the outer tube 10 is responsible for providing the final mechanical strength of the multi-layer tube. It is also important that the inner surface of the outer tube 10 is mechanically bonded to the outer surface of the inner tube 20 so that no oxygen is trapped between the two tubes. The presence of oxygen at the interface between the tubes can lead to the formation of oxides, which form corrosion and can prevent good cladding between the tubes. A tubular element comprising mechanically bonded tubes may be referred to as a liner.

在管之间的机械结合的形成可通过本领域中的任何方法制造,诸如其中的通过机械的膨胀、挤压、冷拉拔、轧制的机械成型步骤。优选地,在管之间的机械结合成型步骤之前,在将要机械地结合在一起的外管10的内表面上和内管20的外表面上执行喷丸处理步骤。这些表面优选地是用钢丸撞击以便增加它们的粗糙度,并且优化材料之间的接触力,从而改善管之间的机械结合。在喷丸处理中的钢丸的使用是有利的,这是因为由于弹丸是由钢制成的,它们不会增加管的表面上的杂质。The mechanical bond between the tubes can be formed by any method known in the art, such as mechanical forming steps such as expansion, extrusion, cold drawing, and rolling. Preferably, prior to the mechanical bond forming step, a shot peening step is performed on the inner surface of the outer tube 10 and the outer surface of the inner tube 20 to be mechanically bonded together. These surfaces are preferably struck with steel shot to increase their roughness and optimize the contact force between the materials, thereby improving the mechanical bond between the tubes. The use of steel shot in the shot peening process is advantageous because, since the shot is made of steel, it does not add impurities to the surface of the tubes.

在图4中可看到在组成根据本发明的产品的实例的衬里管1的外管10与内管20之间的机械结合。该图包含管之间的接合的界面的(未侵蚀)的横截面的显微图片,其中,外管10在左侧以灰色的较暗阴影示出,并且内管20在右侧以灰色的较浅阴影示出。在与上部的较小框对应的区段中的管之间的界面用在它下方的图表中的两个管的材料的浓度来表示。该图表是上述界面区段的放大版本,其中纵坐标以质量百分比表示了每个元素的浓度,并且横坐标表示在垂直于界面的方向上的衬里管中的位置。该图表显示了在衬里管中的管之间的界面区域中的在X方向上的元素铁(Fe)和元素镍(Ni)的浓度。实线表示铁的浓度,根据本发明的一实施方式,铁是外管10的主要成分之一。虚线表示在该界面区域中的镍的浓度,其中,镍是根据本发明的该实施方式的内管20的主要元素。铁和镍的浓度的剧变出现在表示管之间的界面区域的曲线图的相同位置中。这表示在两个管的材料之间没有显著的扩散,使得在它们之间仅有机械结合而没有冶金结合,即,没有包覆。FIG4 illustrates the mechanical bond between the outer tube 10 and inner tube 20 of a lined pipe 1, an example of a product according to the present invention. The figure includes a micrograph of a cross-section (unetched) of the interface between the tubes, with the outer tube 10 shown on the left in a darker shade of gray and the inner tube 20 on the right in a lighter shade of gray. The interface between the tubes in the section corresponding to the upper smaller box is represented by the concentrations of the materials of the two tubes in the graph below it. The graph is an enlarged version of the interface section, with the ordinate indicating the concentration of each element in mass percent and the abscissa indicating the position in the lined pipe perpendicular to the interface. The graph shows the concentrations of the elements iron (Fe) and nickel (Ni) in the X-direction in the interface region between the tubes in the lined pipe. The solid line represents the concentration of iron, one of the main components of the outer tube 10 according to one embodiment of the present invention. The dashed line represents the concentration of nickel in this interface region, with nickel being the main element of the inner tube 20 according to this embodiment of the present invention. The sudden change in the concentration of iron and nickel occurs in the same position of the graph representing the interface area between the tubes. This indicates that there is no significant diffusion between the materials of the two tubes, so that there is only a mechanical bond between them and no metallurgical bond, i.e., no cladding.

图2示出了根据本发明的方法的优选的实施方式的流程图。在管的机械结合之后和在热拉拔之前,本发明的方法优选地包括润滑内管20的内表面(在热拉拔步骤期间它将接触心轴2)和外管10的外表面(在热拉拔步骤期间它将接触拉拔模4)的步骤。该润滑也可在拉拔步骤期间执行。滑润剂11的流动在图1和图3中示出。润滑剂起作用以便减少由拉拔模和心轴接触管状元件而引起的摩擦力。使用的润滑剂11优选地是基于水和石墨的混合物或用于高温工艺的任何润滑剂,如hex-α-BN。该润滑剂具有不改变管的表面化学成分的优点。FIG2 shows a flow chart of a preferred embodiment of the method according to the invention. After the mechanical joining of the tubes and before the hot drawing, the method according to the invention preferably includes a step of lubricating the inner surface of the inner tube 20 (which will contact the mandrel 2 during the hot drawing step) and the outer surface of the outer tube 10 (which will contact the drawing die 4 during the hot drawing step). This lubrication can also be performed during the drawing step. The flow of lubricant 11 is shown in FIG1 and FIG3. The lubricant acts to reduce the friction caused by the contact between the drawing die and the mandrel with the tubular element. The lubricant 11 used is preferably based on a mixture of water and graphite or any lubricant used for high-temperature processes, such as hex-α-BN. This lubricant has the advantage of not changing the surface chemical composition of the tube.

在根据本发明的方法中,使得冶金结合形成在外管10与内管20之间,执行了至少一个热拉拔步骤22,并且加热和拉拔管的步骤在相同的生产线上同时执行。因此,管状元件的每个部分在相同的生产线上经受感应加热,并且随后经受热拉拔。拉拔借助于位于管状元件之内的心轴2发生。In the method according to the present invention, a metallurgical bond is formed between the outer tube 10 and the inner tube 20, at least one hot drawing step 22 is performed, and the steps of heating and drawing the tube are performed simultaneously on the same production line. Thus, each section of the tubular element is subjected to induction heating and subsequently hot drawing on the same production line. Drawing occurs with the aid of a mandrel 2 located within the tubular element.

热拉拔步骤优选地执行1到5次,以从0.1-5.0m/min变化的速度,并且在从800-1300℃改变的温度下执行。The hot drawing step is preferably performed 1 to 5 times, at a speed varying from 0.1-5.0 m/min, and at a temperature varying from 800-1300°C.

由于拉拔模4的开口具有比管状元件小的直径以通过它被拉伸,在拉拔之前,管状元件优选地经受磨尖(pointing)的步骤,其中,管的端部成形以使其外径减小,使得它最初能被拉伸通过拉拔模4的开口。在本发明的优选实施方式中,管状元件的尖端在生产线上或在炉子中加热,并且然后成形以采取用于它的牵引通过拉拔模所需要的直径和尺寸。磨尖也可通过冷锻制造。Since the opening of the drawing die 4 has a smaller diameter than the tubular element to be drawn through it, before drawing, the tubular element is preferably subjected to a step of sharpening (pointing), in which the end of the tube is shaped to reduce its outer diameter so that it can initially be drawn through the opening of the drawing die 4. In a preferred embodiment of the invention, the tip of the tubular element is heated on the production line or in a furnace and then shaped to take on the diameter and size required for its drawing through the drawing die. The sharpening can also be produced by cold forging.

在用于执行热拉拔的加热步骤中,管状元件被拉伸而通过布置在生产线上的至少一个电磁线圈7的内部,使得当与线圈交叉时,每个管区段通过焦耳效应由感应加热,在线圈的出口处达到900℃的最低温度,并且优选地在950℃到1050℃的范围内,这取决于管的几何形状、要产生的长度、使用的材料、应用的减少以及其他方面。During the heating step for performing hot drawing, the tubular element is stretched while passing inside at least one electromagnetic coil 7 arranged on the line, so that when crossing the coil, each tube segment is heated by induction through the Joule effect, reaching a minimum temperature of 900° C. at the exit of the coil, and preferably ranging from 950° C. to 1050° C., depending on the geometry of the tube, the length to be produced, the materials used, the reduction applied and other aspects.

然后,热的管状元件被拉而穿过在相同的生产线上连续地布置在电磁线圈7的输出端中的拉拔模4。当管状元件越过拉拔模4时,心轴2布置在与拉拔模4的开口对准的管状元件的内部。The hot tubular element is then drawn through a drawing die 4 arranged continuously on the same production line in the output of the electromagnetic coil 7. As the tubular element passes the drawing die 4, the mandrel 2 is arranged inside the tubular element aligned with the opening of the drawing die 4.

在拉拔步骤中,管状元件的壁厚可通过在拉拔模4与心轴2之间的管状元件的压缩而降低。管状元件的压缩参数和最终管的厚度可针对要获得的最终产品而调整。如有必要,在根据本发明的方法中,可执行多于一个的冷拉拔或热拉拔步骤,使得管达到所需尺寸。During the drawing step, the wall thickness of the tubular element can be reduced by compressing the tubular element between the drawing die 4 and the mandrel 2. The compression parameters of the tubular element and the thickness of the final tube can be adjusted to the desired end product. If necessary, in the method according to the invention, more than one cold drawing or hot drawing step can be performed to achieve the desired tube dimensions.

在本发明的优选实施方式中,热拉拔步骤在图1中示出的拉拔工作台上执行,其中管状元件的端部通过车辆而在图1中示出的箭头F的方向上被拉伸,引起管状元件穿过电磁线圈7和拉拔模4,其中将心轴2固定至布置在管状元件内的连杆3。心轴2位于拉拔模开口之内,使得管状元件在心轴2与拉拔模4之间穿过。拉拔设备可通过在它的部件之间的水循环12冷却,如在图1和图3中可以看出。In a preferred embodiment of the invention, the hot drawing step is performed on a drawing station shown in FIG1 , wherein the end of the tubular element is stretched in the direction of the arrow F shown in FIG1 by a vehicle, causing the tubular element to pass through an electromagnetic coil 7 and a drawing die 4, wherein a mandrel 2 is fixed to a connecting rod 3 arranged inside the tubular element. The mandrel 2 is located within the drawing die opening, so that the tubular element passes between the mandrel 2 and the drawing die 4. The drawing equipment can be cooled by circulating water 12 between its components, as can be seen in FIG1 and FIG3 .

用于加热管的电磁感应线圈的使用是有利的,因为它在加热期间允许人检验管的均匀温度,并且动态地控制用于适当校正的其他工艺参数,诸如工作台的速度和线圈的功率。此外,使用该线圈加热同时执行拉拔步骤提供了比通过其他加热方法获得的加热速率更高的加热速率。这些高的加热速率防止可能的晶粒生长,如果材料在高温下暴露很长时间,则在常规加热期间可能发生晶粒生长。The use of an electromagnetic induction coil to heat the tube is advantageous because it allows one to verify the uniform temperature of the tube during heating and dynamically control other process parameters, such as the stage speed and coil power, for proper correction. Furthermore, using this coil to heat while performing the drawing step provides higher heating rates than those achieved through other heating methods. These high heating rates prevent possible grain growth, which can occur during conventional heating if the material is exposed to high temperatures for extended periods.

在本发明中实现的通过感应加热的另一个优点是,电磁感应线圈易于安装在生产线上,并且可活动的线圈消除了对处理热管的需要,这对安全具有直接影响,并且也增加了管生产的速度,因为它消除了将管从炉子运送到生产线的需要。此外,通过感应加热消除了燃烧用于在炉子中加热管的燃料气体的需要。Another advantage of induction heating achieved in the present invention is that the electromagnetic induction coil is easy to install on the production line, and the movable coil eliminates the need to handle the hot tube, which has a direct impact on safety and also increases the speed of tube production because it eliminates the need to transport the tube from the furnace to the production line. In addition, induction heating eliminates the need to burn fuel gas used to heat the tube in the furnace.

在热拉拔之后,当需要以特定格式生产弯曲管时,管可经受至少一个弯曲步骤。After hot drawing, the tube may be subjected to at least one bending step when it is desired to produce a bent tube in a specific format.

根据本发明的方法,在加热和热拉拔步骤之后,可进一步包括以调节材料性能为目的热处理步骤。这些热处理步骤取决于可能需要调节的多层管1的机械和冶金特性。一些材料可能在生产步骤期间损失它们的一些机械、冶金和腐蚀性能。因此,可执行这些额外的热处理以便恢复管的机械、冶金和腐蚀性能,例如,当管10和20由X65钢和因科镍合金制成时。在本发明的优选的实施方式中,在热处理步骤中,多层管经受冷却或淬火和回火步骤,这有利于调节管的机械、冶金和腐蚀性能。The method according to the present invention may further include a heat treatment step after the heating and hot drawing steps for the purpose of adjusting material properties. These heat treatment steps depend on the mechanical and metallurgical properties of the multilayer tube 1 that may need to be adjusted. Some materials may lose some of their mechanical, metallurgical, and corrosion properties during the production steps. Therefore, these additional heat treatments may be performed to restore the mechanical, metallurgical, and corrosion properties of the tube, for example, when tubes 10 and 20 are made of X65 steel and Inconel. In a preferred embodiment of the present invention, during the heat treatment step, the multilayer tube undergoes a cooling or quenching and tempering step, which helps adjust the mechanical, metallurgical, and corrosion properties of the tube.

图3示意性示出了本发明的实施方式,其中管的冷却设备8串联布置在拉拔模4的输出端处。冷却的形式是根据所要获得的多层管的最终参数来确定的。Figure 3 schematically shows an embodiment of the invention in which a tube cooling device 8 is arranged in series at the output of the drawing die 4. The form of cooling is determined according to the final parameters of the multilayer tube to be obtained.

冷却可起作用,例如,在衬有难熔材料的工作台上,以保持高温并且允许长时间的扩散,或使用促进强迫对流冷却的工业风扇以提高外管的机械强度并且避免在加工期间的限制。冷却也可仅仅是大气空气或用于调节材料特性的任何其他冷却方式。Cooling can be effected, for example, on a table lined with refractory material to maintain the high temperature and allow a long diffusion period, or using industrial fans promoting forced convection cooling to increase the mechanical strength of the outer tube and avoid confinement during processing. Cooling can also be atmospheric air only or any other cooling method used to adjust the material properties.

冷拉拔的步骤也可在热拉拔之后执行,以便改善几何公差和表面光洁度。如果执行冷拉拔,内管的内表面和外管的外表面的先前润滑也可被实现。否则,从热拉拔步骤剩余的石墨可用作用于减少摩擦的润滑剂。A cold drawing step can also be performed after hot drawing to improve geometric tolerances and surface finish. If cold drawing is performed, prior lubrication of the inner and outer surfaces of the inner and outer tubes can also be achieved. Otherwise, the remaining graphite from the hot drawing step can be used as a lubricant to reduce friction.

重要地,与现有技术方法不同,在拉拔之后,不需要另外的后续轧制步骤。图5包含根据本发明的示例性产品的在多层管之间的接合处的界面的显微横截面图片,在形成冶金结合的最终多层管1的部分中,其中,外管10在左侧以灰色的较暗阴影示出,而内管20在右侧以灰色的较浅阴影示出。内管与外管之间的界面实际上是不复存在的,其表征在管的这些地方的冶金结合。在与上部的较小框对应的区段中的管之间的界面用在它下方的图表中的两个管的材料的浓度来表示。图表是上述界面区段的放大版本,其中纵坐标以质量百分比表示每个元素的浓度,并且横坐标表示在多层管的内部的位置。如在图4中,图表显示出了在形成冶金结合的部分中的管之间的界面区域中沿X方向的元素铁(Fe)和镍(Ni)的浓度。根据本发明的一实施方式,实线表示代表外管10的铁的浓度,并且虚线对应于表示内管20的镍的浓度。应注意,铁和镍的浓度的变化是平滑的,提供扩散区域,在扩散区域中具有两个提到的元素并且从而内管和外管的材料混合。这表示有冶金结合,即,在管之间的包覆(cladding,包层,复合)。较厚的并且更加均匀的扩散区域通常形成更好的包覆。Importantly, unlike prior art methods, no additional subsequent rolling step is required after drawing. Figure 5 contains a microscopic cross-sectional image of the interface at the joint between multilayer tubes of an exemplary product according to the present invention, in a portion of the final multilayer tube 1 that forms a metallurgical bond, wherein the outer tube 10 is shown on the left in a darker shade of gray, while the inner tube 20 is shown on the right in a lighter shade of gray. The interface between the inner and outer tubes is effectively non-existent, characterizing the metallurgical bond at these locations within the tubes. The interface between the tubes in the section corresponding to the upper smaller box is represented by the concentrations of the materials of the two tubes in the graph below it. The graph is an enlarged version of the aforementioned interface section, with the ordinate representing the concentration of each element in mass percent and the abscissa representing the location within the multilayer tube. As in Figure 4, the graph shows the concentrations of the elements iron (Fe) and nickel (Ni) along the X-direction in the interface region between the tubes in the portion that forms the metallurgical bond. According to one embodiment of the present invention, the solid line represents the iron concentration of the outer tube 10, and the dashed line corresponds to the nickel concentration of the inner tube 20. Note that the change in iron and nickel concentrations is smooth, indicating a diffusion zone where the two elements are present and, therefore, the materials of the inner and outer tubes are mixed. This indicates a metallurgical bond, i.e., a cladding, between the tubes. Thicker and more uniform diffusion zones generally result in better cladding.

可替代地,在对管进行冷却之后,可执行管之间的冶金结合的检验步骤,以用于确认包覆出现。检验可能由于切割管的区段而具有破坏性,例如,以90°的间隔切割以检验在所有这些片段中外管和内管是否保持附接。检验也可以是非破坏性的,通过由超声波测试的检查、微观结构的分析、界面的横截面的分析、扫描电子显微镜/能量弥散X射线探测器(SEM/EDX)测试或辉光放电光谱仪(GDOES)测试以及其他方式来检查冶金包覆是否至少在通过根据本发明的方法生产的管的一部分中获得。Alternatively, after the tubes have been cooled, a metallurgical bonding test step may be performed to confirm the presence of cladding. The test may be destructive by cutting sections of the tube, for example, at 90° intervals, to verify that the outer and inner tubes remain attached in all of these sections. The test may also be non-destructive, by inspecting by ultrasonic testing, microstructural analysis, cross-section analysis of the interface, scanning electron microscopy/energy dispersive X-ray detector (SEM/EDX) testing, or glow discharge spectroscopy (GDOES) testing, among other means, to verify that metallurgical cladding has been achieved in at least a portion of the tube produced by the method according to the invention.

当与现有技术的方法比较时,根据本发明的方法具有较高性能,由于它不需要管或内管和外管在制造装置内的任何位移,除了拉拔设备本身以外。并且考虑到方法的简单性和减少步骤的数量,能够在小的周期内生产大量的多层管,估计的生产率高于100m/h。Compared to prior art methods, the method according to the present invention offers superior performance, as it does not require any displacement of the tube, or of the inner and outer tubes, within the manufacturing apparatus, other than the drawing equipment itself. Furthermore, given the simplicity of the method and the reduced number of steps, it is possible to produce large quantities of multilayer tubes in a short cycle time, with an estimated production rate exceeding 100 m/h.

本发明也涉及一种具有通过在本文中描述的方法生产的冶金结合的多层管,至少包括由外管10形成的外层以及由内管20形成的内层,在这两个管之间的界面的至少部分中该外层冶金结合到内层。可替代地,多层管可包括多层,在它们表面的至少一部分中具有在管10的外部和内部的冶金结合,其负责对最终的多层管提供机械强度。这些层优选地由布置在外管10的外面并且经受在本文中描述的热拉拔工艺的无缝管制成。内管20和外管10优选地是无缝的,以便防止生产的多层管在其表面上有接缝。The present invention also relates to a multilayer tube having a metallurgical bond produced by the method described herein, comprising at least an outer layer formed from an outer tube 10 and an inner layer formed from an inner tube 20, the outer layer being metallurgically bonded to the inner layer in at least a portion of the interface between the two tubes. Alternatively, the multilayer tube may comprise multiple layers having metallurgical bonds on the exterior and interior of the tube 10 in at least a portion of their surface, which provide mechanical strength to the resulting multilayer tube. These layers are preferably made of seamless tubes that are arranged on the exterior of the outer tube 10 and subjected to the hot drawing process described herein. The inner tube 20 and the outer tube 10 are preferably seamless to prevent the produced multilayer tube from having seams on its surface.

通常提供机械强度的外管10包括碳锰钢合金,并且内管20包括耐腐蚀合金、耐磨损合金或耐疲劳合金。The outer tube 10 , which generally provides mechanical strength, comprises a carbon-manganese steel alloy, and the inner tube 20 comprises a corrosion-resistant alloy, a wear-resistant alloy, or a fatigue-resistant alloy.

根据本发明的一实施方式,外管10可具有以下化学成分:According to one embodiment of the present invention, the outer tube 10 may have the following chemical composition:

C≤0.30C≤0.30

Mn≤1.40Mn≤1.40

P≤0.030P≤0.030

S≤0.030S≤0.030

Cu≤0.5Cu≤0.5

Cr≤0.5Cr≤0.5

Ni≤0.5Ni≤0.5

Mo≤0.15Mo≤0.15

Nb+V+Ti≤0.15Nb+V+Ti≤0.15

及以下机械性能,在根据本发明的方法之前和之后(YS=屈服强度并且UTS=抗拉强度):and the following mechanical properties, before and after the method according to the invention (YS=yield strength and UTS=tensile strength):

360MPa<YS<830MPa360MPa<YS<830MPa

455MPa<UTS<935MPa455MPa<UTS<935MPa

最小伸长率εmin=15%。Minimum elongation εmin = 15%.

用于内管20的耐腐蚀合金的腐蚀环境对应于国际标准NACE MR0175的环境水平I-VII。The corrosion environment of the corrosion-resistant alloy used for the inner tube 20 corresponds to the environmental levels I to VII of the international standard NACE MR0175.

如以上说明的,耐腐蚀合金(CRA)或耐磨损合金(WRA)或耐疲劳合金的其他管可应用于外管上,组成另外的外层。内管20和/或用于外部包覆的管可由包括碳钢、低合金钢、高合金钢、不锈钢、镍基合金、钛基合金、钴基合金、铜基合金、锡基合金、锆基合金和因科镍合金中至少一种的材料制成。As described above, other tubes of corrosion resistant alloy (CRA) or wear resistant alloy (WRA) or fatigue resistant alloy may be applied to the outer tube to form an additional outer layer. The inner tube 20 and/or the tube for the outer cladding may be made of a material including at least one of carbon steel, low alloy steel, high alloy steel, stainless steel, nickel-based alloy, titanium-based alloy, cobalt-based alloy, copper-based alloy, tin-based alloy, zirconium-based alloy, and Inconel.

在本发明的可替代的实施方式中,在热拉拔之前,管状元件在外管10与内管20之间的界面上包括金属材料的至少一个中间层。该金属材料的中间层的熔点可低于组成外管10和内管20的金属材料的熔点,但是它不是确保管之间的冶金结合的主要成分。因此,在具有热拉拔工艺的该实施方式中,管可被加热至显著低于950℃至1050℃的报告范围的温度。金属材料的中间层也可由对外管10和内管20具有亲合力的材料形成,以便避免可使材料之间界面变弱的有害相位的形成。中间层可包括镍(Ni)、锆(Zn)或其他金属或金属合金。In an alternative embodiment of the present invention, prior to hot drawing, the tubular element includes at least one intermediate layer of metallic material at the interface between the outer tube 10 and the inner tube 20. This intermediate layer of metallic material may have a melting point lower than the melting points of the metallic materials comprising the outer tube 10 and the inner tube 20, but it is not a primary component that ensures a metallurgical bond between the tubes. Therefore, in this embodiment with a hot drawing process, the tubes may be heated to a temperature significantly lower than the reported range of 950°C to 1050°C. The intermediate layer of metallic material may also be formed from a material that has an affinity for the outer tube 10 and the inner tube 20, thereby avoiding the formation of deleterious phases that could weaken the interface between the materials. The intermediate layer may include nickel (Ni), zirconium (Zn), or other metals or metal alloys.

当形成多层管的层之间的结合满足如以上描述的标准ASTM A578和API 5LD的最低要求时,通过该方法生产的多层管是复合管。根据本发明,复合管可在外管10与内管20之间实现高达100%的包覆。The multilayer pipe produced by this method is a composite pipe when the bonding between the layers forming the multilayer pipe meets the minimum requirements of standards ASTM A578 and API 5LD as described above. According to the present invention, the composite pipe can achieve up to 100% cladding between the outer pipe 10 and the inner pipe 20.

通过本发明的方法生产的多层管的尺寸将取决于其应用。根据本发明的一实施方式,管可具有从50.80mm<dext<355.6mm变化的外直径dext,和从5.0mm<WT<30.0mm变化的壁厚WT,其中,用于管线应用的耐腐蚀合金的管的最小壁厚是WTmin-CRA=2.50mm。The dimensions of the multilayer tube produced by the method of the present invention will depend on its application. According to one embodiment of the present invention, the tube may have an outer diameter dext ranging from 50.80 mm < dext < 355.6 mm, and a wall thickness WT ranging from 5.0 mm < WT < 30.0 mm, wherein the minimum wall thickness of a tube of a corrosion-resistant alloy for pipeline applications is WTmin-CRA = 2.50 mm.

当与在根据本发明的生产方法之前的最初组装管相比时,最终管的总变形值如下:When compared to the initially assembled tube prior to the production method according to the invention, the total deformation values of the final tube are as follows:

外径变形:0.1至20%Outer diameter deformation: 0.1 to 20%

壁厚变形:0.1至40%Wall thickness deformation: 0.1 to 40%

壁截面积变形:0.1至40%Wall cross-sectional area deformation: 0.1 to 40%

以上描述的实例表示优选的实施方式;然而,应当理解的是,本发明的范围包括其他可能的变化,并且仅由所附权利要求的内容限制,其包括所有可能的等同物。The examples described above represent preferred embodiments; however, it should be understood that the scope of the present invention encompasses other possible variations and is limited only by the content of the appended claims, which include all possible equivalents.

Claims (15)

1.一种用于由管状元件生产具有冶金结合的多层管(1)的方法,所述管状元件包括金属材料的至少一个外管(10)和布置在所述外管内的金属材料的一个内管(20),在所述外管和所述内管的界面的至少一些部分处,所述外管(10)的内表面机械地结合至所述内管(20)的外表面,其特征在于,所述方法包括以下步骤:1. A method for producing a multilayer tube (1) with metallurgical bonding from a tubular element, said tubular element comprising at least one outer tube (10) of metallic material and an inner tube (20) of metallic material disposed within said outer tube, wherein at least some portions of the interface between said outer tube and said inner tube, the inner surface of said outer tube (10) is mechanically bonded to the outer surface of said inner tube (20), characterized in that the method comprises the following steps: 通过布置金属材料的所述外管(10)和在所述外管内的金属材料的所述内管(20)而形成所述管状元件,并且使所述内管(20)和所述外管(10)经受机械膨胀,由此在所述外管的内表面与所述内管的外表面之间沿着所述管状元件的整个界面产生机械结合;The tubular element is formed by arranging the outer tube (10) of metal material and the inner tube (20) of metal material inside the outer tube, and the inner tube (20) and the outer tube (10) are subjected to mechanical expansion, thereby creating a mechanical bond between the inner surface of the outer tube and the outer surface of the inner tube along the entire interface of the tubular element. 在生产线上,同时加热并拉拔所述管状元件,以使所述管状元件由第一直径变为更小的第二直径,其中,所述管状元件的每个部分经受由感应进行的加热,并且然后经受热拉拔,并且其中所述管状元件利用位于所述管状元件内的心轴而被拉拔,On the production line, the tubular element is simultaneously heated and drawn to change its diameter from a first diameter to a smaller second diameter, wherein each portion of the tubular element is heated by induction and then thermally drawn, and wherein the tubular element is drawn using a mandrel located within the tubular element. 其中在同时加热并拉拔所述管状元件的步骤中,在所述内管的材料与所述外管的材料混合的扩散区域中,在所述外管的内表面与所述内管的外表面之间直接形成冶金结合,In the step of simultaneously heating and drawing the tubular element, a metallurgical bond is directly formed between the inner surface of the outer tube and the outer surface of the inner tube in the diffusion region where the materials of the inner tube and the outer tube are mixed. 其中在同时加热并拉拔的所述步骤之后,所述方法进一步包括强迫对流冷却所述管状元件的步骤。Following the steps of simultaneously heating and drawing, the method further includes a step of forced convection cooling of the tubular element. 2.根据权利要求1所述的方法,其特征在于,所述外管(10)由碳锰钢合金构成,并且所述内管(20)由耐腐蚀合金构成。2. The method according to claim 1, wherein the outer tube (10) is made of carbon manganese steel alloy and the inner tube (20) is made of corrosion-resistant alloy. 3.根据权利要求1或2所述的方法,其特征在于,当与布置在所述生产线上的电磁线圈(7)交叉时,所述管状元件的每个区段在至少900℃温度下被加热。3. The method according to claim 1 or 2, characterized in that each segment of the tubular element is heated at a temperature of at least 900°C when intersecting with an electromagnetic coil (7) arranged on the production line. 4.根据权利要求1或2所述的方法,其特征在于,在所述加热和所述拉拔的步骤中,所述管状元件被拉而穿过至少一个电磁线圈(7)的内部,在此所述管状元件被加热至950℃至1050℃之间的温度,并且所述管状元件被拉而穿过连续地布置在所述电磁线圈(7)的出口处的拉拔模,其中所述心轴(2)设置在所述管状元件内并与拉拔模(4)的开口对准。4. The method according to claim 1 or 2, characterized in that, in the heating and drawing steps, the tubular element is drawn through the interior of at least one electromagnetic coil (7), wherein the tubular element is heated to a temperature between 950°C and 1050°C, and the tubular element is drawn through a drawing die continuously arranged at the outlet of the electromagnetic coil (7), wherein the mandrel (2) is disposed inside the tubular element and aligned with the opening of the drawing die (4). 5.根据权利要求4所述的方法,其特征在于,所述拉拔的步骤包括通过在所述拉拔模(4)与所述心轴(2)之间压缩所述管状元件来减小所述管状元件的壁厚。5. The method according to claim 4, wherein the drawing step comprises reducing the wall thickness of the tubular element by compressing the tubular element between the drawing die (4) and the mandrel (2). 6.根据权利要求1或2所述的方法,其特征在于,在所述热拉拔的步骤之后,所述方法包括:随后的冷拉拔步骤,以及所述内管(20)的内表面与所述外管(10)的外表面的预先润滑步骤。6. The method according to claim 1 or 2, characterized in that, after the hot drawing step, the method includes: a subsequent cold drawing step, and a pre-lubrication step of the inner surface of the inner tube (20) and the outer surface of the outer tube (10). 7.根据权利要求1或2所述的方法,其特征在于,在拉拔之后,所述方法包括所述管状元件的弯曲步骤。7. The method according to claim 1 or 2, characterized in that, after drawing, the method includes a bending step of the tubular element. 8.根据权利要求1或2所述的方法,其特征在于,当生产所述多层管时,将0.1%至20%的外直径变形、0.1%至40%的壁厚变形和0.1%至40%的壁截面积变形一起提供至安装的所述外管和所述内管。8. The method according to claim 1 or 2, characterized in that, when producing the multilayer tube, 0.1% to 20% of the outer diameter deformation, 0.1% to 40% of the wall thickness deformation and 0.1% to 40% of the wall cross-sectional area deformation are provided together to the installed outer tube and the inner tube. 9.一种具有通过根据权利要求1至8中的任一项所述的方法生产的冶金结合的多层管(1),其特征在于,所述多层管包括金属材料的至少一个外管(10)和布置在所述外管内的金属材料的一个内管(20),在所述外管和所述内管的界面的至少一些部分处,所述外管(10)的内表面冶金结合至所述内管(20)的外表面,所述外管(10)由碳锰钢制成,并且所述内管(20)由耐腐蚀合金制成,9. A multilayer tube (1) having a metallurgically bonded structure produced by the method according to any one of claims 1 to 8, characterized in that the multilayer tube comprises at least one outer tube (10) of metallic material and an inner tube (20) of metallic material disposed within the outer tube, wherein at at least some portions of the interface between the outer tube and the inner tube, the inner surface of the outer tube (10) is metallurgically bonded to the outer surface of the inner tube (20), the outer tube (10) being made of carbon manganese steel, and the inner tube (20) being made of a corrosion-resistant alloy. 其中所述多层管包括在所述内管的材料与所述外管的材料混合的扩散区域中的所述外管的内表面与所述内管的外表面之间的冶金结合。The multilayer tube includes a metallurgical bond between the inner surface of the outer tube and the outer surface of the inner tube in a diffusion region where the materials of the inner tube and the outer tube are mixed. 10.根据权利要求9所述的多层管(1),其特征在于,金属材料的所述内管(20)由包括碳钢、低合金钢、高合金钢、不锈钢、镍基合金、钛基合金、钴基合金、铜基合金、锡基合金、锆基合金和中的至少一种材料制成。10. The multilayer tube (1) according to claim 9, characterized in that the inner tube (20) of the metal material is made of at least one material including carbon steel, low alloy steel, high alloy steel, stainless steel, nickel-based alloy, titanium-based alloy, cobalt-based alloy, copper-based alloy, tin-based alloy, zirconium-based alloy and. 11.根据权利要求9或10所述的多层管(1),其特征在于,所述外管(10)和所述内管(20)是无缝管。11. The multilayer tube (1) according to claim 9 or 10, characterized in that the outer tube (10) and the inner tube (20) are seamless tubes. 12.根据权利要求9或10所述的多层管(1),其特征在于,所述外管(10)是无缝管,并且所述内管(20)具有焊缝。12. The multilayer tube (1) according to claim 9 or 10, characterized in that the outer tube (10) is a seamless tube and the inner tube (20) has a weld. 13.根据权利要求9或10所述的多层管(1),其特征在于,所述多层管进一步包括外层,所述外层布置在所述外管的外部,所述外层由第二外管制成,所述第二外管的内直径大于所述外管(10)的外直径,并且所述外层冶金结合至所述外管(10)。13. The multilayer tube (1) according to claim 9 or 10, characterized in that the multilayer tube further includes an outer layer disposed outside the outer tube, the outer layer being made of a second outer tube having an inner diameter greater than the outer diameter of the outer tube (10), and the outer layer being metallurgically bonded to the outer tube (10). 14.根据权利要求13所述的多层管(1),其特征在于,所述外层由耐腐蚀合金、耐磨损合金和耐疲劳合金中的一种构成。14. The multilayer tube (1) according to claim 13, wherein the outer layer is composed of one of a corrosion-resistant alloy, a wear-resistant alloy, and a fatigue-resistant alloy. 15.根据权利要求9或10所述的多层管(1),其特征在于,在所述外管(10)与所述内管(20)之间达到100%的冶金结合。15. The multilayer tube (1) according to claim 9 or 10, characterized in that 100% metallurgical bonding is achieved between the outer tube (10) and the inner tube (20).
HK16109048.5A 2013-08-23 2014-07-23 Process for producing a multilayer pipe having a metallurgical bond by drawing, and multilayer pipe produced by this process HK1220945B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
BR102013021664-0A BR102013021664B1 (en) 2013-08-23 2013-08-23 process for production of clad tube by drawing and clad tube
BR1020130216640 2013-08-23
PCT/BR2014/000249 WO2014169366A2 (en) 2013-08-23 2014-07-23 Process for producing a multilayer pipe having a metallurgical bond by drawing, and multilayer pipe produced by this process

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HK1220945A1 HK1220945A1 (en) 2017-05-19
HK1220945B true HK1220945B (en) 2021-05-28

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