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HK1261530B - Optical filter - Google Patents

Optical filter

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Publication number
HK1261530B
HK1261530B HK19121370.1A HK19121370A HK1261530B HK 1261530 B HK1261530 B HK 1261530B HK 19121370 A HK19121370 A HK 19121370A HK 1261530 B HK1261530 B HK 1261530B
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Hong Kong
Prior art keywords
refractive index
approximately
spectral range
layers
optical
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HK19121370.1A
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Chinese (zh)
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HK1261530A1 (en
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詹姆斯·斯维泽三世
乔治·J·欧肯法斯
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唯亚威通讯技术有限公司
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Publication of HK1261530A1 publication Critical patent/HK1261530A1/en
Publication of HK1261530B publication Critical patent/HK1261530B/en

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Description

光学滤波器Optical filters

背景background

可以利用光学传感器设备来捕获信息。例如,光学传感器设备可以捕获与一组电磁频率有关的信息。光学传感器设备可以包括捕获信息的一组传感器元件(例如,光学传感器、光谱传感器和/或图像传感器)。例如,传感器元件阵列可用于捕获与多个频率有关的信息。在一个示例中,传感器元件阵列可用于捕获关于特定光谱范围(例如从大约1100纳米(nm)到大约2000nm的光谱范围、具有大约1550nm的中心波长的另一光谱范围等)的信息。传感器元件阵列中的传感器元件可以与滤波器相关联。滤波器可以包括与传递到传感器元件的第一光谱范围的光相关联的通带。滤波器可以与阻挡第二光谱范围的光被传递到传感器元件相关联。Optical sensor devices can be used to capture information. For example, an optical sensor device can capture information related to a set of electromagnetic frequencies. The optical sensor device can include a set of sensor elements (e.g., optical sensors, spectral sensors, and/or image sensors) that capture information. For example, an array of sensor elements can be used to capture information related to multiple frequencies. In one example, the array of sensor elements can be used to capture information about a specific spectral range (e.g., a spectral range from approximately 1100 nanometers (nm) to approximately 2000 nm, another spectral range with a center wavelength of approximately 1550 nm, etc.). The sensor elements in the sensor element array can be associated with a filter. The filter can include a passband associated with light of a first spectral range that is transmitted to the sensor element. The filter can be associated with a filter that blocks light of a second spectral range from being transmitted to the sensor element.

概述Overview

(1)一种带通滤波器,可以包括一组层。该一组层可以包括第一子集层。第一子集层可以包括具有第一折射率的氢化锗(Ge:H)。该一组层可以包括第二子集层。第二子集层可以包括具有第二折射率的材料。第二折射率可以小于第一折射率。(1) A bandpass filter may include a set of layers. The set of layers may include a first subset of layers. The first subset of layers may include germanium hydride (Ge:H) having a first refractive index. The set of layers may include a second subset of layers. The second subset of layers may include a material having a second refractive index. The second refractive index may be less than the first refractive index.

(2)如(1)所述的带通滤波器,其中,所述材料包括以下中的至少一种:二氧化硅(SiO2)材料,氧化铝(Al2O3)材料,二氧化钛(TiO2)材料,五氧化二铌(Nb2O5)材料,五氧化二钽(Ta2O5)材料,或氟化镁(MgF2)材料。(2) The bandpass filter as described in (1), wherein the material includes at least one of the following: silicon dioxide (SiO 2 ) material, aluminum oxide (Al 2 O 3 ) material, titanium dioxide (TiO 2 ) material, niobium pentoxide (Nb 2 O 5 ) material, tantalum pentoxide (Ta 2 O 5 ) material, or magnesium fluoride (MgF 2 ) material.

(3)如(1)所述的带通滤波器,其中,所述第一子集层是高折射率层(H),并且所述第二子集层是低折射率层(L);以及其中,所述一组层以下列项中的至少一项进行布置:(H-L)m阶,(H-L)m-H阶,(L-H)m阶,或L-(H-L)m阶,其中,m是交替的H层和L层的数量。(3) The bandpass filter of (1), wherein the first subset of layers is a high refractive index layer (H) and the second subset of layers is a low refractive index layer (L); and wherein the set of layers is arranged in at least one of the following: (HL) m order, (HL) m -H order, (LH) m order, or L-(HL) m order, where m is the number of alternating H and L layers.

(4)如(1)所述的带通滤波器,其中,所述一组层被配置为使与在大约1100纳米(nm)至2000nm之间的光谱范围相关联的阈值部分的光通过。(4) The bandpass filter of (1), wherein the set of layers is configured to pass light in a threshold portion associated with a spectral range between approximately 1100 nanometers (nm) and 2000 nm.

(5)如(1)所述的带通滤波器,其中,所述一组层被配置为使与在大约1400纳米(nm)至2000nm之间的光谱范围相关联的阈值部分的光通过。(5) The bandpass filter of (1), wherein the set of layers is configured to pass light in a threshold portion associated with a spectral range between approximately 1400 nanometers (nm) and 2000 nm.

(6)如(1)所述的带通滤波器,其中,所述一组层被配置为使与具有大约1550纳米的中心波长的光谱范围相关联的阈值部分的光通过。(6) The bandpass filter of (1), wherein the set of layers is configured to pass light in a threshold portion associated with a spectral range having a center wavelength of approximately 1550 nanometers.

(7)如(1)所述的带通滤波器,其中,在大约1550纳米的波长下,所述第一折射率大于大约3.8。(7) The bandpass filter of (1), wherein the first refractive index is greater than about 3.8 at a wavelength of about 1550 nanometers.

(8)如(1)所述的带通滤波器,其中,在大约1550纳米的波长下,所述第一折射率大约为4.2。(8) The bandpass filter according to (1), wherein the first refractive index is approximately 4.2 at a wavelength of approximately 1550 nanometers.

(9)如(1)所述的带通滤波器,其中,所述第一子集层与在特定光谱范围处小于大约0.01的消光系数相关联。(9) The bandpass filter of (1), wherein the first subset of layers is associated with an extinction coefficient of less than about 0.01 at a particular spectral range.

(10)如(1)所述的带通滤波器,其中,在大约1100纳米(nm)至大约2000nm的光谱范围处,所述第二折射率小于3。(10) The bandpass filter of (1), wherein the second refractive index is less than 3 in a spectral range of about 1100 nanometers (nm) to about 2000 nm.

(11)如(1)所述的带通滤波器,其中,对于从0度到40度的入射角,光谱范围的中心波长的变化小于40纳米。(11) The bandpass filter of (1), wherein the center wavelength of the spectral range varies by less than 40 nanometers for angles of incidence ranging from 0 degrees to 40 degrees.

(12)如(1)所述的带通滤波器,其中,对于从0度到40度的入射角,光谱范围的中心波长的变化小于30纳米。(12) The bandpass filter of (1), wherein the center wavelength of the spectral range varies by less than 30 nanometers for angles of incidence ranging from 0 degrees to 40 degrees.

(13)如(1)所述的带通滤波器,其中,对于从0度到30度的入射角,光谱范围的中心波长的变化小于20纳米。(13) The bandpass filter of (1), wherein the center wavelength of the spectral range varies by less than 20 nanometers for angles of incidence ranging from 0 degrees to 30 degrees.

(14)如(1)所述的带通滤波器,其中,对于从0度到20度的入射角,光谱范围的中心波长的变化小于10纳米。(14) The bandpass filter of (1), wherein the center wavelength of the spectral range varies by less than 10 nanometers for angles of incidence ranging from 0 degrees to 20 degrees.

(15)一种光学滤波器,可以包括基底。光学滤波器可以包括设置在基底上的一组交替的高折射率层和低折射率层,以对入射光进行滤波。光学滤波器可以被配置成使入射光中的在具有大约1550纳米(nm)的中心波长的光谱范围内的第一部分通过,并且反射入射光的不在该光谱范围内的第二部分。高折射率层可以是氢化锗(Ge:H)。低折射率层可以是二氧化硅(SiO2)。(15) An optical filter may include a substrate. The optical filter may include a set of alternating high refractive index layers and low refractive index layers disposed on the substrate to filter incident light. The optical filter may be configured to pass a first portion of the incident light within a spectral range having a center wavelength of approximately 1550 nanometers (nm) and reflect a second portion of the incident light that is not within the spectral range. The high refractive index layer may be germanium hydride (Ge:H). The low refractive index layer may be silicon dioxide (SiO 2 ).

(16)如(15)所述的光学滤波器,其中,使用溅射过程沉积所述高折射率层。(16) The optical filter according to (15), wherein the high refractive index layer is deposited using a sputtering process.

(17)如(15)所述的光学滤波器,其中,所述高折射率层被退火。(17) The optical filter according to (15), wherein the high refractive index layer is annealed.

(18)一种光学系统,可以包括光学滤波器,该光学滤波器被配置为对输入光信号进行滤波并提供滤波后的输入光信号。输入光信号可以包括来自第一光源的光和来自第二光源的光。光学滤波器可以包括一组介电薄膜层。该一组介电薄膜层可包括具有第一折射率的氢化锗的第一子集层。该一组介电薄膜层可以包括具有小于第一折射率的第二折射率的材料的第二子集层。滤波后的输入光信号可包括来自第二光源的相对于输入光信号强度减小的光。光学系统可以包括光学传感器,该光学传感器被配置为接收滤波后的输入光学信号并提供输出电信号。(18) An optical system may include an optical filter configured to filter an input optical signal and provide a filtered input optical signal. The input optical signal may include light from a first light source and light from a second light source. The optical filter may include a set of dielectric thin film layers. The set of dielectric thin film layers may include a first subset of layers of germanium hydride having a first refractive index. The set of dielectric thin film layers may include a second subset of layers of a material having a second refractive index less than the first refractive index. The filtered input optical signal may include light from the second light source having a reduced intensity relative to the input optical signal. The optical system may include an optical sensor configured to receive the filtered input optical signal and provide an output electrical signal.

(19)如(18)所述的光学系统,其中,所述光学滤波器设置在所述光学传感器的传感器元件阵列上。(19) The optical system according to (18), wherein the optical filter is provided on a sensor element array of the optical sensor.

(20)如(18)所述的光学系统,其中,所述光学滤波器与所述光学传感器分离了自由空间。(20) The optical system according to (18), wherein the optical filter is separated from the optical sensor by a free space.

附图说明BRIEF DESCRIPTION OF THE DRAWINGS

图1A-1C是本文描述的示例实施方式的概览图;1A-1C are overview diagrams of example implementations described herein;

图2是本文描述的基于氢化锗的光学滤波器的图;FIG2 is a diagram of a germanium hydride-based optical filter described herein;

图3是用于制造本文描述的基于氢化锗的光学滤波器的系统的图;FIG3 is a diagram of a system for fabricating the germanium hydride-based optical filters described herein;

图4A-4D是与本文描述的基于氢化锗的光学滤波器相关的特性的图;以及4A-4D are graphs of characteristics associated with germanium hydride-based optical filters described herein; and

图5A-5C是与本文描述的基于氢化锗的光学滤波器相关的特性的图。5A-5C are graphs of characteristics associated with germanium hydride-based optical filters described herein.

详细描述Detailed description

以下示例实施方式的详细描述参考了附图。不同附图中的相同附图标记可以标识相同或相似的元素。The following detailed description of example embodiments refers to the accompanying drawings, in which the same reference numerals in different drawings may identify the same or similar elements.

光学传感器设备可以包括传感器元件组成的传感器元件阵列,以接收从诸如光发射器、灯泡、环境光源等光源发起的光。光学传感器设备可利用一种或更多种传感器技术,例如互补金属氧化物半导体(CMOS)技术、电荷耦合器件(CCD)技术等。光学传感器设备的传感器元件(例如,光学传感器)可以获得关于一组电磁频率的信息(例如,光谱数据)。传感器元件可以是基于砷化铟镓(InGaAs)的传感器元件、基于锗化硅(SiGe)的传感器元件等。An optical sensor device may include an array of sensor elements configured to receive light originating from a light source, such as a light emitter, a light bulb, or an ambient light source. The optical sensor device may utilize one or more sensor technologies, such as complementary metal oxide semiconductor (CMOS) technology, charge coupled device (CCD) technology, or the like. The sensor elements (e.g., optical sensors) of the optical sensor device may obtain information (e.g., spectral data) about a set of electromagnetic frequencies. The sensor elements may be indium gallium arsenide (InGaAs)-based sensor elements, silicon germanium (SiGe)-based sensor elements, or the like.

传感器元件可以与滤波器相关联,该滤波器对到传感器元件的光进行滤波,以使传感器元件能够获得关于特定光谱范围的电磁频率的信息。例如,传感器元件可以与具有在以下光谱范围中的通带的滤波器对准以使得导向传感器元件的一部分光被滤波:大约1100纳米(nm)至大约2000nm的光谱范围、大约1500nm至大约1600nm的光谱范围、具有大约1550nm的中心波长的光谱范围等。滤波器可以包括多组介电层,以滤波该部分光。例如,滤波器可以包括交替的高折射率层和低折射率层的介电滤波器叠层,例如作为高折射率材料的氢化硅(Si:H或SiH)或锗(Ge)和作为低折射率材料的二氧化硅(SiO2)的交替层。然而,使用氢化硅作为与具有约1550nm的中心波长的光谱范围相关联的滤波器的高折射率材料可能导致过度的角度偏移(例如,大于阈值的角度偏移)。此外,使用锗作为高折射率材料可导致小于以大约1550nm为中心的通带的阈值透射率,例如小于在大约1550nm的波长下大约20%的透射率。The sensor element can be associated with a filter that filters light directed to the sensor element so that the sensor element can obtain information about electromagnetic frequencies within a specific spectral range. For example, the sensor element can be aligned with a filter having a passband within the following spectral ranges: a spectral range of approximately 1100 nanometers (nm) to approximately 2000 nm, a spectral range of approximately 1500 nm to approximately 1600 nm, a spectral range with a center wavelength of approximately 1550 nm, etc., so that a portion of the light directed to the sensor element is filtered. The filter can include multiple sets of dielectric layers to filter the portion of light. For example, the filter can include a dielectric filter stack of alternating high and low refractive index layers, such as alternating layers of hydrogenated silicon (Si:H or SiH) or germanium (Ge) as the high refractive index material and silicon dioxide (SiO 2 ) as the low refractive index material. However, using hydrogenated silicon as the high refractive index material for a filter associated with a spectral range with a center wavelength of approximately 1550 nm can result in excessive angular shift (e.g., angular shift greater than a threshold value). Furthermore, using germanium as the high refractive index material may result in less than a threshold transmittance for a passband centered around approximately 1550 nm, such as less than approximately 20% transmittance at a wavelength of approximately 1550 nm.

本文描述的一些实施方式提供了以氢化锗(Ge:H或GeH)作为高折射率材料的光学滤波器,从而导致小于阈值的角度偏移。例如,光学滤波器可以包括一层或更多层氢化锗或退火的氢化锗和一层或更多层二氧化硅,以对于以大约1550nm的波长为中心的通带,在45度的入射角时提供小于大约100nm的角度偏移,在30度的入射角时提供小于大约30nm的角度偏移,在15度的入射角时提供小于大约10nm的角度偏移,等等。此外,使用氢化锗和/或退火的氢化锗的光学滤波器可以为以大约1550nm为中心的通带提供大于阈值水平的透射率,例如大于大约40%、大于大约80%、大于大约85%等的透射率。以这种方式,本文描述的一些实施方式以小于阈值的角度偏移且大于阈值水平的透射率对光进行滤波。Some embodiments described herein provide optical filters using germanium hydride (Ge:H or GeH) as a high refractive index material, resulting in an angular shift less than a threshold value. For example, the optical filter can include one or more layers of germanium hydride or annealed germanium hydride and one or more layers of silicon dioxide to provide an angular shift of less than about 100 nm at an incident angle of 45 degrees, an angular shift of less than about 30 nm at an incident angle of 30 degrees, an angular shift of less than about 10 nm at an incident angle of 15 degrees, and so on, for a passband centered around a wavelength of about 1550 nm. In addition, optical filters using germanium hydride and/or annealed germanium hydride can provide a transmittance greater than a threshold level, such as a transmittance greater than about 40%, greater than about 80%, greater than about 85%, and so on, for a passband centered around about 1550 nm. In this manner, some embodiments described herein filter light with an angular shift less than a threshold value and a transmittance greater than a threshold value.

图1A-1C是本文描述的实施方式100/100’/100”的概览图。如图1A所示,示例实施方式100包括传感器系统110。传感器系统110可以是光学系统的一部分,并且可以提供与传感器决定相对应的电输出。传感器系统110包括光学滤波器结构120和光学传感器140,光学滤波器结构120包括光学滤波器130。例如,光学滤波器结构120可以包括执行通带滤波功能的光学滤波器130。在另一示例中,光学滤波器130可以与光学传感器140的传感器元件阵列对准。1A-1C are overview diagrams of embodiments 100/100'/100" described herein. As shown in FIG1A , example embodiment 100 includes a sensor system 110. Sensor system 110 can be part of an optical system and can provide an electrical output corresponding to a sensor determination. Sensor system 110 includes an optical filter structure 120 and an optical sensor 140, where optical filter structure 120 includes an optical filter 130. For example, optical filter structure 120 can include optical filter 130 that performs a passband filtering function. In another example, optical filter 130 can be aligned with an array of sensor elements of optical sensor 140.

尽管本文描述的一些实施方式可能是就传感器系统中的光学滤波器而言的,但是本文描述的实施方式可以在另一种类型的系统中使用,可以在传感器系统的外部使用,等等。Although some embodiments described herein may be in the context of an optical filter in a sensor system, the embodiments described herein can be used in another type of system, can be used external to a sensor system, and so on.

如图1A进一步所示,并且通过附图标记150,输入光信号被导向光学滤波器结构120。输入光信号可以包括但不限于与特定光谱范围(例如,以大约1550nm为中心的光谱范围)相关联的光,例如1500nm至1600nm的光谱范围、1100nm至2000nm的光谱范围等。例如,光发射器可以将光导向光学传感器140,以允许光学传感器140执行对光的测量。在另一示例中,光发射器可以针对另一功能来引导另一光谱范围的光,例如针对测试功能、感测功能、通信功能等。As further shown in FIG1A and indicated by reference numeral 150, an input optical signal is directed to the optical filter structure 120. The input optical signal may include, but is not limited to, light associated with a particular spectral range (e.g., a spectral range centered around approximately 1550 nm), such as a spectral range of 1500 nm to 1600 nm, a spectral range of 1100 nm to 2000 nm, and the like. For example, the light emitter may direct the light to the optical sensor 140 to allow the optical sensor 140 to perform measurements of the light. In another example, the light emitter may direct light of another spectral range for another function, such as a testing function, a sensing function, a communication function, and the like.

如图1A进一步所示,并且通过附图标记160,具有第一光谱范围的光信号的第一部分不被传递通过光学滤波器130和光学滤波器结构120。例如,可包括光学滤波器130的高折射率材料层和低折射率材料层的介电薄膜层的介电滤波器叠层可使得第一部分的光在第一方向上被反射、被吸收等。在这种情况下,第一部分的光可以是入射到光学滤波器130上的不包括在光学滤波器130的通频带中的阈值部分的光,例如不在以大约1550nm为中心的特定光谱范围内的大于95%的光。如附图标记170所示,光信号的第二部分被传递通过光学滤波器130和光学滤波器结构120。例如,光学滤波器130可以沿着朝向光学传感器140的第二方向使具有第二光谱范围的第二部分的光通过。在这种情况下,第二部分的光可以是在光学滤波器130的通频带内的入射到光学滤波器130上的阈值部分的光,例如在以大约1550nm为中心的光谱范围内的大于50%的入射光。As further shown in FIG1A and indicated by reference numeral 160, a first portion of the optical signal having a first spectral range is not passed through optical filter 130 and optical filter structure 120. For example, a dielectric filter stack, which may include dielectric thin film layers of high refractive index material and low refractive index material layers of optical filter 130, may cause the first portion of light to be reflected, absorbed, or the like in a first direction. In this case, the first portion of light may be a threshold portion of light incident on optical filter 130 that is not included in the passband of optical filter 130, such as greater than 95% of light that is not within a particular spectral range centered around approximately 1550 nm. As indicated by reference numeral 170, a second portion of the optical signal is passed through optical filter 130 and optical filter structure 120. For example, optical filter 130 may pass a second portion of light having a second spectral range in a second direction toward optical sensor 140. In this case, the second portion of light may be a threshold portion of light incident on optical filter 130 that is within the passband of optical filter 130, such as greater than 50% of light that is incident on optical filter 130 within the spectral range centered around approximately 1550 nm.

如图1A进一步所示,基于被传递到光学传感器140的光信号的第二部分,光学传感器140可以为传感器系统110提供输出电信号180,例如用于成像、环境光感测、检测物体的存在、执行测量、促进通信等。在一些实施方式中,可以使用光学滤波器130和光学传感器140的另外的布置。例如,光学滤波器130可将光信号的第二部分沿另一方向导向不同位置的光学传感器140,而不是与输入光信号共线地使光信号的第二部分通过。1A , based on the second portion of the light signal passed to the optical sensor 140, the optical sensor 140 can provide an output electrical signal 180 to the sensor system 110, for example, for imaging, ambient light sensing, detecting the presence of an object, performing measurements, facilitating communications, etc. In some embodiments, alternative arrangements of the optical filter 130 and the optical sensor 140 can be used. For example, instead of passing the second portion of the light signal in-line with the input light signal, the optical filter 130 can direct the second portion of the light signal in another direction to a differently located optical sensor 140.

如图1B所示,另一实施方式100’包括形成光学传感器140并集成到光学滤波器结构120的基底中的传感器元件阵列的一组传感器元件。在这种情况下,光学滤波器130直接设置在基底上。输入光信号150-1和150-2以多个不同角度被接收,并且输入光信号150-1和150-2的第一部分160-1和160-2以多个不同角度被反射。在这种情况下,输入光信号150-1和150-2的第二部分被传递通过光学滤波器130到达形成光学传感器140的传感器元件阵列,光学传感器140提供输出电信号180。As shown in FIG1B , another embodiment 100′ includes a set of sensor elements forming an array of sensor elements integrated into a substrate of an optical filter structure 120. In this case, the optical filter 130 is disposed directly on the substrate. Input light signals 150-1 and 150-2 are received at a plurality of different angles, and first portions 160-1 and 160-2 of the input light signals 150-1 and 150-2 are reflected at a plurality of different angles. In this case, second portions of the input light signals 150-1 and 150-2 are transmitted through the optical filter 130 to the array of sensor elements forming the optical sensor 140, which provides an output electrical signal 180.

如图1C所示,另一实施方式100”包括形成光学传感器140并且与光学滤波器结构120分离(例如,分离了在自由空间光学类型的光学系统中的自由空间)的传感器元件阵列的一组传感器元件。在这种情况下,光学滤波器130设置在光学滤波器结构120上。输入光信号150-1和150-2在光学滤波器130处以多个不同角度被接收。输入光信号150-1和150-2的第一部分160-1和160-2被反射,并且输入光信号150-1和150-2的第二部分170-1和170-2被传递通过光学滤波器130和光学滤波器结构120。基于接收到第二部分170-1和170-2,传感器元件阵列提供输出电信号180。As shown in FIG. 1C , another embodiment 100 ″ includes a set of sensor elements forming an array of sensor elements of an optical sensor 140 and separated from an optical filter structure 120 (e.g., separated from free space in an optical system of the free-space optics type). In this case, an optical filter 130 is disposed on the optical filter structure 120. Input optical signals 150-1 and 150-2 are received at the optical filter 130 at a plurality of different angles. First portions 160-1 and 160-2 of the input optical signals 150-1 and 150-2 are reflected, and second portions 170-1 and 170-2 of the input optical signals 150-1 and 150-2 are passed through the optical filter 130 and the optical filter structure 120. Based on receiving the second portions 170-1 and 170-2, the sensor element array provides an output electrical signal 180.

如上所述,图1A-1C仅作为示例提供。其它示例是可能的,并且可以不同于关于图1A-1C描述的示例。As mentioned above, Figures 1A-1C are provided as examples only. Other examples are possible and may differ from the examples described with respect to Figures 1A-1C.

图2是示例性光学滤波器200的示图。图2示出了使用氢化锗作为高折射率材料的光学滤波器的示例叠层。如图2进一步所示,光学滤波器200包括光学滤波器涂层部分210和基底220。FIG2 is a diagram of an exemplary optical filter 200. FIG2 shows an example stack of optical filters using germanium hydride as a high refractive index material. As further shown in FIG2, the optical filter 200 includes an optical filter coating portion 210 and a substrate 220.

光学滤波器涂层部分210包括一组光学滤波器层。例如,光学滤波器涂层部分210包括第一组层230-1至230-N(N≥1)(例如,高折射率层(H层))和第二组层240-1至240-(N+1)(例如,低折射率层(L层))。在一些实施方式中,层230和240可以以特定顺序排列,例如(H-L)m(m≥1)顺序、(H-L)m-H顺序、(L-H)m顺序、L-(H-L)m顺序等。例如,如图所示,层230和240以(H-L)n-H的顺序设置,其中H层设置在光学滤波器200的表面处,并且H层紧邻基底220的表面。在一些实施方式中,光学滤波器200中可以包括一个或更多个其他层,例如一个或更多个保护层、提供一个或更多个其他滤波功能(例如,阻断剂、抗反射涂层等)的一个或更多个层,等。The optical filter coating portion 210 includes a set of optical filter layers. For example, the optical filter coating portion 210 includes a first set of layers 230-1 to 230-N (N ≥ 1) (e.g., high refractive index layers (H layers)) and a second set of layers 240-1 to 240-(N+1) (e.g., low refractive index layers (L layers)). In some embodiments, the layers 230 and 240 can be arranged in a specific order, such as a (HL) m (m ≥ 1) order, a (HL) m -H order, a (LH) m order, an L-(HL) m order, etc. For example, as shown, the layers 230 and 240 are arranged in a (HL) n -H order, where the H layer is disposed at the surface of the optical filter 200 and is immediately adjacent to the surface of the substrate 220. In some embodiments, the optical filter 200 may include one or more other layers, such as one or more protective layers, one or more layers providing one or more other filtering functions (e.g., a blocker, an anti-reflection coating, etc.), etc.

层230可以包括一组氢化锗层。在一些实施方式中,可将另一种材料用于H层,例如在特定光谱范围(例如,约1100nm至约2000nm的光谱范围、约1400nm至约1600nm的光谱范围、约1550nm的波长等)上折射率大于L层的折射率、折射率大于2.0、折射率大于3.0、折射率大于4.0、折射率大于4.5、折射率大于4.6等的另一种材料。在另一示例中,层230可被选择以包括在约1550nm的波长下约4.2的折射率。Layer 230 may include a set of germanium hydride layers. In some embodiments, another material may be used for the H layer, such as another material having a refractive index greater than that of the L layer, a refractive index greater than 2.0, a refractive index greater than 3.0, a refractive index greater than 4.0, a refractive index greater than 4.5, a refractive index greater than 4.6, etc., over a specific spectral range (e.g., a spectral range of about 1100 nm to about 2000 nm, a spectral range of about 1400 nm to about 1600 nm, a wavelength of about 1550 nm, etc.). In another example, layer 230 may be selected to include a refractive index of approximately 4.2 at a wavelength of approximately 1550 nm.

在一些实施方式中,可以为H层230选择特定的基于氢化锗的材料,例如氢化锗、退火的氢化锗等。在一些实施方式中,层230和/或240可与在特定光谱范围(例如,约800nm至约2300nm的光谱范围,约1100nm至约2000nm的光谱范围,约1550nm的波长等)上的特定消光系数(例如在约1550nm处小于约0.1、小于约0.05、小于约0.01、小于约0.005的消光系数、小于约0.001的消光系数、小于约0.0008的消光系数等)相关联。In some embodiments, a specific germanium hydride-based material, such as germanium hydride, annealed germanium hydride, etc., can be selected for the H layer 230. In some embodiments, layers 230 and/or 240 can be associated with a specific extinction coefficient (e.g., an extinction coefficient of less than about 0.1, less than about 0.05, less than about 0.01, less than about 0.005, less than about 0.001, less than about 0.0008 at about 1550 nm, etc.) over a specific spectral range (e.g., a spectral range of about 800 nm to about 2300 nm, a spectral range of about 1100 nm to about 2000 nm, a wavelength of about 1550 nm, etc.).

层240可以包括一组二氧化硅(SiO2)层。在一些实施方式中,针对L层可以使用另一种材料。在一些实施方式中,可以为L层240选择特定材料。例如,层240可以包括一组二氧化硅(SiO2)层、一组氧化铝(Al2O3)层、一组二氧化钛(TiO2)层、一组五氧化二铌(Nb2O5)层、一组五氧化二钽(Ta2O5)层、一组氟化镁(MgF2)层等。在这种情况下,层240可以被选择为包括在例如特定光谱范围(例如,约1100nm至约2000nm的光谱范围、约1400nm至约1600nm的光谱范围、约1550nm的波长等)上低于层230的折射率的折射率。例如,层240可被选择为在特定光谱范围(例如,约1100nm至约2000nm的光谱范围、约1400nm至约1600nm的光谱范围、约800nm的光谱范围、约1550nm的波长等)上与小于3的折射率相关联。Layer 240 may include a set of silicon dioxide (SiO 2 ) layers. In some embodiments, another material may be used for the L layer. In some embodiments, a specific material may be selected for L layer 240. For example, layer 240 may include a set of silicon dioxide (SiO 2 ) layers, a set of aluminum oxide (Al 2 O 3 ) layers, a set of titanium dioxide (TiO 2 ) layers, a set of niobium pentoxide (Nb 2 O 5 ) layers, a set of tantalum pentoxide (Ta 2 O 5 ) layers, a set of magnesium fluoride (MgF 2 ) layers, etc. In this case, layer 240 may be selected to include a refractive index lower than the refractive index of layer 230 over a specific spectral range (e.g., a spectral range of approximately 1100 nm to approximately 2000 nm, a spectral range of approximately 1400 nm to approximately 1600 nm, a wavelength of approximately 1550 nm, etc.). For example, layer 240 may be selected to be associated with a refractive index of less than 3 over a particular spectral range (e.g., a spectral range of about 1100 nm to about 2000 nm, a spectral range of about 1400 nm to about 1600 nm, a spectral range of about 800 nm, a wavelength of about 1550 nm, etc.).

在另一个示例中,层240可以被选择为在特定光谱范围(例如,约1100nm至约2000nm的光谱范围、约1400nm至约1600nm的光谱范围、约1550nm的波长等)上与小于2.5的折射率相关联。在另一示例中,层240可以被选择为在特定光谱范围(例如,约1100nm至约2000nm的光谱范围、约1400nm至约1600nm的光谱范围、约1550nm的波长等)上与小于2的折射率相关联。在另一个示例中,层240可以被选择为在特定光谱范围(例如,约1100nm至约2000nm的光谱范围、约1400nm至约1600nm的光谱范围、约1550nm的波长等)上与小于1.5的折射率相关联。在一些实施方式中,可以基于带外阻挡光谱范围的期望宽度、与入射角变化相关联的期望中心波长偏移等为层240选择特定材料。In another example, layer 240 can be selected to be associated with a refractive index of less than 2.5 over a particular spectral range (e.g., a spectral range of about 1100 nm to about 2000 nm, a spectral range of about 1400 nm to about 1600 nm, a wavelength of about 1550 nm, etc.). In another example, layer 240 can be selected to be associated with a refractive index of less than 2 over a particular spectral range (e.g., a spectral range of about 1100 nm to about 2000 nm, a spectral range of about 1400 nm to about 1600 nm, a wavelength of about 1550 nm, etc.). In another example, layer 240 can be selected to be associated with a refractive index of less than 1.5 over a particular spectral range (e.g., a spectral range of about 1100 nm to about 2000 nm, a spectral range of about 1400 nm to about 1600 nm, a wavelength of about 1550 nm, etc.). In some embodiments, a particular material may be selected for layer 240 based on the desired width of the out-of-band blocked spectral range, the desired center wavelength shift associated with changes in angle of incidence, and the like.

在一些实施方式中,光学滤波器涂层部分210可以与特定数量m的层相关联,例如,基于氢化锗的光学滤波器可以包括大约20层的交替的H层和L层。在另一实例中,光学滤波器200可与另一数量的层相关联,例如2层至1000层的范围、4层至50层的范围等。在一些实施方式中,光学滤波器涂层部分210的每一层可与特定厚度相关联。例如,层230和240可各自与在约5nm和约2000nm之间的厚度相关联,导致光学滤波器涂层部分210与在约0.2μm和100μm之间的厚度、在约0.5μm与20μm之间的厚度等相关联。In some embodiments, the optical filter coating portion 210 can be associated with a specific number m of layers. For example, a germanium hydride-based optical filter can include approximately 20 alternating H and L layers. In another example, the optical filter 200 can be associated with another number of layers, such as a range of 2 to 1000 layers, a range of 4 to 50 layers, etc. In some embodiments, each layer of the optical filter coating portion 210 can be associated with a specific thickness. For example, layers 230 and 240 can each be associated with a thickness between approximately 5 nm and approximately 2000 nm, resulting in the optical filter coating portion 210 being associated with a thickness between approximately 0.2 μm and 100 μm, a thickness between approximately 0.5 μm and 20 μm, etc.

在一些实施方式中,层230和240可以与多个厚度相关联,例如层230的第一厚度和层240的第二厚度、层230的第一子集的第一厚度和层230的第二子集的第二厚度、层240的第一子集的第一厚度和层240的第二子集的第二厚度等。在这种情况下,层厚度和/或层的数量可以基于一组预期的光学特性来选择,例如预期通带、预期透射率等。例如,层厚度和/或层的数量可以被选择为允许光学滤波器200用于大约1100nm至大约2000nm的光谱范围、大约1550nm的中心波长等。In some embodiments, layers 230 and 240 can be associated with multiple thicknesses, such as a first thickness for layer 230 and a second thickness for layer 240, a first thickness for a first subset of layers 230 and a second thickness for a second subset of layers 230, a first thickness for a first subset of layers 240 and a second thickness for a second subset of layers 240, etc. In such cases, the layer thicknesses and/or the number of layers can be selected based on a set of desired optical properties, such as a desired passband, a desired transmittance, etc. For example, the layer thicknesses and/or the number of layers can be selected to allow the optical filter 200 to be used in a spectral range of approximately 1100 nm to approximately 2000 nm, with a center wavelength of approximately 1550 nm, etc.

在一些实施方式中,光学滤波器涂层部分210可以使用溅射过程来制造。例如,光学滤波器涂层部分210可以使用基于脉冲磁控管的溅射过程来制造,以在玻璃基底上溅射交替层230和240。在一些实施方式中,光学滤波器涂层部分210可以与入射角变化的情况下的相对低的中心波长偏移相关联。例如,光学滤波器涂层部分210可以在入射角从0度变化到15度的情况下引起大小上小于约20nm、小于约15nm、小于约10nm等的中心波长偏移;在入射角从0度变化到30度的情况下引起小于约100nm、小于约50nm、小于约30nm等的中心波长偏移;在入射角从0度变化到45度的情况下引起小于约200nm、小于约150nm、小于约125nm、小于约100nm等的中心波长偏移;等。In some embodiments, the optical filter coating portion 210 can be fabricated using a sputtering process. For example, the optical filter coating portion 210 can be fabricated using a pulsed magnetron-based sputtering process to sputter alternating layers 230 and 240 onto a glass substrate. In some embodiments, the optical filter coating portion 210 can be associated with relatively low center wavelength shifts with varying angles of incidence. For example, the optical filter coating portion 210 can cause a center wavelength shift of less than approximately 20 nm, less than approximately 15 nm, less than approximately 10 nm, etc., with an angle of incidence varying from 0 degrees to 15 degrees; less than approximately 100 nm, less than approximately 50 nm, less than approximately 30 nm, etc., with an angle of incidence varying from 0 degrees to 30 degrees; less than approximately 200 nm, less than approximately 150 nm, less than approximately 125 nm, less than approximately 100 nm, etc., with an angle of incidence varying from 0 degrees to 45 degrees; and so on.

在一些实施方式中,光学滤波器涂层部分210附接到基底,例如基底220。例如,光学滤波器涂层部分210可以附接到玻璃基底。在一些实施方式中,光学滤波器涂层部分210可以与入射介质相关联,例如空气介质或玻璃介质。在一些实施方式中,光学滤波器200可以设置在一组棱镜之间。In some embodiments, the optical filter coating portion 210 is attached to a substrate, such as substrate 220. For example, the optical filter coating portion 210 can be attached to a glass substrate. In some embodiments, the optical filter coating portion 210 can be associated with an incident medium, such as an air medium or a glass medium. In some embodiments, the optical filter 200 can be disposed between a set of prisms.

在一些实施方式中,退火过程可用于制造光学滤波器涂层部分210。例如,在基底上溅射沉积层230和240之后,光学滤波器200可被退火以改善光学滤波器200的一个或更多个光学特性,例如相对于未执行退火过程的另一光学滤波器降低光学滤波器200的吸收系数。In some embodiments, an annealing process can be used to fabricate the optical filter coating portion 210. For example, after sputter-depositing layers 230 and 240 on a substrate, the optical filter 200 can be annealed to improve one or more optical properties of the optical filter 200, such as reducing the absorption coefficient of the optical filter 200 relative to another optical filter that has not undergone the annealing process.

如上所述,图2仅作为示例被提供。其它示例是可能的,并且可以不同于关于图2描述的示例。As mentioned above, FIG2 is provided only as an example. Other examples are possible and may differ from the example described with respect to FIG2.

图3是用于制造本文所述的基于氢化锗的光学滤波器的溅射沉积系统的示例300的图。FIG. 3 is a diagram of an example 300 of a sputter deposition system for fabricating the germanium hydride-based optical filters described herein.

如图3所示,示例300包括真空室310、基底320、阴极330、靶331、阴极电源340、阳极350、等离子体活化源(PAS)360和PAS电源370。靶331可以包括锗材料。PAS电源370可用于为PAS 360供电,并可包括射频(RF)电源。阴极电源340可用于为阴极330供电,并可包括脉冲直流(DC)电源。As shown in FIG3 , example 300 includes a vacuum chamber 310, a substrate 320, a cathode 330, a target 331, a cathode power supply 340, an anode 350, a plasma activation source (PAS) 360, and a PAS power supply 370. Target 331 may include a germanium material. PAS power supply 370 may be used to power PAS 360 and may include a radio frequency (RF) power supply. Cathode power supply 340 may be used to power cathode 330 and may include a pulsed direct current (DC) power supply.

关于图3,靶331在氢气(H2)以及惰性气体(如氩气)的存在下溅射,以沉积氢化锗材料作为基底320上的层。惰性气体可以通过阳极350和/或PAS 360提供到腔室中。氢通过用于活化氢的PAS 360引入真空室310。另外,或者替代地,阴极330可引起氢活化(例如,在这种情况下,氢可从真空室310的另一部分引入)或者阳极350可引起氢活化(例如,在这种情况下,氢可通过阳极350引入真空室310)。在一些实施方式中,氢可以采取氢气、氢气和惰性气体(例如氩气)的混合物等的形式。PAS 360可以位于阴极330的阈值接近度内,允许来自PAS 360的等离子体和来自阴极330的等离子体重叠。PAS 360的使用允许氢化锗层以相对高的沉积速率沉积。在一些实施方式中,以大约0.05nm/s至大约2.0nm/s的沉积速率、以大约0.5nm/s至大约1.2nm/s的沉积速率、以大约0.8nm/s的沉积速率等沉积氢化锗层。3 , target 331 is sputtered in the presence of hydrogen (H 2 ) and an inert gas (e.g., argon) to deposit a germanium hydride material as a layer on substrate 320. The inert gas may be provided to the chamber via anode 350 and/or PAS 360. Hydrogen is introduced into vacuum chamber 310 via PAS 360 for hydrogen activation. Additionally or alternatively, cathode 330 may cause hydrogen activation (e.g., in which case hydrogen may be introduced from another portion of vacuum chamber 310) or anode 350 may cause hydrogen activation (e.g., in which case hydrogen may be introduced into vacuum chamber 310 via anode 350). In some embodiments, the hydrogen may be in the form of hydrogen gas, a mixture of hydrogen gas and an inert gas (e.g., argon), or the like. PAS 360 may be located within a threshold proximity of cathode 330, allowing the plasma from PAS 360 and the plasma from cathode 330 to overlap. The use of PAS 360 allows the germanium hydride layer to be deposited at a relatively high deposition rate. In some embodiments, the germanium hydride layer is deposited at a deposition rate of about 0.05 nm/s to about 2.0 nm/s, at a deposition rate of about 0.5 nm/s to about 1.2 nm/s, at a deposition rate of about 0.8 nm/s, or the like.

尽管本文描述的溅射过程,是就特定几何形状和特定实施方式而言的,但是其他几何形状和其他实施方式也是可能的。例如,可以从另一个方向、从在阴极330的阈值接近度内的气体歧管等注入氢。尽管本文就不同的组件配置方面进行了描述,但是使用不同的材料、不同的制造工艺等也可以实现不同的锗的相对浓度。Although the sputtering process is described herein with respect to a specific geometry and a specific embodiment, other geometries and other embodiments are possible. For example, hydrogen can be injected from another direction, from a gas manifold within a threshold proximity of the cathode 330, etc. Although described herein with respect to different component configurations, different relative concentrations of germanium can also be achieved using different materials, different manufacturing processes, etc.

如上所述,图3仅作为示例被提供。其它示例是可能的,并且可以不同于关于图3描述的示例。As mentioned above, FIG3 is provided only as an example. Other examples are possible and may differ from the example described with respect to FIG3.

图4A-4D示出了与使用氢化锗作为高折射率材料的光学滤波器有关的示例。图4A-4D示出了与基于氢化锗的单层膜有关的特性。Figures 4A-4D illustrate examples related to optical filters using germanium hydride as a high refractive index material. Figures 4A-4D illustrate characteristics related to a single-layer film based on germanium hydride.

如图4A所示,且通过图表400,提供了显示一组膜410-1至410-5的透射率的滤波器响应。每个膜410可以是大约2.5微米的单层膜。膜410-1与和0标准立方厘米/分钟(SCCM)的流速相关的氢浓度相关。换句话说,膜410-1使用未氢化锗。膜410-2、410-3、410-4和410-5与和20SCCM、100SCCM、160SCCM和200SCCM的流速相关的氢浓度相关。换句话说,膜410-2至410-5使用氢浓度增加的氢化锗。在这种情况下,氢化锗膜,例如膜410-2至410-5,相对于非氢化锗膜410-1,与增加的透射率相关联。以这种方式,在光学滤波器中利用氢化锗可以提供改进的透射率。例如,基于氢化锗膜中的氢浓度,对于1100nm至2000nm的光谱范围、1400nm至1600nm的光谱范围、具有1550nm波长的光谱范围等,氢化锗膜可以与大于20%、大于40%、大于60%、大于80%、大于85%、大于90%等的透射率相关联。As shown in Figure 4A, and by chart 400, a filter response showing the transmittance of a group of films 410-1 to 410-5 is provided. Each film 410 can be a single-layer film of approximately 2.5 microns. Film 410-1 is associated with a hydrogen concentration associated with a flow rate of 0 standard cubic centimeters per minute (SCCM). In other words, film 410-1 uses non-germanium hydride. Films 410-2, 410-3, 410-4, and 410-5 are associated with a hydrogen concentration associated with a flow rate of 20 SCCM, 100 SCCM, 160 SCCM, and 200 SCCM. In other words, films 410-2 to 410-5 use germanium hydride with increased hydrogen concentration. In this case, germanium hydride films, such as films 410-2 to 410-5, are associated with increased transmittance relative to non-germanium hydride film 410-1. In this way, utilizing germanium hydride in an optical filter can provide improved transmittance. For example, based on the hydrogen concentration in the germanium hydride film, the germanium hydride film can be associated with a transmittance greater than 20%, greater than 40%, greater than 60%, greater than 80%, greater than 85%, greater than 90%, etc. for a spectral range of 1100nm to 2000nm, a spectral range of 1400nm to 1600nm, a spectral range with a wavelength of 1550nm, etc.

如图4B所示,且通过图表420,提供了膜410的折射率和消光系数。在1400nm的波长下,未氢化锗膜410-1与大约0.1的消光系数相关联,该消光系数大于氢化锗膜410-2、410-3和410-5的消光系数,氢化锗膜410-2、410-3和410-5的消光系数分别为大约0.05、大约0.005和大约0.002。类似地,在1400nm的波长下,未氢化锗膜410-1与4.7的折射率相关联,相对照地,氢化锗膜410-2、410-3和410-5分别与4.6、4.4和4.3的折射率相关联。在这种情况下,氢化锗膜410-2、410-3和410-5与减小的消光系数相关联,同时保持阈值折射率(例如,大于4.0、大于4.2、大于4.4、大于4.5等)。As shown in FIG4B and provided by graph 420, the refractive index and extinction coefficient of film 410 are shown. At a wavelength of 1400 nm, the non-hydrogenated germanium film 410-1 is associated with an extinction coefficient of approximately 0.1, which is greater than the extinction coefficients of the hydrogenated germanium films 410-2, 410-3, and 410-5, which have extinction coefficients of approximately 0.05, approximately 0.005, and approximately 0.002, respectively. Similarly, at a wavelength of 1400 nm, the non-hydrogenated germanium film 410-1 is associated with a refractive index of 4.7, while the hydrogenated germanium films 410-2, 410-3, and 410-5 are associated with refractive indices of 4.6, 4.4, and 4.3, respectively. In this case, hydrogenated germanium films 410-2, 410-3, and 410-5 are associated with a reduced extinction coefficient while maintaining a threshold refractive index (eg, greater than 4.0, greater than 4.2, greater than 4.4, greater than 4.5, etc.).

在1550nm的波长下,未氢化锗膜410-1与大约0.07的消光系数相关联,该消光系数大于氢化锗膜410-2、410-3和410-5的消光系数,氢化锗膜410-2、410-3和410-5的消光系数分别为大约0.03、大约0.003和大约0.001。类似地,在1550nm的波长下,未氢化锗膜410-1与4.6的折射率相关联,相对照地,氢化锗膜410-2、410-3和410-5分别与4.4、4.3和4.2的折射率相关联。在这种情况下,氢化锗膜410-2、410-3和410-5与减小的消光系数相关联,同时保持阈值折射率(例如,大于4.0、大于4.2、大于4.4等)。At a wavelength of 1550 nm, the non-hydrogenated germanium film 410-1 is associated with an extinction coefficient of approximately 0.07, which is greater than the extinction coefficients of the hydrogenated germanium films 410-2, 410-3, and 410-5, which have extinction coefficients of approximately 0.03, approximately 0.003, and approximately 0.001, respectively. Similarly, at a wavelength of 1550 nm, the non-hydrogenated germanium film 410-1 is associated with a refractive index of 4.6, compared to the hydrogenated germanium films 410-2, 410-3, and 410-5, which have refractive indices of 4.4, 4.3, and 4.2, respectively. In this case, the hydrogenated germanium films 410-2, 410-3, and 410-5 are associated with a reduced extinction coefficient while maintaining a threshold refractive index (e.g., greater than 4.0, greater than 4.2, greater than 4.4, etc.).

在2000nm的波长下,未氢化锗膜410-1与大约0.05的消光系数相关联,该消光系数大于氢化锗膜410-2、410-3和410-5的消光系数,氢化锗膜410-2、410-3和410-5的消光系数分别为大约0.005、大约0.0005和大约0.000001。类似地,在1550nm的波长下,未氢化锗膜410-1与4.5的折射率相关联,相对照地,氢化锗膜410-2、410-3和410-5分别与4.4、4.2和4.1的折射率相关联。在这种情况下,氢化锗膜410-2、410-3和410-5与减小的消光系数相关联,同时保持阈值折射率(例如,大于3.5、大于3.75、大于4.0)。At a wavelength of 2000 nm, the non-hydrogenated germanium film 410-1 is associated with an extinction coefficient of approximately 0.05, which is greater than the extinction coefficients of the hydrogenated germanium films 410-2, 410-3, and 410-5, which have extinction coefficients of approximately 0.005, approximately 0.0005, and approximately 0.000001, respectively. Similarly, at a wavelength of 1550 nm, the non-hydrogenated germanium film 410-1 is associated with a refractive index of 4.5, compared to the hydrogenated germanium films 410-2, 410-3, and 410-5, which have refractive indices of 4.4, 4.2, and 4.1, respectively. In this case, the hydrogenated germanium films 410-2, 410-3, and 410-5 are associated with a reduced extinction coefficient while maintaining a threshold refractive index (e.g., greater than 3.5, greater than 3.75, greater than 4.0).

如图4C所示,切通过图表430,提供了氢化锗膜410-5和氢化硅膜410-6的折射率。在这种情况下,氢化锗膜410-5的折射率均大于氢化硅膜410-6的折射率。4C, the refractive indexes of the germanium hydrogenated film 410-5 and the silicon hydrogenated film 410-6 are provided by cutting through the graph 430. In this case, the refractive index of the germanium hydrogenated film 410-5 is greater than the refractive index of the silicon hydrogenated film 410-6.

如图4D所示,且通过图表440,提供了关于氢化锗膜410-5和退火的氢化锗膜410-5’的折射率和消光系数。在这种情况下,例如在大约300摄氏度下施加退火过程60分钟,导致形成退火的氢化锗膜410-5′,导致相对于氢化锗膜410-5在中心波长为大约1550nm的光谱范围处折射率增加(例如增加到大约4.3)和消光系数减小(例如减小到大约0.0006),从而减小角度偏移并提高透射率。4D , and provided with respect to the refractive index and extinction coefficient of the hydrogenated germanium film 410-5 and the annealed hydrogenated germanium film 410-5′, is a graph 440. In this case, applying an annealing process at, for example, approximately 300 degrees Celsius for 60 minutes results in the formation of the annealed hydrogenated germanium film 410-5′, which results in an increase in the refractive index (e.g., to approximately 4.3) and a decrease in the extinction coefficient (e.g., to approximately 0.0006) relative to the hydrogenated germanium film 410-5 over a spectral range having a central wavelength of approximately 1550 nm, thereby reducing angular deviation and improving transmittance.

如上所述,图4A-4D仅作为示例提供。其它示例是可能的,并且可以不同于关于图4A-4D描述的示例。As mentioned above, Figures 4A-4D are provided as examples only. Other examples are possible and may differ from the examples described with respect to Figures 4A-4D.

图5A-5C是与光学滤波器相关的特性图。图5A-5C示出了与带通滤波器相关的特性。5A to 5C are characteristic diagrams related to optical filters. Figs. 5A to 5C show characteristics related to bandpass filters.

如图5A所示,且通过图表500,提供了关于氢化锗光学滤波器510的滤波器响应。光学滤波器510可以包括氢化锗和二氧化硅的交替层。在一些实施方式中,光学滤波器510可以与大约5.6μm的厚度相关联,并且对于0度的入射角可以与以大约1550nm为中心的通频带相关联。此外,对于从0度到40度的入射角,光学滤波器510与大于阈值量(例如,大于约90%)的透射率相关联。As shown in FIG5A and via graph 500, a filter response for a hydrogenated germanium optical filter 510 is provided. Optical filter 510 can include alternating layers of hydrogenated germanium and silicon dioxide. In some embodiments, optical filter 510 can be associated with a thickness of approximately 5.6 μm and can be associated with a passband centered at approximately 1550 nm for an angle of incidence of 0 degrees. Furthermore, optical filter 510 is associated with a transmittance greater than a threshold amount (e.g., greater than approximately 90%) for angles of incidence from 0 degrees to 40 degrees.

如图5B所示,且通过图表520,提供了关于基于氢化硅的光学滤波器530的滤波器响应。光学滤波器530可以包括氢化硅和二氧化硅的交替层。在一些实施方式中,光学滤波器530可以与大约5.9微米(μm)的厚度相关联,并且对于0度的入射角可以与以大约1550nm为中心的通频带相关联。As shown in FIG5B and via graph 520, a filter response for a hydrogenated silicon based optical filter 530 is provided. Optical filter 530 may include alternating layers of hydrogenated silicon and silicon dioxide. In some embodiments, optical filter 530 may be associated with a thickness of approximately 5.9 micrometers (μm) and may be associated with a passband centered at approximately 1550 nm for an angle of incidence of 0 degrees.

如图5C所示,且通过图表540,相对于光学滤波器510(Si:Ge),对于入射角从0度变化到大约40度,光学滤波器530(Si:H)与减小的角度偏移相关联。例如,光学滤波器510与例如以下中心波长的变化相关联:在大约0-10度的入射角处小于大约5nm、在大约0-10度的入射角处小于大约4nm、在大约0-10度的入射角处小于大约3nm、在大约0-10度的入射角处小于大约2nm等的中心波长的变化。类似地,光学滤波器510与例如以下中心波长的变化相关联:在10-20度的入射角处小于约15nm、在10-20度的入射角处小于约10nm、在10-20度的入射角处小于约9nm、在10-20度的入射角处小于约8nm等的中心波长的变化。As shown in FIG5C and by graph 540, optical filter 530 (Si:H) is associated with a reduced angular shift relative to optical filter 510 (Si:Ge) for angles of incidence varying from 0 to approximately 40 degrees. For example, optical filter 510 is associated with a center wavelength shift of, for example, less than approximately 5 nm at an angle of incidence of approximately 0-10 degrees, less than approximately 4 nm at an angle of incidence of approximately 0-10 degrees, less than approximately 3 nm at an angle of incidence of approximately 0-10 degrees, less than approximately 2 nm at an angle of incidence of approximately 0-10 degrees, etc. Similarly, optical filter 510 is associated with a center wavelength shift of, for example, less than approximately 15 nm at an angle of incidence of 10-20 degrees, less than approximately 10 nm at an angle of incidence of 10-20 degrees, less than approximately 9 nm at an angle of incidence of 10-20 degrees, less than approximately 8 nm at an angle of incidence of 10-20 degrees, etc.

类似地,光学滤波器510与例如以下中心波长的变化相关联:在20度入射角处小于约8nm、在20度入射角处小于约9nm、在20-30度入射角处小于约30nm、在20-30度入射角处小于约20nm、在20-30度入射角处小于约15nm、在20-30度入射角处小于约10nm等。类似地,光学滤波器510与例如以下中心波长的变化相关联:在大约30-40度的入射角处小于大约40nm、在大约30-40度的入射角处小于大约35nm、在大约30-40度的入射角处小于大约30nm、在大约30-40度的入射角处小于大约25nm、在大约30-40度的入射角处小于大约20nm等。Similarly, the optical filter 510 is associated with, for example, a variation in center wavelength of less than about 8 nm at a 20 degree angle of incidence, less than about 9 nm at a 20 degree angle of incidence, less than about 30 nm at a 20-30 degree angle of incidence, less than about 20 nm at a 20-30 degree angle of incidence, less than about 15 nm at a 20-30 degree angle of incidence, less than about 10 nm at a 20-30 degree angle of incidence, etc. Similarly, the optical filter 510 is associated with, for example, a variation in center wavelength of less than about 40 nm at an approximately 30-40 degree angle of incidence, less than about 35 nm at an approximately 30-40 degree angle of incidence, less than about 30 nm at an approximately 30-40 degree angle of incidence, less than about 25 nm at an approximately 30-40 degree angle of incidence, less than about 20 nm at an approximately 30-40 degree angle of incidence, etc.

如上所述,图5A-5C仅作为示例提供。其它示例是可能的,并且可以不同于关于图5A-5C描述的示例。As mentioned above, Figures 5A-5C are provided as examples only. Other examples are possible and may differ from the examples described with respect to Figures 5A-5C.

这样,氢化锗光学滤波器,例如以氢化锗作为高折射率层和另一种材料作为低折射率层的光学滤波器,相对于用于与中心波长约为1550nm的光谱范围相关联的光学滤波器的其他材料,可以提供改进的角度偏移、改进的透射率和减小的物理厚度。Thus, germanium hydride optical filters, such as those having germanium hydride as a high refractive index layer and another material as a low refractive index layer, can provide improved angular offset, improved transmittance, and reduced physical thickness relative to other materials used for optical filters associated with a spectral range having a center wavelength of approximately 1550 nm.

前述公开提供了说明和描述,但并不旨在穷举或将实施方式限制到所公开的精确形式。根据以上公开想到的,或者可以从实施方式的实践中获得修改和变化是可能的。The foregoing disclosure provides illustration and description, but is not intended to be exhaustive or to limit the embodiments to the precise form disclosed. Modifications and variations are possible in light of the above disclosure or may be acquired from practice of the embodiments.

本文结合阈值描述了一些实施方式。如本文所使用的,满足阈值可以指值大于阈值、多于阈值、高于阈值、大于或等于阈值、小于阈值、少于阈值、低于阈值、小于或等于阈值、等于阈值等。Some embodiments are described herein in conjunction with threshold values. As used herein, satisfying a threshold value may refer to a value being greater than a threshold value, more than a threshold value, higher than a threshold value, greater than or equal to a threshold value, less than a threshold value, less than a threshold value, lower than a threshold value, less than or equal to a threshold value, equal to a threshold value, etc.

尽管在权利要求中陈述和/或在说明书中公开了特征的特定组合,但是这些组合并不旨在限制可能的实施方式的公开内容。事实上,这些特征中的许多可以以权利要求中未具体陈述和/或说明书中未公开的方式组合。尽管下面列出的每个从属权利要求可以直接从属于仅仅一个权利要求,但是可能的实施方式的公开内容包括与权利要求集合中的每个其他权利要求相结合的每个从属权利要求。Although particular combinations of features are recited in the claims and/or disclosed in the specification, these combinations are not intended to limit the disclosure of possible implementations. In fact, many of these features can be combined in ways not specifically recited in the claims and/or disclosed in the specification. Although each dependent claim listed below may be directly dependent on only one claim, the disclosure of possible implementations includes each dependent claim in combination with every other claim in the claim set.

除非明确说明,否则本文使用的任何元素、动作或指令都不应被解释为关键或必要的。此外,本文所用的冠词“一(a)”和“一(an)”旨在包括一个或更多个项目,并且可以与“一个或更多个”互换使用。此外,如本文所使用的,术语“集合”旨在包括一个或更多个项目(例如,相关项目、不相关项目、相关项目和不相关项目的组合等),并且可以与“一个或更多个”互换使用。在仅旨在说明一个项目的情况下,使用术语“一个(one)”或类似的语言。此外,本文使用的术语“具有(has)”、“具有(have)”、“具有(having)”等旨在是开放式的术语。此外,除非另有明确说明,否则“基于”一词旨在表示“至少部分基于”。Unless explicitly stated, any element, action or instruction used herein should not be interpreted as key or necessary. In addition, the articles "a" and "an" used herein are intended to include one or more projects and can be used interchangeably with "one or more". In addition, as used herein, the term "set" is intended to include one or more projects (for example, related projects, unrelated projects, a combination of related projects and unrelated projects, etc.), and can be used interchangeably with "one or more". In the case of only intending to illustrate an project, the term "one" or similar language is used. In addition, the terms "has", "have", "having" etc. used herein are intended to be open terms. In addition, unless explicitly stated otherwise, the term "based on" is intended to represent "at least partially based on".

Claims (18)

1.一种带通滤波器,包括:1. A bandpass filter, comprising: 一组层,包括:A set of layers, including: 第一子集层,First subset level, 所述第一子集层是具有第一折射率的氢化锗;以及The first subset layer is germanium hydride having a first refractive index; and 第二子集层,Second subset level, 所述第二子集层包括具有第二折射率的材料,The second subset layer comprises a material having a second refractive index. 所述第二折射率小于所述第一折射率,以及The second refractive index is less than the first refractive index, and 所述材料包括以下中的至少一种:The material includes at least one of the following: 二氧化硅材料,Silica material, 氧化铝材料,Alumina materials 二氧化钛材料,Titanium dioxide materials, 五氧化二铌材料,Niobium pentoxide material, 五氧化二钽材料,或tantalum pentoxide material, or 氟化镁材料,Magnesium fluoride materials 其中,在大约1550纳米的波长下,所述第一折射率大于4.2。Specifically, at a wavelength of approximately 1550 nanometers, the first refractive index is greater than 4.2. 2.如权利要求1所述的带通滤波器,其中,所述第一子集层是高折射率层H,并且所述第二子集层是低折射率层L;以及2. The bandpass filter of claim 1, wherein the first subset layer is a high-refractive-index layer H, and the second subset layer is a low-refractive-index layer L; and 其中,所述一组层以下列项中的至少一项进行布置:The set of layers is arranged in at least one of the following ways: (H-L)m阶,(HL) m -order, (H-L)m-H阶,(HL) m -H order, (L-H)m阶,或(LH) m order, or L-(H-L)m阶,L-(H-L)m order, 其中,m是交替的H层和L层的数量。Where m is the number of alternating H and L layers. 3.如权利要求1所述的带通滤波器,其中,所述一组层被配置为使与在1100纳米至2000纳米之间的光谱范围相关联的阈值部分的光通过。3. The bandpass filter of claim 1, wherein the set of layers is configured to allow light of a threshold portion associated with a spectral range between 1100 nm and 2000 nm to pass through. 4.如权利要求1所述的带通滤波器,其中,所述一组层被配置为使与在1400纳米至2000纳米之间的光谱范围相关联的阈值部分的光通过。4. The bandpass filter of claim 1, wherein the set of layers is configured to allow light of a threshold portion associated with a spectral range between 1400 nm and 2000 nm to pass through. 5.如权利要求1所述的带通滤波器,其中,所述一组层被配置为使与具有大约1550纳米的中心波长的光谱范围相关联的阈值部分的光通过。5. The bandpass filter of claim 1, wherein the set of layers is configured to allow light to pass through a threshold portion of a spectral range having a center wavelength of approximately 1550 nanometers. 6.如权利要求1所述的带通滤波器,其中,所述第一子集层与消光系数相关联,该消光系数在以大约1550纳米为中心的光谱范围处小于0.01。6. The bandpass filter of claim 1, wherein the first subset layer is associated with an extinction coefficient less than 0.01 in a spectral range centered at approximately 1550 nm. 7.如权利要求1所述的带通滤波器,其中,在1100纳米至2000纳米的光谱范围处,所述第二折射率小于3。7. The bandpass filter of claim 1, wherein the second refractive index is less than 3 in the spectral range of 1100 nm to 2000 nm. 8.如权利要求1所述的带通滤波器,其中,对于从0度到40度的入射角,光谱范围的中心波长的变化小于40纳米。8. The bandpass filter of claim 1, wherein the change in the center wavelength of the spectral range is less than 40 nanometers for an incident angle from 0 degrees to 40 degrees. 9.如权利要求1所述的带通滤波器,其中,对于从0度到40度的入射角,光谱范围的中心波长的变化小于30纳米。9. The bandpass filter of claim 1, wherein the variation of the center wavelength of the spectral range is less than 30 nanometers for an incident angle from 0 degrees to 40 degrees. 10.如权利要求1所述的带通滤波器,其中,对于从0度到30度的入射角,光谱范围的中心波长的变化小于20纳米。10. The bandpass filter of claim 1, wherein the variation of the center wavelength of the spectral range is less than 20 nanometers for an incident angle from 0 degrees to 30 degrees. 11.如权利要求1所述的带通滤波器,其中,对于从0度到20度的入射角,光谱范围的中心波长的变化小于10纳米。11. The bandpass filter of claim 1, wherein the variation of the center wavelength of the spectral range is less than 10 nanometers for an incident angle from 0 degrees to 20 degrees. 12.一种光学滤波器,包括:12. An optical filter, comprising: 基底;以及Base; and 一组交替的高折射率层和低折射率层,所述一组交替的高折射率层和低折射率层设置在所述基底上以对入射光进行滤波,A set of alternating high-refractive-index and low-refractive-index layers, disposed on the substrate, are used to filter incident light. 其中,所述光学滤波器被配置为使所述入射光中的在中心波长大约为1550纳米的光谱范围内的第一部分通过并且反射入射光的不在所述光谱范围内的第二部分,The optical filter is configured to allow a first portion of the incident light in a spectral range with a center wavelength of approximately 1550 nanometers to pass through, and to reflect a second portion of the incident light that is not in the spectral range. 所述高折射率层是氢化锗,以及The high refractive index layer is germanium hydride, and 所述低折射率层是二氧化硅,The low-refractive-index layer is silicon dioxide. 并且其中,在大约1550纳米的波长下,所述高折射率层的折射率大于4.2。Furthermore, the refractive index of the high-refractive-index layer is greater than 4.2 at a wavelength of approximately 1550 nanometers. 13.如权利要求12所述的光学滤波器,其中,使用溅射过程沉积所述高折射率层。13. The optical filter of claim 12, wherein the high refractive index layer is deposited using a sputtering process. 14.如权利要求12所述的光学滤波器,其中,所述高折射率层是退火的。14. The optical filter of claim 12, wherein the high refractive index layer is annealed. 15.一种光学系统,包括:15. An optical system comprising: 光学滤波器,所述光学滤波器被配置为对输入光信号进行滤波并提供滤波后的输入光信号,An optical filter, configured to filter an input optical signal and provide a filtered input optical signal. 所述输入光信号包括来自第一光源的光和来自第二光源的光,The input optical signal includes light from a first light source and light from a second light source. 所述光学滤波器包括一组介电薄膜层,The optical filter includes a set of dielectric thin film layers. 所述一组介电薄膜层包括:The set of dielectric thin film layers includes: 具有第一折射率的氢化锗的第一子集层,The first subset layer of germanium hydride with the first refractive index, 具有小于所述第一折射率的第二折射率的材料的第二子集层,A second subset layer of material having a second refractive index less than the first refractive index. 其中,在大约1550纳米的波长下,所述第一折射率大于4.2,Specifically, at a wavelength of approximately 1550 nanometers, the first refractive index is greater than 4.2. 所述材料包括以下中的至少一种:The material includes at least one of the following: 二氧化硅材料,Silica material, 氧化铝材料,Alumina materials 二氧化钛材料,Titanium dioxide materials, 五氧化二铌材料,Niobium pentoxide material, 五氧化二钽材料,或tantalum pentoxide material, or 氟化镁材料,以及Magnesium fluoride materials, and 所述滤波后的输入光信号包括来自所述第二光源的相对于所述输入光信号减小强度的光;和The filtered input optical signal includes light from the second light source with reduced intensity relative to the input optical signal; and 光学传感器,所述光学传感器被配置为接收所述滤波后的输入光信号并提供输出电信号。An optical sensor configured to receive the filtered input optical signal and provide an output electrical signal. 16.如权利要求15所述的光学系统,其中,所述光学滤波器设置在所述光学传感器的传感器元件阵列上。16. The optical system of claim 15, wherein the optical filter is disposed on the sensor element array of the optical sensor. 17.如权利要求15所述的光学系统,其中,所述光学滤波器与传感器元件分离了自由空间。17. The optical system of claim 15, wherein the optical filter is separated from the sensor element in free space. 18.如权利要求15所述的光学系统,其中,所述光学滤波器具有大约5.6μm的厚度。18. The optical system of claim 15, wherein the optical filter has a thickness of approximately 5.6 μm.
HK19121370.1A 2017-07-24 2019-03-22 Optical filter HK1261530B (en)

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HK1261530B true HK1261530B (en) 2021-09-17

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