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HK1254243B - Drain pipe cleaning kit and cleaning method using same - Google Patents

Drain pipe cleaning kit and cleaning method using same Download PDF

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Publication number
HK1254243B
HK1254243B HK18113386.5A HK18113386A HK1254243B HK 1254243 B HK1254243 B HK 1254243B HK 18113386 A HK18113386 A HK 18113386A HK 1254243 B HK1254243 B HK 1254243B
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HK
Hong Kong
Prior art keywords
cleaning
foaming
drain pipe
agent
drain
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Application number
HK18113386.5A
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Chinese (zh)
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HK1254243A1 (en
Inventor
柳仁基
金致会
郭尚运
李相旻
辛胜日
权赫秀
赵珉庆
Original Assignee
株式会社 Lg 生活健康
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Publication date
Priority claimed from KR1020160029739A external-priority patent/KR20170015100A/en
Priority claimed from KR1020160041660A external-priority patent/KR101857117B1/en
Priority claimed from KR1020160086883A external-priority patent/KR102540064B1/en
Priority claimed from KR1020160086875A external-priority patent/KR20170101084A/en
Priority claimed from KR1020160089926A external-priority patent/KR20180008090A/en
Application filed by 株式会社 Lg 生活健康 filed Critical 株式会社 Lg 生活健康
Priority claimed from PCT/KR2016/008407 external-priority patent/WO2017023051A1/en
Publication of HK1254243A1 publication Critical patent/HK1254243A1/en
Publication of HK1254243B publication Critical patent/HK1254243B/en

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Description

排水管清洗套装以及利用该套装的清洗方法Drain pipe cleaning kit and cleaning method using the same

技术领域Technical Field

本发明涉及一种发泡清洗用排水管清洗剂、能够将其持续地向排水管供给的清洗容器以及利用该清洗剂和该清洗容器的清洗方法,更加具体地,涉及一种将发泡清洗用排水管清洗剂持续地向排水管供给,从而能够使清洗效果达到最大化的清洗容器、清洗套装以及利用该套装的清洗方法。The present invention relates to a drain pipe cleaning agent for foaming cleaning, a cleaning container capable of continuously supplying the drain pipe cleaning agent to a drain pipe, and a cleaning method using the cleaning agent and the cleaning container. More specifically, the present invention relates to a cleaning container capable of continuously supplying the drain pipe cleaning agent for foaming cleaning to a drain pipe so as to maximize the cleaning effect, a cleaning kit, and a cleaning method using the kit.

本申请基于2015年7月31日申请的韩国专利申请第10-2015-0108579号、2016年3月11日申请的韩国专利申请第10-2016-0029739号、2016年3月2日申请的韩国专利申请第10-2016-0025287号、2016年4月5日申请的韩国专利申请第10-2016-0041660号、2016年2月26日申请的韩国专利申请第10-2016-0023278号、2016年7月8日申请的韩国专利申请第10-2016-0086875号、2016年2月26日申请的韩国专利申请第10-2016-0023334号、2016年7月8日申请的韩国专利申请第10-2016-0086883号以及2016年7月15日申请的韩国专利申请第10-2016-0089926号要求优先权,这些专利申请的说明书以及附图所公开的全部内容在此引入本申请作为参考。This application is based on Korean Patent Application No. 10-2015-0108579 filed on July 31, 2015, Korean Patent Application No. 10-2016-0029739 filed on March 11, 2016, Korean Patent Application No. 10-2016-0025287 filed on March 2, 2016, Korean Patent Application No. 10-2016-0041660 filed on April 5, 2016, and Korean Patent Application No. 10-2016-0023278 filed on February 26, 2016 , Korean Patent Application No. 10-2016-0086875 filed on July 8, 2016, Korean Patent Application No. 10-2016-0023334 filed on February 26, 2016, Korean Patent Application No. 10-2016-0086883 filed on July 8, 2016, and Korean Patent Application No. 10-2016-0089926 filed on July 15, 2016, and the disclosures of the specifications and drawings of these patent applications are incorporated herein by reference in their entirety.

背景技术Background Art

水槽的过滤网和排水管在烹制料理或丢弃的过程中会残留食物,由于时常浸在水中,形成容易滋生微生物的环境,因此,容易变脏并引发严重的气味。为了使过滤网或排水管能够保持清洁而对其进行清理不但不方便,而且需要耗费很多时间以及劳力。然而,除了更换过滤网或排水管的方法以外,就没有其它特殊的对策,因此成为了问题。Sink filters and drain pipes, where food residue is left behind during cooking and disposal, are constantly submerged in water, creating an environment conducive to microbial growth. This can lead to soiling and the development of odors. Cleaning these filters and drain pipes to ensure they remain clean is inconvenient, time-consuming, and labor-intensive. However, there are no specific solutions other than replacing the filter or drain pipe, creating a significant problem.

为了解决上述问题,美国专利申请14-529388中公开了一种利用淀粉酶等水解酶使过氧化氢发泡后,清洗管道的二液型系统。然而,在这种系统中,过氧化氢的杀菌漂白能力相比次氯酸钠明显降低,因此,具有无法充分发挥杀菌漂白效果的缺点。To address this issue, U.S. Patent Application No. 14-529388 discloses a two-liquid system for cleaning pipes using hydrolytic enzymes such as amylase to foam hydrogen peroxide. However, this system suffers from the drawback of being unable to fully exert its bactericidal and bleaching effects, as hydrogen peroxide has significantly lower bactericidal and bleaching capabilities than sodium hypochlorite.

另外,美国公开专利US2003/0171234A1中,公开了一种将有黏度的次氯酸钠组合物和发泡剂同时倒入,并使其发泡后清洗管道的方法。然而,在这种清洗方法中,次氯酸钠和发泡剂不容易均匀混合,且在垂直设置的水槽管道内,泡沫无法长时间滞留而立即排出,因此,保持清洗能力有限。另外,为了得到发泡效果,将次氯酸钠组合物和酸性的过氧化氢混合时,存在着产生大量对人体有害的氯气的问题。In addition, U.S. Patent Publication No. US2003/0171234A1 discloses a method for cleaning pipes by simultaneously pouring a viscous sodium hypochlorite composition and a foaming agent and allowing them to foam. However, this cleaning method is not easy to evenly mix the sodium hypochlorite and foaming agent. Furthermore, in vertically arranged water tank pipes, the foam cannot be retained for a long time and discharged immediately, thus limiting the cleaning capacity. Furthermore, mixing the sodium hypochlorite composition with acidic hydrogen peroxide to achieve the foaming effect produces a large amount of chlorine gas that is harmful to the human body.

因此,目前的实情是,需要开发一种通过加长发泡清洗剂组合物清洗效果的持续时间,能够更加有效地清洗水槽排水管的道具或方法。另外,在发泡清洗剂组合物中,为了提高清洗能力,调节组分的配合比率以充分引起发泡反应,以及抑制氯气的产生非常重要。Therefore, there is a current need for a tool or method that can more effectively clean sink drains by extending the duration of the cleaning effect of a foaming cleaning composition. Furthermore, in order to enhance cleaning performance, it is crucial to adjust the component ratios in a foaming cleaning composition to fully induce the foaming reaction and suppress the generation of chlorine gas.

发明内容Summary of the Invention

发明要解决的课题Problems to be solved by the invention

鉴于上述情况,本发明所要解决的课题是,提供一种利用通过发泡清洗用排水管清洗剂产生的泡沫清洗过滤网,使所述清洗剂缓慢地流入排水管,能够对排水管持续产生清洗效果的清洗容器。In view of the above situation, the present invention aims to provide a cleaning container that utilizes foam generated by a foaming drainpipe cleaner to clean a filter, allowing the cleaner to slowly flow into the drainpipe to continuously clean the drainpipe.

另外,本发明所要解决的课题是,提供一种对排水管的清洗效果达到最大化,并且抑制了氯气产生的排水管清洗剂组合物。Another object of the present invention is to provide a drain cleaning composition that maximizes the cleaning effect on drains and suppresses the generation of chlorine gas.

另外,本发明所要解决的课题是,提供一种包括发泡清洗用排水管清洗剂以及发泡清洗用排水管清洗容器的套装。Another object of the present invention is to provide a set including a drain cleaning agent for foaming cleaning and a drain cleaning container for foaming cleaning.

另外,本发明所要解决的问题是,提供一种利用所述清洗容器,能够同时有效地清洗厨房水槽过滤网以及排水管的方法。In addition, the problem to be solved by the present invention is to provide a method for simultaneously and effectively cleaning a kitchen sink filter and a drain pipe by using the cleaning container.

解决课题的方法Solutions to Problems

为了解决上述课题,本发明提供一种能够使发泡清洗用排水管清洗剂缓慢地流入排水管内的清洗容器,以及利用该容器有效地对厨房水槽的过滤网以及排水管进行发泡清洗的方法。To solve the above problems, the present invention provides a cleaning container capable of slowly flowing a foaming drain cleaner into a drain pipe, and a method for efficiently foaming and cleaning a kitchen sink filter and drain pipe using the container.

为了克服上述以往技术中的问题,本发明的发明人通过锐意研究努力,开发了一种包括能够使发泡清洗用清洗剂缓慢地流入过滤网、排水口以及排水管中的流入口和排出口的清洗容器。本发明人惊奇地发现,将发泡清洗用清洗剂和所述清洗容器同时使用时,产生了丰富泡沫的清洗剂通过流入口排出,从而能够有效地清洗过滤网和排水口,并且,使发泡清洗剂通过排出口缓慢地排出,能够长时间地发泡清洗排水管,从而能够显著地提高厨房水槽的过滤网、排水口以及排水管的清洗效果,由此完成了本发明。To overcome the aforementioned problems of the prior art, the inventors of the present invention, through dedicated research and effort, developed a cleaning container comprising an inlet and an outlet that allow a foaming cleaning agent to slowly flow into the filter, drain, and drain pipe. The inventors surprisingly discovered that when the foaming cleaning agent and the cleaning container are used together, the richly foamed cleaning agent is discharged through the inlet, effectively cleaning the filter and drain. Furthermore, the slow discharge of the foaming cleaning agent through the outlet allows the drain pipe to be foamed for a prolonged period of time, significantly improving the cleaning effectiveness of the kitchen sink filter, drain, and drain pipe. This led to the completion of the present invention.

本发明提供一种发泡清洗用排水管清洗容器,其中,包括:具有形成于内部的容纳空间的容器本体;使发泡清洗用排水管清洗剂流入所述容纳空间的流入口;以及,形成于所述容器本体,以使容纳于所述容器本体的所述容纳空间与排水管连通,将容纳于所述容纳空间中的清洗剂向所述排水管排出的至少一个排出口,与将清洗剂立即向排水管处理的情况相比,所述排出口能够以缓慢的速度排出。所述将清洗剂立即向排水管处理的情况,是指不使用所述清洗容器,将清洗剂直接向排水口或排水管处理的情况。所述清洗容器可设置于用于与排水管相连接的排水口。The present invention provides a drain cleaning container for foaming cleaning, which includes: a container body having a storage space formed therein; an inlet for allowing a drain cleaning agent for foaming cleaning to flow into the storage space; and at least one discharge port formed in the container body so that the storage space contained in the container body is connected to a drain pipe and the cleaning agent contained in the storage space is discharged to the drain pipe, and the discharge port can discharge the cleaning agent at a slower speed than when the cleaning agent is immediately disposed of to the drain pipe. The case of immediately disposing the cleaning agent to the drain pipe refers to the case of not using the cleaning container and directly disposing the cleaning agent to a drain outlet or drain pipe. The cleaning container can be provided at a drain outlet for connection to a drain pipe.

所述发泡清洗用排水管清洗容器使由发泡清洗剂组合物产生的泡沫通过流入口溢出并滞留在排水口以及过滤网,能够有效地清洗排水口或过滤网,并且,使清洗剂通过窄小的排出口缓慢地流出,持续地保持了对排水管的清洗效果,因此,对排水管的清洗效果非常优异。优选地,所述发泡清洗用排水管清洗容器在利用已发泡的泡沫清洗排水口或过滤网的同时,利用通过窄小的排出口流出的清洗剂清洗排水管。The foaming drainpipe cleaning container allows the foam generated by the foaming cleaning agent composition to overflow through the inlet and remain in the drain outlet and filter, effectively cleaning the drain outlet or filter. Furthermore, the cleaning agent is slowly discharged through the narrow outlet, continuously maintaining the cleaning effect on the drainpipe, thereby achieving an excellent drainpipe cleaning effect. Preferably, the foaming drainpipe cleaning container uses the generated foam to clean the drain outlet or filter while simultaneously using the cleaning agent flowing out of the narrow outlet to clean the drainpipe.

作为一实施例,为了利用由发泡性清洗剂产生的泡沫清洗排水口以及过滤网,并使清洗剂缓慢地流入排水管,所述发泡清洗用排水管清洗容器可以为包括排出口的杯子形态。图1中,示出了所述杯子形态的发泡清洗用排水管清洗容器的一个实施例。As one embodiment, the foaming cleaning container for drain pipes can be in the form of a cup with a drain outlet, in order to utilize the foam generated by the foaming cleaning agent to clean the drain outlet and filter, and to allow the cleaning agent to flow slowly into the drain pipe. FIG1 shows an embodiment of the cup-shaped foaming cleaning container for drain pipes.

作为一实施例,所述发泡清洗用排水管清洗容器可以使用从上至下直径逐渐减小的形态的容器。图5中,示出了具有如上所述的特征的发泡清洗用排水管清洗容器的图。所述上方面的直径可以为与排水口或过滤网相同或稍微小的直径。另外,所述上方面的直径可以为预设的直径,以能够插入排水口或过滤网构成插套结合。另外,所述上放面还可以包括卡台,以能够沿着上端部的边缘卡在排水口上。综上所述,由于容器的形态为从上面至下面直径逐渐减小的形态,容器的上端能够挂在排水口或过滤网上,下端能够进入过滤网的内侧。As one embodiment, the drainpipe cleaning container for foaming cleaning can use a container with a shape in which the diameter gradually decreases from top to bottom. FIG5 shows a diagram of a drainpipe cleaning container for foaming cleaning having the characteristics described above. The diameter of the upper surface can be the same as or slightly smaller than the diameter of the drain outlet or the filter. In addition, the diameter of the upper surface can be a preset diameter so that it can be inserted into the drain outlet or the filter to form a socket combination. In addition, the upper surface can also include a card table so that it can be clamped on the drain outlet along the edge of the upper end. In summary, since the shape of the container is a shape in which the diameter gradually decreases from top to bottom, the upper end of the container can be hung on the drain outlet or the filter, and the lower end can enter the inner side of the filter.

另外,所述发泡清洗用排水管清洗容器可以包括以预设间隔设置有凹凸槽的凹凸结构,以使通过流入口排出的清洗剂能够沿着外表面流淌。通过如上所述的凹凸结构,即便容器紧贴于过滤网或排水口,排出的清洗剂也沿着凹凸结构向下流淌,能够提升对过滤网或排水口的清洗效果。Furthermore, the foaming cleaning drainpipe cleaning container may include a concave-convex structure with concave-convex grooves arranged at predetermined intervals, so that the cleaning agent discharged through the inlet flows along the outer surface. With such a concave-convex structure, even if the container is in close contact with a filter or drain outlet, the discharged cleaning agent will flow downward along the concave-convex structure, thereby improving the cleaning effect of the filter or drain outlet.

所述发泡清洗用排水管清洗容器中,容纳于所述容纳空间中的清洗剂相比于将清洗剂立即向排水管处理的情况,能够以缓慢的速度排出,所述速度不受特殊限制,但所述速度可以是容纳于容纳空间中的清洗剂经过10~180分钟,优选经过20~150分钟,更优选经过30~120分钟排出的速度。如此地,通过调节排出速度以便清洗剂能够长时间慢慢地排出,能够对排水管持续产生清洗效果,由此,与单纯向排水口倒入清洗剂来清洗排水管的方法相比,能够显著地提升清洗效果。In the foaming drain cleaning container, the cleaning agent contained in the holding space can be discharged at a slower rate than when the cleaning agent is immediately discharged into the drain. The rate is not particularly limited, but the rate can be such that the cleaning agent contained in the holding space is discharged over a period of 10 to 180 minutes, preferably 20 to 150 minutes, and more preferably 30 to 120 minutes. By adjusting the discharge rate so that the cleaning agent is discharged slowly over a longer period of time, a continuous cleaning effect can be achieved on the drain, thereby significantly improving the cleaning effect compared to a method of simply pouring the cleaning agent into the drain outlet.

本发明中,所述清洗容器的排出口可具有预设的直径,以便所述清洗剂能够通过所述排出口以1~100ml/min,优选以5~50ml/min,更优选以7~20ml/min的速度排出。In the present invention, the discharge port of the cleaning container may have a preset diameter so that the cleaning agent can be discharged through the discharge port at a speed of 1 to 100 ml/min, preferably 5 to 50 ml/min, and more preferably 7 to 20 ml/min.

所述排水管清洗容器中,所述排出口的预设直径可以为0.1~10mm,优选为0.3~5mm,更优选为0.5~3mm。当所述排出口的直径小于0.1mm时,由于清洗剂过于缓慢地流出,会导致清洗时间延长,而超过10mm时,由于过快地流出,会导致本发明所期待的清洗能力的提升效果微弱。In the drainpipe cleaning container, the preset diameter of the discharge port can be 0.1 to 10 mm, preferably 0.3 to 5 mm, and more preferably 0.5 to 3 mm. When the diameter of the discharge port is less than 0.1 mm, the cleaning agent flows out too slowly, resulting in a prolonged cleaning time. When the diameter of the discharge port exceeds 10 mm, the cleaning agent flows out too quickly, resulting in a weak effect of improving the cleaning ability expected by the present invention.

另外,根据本发明一优选实施例,所述清洗容器可以包括具有预设直径和数量的排出口,以便清洗剂能够通过排出口排出10~180分钟,优选排出20~150分钟,更优选排出30~120分钟。尤其是,当发泡清洗用清洗剂的排出时间少于30分钟时,微生物的平均杀灭率低,而超过120分钟时,其杀菌能力的增强效果微弱,因此,排出时间优选控制在30分钟~120分钟之间。Furthermore, according to a preferred embodiment of the present invention, the cleaning container may include discharge ports having a predetermined diameter and number, so that the cleaning agent can be discharged through the discharge ports for 10 to 180 minutes, preferably 20 to 150 minutes, and more preferably 30 to 120 minutes. In particular, when the discharge time of the foaming cleaning agent is less than 30 minutes, the average killing rate of microorganisms is low, while when it exceeds 120 minutes, the enhanced sterilization effect is minimal. Therefore, the discharge time is preferably controlled between 30 and 120 minutes.

所述排水管清洗容器中,所述排出口的预设直径可以为0.1~10mm,优选为0.3~5mm,更优选为0.5~3mm,最优选为1~2.5mm。另外,所述排出口的数量可以为1~8个,优选为1~6个,更优选为2~5个。优选地,当本发明的排水管清洗容器中排出口以1~2.5mm直径形成有2~5个时,能够使清洗剂通过排出口排出30分钟~120分钟,因此,排水管清洗效果能够发挥到最优异。更为优选地,使用本发明的清洗剂对排水管进行清洗50分钟以上,就能够充分地发挥其清洗效果,即便继续清洗,其效果也不会有明显的差异,且只会不必要地延长使用时间。In the drain cleaning container, the preset diameter of the discharge port can be 0.1 to 10 mm, preferably 0.3 to 5 mm, more preferably 0.5 to 3 mm, and most preferably 1 to 2.5 mm. In addition, the number of the discharge ports can be 1 to 8, preferably 1 to 6, and more preferably 2 to 5. Preferably, when the drain cleaning container of the present invention has 2 to 5 discharge ports with a diameter of 1 to 2.5 mm, the cleaning agent can be discharged through the discharge ports for 30 to 120 minutes, so that the drain cleaning effect can be best achieved. More preferably, the cleaning agent of the present invention can be used to clean the drain for more than 50 minutes to fully exert its cleaning effect. Even if the cleaning is continued, there will be no significant difference in the effect, and it will only unnecessarily extend the use time.

另外,本发明提供一种发泡清洗用排水管清洗容器,其中,包括:具有形成于内部的容纳空间的容器本体;使发泡清洗用排水管清洗剂流入所述容纳空间的流入口;形成于所述容器本体,以使容纳于所述容器本体中的所述容纳空间与排水管连通,将容纳于所述容纳空间中的清洗剂向所述排水管排出的至少一个排出口;以及,使所述发泡清洗用排水管清洗剂通过的网眼构件,与将清洗剂立即向排水管处理的情况相比,能够以缓慢的速度排出。In addition, the present invention provides a drain pipe cleaning container for foaming cleaning, which includes: a container body having a storage space formed inside; an inlet for allowing a drain pipe cleaning agent for foaming cleaning to flow into the storage space; at least one discharge outlet formed in the container body so that the storage space contained in the container body is connected to a drain pipe and the cleaning agent contained in the storage space is discharged into the drain pipe; and a mesh component through which the drain pipe cleaning agent for foaming cleaning passes, so that the cleaning agent can be discharged at a slower speed compared to the case where the cleaning agent is immediately disposed of into the drain pipe.

所述发泡清洗用排水管清洗容器中,使排水管清洗剂通过的网眼构件可形成于所述流入口。由此,通过流入口的网眼构件流入的清洗剂的第一剂和第二剂,能够在清洗容器的内部均匀地向下扩散并均匀地混合。并且,发泡清洗剂的泡沫通过形成于所述流入口的网眼构件排出外部,由此形成更加稠密的泡沫,使得清洗效果能够显著提升。In the drainpipe cleaning container for foaming cleaning, a mesh member for allowing the drainpipe cleaning agent to pass through can be formed at the inlet. This allows the first and second doses of cleaning agent, flowing through the mesh member at the inlet, to diffuse downward and mix evenly within the cleaning container. Furthermore, the foam of the foaming cleaning agent is discharged to the outside through the mesh member formed at the inlet, thereby forming a denser foam, significantly improving the cleaning effect.

本发明中,所述网眼构件的形态可以是网状。或是,可以使用由间隔不均匀的无纺布材质构成的构件来代替规定间隔的网状的网眼构件,但但并不限定于此。In the present invention, the mesh member may be in the form of a net, or a member made of a non-woven fabric with uneven spacing may be used instead of the mesh member with a predetermined spacing, but the present invention is not limited thereto.

优选地,所述网眼构件的孔径大小(pore size)可以为100~10000μm,优选为300~4000μm,更优选为400~2000μm,最优选为400~900μm。当所述网眼构件的孔径大小小于100μm时,由于清洗剂组合物不容易通过,因此不适合,而超过10000μm时,清洗剂混合物的均匀化、以及排出的泡沫的稠密化效果会下降。Preferably, the pore size of the mesh member is 100 to 10,000 μm, more preferably 300 to 4,000 μm, more preferably 400 to 2,000 μm, and most preferably 400 to 900 μm. A pore size of less than 100 μm is unsuitable because the cleaning composition does not readily pass through it. A pore size exceeding 10,000 μm reduces the homogenization of the cleaning mixture and the densification of the discharged foam.

本发明中,所述网眼构件可以由金属丝构成,所述金属丝包括选自于由不锈钢、玻璃纤维以及聚乙烯(PE)等所组成的组中的任意一种以上材质。另外,所述网眼构件,可以使用金属丝的纵线和横线垂直交叉形成正方形网目的构件。从本发明的目的考虑,当清洗剂组合物通过如上所述的网眼构件流入时,流入的清洗剂的均匀化效果以及通过流入口排出的发泡泡沫的稠密化效果最为优异。In the present invention, the mesh member can be composed of metal wire, and the metal wire includes any one or more materials selected from the group consisting of stainless steel, glass fiber, and polyethylene (PE). In addition, the mesh member can be a member in which the longitudinal and transverse lines of the metal wires intersect perpendicularly to form a square mesh. From the perspective of the present invention, when the cleaning agent composition flows through the mesh member as described above, the homogenization effect of the cleaning agent flowing in and the densification effect of the foam discharged through the inlet are most excellent.

作为一实施例,为了利用由发泡性清洗剂所产生的泡沫清洗排水口以及过滤网,并使清洗剂缓慢地流入排水管,所述发泡清洗用排水管清洗容器包括排出口,且可以为流入口形成有网眼构件的杯子形态,图12中,示出了所述杯子形态的发泡清洗用排水管清洗容器的一个实施例。As one embodiment, in order to utilize the foam generated by the foaming cleaning agent to clean the drain outlet and the filter and allow the cleaning agent to slowly flow into the drain pipe, the drain pipe cleaning container for foaming cleaning includes a drain outlet and can be in the form of a cup with a mesh component formed at the inlet. Figure 12 shows an embodiment of the cup-shaped drain pipe cleaning container for foaming cleaning.

本发明中,作为上述发泡清洗用排水管清洗容器的材质,可以使用HDPE(高密度聚乙烯,high density polyethylene)、LDPE(低密度聚乙烯,low density polyethylene)、PET(聚对苯二甲酸乙二醇酯,polyethylene terephthalate)、PP(聚丙烯,polypropylene)、PE(聚乙烯,polyethylene)、PC(聚碳酸酯,polycarbonate)、PS(聚苯乙烯,polystyrene)或ABS(丙烯腈-丁二烯-苯乙烯共聚物,acrylonitrile butadienestyrene)等常规使用的塑料材质、纸、玻璃或金属等材质。In the present invention, as the material of the above-mentioned drain pipe cleaning container for foaming cleaning, commonly used plastic materials such as HDPE (high-density polyethylene), LDPE (low-density polyethylene), PET (polyethylene terephthalate), PP (polypropylene), PE (polyethylene), PC (polycarbonate), PS (polystyrene) or ABS (acrylonitrile butadiene styrene), paper, glass or metal can be used.

本发明中,对发泡清洗用排水管清洗剂组合物而言,为了清洗过滤网、排水口或排水管而包含漂白剂的组合物等常规使用的清洗用组合物都可以使用,没有特别的限制。In the present invention, the drain cleaning composition for foaming cleaning may be any commonly used cleaning composition such as a composition containing a bleaching agent for cleaning filters, drain outlets, or drain pipes, without particular limitation.

优选地,本发明提供一种分别包含第一剂组合物和第二剂组合物的发泡清洗用排水管清洗剂,其中,所述第一剂组合物包含氯系清洗剂成分,优选包含次氯酸盐;所述第二剂组合物包含发泡剂,优选包含过氧化氢。更加具体地,所述发泡清洗用排水管清洗剂,可以分别包含含有氯系清洗剂成分的第一剂组合物以及含有发泡剂的第二剂组合物。所述第一剂组合物或第二剂组合物可以包含阴离子表面活性剂、非离子表面活性剂或两者的混合物等。Preferably, the present invention provides a foaming drainpipe cleaning agent comprising a first composition and a second composition, respectively, wherein the first composition comprises a chlorine-based cleaning agent, preferably hypochlorite, and the second composition comprises a foaming agent, preferably hydrogen peroxide. More specifically, the foaming drainpipe cleaning agent may comprise a first composition comprising a chlorine-based cleaning agent and a second composition comprising a foaming agent. The first or second composition may comprise an anionic surfactant, a nonionic surfactant, or a mixture thereof.

本发明中,使用时可将所述第一剂组合物和第二剂组合物在下述本发明的发泡清洗用排水管清洗容器的容纳空间内进行混合后使用。另外,使用时,所述第一剂组合物和第二剂组合物的重量比(第一剂组合物:第二剂组合物)可以为10:1~1:10,优选为5:1~1:5,更优选为3:1~1:3,并且在该重量比范围内发泡能力以及清洗能力最为优异。In the present invention, the first and second compositions can be mixed in the container of the foaming drainpipe cleaning container of the present invention before use. Furthermore, the weight ratio of the first and second compositions (first composition:second composition) can be 10:1 to 1:10, preferably 5:1 to 1:5, and more preferably 3:1 to 1:3. Within this weight ratio range, foaming and cleaning performance are optimal.

本发明中,作为氯系清洗剂成分和发泡剂,优选次氯酸盐和过氧化氢的反应,可以使用如下述反应式1所示的产生氧气而进行发泡的反应。除此之外,还可以使用多种方法进行发泡反应,例如,可举出碳酸钠或碳酸氢钠等与有机酸(柠檬酸或乳酸等)或无机酸(氨基磺酸等)的反应,也可以将表面活性剂或杀菌剂等配合而得到类似的效果。然而,在本发明中,能够以次氯酸盐和过氧化氢作为主成分进行反应,从而产生发泡清洗效果,在这种情况下,与其他发泡清洗方法相比,清洗效果最为优异。In the present invention, the reaction of hypochlorite and hydrogen peroxide as the chlorine-based cleaning agent component and foaming agent is preferred. A foaming reaction that generates oxygen gas, as shown in the following reaction formula 1, can be used. In addition, various other methods can be used to generate the foaming reaction, such as the reaction of sodium carbonate or sodium bicarbonate with an organic acid (such as citric acid or lactic acid) or an inorganic acid (such as aminosulfonic acid). Similar effects can also be achieved by adding surfactants or disinfectants. However, in the present invention, a foaming cleaning effect can be generated by reacting hypochlorite and hydrogen peroxide as the main components. In this case, the cleaning effect is superior to other foaming cleaning methods.

反应式1:Reaction 1:

NaOCl+H2O2NaCl+H2O+1/2O2 NaOCl+H 2 O 2 NaCl+H 2 O+1/2O 2

本发明中,第一剂作为主成分可包含氯系清洗剂成分,优选可包含次氯酸盐,其杀菌和漂泊效果优异,且被稀释后分解速度快,残留性少,口服毒性低,因此,能够有效地使用于食品以及餐具的杀菌消毒。In the present invention, the first agent may contain a chlorine-based cleaning agent component as a main component, preferably hypochlorite, which has excellent sterilization and bleaching effects, decomposes quickly after dilution, has little residual content, and has low oral toxicity. Therefore, it can be effectively used for sterilization and disinfection of food and tableware.

所述作为杀菌或消毒的有效成分使用的次氯酸盐,可以使用选自于由次氯酸钠(sodiumhypochloriteion,NaOCl)、次氯酸钾、次氯酸钙以及次氯酸镁等所组成的组中的一种或多种。作为次氯酸盐可以优选使用次氯酸钠。The hypochlorite used as an effective component for sterilization or disinfection can be one or more selected from the group consisting of sodium hypochlorite (NaOCl), potassium hypochlorite, calcium hypochlorite, and magnesium hypochlorite. Sodium hypochlorite can be preferably used as the hypochlorite.

所述氯系清洗剂成分、优选次氯酸盐的使用量相对于第一剂组合物总重量可以为0.1~30重量%,优选为5~27重量%,更优选为15~25重量%。当所述氯系清洗剂成分的使用量低于0.1重量%时,其杀菌或消毒功能微弱,而超过30重量%时,与表面活性剂的相容性不良,并且对氯酸离子本身的稳定性也不利。The chlorine-based cleaning agent component, preferably hypochlorite, can be used in an amount of 0.1 to 30% by weight, preferably 5 to 27% by weight, and more preferably 15 to 25% by weight, relative to the total weight of the first composition. When the amount of the chlorine-based cleaning agent component used is less than 0.1% by weight, its bactericidal or disinfecting function is weak, while when it exceeds 30% by weight, its compatibility with surfactants is poor and the stability of the chlorate ion itself is also adversely affected.

在本发明中,为了提高清洗剂组合物的发泡清洗效果,能够以1:1~10:1,优选以1.25:1~9:1,更优选以2:1~7:1,最优选以3:1~5:1的当量比(次氯酸盐:过氧化氢)含有所述次氯酸盐和过氧化氢。所述当量比范围的清洗剂组合物,其发泡能力以及清洗能力最为优异。In the present invention, to enhance the foaming and cleaning effect of the cleaning composition, the hypochlorite and hydrogen peroxide may be contained in an equivalent ratio (hypochlorite:hydrogen peroxide) of 1:1 to 10:1, preferably 1.25:1 to 9:1, more preferably 2:1 to 7:1, and most preferably 3:1 to 5:1. Cleaning compositions with this equivalent ratio exhibit the best foaming and cleaning performance.

另外,本发明提供一种包括含有氯系清洗剂成分的第一剂、含有发泡剂的第二剂、以及pH调节剂的排水管清洗剂组合物,优选提供排水管清洗用二液型发泡清洗剂组合物。优选地,所述氯系清洗剂可以使用次氯酸盐等,所述发泡剂可以使用过氧化氢等。为了将所述氯系清洗剂成分与发泡剂进行混合时,使pH值保持在9以上而追加pH调节剂时,能够显著地抑制对人体有害的氯气的产生。The present invention also provides a drain cleaning composition comprising a first component containing a chlorine-based cleaning agent, a second component containing a foaming agent, and a pH adjuster. Preferably, the composition provides a two-component foaming cleaning agent for drain cleaning. Preferably, the chlorine-based cleaning agent may be a hypochlorite, for example, and the foaming agent may be a hydrogen peroxide, for example. The addition of a pH adjuster to maintain a pH of 9 or above when the chlorine-based cleaning agent and foaming agent are mixed significantly suppresses the generation of chlorine gas, which is harmful to the human body.

更加具体地,由于本发明的排水管清洗剂组合物包含pH调节剂,能够使包含第一剂的氯系清洗剂成分、优选包含次氯酸钠的组合物的pH保持在12以上。此外,将本发明第二剂的酸性发泡剂组合物与第一剂混合后,混合物的pH仍然能保持在9以上,不会生成大量的氯气,因此,可以安全地对厨房水槽的过滤网以及排水管进行发泡清洗。More specifically, because the drain cleaning composition of the present invention includes a pH adjuster, it can maintain the pH of the composition comprising the first-part chlorine-based cleaning agent component, preferably sodium hypochlorite, at a level of 12 or higher. Furthermore, after mixing the second-part acidic foaming agent composition of the present invention with the first-part composition, the pH of the mixture can still be maintained at a level of 9 or higher, preventing the generation of significant amounts of chlorine gas. Therefore, kitchen sink filters and drains can be safely foamed and cleaned.

在本发明中,将以次氯酸钠为主成分的第一剂和以酸性的过氧化氢为主成分的第二剂进行混合的过程中,会产生大量有害的氯气,由于氯气对人体非常危险,因此,要慎重地设计第一剂和第二剂的配方,以产生最少量的氯气。特别是,优选将第一剂与第二剂混合时,也将氯气的产生量降低到最少。次氯酸钠在pH小于9的条件下,会产生大量的氯气,因此,对人体非常危险,并且,将第一剂和第二剂混合时也会在一瞬间急剧地产生氯气,因此,为了防止上述情况的发生,调节混合液的pH非常重要。In the present invention, the process of mixing a first agent, primarily sodium hypochlorite, and a second agent, primarily acidic hydrogen peroxide, produces a large amount of harmful chlorine gas. Because chlorine gas is extremely dangerous to the human body, the formulations of the first and second agents are carefully designed to minimize chlorine gas production. In particular, it is preferred that the first and second agents be mixed in a manner that minimizes chlorine gas production. Sodium hypochlorite produces large amounts of chlorine gas at a pH below 9, making it extremely dangerous to the human body. Furthermore, mixing the first and second agents can also produce a rapid and instantaneous burst of chlorine gas. Therefore, to prevent this, it is crucial to adjust the pH of the mixture.

本发明中,在将第一剂与第二剂混合的过程中,包含于第一剂中的次氯酸钠的一部分与过氧化氢进行反应,转换为氯化钠、水以及氧气。为了抑制反应后剩余的次氯酸钠急速分解而产生大量的氯气,第一剂和第二剂的混合物的pH值优选为9~14,更优选为11~14,此时更安全。In the present invention, during the mixing of the first and second agents, a portion of the sodium hypochlorite contained in the first agent reacts with hydrogen peroxide to convert into sodium chloride, water, and oxygen. To prevent the rapid decomposition of the remaining sodium hypochlorite after the reaction and the generation of a large amount of chlorine gas, the pH of the mixture of the first and second agents is preferably 9 to 14, more preferably 11 to 14, which is safer.

本发明的排水管清洗剂组合物中包含pH调节剂,因此,在混合第一剂和第二剂时,能够显著地抑制氯气的产生。使用所述排水管清洗剂组合物时产生的氯气的量少于300ppm,优选少于100ppm,更优选为少于50ppm。作为参考,根据安全健康机构提供的化学品安全技术说明书(MSDS)的标准,氯气的毒性浓度(LC50)为293ppm。使用本发明中的排水管清洗剂组合物时,与所述毒性浓度(LC50)相比,能够显著地抑制氯气的产生量,因此,对人体的安全性非常优异。The drain cleaning composition of the present invention includes a pH regulator, thereby significantly suppressing the generation of chlorine gas when the first and second agents are mixed. The amount of chlorine gas generated when using the drain cleaning composition is less than 300 ppm, preferably less than 100 ppm, and more preferably less than 50 ppm. For reference, according to the Material Safety Data Sheet (MSDS) provided by the safety and health agency, the toxicity concentration (LC50) of chlorine gas is 293 ppm. When using the drain cleaning composition of the present invention, the amount of chlorine gas generated can be significantly suppressed compared to the toxicity concentration (LC50), thereby being extremely safe for the human body.

本发明中,排水管清洗剂组合物中可以使用pH调节剂,以便将第一剂和第二剂混合后使pH保持在9以上,从而使氯气的产生量达到最少。作为所述pH调节剂,可以使用选自于由氢氧化钠(NaOH)、氢氧化钾(KOH)、硅酸钠(Na3SiO3,Na4SiO4)以及碳酸钠(Na2CO3)等组成的组中的任意一种以上,优选可以使用氢氧化钠。In the present invention, a pH adjuster may be used in the drain cleaning composition to maintain a pH of 9 or higher after mixing the first and second components, thereby minimizing the generation of chlorine gas. The pH adjuster may be any one or more selected from the group consisting of sodium hydroxide (NaOH), potassium hydroxide (KOH), sodium silicate ( Na3SiO3 , Na4SiO4 ), and sodium carbonate (Na2CO3 ) , with sodium hydroxide being preferred.

本发明中的排水管清洗剂组合物中包含pH调节剂,因此,在混合第一剂和第二剂时,能够将pH值保持在9~14。优选地,所述pH调节剂可以包含于所述第一剂中,此时,所述第一剂的pH能够保持在12~14。The drain cleaning composition of the present invention contains a pH adjuster, so when the first and second agents are mixed, the pH value can be maintained at 9 to 14. Preferably, the pH adjuster can be included in the first agent, in which case the pH of the first agent can be maintained at 12 to 14.

本发明中,所述pH调节剂与包含于第二剂中的酸性物质的氢离子总量的当量比(pH调节剂:包含于第二剂中的酸性物质的氢离子总量的当量)为1.1~10:1,优选为1.1~5:1,更优选为1.1~3:1。当所述pH调节剂的含量小于1.1:1的当量比(pH调节剂:包含于第二剂中的酸性物质的氢离子总量的当量)时,由于混合后的pH值小于9,因此,氯气的产生量会急剧增加。当所述pH调节剂得含量超过10:1的当量比(pH调节剂:包含于第二剂中的酸性物质的氢离子总量的当量)时,氯系清洗剂成分和发泡剂的反应性会降低。In the present invention, the equivalent ratio of the pH adjuster to the total amount of hydrogen ions of the acidic substance contained in the second agent (pH adjuster: equivalent amount of the total amount of hydrogen ions of the acidic substance contained in the second agent) is 1.1 to 10:1, preferably 1.1 to 5:1, and more preferably 1.1 to 3:1. When the content of the pH adjuster is less than an equivalent ratio of 1.1:1 (pH adjuster: equivalent amount of the total amount of hydrogen ions of the acidic substance contained in the second agent), the amount of chlorine gas generated will increase sharply because the pH value after mixing is less than 9. When the content of the pH adjuster exceeds an equivalent ratio of 10:1 (pH adjuster: equivalent amount of the total amount of hydrogen ions of the acidic substance contained in the second agent), the reactivity of the chlorine-based cleaning agent component and the foaming agent will decrease.

本发明中,所述第一剂组合物可以包含阴离子表面活性剂、非离子表面活性剂或两者的混合物,以增强次氯酸离子的杀菌、消毒能力,并提高其清洗效果以及黏度。优选地,所述阴离子表面活性剂可以包含下述化学式1的烷基醚硫酸盐,优选包含SLES(十二烷基醚硫酸钠,sodium lauryl ether sulfate)。In the present invention, the first composition may include an anionic surfactant, a nonionic surfactant, or a mixture of the two to enhance the bactericidal and disinfecting ability of hypochlorite ions and improve their cleaning effect and viscosity. Preferably, the anionic surfactant may include an alkyl ether sulfate of the following chemical formula 1, preferably SLES (sodium lauryl ether sulfate).

化学式1:Chemical formula 1:

R(CH2CH2O)nSO3MR(CH 2 CH 2 O) n SO 3 M

(化学式1中,上述R表示C10~C16的烷基,n表示1~5的整数,M表示钠或钾。)(In Chemical Formula 1, R represents a C10-C16 alkyl group, n represents an integer of 1-5, and M represents sodium or potassium.)

优选地,上述阴离子表面活性剂中可以包含上述化学式1的烷基醚硫酸盐和下述化学式2的烷基胺氧化物的混合物。优选地,作为下述化学式2的烷基胺氧化物,可以使用月桂基胺氧化物(lauramine oxide)。Preferably, the anionic surfactant may include a mixture of the alkyl ether sulfate of the above Chemical Formula 1 and the alkylamine oxide of the following Chemical Formula 2. Preferably, as the alkylamine oxide of the following Chemical Formula 2, lauramine oxide may be used.

化学式2:Chemical formula 2:

(化学式2中,上述R’表示C10~C16的烷基。)(In Chemical Formula 2, R' represents a C10-C16 alkyl group.)

在本发明中,通过使用上述烷基醚硫酸盐与烷基胺氧化物的混合物作为阴离子表面活性剂,借助表面活性剂相互间的协同作用,以及表面活性剂与次氯酸盐之间的相互作用,与单独使用各成分的情况相比,能够形成优异的清洗能力以及黏度。In the present invention, by using the mixture of the above-mentioned alkyl ether sulfate and alkylamine oxide as the anionic surfactant, due to the synergistic effect between the surfactants and the interaction between the surfactant and hypochlorite, it is possible to form excellent cleaning ability and viscosity compared with the case of using each component alone.

优选地,上述烷基醚硫酸盐与烷基胺氧化物的重量比可以为1:20~20:1,优选为1:10~10:1,更优选为1:1~10:1,最优选为3:1~7:1(烷基醚硫酸盐:烷基胺氧化物)。当上述烷基醚硫酸盐与烷基胺氧化物的使用量在所述重量比范围时,本发明中的第一剂组合物的黏度可形成为最优异。Preferably, the weight ratio of the alkyl ether sulfate to the alkylamine oxide can be 1:20 to 20:1, preferably 1:10 to 10:1, more preferably 1:1 to 10:1, and most preferably 3:1 to 7:1 (alkyl ether sulfate:alkyl amine oxide). When the weight ratio of the alkyl ether sulfate to the alkylamine oxide is within this range, the viscosity of the first composition of the present invention can be optimized.

本发明中,所述第一剂组合物还可以包含无机碱盐,以在保持碱性的情况下,促进基于表面活性剂与次氯酸离子的相互作用的黏度形成。作为所述无机碱盐,可以使用选自于由碳酸钠(Na2CO3)、碳酸氢钠(NaHCO3)、硅酸钠(Na3SiO3,Na4SiO4)以及氢氧化钠(NaOH)等所组成的组中的任意一种以上,优选可以使用氢氧化钠。In the present invention, the first composition may further include an inorganic alkali salt to promote viscosity formation due to the interaction between the surfactant and hypochlorite ions while maintaining alkalinity. The inorganic alkali salt may be any one or more selected from the group consisting of sodium carbonate ( Na2CO3 ), sodium bicarbonate ( NaHCO3 ), sodium silicate ( Na3SiO3 , Na4SiO4 ) , and sodium hydroxide (NaOH), with sodium hydroxide being preferred.

上述无机碱盐的使用量相对于第一剂组合物总重量为0.1~10重量%,优选为0.5~7重量%。当上述无机碱盐的使用量低于0.1重量%时,保持碱性以及促进黏度形成的效果微弱,而超过10重量%时,次氯酸盐和过氧化氢的反应性会降低。The inorganic alkali salt is used in an amount of 0.1 to 10% by weight, preferably 0.5 to 7% by weight, relative to the total weight of the first composition. When the inorganic alkali salt is used in an amount less than 0.1% by weight, the effects of maintaining alkalinity and promoting viscosity formation are minimal, while when the amount exceeds 10% by weight, the reactivity of hypochlorite with hydrogen peroxide decreases.

上述无机碱盐的种类和使用量可在能够使第一剂组合物的pH保持在10~14的范围内选择,其中,将pH保持在10以上,不仅是使第一剂组合物的化学稳定性达到最大化的重要因素,也是提高表面活性剂的去污能力的重要因素。另外,将第一剂组合物的pH保持在10~14,有助于在水溶液相中使次氯酸盐化合物的化学分解最小化,以及使次氯酸盐化合物与表面活性剂之间的化学相互作用最小化。The type and amount of the inorganic alkaline salt can be selected so as to maintain the pH of the first composition within a range of 10 to 14. Maintaining a pH above 10 is not only an important factor in maximizing the chemical stability of the first composition, but also in enhancing the detergency of the surfactant. Furthermore, maintaining the pH of the first composition within a range of 10 to 14 helps minimize the chemical decomposition of the hypochlorite compound in the aqueous solution phase, as well as chemical interactions between the hypochlorite compound and the surfactant.

在本发明中,为了在使用发泡清洗用排水管清洗剂时减少次氯酸盐离子的强烈的气味,并且满足审美要求,还可以包含香料。所述香料可以使用对次氯酸离子稳定的香料,其使用量相对于第一剂组合物总重量为0.01~2重量%。In the present invention, to reduce the strong odor of hypochlorite ions during use and to meet aesthetic requirements, a fragrance may be included in the foaming drainpipe cleaner. The fragrance may be a fragrance that is stable to hypochlorite ions and is used in an amount of 0.01 to 2% by weight relative to the total weight of the first composition.

另外,如上所述,本发明的第一剂组合物的pH值优选保持在10~14,因此,当制成的第一剂组合物的pH值不在该范围内时,还可以使用pH调节剂,将pH值调节为10~14。作为所述pH调节剂,可以使用柠檬酸、氢氧化钠、氢氧化钙或三乙醇胺等。As described above, the pH of the first composition of the present invention is preferably maintained at 10 to 14. Therefore, when the pH of the prepared first composition is outside this range, a pH adjuster may be used to adjust the pH to 10 to 14. Examples of the pH adjuster include citric acid, sodium hydroxide, calcium hydroxide, and triethanolamine.

本发明中,为了产生泡沫,上述发泡清洗用排水管清洗剂使用作为氧系发泡性组合物的第二剂组合物,该第二剂组合物作为主成分可以包含能够与第一剂组合物中的次氯酸盐进行反应而产生氧气的过氧化氢。另外,所述第二剂组合物中可以包含阴离子表面活性剂、非离子表面活性剂或两者的混合物,以在保持大于100cps的黏度的情况下提高清洗效果,并且,为了使过氧化氢能够稳定地流通,可以包含自由基稳定剂。In the present invention, the foaming drainpipe cleaner utilizes a second oxygen-based foaming composition to generate foam. This second composition may contain hydrogen peroxide as a main component, which reacts with the hypochlorite in the first composition to generate oxygen gas. Furthermore, the second composition may contain an anionic surfactant, a nonionic surfactant, or a mixture thereof to enhance cleaning effectiveness while maintaining a viscosity greater than 100 cps. Furthermore, a free radical stabilizer may be included to ensure stable flow of hydrogen peroxide.

所述过氧化氢的含量相对于第二剂组合物总重量可以为0.1~30重量%,优选为5~27重量%,更优选为15~25重量%。当所述过氧化氢的含量低于0.1重量%时,发泡效果以及基于该效果的清洗效果的提升微弱,而超过30重量%时,第二剂组合物的稳定性降低,因此,不容易流通。The content of hydrogen peroxide can be 0.1 to 30% by weight, preferably 5 to 27% by weight, and more preferably 15 to 25% by weight relative to the total weight of the second composition. When the content of hydrogen peroxide is less than 0.1% by weight, the foaming effect and the resulting improvement in cleaning effect are minimal. When the content of hydrogen peroxide exceeds 30% by weight, the stability of the second composition is reduced, making it difficult to circulate.

在本发明中,对上述第二剂组合物而言,稳定作为其主成分的过氧化氢非常重要,为此,第二剂组合物还可以包含自由基稳定剂。作为所述自由基稳定剂,可以使用由下述化学式3表示的水杨酸等,但并不限定于此。In the present invention, it is very important for the second composition to stabilize hydrogen peroxide as its main component. To this end, the second composition may further include a free radical stabilizer. As the free radical stabilizer, salicylic acid represented by the following chemical formula 3 can be used, but is not limited thereto.

化学式3:Chemical formula 3:

上述自由基稳定剂的含量相对于第二剂组合物总重量可以为0.01~15重量%,优选为0.1~5重量%,更优选为0.5~3重量%。当所述自由基稳定剂的含量低于0.01重量%时,过氧化氢的稳定化效果不够充分,而超过15重量%时,会降低第二剂组合物的稳定性。The content of the free radical stabilizer can be 0.01 to 15% by weight, preferably 0.1 to 5% by weight, and more preferably 0.5 to 3% by weight, relative to the total weight of the second composition. When the content of the free radical stabilizer is less than 0.01% by weight, the stabilization effect of hydrogen peroxide is insufficient, while when the content exceeds 15% by weight, the stability of the second composition is reduced.

本发明中,上述第二剂组合物除了如上所述的构成成分之外,还可以包含通常使用于清洗剂组合物中的碳酸钠、硫酸钠等无机盐、高分子或香料等。In the present invention, the second composition may contain, in addition to the above-mentioned components, inorganic salts such as sodium carbonate and sodium sulfate, polymers, and fragrances generally used in cleaning compositions.

在本发明中,为了增强次氯酸离子的杀菌、消毒效果,并提高其清洗效果以及黏度,上述第一剂组合物以及第二剂组合物可以分别包含阴离子表面活性剂、非离子表面活性剂或两者的混合物。In the present invention, in order to enhance the bactericidal and disinfecting effects of hypochlorite ions and improve their cleaning effect and viscosity, the first composition and the second composition may each contain an anionic surfactant, a nonionic surfactant, or a mixture of the two.

上述阴离子表面活性剂的含量相对于第一剂组合物总重量或第二剂组合物总重量,可以为0.1~10重量%,优选为0.5~7重量%。所述非离子表面活性剂的含量相对于第一剂组合物总重量或第二剂组合物的总重量,可以为0.1~10重量%,优选为0.5~7重量%。当所述阴离子表面活性剂或非离子表面活性剂的含量低于0.1重量%时,其清洗能力无法充分地发挥,并且,第一剂组合物或第二剂组合物中难以形成黏度,而超过10重量%时,会阻碍次氯酸离子或过氧化氢的稳定性。The content of the anionic surfactant can be 0.1 to 10% by weight, preferably 0.5 to 7% by weight, relative to the total weight of the first composition or the second composition. The content of the nonionic surfactant can be 0.1 to 10% by weight, preferably 0.5 to 7% by weight, relative to the total weight of the first composition or the second composition. When the content of the anionic surfactant or nonionic surfactant is less than 0.1% by weight, its cleaning ability cannot be fully exerted, and it is difficult to form viscosity in the first composition or the second composition. When the content exceeds 10% by weight, the stability of hypochlorite ions or hydrogen peroxide will be hindered.

优选地,所述第一剂组合物以及第二剂组合物,可以分别包含阴离子表面活性剂和非离子表面活性剂的混合物。更加优选地,在所述混合物中,阴离子表面活性剂与非离子表面活性剂的重量比可以为1:10~10:1,优选为1:5~5:1,更优选为1:3~3:1(阴离子表面活性剂:非离子表面活性剂),在上述重量比范围内,形成黏度以及清洗能力的提升效果最为优异。Preferably, the first composition and the second composition may each comprise a mixture of an anionic surfactant and a nonionic surfactant. More preferably, in the mixture, the weight ratio of the anionic surfactant to the nonionic surfactant may be 1:10 to 10:1, preferably 1:5 to 5:1, and more preferably 1:3 to 3:1 (anionic surfactant:nonionic surfactant). Within the above weight ratio range, the viscosity and cleaning ability are most effectively improved.

在本发明中,所述阴离子表面活性剂、非离子表面活性剂或两者的混合物的含量,相对于清洗剂的总重量可以为1~40重量%,优选为3~30重量%,更优选为5~20重量%。当所述表面活性剂的含量低于1重量%时,洗涤剂功能微弱,而超过40重量%时,清洗剂的溶解性会降低。In the present invention, the content of the anionic surfactant, nonionic surfactant, or a mixture thereof may be 1 to 40% by weight, preferably 3 to 30% by weight, and more preferably 5 to 20% by weight, relative to the total weight of the cleaning agent. When the content of the surfactant is less than 1% by weight, the cleaning agent has a weak detergent function, while when it exceeds 40% by weight, the solubility of the cleaning agent may be reduced.

上述阴离子表面活性剂,例如可以包含选自于由直链烷基苯磺酸盐(R1-CH2-SO3Na,其中,R1表示C9~C15的烷基)、脂肪酸盐(R2-CH2-COONa,其中,R2表示C11~C16的烷基)、碱性磺酸盐(R3=CH-SO3Na,其中,R3表示C11~C18的烷基)、以及α-烯烃磺酸盐(R4-CH=CH-CH2SO3Na,其中,R4表示C12~C18的烷基)等所组成的组中的任意一种以上,但并不限定于此。The anionic surfactant may include, for example, at least one selected from the group consisting of linear alkylbenzene sulfonates (R1- CH2 - SO3Na , wherein R1 represents a C9-C15 alkyl group), fatty acid salts (R2- CH2 -COONa, wherein R2 represents a C11-C16 alkyl group), basic sulfonates (R3=CH- SO3Na , wherein R3 represents a C11-C18 alkyl group), and α-olefin sulfonates (R4-CH=CH- CH2SO3Na , wherein R4 represents a C12-C18 alkyl group), but is not limited thereto.

上述非离子表面活性剂,例如可以包含选自于由脂肪烷氧基聚氧乙烯二醇(R5-CH-(O-CH2-CH2)l-OH,其中,R5表示C11~C18的烷基,l表示5~25的整数)、脂肪酸聚氧乙烯二醇(R6-CO-(O-CH2-CH2)m-OH,其中,R6表示C11~C18的烷基,m表示5~25的整数)、烷基苯基聚氧乙烯二醇(R7-Ar-O-(CH20CH2-O)n-H,其中,R7表示C11~C18的烷基,Ar表示苯环,n表示5~25的整数)以及聚氧乙烯二醇(H-(O-CH2-CH2)i-OH,其中,i表示总分子量为1000~30000的整数)等所组成的组中的任意一种以上,但并不限定于此。The nonionic surfactant may include, for example, at least one selected from the group consisting of fatty alkoxypolyoxyethylene glycol (R5-CH-(O- CH2 - CH2 )l-OH, wherein R5 represents a C11-C18 alkyl group and l represents an integer of 5-25), fatty acid polyoxyethylene glycol (R6-CO-(O- CH2 - CH2 )m-OH, wherein R6 represents a C11-C18 alkyl group and m represents an integer of 5-25), alkylphenyl polyoxyethylene glycol (R7-Ar-O-( CH2OCH2 - O )nH, wherein R7 represents a C11-C18 alkyl group, Ar represents a benzene ring and n represents an integer of 5-25), and polyoxyethylene glycol (H-(O- CH2 - CH2 )i-OH, wherein i represents a total molecular weight of an integer of 1000 to 30000), but is not limited thereto.

在不损害本发明目的的范围内,本发明还可以包含其他任意的成分,并且,为了保持作为清洗剂组合物的基本物性以及品质,还可以包含通常有效地使用于清洗剂组合物中的防腐剂、增稠剂、黏度调节剂、香料或染料等。The present invention may further comprise other optional components within the scope not impairing the purpose of the present invention. In addition, in order to maintain the basic physical properties and quality of the cleaning composition, preservatives, thickeners, viscosity modifiers, fragrances, dyes, etc. that are generally and effectively used in cleaning compositions may also be included.

例如,作为防腐剂,可以使用对羟基苯甲酸甲酯、甲基氯异塞唑晽酮以及甲基异噻唑啉酮的混合物(商品名:Kathon CG,制造商:美国罗门哈斯公司)等。作为增稠剂以及黏度调节剂,可以使用羟丙基甲基纤维素、羟甲基纤维素、氯化钠、氯化铵、丙二醇或己二醇等。作为染料,可以使用水溶性焦油色素等。For example, as a preservative, a mixture of methylparaben, methylchloroisothiazolinone, and methylisothiazolinone (trade name: Kathon CG, manufacturer: Rohm and Haas Company, USA) can be used. As a thickener and viscosity modifier, hydroxypropyl methylcellulose, hydroxymethylcellulose, sodium chloride, ammonium chloride, propylene glycol, or hexylene glycol can be used. As a dye, a water-soluble tar pigment can be used.

本发明中,上述发泡清洗用排水管清洗剂还可以包含增稠剂,以减缓排出速度。含有所述增稠剂的清洗剂组合物的黏度可以为100~10000cps。作为所述增稠剂,例如可以使用选自于由黄原胶、刺槐豆胶、卡拉胶、果胶以及明胶等所组成的组中的一种以上,但并不限定于此。In the present invention, the foaming drain cleaner may further include a thickener to slow down drainage. The viscosity of the cleaning composition containing the thickener may be 100 to 10,000 cps. Examples of the thickener include, but are not limited to, one or more selected from the group consisting of xanthan gum, locust bean gum, carrageenan, pectin, and gelatin.

另外,本发明提供一种发泡清洗用排水管清洗剂,其中,分别包含第一剂组合物和第二剂组合物,所述第一剂组合物中,相对于第一剂组合物的总重量,包含0.1~30重量%的次氯酸盐、0.1~10重量%的阴离子表面活性剂、0.1~10重量%的非离子表面活性剂以及0.05~10重量%的无机碱盐;所述第二剂组合物中,相对于第二剂组合物的总重量,包含0.1~30重量%的过氧化氢、0.1~10重量%的阴离子表面活性剂、0.1~10重量%的非离子表面活性剂以及0.05~10重量%的自由基稳定剂。上述发泡清洗用排水管清洗剂对厨房水槽的过滤网以及排水管,具有优异的杀菌、消毒效果,并且,具有100cps以上的优异的黏度。The present invention also provides a foaming drain cleaner comprising a first composition and a second composition. The first composition comprises, relative to the total weight of the first composition, 0.1-30% by weight of a hypochlorite, 0.1-10% by weight of an anionic surfactant, 0.1-10% by weight of a nonionic surfactant, and 0.05-10% by weight of an inorganic alkali salt. The second composition comprises, relative to the total weight of the second composition, 0.1-30% by weight of hydrogen peroxide, 0.1-10% by weight of an anionic surfactant, 0.1-10% by weight of a nonionic surfactant, and 0.05-10% by weight of a free radical stabilizer. This foaming drain cleaner has excellent sterilizing and disinfecting effects on kitchen sink filters and drain pipes and has an excellent viscosity of over 100 cps.

另外,上述发泡清洗用排水管清洗剂的第一剂中可包含pH调节剂,其中,所述pH调节剂与包含于上述第二剂中的酸性物质的氢离子总量的当量比(pH调节剂:包含于第二剂中的酸性物质的氢离子总量的当量)为1.1~10:1。或着,上述发泡清洗用排水管清洗剂的第一剂中可以包含相对于第一剂组合物的总重量为0.3~10重量%的pH调节剂。在这种情况下,使用发泡清洗液排水管清洗剂时,能够显著地抑制氯气的产生,因此对人体安全。Additionally, the first dose of the foaming drain cleaner may contain a pH adjuster, wherein the equivalent ratio of the pH adjuster to the total hydrogen ions of the acidic substance contained in the second dose (pH adjuster: equivalents of the total hydrogen ions of the acidic substance contained in the second dose) is 1.1 to 10:1. Alternatively, the first dose of the foaming drain cleaner may contain 0.3 to 10% by weight of the pH adjuster relative to the total weight of the first dose composition. In this case, the foaming drain cleaner significantly suppresses the generation of chlorine gas, making it safe for human health.

另外,上述发泡清洗用排水管清洗剂中可以包含1:1~10:1当量比(次氯酸盐:过氧化氢)的上述次氯酸盐以及过氧化氢。在这种情况下,上述发泡清洗用排水管清洗剂组合物的泡沫产生量得以显著提升,并且,对过滤网、排水口以及排水管的杀菌、消毒效果非常优异。Furthermore, the foaming drain cleaner composition may contain the hypochlorite and hydrogen peroxide at an equivalent ratio (hypochlorite:hydrogen peroxide) of 1:1 to 10:1. In this case, the foaming drain cleaner composition significantly increases the amount of foam generated and exhibits excellent sterilization and disinfection effects on filters, drain outlets, and drain pipes.

另外,本发明提供一种发泡清洗用排水管清洗套装,其包括上述发泡清洗用排水管清洗容器以及上述发泡清洗用排水管清洗剂。上述套装可以应用于普遍使用者方便且有效地清洗厨房水槽的过滤网、排水口以及排水管。The present invention also provides a foaming drain cleaning kit comprising the foaming drain cleaning container and the foaming drain cleaning agent. The kit can be used by a general user to conveniently and effectively clean the filter, drain outlet, and drain pipe of a kitchen sink.

优选地,本发明提供一种发泡清洗用排水管清洗套装,其特征在于,包括:发泡清洗用排水管清洗剂,该发泡清洗用排水管清洗剂包括含有次氯酸盐的第一剂和含有过氧化氢的第二剂;以及,发泡清洗用排水管清洗容器,该发泡清洗用排水管清洗容器包括具有形成于内部的容纳空间的容器本体和使发泡清洗用排水管清洗剂流入所述容纳空间的流入口,且所述容纳空间的体积小于所述发泡清洗用排水管清洗剂的总体积。Preferably, the present invention provides a drain pipe cleaning kit for foaming cleaning, characterized in that it comprises: a drain pipe cleaning agent for foaming cleaning, the drain pipe cleaning agent for foaming cleaning including a first agent containing hypochlorite and a second agent containing hydrogen peroxide; and a drain pipe cleaning container for foaming cleaning, the drain pipe cleaning container for foaming cleaning including a container body having a storage space formed therein and an inlet for allowing the drain pipe cleaning agent for foaming cleaning to flow into the storage space, and the volume of the storage space is smaller than the total volume of the drain pipe cleaning agent for foaming cleaning.

对上述清洗套装而言,当将包含于其中的清洗容器与清洗剂同时使用时,由于清洗容器的容纳空间小于清洗剂的总体积,因此,产生了丰富泡沫的清洗剂会通过流入口溢出并流淌,从而能够有效地清洗过滤网和排水口。For the above-mentioned cleaning kit, when the cleaning container and the cleaning agent included therein are used simultaneously, since the storage space of the cleaning container is smaller than the total volume of the cleaning agent, the cleaning agent with rich foam will overflow and flow through the inlet, thereby effectively cleaning the filter and the drain outlet.

更加具体地,所述容纳空间的体积可以小于发泡状态下的排水管清洗剂的第一剂和第二剂的混合物以及由此产生的气泡的体积,因此,发泡清洗用排水管清洗剂的第一剂和第二剂的混合物或其气泡会通过所述容纳空间的流入口溢出并流淌,从而对过滤网和排水口的清洗能力十分优异。当所述容纳空间的体积大于第一剂和第二剂的混合物以及气泡体积的和时,由于清洗剂不会通过流入口溢出,因此,对位于清洗容器上部的过滤网,无法充分地发挥清洗效果。More specifically, the volume of the storage space can be smaller than the volume of the mixture of the first and second doses of the drain cleaner in a foaming state and the bubbles generated thereby. Therefore, the mixture of the first and second doses of the foaming drain cleaner or the bubbles generated thereby can overflow and flow through the inlet of the storage space, thereby effectively cleaning the filter and drain outlet. If the volume of the storage space is larger than the combined volume of the mixture of the first and second doses and the bubbles, the cleaning agent will not overflow through the inlet, and thus, the filter located above the cleaning container will not be adequately cleaned.

在本发明中,上述容纳空间的体积以及上述发泡清洗剂的体积的体积比可以为1:1.01~5,优选为1:1.05~3,更优选为1:1.1~2(容纳空间的体积:发泡后的清洗剂的体积)。当相对于所述容纳空间的体积,发泡清洗剂的体积低于1:1.01(容纳空间的体积:发泡后的清洗剂的体积)时,发泡清洗剂不会溢出容器或少量地溢出,因此,清洗效果会微弱。而相对于所述容纳空间的体积,发泡后的清洗剂的体积超过1:5(容纳空间的体积:发泡后的清洗剂的体积)时,存在着发泡后的清洗剂会过度地溢出至排水口周围的水槽底部的问题。In the present invention, the volume ratio of the volume of the above-mentioned storage space and the volume of the above-mentioned foaming cleaning agent can be 1:1.01-5, preferably 1:1.05-3, and more preferably 1:1.1-2 (volume of the storage space: volume of the cleaning agent after foaming). When the volume of the foaming cleaning agent relative to the volume of the storage space is less than 1:1.01 (volume of the storage space: volume of the cleaning agent after foaming), the foaming cleaning agent will not overflow the container or will overflow in small amounts, so the cleaning effect will be weak. If the volume of the foamed cleaning agent relative to the volume of the storage space exceeds 1:5 (volume of the storage space: volume of the cleaning agent after foaming), there is a problem that the foamed cleaning agent will excessively overflow to the bottom of the sink around the drain outlet.

另外,本发明提供一种使用所述发泡清洗用排水管清洗容器,发泡清洗厨房水槽的过滤网以及排水管的发泡清洗方法。将使用上述发泡清洗用排水管清洗剂以及清洗容器的本发明的清洗方法示于图2。The present invention also provides a method for foaming and cleaning a kitchen sink filter and a drainpipe using the foaming drainpipe cleaning container. FIG2 shows the cleaning method of the present invention using the foaming drainpipe cleaning agent and the cleaning container.

所述清洗方法,包括:S1步骤,将上述发泡清洗用排水管清洗容器安装在排水口;以及S2步骤,将上述清洗剂的第一剂组合物和第二剂组合物同时或依次倒入所述清洗容器的容纳空间中。其中,在上述S2步骤中,将第一剂组合物和第二剂组合物依次倒入时,其倒入的顺序没有关系。The cleaning method comprises: step S1, installing the aforementioned foaming cleaning drainpipe cleaning container at the drain outlet; and step S2, simultaneously or sequentially pouring the aforementioned first and second cleaning agent compositions into the receiving space of the cleaning container. In step S2, when the first and second compositions are poured sequentially, the order of pouring is irrelevant.

在上述发泡清洗厨房水槽的过滤网和排水管的方法中,在上述S2步骤之后,通过第一剂组合物和第二剂组合物的混合引起发泡,从上述清洗容器的流入口溢出的泡沫清洗过滤网,液相的发泡清洗剂通过排出口缓慢地流出,从而对排水管持续地发挥清洗效果,因此,本发明的清洗方法能够同时有效地清洗过滤网和排水管。In the above-mentioned method for foaming and cleaning the filter and drain pipe of a kitchen sink, after the above-mentioned step S2, foaming is caused by mixing the first composition and the second composition. The foam overflows from the inlet of the above-mentioned cleaning container to clean the filter, and the liquid foaming cleaning agent slowly flows out through the outlet, thereby continuously exerting a cleaning effect on the drain pipe. Therefore, the cleaning method of the present invention can effectively clean the filter and the drain pipe at the same time.

发明效果Effects of the Invention

本发明的发泡清洗用排水管清洗容器使发泡清洗剂的泡沫溢出至厨房水槽的过滤网和排水口处,从而能够有效地对其进行清洗,并且使发泡清洗用排水管清洗剂缓慢地流入排水管,能够针对排水管持续地发挥清洗效果。The foaming drain cleaning container of the present invention allows the foam of the foaming cleaning agent to overflow onto the filter screen and drain outlet of the kitchen sink, thereby effectively cleaning them, and allows the foaming drain cleaning agent to slowly flow into the drain pipe, thereby continuously exerting a cleaning effect on the drain pipe.

另外,根据本发明的排水管清洗剂组合物,当包含特定重量比的氯系清洗剂成分和发泡剂时,会产生丰富的泡沫,从而针对水槽的过滤网、排水口以及排水管具有非常优异的杀菌、清洗效果。In addition, the drain cleaning composition of the present invention, when containing a chlorine-based cleaning agent component and a foaming agent in a specific weight ratio, can generate abundant foam, thereby having a very excellent sterilization and cleaning effect on the filter screen, drain outlet and drain pipe of the sink.

另外,当本发明的排水管清洗剂组合物还包含pH调节剂时,能够将混合第一剂和第二剂时的pH值保持在9以上,从而能够显著地抑制由氯系清洗剂成分与发泡剂的反应引起的氯气的产生,进而能够发挥安全、优异的清洗效果。In addition, when the drain cleaning composition of the present invention further contains a pH adjuster, the pH value when the first and second agents are mixed can be maintained at or above 9, thereby significantly suppressing the generation of chlorine gas caused by the reaction between the chlorine-based cleaning agent components and the foaming agent, thereby achieving a safe and excellent cleaning effect.

另外,本发明的发泡清洗用排水管清洗套装,使发泡清洗剂的泡沫从清洗容器中溢出,从而能够有效地清洗厨房水槽的过滤网以及排水口。In addition, the foaming cleaning drain pipe cleaning kit of the present invention allows the foam of the foaming cleaning agent to overflow from the cleaning container, thereby effectively cleaning the filter screen and drain outlet of the kitchen sink.

附图说明BRIEF DESCRIPTION OF THE DRAWINGS

图1表示本发明的发泡清洗用排水管清洗容器的一实施例。FIG1 shows an embodiment of a drainpipe cleaning container for foaming cleaning according to the present invention.

图2表示使用本发明的发泡清洗用排水管清洗剂以及清洗容器,发泡清洗厨房水槽的过滤网以及排水管的方法。FIG2 shows a method for foaming and cleaning a filter screen and a drain pipe of a kitchen sink using the foaming drain pipe cleaner and the cleaning container of the present invention.

图3和图4表示使用本发明的发泡清洗用排水管清洗剂以及清洗容器,对过滤网以及排水管进行清洗前(左侧)以及清洗后(右侧)的照片。3 and 4 show photographs of a filter and a drain pipe before (left side) and after (right side) cleaning using the foaming drain pipe cleaning agent and cleaning container of the present invention.

图5是表示本发明的反应杯子的一实施例的图。FIG. 5 is a diagram showing an embodiment of a reaction cup according to the present invention.

图6和图7是在实验例2中对排水管进行比较例的处理前、后的对比照片。FIG6 and FIG7 are comparative photographs of the drainage pipe before and after treatment in Experimental Example 2 as a comparative example.

图8和图9是在实验例2中对排水管进行实施例的处理前、后的对比照片。FIG8 and FIG9 are comparative photos of the drain pipe before and after being treated according to the embodiment in Experimental Example 2. FIG.

图10是表示实验例4中将实施例13的第一剂和第二剂进行混合后对氯气浓度的GC/MS分析结果的图表。FIG10 is a graph showing the GC/MS analysis results of chlorine gas concentration after mixing the first agent and the second agent of Example 13 in Experimental Example 4.

图11是表示实验例4中将比较例4的第一剂和第二剂进行混合后对氯气浓度的GC/MS分析结果的图表。11 is a graph showing the results of GC/MS analysis of chlorine gas concentration after mixing the first agent and the second agent of Comparative Example 4 in Experimental Example 4.

图12表示包含网眼构件的发泡清洗用排水管清洗容器的一实施例。FIG. 12 shows an embodiment of a drainpipe cleaning container for foaming cleaning including a mesh member.

具体实施方式DETAILED DESCRIPTION

以下,为了帮助理解本发明,将举出实施例进行详细说明。然而,本发明的实施例能够以各种方式进行修改,并且,不应当理解为本发明的范围限定于下述实施例。本发明的实施例,是为了向本领域的普通技术人员更完整地说明本发明而提供。Below, in order to help understand the present invention, the following embodiments will be described in detail. However, the embodiments of the present invention can be modified in various ways, and it should not be understood that the scope of the present invention is limited to the following embodiments. The embodiments of the present invention are provided to more fully illustrate the present invention to those of ordinary skill in the art.

实施例:制造发泡清洗用排水管清洗剂Example: Manufacturing a foaming drain cleaning agent

按照下述表1和表2的组成比率,将原料成分进行混合并搅拌,从而制造了第一剂组合物和第二剂组合物。The raw material components were mixed and stirred according to the composition ratios shown in Tables 1 and 2 below to produce a first composition and a second composition.

【表1】【Table 1】

第一剂组合物First dose composition

原料名称Raw material name 重量比Weight ratio 11 纯净水purified water 加入至100Add to 100 22 次氯酸钠(12%)Sodium hypochlorite (12%) 20%20% 33 SLES(3mol,27%)SLES (3 mol, 27%) 5%5% 44 月桂基胺氧化物Laurylamine oxide 1%1% 55 香料spices 0.1%0.1%

【表2】【Table 2】

第二剂组合物Second dose composition

原料名称Raw material name 重量比Weight ratio 11 纯净水purified water 加入至100Add to 100 22 过氧化氢(35%)Hydrogen peroxide (35%) 20%20% 33 SLESSLES 5%5% 44 水杨酸salicylic acid 1%1% 55 硫酸钠sodium sulfate 0.5%0.5% 66 香料spices 0.1%0.1%

清洗容器制作成图5的一实施例中表示的杯子形态的容器。将所述第一剂和第二剂组合物与清洗容器同时使用时,确认到第一剂以及第二剂的发泡性混合物通过流入口溢出,能够清洗过滤网,发泡性液相组合物通过贯穿于杯子上的排出口持续地排出。The cleaning container was fabricated in the form of a cup, as shown in one embodiment of FIG5 . When the first and second compositions were used simultaneously with the cleaning container, it was confirmed that the foamable mixture of the first and second compositions overflowed through the inlet, cleaning the filter, and the foamable liquid composition was continuously discharged through the outlet provided through the cup.

实验例1:清洗容器的使用对排水口杀菌能力以及清洗能力的测评Experimental Example 1: Evaluation of the Sterilization and Cleaning Capacity of Drain Outlets Using a Cleaning Container

拜访了6个家庭,利用本发明的第一剂和第二剂以及杯状的清洗容器,对水槽的排水管进行了1.5小时的清洗处理后,测评了排水口处的微生物数量。从下述表3中表示的实验结果可以确认到,在排水管中,平均99.93%的微生物被杀灭,因此,其杀菌效果优异。Six households were visited and their sink drains were cleaned for 1.5 hours using the first and second doses of the present invention and a cup-shaped cleaning container. The number of microorganisms at the drain outlets was then measured. The experimental results, shown in Table 3 below, confirmed that an average of 99.93% of microorganisms in the drains were eliminated, demonstrating excellent sterilization effectiveness.

【表3】【Table 3】

处理前后的微生物杀灭率Microbial killing rate before and after treatment

另外,在图3和图4中示出了清洗前(左侧)以及清洗后(右侧)的照片。可以确认到,当使用本发明的发泡性清洗剂组合物以及清洗容器时,针对过滤网和排水口的清洗效果非常优异。3 and 4 show photographs before cleaning (left) and after cleaning (right). It was confirmed that the foaming cleaning composition of the present invention and the cleaning container have excellent cleaning effects on the filter and the drain port.

实验例2:清洗容器使用对排水管杀菌能能力以及清洗能力的测评Experimental Example 2: Evaluation of the sterilization and cleaning capabilities of drain pipes using cleaning containers

拜访了7个家庭,利用本发明的第一剂和第二剂以及杯状的清洗容器,对水槽的排水管进行了1.5小时的清洗处理后,测评了排水管中的微生物的数量。Seven households were visited. After cleaning the drain pipes of sinks for 1.5 hours using the first and second agents of the present invention and a cup-shaped cleaning container, the number of microorganisms in the drain pipes was evaluated.

在实施例中,将反应杯放入水槽中,倒入500ml的第一剂后再倒入250ml的第二剂,然后放置了1.5小时。在比较例中,向水槽中同时倒入500ml的第一剂和250ml的第二剂后,放置了1.5小时。之后,采取了距离水槽排水管的管道入口约10cm处的微生物试样,并进行了测量。In the Example, a cuvette was placed in a sink, 500 ml of the first dose was poured in, followed by 250 ml of the second dose, and then allowed to stand for 1.5 hours. In the Comparative Example, 500 ml of the first dose and 250 ml of the second dose were poured simultaneously into the sink and allowed to stand for 1.5 hours. A microbial sample was then collected and measured approximately 10 cm from the sink drainpipe entrance.

从下述表4中示出的实验结果可知,未使用反应杯的比较例1~3中,表现出了57.10%的平均杀菌能力,与此相比,在利用了反应杯的实施例1~4的排水管中,表现出了99.95%的平均杀菌能力。由此能够确认到,使用本发明的反应杯时,其杀菌效果非常优异。The experimental results shown in Table 4 below show that Comparative Examples 1 to 3, which did not use a cuvette, exhibited an average sterilization efficiency of 57.10%. In contrast, the drain pipes of Examples 1 to 4, which used a cuvette, exhibited an average sterilization efficiency of 99.95%. This confirms that the cuvette of the present invention exhibits a very excellent sterilization effect.

【表4】【Table 4】

另外,图6和图7中示出了比较例的清洗之前(图6)以及清洗之后(图7)的照片,图8和图9中示出了实施例的清洗之前(图8)以及清洗之后(图9)的照片。根据上述结果确认到,当使用本发明的发泡性清洗剂组合物以及排水管清洗容器时,对排水管的清洗效果非常优异。6 and 7 show photographs of the comparative example before cleaning ( FIG. 6 ) and after cleaning ( FIG. 7 ), and FIG. 8 and 9 show photographs of the example before cleaning ( FIG. 8 ) and after cleaning ( FIG. 9 ). These results confirm that the foaming cleaning composition and drain cleaning container of the present invention provide a very excellent drain cleaning effect.

实验例3:排出口的直径以及数量对排出时间以及杀菌能力的测评Experimental Example 3: Evaluation of the Diameter and Number of Discharge Ports on Discharge Time and Sterilization Capacity

为了测评排出口的直径以及数量对排出时间以及杀菌能力的影响,根据上述表1和表2的组成比制造了第一剂和第二剂。之后,向分别具有下述表5所示的排出口大小以及数量的杯状的清洗容器中,倒入500ml的第一剂和250ml的第二剂后,测量了内容物全部排出所需的时间。To evaluate the effects of the diameter and number of discharge ports on discharge time and sterilization performance, the first and second doses were prepared according to the composition ratios listed in Tables 1 and 2. Subsequently, 500 ml of the first dose and 250 ml of the second dose were poured into cup-shaped cleaning containers having the corresponding discharge port sizes and numbers shown in Table 5. The time required for complete discharge was measured.

【表5】【Table 5】

根据上述表5所示的结果确认到,当排出口的直径为1~2.5mm,且数量为2~5个时(实施例10~12),发泡清洗剂的排出时间约为30分钟~2小时。并且,发现当所述发泡组合物的排出时间大于30分钟时,表现出了99.9%以上的微生物杀灭率,而超过2小时之后,难以获得杀菌能力继续增强的效果。The results shown in Table 5 above confirm that when the diameter of the discharge outlet is 1 to 2.5 mm and the number of outlets is 2 to 5 (Examples 10 to 12), the discharge time of the foaming cleaning agent is approximately 30 minutes to 2 hours. Furthermore, it was found that when the foaming composition is discharged for a time greater than 30 minutes, a microbial kill rate exceeding 99.9% is achieved, while after 2 hours, further enhanced sterilization performance is difficult to achieve.

实验例4:混合包含pH调节剂的清洗剂组合物后的氯气浓度Experimental Example 4: Chlorine Concentration after Mixing a Cleaning Composition Containing a pH Adjuster

按照下述表6所示的组成比率,将原料成分混合并搅拌,从而制成了本发明的比较例以及实施例的第一剂组合物和第二剂组合物。The raw material components were mixed and stirred according to the composition ratios shown in Table 6 below to prepare first and second compositions of comparative examples and examples of the present invention.

将第一剂的NaOH含量设定成各不相同而制造的比较例和实施例的第一剂和第二剂组合物,以1:1的比率进行混合后,利用气相色谱分析法对pH以及氯气产生量进行了分析。The first and second compositions of Comparative Examples and Examples, prepared with different NaOH contents in the first composition, were mixed at a ratio of 1:1 and analyzed for pH and chlorine gas generation by gas chromatography.

【表6】【Table 6】

根据上述表6所示的实验结果可以确认到,如同比较例4和比较例5,当第一剂中的NaOH含量低于0.2%时,混合后的pH值低于9,并且产生明显大量的氯气。According to the experimental results shown in Table 6, it can be confirmed that, like Comparative Examples 4 and 5, when the NaOH content in the first agent is less than 0.2%, the pH value after mixing is less than 9, and a significant amount of chlorine gas is generated.

相反,根据图10以及图11所示的对实施例13的氯气产生量的分析结果,可以确认到,实施例13中的氯气浓度为15.3ppm,与比较例相比氯气的产生量明显低。作为参考,实施例13中的氯气浓度是明显低于毒性浓度(LC50)293ppm的浓度。In contrast, the analysis results of chlorine gas generation in Example 13, shown in Figures 10 and 11, confirm that the chlorine gas concentration in Example 13 was 15.3 ppm, significantly lower than that in the Comparative Example. For reference, the chlorine gas concentration in Example 13 was significantly lower than the toxic concentration (LC50) of 293 ppm.

实验例5:包含pH调节剂的清洗剂组合物的杀菌能力的测评Experimental Example 5: Evaluation of the Bactericidal Ability of a Cleaning Composition Containing a pH Adjuster

拜访了6个家庭,利用对应于本发明实施例13的组合物的500ml的第一剂和500ml的第二剂,以及下端贯穿有4个直径为1mm的孔的杯形状反应容器,对水槽的排水管进行了1.5小时的清洗处理后,测评了排水口处的微生物的数量。Six households were visited and their sink drains were cleaned for 1.5 hours using 500 ml of the first dose and 500 ml of the second dose of the composition corresponding to Example 13 of the present invention, along with a cup-shaped reaction container having four holes with a diameter of 1 mm at the bottom. The number of microorganisms at the drain outlet was then measured.

【表7】【Table 7】

处理前后的微生物杀灭率Microbial killing rate before and after treatment

根据上述表7所示的实验结果,可以确认到,排水管中的平均99.93%的微生物被杀灭,杀菌效果优异。According to the experimental results shown in Table 7, it was confirmed that an average of 99.93% of the microorganisms in the drainage pipe were killed, indicating an excellent sterilization effect.

实验例6:根据次氯酸盐与过氧化氢的当量比的清洗剂泡沫产生量的测评Experimental Example 6: Evaluation of the amount of foam generated by cleaning agents based on the equivalent ratio of hypochlorite to hydrogen peroxide

【表8】【Table 8】

第一剂组合物First dose composition

根据上述表8和表2所示的组成,制造第一剂和第二剂后,以下述表9所示的当量比,分别制造了比较例和实施例。After preparing the first and second agents according to the compositions shown in Table 8 and Table 2, comparative examples and examples were prepared at the equivalent ratios shown in Table 9 below.

【表9】【Table 9】

第一剂次氯酸钠(mol)First dose of sodium hypochlorite (mol) 第二剂过氧化氢(mol)Second dose of hydrogen peroxide (mol) 比较例6Comparative Example 6 0.790.79 11 比较例7Comparative Example 7 10.5910.59 11 实施例16Example 16 1.261.26 11 实施例17Example 17 3.163.16 11 实施例18Example 18 5.535.53 11

向3500mL的烧杯中倒入500ml的第一剂后,再倒入250ml的第二剂,测量了所产生的气泡量和破泡时间,将结果示于下述表10中。After 500 ml of the first dose was poured into a 3500 mL beaker, 250 ml of the second dose was poured therein, and the amount of bubbles generated and the bubble bursting time were measured. The results are shown in Table 10 below.

【表10】【Table 10】

泡沫量以及破泡时间的测评结果Evaluation results of foam volume and foam breaking time

比较例6Comparative Example 6 比较例7Comparative Example 7 实施例16Example 16 实施例17Example 17 实施例18Example 18 初期泡沫量Initial foam volume 2500ml2500ml 1300ml1300ml 2400ml2400ml 2200ml2200ml 1900ml1900ml 破泡时间Bubble breaking time 150分钟150 minutes 40分钟40 minutes 140分钟140 minutes 120分钟120 minutes 70分钟70 minutes

根据上述表10所示的结果可知,在次氯酸钠当量比超过10:1(次氯酸盐:过氧化氢)的比较例7中,初期产生的泡沫量比较少。并且,由于比较例7的破泡时间也短,不适合清洗剂组合物长时间滞留在排水管中表现出充分的清洗能力的情况。The results shown in Table 10 above indicate that in Comparative Example 7, where the sodium hypochlorite equivalent ratio exceeded 10:1 (hypochlorite:hydrogen peroxide), the amount of foam generated initially was relatively small. Furthermore, since the foam burst time in Comparative Example 7 was also short, it is not suitable for situations where the cleaning composition remains in the drainpipe for an extended period of time and exhibits sufficient cleaning performance.

实验例7:混合溶液的排水管杀菌能力以及清洗能力的测评Experimental Example 7: Evaluation of the sterilization and cleaning capabilities of mixed solutions for drain pipes

针对将实验例6的比较例以及实施例中的500ml第一剂和250ml第二剂加以混合后的溶液,进行了杀菌能力以及清洗能力的测评。拜访了5个家庭,利用上述第一剂和第二剂的清洗剂组合物以及本发明的清洗容器,对水槽的排水管进行了1.5小时的清洗处理。之后,测评了排水口处的微生物的数量,并确认了污染去除程度。The bactericidal and cleaning abilities of solutions prepared by mixing 500 ml of the first agent and 250 ml of the second agent from the comparative example and example of Experimental Example 6 were evaluated. Five households were visited and sink drains were cleaned for 1.5 hours using the first and second agent cleaning compositions and the cleaning container of the present invention. Afterwards, the number of microorganisms at the drain outlet was measured to confirm the degree of contamination removal.

【表11】【Table 11】

处理前后的微生物杀灭率Microbial killing rate before and after treatment

处理前(CFU/mL)Before treatment (CFU/mL) 处理后(CFU/mL)After treatment (CFU/mL) 杀灭率(%)Killing rate (%) 比较例6Comparative Example 6 5.6E+075.6E+07 5.9E+065.9E+06 89.4689.46 比较例7Comparative Example 7 5.1E+075.1E+07 4.8E+054.8E+05 99.0699.06 实施例16Example 16 3.1E+083.1E+08 1.6E+051.6E+05 99.9599.95 实施例17Example 17 4.3E+074.3E+07 1.9E+041.9E+04 99.9699.96 实施例18Example 18 7.7E+077.7E+07 3.4E+043.4E+04 99.9699.96

根据上述表11所示的实验结果可以确认到,当第一剂中的次氯酸钠的含量低时,即,如比较例6,当相对于第二剂中的过氧化氢的当量,次氯酸钠的当量为0.79倍时,第一剂与第二剂反应后所剩余的次氯酸钠的量少,因此,杀菌能力的发挥微弱。此外,如比较例7,当相对于过氧化氢,次氯酸钠的当量多,即为10.59倍时,由于排水管中无法充分地留有泡沫,杀菌能力还是无法发挥到最大化。The experimental results shown in Table 11 above confirm that when the sodium hypochlorite content in the first dose is low, that is, when the equivalent of sodium hypochlorite relative to the equivalent of hydrogen peroxide in the second dose is 0.79 times, as in Comparative Example 6, the amount of sodium hypochlorite remaining after the reaction between the first and second doses is small, resulting in a weak bactericidal effect. Furthermore, when the equivalent of sodium hypochlorite relative to hydrogen peroxide is high, that is, 10.59 times, as in Comparative Example 7, the bactericidal effect is not maximized because sufficient foam is not retained in the drainpipe.

另外,通过第一剂和第二剂的混合溶液对所拜访家庭的水槽的排水口进行1.5小时的清洗处理后,用肉眼确认了过滤网和排水管的污染去除程度,将清洗能力的测评结果示于表12中。In addition, after cleaning the drain outlets of the sinks of the visited households with the mixed solution of the first and second doses for 1.5 hours, the degree of contamination removal in the filters and drain pipes was visually confirmed. The cleaning performance evaluation results are shown in Table 12.

【表12】【Table 12】

处理后的污染去除测评Pollution removal evaluation after treatment

比较例6Comparative Example 6 比较例7Comparative Example 7 实施例16Example 16 实施例17Example 17 实施例18Example 18 水槽过滤网Sink filter 排水管drain pipe XX

(◎:非常好;○:好;△:一般;X:不好)(◎: Very good; ○: Good; △: Average; X: Not good)

从上述表12可以确认到,当第一剂中的次氯酸钠的含量低时,即,如比较例6,当相对于过氧化氢,次氯酸钠的当量为0.79倍时,清洗能力的发挥弱。此外,在比较例7中,虽然相对于过氧化氢,次氯酸钠的当量高,即为10.59倍,但是,由于清洗泡沫没能充分地滞留于排水管的内壁,导致清洗能力没能正常发挥。Table 12 above confirms that when the sodium hypochlorite content in the first dose is low, that is, when the sodium hypochlorite equivalent to hydrogen peroxide is 0.79 times, as in Comparative Example 6, the cleaning performance is weak. Furthermore, in Comparative Example 7, although the sodium hypochlorite equivalent to hydrogen peroxide is high, namely 10.59 times, the cleaning foam does not sufficiently remain on the inner wall of the drainpipe, resulting in poor cleaning performance.

实验例8:清洗容器的网眼构件对排水口杀菌能力以及清洗能力的测评Experimental Example 8: Evaluation of the sterilization and cleaning capabilities of the mesh component of the cleaning container

拜访了8个家庭,向2个家庭的水槽的排水口安装了无网眼构件的清洗容器,向6个家庭安装了附着有网眼构件的清洗容器,并通过第一剂和第二剂进行处理。对水槽排水管进行了1.5小时的清洗处理后,测评了排水口的微生物数量。We visited eight households, installed non-mesh cleaning containers in the sink drains of two households, and installed mesh cleaning containers in six households. We then treated the sink drains with both the first and second doses. After cleaning the sink drains for 1.5 hours, we measured the number of microorganisms in the drains.

根据下述表13所示的实验结果可以确认到,利用附着有网眼构件的清洗容器处理了清洗剂的排水管中,有平均99.87%的微生物被杀灭。由该结果可以确认到,与利用无网眼构件的清洗容器进行处理的比较例相比,利用附着有网眼构件的清洗容器进行处理的实施例的杀菌能力明显高。The experimental results shown in Table 13 below confirm that an average of 99.87% of microorganisms were killed in drainpipes treated with cleaning agents using a cleaning container with a mesh member. These results confirm that the Example, treated with a cleaning container with a mesh member, exhibited significantly higher sterilization capabilities than the Comparative Example, treated with a cleaning container without a mesh member.

【表13】【Table 13】

处理前后的微生物杀灭率Microbial killing rate before and after treatment

处理前(CFU/mL)Before treatment (CFU/mL) 处理后(CFU/mL)After treatment (CFU/mL) 杀灭率(%)Killing rate (%) 比较例8Comparative Example 8 2.6E+072.6E+07 2.5E+062.5E+06 90.3890.38 比较例9Comparative Example 9 1.1E+071.1E+07 2.3E+052.3E+05 97.9197.91 比较例平均Comparative example average 94.1594.15 实施例19Example 19 3.1E+063.1E+06 1.9E+031.9E+03 99.9499.94 实施例20Example 20 1.5E+071.5E+07 2.3E+042.3E+04 99.8599.85 实施例21Example 21 6.5E+076.5E+07 3.9E+043.9E+04 99.9499.94 实施例22Example 22 2.2E+072.2E+07 5.0E+045.0E+04 99.7799.77 实施例23Example 23 1.7E+071.7E+07 3.8E+043.8E+04 99.7899.78 实施例24Example 24 5.2E+065.2E+06 1.6E+031.6E+03 99.9799.97 实施例平均Example average 99.8799.87

另外,用肉眼对污染的去除程度进行了判定后,将清洗能力的测评结果示于下述表14中。由下述表14所示的结果可以确认到,与比较例相比,实施例在整体上表现出了优异的清洗能力。由该结果可以确认到,清洗容器中处理的第一剂和第二剂的混合液,在通过网眼构件的过程中形成了稠密的泡沫,通过该清洗泡沫附着在排水管的壁面,更加有效地去除了污染。【表14】In addition, the degree of contamination removal was visually assessed, and the cleaning performance evaluation results are shown in Table 14 below. The results shown in Table 14 below confirm that the Examples exhibited superior cleaning performance overall compared to the Comparative Examples. These results confirm that the mixed solution of the first and second agents processed in the cleaning container formed dense foam as it passed through the mesh member. This foam adhered to the wall of the drainpipe, effectively removing contamination. [Table 14]

处理前后的清洗能力的对比测评Comparative evaluation of cleaning ability before and after treatment

(◎:非常好,○:好,△:一般,X:不好)。(◎: very good, ○: good, △: average, X: not good).

Claims (26)

1.一种发泡清洗用排水管清洗容器,包括:1. A drain pipe for cleaning containers using foaming cleaning, comprising: 容器本体,具有形成于内部的容纳空间;The container body has an internal containing space; 流入口,使发泡清洗用排水管清洗剂流入所述容纳空间;以及,The inlet allows the foaming cleaning agent to flow into the receiving space; and... 至少一个排出口,形成于所述容器本体,以使所述容器本体的所述容纳空间与排水管连通,将容纳于所述容纳空间的清洗剂向所述排水管排出,At least one outlet is formed in the container body so that the receiving space of the container body is in communication with a drain pipe, so that the cleaning agent contained in the receiving space is discharged into the drain pipe. 与将清洗剂立即用于排水管处理的情况相比,所述排出口以更缓慢的速度排出所述清洗剂。Compared to applying the cleaning agent immediately to the drain pipe, the outlet discharges the cleaning agent at a slower rate. 2.如权利要求1所述的发泡清洗用排水管清洗容器,其特征在于,所述清洗容器安装在用于与所述排水管相连接的排水口上。2. The foaming cleaning drain pipe cleaning container as described in claim 1, characterized in that the cleaning container is installed on a drain outlet for connection with the drain pipe. 3.如权利要求1所述的发泡清洗用排水管清洗容器,其特征在于,3. The foaming cleaning drain pipe for cleaning containers as described in claim 1, characterized in that, 所述清洗容器的直径从上至下逐渐减小。The diameter of the cleaning container gradually decreases from top to bottom. 4.如权利要求1所述的发泡清洗用排水管清洗容器,其特征在于,4. The foaming cleaning drain pipe for cleaning containers as described in claim 1, characterized in that, 所述清洗容器包含以预设间隔设置有凹凸槽的凹凸结构,以使通过所述流入口排出的清洗剂能够沿着外表面流淌。The cleaning container includes a textured structure with grooves at preset intervals, so that the cleaning agent discharged through the inlet can flow along the outer surface. 5.如权利要求1所述的发泡清洗用排水管清洗容器,其特征在于,5. The foaming cleaning drain pipe for cleaning containers as described in claim 1, characterized in that, 所述排出口具有预设的直径,以使所述清洗剂能够通过所述排出口以1~100ml/min的速度排出。The outlet has a preset diameter so that the cleaning agent can be discharged through the outlet at a rate of 1 to 100 ml/min. 6.如权利要求5所述的发泡清洗用排水管清洗容器,其特征在于,6. The foaming cleaning drain pipe for cleaning containers as described in claim 5, characterized in that, 所述预设的直径为0.1~10mm。The preset diameter is 0.1 to 10 mm. 7.如权利要求1所述的发泡清洗用排水管清洗容器,其特征在于,7. The foaming cleaning drain pipe for cleaning containers as described in claim 1, characterized in that, 所述排出口具有预设的直径和数量,以使所述清洗剂通过所述排出口排出10~180分钟。The outlet has a preset diameter and number to allow the cleaning agent to be discharged through the outlet for 10 to 180 minutes. 8.如权利要求7所述的发泡清洗用排水管清洗容器,其特征在于,8. The foaming cleaning drain pipe for cleaning containers as described in claim 7, characterized in that, 所述排出口的预设的直径为0.1~10mm。The preset diameter of the outlet is 0.1 to 10 mm. 9.如权利要求7所述的发泡清洗用排水管清洗容器,其特征在于,9. The foaming cleaning drain pipe for cleaning containers as described in claim 7, characterized in that, 所述排出口的数量为1~8个。The number of discharge outlets is 1 to 8. 10.如权利要求1所述的发泡清洗用排水管清洗容器,其特征在于,10. The foaming cleaning drain pipe for cleaning containers as described in claim 1, characterized in that, 所述清洗容器包括使发泡清洗用排水管清洗剂通过的网眼构件。The cleaning container includes a mesh component that allows foamed cleaning agent for drain pipes to pass through. 11.如权利要求10所述的发泡清洗用排水管清洗容器,其特征在于,11. The foaming cleaning drain pipe for cleaning containers as described in claim 10, characterized in that, 所述网眼构件形成于所述流入口。The mesh component is formed at the inlet. 12.如权利要求10所述的发泡清洗用排水管清洗容器,其特征在于,12. The foaming cleaning drain pipe for cleaning containers as described in claim 10, characterized in that, 所述网眼构件为网状。The mesh component is mesh-like. 13.如权利要求10所述的发泡清洗用排水管清洗容器,其特征在于,13. The foaming cleaning drain pipe for cleaning containers as described in claim 10, characterized in that, 所述网眼构件的孔径大小为100~10000μm。The mesh component has a pore size of 100 to 10000 μm. 14.如权利要求1所述的发泡清洗用排水管清洗容器,其特征在于,14. The foaming cleaning drain pipe for cleaning containers as described in claim 1, characterized in that, 所述发泡清洗用排水管清洗剂包括:含有氯系清洗剂成分的第一剂、含有发泡剂的第二剂以及pH调节剂。The foaming cleaning agent for drain pipes includes: a first agent containing chlorine-based cleaning agents, a second agent containing foaming agents, and a pH adjuster. 15.如权利要求1所述的发泡清洗用排水管清洗容器,其中,15. The drain pipe for cleaning containers using foaming cleaning as described in claim 1, wherein, 所述发泡清洗用排水管清洗剂包括:含有氯系清洗剂成分的第一剂、含有发泡剂的第二剂以及pH调节剂,The foaming cleaning agent for drain pipes comprises: a first agent containing chlorine-based cleaning agents, a second agent containing a foaming agent, and a pH adjuster. 所述发泡清洗用排水管清洗剂在混合所述第一剂和所述第二剂时的pH值为9~14。The pH value of the foaming cleaning drain cleaner is 9-14 when the first agent and the second agent are mixed. 16.如权利要求15所述的发泡清洗用排水管清洗容器,其特征在于,16. The foaming cleaning drain pipe for cleaning containers as described in claim 15, characterized in that, 所述pH调节剂包含于所述第一剂中。The pH adjuster is contained in the first agent. 17.如权利要求16所述的发泡清洗用排水管清洗容器,其特征在于,17. The foaming cleaning drain pipe for cleaning containers as described in claim 16, characterized in that, 所述第一剂的pH值为12~14。The pH value of the first agent is 12-14. 18.如权利要求15所述的发泡清洗用排水管清洗容器,其特征在于,18. The foaming cleaning drain pipe for cleaning containers as described in claim 15, characterized in that, 以所述pH调节剂与包含于所述第二剂中的酸性物质的氢离子总量的当量比为1.1~10:1的方式,即以pH调节剂:包含于第二剂中的酸性物质的氢离子总量的当量比为1.1~10:1的方式,包含所述pH调节剂。The pH adjuster is contained in such a manner that the equivalent ratio of the total hydrogen ions of the pH adjuster to the total hydrogen ions of the acidic substances contained in the second agent is 1.1 to 10:1, that is, in such a manner that the equivalent ratio of the pH adjuster to the total hydrogen ions of the acidic substances contained in the second agent is 1.1 to 10:1. 19.如权利要求15所述的发泡清洗用排水管清洗容器,其特征在于,19. The foaming cleaning drain pipe for cleaning containers as described in claim 15, characterized in that, 所述发泡清洗用排水管清洗剂在混合所述第一剂和所述第二剂时产生的氯气量少于300ppm。The amount of chlorine gas produced when the foaming cleaning agent for drain pipes is less than 300 ppm is mixed with the first agent and the second agent. 20.一种发泡清洗用排水管清洗套装,其特征在于,包括:20. A foaming cleaning drain pipe cleaning kit, characterized in that it comprises: 发泡清洗用排水管清洗剂,包括含有次氯酸盐的第一剂和含有过氧化氢的第二剂;以及,A foaming drain cleaner, comprising a first agent containing hypochlorite and a second agent containing hydrogen peroxide; and, 发泡清洗用排水管清洗容器,包括:具有形成于内部的容纳空间的容器本体;使发泡清洗用排水管清洗剂流入所述容纳空间的流入口;至少一个排出口,形成于所述容器本体,以使所述容器本体的所述容纳空间与排水管连通,将容纳于所述容纳空间的清洗剂向所述排水管排出,与将清洗剂立即用于排水管处理的情况相比,所述排出口以更缓慢的速度排出所述清洗剂,A foaming cleaning drain pipe cleaning container includes: a container body having an internally formed receiving space; an inlet for allowing foaming cleaning drain pipe cleaning agent to flow into the receiving space; and at least one outlet formed in the container body such that the receiving space of the container body is in communication with a drain pipe, through which the cleaning agent contained in the receiving space is discharged into the drain pipe. The outlet discharges the cleaning agent at a slower rate compared to immediately applying the cleaning agent to the drain pipe. 所述容纳空间的体积小于所述发泡清洗用排水管清洗剂的总体积。The volume of the containing space is smaller than the total volume of the foaming cleaning agent for drain pipes. 21.如权利要求20所述的发泡清洗用排水管清洗套装,其特征在于,21. The foaming cleaning drain pipe cleaning kit as described in claim 20, characterized in that, 所述容纳空间的体积小于发泡状态下的所述排水管清洗剂的含有次氯酸盐的第一剂、含有过氧化氢的第二剂的混合物以及由该混合物产生的气泡的体积。The volume of the containment space is smaller than the volume of the mixture of the first agent containing hypochlorite, the second agent containing hydrogen peroxide, and the bubbles generated by the mixture in the foamed state of the drain cleaner. 22.如权利要求21所述的发泡清洗用排水管清洗套装,其特征在于,22. The foaming cleaning drain pipe cleaning kit as described in claim 21, characterized in that, 所述容纳空间的体积与所述发泡后清洗剂的体积的体积比,即容纳空间的体积:发泡后的清洗剂的体积为1:1.01~5。The volume ratio of the containment space to the foamed cleaning agent, i.e., the volume of the containment space to the volume of the foamed cleaning agent, is 1:1.01 to 5. 23.如权利要求21所述的发泡清洗用排水管清洗套装,其特征在于,23. The foaming cleaning drain pipe cleaning kit as described in claim 21, characterized in that, 所述第一剂和所述第二剂的混合物或由该混合物产生的气泡,通过发泡清洗用排水管清洗容器的所述流入口溢出。The mixture of the first agent and the second agent, or the bubbles generated by the mixture, overflow from the inlet of the container through the foaming cleaning drain pipe. 24.一种发泡清洗用排水管清洗套装,其中,包括:24. A foaming cleaning drain pipe cleaning kit, comprising: 权利要求1所述的发泡清洗用排水管清洗容器以及发泡清洗用排水管清洗剂。The foaming cleaning drain pipe cleaning container and the foaming cleaning drain pipe cleaning agent as described in claim 1. 25.如权利要求24所述的发泡清洗用排水管清洗套装,其特征在于,25. The foaming cleaning drain pipe cleaning kit as described in claim 24, characterized in that, 所述发泡清洗用排水管清洗剂还包含增稠剂,且黏度为100~10000cps。The foaming cleaning agent for drain pipes also contains a thickener and has a viscosity of 100 to 10,000 cps. 26.一种发泡清洗厨房水槽的过滤网和排水管的方法,其中,使用权利要求1所述的发泡清洗用排水管清洗容器。26. A method for foaming and cleaning a kitchen sink filter and drain pipe, wherein the container is cleaned using the foaming and cleaning drain pipe as described in claim 1.
HK18113386.5A 2015-07-31 2016-07-29 Drain pipe cleaning kit and cleaning method using same HK1254243B (en)

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Application Number Priority Date Filing Date Title
KR20150108579 2015-07-31
KR10-2015-0108579 2015-07-31
KR10-2016-0023278 2016-02-26
KR20160023278 2016-02-26
KR10-2016-0023334 2016-02-26
KR20160023334 2016-02-26
KR10-2016-0025287 2016-03-02
KR20160025287 2016-03-02
KR10-2016-0029739 2016-03-11
KR1020160029739A KR20170015100A (en) 2015-07-31 2016-03-11 Cleaning container for drain and cleaning method using thereof
KR10-2016-0041660 2016-04-05
KR1020160041660A KR101857117B1 (en) 2016-03-02 2016-04-05 Cleaning composition for drain having an excellent cleaning effect
KR10-2016-0086883 2016-07-08
KR1020160086883A KR102540064B1 (en) 2016-02-26 2016-07-08 Cleaning kit for drain and cleaning method using thereof
KR10-2016-0086875 2016-07-08
KR1020160086875A KR20170101084A (en) 2016-02-26 2016-07-08 Cleaning composition for drain preventing generation of chlorine gas
KR1020160089926A KR20180008090A (en) 2016-07-15 2016-07-15 Cleaning container for drain comprising mesh material and cleaning method using thereof
KR10-2016-0089926 2016-07-15
PCT/KR2016/008407 WO2017023051A1 (en) 2015-07-31 2016-07-29 Drain pipe cleaning kit and cleaning method using same

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HK1254243B true HK1254243B (en) 2022-01-14

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