HK1251861B - Biomass treatment process and apparatus - Google Patents
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技术领域Technical Field
本发明涉及生物质处理方法和生物质处理装置,包括但不限于生物质致密成型和烘焙系统。The present invention relates to a biomass processing method and a biomass processing device, including but not limited to a biomass densification molding and baking system.
背景技术Background Art
为了减少温室气体(GHG)排放,尤其是减少在燃煤发电厂和重工业(例如冶金工业)中的温室气体排放,可以通过在燃煤炉中共同燃烧生物质以生成可持续的能量来减少温室气体。然而,因为大多数燃煤发电厂是基于粉煤炉,生物质不能在未经预处理的情况下在燃煤发电厂中以较高的混合百分比进行共同燃烧(原因是生物质在其性质方面仍然具有纤维结构),所以生物质不容易研磨和粉碎。在另一方面,生物质的能量值远低于煤,因此为了使用燃煤发电厂的相同的设备基础设施,生物质的预处理是用以增加能量密度以及可研磨性的强制性措施。另外,从木质基到草本基、到水生基的生物质的宽泛类型范围抑制了生物质的大规模标准化,因此生物质燃料的全球化市场的建立难以实现。为了实现不同的生物质输入、但仅有一个标准生物质输出的多输入单输出(MISO)概念,生物质的致密成型和预处理是达到国家标准化和国际标准化所必须的。To reduce greenhouse gas (GHG) emissions, particularly those from coal-fired power plants and heavy industries (e.g., metallurgy), biomass can be co-combusted in coal-fired furnaces to generate sustainable energy. However, because most coal-fired power plants are based on pulverized coal furnaces, biomass cannot be co-combusted at high mixing percentages in coal-fired power plants without pretreatment (because biomass, by its very nature, still has a fibrous structure), making it difficult to grind and pulverize biomass. On the other hand, the energy value of biomass is much lower than that of coal, so pretreatment of biomass is mandatory to increase energy density and grindability in order to use the same equipment infrastructure of coal-fired power plants. In addition, the wide range of biomass types, from wood-based to herb-based to aquatic-based, inhibits large-scale standardization of biomass, making the establishment of a global market for biomass fuels difficult to achieve. To achieve the concept of multiple-input single-output (MISO), which has different biomass inputs but only one standardized biomass output, biomass compaction and pretreatment are necessary to achieve national and international standardization.
烘焙是不完全的热解过程(图1),其中,生物质在无氧或低氧的环境中进行热化学预处理。经过烘焙的生物质的最终产物是疏水性的,具有较高的能量密度并且易于研磨,更接近于匹配煤的性质,以使得经过烘焙的生物质在燃煤发电厂中的共同燃烧更容易,不需要对燃煤发电厂中现有的设备基础设施进行成本高昂的改造或添加。Torrefaction is an incomplete pyrolysis process (Figure 1) in which biomass is thermochemically pretreated in an oxygen-free or low-oxygen environment. The final product of torrefied biomass is hydrophobic, has a high energy density, is easily grinded, and more closely matches the properties of coal, making it easier to co-combust torrefied biomass in coal-fired power plants without requiring costly modifications or additions to existing equipment infrastructure.
在另一方面,经过烘焙的生物质不容易使用用作胶粘剂的驻留木质素而致密成型为颗粒或压块的形式,原因是所需的高烘焙温度会减小经过烘焙的生物质中的木质素浓度,并且进一步增加驻留木质素的玻璃态转化温度,从而使得常规的颗粒成型机(pelletpress)必须要在超过当前技术限制的较高温度下并且还要以较高的能耗进行操作。为了便于对经过烘焙的生物质进行致密成型处理,通常要加入外部粘结剂。不幸的是,外部粘结剂通常不是疏水性的,从而使得当水分含量高时,具有附加粘结剂的经过烘焙的颗粒或压块自身吸水并且解体,结果造成运输问题和储存问题,尤其是在雨季或者雪季。On the other hand, the biomass through curing is not easy to use the resident lignin as adhesive and densely molded into the form of particles or briquette, because required high curing temperature can reduce the lignin concentration in the biomass through curing, and further increase the glass transition temperature of the resident lignin, so that conventional pellet press must operate at a higher temperature than current technology limits and with higher energy consumption. For the convenience of carrying out dense molding process to the biomass through curing, external binder is usually added. Unfortunately, external binder is not hydrophobic usually, so that when moisture content is high, the particles through curing or briquette with additional binder absorb water and disintegrate, resulting in transportation problems and storage problems, especially in rainy season or snowy season.
在现有技术中,已知在烘焙过程能够开始之前,需要原料是完全干燥的。In the prior art, it is known that the raw materials need to be completely dry before the baking process can begin.
美国专利US9347011教导一种烘焙系统,其具有两个独立的、采用不同处理技术的烘焙处理装置,其中,第一处理装置主要用于干燥未经致密成型的湿的生物质,而第二处理装置执行烘焙。第一处理装置是流化床反应器的类型,其具有的原料灵活性有限并且被优化以主要处理木质生物质例如锯屑。在另一方面,用于所述烘焙系统的原料必须是未经致密成型的生物质,原因是经过致密成型的呈颗粒或压块形式的生物质不适合用于流化床反应器。在烘焙之后进行的颗粒或压块形式的后续致密成型是耗能的,并且可能需要用到通常不是疏水性的附加粘结剂。US Patent No. 9,347,011 teaches a torrefaction system having two independent torrefaction treatment units employing different treatment technologies, wherein the first treatment unit is primarily used to dry wet biomass that has not been densified, while the second treatment unit performs the torrefaction. The first treatment unit is of the type of fluidized bed reactor, which has limited raw material flexibility and is optimized to primarily process woody biomass such as sawdust. On the other hand, the raw material for the torrefaction system must be biomass that has not been densified, because densified biomass in the form of pellets or briquettes is not suitable for use in fluidized bed reactors. The subsequent densification of the pellets or briquettes after the torrefaction is energy-consuming and may require the use of an additional binder that is generally not hydrophobic.
美国专利US9206368教导一种单一处理阶段的质量流烘焙反应器。这种常规反应器类型的缺点是“隧道效应(tunneling effect)”,尤其是当扩展到大型反应器以用于实现较大规模的生产能力时,其中来自反应器腔室底部的高温气体可能会找到通过生物质到达最近的气体排放出口的一些捷径,并且因此在反应器腔室内形成不同的高温区和低温区,导致经过烘焙的生物质的非均匀品质。在另一方面,用于单一处理阶段的温度、氧含量和驻留时间的烘焙参数控制不足以灵活处理与不同的性质和水分含量相关联的不同种类的生物质,因此MISO概念几乎不可能实现。此外,用于所述烘焙系统的原料是“具有25%或更少的水分含量并且在最长维度上具有从约13mm至约-75mm的尺寸”的非均匀和未经致密成型的生物质,从而使得在烘焙之后进行的均匀颗粒或压块形式的致密成型是耗能的,并且可能需要用到通常不是疏水性的附加粘结剂。U.S. Patent No. 9,206,368 teaches a single-stage mass flow torrefaction reactor. A disadvantage of this conventional reactor type is the "tunneling effect," particularly when scaled up to large reactors for larger production capacities. High-temperature gases from the bottom of the reactor chamber can find shortcuts through the biomass to the nearest gas exhaust outlet, creating distinct high- and low-temperature zones within the reactor chamber, leading to non-uniform quality of the torrefied biomass. Furthermore, the torrefaction parameter control of temperature, oxygen content, and residence time for a single stage is insufficient to flexibly process different types of biomass associated with varying properties and moisture content, making the MISO concept virtually impossible to implement. Furthermore, the feedstock for the torrefaction system is non-uniform and undensified biomass, "having a moisture content of 25% or less and a size ranging from about 13 mm to about -75 mm in its longest dimension," making densification into uniform pellets or briquettes after torrefaction energy-intensive and potentially requiring the use of an additional binder, which is typically not hydrophobic.
因此,用本发明来改进现有技术中的烘焙系统是尚未满足的需求。Therefore, there is an unmet need to improve the baking systems of the prior art using the present invention.
发明内容Summary of the Invention
通过本文中公开的各个方面和实施例来满足上述需求。The above needs are met by the various aspects and embodiments disclosed herein.
本发明的目的之一是在进入烘焙阶段之前首先将生物质致密成型为均匀颗粒或压块的形式,其目的是如果在烘焙阶段之后进行颗粒成型和压块成型的致密成型阶段,则能够避免使用附加的用于致密成型的粘结剂。在另一方面,来自不同原料的经过致密成型的生物质具有共同的均匀尺寸,可以针对在两阶段紧凑式移动床反应器类型中的烘焙利用致密成型阶段和烘焙阶段中的每一阶段所用的相应受控烘焙参数来优化该均匀尺寸,以便实现MISO概念。One of the objectives of the present invention is to densify the biomass into uniform pellets or briquettes before entering the torrefaction stage. This is intended to avoid the need for additional binders for densification if the densification stage of pellet and briquette formation is performed after the torrefaction stage. Furthermore, the densified biomass from different feedstocks has a common uniform size, which can be optimized for torrefaction in a two-stage compact moving bed reactor using controlled torrefaction parameters in each of the densification and torrefaction stages, thereby achieving the MISO concept.
本发明的另一目的是提供具有成本效益的烘焙方法和烘焙装置,其用于生产经济的、具有疏水特性的、经过烘焙的颗粒或压块而无需使用粘结剂,容易扩展到基于成本合理的设备以及适用于MISO概念的可行性而利用连续烘焙方法进行商业化批量生产,并且无需对燃煤发电厂中的现有设备进行重大改造。Another object of the present invention is to provide a cost-effective torrefaction method and torrefaction apparatus for producing economical, hydrophobic torrefied pellets or briquettes without the use of binders, which is easily scalable to commercial batch production using a continuous torrefaction process based on reasonable cost equipment and feasibility applicable to the MISO concept, and does not require major modifications to existing equipment in coal-fired power plants.
本发明的又一目的是对于导致非均质烘焙产物的紧凑式移动床烘焙反应器中的每个生物质颗粒或压块避免“隧道效应”和不同的驻留时间。本发明提供一种星形或蛛网形或环形的形式的高温空气分配系统,其使“隧道效应”最小化,由此高温空气在烘焙处理室内以相同的设定温度与所有的生物质均匀接触。在烘焙处理室的顶部处的刮器臂均匀地分配输入的生物质,并且在处理室的端部处的生物质排出装置均匀地调节经过烘焙的生物质的产量,以便对于自顶向下通过整个所述处理室的每个颗粒或压块保持驻留时间恒定。本发明的紧凑式移动床反应器的烘焙室进一步分为第一处理阶段(预烘焙阶段)和第二处理阶段(烘焙阶段),以便与生物质的性质和水分含量相关联地应对各种不同的生物质,由此能够用本发明更容易地实现MISO概念。Another object of the present invention is to avoid the "tunneling effect" and different residence times for each biomass particle or briquette in a compact moving bed torrefaction reactor that result in non-homogeneous torrefaction products. The present invention provides a high-temperature air distribution system in the form of a star, spider web, or ring that minimizes the "tunneling effect" so that the high-temperature air comes into uniform contact with all the biomass at the same set temperature within the torrefaction chamber. The scraper arm at the top of the torrefaction chamber evenly distributes the input biomass, and the biomass discharge device at the end of the treatment chamber evenly regulates the yield of torrefied biomass so as to maintain a constant residence time for each particle or briquette passing through the entire treatment chamber from top to bottom. The torrefaction chamber of the compact moving bed reactor of the present invention is further divided into a first treatment stage (pre-toasting stage) and a second treatment stage (toasting stage) so as to cope with a variety of different biomasses in relation to their properties and moisture content, thereby making it easier to implement the MISO concept with the present invention.
因此,本发明的第一方面涉及一种用于处理生物质的方法,所述方法包括致密成型阶段、第一处理阶段、第二处理阶段、以及冷却处理阶段。所述致密成型阶段包括将基本干燥和尺寸减小的生物质进给到连续或分批生物质处理系统,其中所述生物质包含一定的水分含量。在一个实施例中,包含在所述生物质中的所述水分含量在重量百分比为8%至12%的范围内。所述致密成型阶段还包括将所述生物质致密成型为颗粒或压块的形式。所述致密成型阶段另外还包括将经过致密成型的呈颗粒或压块形式的生物质排出到所述第一处理阶段。所述第一处理阶段包括将包含所述水分含量的所述经过致密成型的生物质加热到预烘焙温度并持续第一驻留时间。在一个实施例中,在所述第一处理阶段中使用的所述预烘焙温度在260℃至300℃的范围内。所述生物质还可以通过在所述第一处理阶段中的所述加热使所述水分从所述生物质蒸发而进一步干燥或完全干燥,以使得所述生物质在所述加热之后变成至少部分经过烘焙的生物质或经过预烘焙的生物质。然后将所述经过预烘焙的生物质从所述第一处理阶段排出到所述第二处理阶段。所述第二处理阶段包括将所述经过预烘焙的生物质加热到烘焙温度并持续第二驻留时间。在一个实施例中,在所述第二处理阶段中使用的所述烘焙温度在240℃至280℃的范围内。所述第二驻留时间可以等于或长于所述第一驻留时间。在一个实施例中,本发明的方法中的第一驻留时间和第二驻留时间所用的实际驻留时长取决于执行第一处理阶段和第二处理阶段的隔室的相应高度、以及在第二处理阶段中在烘焙之后的经过烘焙的生物质的输出速率。所述经过预烘焙的生物质在所述第二处理阶段中的所述加热之后变成经过烘焙的生物质,并且随后所述经过烘焙的生物质从所述第二处理阶段排出到所述冷却处理阶段。所述冷却处理阶段包括将所述经过烘焙的生物质冷却至低于100℃的温度。在一个实施例中,通过在所述冷却处理阶段中的所述冷却将所述经过烘焙的生物质冷却到约室温。在另一实施例中,通过使所述经过烘焙的生物质与冷却剂气体直接接触而执行在所述冷却处理阶段中的所述冷却。在其它实施例中,通过使所述经过烘焙的生物质与水直接接触而执行在所述冷却处理阶段中的所述冷却。在示例性实施例中,本方法的所述第一处理阶段和第二处理阶段在相同的烘焙装置中执行,这不同于在两个独立装置中执行的常规方法。分别向所述第一处理阶段和第二处理阶段提供第一高温气体和第二高温气体以用于达到所述第一处理温度和第二处理温度。在一个实施例中,所述第一高温气体通过至少一个第一高温气体入口至少提供给所述第一处理阶段,并且剩余的所述第一高温气体通过至少一个第一高温气体出口至少从所述第一处理阶段排出。在另一实施例中,所述第二高温气体通过至少一个第二高温气体入口至少提供给所述第二处理阶段,并且剩余的所述第二高温气体通过至少一个第二高温气体出口至少从所述第二处理阶段排出。所述第二高温气体在所述第二高温气体入口处具有的温度等于或低于所述第一高温气体在所述第一高温气体入口处具有的温度。所述第一高温气体和/或第二高温气体可以包括氧。在一个实施例中,所述第一高温气体与进给到所述第一处理阶段中的所述经过致密成型的生物质直接接触,其中所述第一高温气体包括体积百分比等于或小于10%的氧。在另一实施例中,所述第二高温气体与进给到所述第二处理阶段中的所述经过预烘焙的生物质直接接触,其中所述第二高温气体包括体积百分比等于或小于3%的氧。在所述第一处理阶段和/或第二处理阶段之后包含挥发性可燃气体的所述第一高温气体的剩余部分和/或所述第二高温气体的剩余部分可以再循环。在一个实施例中,在所述第一处理阶段之后通过所述第一高温气体出口排出的所述第一高温气体的所述剩余部分再循环到燃烧器以用于生成烟道气,所述烟道气用于经由一个或多个热交换装置加热随后要通过所述第一高温气体入口提供给所述第一处理阶段的第一高温气体。在另一实施例中,在所述第二处理阶段之后通过所述第二高温气体出口排出的所述第二高温气体的所述剩余部分再循环到燃烧器以用于生成烟道气,所述烟道气用于经由一个或多个热交换装置加热随后要通过所述第二高温气体入口提供给所述第二处理阶段的第二高温气体。用于经由一个或多个热交换装置分别加热第一高温气体和第二高温气体的所述烟道气所用的所述燃烧器可以是相同的或不同的。可选地,例如在所述致密成型阶段之前,离开热交换装置的烟道气也可以将热提供给其它阶段,来自热交换步骤的烟道气热可以用于在引入到颗粒成型和压块成型的致密成型步骤之前将生物质的水分含量减小到重量百分比为8%至12%的范围内。通过经由所述一个或多个热交换装置将所述第一高温气体和/或第二高温气体的剩余部分再循环到所述燃烧器,本发明的方法在将初始的第一高温气体和第二高温气体提供给第一处理阶段和第二处理阶段之后可以是自持续(self-sustained)的。Therefore, a first aspect of the present invention relates to a method for processing biomass, comprising a densification stage, a first processing stage, a second processing stage, and a cooling processing stage. The densification stage comprises feeding substantially dried and size-reduced biomass to a continuous or batch biomass processing system, wherein the biomass contains a certain moisture content. In one embodiment, the moisture content contained in the biomass is in the range of 8% to 12% by weight. The densification stage also comprises densifying the biomass into pellets or briquettes. The densification stage further comprises discharging the densified biomass in the form of pellets or briquettes to the first processing stage. The first processing stage comprises heating the densified biomass containing the moisture content to a pre-toasting temperature for a first residence time. In one embodiment, the pre-toasting temperature used in the first processing stage is in the range of 260°C to 300°C. The biomass may be further dried or completely dried by evaporating the moisture from the biomass during the heating in the first processing stage, so that the biomass becomes at least partially torrefied or pre-toasted biomass after the heating. The pre-torrefied biomass is then discharged from the first processing stage to a second processing stage. The second processing stage involves heating the pre-torrefied biomass to a torrefaction temperature for a second residence time. In one embodiment, the torrefaction temperature used in the second processing stage is in the range of 240°C to 280°C. The second residence time may be equal to or longer than the first residence time. In one embodiment, the actual residence times used for the first and second residence times in the method of the present invention depend on the respective heights of the compartments performing the first and second processing stages, as well as the output rate of the torrefied biomass in the second processing stage after torrefaction. Following the heating in the second processing stage, the pre-torrefied biomass becomes torrefied biomass, and the torrefied biomass is then discharged from the second processing stage to the cooling processing stage. The cooling processing stage involves cooling the torrefied biomass to a temperature below 100°C. In one embodiment, the cooling in the cooling processing stage cools the torrefied biomass to approximately room temperature. In another embodiment, the cooling in the cooling processing stage is performed by directly contacting the torrefied biomass with a coolant gas. In other embodiments, the cooling in the cooling process stage is performed by directly contacting the torrefied biomass with water. In an exemplary embodiment, the first and second process stages of the present method are performed in the same torrefaction apparatus, unlike conventional methods in which they are performed in two separate apparatuses. A first high-temperature gas and a second high-temperature gas are respectively supplied to the first and second process stages to achieve the first and second process temperatures. In one embodiment, the first high-temperature gas is supplied to at least the first process stage via at least one first high-temperature gas inlet, and the remaining first high-temperature gas is discharged from at least the first process stage via at least one first high-temperature gas outlet. In another embodiment, the second high-temperature gas is supplied to at least the second process stage via at least one second high-temperature gas inlet, and the remaining second high-temperature gas is discharged from at least the second process stage via at least one second high-temperature gas outlet. The second high-temperature gas has a temperature at the second high-temperature gas inlet that is equal to or lower than the temperature of the first high-temperature gas at the first high-temperature gas inlet. The first and/or second high-temperature gases may include oxygen. In one embodiment, the first high-temperature gas is in direct contact with the densified biomass fed to the first process stage, wherein the first high-temperature gas contains 10% or less oxygen by volume. In another embodiment, the second high-temperature gas directly contacts the pre-torrefied biomass fed to the second process stage, wherein the second high-temperature gas comprises 3% or less oxygen by volume. The remaining portion of the first high-temperature gas containing volatile combustible gases and/or the remaining portion of the second high-temperature gas after the first process stage and/or the second process stage may be recycled. In one embodiment, the remaining portion of the first high-temperature gas exhausted through the first high-temperature gas outlet after the first process stage is recycled to a burner to generate flue gas, which is used to heat the first high-temperature gas, which is subsequently supplied to the first process stage through the first high-temperature gas inlet, via one or more heat exchange devices. In another embodiment, the remaining portion of the second high-temperature gas exhausted through the second high-temperature gas outlet after the second process stage is recycled to a burner to generate flue gas, which is used to heat the second high-temperature gas, which is subsequently supplied to the second process stage through the second high-temperature gas inlet, via one or more heat exchange devices. The burners used to heat the flue gases of the first and second high-temperature gases, respectively, via the one or more heat exchange devices, may be the same or different. Optionally, the flue gas leaving the heat exchange device can also provide heat to other stages, for example, before the densification stage. The flue gas heat from the heat exchange step can be used to reduce the moisture content of the biomass to a range of 8% to 12% by weight before being introduced into the densification step of pellet forming and briquette forming. By recycling the remaining portion of the first high-temperature gas and/or the second high-temperature gas to the burner via the one or more heat exchange devices, the method of the present invention can be self-sustaining after providing the initial first high-temperature gas and the second high-temperature gas to the first process stage and the second process stage.
本发明的第一方面中的所述方法还包括经由控制系统进行监测和控制步骤以确保所有关键参数满足预定烘焙条件,所述控制系统用于监测和/或控制以下参数中的一个或多个:在所述方法的不同阶段的生物质中的实际水分含量、用于第一处理阶段和第二处理阶段的隔室中的高温气体的实际氧含量、腔室的实际温度、和/或第一驻留时间和第二驻留时间所用的实际时长。本发明的第一方面中的所述方法的所述监测和控制步骤可以由具有传感器和控制装置的系统执行。The method of the first aspect of the present invention further includes a monitoring and control step via a control system to ensure that all key parameters meet predetermined torrefaction conditions, wherein the control system is configured to monitor and/or control one or more of the following parameters: the actual moisture content of the biomass at different stages of the method, the actual oxygen content of the high-temperature gas in the compartments used for the first and second processing stages, the actual temperature of the chamber, and/or the actual duration of the first and second residence times. The monitoring and control step of the method of the first aspect of the present invention can be performed by a system having sensors and a control device.
根据本发明的第一方面的实施例,用于执行所述方法的连续或分批生物质处理系统是紧凑式移动床反应器。According to an embodiment of the first aspect of the present invention, the continuous or batch biomass processing system for performing the method is a compact moving bed reactor.
在本发明的第二方面中,提供一种包括处理室的连续或分批生物质处理装置。在示例性实施例中,所述处理室是紧凑式移动床反应器的类型。所述处理室优选地包括双壁壳体,并且优选地是限定了基本竖直轴线的环形的形式。所述处理室包括第一处理隔室和第二处理隔室。所述处理室还包括:布置在所述处理室的顶部处的至少一个气体密封阀入口,其用于将基本干燥和经过致密成型的生物质供应到所述处理室中;生物质分配装置;布置在所述处理室的底部处的生物质排出装置,其用于均匀地排出呈颗粒形式的经过烘焙的生物质;作为经过烘焙的生物质的最终出口的至少一个气体密封阀出口;至少一个第一高温气体入口和至少一个第一高温气体出口,它们分别用于将第一高温气体提供给处理室的第一处理隔室以及从处理室的第一处理隔室排出第一高温气体的剩余部分以便再循环;至少一个第二高温气体入口和至少一个第二高温气体出口,它们分别用于将第二高温气体提供给处理室的第二处理隔室以及从处理室的第二处理隔室排出第二高温气体的剩余部分以便再循环;双壁壳体的外壁和内穿孔壁,其中在所述外壁和内穿孔壁之间限定内周边间隙;高温气体分配系统,其包括布置为星形或蛛网形或环形的形式的、多个穿孔双分离板;布置在处理室的中部的至少一个穿孔管道。在一个实施例中,所述内穿孔壁、由穿孔双分离板构成的所述高温气体分配系统和所述至少一个穿孔管道沿着竖直轴线从处理室的底部向顶部升高。在优选实施例中,第一高温气体入口安装在处理室的第一处理隔室的顶部处。第一高温气体通过第一高温气体入口提供,然后沿着双壁壳体的内周边间隙和布置为星形或蛛网形或环形的形式的内穿孔双分离板的间隙推送,以便将进给到处理室的第一处理隔室中的所有生物质均匀地加热到预定温度并持续第一驻留时间。此后,在第一处理阶段之后的第一高温气体的剩余部分通过在处理室的中部的穿孔管道回收并且由至少一个第一高温气体出口排出。优选地,至少一个第一高温气体出口安装在第一处理隔室的底部处,以用于回收第一高温气体的剩余部分以便将来自第一高温气体的剩余部分的热经由热交换装置再循环送回到第一处理隔室。在优选实施例中,第二高温气体入口安装在处理室的第二处理隔室的底部处。第二高温气体通过第二高温气体入口提供,然后沿着双壁壳体的内周边间隙和布置为星形或蛛网形或环形的形式的内穿孔双分离板的间隙推送,以便将进给到处理室的第二处理隔室中的所有生物质均匀地加热到预定温度并持续第二驻留时间。此后,在第二处理阶段之后的第二高温气体的剩余部分通过在第二处理隔室的中部的穿孔管道回收并且由至少一个第二高温气体出口排出。优选地,至少一个第二高温气体出口安装在第二处理隔室的顶部处,以用于回收第二高温气体的剩余部分以便将来自第二高温气体的剩余部分的热经由热交换装置再循环送回到第二处理隔室。另外,处理室可以包括控制系统,所述控制系统用于根据处理室的每个部分/部段/隔室中的预定条件来监测和控制不同的参数。In a second aspect of the present invention, a continuous or batch biomass processing apparatus is provided that includes a processing chamber. In an exemplary embodiment, the processing chamber is of the compact moving bed reactor type. The processing chamber preferably comprises a double-walled housing and is preferably annular in form defining a substantially vertical axis. The processing chamber includes a first processing compartment and a second processing compartment. The processing chamber further comprises: at least one gas-tight valve inlet arranged at the top of the processing chamber, which is used to supply substantially dry and densely formed biomass into the processing chamber; a biomass distribution device; a biomass discharge device arranged at the bottom of the processing chamber, which is used to uniformly discharge the torrefied biomass in the form of particles; at least one gas-tight valve outlet as a final outlet for the torrefied biomass; at least one first high-temperature gas inlet and at least one first high-temperature gas outlet, which are respectively used to supply a first high-temperature gas to a first processing compartment of the processing chamber and to discharge a remaining portion of the first high-temperature gas from the first processing compartment of the processing chamber for recycling; at least one second high-temperature gas inlet and at least one second high-temperature gas outlet, which are respectively used to supply a second high-temperature gas to a second processing compartment of the processing chamber and to discharge a remaining portion of the second high-temperature gas from the second processing compartment of the processing chamber for recycling; an outer wall and an inner perforated wall of a double-walled shell, wherein an inner peripheral gap is defined between the outer wall and the inner perforated wall; a high-temperature gas distribution system, which comprises a plurality of perforated double separation plates arranged in a star shape, a spider web shape or a ring shape; and at least one perforated pipe arranged in the middle of the processing chamber. In one embodiment, the inner perforated wall, the hot gas distribution system comprised of perforated double separator plates, and the at least one perforated conduit rise along a vertical axis from the bottom to the top of the treatment chamber. In a preferred embodiment, a first hot gas inlet is mounted at the top of the first processing compartment of the treatment chamber. First hot gas is supplied through the first hot gas inlet and then pushed along the inner peripheral gaps of the double-walled shell and the gaps between the inner perforated double separator plates, which are arranged in a star, spiderweb, or ring pattern, to uniformly heat all biomass fed into the first processing compartment of the treatment chamber to a predetermined temperature for a first residence time. Thereafter, the remaining portion of the first hot gas after the first treatment stage is recovered through the perforated conduit in the middle of the treatment chamber and discharged through the at least one first hot gas outlet. Preferably, the at least one first hot gas outlet is mounted at the bottom of the first processing compartment to recover the remaining portion of the first hot gas so that heat from the remaining portion of the first hot gas can be recycled back to the first processing compartment via a heat exchange device. In a preferred embodiment, a second hot gas inlet is mounted at the bottom of the second processing compartment of the treatment chamber. A second high-temperature gas is provided through a second high-temperature gas inlet and then pushed along the inner peripheral gap of the double-walled shell and the gaps between the inner perforated double separation plates arranged in a star-shaped, spider-web-shaped, or ring-shaped manner, so as to uniformly heat all biomass fed into the second processing compartment of the processing chamber to a predetermined temperature for a second residence time. Thereafter, the remaining portion of the second high-temperature gas after the second processing stage is recovered through a perforated pipe in the middle of the second processing compartment and discharged through at least one second high-temperature gas outlet. Preferably, at least one second high-temperature gas outlet is installed at the top of the second processing compartment for recovering the remaining portion of the second high-temperature gas so that the heat from the remaining portion of the second high-temperature gas can be recycled back to the second processing compartment via a heat exchange device. In addition, the processing chamber can include a control system for monitoring and controlling different parameters according to predetermined conditions in each part/section/compartment of the processing chamber.
根据本发明的第二方面的实施例,所述生物质分配装置包括安装在由马达驱动的旋转刮器轮中的至少一个旋转刮器臂,以用于在经由所述气体密封阀入口排出到第一处理隔室中之前均匀地分配经过致密成型的生物质。According to an embodiment of the second aspect of the invention, the biomass distribution device comprises at least one rotating scraper arm mounted in a motor driven rotating scraper wheel for evenly distributing the compacted biomass before discharge into the first processing compartment via the gas sealing valve inlet.
根据本发明的第二方面的实施例,所述生物质排出装置包括由至少一个旋转马达驱动的两个同轴旋转盘,其中每一个所述同轴旋转盘都具有交替布置的星形的多个开口和多个型块;所述两个同轴旋转盘在相同或彼此相反的方向上、并且以相同或不同的速度旋转,以便根据受控的输出速率从第二处理隔室均匀地排出经过烘焙的生物质。According to an embodiment of the second aspect of the present invention, the biomass discharge device includes two coaxial rotating disks driven by at least one rotary motor, wherein each of the coaxial rotating disks has a plurality of star-shaped openings and a plurality of blocks arranged alternately; the two coaxial rotating disks rotate in the same or opposite directions and at the same or different speeds so as to uniformly discharge the roasted biomass from the second processing compartment according to a controlled output rate.
根据本发明的第二方面的实施例,双壁壳体的间隙和所述第一处理隔室的穿孔双分离板的间隙以及双壁壳体的间隙和所述第二处理隔室的穿孔双分离板的间隙由非穿孔隔板分离以避免在第一处理隔室和第二处理隔室之间或者在第一处理阶段和第二处理阶段之间的任何气体或温度冲突,同时经过预烘焙的生物质从第一处理隔室移动到第二处理隔室而没有任何阻塞。According to an embodiment of the second aspect of the present invention, the gap between the double-walled shell and the gap between the perforated double separation plate of the first processing compartment and the gap between the double-walled shell and the gap between the perforated double separation plate of the second processing compartment are separated by non-perforated partitions to avoid any gas or temperature conflict between the first processing compartment and the second processing compartment or between the first processing stage and the second processing stage, while the pre-baked biomass moves from the first processing compartment to the second processing compartment without any blockage.
根据本发明的第二方面的实施例,布置为星形或蛛网形的形式的所述穿孔双分离板包括至少一个第一端部,所述至少一个第一端部连接到布置在所述处理室的中部的所述穿孔管道。According to an embodiment of the second aspect of the present invention, the perforated double separation plate arranged in the form of a star or spider web comprises at least one first end connected to the perforated duct arranged in the middle of the process chamber.
根据本发明的第二方面的另一实施例,布置为星形或蛛网形的形式的所述穿孔双分离板包括至少一个第二端部,所述至少一个第二端部连接到所述处理室的所述内穿孔壁。According to another embodiment of the second aspect of the present invention, the perforated double separation plates arranged in the form of a star or spider web comprise at least one second end connected to the inner perforated wall of the process chamber.
根据本发明的第二方面的实施例,每一个所述穿孔双分离板将所述处理室分成至少两个竖直部段。According to an embodiment of the second aspect of the present invention, each of the perforated double separation plates divides the process chamber into at least two vertical sections.
根据本发明的第一方面或第二方面的实施例,在所述第一处理阶段或者在所述第一处理隔室中进行处理之后,经过预烘焙的生物质借助于重力排出到所述第二处理阶段或所述第二处理隔室中。According to an embodiment of the first or second aspect of the invention, after treatment in the first treatment stage or in the first treatment compartment, the pre-torrefied biomass is discharged by gravity into the second treatment stage or the second treatment compartment.
根据本发明的第二方面的实施例,来自所述第一高温气体入口的所述第一高温气体包括体积百分比等于或小于10%的氧。According to an embodiment of the second aspect of the present invention, the first high-temperature gas from the first high-temperature gas inlet includes oxygen in an amount equal to or less than 10% by volume.
根据本发明的第二方面的实施例,来自所述第二高温气体入口的所述第二高温气体包括体积百分比等于或小于3%的氧。According to an embodiment of the second aspect of the present invention, the second high-temperature gas from the second high-temperature gas inlet includes oxygen in an amount equal to or less than 3% by volume.
根据本发明的第二方面的实施例,所述第一处理隔室中的所述预定温度在260℃至300℃的范围内。According to an embodiment of the second aspect of the invention, the predetermined temperature in the first processing compartment is in the range of 260°C to 300°C.
根据本发明的第二方面的实施例,所述第二处理隔室中的所述预定温度在240℃至280℃的范围内。According to an embodiment of the second aspect of the invention, said predetermined temperature in the second processing compartment is in the range of 240°C to 280°C.
根据本发明的第二方面的实施例,所述第二高温气体的温度保持为等于或低于所述第一高温气体的温度。According to an embodiment of the second aspect of the present invention, the temperature of the second high-temperature gas is maintained equal to or lower than the temperature of the first high-temperature gas.
根据本发明的第二方面的实施例,所述第二处理隔室的高度等于或高于所述第一处理隔室的高度。According to an embodiment of the second aspect of the invention, the height of the second processing compartment is equal to or higher than the height of the first processing compartment.
根据本发明的第一方面或第二方面的实施例,第一处理阶段和第二处理阶段或者分别在第一处理隔室和第二处理隔室中对生物质进行处理所用的所述第一驻留时间和第二驻留时间的持续时长取决于第一处理隔室和第二处理隔室的高度和/或取决于所述生物质排出装置的受控输出速率。According to an embodiment of the first or second aspect of the invention, the duration of the first and second treatment stages or of the first and second residence times for treating the biomass in the first and second treatment compartments, respectively, depends on the height of the first and second treatment compartments and/or on the controlled output rate of the biomass discharge device.
根据本发明的第一方面或第二方面的实施例,所述控制系统包括传感器和控制装置,所述传感器和控制装置用于实时监测和控制水分含量、氧含量、温度和驻留时间以确保所有参数都符合每一个阶段或每一个隔室中的预定条件。According to an embodiment of the first aspect or the second aspect of the present invention, the control system includes sensors and control devices, which are used to monitor and control moisture content, oxygen content, temperature and residence time in real time to ensure that all parameters meet predetermined conditions in each stage or each compartment.
本发明包括在说明书中单独地或集中地提及或指明的所有的步骤和特征、以及任意和全部的组合或者这些步骤或特征中的任意的两个或更多个。本发明还包括如本文中所述的所有的这些修改和变型。The present invention includes all steps and features mentioned or indicated in the specification individually or collectively, and any and all combinations or any two or more of these steps or features. The present invention also includes all these modifications and variations as described herein.
通过阅读随后的说明内容,本发明的其它方面和优点对于本领域技术人员而言将是显而易见的。Other aspects and advantages of the present invention will become apparent to those skilled in the art from a reading of the ensuing description.
将在下面的具体实施方式中部分地阐述本发明和方法的各种示例和特征。该发明内容部分旨在提供本发明的概述,并且不旨在提供排他性或穷举性的阐释。本文包括以下的具体实施方式以提供关于本公开和方法的更多信息。Various examples and features of the present invention and method will be partially described in the following detailed description. This summary of the invention is intended to provide an overview of the present invention and is not intended to provide an exclusive or exhaustive explanation. The following detailed description is included herein to provide more information about the present disclosure and method.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
结合附图,根据本发明的以下描述,本发明的上述和其它的目的和特征将变得显而易见,在附图中:The above and other objects and features of the present invention will become apparent from the following description of the present invention when taken in conjunction with the accompanying drawings, in which:
图1是示出了在木质生物质的热解过程的不同阶段所需的能量密度与时间和温度之间的一般关系的曲线图;FIG1 is a graph showing the general relationship between energy density, time, and temperature required at different stages of the pyrolysis process of woody biomass;
图2A是示出了根据本发明的实施例给出的方法中的致密成型阶段和烘焙阶段的流程图;2A is a flow chart showing a densification molding stage and a baking stage in a method according to an embodiment of the present invention;
图2B是示出了根据本发明的另一实施例给出的具有附加控制和监测步骤的方法中的致密成型阶段和烘焙阶段的另一流程图;2B is another flow chart showing the densification and baking stages of a method with additional control and monitoring steps according to another embodiment of the present invention;
图3是示出了根据本发明的实施例给出的装置中的结构和不同材料的流动的示意图,其中不同材料的流动方向由箭头表示;3 is a schematic diagram showing the structure of a device and the flow of different materials according to an embodiment of the present invention, wherein the flow directions of different materials are indicated by arrows;
图4是根据本发明的实施例给出的装置中的生物质分配装置的从气体密封阀入口观察的俯视图;4 is a top view of the biomass distribution device in the device according to an embodiment of the present invention as viewed from the inlet of the gas sealing valve;
图5A是根据本发明的实施例给出的装置中的生物质排出装置的透视图;5A is a perspective view of a biomass discharge device in a device according to an embodiment of the present invention;
图5B是示出了根据本发明的实施例给出的装置中的生物质排出装置的两个同轴盘的结构的示意图,其中阴影部分表示型块,而非阴影部分表示每个盘的开口;5B is a schematic diagram showing the structure of two coaxial disks of a biomass discharge device in an apparatus according to an embodiment of the present invention, wherein the shaded portion represents a block, and the unshaded portion represents an opening of each disk;
图6A是穿孔双分离板的横截面图(图3中的截面A-A'或截面B-B'),示出了在本发明的装置中或者在本发明的方法中使用的一种星形高温气体分配系统;FIG6A is a cross-sectional view of a perforated double separation plate (section AA' or section BB' in FIG3), showing a star-shaped high-temperature gas distribution system used in the apparatus or method of the present invention;
图6B是穿孔双分离板的透视图,示出了在本发明的装置中或者在本发明的方法中使用的一种星形高温气体分配系统;6B is a perspective view of a perforated double separation plate showing a star-shaped high-temperature gas distribution system used in the apparatus or method of the present invention;
图7A是穿孔双分离板的横截面图(图3中的截面A-A'或截面B-B'),示出了在本发明的装置中或者在本发明的方法中使用的一种蛛网形高温气体分配系统;FIG7A is a cross-sectional view of a perforated double separation plate (section AA' or section BB' in FIG3), showing a spider-web-shaped high-temperature gas distribution system used in the apparatus or method of the present invention;
图7B是穿孔双分离板的横截面图(图3中的截面A-A'或截面B-B'),示出了在本发明的装置中或者在本发明的方法中使用的另一种蛛网形高温气体分配系统;FIG7B is a cross-sectional view of a perforated double separation plate (section AA' or section BB' in FIG3), showing another spider-web-shaped high-temperature gas distribution system used in the apparatus or method of the present invention;
图8是穿孔双分离板的横截面图(图3中的截面A-A'或截面B-B'),示出了在本发明的装置中或者在本发明的方法中使用的一种环形高温气体分配系统;FIG8 is a cross-sectional view of a perforated double separation plate (section AA' or section BB' in FIG3), showing an annular high-temperature gas distribution system used in the apparatus or method of the present invention;
图9是示出了根据本发明的实施例的内穿孔双分离板的穿孔的结构的示意图。FIG. 9 is a schematic diagram illustrating a perforated structure of an inner perforated double separation plate according to an embodiment of the present invention.
具体实施方式DETAILED DESCRIPTION
定义definition
如本文中所述,术语“一”或“一个”用于包括一个或一个以上,术语“或”用于表示非排他性的“或”,除非另有说明。另外,应当理解本文中所使用的并且未另外定义的短语或术语仅仅用于描述而并不是限制性的。此外,本文中引用的所有公开文献、专利和专利文献通过全文引用而并入本文,就像通过引用而单独地并入一样。在本文与通过引用并入的那些文献之间的用法不一致的情况下,在所并入的文献中的用法应当被认为是对本文的补充;对于不相容的矛盾之处,应以本文中的用法为准。As used herein, the terms "a" or "an" are used to include one or more than one, and the term "or" is used to represent a non-exclusive "or", unless otherwise specified. In addition, it should be understood that phrases or terms used herein and not otherwise defined are used for descriptive purposes only and are not limiting. In addition, all publications, patents, and patent documents cited herein are incorporated herein by reference in their entirety, just as if individually incorporated by reference. In the event of any inconsistency between the usage herein and those documents incorporated by reference, the usage in the incorporated document should be considered supplementary to that herein; for inconsistencies, the usage in this document shall prevail.
术语“约”可以允许数值或者范围的一定程度的变化性,例如在所述数值或所述范围的极限的10%以内或者5%以内。The term "about" can allow a degree of variability in a value or range, for example, within 10% or within 5% of the stated value or limit of the stated range.
术语“独立地选自”是指引用相同的群组、不同的群组、或其组合,除非上下文另有清楚说明。因此,在该定义下,例如短语“X1、X2和X3独立地选自惰性气体”应当包括下列情形:X1、X2和X3全部相同,X1、X2和X3各不相同,X1和X2相同但是X3不同,以及其它类似的排列组合。The term "independently selected" refers to reference to the same group, different groups, or a combination thereof, unless the context clearly indicates otherwise. Thus, under this definition, for example, the phrase "X1, X2, and X3 are independently selected from inert gases" should include the following: X1, X2, and X3 are all the same, X1, X2, and X3 are different, X1 and X2 are the same but X3 is different, and other similar permutations and combinations.
在说明书中提及“一个实施例”、“实施例”、“示例性实施例”等表示所述的实施例可以包括特定的特征、结构或特性,但是不必每一个实施例都包括所述特定的特征、结构或特性。而且,这样的短语不一定指代相同的实施例。此外,当结合实施例描述特定的特征、结构或特性时,无论是否明确地描述,都认为能够在本领域技术人员的知识范围内结合其它的实施例实现这样的特征、结构或特性。References in the specification to "one embodiment," "an embodiment," "an exemplary embodiment," etc., indicate that the described embodiment may include a particular feature, structure, or characteristic, but not every embodiment necessarily includes the particular feature, structure, or characteristic. Moreover, such phrases do not necessarily refer to the same embodiment. In addition, when a particular feature, structure, or characteristic is described in conjunction with an embodiment, whether or not explicitly described, it is assumed that such feature, structure, or characteristic can be implemented in conjunction with other embodiments within the knowledge of those skilled in the art.
以范围格式表达的数值应当以灵活的方式解释为不仅包括作为范围的极限而明确表述的数值,而且包括在该范围内所包含的所有单独的数值或子范围,就像每个数值和子范围都被明确地表述一样。例如,“约0.1%至约5%”的浓度范围应当解释为不仅包括明确表述的重量百分比为约0.1%至约5%的浓度,而且包括在该指明范围内的单独的浓度(例如,1%,2%,3%以及4%)和子范围(例如,0.1%至0.5%,1.1%至2.2%以及3.3%至4.4%)。Numerical values expressed in range format should be interpreted in a flexible manner to include not only the numerical values explicitly stated as the limits of the range, but also all individual numerical values or subranges contained within that range, as if each numerical value and subrange were explicitly stated. For example, a concentration range of "about 0.1% to about 5%" should be interpreted to include not only the explicitly stated concentrations of about 0.1% to about 5% by weight, but also individual concentrations (e.g., 1%, 2%, 3%, and 4%) and subranges (e.g., 0.1% to 0.5%, 1.1% to 2.2%, and 3.3% to 4.4%) within the indicated range.
在整个说明书中,除非上下文另有要求,否则词语“包括”或其变型例如“包含”或“由…构成”应被理解为表达包括所述个体或者个体的群组在内,但不排除任何其它的个体或者个体的群组。还应当注意,在本公开中,特别是在权利要求和/或各段落中,诸如“包括”、“包含”或“由…构成”等这样的术语可以具有美国专利法所赋予的含义;例如,它们可以表示“包括”、“被包括在内”等;并且诸如“基本上由…构成”和“基本上由…组成”这样的术语具有美国专利法所赋予的含义,例如,它们允许未明确表述的要素,但是排除在现有技术中已发现的要素或者影响本发明的基本特性或新颖特性的要素。Throughout the specification, unless the context requires otherwise, the word "comprise" or variations such as "comprising" or "consisting of" should be understood to express the inclusion of the stated individual or group of individuals but not the exclusion of any other individual or group of individuals. It should also be noted that in this disclosure, particularly in the claims and/or paragraphs, terms such as "comprise," "comprising," or "consisting of" may have the meanings ascribed to them by U.S. patent law; for example, they may mean "including," "comprised of," etc.; and terms such as "consisting essentially of" and "consisting essentially of" have the meanings ascribed to them by U.S. patent law, for example, they allow for elements not expressly recited but exclude elements found in the prior art or that affect the basic or novel characteristics of the invention.
此外,在整个本说明书和权利要求书中,除非上下文另有要求,否则词语“包括”或其变型例如“包含”或“由…构成”应被理解为表达包括所述个体或者个体的群组在内,但不排除任何其它的个体或者个体的群组。Furthermore, throughout this specification and claims, unless the context requires otherwise, the word "comprise" or variations such as "comprising" or "consisting of," will be understood to express the inclusion of a stated individual or group of individuals but not the exclusion of any other individual or group of individuals.
在本文中所述的生物质处理方法中,各项步骤能够按照任意顺序执行且不脱离本发明的原理,在时间或操作顺序被明确表述时除外。权利要求中的关于首先执行第一步骤并且随后相继执行若干其它步骤的表述应当被视为表示第一步骤在任何其它步骤之前执行,但是其它步骤可以按照任意合适的顺序执行,除非在其它步骤中对于顺序有进一步的表述。例如,表述“步骤A,步骤B,步骤C,步骤D,和步骤E”的权利要求要素应当被解读为首先执行步骤A,最后执行步骤E,并且步骤B、C和D可以在步骤A和E之间按照任意顺序执行,并且这样的顺序仍然落在要求保护的方法的语义范围内。也可以重复给定的步骤或步骤的子集。In the biomass processing methods described herein, the steps can be performed in any order without departing from the principles of the invention, except where a temporal or operational sequence is expressly stated. Statements in the claims that a first step is performed first and a number of other steps are performed subsequently should be deemed to mean that the first step is performed before any other steps, but that the other steps may be performed in any suitable order unless further stated in the other steps regarding the order. For example, a claim element stating "step A, step B, step C, step D, and step E" should be interpreted as step A being performed first and step E being performed last, and steps B, C, and D may be performed in any order between steps A and E and still fall within the semantic scope of the claimed method. Given steps or subsets of steps may also be repeated.
此外,可以同时执行指定的步骤,除非权利要求的用语明确表述要独立地执行这些步骤。例如,执行X的权利要求步骤和执行Y的权利要求步骤可以在单个操作内同时进行,并且所得到的方法应当落在要求保护的方法的语义范围内。Furthermore, specified steps may be performed simultaneously unless the claim language explicitly states that the steps are to be performed independently. For example, a claim step of performing X and a claim step of performing Y may be performed simultaneously within a single operation, and the resulting method would fall within the semantic scope of the claimed method.
术语“生物质”应理解为表示任何有机材料,优选地表示任何植物或者基于植物的有机材料,包括但不限于木质生物质(例如,锯屑、森林残余物等);草本生物质(例如,玉米秸秆和残余物、甘蔗渣、甘蔗残余物等);果实生物质;水生生物质;共混物和混合物。The term "biomass" should be understood to mean any organic material, preferably any plant or plant-based organic material, including but not limited to woody biomass (e.g., sawdust, forest residues, etc.); herbaceous biomass (e.g., corn stover and residues, bagasse, sugarcane residues, etc.); fruit biomass; aquatic biomass; blends and mixtures.
本文使用的选定术语的其它定义可以在本发明的详细描述中找到并且全文适用。除非另外限定,否则本文使用的所有其它的技术术语具有与本发明所属领域的普通技术人员的通常理解相同的含义。Other definitions of selected terms used herein can be found in the detailed description of the invention and apply throughout. Unless otherwise defined, all other technical terms used herein have the same meaning as commonly understood by those of ordinary skill in the art to which the invention belongs.
本发明的详细描述Detailed description of the invention
在以下描述中,阐述优选实施例。对于本领域技术人员而言显而易见的是,在不脱离本发明的范围和精神的前提下,可以进行包括添加和/或替换在内的修改。可以省略具体细节以免掩盖本发明;然而,写出的公开内容是为了使本领域技术人员能够实践本文中的教导而无需过度的实验。In the following description, preferred embodiments are described. It will be apparent to those skilled in the art that modifications, including additions and/or substitutions, may be made without departing from the scope and spirit of the invention. Specific details may be omitted so as not to obscure the invention; however, this disclosure is written to enable those skilled in the art to practice the teachings herein without undue experimentation.
给出以下示例以作为本发明的示例性实施例,但是不应理解为将本发明限制到所阐述的具体实施例。除非相反地指明,否则所有的份额和百分比都是以重量计。所有数值都是近似值。当给出数值范围时,应当理解为在所述范围之外的实施例仍然可以落入本发明的范围内。在每个示例中描述的具体细节不应被解读为本发明的必要特征。The following examples are provided as exemplary embodiments of the present invention, but should not be construed as limiting the present invention to the specific embodiments described. Unless otherwise indicated, all parts and percentages are by weight. All numerical values are approximate. When a numerical range is given, it should be understood that embodiments outside of the range may still fall within the scope of the present invention. The specific details described in each example should not be interpreted as essential features of the present invention.
示例Example
图2A示出了用连续或分批生物质处理系统处理生物质的方法,所述方法包括致密成型阶段(500)、第一处理阶段(800)和第二处理阶段(900)、以及冷却处理阶段(600)。在图2B中,除了图2A所示的阶段之外,还向方法中加入了具有传感器和控制装置的附加控制系统(300)以用于实时监测和控制实际水分含量、实际氧含量、实际温度、气体的流速和驻留时间等,从而确保所有参数符合预定的致密成型和烘焙条件,并且所述方法包括:将基本干燥和尺寸减小的、包含一定的水分含量(优选地重量百分比在8%至12%之间)的生物质(10)进给到致密成型阶段(500)中以生成颗粒或压块形式的经过致密成型的生物质;将经过致密成型的生物质从致密成型阶段(500)排出到第一处理阶段(800),所述第一处理阶段包括将包含水分的经过致密成型的生物质加热到预烘焙温度(优选地在260℃至300℃的范围内)并持续第一驻留时间,其中,通过在第一处理阶段(800)中蒸发水分而基本上完全干燥包含水分的经过致密成型的生物质,并且在所述第一处理阶段(800)之后至少部分地烘焙经过致密成型的生物质以形成经过预烘焙的生物质。此后,将经过预烘焙的生物质从第一处理阶段(800)排出到第二处理阶段(900),所述第二处理阶段包括以优选地在240℃至280℃的范围内的温度加热供应到第二处理阶段(900)的经过预烘焙的生物质并持续第二驻留时间,以便形成经过烘焙的生物质(20);经由生物质排出装置(70)和气体密封阀出口(25)将经过烘焙的生物质(20)从第二处理阶段(900)排出到冷却处理阶段(600)。还设有由热交换装置使用来自燃烧器的烟道气(12)而执行的热交换步骤(700),以用于加热经历第一处理阶段和第二处理阶段之后回收的高温气体的一部分,以便将这些回收的高温气体重新引入到第一处理阶段和第二处理阶段中。离开热交换装置的烟道气(12)也能够例如在所述致密成型阶段(500)之前向其它阶段(701)供热,来自热交换步骤(700)的烟道气热可以用于在将生物质引至颗粒成型或压块成型的致密成型步骤之前将生物质的水分含量减小到重量百分比为8%至12%的范围内。FIG2A shows a method for processing biomass using a continuous or batch biomass processing system, the method comprising a densification stage (500), a first processing stage (800), a second processing stage (900), and a cooling processing stage (600). In FIG2B , in addition to the stages shown in FIG2A , an additional control system (300) having sensors and control devices is added to the method for real-time monitoring and control of actual moisture content, actual oxygen content, actual temperature, gas flow rate and residence time, etc., to ensure that all parameters meet predetermined densification and baking conditions, and the method comprises: feeding substantially dried and size-reduced biomass (10) containing a certain moisture content (preferably between 8% and 12% by weight) into the densification stage (500) to generate densified biomass in the form of pellets or briquettes. the densified biomass being discharged from the densification stage (500) to a first processing stage (800), the first processing stage comprising heating the moisture-containing densified biomass to a pre-toasting temperature (preferably in the range of 260° C. to 300° C.) for a first residence time, wherein the moisture-containing densified biomass is substantially completely dried by evaporating the moisture in the first processing stage (800), and the densified biomass is at least partially toasted after the first processing stage (800) to form pre-toasted biomass. Thereafter, the pre-torrefied biomass is discharged from the first treatment stage (800) to a second treatment stage (900), the second treatment stage comprising heating the pre-torrefied biomass supplied to the second treatment stage (900) at a temperature preferably in the range of 240°C to 280°C for a second residence time to form torrefied biomass (20); the torrefied biomass (20) is discharged from the second treatment stage (900) to a cooling treatment stage (600) via a biomass discharge device (70) and a gas sealing valve outlet (25). A heat exchange step (700) is also provided using flue gas (12) from the burner by a heat exchange device for heating a portion of the high-temperature gas recovered after the first and second treatment stages, so as to reintroduce the recovered high-temperature gas into the first and second treatment stages. The flue gas (12) leaving the heat exchange device can also provide heat to other stages (701), for example before the densification molding stage (500), and the flue gas heat from the heat exchange step (700) can be used to reduce the moisture content of the biomass to a range of 8% to 12% by weight before the biomass is introduced into the densification molding step of pellet molding or briquette molding.
优选地,本方法的第一处理阶段(800)和第二处理阶段(900)在相同的处理室中执行。相对于任何常规方法而言,根据本方法在相同的处理室中执行第一处理阶段和第二处理阶段能够在使用相同的时间量和温度的同时减少生物质的烘焙所需的能量。根据本方法可以使用与常规方法相同用量的能量,同时能够降低用于生物质的烘焙的时时间量和温度。总之,与常规方法相比,本方法至少能够节省用于生物质的烘焙的能量、时间和温度,从而导致成本降低。Preferably, the first treatment stage (800) and the second treatment stage (900) of the present method are performed in the same treatment chamber. Compared to any conventional method, performing the first treatment stage and the second treatment stage in the same treatment chamber according to the present method can reduce the energy required for the baking of the biomass while using the same amount of time and temperature. According to the present method, the same amount of energy as the conventional method can be used while reducing the amount of time and temperature used for the baking of the biomass. In short, compared with the conventional method, the present method can at least save energy, time and temperature used for the baking of the biomass, thereby reducing costs.
在本方法的第一处理阶段(800)和第二处理阶段(900)期间,相应的连续或分批生物质处理系统或生物质处理装置包括至少一个第一高温气体入口(110)和至少一个第一高温气体出口(111);以及至少一个第二高温气体入口(220)和至少一个第二高温气体出口(222),如图3所示,以用于相应的第一高温气体和第二高温气体流入和流出装置的相应处理隔室。During the first processing stage (800) and the second processing stage (900) of the present method, the corresponding continuous or batch biomass processing system or biomass processing device includes at least one first high-temperature gas inlet (110) and at least one first high-temperature gas outlet (111); and at least one second high-temperature gas inlet (220) and at least one second high-temperature gas outlet (222), as shown in Figure 3, for the corresponding first high-temperature gas and second high-temperature gas to flow into and out of the corresponding processing compartments of the device.
在图3中,来自执行第一处理阶段的第一处理隔室中的第一高温气体入口(110)的第一高温气体(11)与经由气体密封阀入口(15)来自致密成型阶段的基本干燥和经过致密成型的生物质直接接触,其中所述第一高温气体包括体积百分比等于或小于10%的氧。来自执行第二处理阶段的第二处理隔室中的第二高温气体入口(220)的第二高温气体(22)与来自第一处理阶段的经过预烘焙的生物质直接接触,其中所述第二高温气体包括体积百分比等于或小于3%的氧。In Figure 3, a first high-temperature gas (11) from a first high-temperature gas inlet (110) in a first processing compartment performing a first processing stage is in direct contact with the substantially dried and densified biomass from the densification stage via a gas sealing valve inlet (15), wherein the first high-temperature gas comprises oxygen in an amount equal to or less than 10% by volume. A second high-temperature gas (22) from a second high-temperature gas inlet (220) in a second processing compartment performing a second processing stage is in direct contact with the pre-torrefied biomass from the first processing stage, wherein the second high-temperature gas comprises oxygen in an amount equal to or less than 3% by volume.
离开第一处理隔室的第一高温气体出口(111)的、包含挥发性可燃气体的第一高温气体(11)的至少一部分(11a)再循环到燃烧器(400)以用于生成烟道气(12),这些烟道气经由热交换装置加热回收的第一高温气体(11)中的要重新引入到第一处理隔室中的一部分。类似地,离开第二处理隔室的第二高温气体出口(222)的包含挥发性可燃气体的第二高温气体(22)的至少一部分(22a)再循环到燃烧器(400)以用于生成烟道气(12),这些烟道气用于经由热交换装置加热回收的第二高温气体(22)中的要重新引入到第二处理隔室中的一部分。At least a portion (11a) of the first high-temperature gas (11) containing volatile combustible gas exiting the first high-temperature gas outlet (111) of the first processing compartment is recycled to the burner (400) for generating flue gas (12), which is used to heat a portion of the recovered first high-temperature gas (11) to be reintroduced into the first processing compartment via a heat exchange device. Similarly, at least a portion (22a) of the second high-temperature gas (22) containing volatile combustible gas exiting the second high-temperature gas outlet (222) of the second processing compartment is recycled to the burner (400) for generating flue gas (12), which is used to heat a portion of the recovered second high-temperature gas (22) to be reintroduced into the second processing compartment via a heat exchange device.
由于第一处理阶段用于完全干燥除去经过致密成型的生物质(10)中的所有剩余水分,因此生物质在第一处理阶段中的第一驻留时间等于或短于在第二处理阶段中执行实际烘焙所用的第二驻留时间。Since the first treatment stage is used to completely dry out any remaining moisture in the densified biomass (10), the first residence time of the biomass in the first treatment stage is equal to or shorter than the second residence time used in the second treatment stage for performing the actual torrefaction.
为了在第一处理阶段中快速干燥除去相对较低温的经过致密成型的生物质(10)中的剩余水分,第一处理阶段中在第一高温气体入口(110)处的第一高温气体(11)的温度被设定为等于或高于第一处理阶段中在第二高温气体入口(220)处的第二高温气体(22)的温度。在第一高温气体入口处的第一高温气体的温度以及在第二高温气体入口处的第二高温气体的温度可以分别由控制和监测装置(图2B中的300)监测和控制。In order to quickly dry and remove the remaining moisture in the relatively low-temperature densified biomass (10) in the first process stage, the temperature of the first high-temperature gas (11) at the first high-temperature gas inlet (110) in the first process stage is set to be equal to or higher than the temperature of the second high-temperature gas (22) at the second high-temperature gas inlet (220) in the first process stage. The temperature of the first high-temperature gas at the first high-temperature gas inlet and the temperature of the second high-temperature gas at the second high-temperature gas inlet can be monitored and controlled by the control and monitoring device (300 in Figure 2B), respectively.
然后,在冷却处理阶段(600)将离开第二处理阶段的经过烘焙的生物质冷却到低于100℃,优选地冷却到约为室温(例如25℃)的温度,原因在于经过烘焙的高温颗粒或压块是反应性的。通过使经过烘焙的生物质与冷却剂气体直接接触或者通过使经过烘焙的生物质与水直接接触而执行冷却处理阶段。The torrefied biomass leaving the second treatment stage is then cooled in a cooling treatment stage (600) to a temperature below 100°C, preferably to a temperature of about room temperature (e.g., 25°C), because the torrefied hot pellets or briquettes are reactive. The cooling treatment stage is performed by directly contacting the torrefied biomass with a coolant gas or by directly contacting the torrefied biomass with water.
图3提供了用于根据本发明的方法处理生物质的连续或分批紧凑式移动床反应器类型的装置。所述装置包括具有双壁壳体的处理室,并且优选地为环形的形式,其限定基本竖直的轴线。在双壁壳体的外壁和内壁之间限定内周边间隙。所述处理室包括:经由至少一个气体密封阀入口(15)来自处理室的顶部的生物质(10)的供给;至少一个生物质分配装置(40);用于在处理室的底部处均匀地排出经过烘焙的生物质颗粒的生物质排出装置(70);经由至少一个气体密封阀出口(25)的至少一个经过烘焙的生物质的最终出口;用于第一处理阶段的至少一个第一高温气体入口(110)和至少一个第一高温气体出口(111);用于第二处理阶段的至少一个第二高温气体入口(220)和至少一个第二高温气体出口(222);处理室的双壁壳体的内穿孔壁(60);高温气体分配系统,其包括在处理室中布置成星形或蛛网形或环形的形式的多个穿孔双分离板(62),布置在处理室的中部的至少一个穿孔管道(91、92),其中内穿孔壁(60)、穿孔双分离板(62)和穿孔管道(91、92)沿着竖直轴线从处理室的底部向顶部升高,并且其中第一高温气体(11)供给到优选安装在第一处理隔室的顶部的至少一个第一高温气体入口(110),沿着双壁壳体的内周边间隙和布置成星形或蛛网形或环形的形式的穿孔双分离板(62)的间隙推送以均匀地加热第一处理隔室中所有的经过致密成型的生物质(10),并且最终通过布置在处理室的中部的穿孔管道(91)回收,并且由优选安装在第一处理隔室的底部的至少一个第一高温气体出口(111)排出。类似地,第二高温气体(22)供给到优选安装在第二处理隔室的底部的至少一个第二高温气体入口(220),沿着双壁壳体的内周边间隙和布置成星形或蛛网形或环形的形式的穿孔双分离板(62)的间隙推送以均匀地加热第二处理隔室中所有的经过预烘焙的生物质,并且最终通过布置在处理室的中部的穿孔管道(92)回收,并且由优选安装在第二处理隔室的顶部的至少一个第二高温气体出口(222)排出。Figure 3 provides a device of the continuous or batch compact moving bed reactor type for treating biomass according to the method of the present invention. The device comprises a treatment chamber having a double-walled shell and preferably in the form of an annular shape, which defines a substantially vertical axis. An inner peripheral gap is defined between the outer wall and the inner wall of the double-walled shell. The treatment chamber comprises: a supply of biomass (10) from the top of the treatment chamber via at least one gas-tight valve inlet (15); at least one biomass distribution device (40); a biomass discharge device (70) for uniformly discharging the torrefied biomass particles at the bottom of the treatment chamber; at least one final outlet for torrefied biomass via at least one gas-tight valve outlet (25); at least one first high-temperature gas inlet (110) and at least one first high-temperature gas outlet (111) for the first treatment stage; at least one second high-temperature gas inlet (220) and at least one second high-temperature gas outlet (222) for the second treatment stage; an inner perforated wall (60) of the double-walled shell of the treatment chamber; a high-temperature gas distribution system comprising a plurality of gas-tight valves arranged in the treatment chamber in the form of a star, spider web or an annular shape. A perforated double separation plate (62), at least one perforated pipe (91, 92) arranged in the middle of the treatment chamber, wherein the inner perforated wall (60), the perforated double separation plate (62) and the perforated pipe (91, 92) rise from the bottom to the top of the treatment chamber along the vertical axis, and wherein the first high-temperature gas (11) is supplied to at least one first high-temperature gas inlet (110) preferably installed at the top of the first treatment compartment, and is pushed along the inner peripheral gap of the double-walled shell and the gap of the perforated double separation plate (62) arranged in a star-shaped, spider-web-shaped or ring-shaped form to uniformly heat all the densely formed biomass (10) in the first treatment compartment, and is finally recovered through the perforated pipe (91) arranged in the middle of the treatment chamber and discharged by at least one first high-temperature gas outlet (111) preferably installed at the bottom of the first treatment compartment. Similarly, the second high-temperature gas (22) is supplied to at least one second high-temperature gas inlet (220) preferably installed at the bottom of the second processing compartment, pushed along the inner peripheral gap of the double-walled shell and the gap of the perforated double separation plate (62) arranged in a star shape, spider web shape or ring shape to uniformly heat all the pre-baked biomass in the second processing compartment, and is finally recovered through the perforated pipe (92) arranged in the middle of the processing chamber, and discharged by at least one second high-temperature gas outlet (222) preferably installed at the top of the second processing compartment.
根据生产规模,可以进一步将优选呈环形的多个双壁结构引入处理室中。在较大生产规模的情况下,在处理室的双壁壳体内部,可以引入呈环形的附加双壁结构,其包括外壁和内壁(任意的一个壁或者两个壁可以穿孔),限定用于其它高温气体入口的内间隙以沿着呈环形的所述附加双壁结构的内间隙引导高温气体,并且随后经过所述双壁结构的外内穿孔壁引导到第一处理隔室和第二处理隔室中的任何一个。换句话说,通过将双壁结构加入到处理室中即可容易地扩展本装置。引入所述双壁结构的优点之一是,当生产规模增加时,即使所处理的生物质的体积增加,也能够在处理室中有效地且均匀地分配高温气体。通过在本发明的处理室内部引入附加双壁结构而进行扩展的成本相对低于改造任何常规烘焙反应器以应对生产规模增加的成本,原因是常规烘焙反应器在改造期间通常会受限于其形状和设计。在扩展的情况下,本装置优于常规烘焙反应器的另一优点是,即使引入了用于将更多高温气体引导到处理室中的多个双壁结构,也仅需要将至少一个穿孔管道布置在处理室的沿其竖直轴线的中部以用于将高温气体的剩余部分引出处理室,这表明基于本装置的设计的改造成本能够显著降低。而且,在效率方面,在扩展的情况下借助于引入该类型的双壁结构即可在处理室内部更均匀地分配高温气体,这表明本装置更节能、耗时更少并且在处理生物质时能够保持均质的产品质量。Depending on the scale of production, multiple double-wall structures, preferably in an annular shape, can be further introduced into the processing chamber. In the case of larger production scales, an additional double-wall structure in the shape of an annulus can be introduced inside the double-walled shell of the processing chamber, comprising an outer wall and an inner wall (either one or both walls can be perforated), defining an inner gap for an additional hot gas inlet to guide the hot gas along the inner gap of the additional double-wall structure in the annular shape, and then through the outer and inner perforated walls of the double-wall structure to either the first processing compartment or the second processing compartment. In other words, the device can be easily expanded by adding a double-wall structure to the processing chamber. One advantage of introducing the double-wall structure is that when the production scale increases, even if the volume of the biomass being processed increases, the hot gas can be effectively and evenly distributed in the processing chamber. The cost of expansion by introducing the additional double-wall structure inside the processing chamber of the present invention is relatively lower than the cost of modifying any conventional torrefaction reactor to cope with the increase in production scale, because conventional torrefaction reactors are generally limited by their shape and design during modification. Another advantage of this device over conventional torrefaction reactors in the expanded case is that, even with the introduction of multiple double-wall structures to direct more high-temperature gas into the processing chamber, only at least one perforated pipe needs to be arranged in the middle of the processing chamber along its vertical axis to direct the remaining portion of the high-temperature gas out of the processing chamber. This significantly reduces modification costs based on the design of this device. Furthermore, in terms of efficiency, the introduction of this type of double-wall structure in the expanded case allows for more uniform distribution of the high-temperature gas within the processing chamber, meaning that this device is more energy-efficient, less time-consuming, and can maintain consistent product quality when processing biomass.
图4示出了生物质分配装置的一个实施例,其具有安装在由马达(30)驱动的旋转刮器轮(40)上的至少一个旋转刮器臂(42),以均匀地分配来自气体密封阀入口(15)的生物质。Figure 4 shows an embodiment of a biomass distribution device having at least one rotating scraper arm (42) mounted on a rotating scraper wheel (40) driven by a motor (30) to evenly distribute biomass from a gas sealing valve inlet (15).
为了在第一处理隔室的双壁壳体和第二处理隔室的双壁壳体之间分离第一高温气体(11)和第二高温气体(22),设置非穿孔气体隔板(65)。In order to separate the first high temperature gas (11) and the second high temperature gas (22) between the double-walled shell of the first process compartment and the double-walled shell of the second process compartment, a non-perforated gas separator (65) is provided.
为了构造的稳定性,穿孔双分离板(62)布置成星形或蛛网形的形式,穿孔双分离板的至少一个第一端部连接到处于处理室的中部的穿孔管道(91、92)。For structural stability, the perforated double separation plates (62) are arranged in a star or spider web form, and at least one first end of the perforated double separation plates is connected to a perforated pipe (91, 92) in the middle of the treatment chamber.
为了构造的稳定性,穿孔双分离板(62)布置成星形或蛛网形的形式,穿孔双分离板的至少一个第二端部连接到处理室的内穿孔壁(60)。For structural stability, the perforated double separation plates (62) are arranged in a star or spider web form, and at least one second end of the perforated double separation plates is connected to the inner perforated wall (60) of the processing chamber.
图6A、图6B、图7A、图7B和图8分别示出了星形、蛛网形或环形的高温气体分配处理室,其中穿孔双分离板(62)布置成将处理室分为至少两个基本竖直部段。如图6A和图6B所示,呈星形的穿孔双分离板(62)将处理室(包括第一处理隔室和第二处理隔室)分成八个竖直部段,这些竖直部段围绕沿着竖直轴线布置在处理室的中部的穿孔管道(91、92)。如图7A所示,呈蛛网形的穿孔双分离板(62)将处理室分成十六个竖直部段;而在图7B中,另一呈蛛网形的穿孔分离板(62)将处理室分成八个竖直部段。在图8中,穿孔双分离板(62)将处理室分成两个竖直部段,其中一个竖直部段被另一个竖直部段围绕。Figures 6A, 6B, 7A, 7B, and 8 illustrate a high-temperature gas distribution process chamber in a star-shaped, spider-web-shaped, or annular shape, respectively, wherein a perforated double separator plate (62) is arranged to divide the process chamber into at least two substantially vertical sections. As shown in Figures 6A and 6B, the star-shaped perforated double separator plate (62) divides the process chamber (including the first process compartment and the second process compartment) into eight vertical sections, which are arranged around perforated pipes (91, 92) arranged in the middle of the process chamber along a vertical axis. As shown in Figure 7A, the spider-web-shaped perforated double separator plate (62) divides the process chamber into sixteen vertical sections; while in Figure 7B, another spider-web-shaped perforated separator plate (62) divides the process chamber into eight vertical sections. In Figure 8, the perforated double separator plate (62) divides the process chamber into two vertical sections, one of which is surrounded by the other.
生物质(10)借助于重力从第一处理阶段移动到第二处理阶段以便取消其间的任何机械或气动部件,由此节省维护、能量、时间和成本。当经过预烘焙的生物质在本装置的处理室中从第一处理隔室移动到第二处理隔室时,其通过穿孔双分离板的竖直空间。为了避免在通过期间由生物质阻塞穿孔双分离板(62)的任何穿孔,穿孔设计成仅允许高温气体(11、22)流过而生物质(10)不能流过。在图9中示出了具有该类型穿孔的穿孔双分离板的一个实施例。实线箭头表示高温气体的流动,并且无阴影箭头表示生物质在处理室内部从第一处理隔室移动到第二处理隔室的方向。在图9所示的实施例中,穿孔(93)配置成仅允许气体流入或流出穿孔双分离板的间隙,而不允许生物质或其它固体通过所述穿孔。为了具有这样的配置,通过开通穿孔双分离板的壁的一部分以使得穿孔基本能透过气体但是不能透过生物质或其它固体,即可形成帽状结构,其类似于从穿孔双分离板的壁延伸的略微弯曲的突起(93a)。而且,在该实施例中通过开通穿孔双分离板的壁而形成的略微弯曲的突起可以在一个方向上突出,以使得只能透过气体的孔隙状开口(93b)面向从第一处理隔室到第二处理隔室的生物质运动不受突起(93a)阻挡的方向,进一步减小生物质通过穿孔双分离板的穿孔(93a)的几率。所述穿孔优选地通过对形成穿孔双分离板的所述壁的金属材料片材进行冲压和打孔而制成。该类型的穿孔也可以应用于本发明的需要穿孔以允许高温气体流入和/或流出处理室的其它部分,例如穿孔管道或者内穿孔壁。Biomass (10) moves from the first processing stage to the second processing stage by means of gravity in order to cancel any mechanical or pneumatic components therebetween, thereby saving maintenance, energy, time and cost. When the pre-baked biomass moves from the first processing compartment to the second processing compartment in the processing chamber of this device, it passes through the vertical space of the perforated double separation plate. In order to avoid any perforation of the perforated double separation plate (62) being blocked by biomass during passing, the perforation is designed to only allow high-temperature gas (11, 22) to flow through while biomass (10) cannot flow through. An embodiment of a perforated double separation plate with this type of perforation is shown in Figure 9. The solid arrows represent the flow of high-temperature gas, and the unshaded arrows represent the direction in which biomass moves from the first processing compartment to the second processing compartment inside the processing chamber. In the embodiment shown in Figure 9, the perforations (93) are configured to only allow gas to flow into or out of the gap of the perforated double separation plate, without allowing biomass or other solids to pass through the perforations. In order to have such a configuration, a cap-like structure is formed by opening a portion of the wall of the perforated double separator plate so that the perforations are substantially permeable to gas but not to biomass or other solids, which is similar to a slightly curved protrusion (93a) extending from the wall of the perforated double separator plate. Moreover, in this embodiment, the slightly curved protrusion formed by opening the wall of the perforated double separator plate can protrude in one direction so that the pore-like opening (93b) that can only pass through gas faces the direction in which the biomass movement from the first processing compartment to the second processing compartment is not blocked by the protrusion (93a), further reducing the probability of biomass passing through the perforations (93a) of the perforated double separator plate. The perforations are preferably made by stamping and punching the metal material sheet forming the wall of the perforated double separator plate. This type of perforation can also be applied to other parts of the present invention that need perforations to allow high-temperature gas to flow into and/or out of the processing chamber, such as perforated pipes or inner perforated walls.
对于用于快速干燥除去生物质(10)中的剩余水分的预烘焙的第一处理阶段,即使与温度为260-300℃的第一高温气体(11)直接接触,第一高温气体(11)也能够耐受氧体积百分比至多为10%的氧浓度而不会自启动生物质的内部燃烧。相反地,当完全干燥的生物质进入第二处理阶段时,为了避免因与温度为240-280℃的第二高温气体(22)直接接触而引起生物质的自燃,氧浓度需要保持在至多为3%的氧体积百分比。第二处理阶段的温度设定成等于或低于第一处理阶段的温度,以便更好地控制经过烘焙的生物质的质量和能量平衡以及避免碳化的发生。For the first treatment stage of pre-baking for rapid drying and removal of residual moisture in the biomass (10), even in direct contact with the first high-temperature gas (11) at a temperature of 260-300°C, the first high-temperature gas (11) can tolerate an oxygen concentration of up to 10% by volume without self-initiating internal combustion of the biomass. Conversely, when the completely dried biomass enters the second treatment stage, in order to avoid spontaneous combustion of the biomass due to direct contact with the second high-temperature gas (22) at a temperature of 240-280°C, the oxygen concentration needs to be maintained at up to 3% by volume. The temperature of the second treatment stage is set to be equal to or lower than the temperature of the first treatment stage in order to better control the mass and energy balance of the baked biomass and to avoid the occurrence of carbonization.
为了实现以自热模式节省外部燃料的烘焙方法的节能,离开第一处理阶段的包含挥发性可燃气体的第一高温气体(11)的至少一部分再循环到燃烧器(400)以用于生成烟道气(12),这些烟道气用于经由热交换装置加热要重新引入到执行第一处理阶段的第一处理隔室中的第一高温气体(11),并且离开第二处理阶段的包含挥发性可燃气体的第二高温气体(22)的至少一部分再循环到燃烧器(400)以用于生成烟道气(12),这些烟道气用于经由热交换装置加热要重新引入到执行第二处理阶段的第二处理隔室中的第二高温气体(22)。对于分别用于加热第一高温气体和第二高温气体的所述烟道气而言,所述一个或多个热交换装置可以是相同的或不同的。以该方式,不需要附加的外部燃料来连续地加热用于所述第一处理阶段和第二处理阶段或者所述第一处理隔室和第二处理隔室的第一高温气体和第二高温气体,从而提供用于处理生物质的自持续的方法或装置。In order to achieve energy saving in a torrefaction method that saves external fuel in an autothermal mode, at least a portion of the first high-temperature gas (11) containing volatile combustible gas leaving the first process stage is recycled to the burner (400) for generating flue gas (12), which is used to heat the first high-temperature gas (11) to be reintroduced into the first process compartment where the first process stage is performed, via a heat exchange device, and at least a portion of the second high-temperature gas (22) containing volatile combustible gas leaving the second process stage is recycled to the burner (400) for generating flue gas (12), which is used to heat the second high-temperature gas (22) to be reintroduced into the second process compartment where the second process stage is performed, via a heat exchange device. The one or more heat exchange devices for heating the flue gas of the first high-temperature gas and the second high-temperature gas, respectively, may be the same or different. In this way, no additional external fuel is required to continuously heat the first high-temperature gas and the second high-temperature gas for the first process stage and the second process stage or the first process compartment and the second process compartment, thereby providing a self-sustaining method or device for processing biomass.
由于生物质(10)从气体密封阀入口(15)到气体密封阀出口(25)的自顶向下的转移是通过重力进行,因此生物质在处理室中的驻留时间与处理室的相应处理隔室的高度成比例。仅主要用于完全干燥除去经过致密成型的生物质中的水分的第一处理阶段可以在等于或短于第二处理阶段中的烘焙处理的驻留时间的驻留时间内执行,因此,执行第一处理阶段的第一处理隔室的高度等于或短于执行第二处理阶段的第二处理隔室的高度。Since the biomass (10) is transferred from the gas-tight valve inlet (15) to the gas-tight valve outlet (25) from top to bottom by gravity, the residence time of the biomass in the treatment chamber is proportional to the height of the corresponding treatment compartment of the treatment chamber. The first treatment stage, which is mainly used to completely dry and remove moisture from the compacted biomass, can be performed within a residence time that is equal to or shorter than the residence time of the torrefaction treatment in the second treatment stage. Therefore, the height of the first treatment compartment in which the first treatment stage is performed is equal to or shorter than the height of the second treatment compartment in which the second treatment stage is performed.
为了给通过第一处理阶段和第二处理阶段的每个颗粒或压块提供均匀的驻留时间,应当采用特别设计的生物质排出装置(70)。图5A和图5B示出了生物质排出装置的一个实施例,其包括由至少一个旋转马达(80)驱动的两个同轴旋转盘(71和72),其中每个盘具有交替布置的星形的多个开口(711或722)和多个型块(710或720),并且其中两个盘在相同或彼此相反的方向上旋转和/或以相同或不同的速度旋转,以便根据受控的输出速率从第二处理室均匀地排出所有的经过烘焙的生物质。In order to provide a uniform residence time for each particle or briquette passing through the first and second processing stages, a specially designed biomass discharge device (70) should be used. Figures 5A and 5B show an embodiment of the biomass discharge device, which includes two coaxial rotating disks (71 and 72) driven by at least one rotary motor (80), wherein each disk has a plurality of openings (711 or 722) and a plurality of briquettes (710 or 720) arranged alternately in a star shape, and wherein the two disks rotate in the same or opposite directions and/or at the same or different speeds so as to uniformly discharge all the torrefied biomass from the second processing chamber according to a controlled output rate.
为了有效地控制和监测整个致密成型和烘焙系统,安装具有传感器和控制装置的控制系统(300)以用于监测和控制处理室中的实际水分含量、实际氧含量和实际温度,从而确保所有参数都符合预定的烘焙条件。In order to effectively control and monitor the entire compacting and baking system, a control system (300) having sensors and control devices is installed to monitor and control the actual moisture content, actual oxygen content and actual temperature in the processing chamber, thereby ensuring that all parameters meet the predetermined baking conditions.
尽管已经参照有限数量的实施例描述了本发明,但是一个实施例的具体特征不应当必然归属于本发明的其它实施例。在一些实施例中的方法可以包括本文中未提及的许多步骤。在另一些实施例中的方法不包括或者基本上没有本文中未列举的任何步骤。存在源自所述实施例的多种修改和变型。所附的权利要求旨在涵盖落入本发明的范围内的所有这些修改和变型。Although the present invention has been described with reference to a limited number of embodiments, the specific features of one embodiment should not necessarily be attributed to other embodiments of the invention. The method in some embodiments may include many steps not mentioned herein. The method in other embodiments does not include or is substantially free of any steps not enumerated herein. There are many modifications and variations derived from the described embodiments. The appended claims are intended to cover all such modifications and variations that fall within the scope of the invention.
工业实用性Industrial Applicability
通过在烘焙阶段之前首先执行均质颗粒或压块形式的致密成型阶段以符合MISO原理,本发明的方法在处理生物质和其它等同的固体废料(特别是木质/农业生物质/固体废料)方面是有效的和能量高效的,因此本发明的方法消除了与经过烘焙的生物质的后致密成型(包括但不限于使用粘结剂)相关联的大多数问题。另外,本发明的装置不仅用于实施本发明的方法,而且也适用于其它的处理方法例如需要输入物料的均匀分配、需要具有再循环高温气体的连续供给的处理室的实时控制和监测、和/或需要最终产品的均匀排出的方法。本发明的装置也适用于处理诸如咖啡豆或者其它农业/非农业材料这样的物料,这些物料需要对热和热化学处理方法所用的氧、温度、驻留时间和均质性进行实时控制。The method of the present invention is effective and energy efficient in processing biomass and other equivalent solid wastes (particularly woody/agricultural biomass/solid wastes) by first performing a densification stage in the form of homogenized pellets or briquettes prior to the roasting stage in accordance with the MISO principle, thereby eliminating most of the problems associated with post-densification of roasted biomass (including but not limited to the use of binders). In addition, the apparatus of the present invention is not only useful for implementing the method of the present invention, but is also applicable to other processing methods such as those requiring uniform distribution of input material, requiring real-time control and monitoring of the processing chamber with a continuous supply of recirculating high-temperature gas, and/or requiring uniform discharge of the final product. The apparatus of the present invention is also suitable for processing materials such as coffee beans or other agricultural/non-agricultural materials that require real-time control of oxygen, temperature, residence time and homogeneity for thermal and thermochemical processing methods.
Claims (42)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15/270,963 US10221359B2 (en) | 2016-09-20 | 2016-09-20 | Biomass treatment process and apparatus |
| US15/270,963 | 2016-09-20 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| HK1251861A1 HK1251861A1 (en) | 2019-04-26 |
| HK1251861B true HK1251861B (en) | 2021-02-05 |
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