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HK1199144B - Sensor device including one or more metal-dielectric optical filters - Google Patents

Sensor device including one or more metal-dielectric optical filters Download PDF

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Publication number
HK1199144B
HK1199144B HK14112332.6A HK14112332A HK1199144B HK 1199144 B HK1199144 B HK 1199144B HK 14112332 A HK14112332 A HK 14112332A HK 1199144 B HK1199144 B HK 1199144B
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filters
sensor device
layers
filter
dielectric
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HK14112332.6A
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HK1199144A1 (en
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乔治‧J‧欧肯法斯
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唯亚威通讯技术有限公司
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Publication of HK1199144B publication Critical patent/HK1199144B/en

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Description

包括一个或多个金属-电介质滤光器的传感器设备Sensor device comprising one or more metal-dielectric filters

技术领域Technical Field

本发明涉及包括一个或多个滤光器的传感器设备,更具体地,涉及一个或多个金属-电介质滤光器。The present invention relates to sensor devices comprising one or more optical filters, and more particularly to one or more metal-dielectric optical filters.

背景技术Background Art

图像传感器是在成像设备(例如摄像机、扫描仪和复印机)中使用,来将光信号转换成电信号,以允许图像捕获的传感器设备。图像传感器通常包括多个传感器元件和布置在多个传感器元件上的多个滤光器。彩色图像传感器包括布置在阵列(即,颜色滤光器阵列(CFA))中的多个颜色滤光器。CFA包括具有不同的颜色通带的不同类型的颜色滤光器,例如红色、绿色和蓝色(RGB)滤光器。Image sensors are sensor devices used in imaging devices (such as cameras, scanners, and copiers) to convert optical signals into electrical signals to allow image capture. Image sensors typically include multiple sensor elements and multiple filters arranged over the multiple sensor elements. A color image sensor includes multiple color filters arranged in an array, known as a color filter array (CFA). A CFA includes different types of color filters with different color passbands, such as red, green, and blue (RGB) filters.

按照惯例,使用染料形成的吸收滤光器被用作颜色滤光器。不幸的是,这样的基于染料的颜色滤光器具有相对宽的颜色通带,导致较不鲜艳的颜色。可替代地,由堆叠的电介质层形成的二向色滤光器(即,干涉滤光器)可用作颜色滤光器。这样的全电介质颜色滤光器具有较高的透射水平和较窄的颜色通带,从而得到较亮和更鲜艳的颜色。然而,全电介质颜色滤光器的颜色通带在有入射角变化的情况下经历相对大的中心波长偏移,导致在颜色上的不希望有的偏移。Conventionally, absorption filters formed using dyes are used as color filters. Unfortunately, such dye-based color filters have relatively wide color passbands, resulting in less vivid colors. Alternatively, dichroic filters (i.e., interference filters) formed from stacked dielectric layers can be used as color filters. Such all-dielectric color filters have higher transmission levels and narrower color passbands, resulting in brighter and more vivid colors. However, the color passband of all-dielectric color filters experiences relatively large central wavelength shifts when the incident angle varies, resulting in undesirable color shifts.

此外,全电介质颜色滤光器一般包括大量堆叠的电介质层,并且相对厚。因此,全电介质颜色滤光器制造起来昂贵和困难。特别是,全电介质颜色滤光器难以用化学方法蚀刻。剥离工艺因此优选用于图案化。在1992年6月9日授权的Hanrahan的美国专利号5,120,622中、在1998年1月27日授权的Buchsbaum的美国专利5,711,889中、在2001年5月29日授权的Edlinger等人的美国专利号6,238,583中、在2003年10月28日授权的Buchsbaum等人的美国专利号6,638,668中、以及在2010年1月19日授权的Buchsbaum等人的美国专利号7,648,808中,公开了用于图案化全电介质CFA的剥离工艺的例子,这些专利通过引用被并入本文。然而,剥离工艺通常被限制于滤光器间隔大约是滤光器高度的两倍,这使难以实现适合于较小的彩色图像传感器的全电介质CFA。Furthermore, all-dielectric color filters typically consist of a large number of stacked dielectric layers and are relatively thick. Consequently, all-dielectric color filters are expensive and difficult to manufacture. In particular, all-dielectric color filters are difficult to etch chemically. Therefore, lift-off processes are preferred for patterning. Examples of lift-off processes for patterning all-dielectric CFAs are disclosed in U.S. Patent Nos. 5,120,622 to Hanrahan, issued June 9, 1992; 5,711,889 to Buchsbaum, issued January 27, 1998; 6,238,583 to Edlinger et al., issued May 29, 2001; 6,638,668 to Buchsbaum et al., issued October 28, 2003; and 7,648,808 to Buchsbaum et al., issued January 19, 2010, which are incorporated herein by reference. However, lift-off processes are generally limited to filter spacing that is approximately twice the filter height, which makes it difficult to implement all-dielectric CFAs suitable for smaller color image sensors.

除了在颜色通带中透射可见光以外,基于染料的颜色滤光器和全电介质颜色滤光器还透射导致噪声的红外(IR)光。因此,彩色图像传感器一般还包括布置在CFA上的IR阻拦滤光器。按照惯例,由有色玻璃形成的吸收滤光器或由堆叠的电介质层形成的二向色滤光器被用作IR阻拦滤光器。可替代地,由堆叠的金属层和电介质层形成的诱导透射滤光器可用作IR阻拦滤光器。在1997年7月15日授权的Sakamoto等人的美国专利号5,648,653中和在2006年11月7日授权的Ockenfuss等人的美国专利号7,133,197中,公开了金属-电介质IR阻拦滤光器的例子,这两个专利通过引用被并入本文。In addition to transmitting visible light in the color passband, dye-based color filters and all-dielectric color filters also transmit infrared (IR) light, which contributes to noise. Therefore, color image sensors generally also include an IR-blocking filter disposed on the CFA. Conventionally, an absorptive filter formed of colored glass or a dichroic filter formed of stacked dielectric layers is used as an IR-blocking filter. Alternatively, an induced-transmission filter formed of stacked metal and dielectric layers can be used as an IR-blocking filter. Examples of metal-dielectric IR-blocking filters are disclosed in U.S. Patent No. 5,648,653, issued on July 15, 1997, to Sakamoto et al., and U.S. Patent No. 7,133,197, issued on November 7, 2006, to Ockenfuss et al., both of which are incorporated herein by reference.

为了避免IR阻拦滤光器的使用,由堆叠的金属和电介质层形成的诱导透射滤光器可用作颜色滤光器。这样的金属-电介质颜色滤光器是固有地IR阻拦的。一般地,金属-电介质颜色滤光器具有相对窄的颜色通带,其在有入射角的变化的情况下波长不发生明显偏移。此外,金属-电介质颜色滤光器通常比全电介质颜色滤光器薄得多。在1990年12月25日授权的McGuckin等人的美国专利号4,979,803中、在2000年2月29日授权的Wang的美国专利号6,031,653中、在2009年12月10日公开的Gidon等人的美国专利申请号2009/0302407中、在2011年8月25日公开的Grand的美国专利申请号2011/0204463中以及在2012年4月12日公开的Gidon等人的美国专利申请号2012/0085944中,公开了金属-电介质颜色滤光器,这些专利/专利申请通过引用被并入本文。To avoid the use of IR-blocking filters, induced transmission filters formed from stacked metal and dielectric layers can be used as color filters. Such metal-dielectric color filters are inherently IR-blocking. Generally, metal-dielectric color filters have a relatively narrow color passband that does not significantly shift in wavelength with changes in the angle of incidence. In addition, metal-dielectric color filters are typically much thinner than all-dielectric color filters. Metal-dielectric color filters are disclosed in U.S. Patent No. 4,979,803 to McGuckin et al., issued on December 25, 1990, in U.S. Patent No. 6,031,653 to Wang, issued on February 29, 2000, in U.S. Patent Application No. 2009/0302407 to Gidon et al., published on December 10, 2009, in U.S. Patent Application No. 2011/0204463 to Grand, published on August 25, 2011, and in U.S. Patent Application No. 2012/0085944 to Gidon et al., published on April 12, 2012, which are incorporated herein by reference.

一般,在金属-电介质颜色滤光器中的金属层是银层,其在环境中是不稳定的,并且在暴露于甚至少量水或硫时发生恶化。用化学方法对银层进行蚀刻使得银层的边缘暴露于环境,允许其恶化。因此,在大多数情况中,通过调节仅仅电介质层的厚度,以便为金属-电介质颜色滤光器选择不同的颜色通带,来图案化金属-电介质CFA。换句话说,具有不同的颜色通带的不同类型的金属-电介质颜色滤光器需要有彼此相同数量的银层和彼此相同厚度的银层。不幸的是,这些要求严重限制金属-电介质颜色滤光器的可能光学设计。Typically, the metal layer in a metal-dielectric color filter is a silver layer, which is environmentally unstable and degrades when exposed to even small amounts of water or sulfur. Chemically etching the silver layer exposes the edges of the silver layer to the environment, allowing it to degrade. Therefore, in most cases, metal-dielectric CFAs are patterned by adjusting the thickness of only the dielectric layer to select different color passbands for the metal-dielectric color filter. In other words, different types of metal-dielectric color filters with different color passbands require the same number of silver layers and the same thickness of silver layers. Unfortunately, these requirements severely limit the possible optical designs of metal-dielectric color filters.

发明内容Summary of the Invention

本发明提供了不受这些要求约束的金属-电介质光滤光器,其特别适合于在图像传感器和其它传感器设备中使用。The present invention provides metal-dielectric optical filters that are not subject to these requirements and are particularly suitable for use in image sensors and other sensor devices.

因此,本发明涉及传感器设备,其包括:一个或多个传感器元件;以及布置在一个或多个传感器元件上的一个或多个滤光器,其中一个或多个滤光器中的每一个包括:多个电介质层;以及与所述多个电介质层交替地堆叠的多个金属层,其中所述多个金属层中的每一个在滤光器的周边处具有由所述多个电介质层中的一个或多个保护性地覆盖的锥形边缘。Therefore, the present invention relates to a sensor device comprising: one or more sensor elements; and one or more filters arranged on the one or more sensor elements, wherein each of the one or more filters comprises: a plurality of dielectric layers; and a plurality of metal layers stacked alternately with the plurality of dielectric layers, wherein each of the plurality of metal layers has a tapered edge at the periphery of the filter, which is protectively covered by one or more of the plurality of dielectric layers.

附图说明BRIEF DESCRIPTION OF THE DRAWINGS

将参考附图更详细地描述本发明,其中:The present invention will be described in more detail with reference to the accompanying drawings, in which:

图1A是本发明的滤光器的第一实施例的横截面的示意图;FIG1A is a schematic diagram of a cross section of a first embodiment of an optical filter of the present invention;

图1B到1G示出了制造图1A的滤光器的方法中的各个步骤;1B to 1G illustrate various steps in a method of manufacturing the optical filter of FIG. 1A ;

图2是本发明的滤光器的第二实施例的横截面的示意图;FIG2 is a schematic diagram of a cross section of a second embodiment of an optical filter of the present invention;

图3是多个滤光器的横截面的示意图;FIG3 is a schematic diagram of a cross section of multiple optical filters;

图4A是示例性红色滤光器的层数、材料和厚度的表;FIG4A is a table of the number of layers, materials, and thicknesses of an exemplary red filter;

图4B是示例性绿色滤光器的层数、材料和厚度的表;FIG4B is a table of the number of layers, materials, and thicknesses of an exemplary green filter;

图4C是示例性蓝色滤光器的层数、材料和厚度的表;FIG4C is a table of the number of layers, materials, and thicknesses of an exemplary blue filter;

图4D是示例性明视滤光器(photopic filter)的层数、材料和厚度的表;FIG4D is a table of the number of layers, materials, and thicknesses of exemplary photopic filters;

图5A和5B是图4A到4C的示例性红色、绿色和蓝色滤光器的透射光谱的曲线;5A and 5B are graphs of the transmission spectra of the exemplary red, green, and blue filters of FIGS. 4A to 4C ;

图5C是图4D的示例性明视滤光器的在0°到60°的入射角下的透射光谱的曲线;FIG5C is a graph of the transmission spectrum of the exemplary photopic filter of FIG4D at incident angles of 0° to 60°;

图6A是图4A到4C的示例性红色、绿色和蓝色(RGB)滤光器组的和常规的基于染料的RGB滤光器组的色域的曲线;6A is a graph of the color gamut of the exemplary red, green, and blue (RGB) filter set of FIGS. 4A through 4C and a conventional dye-based RGB filter set;

图6B是图4A的示例性红色滤光器的和常规的全电介质红色滤光器的在0°到60°的入射角下的颜色轨迹的曲线;6B is a graph of the color loci of the exemplary red filter of FIG. 4A and a conventional all-dielectric red filter at incident angles of 0° to 60°;

图6C是图4D的示例性明视滤光器的在0°到60°的入射角下的颜色轨迹的曲线;FIG6C is a graph of the color locus of the exemplary photopic filter of FIG4D at incident angles of 0° to 60°;

图7是本发明的传感器设备的第一实施例的横截面的示意图;以及FIG7 is a schematic diagram of a cross-section of a first embodiment of a sensor device of the present invention; and

图8是本发明的传感器设备的第二实施例的横截面的示意图。FIG8 is a schematic diagram of a cross section of a second embodiment of a sensor device of the present invention.

本发明的详细描述Detailed description of the invention

本发明提供了具有被保护的金属层的金属-电介质滤光器,其特别适合于用在传感器设备中。滤光器包括交替地堆叠的多个电介质层和多个金属层。金属层由电介质层内在地保护。特别是,金属层具有由一个或多个电介质层保护性地覆盖的锥形边缘。因此,金属层增加了对环境恶化的抵抗性,导致更耐用的滤光器。The present invention provides a metal-dielectric filter having a protected metal layer, which is particularly suitable for use in sensor devices. The filter comprises a plurality of dielectric layers and a plurality of metal layers stacked alternately. The metal layers are intrinsically protected by the dielectric layers. In particular, the metal layers have tapered edges that are protectively covered by one or more dielectric layers. As a result, the metal layers increase resistance to environmental degradation, resulting in a more durable filter.

在一些实施例中,电介质层和金属层被堆叠,而没有任何中间层。参考图1A,布置在衬底110上的滤光器100的第一实施例包括交替地堆叠的三个电介质层120和两个金属层130。每个金属层130被布置在两个电介质层120之间并相邻于这两个电介质层120,且从而被保护而不受环境影响。In some embodiments, dielectric layers and metal layers are stacked without any intermediate layers. Referring to FIG1A , a first embodiment of an optical filter 100 disposed on a substrate 110 includes three dielectric layers 120 and two metal layers 130 stacked alternately. Each metal layer 130 is disposed between and adjacent to two dielectric layers 120, and is thereby protected from environmental influences.

金属层130具有在滤光器100的周边101处的锥形边缘131。换句话说,金属层130在滤光器100的整个中心部分102的厚度实质上是均匀的,但在滤光器100的周边101处的厚度逐渐变小。同样,电介质层120在滤光器100的整个中心部分102的厚度实质上是均匀的,但在滤光器100的周边101处的厚度逐渐变小。因此,滤光器100的中心部分102在高度上实质上是均匀的,而滤光器100的周边101是倾斜的。换句话说,滤光器100具有实质上平的顶部和倾斜的侧边。The metal layer 130 has a tapered edge 131 at the periphery 101 of the filter 100. In other words, the thickness of the metal layer 130 is substantially uniform throughout the central portion 102 of the filter 100, but tapers off at the periphery 101 of the filter 100. Similarly, the thickness of the dielectric layer 120 is substantially uniform throughout the central portion 102 of the filter 100, but tapers off at the periphery 101 of the filter 100. Thus, the central portion 102 of the filter 100 is substantially uniform in height, while the periphery 101 of the filter 100 is sloped. In other words, the filter 100 has a substantially flat top and sloped sides.

有利地,金属层130的锥形边缘131不暴露于环境。而是,金属层130的锥形边缘131由一个或多个电介质层120覆盖。一个或多个电介质层120例如通过阻止硫和水扩散到金属层130中来抑制金属层130的环境恶化(例如腐蚀)。优选地,金属层130实质上被电介质层120封装。更优选地,金属层130的锥形边缘由相邻的电介质层120保护性地覆盖,且金属层130实质上由相邻的电介质层120封装。Advantageously, the tapered edge 131 of the metal layer 130 is not exposed to the environment. Instead, the tapered edge 131 of the metal layer 130 is covered by one or more dielectric layers 120. The one or more dielectric layers 120 inhibit environmental degradation (e.g., corrosion) of the metal layer 130, for example, by preventing sulfur and water from diffusing into the metal layer 130. Preferably, the metal layer 130 is substantially encapsulated by the dielectric layers 120. More preferably, the tapered edge of the metal layer 130 is protectively covered by the adjacent dielectric layer 120, and the metal layer 130 is substantially encapsulated by the adjacent dielectric layer 120.

参考图1B到1G,滤光器100的第一实施例可通过剥离工艺来制造。具体参考图1B,在第一步骤中,提供衬底110。具体参考图1C,在第二步骤中,光致抗蚀层140被施加到衬底110上。一般地,通过旋涂或喷涂来施加光致抗蚀层140。1B to 1G , a first embodiment of an optical filter 100 can be manufactured using a lift-off process. Specifically referring to FIG. 1B , in a first step, a substrate 110 is provided. Specifically referring to FIG. 1C , in a second step, a photoresist layer 140 is applied to substrate 110. Typically, photoresist layer 140 is applied by spin coating or spray coating.

具体参考图1D,在第三步骤中,光致抗蚀层140被图案化,以暴露衬底110的将布置滤光器100的区域,即,滤光器区。衬底110的其它区域依然由图案化的光致抗蚀层140覆盖。一般地,通过首先借助于掩模使光致抗蚀层140的覆盖衬底110的滤光器区的区域暴露于紫外(UV)光,并接着通过使用适当的显影剂或溶剂来显影(即,蚀刻)光致抗蚀层140的暴露区域,来图案化光致抗蚀层140。With specific reference to FIG1D , in the third step, photoresist layer 140 is patterned to expose the area of substrate 110 where optical filter 100 will be disposed, i.e., the filter region. Other areas of substrate 110 remain covered by patterned photoresist layer 140. Typically, photoresist layer 140 is patterned by first exposing the areas of photoresist layer 140 covering the filter region of substrate 110 to ultraviolet (UV) light using a mask, and then developing (i.e., etching) the exposed areas of photoresist layer 140 using a suitable developer or solvent.

光致抗蚀层140被图案化,使得围绕滤光器区的图案化的光致抗蚀层140而形成悬突部141(即,底切部)。一般地,悬突部141通过例如使用适当的溶剂用化学方法修改光致抗蚀层140的顶部来形成,使得顶部比光致抗蚀层140的底部显影得更慢。可替代地,悬突部141可通过将双层光致抗蚀层140施加到衬底110来形成,双层光致抗蚀层140由更慢地显影的顶层和更快地显影的底层组成。The photoresist layer 140 is patterned so that an overhang 141 (i.e., an undercut portion) is formed around the patterned photoresist layer 140 of the filter region. Typically, the overhang 141 is formed by chemically modifying the top portion of the photoresist layer 140, for example using an appropriate solvent, so that the top portion develops more slowly than the bottom portion of the photoresist layer 140. Alternatively, the overhang 141 can be formed by applying a double-layer photoresist layer 140 to the substrate 110, the double-layer photoresist layer 140 consisting of a slower-developing top layer and a faster-developing bottom layer.

具体参考图1E,在第四步骤中,多层堆叠103被沉积在图案化的光致抗蚀层140和衬底110的滤光器区上。布置在衬底110的滤光器区上的多层堆叠103的一部分形成滤光器100。可通过使用各种沉积技术来沉积相应于滤光器100的层的多层堆叠103的层,这些沉积技术例如是:蒸发(例如热蒸发、电子束蒸发、等离子体辅助蒸发或反应离子蒸发);溅射(例如磁控溅射、反应溅射、交流(AC)溅射、直流(DC)溅射、脉冲DC溅射或离子束溅射);化学气相沉积(例如等离子体增强化学气相沉积);以及原子层沉积。而且,可通过使用不同的沉积技术来沉积不同的层。例如,可通过金属靶的溅射来沉积金属层130,且在存在氧的情况下可通过金属靶的反应溅射来沉积电介质层120。With specific reference to FIG. 1E , in a fourth step, multilayer stack 103 is deposited on patterned photoresist layer 140 and the filter region of substrate 110. The portion of multilayer stack 103 disposed on the filter region of substrate 110 forms optical filter 100. The layers of multilayer stack 103 corresponding to the layers of optical filter 100 can be deposited using various deposition techniques, such as: evaporation (e.g., thermal evaporation, electron beam evaporation, plasma-assisted evaporation, or reactive ion evaporation); sputtering (e.g., magnetron sputtering, reactive sputtering, alternating current (AC) sputtering, direct current (DC) sputtering, pulsed DC sputtering, or ion beam sputtering); chemical vapor deposition (e.g., plasma-enhanced chemical vapor deposition); and atomic layer deposition. Furthermore, different layers can be deposited using different deposition techniques. For example, metal layer 130 can be deposited by sputtering a metal target, and dielectric layer 120 can be deposited by reactive sputtering of a metal target in the presence of oxygen.

因为悬突物141遮蔽衬底110的滤光器区的周边,所沉积的层朝向滤光器100的周边101在厚度上逐渐变小。当电介质层120被沉积在金属层130上时,电介质层120不仅覆盖金属层130的顶表面,而且覆盖金属层130的锥形边缘131,从而保护金属层130不受环境影响。Because the overhang 141 obscures the perimeter of the filter area of the substrate 110, the deposited layers taper in thickness toward the perimeter 101 of the filter 100. When the dielectric layer 120 is deposited on the metal layer 130, the dielectric layer 120 covers not only the top surface of the metal layer 130 but also the tapered edge 131 of the metal layer 130, thereby protecting the metal layer 130 from environmental influences.

具体参考图1F,在第五步骤中,在图案化的光致抗蚀层140上的多层堆叠103的一部分连同光致抗蚀层140一起被移除,即,剥离。一般地,通过使用适当的剥离剂或溶剂来剥离光致抗蚀层140。滤光器100保持在衬底110的滤光器区上。衬底110可例如是常规传感器元件。1F , in a fifth step, a portion of the multilayer stack 103 on the patterned photoresist layer 140 is removed, i.e., stripped, along with the photoresist layer 140. Typically, the photoresist layer 140 is stripped using a suitable stripper or solvent. The optical filter 100 remains on the filter region of the substrate 110. The substrate 110 may be, for example, a conventional sensor element.

应注意,图1B到1F的剥离工艺也可用于在衬底110上同时形成相同类型(即,具有相同的光学设计)的多个滤光器100。而且,剥离工艺可重复,以便其后在同一衬底110上形成不同类型(即,具有不同的光学设计)的一个或多个滤光器。因此,可在衬底110上形成滤光器阵列。衬底110可以例如是常规传感器阵列。It should be noted that the lift-off process of Figures 1B to 1F can also be used to simultaneously form multiple filters 100 of the same type (i.e., having the same optical design) on a substrate 110. Furthermore, the lift-off process can be repeated to subsequently form one or more filters of different types (i.e., having different optical designs) on the same substrate 110. Thus, an array of filters can be formed on the substrate 110. The substrate 110 can be, for example, a conventional sensor array.

参考图1G,在可选的第六步骤中,额外的电介质涂层150被沉积在滤光器100上。可通过使用之前提到的沉积技术之一来沉积电介质涂层150。电介质涂层150覆盖滤光器100的中心部分102和周边101,即,滤光器100的所有暴露的部分,从而保护滤光器100不受环境影响。1G , in an optional sixth step, an additional dielectric coating 150 is deposited on the filter 100. The dielectric coating 150 can be deposited using one of the previously mentioned deposition techniques. The dielectric coating 150 covers the central portion 102 and the periphery 101 of the filter 100, i.e., all exposed portions of the filter 100, thereby protecting the filter 100 from environmental influences.

在其它实施例中,滤光器包括布置在电介质层和金属层之间的多个腐蚀抑制层,其进一步保护金属层。参考图2,布置在衬底210上的滤光器200的第二实施例类似于滤光器100的第一实施例,但还包括插入在三个电介质层220和两个金属层230之间的四个腐蚀抑制层260。In other embodiments, the optical filter includes multiple corrosion-inhibiting layers disposed between the dielectric layer and the metal layer, which further protect the metal layer. Referring to FIG2 , a second embodiment of an optical filter 200 disposed on a substrate 210 is similar to the first embodiment of the optical filter 100 but further includes four corrosion-inhibiting layers 260 interposed between three dielectric layers 220 and two metal layers 230.

金属层230中的每一个被布置在两个腐蚀抑制层260之间且相邻于这两个腐蚀抑制层260,并因而进一步被保护而不受环境影响。腐蚀抑制层260主要在沉积过程期间抑制金属层230的腐蚀。特别是,腐蚀抑制层260保护金属层230的在光路中的部分,阻止金属层230的光学特性的恶化。优选地,金属层230的锥形边缘231被相邻的腐蚀抑制层260保护性地覆盖,并被最接近的电介质层220保护性地覆盖。因此,金属层230优选地实质上被相邻的腐蚀抑制层260以及被最接近的电介质层220封装。Each of the metal layers 230 is disposed between and adjacent to two corrosion-inhibiting layers 260, and is thus further protected from environmental influences. The corrosion-inhibiting layers 260 primarily inhibit corrosion of the metal layers 230 during the deposition process. In particular, the corrosion-inhibiting layers 260 protect the portion of the metal layer 230 that is in the optical path, preventing degradation of the optical properties of the metal layer 230. Preferably, the tapered edge 231 of the metal layer 230 is protectively covered by the adjacent corrosion-inhibiting layers 260 and by the proximate dielectric layer 220. Thus, the metal layer 230 is preferably substantially encapsulated by the adjacent corrosion-inhibiting layers 260 and by the proximate dielectric layer 220.

滤光器200的第二实施例可通过与用于制造滤光器100的第一实施例的剥离工艺类似的剥离工艺制造。然而,在第四步骤中沉积的多层堆叠的层相应于滤光器200的层。特别是,腐蚀抑制层260在每个金属层230之前和之后被沉积。有利地,腐蚀抑制层260在电介质层220的沉积期间抑制金属层230的腐蚀,即,氧化。The second embodiment of the optical filter 200 can be manufactured by a lift-off process similar to the lift-off process used to manufacture the first embodiment of the optical filter 100. However, the layers of the multilayer stack deposited in the fourth step correspond to the layers of the optical filter 200. In particular, the corrosion-inhibiting layer 260 is deposited before and after each metal layer 230. Advantageously, the corrosion-inhibiting layer 260 inhibits corrosion, i.e., oxidation, of the metal layer 230 during the deposition of the dielectric layer 220.

腐蚀抑制层260可通过使用之前提到的沉积技术之一被沉积为金属化合物,例如金属氮化物或金属氧化物层。可替代地,腐蚀抑制层260可通过首先使用之前提到的沉积技术之一沉积适当的金属层、并随后氧化该金属层来形成。优选地,每个腐蚀抑制层260通过首先沉积适当的金属层、氧化该金属层并接着沉积金属氧化物层来形成。例如,腐蚀抑制层260可通过适当金属靶的溅射、接下来是氧化、再接下来是在存在氧的情况下适当金属靶的反应溅射来形成。在美国专利号7,133,197中公开了形成腐蚀抑制层的方法的进一步的细节。The corrosion inhibition layer 260 can be deposited as a metal compound, such as a metal nitride or metal oxide layer, using one of the previously mentioned deposition techniques. Alternatively, the corrosion inhibition layer 260 can be formed by first depositing a suitable metal layer using one of the previously mentioned deposition techniques, and then oxidizing the metal layer. Preferably, each corrosion inhibition layer 260 is formed by first depositing a suitable metal layer, oxidizing the metal layer, and then depositing a metal oxide layer. For example, the corrosion inhibition layer 260 can be formed by sputtering a suitable metal target, followed by oxidation, and then reactive sputtering of the suitable metal target in the presence of oxygen. Further details of the method of forming the corrosion inhibition layer are disclosed in U.S. Patent No. 7,133,197.

本发明的滤光器可具有各种光学设计。此后将更详细地描述示例性滤光器的光学设计。通常,通过为特定的通带选择适当的层数、材料和/或厚度来优化滤光器的光学设计。The optical filter of the present invention can have various optical designs. The optical design of exemplary optical filters will be described in more detail below. In general, the optical design of the filter is optimized by selecting the appropriate number of layers, materials and/or thicknesses for a specific passband.

一般地,滤光器包括2到6个金属层、3到7个电介质层和可选的4到12个腐蚀抑制层。通常,增加金属层的数量提供了具有较陡的边缘但具有较低的带内透射率的通带。Typically, the filter comprises 2 to 6 metal layers, 3 to 7 dielectric layers and optionally 4 to 12 corrosion inhibition layers. In general, increasing the number of metal layers provides a passband with steeper edges but lower in-band transmission.

光学设计中的第一层(即,沉积在衬底上的第一层)可以是金属层或电介质层。光学设计中的最后一层(即,沉积在衬底上的最后一层)通常是电介质层。当第一层是金属层时,滤光器可由以(M/D)n的顺序堆叠的n个金属层(M)和n个电介质层(D)组成,其中n≥2。可替代地,滤光器可由以(C/M/C/D)n的顺序堆叠的n个金属层(M)、n个电介质层(D)和2n个腐蚀抑制层(C)组成,其中n≥2。当第一层是电介质层时,滤光器可由以D(M/D)n的顺序堆叠的n个金属层(M)和n+1个电介质层(D)组成,其中n≥2。可替代地,滤光器可由以D(C/M/C/D)n的顺序堆叠的n个金属层(M)、n+1个电介质层(D)和2n个腐蚀抑制层(C)组成,其中n≥2。The first layer in an optical design (i.e., the first layer deposited on the substrate) can be a metal layer or a dielectric layer. The last layer in an optical design (i.e., the last layer deposited on the substrate) is typically a dielectric layer. When the first layer is a metal layer, the filter can consist of n metal layers (M) and n dielectric layers (D), stacked in the order (M/D)n, where n ≥ 2. Alternatively, the filter can consist of n metal layers (M), n dielectric layers (D), and 2n corrosion-inhibiting layers (C), stacked in the order (C/M/C/D)n, where n ≥ 2. When the first layer is a dielectric layer, the filter can consist of n metal layers (M) and n+1 dielectric layers (D), stacked in the order D(M/D)n, where n ≥ 2. Alternatively, the filter may consist of n metal layers (M), n+1 dielectric layers (D), and 2n corrosion-inhibiting layers (C) stacked in the order D(C/M/C/D)n, where n≥2.

每个金属层由金属或合金组成。一般地,每个金属层由银组成。可替代地,每个金属层可由银合金组成。例如,基本上由大约0.5重量百分比(wt%)的金、大约0.5wt%的锡,以及余量为银(a balance of silver)组成的银合金可提供提高的抗腐蚀性。通常但不是必要地,金属层由相同的金属或合金组成,但具有不同的厚度。一般地,每个金属层具有在大约5nm和大约50nm之间、优选地在大约10nm和大约35nm之间的物理厚度。Each metal layer is composed of a metal or alloy. Typically, each metal layer is composed of silver. Alternatively, each metal layer may be composed of a silver alloy. For example, a silver alloy consisting essentially of approximately 0.5 weight percent (wt%) gold, approximately 0.5 wt% tin, and a balance of silver may provide improved corrosion resistance. Typically, but not necessarily, the metal layers are composed of the same metal or alloy, but have different thicknesses. Typically, each metal layer has a physical thickness between approximately 5 nm and approximately 50 nm, preferably between approximately 10 nm and approximately 35 nm.

每个电介质层由电介质材料组成。一般地,每个电介质层由在可见光光谱区中透明的高折射率电介质材料(即,具有在550nm下大于大约1.65的折射率的电介质材料)组成。高折射率电介质材料的适当例子包括二氧化钛(TiO2)、二氧化锆(ZrO2)、五氧化二铌(Nb2O5)、五氧化钽(Ta2O5)和它们的混合物。优选地,高折射率电介质材料也是UV吸收的,即,在近UV光谱区中吸收。例如,包括TiO2和/或Nb2O5或由TiO2和/或Nb2O5组成的高折射率电介质材料可提供增强的UV阻拦,即,在近UV光谱区中的较低的带外透射率。优选地,高折射率电介质材料具有在550nm下大于大约2.0、更优选地在550nm下大于大约2.35的折射率。较高的折射率通常是合乎需要的。然而,当前可用的透明高折射率电介质材料通常具有在550nm下小于大约2.7的折射率。Each dielectric layer is composed of a dielectric material. Generally, each dielectric layer is composed of a high-refractive-index dielectric material that is transparent in the visible light spectral region (i.e., a dielectric material having a refractive index greater than approximately 1.65 at 550 nm). Suitable examples of high-refractive-index dielectric materials include titanium dioxide ( TiO₂ ), zirconium dioxide ( ZrO₂ ), niobium pentoxide ( Nb₂O₅ ), tantalum pentoxide ( Ta₂O₅ ), and mixtures thereof. Preferably, the high-refractive-index dielectric material is also UV-absorbing, i.e., absorbing in the near-UV spectral region. For example, a high-refractive-index dielectric material comprising or consisting of TiO₂ and /or Nb₂O₅ can provide enhanced UV blocking, i.e., lower out-of-band transmittance in the near-UV spectral region. Preferably, the high-refractive-index dielectric material has a refractive index greater than approximately 2.0 at 550 nm, more preferably greater than approximately 2.35 at 550 nm. A higher refractive index is generally desirable. However, currently available transparent high-refractive-index dielectric materials generally have a refractive index of less than about 2.7 at 550 nm.

通常但不是必要地,电介质层由相同的电介质材料组成,但具有不同的厚度。一般地,每个电介质层具有在大约20nm和大约300nm之间的厚度。这个物理厚度被选择为与光学设计所需要的四分之一波光学厚度(QWOT)相对应。QWOT被定义为4nt,其中n是电介质材料的折射率,而t是物理厚度。一般地,每个电介质层具有在大约200nm和大约2400nm之间的QWOT。Typically, but not necessarily, the dielectric layers are composed of the same dielectric material but have different thicknesses. Typically, each dielectric layer has a thickness between approximately 20 nm and approximately 300 nm. This physical thickness is selected to correspond to the quarter-wave optical thickness (QWOT) required by the optical design. QWOT is defined as 4 nt, where n is the refractive index of the dielectric material and t is the physical thickness. Typically, each dielectric layer has a QWOT between approximately 200 nm and approximately 2400 nm.

每个可选的腐蚀抑制层由腐蚀抑制材料组成。一般地,腐蚀抑制层由腐蚀抑制电介质材料组成。适当的腐蚀抑制电介质材料的例子包括氮化硅(Si3N4)、TiO2、Nb2O5、氧化锌(ZnO)和它们的混合物。优选地,腐蚀抑制电介质材料是具有比金属层的金属或合金更高的伽伐尼电位(galvanic potential)的金属的化合物,例如氮化物或氧化物。Each optional corrosion-inhibiting layer is composed of a corrosion-inhibiting material. Typically, the corrosion-inhibiting layer is composed of a corrosion-inhibiting dielectric material. Examples of suitable corrosion-inhibiting dielectric materials include silicon nitride ( Si3N4 ), TiO2 , Nb2O5 , zinc oxide (ZnO), and mixtures thereof. Preferably, the corrosion-inhibiting dielectric material is a compound of a metal having a higher galvanic potential than the metal or alloy of the metal layer, such as a nitride or oxide.

腐蚀抑制层通常适当地薄,以实质上避免对滤光器的光学设计作出贡献,特别是当它们在可见光光谱区中吸收时。一般地,每个腐蚀抑制层具有在大约0.1nm和大约10nm之间、优选地在大约1nm和大约5nm之间的物理厚度。在美国专利号7,133,197中公开了适当的腐蚀抑制层的进一步的细节。Corrosion inhibition layers are typically suitably thin to avoid substantially contributing to the optical design of the filter, particularly when they absorb in the visible light spectral region. Typically, each corrosion inhibition layer has a physical thickness between about 0.1 nm and about 10 nm, preferably between about 1 nm and about 5 nm. Further details of suitable corrosion inhibition layers are disclosed in U.S. Patent No. 7,133,197.

可选的电介质涂层由电介质材料组成。电介质涂层可由相同的电介质材料组成,并可具有与电介质层同样的厚度。一般地,电介质涂层由与最后一个电介质层相同的电介质材料组成,并具有最后一个电介质层的设计厚度(即,光学设计所需的厚度)的一部分的厚度。换句话说,光学设计的最后一个电介质层在电介质层和电介质涂层之间分摊。例如,如果最后一个电介质层具有设计厚度td,且电介质涂层具有涂层厚度tc,例如250QWOT,则最后一个电介质层的实际厚度ta由ta=td-tc给出。The optional dielectric coating is composed of a dielectric material. The dielectric coating can be composed of the same dielectric material and can have the same thickness as the dielectric layer. Generally, the dielectric coating is composed of the same dielectric material as the last dielectric layer and has a thickness that is a fraction of the design thickness of the last dielectric layer (i.e., the thickness required by the optical design). In other words, the last dielectric layer of the optical design is split between the dielectric layer and the dielectric coating. For example, if the last dielectric layer has a design thickness td and the dielectric coating has a coating thickness tc, e.g., 250 QWOT, then the actual thickness ta of the last dielectric layer is given by ta = td - tc.

参考图3,滤光器300一般具有滤光器高度h(即,滤光器300的中心部分离衬底310的高度),所述高度小于1μm,优选地小于0.6μm。此外一般地,滤光器300具有滤光器宽度w(即,滤光器300的中心部分的宽度),所述宽度小于2μm、优选地小于1μm。有利地,当通过剥离工艺形成多个滤光器300时,相对小的滤光器高度允许较小的滤光器间隔。一般地,滤光器300具有滤光器间隔d(即,在最接近的滤光器300的中心部分之间的间隔),所述间隔小于2μm、优选地小于1μm。Referring to FIG. 3 , the optical filter 300 generally has a filter height h (i.e., the height of the center portion of the optical filter 300 from the substrate 310) that is less than 1 μm, preferably less than 0.6 μm. Furthermore, the optical filter 300 generally has a filter width w (i.e., the width of the center portion of the optical filter 300) that is less than 2 μm, preferably less than 1 μm. Advantageously, when multiple optical filters 300 are formed using a lift-off process, the relatively small filter height allows for smaller filter spacing. The optical filter 300 generally has a filter spacing d (i.e., the spacing between the center portions of the closest optical filters 300) that is less than 2 μm, preferably less than 1 μm.

滤光器是具有高带内透射率和低带外透射率的金属-电介质带通滤光器,即,诱导透射滤光器。一般地,滤光器具有大于大约50%的最大带内透射率,在大约300nm和大约400nm之间,即,在近UV光谱区中具有小于大约2%的平均带外透射率,以及在大约750nm和大约1100nm之间,即,在红外(IR)光谱区中具有小于大约0.3%的平均带外透射率。通常,滤光器还具有低的角偏移,即,在从0°起的入射角变化的情况下的中心波长偏移。一般地,对于中心在600nm处的滤光器,滤光器在60°入射角下具有在幅值上小于大约5%或小于大约30nm的角偏移。The filter is a metallo-dielectric bandpass filter with high in-band transmittance and low out-of-band transmittance, i.e., an induced transmission filter. Typically, the filter has a maximum in-band transmittance greater than approximately 50%, an average out-of-band transmittance less than approximately 2% between approximately 300 nm and approximately 400 nm, i.e., in the near-UV spectral region, and an average out-of-band transmittance less than approximately 0.3% between approximately 750 nm and approximately 1100 nm, i.e., in the infrared (IR) spectral region. Typically, the filter also has low angular shift, i.e., the center wavelength shift with varying angles of incidence from 0°. Typically, for a filter centered at 600 nm, the filter has an angular shift of less than approximately 5% in magnitude, or less than approximately 30 nm, at a 60° angle of incidence.

在一些实施例中,滤光器是具有在可见光光谱区中的相对窄的颜色通带的颜色滤光器。例如,滤光器可以是红色、绿色、蓝色、青色、黄色或紫红色滤光器。在其它实施例中,滤光器是明视滤光器(photopic filter),其具有在可见光光谱区中的明视通带,即,模拟人眼对相对亮的光的光谱响应的通带。又在一些其它实施例中,滤光器是在可见光光谱区中具有相对宽的通带的IR阻拦滤光器。In some embodiments, the optical filter is a color filter having a relatively narrow color passband in the visible light spectral region. For example, the filter can be a red, green, blue, cyan, yellow, or magenta filter. In other embodiments, the optical filter is a photopic filter having a photopic passband in the visible light spectral region, i.e., a passband that simulates the spectral response of the human eye to relatively bright light. In still other embodiments, the optical filter is an IR blocking filter having a relatively wide passband in the visible light spectral region.

示例性红色、绿色和蓝色滤光器,即,示例性RGB滤光器组的光学设计(即,层数、材料和厚度)分别在图4A、4B和4C中被制成表。示例性明视滤光器的光学设计在图4D中被制成表。每种光学设计的层从沉积在衬底上的第一层起被编号。The optical designs (i.e., number of layers, materials, and thicknesses) of exemplary red, green, and blue filters, i.e., exemplary RGB filter sets, are tabulated in Figures 4A, 4B, and 4C, respectively. The optical design of an exemplary photopic filter is tabulated in Figure 4D. The layers of each optical design are numbered starting with the first layer deposited on the substrate.

每个金属层由银组成,并具有在大约13nm和大约34nm之间的物理厚度。每个电介质层由高折射率电介质材料(H)组成,并具有在大约240nm和大约2090nm之间的QWOT。例如,高折射率电介质材料可以是在550nm下具有大约2.43的折射率的Nb2O5和TiO2的混合物。每个腐蚀抑制层由ZnO组成,且每层具有大约2nm的物理厚度。Each metal layer is composed of silver and has a physical thickness between approximately 13 nm and approximately 34 nm. Each dielectric layer is composed of a high-refractive-index dielectric material (H) and has a QWOT between approximately 240 nm and approximately 2090 nm. For example, the high-refractive-index dielectric material may be a mixture of Nb2O5 and TiO2 having a refractive index of approximately 2.43 at 550 nm. Each corrosion-inhibiting layer is composed of ZnO and has a physical thickness of approximately 2 nm.

当高折射率电介质材料在550nm下具有大约2.43的折射率时,红色滤光器的滤光器高度为606nm,绿色滤光器的滤光器高度为531nm,蓝色滤光器的滤光器高度为252nm,以及明视滤光器的滤光器高度为522nm。这些滤光器的高度明显小于常规全电介质滤光器的滤光器高度。When the high-refractive-index dielectric material has a refractive index of approximately 2.43 at 550 nm, the filter height of the red filter is 606 nm, the filter height of the green filter is 531 nm, the filter height of the blue filter is 252 nm, and the filter height of the photopic filter is 522 nm. These filter heights are significantly smaller than those of conventional all-dielectric filters.

在图5A和5B中绘制出示例性红色、绿色和蓝色滤光器的透射光谱570、571和572。示例性红色滤光器的透射光谱570包括中心在大约620nm处的红色通带,示例性绿色滤光器的透射光谱571包括中心在大约530nm处的绿色通带,以及示例性蓝色滤光器的透射光谱572包括中心在大约445nm处的蓝色通带。5A and 5B , the transmission spectra 570, 571, and 572 of exemplary red, green, and blue filters are plotted. The transmission spectrum 570 of the exemplary red filter includes a red passband centered at approximately 620 nm, the transmission spectrum 571 of the exemplary green filter includes a green passband centered at approximately 530 nm, and the transmission spectrum 572 of the exemplary blue filter includes a blue passband centered at approximately 445 nm.

在图5C中绘制出在0°到60°的入射角下的示例性明视滤光器的透射光谱573和574。在0°入射角下的示例性明视滤光器的透射光谱573包括中心在大约555nm处的明视通带。在60°入射角下的示例性明视滤光器的透射光谱574中,明视通带中心在大约520nm处。换句话说,在60°入射角下的示例性明视滤光器的角偏移为大约-25nm。FIG5C shows transmission spectra 573 and 574 of an exemplary photopic filter at angles of incidence ranging from 0° to 60°. Transmission spectrum 573 of the exemplary photopic filter at an angle of incidence of 0° includes a photopic passband centered at approximately 555 nm. Transmission spectrum 574 of the exemplary photopic filter at an angle of incidence of 60° includes a photopic passband centered at approximately 520 nm. In other words, the angular offset of the exemplary photopic filter at an angle of incidence of 60° is approximately −25 nm.

每个示例性滤光器具有大于大约60%的最大带内透射率。有利地,示例性滤光器提供相对于常规基于染料滤光器和全电介质滤光器的提高的IR阻拦,减少了由IR泄漏引起的噪声。具体地,每个示例性滤光器具有在大约750nm和大约1100nm之间(即,在IR光谱区中)的小于大约0.3%的平均带外透射率。示例性滤光器,特别是示例性红色滤光器还提供相对于一些常规金属-电介质颜色滤光器提高的UV阻拦,减少了由UV泄漏引起的噪声。具体地,每个示例性滤光器具有在大约300nm和大约400nm之间(即,在近UV光谱区中)的小于大约2%的平均带外透射率。Each exemplary filter has a maximum in-band transmittance greater than approximately 60%. Advantageously, the exemplary filters provide improved IR rejection relative to conventional dye-based and all-dielectric filters, reducing noise caused by IR leakage. Specifically, each exemplary filter has an average out-of-band transmittance of less than approximately 0.3% between approximately 750 nm and approximately 1100 nm (i.e., in the IR spectral region). The exemplary filters, particularly the exemplary red filter, also provide improved UV rejection relative to some conventional metal-dielectric color filters, reducing noise caused by UV leakage. Specifically, each exemplary filter has an average out-of-band transmittance of less than approximately 2% between approximately 300 nm and approximately 400 nm (i.e., in the near-UV spectral region).

示例性RGB滤光器组的色域680连同常规的基于染料的RGB滤光器组的色域681一起绘制在图6A中的CIE xy色度图中,用于比较。有利地,示例性RGB滤光器组的色域680明显大于常规的基于染料的RGB滤光器组的色域681。The color gamut 680 of the exemplary RGB filter set is plotted in the CIE xy chromaticity diagram in FIG6A for comparison, along with the color gamut 681 of a conventional dye-based RGB filter set. Advantageously, the color gamut 680 of the exemplary RGB filter set is significantly larger than the color gamut 681 of the conventional dye-based RGB filter set.

在0°到60°的入射角下的示例性红色滤光器的颜色轨迹682连同在0°到60°的入射角下的常规的全电介质红色滤波片的颜色轨迹683一起绘制在图6B中的CIE xy色度图中。在0°到60°的入射角下的示例性明视滤光器的颜色轨迹684绘制在图6C中的CIE xy色度图中。有利地,示例性滤光器的角偏移明显小于常规的全电介质滤光器的角偏移。The color locus 682 of the exemplary red filter at an incident angle of 0° to 60° is plotted in the CIE xy chromaticity diagram in FIG6B , along with the color locus 683 of a conventional all-dielectric red filter at an incident angle of 0° to 60°. The color locus 684 of the exemplary photopic filter at an incident angle of 0° to 60° is plotted in the CIE xy chromaticity diagram in FIG6C . Advantageously, the angular offset of the exemplary filter is significantly less than that of a conventional all-dielectric filter.

本发明的滤光器当被包括为传感器设备的一部分时特别有用。所述传感器设备可以是除了包括本发明的一个或多个滤光器以外还包括一个或多个传感器元件的任何类型的传感器设备。例如,所述传感器设备可以是环境光传感器、接近度传感器或图像传感器。一个或多个传感器元件可以是任何类型的常规传感器元件。一般地,所述一个或多个传感器元件是光电传感器,例如光电二极管、电荷耦合器件(CCD)传感器元件或互补金属氧化物半导体(CMOS)传感器元件。所述一个或多个传感器元件可以是正面或背面照明的。The optical filters of the present invention are particularly useful when included as part of a sensor device. The sensor device can be any type of sensor device that, in addition to including one or more optical filters of the present invention, also includes one or more sensor elements. For example, the sensor device can be an ambient light sensor, a proximity sensor, or an image sensor. The one or more sensor elements can be any type of conventional sensor element. Typically, the one or more sensor elements are photosensors, such as photodiodes, charge-coupled device (CCD) sensor elements, or complementary metal oxide semiconductor (CMOS) sensor elements. The one or more sensor elements can be front- or back-illuminated.

所述一个或多个滤光器被布置在一个或多个传感器元件上,使得一个或多个滤光器过滤被提供到一个或多个传感器元件的光。一般地,每个滤光器被布置在一个传感器元件上。换句话说,传感器设备的每个象素一般包括一个波光器和一个传感器元件。优选地,所述一个或多个滤光器被直接布置在一个或多个传感器元件上。例如,所述一个或多个滤光器可通过剥离工艺在一个或多个传感器元件上形成。然而,在一些实例中,可以有布置在一个或多个滤光器和一个或多个传感器元件之间的一个或多个涂层。The one or more optical filters are arranged on the one or more sensor elements so that the one or more optical filters filter the light provided to the one or more sensor elements. Generally, each optical filter is arranged on one sensor element. In other words, each pixel of the sensor device generally includes a filter and a sensor element. Preferably, the one or more optical filters are arranged directly on the one or more sensor elements. For example, the one or more optical filters can be formed on the one or more sensor elements by a lift-off process. However, in some instances, there may be one or more coatings arranged between the one or more optical filters and the one or more sensor elements.

在一些实施例中,传感器设备包括单个传感器元件和布置在传感器元件上的单个滤光器。参考图7,传感器设备790的第一实施例包括传感器元件711和布置在传感器元件711上的滤光器700。例如,传感器设备790可以是环境光传感器,传感器711可以是光电二极管,且滤光器700可以是明视滤光器,例如图4D的示例性明视滤光器或IR阻拦滤光器。In some embodiments, the sensor device includes a single sensor element and a single optical filter disposed on the sensor element. Referring to FIG7 , a first embodiment of a sensor device 790 includes a sensor element 711 and an optical filter 700 disposed on the sensor element 711. For example, the sensor device 790 can be an ambient light sensor, the sensor 711 can be a photodiode, and the optical filter 700 can be a photopic filter, such as the exemplary photopic filter of FIG4D , or an IR blocking filter.

在其它实施例中,传感器设备包括多个传感器元件和布置在多个传感器元件上的多个滤光器。一般地,传感器元件被布置成阵列。换句话说,传感器元件形成传感器阵列,例如光电二极管阵列、CCD阵列、CMOS阵列或任何其它类型的常规传感器阵列。此外一般地,滤光器被布置成阵列。换句话说,滤光器形成滤光器阵列,例如颜色滤光器阵列(CFA)。优选地,传感器阵列和滤光器阵列是相应的二维阵列,即,镶嵌图案(mosaics)。例如,阵列可以是具有行和列的矩形阵列。In other embodiments, the sensor device includes a plurality of sensor elements and a plurality of filters arranged on the plurality of sensor elements. Generally, the sensor elements are arranged in an array. In other words, the sensor elements form a sensor array, such as a photodiode array, a CCD array, a CMOS array, or any other type of conventional sensor array. Furthermore, generally, the filters are arranged in an array. In other words, the filters form a filter array, such as a color filter array (CFA). Preferably, the sensor array and the filter array are corresponding two-dimensional arrays, i.e., mosaics. For example, the array can be a rectangular array having rows and columns.

通常,这些滤光器实质上彼此分离。换句话说,滤光器的周边通常彼此不接触。然而,在一些实例中,滤光器的电介质层可能无意地接触,而金属层特别是锥形边缘保持彼此分离。Typically, these filters are substantially separated from each other. In other words, the perimeters of the filters generally do not touch each other. However, in some instances, the dielectric layers of the filters may inadvertently touch while the metal layers, particularly the tapered edges, remain separated from each other.

一般地,多个滤光器包括具有彼此不同的通带的不同类型的滤光器。例如,多个滤光器可包括颜色滤光器,例如红色、绿色、蓝色、青色、黄色和/或紫红色滤光器、明视滤光器、IR阻拦滤光器或其组合。在一些实施例中,多个滤光器包括形成CFA的不同类型的颜色滤光器。例如,多个滤光器可包括形成RGB滤光器阵列(例如Bayer滤光器阵列)的红色、绿色和蓝色滤光器,例如图4A到4C的示例性红色、绿色和蓝色滤光器。Generally, the plurality of filters includes different types of filters having different passbands. For example, the plurality of filters may include color filters, such as red, green, blue, cyan, yellow, and/or magenta filters, photopic filters, IR-blocking filters, or combinations thereof. In some embodiments, the plurality of filters includes different types of color filters forming a CFA. For example, the plurality of filters may include red, green, and blue filters forming an RGB filter array (e.g., a Bayer filter array), such as the exemplary red, green, and blue filters of Figures 4A to 4C.

有利地,不同类型的滤光器可具有彼此不同数量的金属层和/或不同厚度的金属层。在一些实施例中,不同类型的滤光器中的至少两个包括彼此不同数量的金属层。在同一或其它实施例中,不同类型的滤光器中的至少两个具有彼此不同的金属层厚度。例如,图4C的示例性蓝色滤光器与图4A和4B的示例性红色和绿色滤光器具有不同数量的金属层。而且,图4A到4C的所有示例性红色、绿色和蓝色滤光器具有彼此不同的金属层厚度。Advantageously, different types of filters can have different numbers of metal layers and/or different thicknesses of metal layers. In some embodiments, at least two of the different types of filters include different numbers of metal layers. In the same or other embodiments, at least two of the different types of filters have different metal layer thicknesses. For example, the exemplary blue filter of FIG. 4C has a different number of metal layers than the exemplary red and green filters of FIG. 4A and 4B. Furthermore, all of the exemplary red, green, and blue filters of FIG. 4A through 4C have different metal layer thicknesses.

参考图8,传感器设备890的第二实施例包括多个传感器元件811和布置在多个传感器元件811上的多个滤光器800和804。多个滤光器800和804包括具有第一通带的第一类型的滤光器800和具有与第一通带不同的第二通带的第二类型的滤光器804。例如,传感器设备890可以是图像传感器,多个传感器元件811可形成CCD阵列,且多个滤光器800和804可形成Bayer滤光器阵列,图中只示出其中一行的一部分。第一类型的滤光器800可以是绿色滤光器,例如示例性图4B的示例性绿色滤光器,而第二类型的滤光器804可以是蓝色滤光器,例如示例性图4C的示例性蓝色滤光器。8 , a second embodiment of a sensor device 890 includes a plurality of sensor elements 811 and a plurality of optical filters 800 and 804 arranged on the plurality of sensor elements 811. The plurality of optical filters 800 and 804 include a first type of optical filter 800 having a first passband and a second type of optical filter 804 having a second passband different from the first passband. For example, the sensor device 890 may be an image sensor, the plurality of sensor elements 811 may form a CCD array, and the plurality of optical filters 800 and 804 may form a Bayer filter array, of which only a portion of a row is shown. The first type of optical filter 800 may be a green filter, such as the exemplary green filter of exemplary FIG. 4B , and the second type of optical filter 804 may be a blue filter, such as the exemplary blue filter of exemplary FIG. 4C .

当然,可设想很多其它实施例而不偏离本发明的精神和范围。Of course, numerous other embodiments can be envisaged without departing from the spirit and scope of the invention.

Claims (20)

1.一种传感器设备,包括:1. A sensor device, comprising: 一个或多个传感器元件;以及One or more sensor elements; and 一个或多个滤光器,所述一个或多个滤光器被布置在所述一个或多个传感器元件上,其中所述一个或多个滤光器中的每一个包括:One or more filters, said one or more filters being disposed on said one or more sensor elements, wherein each of said one or more filters includes: 多个电介质层;以及Multiple dielectric layers; and 与所述多个电介质层交替地堆叠的多个金属层,其中Multiple metal layers stacked alternately with the plurality of dielectric layers, wherein 所述多个金属层中的每一个在所述滤光器的周边处具有由所述多个电介质层中的一个或多个实质上封装的锥形边缘,Each of the plurality of metal layers has a tapered edge at the periphery of the filter, which is substantially encapsulated by one or more of the plurality of dielectric layers. 使用所述多个电介质层中的至少一个将所述多个金属层中的每一个与所述一个或多个滤光器中的滤光器的衬底分离,并且Each of the plurality of metal layers is separated from the substrate of the filter in the one or more filters using at least one of the plurality of dielectric layers, and 所述多个金属层中的每一个具有在5nm和50nm之间的物理厚度,并且所述多个电介质层中的每一个具有在20nm和300nm之间的厚度。Each of the plurality of metal layers has a physical thickness between 5 nm and 50 nm, and each of the plurality of dielectric layers has a thickness between 20 nm and 300 nm. 2.如权利要求1所述的传感器设备,其中所述一个或多个滤光器被直接布置在所述一个或多个传感器元件上。2. The sensor device of claim 1, wherein the one or more filters are disposed directly on the one or more sensor elements. 3.如权利要求2所述的传感器设备,其中所述一个或多个滤光器通过剥离工艺在所述一个或多个传感器元件上形成。3. The sensor device of claim 2, wherein the one or more filters are formed on the one or more sensor elements by a stripping process. 4.如权利要求1所述的传感器设备,其中所述一个或多个滤光器具有实质上平的顶部和倾斜的侧部。4. The sensor device of claim 1, wherein the one or more filters have a substantially flat top and sloping sides. 5.如权利要求1所述的传感器设备,其中所述多个金属层中的每一个实质上被所述多个电介质层中的两个最接近的电介质层封装。5. The sensor device of claim 1, wherein each of the plurality of metal layers is substantially encapsulated by the two closest dielectric layers of the plurality of dielectric layers. 6.如权利要求1所述的传感器设备,其中所述多个金属层中的每一个由银组成。6. The sensor device of claim 1, wherein each of the plurality of metal layers is composed of silver. 7.如权利要求1所述的传感器设备,其中所述多个电介质层中的每一个由在550nm下具有大于2.0的折射率的高折射率电介质材料组成。7. The sensor device of claim 1, wherein each of the plurality of dielectric layers is composed of a high refractive index dielectric material having a refractive index greater than 2.0 at 550 nm. 8.如权利要求7所述的传感器设备,其中所述高折射率电介质材料是紫外吸收的,并且其中所述一个或多个滤光器中的每一个具有在300nm和400nm之间的小于2%的平均带外透射率。8. The sensor device of claim 7, wherein the high refractive index dielectric material is ultraviolet absorbing, and wherein each of the one or more filters has an average out-of-band transmittance of less than 2% between 300 nm and 400 nm. 9.如权利要求1所述的传感器设备,其中所述多个电介质层中的每一个由二氧化钛、二氧化锆、五氧化二铌、五氧化钽或它们的混合物组成。9. The sensor device of claim 1, wherein each of the plurality of dielectric layers is composed of titanium dioxide, zirconium dioxide, niobium pentoxide, tantalum pentoxide, or mixtures thereof. 10.如权利要求1所述的传感器设备,其中所述一个或多个滤光器中的每一个还包括布置在所述多个电介质层和所述多个金属层之间的多个腐蚀抑制层。10. The sensor device of claim 1, wherein each of the one or more filters further comprises a plurality of corrosion-inhibiting layers disposed between the plurality of dielectric layers and the plurality of metal layers. 11.如权利要求10所述的传感器设备,其中所述电介质层D、所述多个腐蚀抑制层C和所述多个金属层M以D(C/M/C/D)n的顺序堆叠,且其中n≥2。11. The sensor device of claim 10, wherein the dielectric layer D, the plurality of corrosion inhibition layers C and the plurality of metal layers M are stacked in the order D(C/M/C/D) n , and wherein n≥2. 12.如权利要求10所述的传感器设备,其中所述多个腐蚀抑制层中的每一个由ZnO组成。12. The sensor device of claim 10, wherein each of the plurality of corrosion inhibition layers is composed of ZnO. 13.如权利要求1所述的传感器设备,还包括保护性地覆盖所述一个或多个滤光器的电介质涂层。13. The sensor device of claim 1, further comprising a dielectric coating that protectively covers the one or more filters. 14.如权利要求1所述的传感器设备,其中所述一个或多个滤光器是一个或多个颜色滤光器、明视滤光器、红外阻拦滤光器或它们的组合。14. The sensor device of claim 1, wherein the one or more filters are one or more color filters, photosensitive filters, infrared blocking filters, or combinations thereof. 15.如权利要求1所述的传感器设备,其中所述一个或多个传感器元件由多个传感器元件组成,且其中所述一个或多个滤光器由多个滤光器组成。15. The sensor device of claim 1, wherein the one or more sensor elements are composed of a plurality of sensor elements, and wherein the one or more filters are composed of a plurality of filters. 16.如权利要求15所述的传感器设备,其中所述一个或多个传感器元件被布置成二维阵列,且其中所述多个滤光器被布置成相应的二维阵列。16. The sensor device of claim 15, wherein the one or more sensor elements are arranged in a two-dimensional array, and wherein the plurality of filters are arranged in a corresponding two-dimensional array. 17.如权利要求15所述的传感器设备,其中所述多个滤光器实质上彼此分离。17. The sensor device of claim 15, wherein the plurality of filters are substantially separate from each other. 18.如权利要求15所述的传感器设备,其中所述多个滤光器包括不同类型的滤光器,所述不同类型的滤光器具有彼此不同的通带。18. The sensor device of claim 15, wherein the plurality of filters comprises different types of filters having different passbands. 19.如权利要求18所述的传感器设备,其中所述不同类型的滤光器中的至少两个包括彼此不同数量的金属层。19. The sensor device of claim 18, wherein at least two of the different types of filters comprise different numbers of metal layers. 20.如权利要求18所述的传感器设备,其中所述不同类型的滤光器中的至少两个具有彼此不同的金属层厚度。20. The sensor device of claim 18, wherein at least two of the different types of filters have metal layer thicknesses that differ from each other.
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