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HK1072279A1 - Corona-generated chemical vapor deposition on a substrate - Google Patents

Corona-generated chemical vapor deposition on a substrate Download PDF

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Publication number
HK1072279A1
HK1072279A1 HK05103485.1A HK05103485A HK1072279A1 HK 1072279 A1 HK1072279 A1 HK 1072279A1 HK 05103485 A HK05103485 A HK 05103485A HK 1072279 A1 HK1072279 A1 HK 1072279A1
Authority
HK
Hong Kong
Prior art keywords
substrate
gas
electrode
coating
corona discharge
Prior art date
Application number
HK05103485.1A
Other languages
English (en)
French (fr)
Chinese (zh)
Other versions
HK1072279B (en
Inventor
Aaron M. Gabelnick
Richard T. Fox
Ing-Feng Hu
Dmitry P. Dinega
Original Assignee
Dow Global Technologies Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc. filed Critical Dow Global Technologies Inc.
Publication of HK1072279A1 publication Critical patent/HK1072279A1/en
Publication of HK1072279B publication Critical patent/HK1072279B/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/455Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
    • C23C16/45563Gas nozzles
    • C23C16/45565Shower nozzles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/62Plasma-deposition of organic layers
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/40Oxides
    • C23C16/401Oxides containing silicon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/50Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges
    • C23C16/503Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges using DC or AC discharges
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/50Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges
    • C23C16/505Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges using radio frequency discharges
    • C23C16/509Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges using radio frequency discharges using internal electrodes
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/54Apparatus specially adapted for continuous coating

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Vapour Deposition (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Organic Insulating Materials (AREA)
  • Fixed Capacitors And Capacitor Manufacturing Machines (AREA)
  • Surface Treatment Of Optical Elements (AREA)
  • Manufacturing Of Printed Wiring (AREA)
  • Polymerisation Methods In General (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)

Claims (7)

  1. Kontinuierlicher Prozess zum Erstellen einer optisch durchsichtigen Beschichtung auf einem sich bewegenden Substrat, folgende Schritte umfassend: 1) Erzeugen einer Korona-Entladung in einem Bereich zwischen a) einer Elektrode, die mindestens einen Einlass und mindestens einen Auslass hat, und b) einer Gegenelektrode, die ein sich bewegendes Substrat trägt; und 2) Strömenlassen einer Mischung aus einem Balance-Gas, einem Arbeits-Gas, das ein Organosiloxan ist, und optional einem Trägergas für das Arbeitsgas durch die Elektrode und die Korona-Entladung, um eine im Plasma polymerisierende Beschichtung auf dem Substrat zu bilden, wobei das Balance-Gas eine Flussrate hat, so dass die Geschwindigkeit durch den mindestens einen Auslass nicht kleiner als 10 m/s und nicht größer als 200 m/s ist, wobei die Konzentration des Arbeitsgases auf der Basis der Gesamt-Gasmischung nicht kleiner als 5 ppm und nicht größer als 200 ppm ist, wobei die optisch durchsichtige Beschichtung eine optische Reinheit von mindestens 98 Prozent und eine Opazität von nicht mehr als 2 Prozent hat.
  2. Prozess aus Anspruch 1, wobei die Gegenelektrode eine rotierende Trommel ist, und wobei entweder die Trommel oder die Elektrode oder sowohl die Trommel, als auch die Elektrode mit einer dielektrischen Hülse ausgerüstet sind.
  3. Prozess aus einem der Ansprüche 1 bis 2, wobei das Balance-Gas Luft, Sauerstoff, Stickstoff, Helium, Argon oder eine Kombination daraus ist.
  4. Prozess aus einem der Ansprüche 1 bis 3, wobei der mindestens eine Auslass der Elektrode eine Vielzahl von Löchern oder Schlitzen ist, und wobei das Arbeitsgas Tetramethyldisiloxan, Hexamethyldisiloxan, Octamethyltrisiloxan, Tetraethylorthosilikat oder Kombinationen daraus ist.
  5. Prozess aus Anspruch 4, wobei das Substrat nach der Abscheidung der im Plasma polymerisierenden Beschichtung im Vergleich zu einem unbehandelten Substrat eine erhöhte Oberflächenenergie hat.
  6. Prozess aus Anspruch 4, wobei die Ablagerung eine Beschichtung bildet, die das Substrat chemisch widerstandsfähig macht.
  7. Prozess aus Anspruch 4, wobei die Ablagerung eine Beschichtung mit einer im Vergleich zu einem unbehandelten Substrat erhöhten Barriere für Gase ausbildet.
HK05103485.1A 2002-02-05 2003-02-03 Corona-generated chemical vapor deposition on a substrate HK1072279B (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US35490502P 2002-02-05 2002-02-05
US354905P 2002-02-05
US40864002P 2002-09-06 2002-09-06
US408640P 2002-09-06
PCT/US2003/003057 WO2003066932A1 (en) 2002-02-05 2003-02-03 Corona-generated chemical vapor deposition on a substrate

Publications (2)

Publication Number Publication Date
HK1072279A1 true HK1072279A1 (en) 2005-08-19
HK1072279B HK1072279B (en) 2009-04-09

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Also Published As

Publication number Publication date
JP2005533174A (ja) 2005-11-04
CN1628187A (zh) 2005-06-15
DE60322347D1 (de) 2008-09-04
US20040091637A1 (en) 2004-05-13
EP1472387A1 (de) 2004-11-03
US6815014B2 (en) 2004-11-09
EP1472387B1 (de) 2008-07-23
CN100432289C (zh) 2008-11-12
WO2003066932A1 (en) 2003-08-14
ATE402277T1 (de) 2008-08-15
JP4494792B2 (ja) 2010-06-30
AU2003207794A1 (en) 2003-09-02

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Legal Events

Date Code Title Description
PC Patent ceased (i.e. patent has lapsed due to the failure to pay the renewal fee)

Effective date: 20130203