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GR1006835B - Synthetic method for 5-(difluoromethoxy)-2-[[(3,4-dimethoxy-2-pyridinyl)methyl]sulfinyl]-1h-benzimidazole and the sesquihydrate of the sodium salt thereof in crystalline form and the application of apharmaceutical formulation thereof. - Google Patents

Synthetic method for 5-(difluoromethoxy)-2-[[(3,4-dimethoxy-2-pyridinyl)methyl]sulfinyl]-1h-benzimidazole and the sesquihydrate of the sodium salt thereof in crystalline form and the application of apharmaceutical formulation thereof.

Info

Publication number
GR1006835B
GR1006835B GR20090100396A GR20090100396A GR1006835B GR 1006835 B GR1006835 B GR 1006835B GR 20090100396 A GR20090100396 A GR 20090100396A GR 20090100396 A GR20090100396 A GR 20090100396A GR 1006835 B GR1006835 B GR 1006835B
Authority
GR
Greece
Prior art keywords
pantoprazole
sesquihydrate
sodium salt
sodium
application
Prior art date
Application number
GR20090100396A
Other languages
Greek (el)
Inventor
Γεωργιος Φαμπιος
Original Assignee
Ανωνυμος Φαρμακευτικη-Χημικη Βιομηχανια Medichrom Α.Ε.,
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ανωνυμος Φαρμακευτικη-Χημικη Βιομηχανια Medichrom Α.Ε., filed Critical Ανωνυμος Φαρμακευτικη-Χημικη Βιομηχανια Medichrom Α.Ε.,
Priority to GR20090100396A priority Critical patent/GR1006835B/en
Publication of GR1006835B publication Critical patent/GR1006835B/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

The present invention relates to the gastric acid secretion inhibitor, pantoprazole, in solid state and in particular in the crystalline form of the sodium salt of pantoprazole, and the application of a medicinal formulation thereof.The present invention provides a procedure comprising mixing of a thioether, about 1.0 equivalent of an active chloro-containing oxidizing agent, preferably calcium hypochlorite, and about 4.5 equivalents of an alkali metal base, to obtain the sulfoxide – pantoprazole. The procedure further comprises the contact of the sulfoxide with a sodium ion source, preferably sodium hydroxide, to provide the sodium salt of the sulfoxide.The invention also provides the use of pantoprazole sodium sesquihydrate for the preparation of a medicinal formulation, in the form of tablets coated with an enteric film, which reduces the gastric acid secretion.Thus, the invention provides a new procedure for the preparation of crystalline forms of pantoprazole sodium sesquihydrate.
GR20090100396A 2009-07-15 2009-07-15 Synthetic method for 5-(difluoromethoxy)-2-[[(3,4-dimethoxy-2-pyridinyl)methyl]sulfinyl]-1h-benzimidazole and the sesquihydrate of the sodium salt thereof in crystalline form and the application of apharmaceutical formulation thereof. GR1006835B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GR20090100396A GR1006835B (en) 2009-07-15 2009-07-15 Synthetic method for 5-(difluoromethoxy)-2-[[(3,4-dimethoxy-2-pyridinyl)methyl]sulfinyl]-1h-benzimidazole and the sesquihydrate of the sodium salt thereof in crystalline form and the application of apharmaceutical formulation thereof.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GR20090100396A GR1006835B (en) 2009-07-15 2009-07-15 Synthetic method for 5-(difluoromethoxy)-2-[[(3,4-dimethoxy-2-pyridinyl)methyl]sulfinyl]-1h-benzimidazole and the sesquihydrate of the sodium salt thereof in crystalline form and the application of apharmaceutical formulation thereof.

Publications (1)

Publication Number Publication Date
GR1006835B true GR1006835B (en) 2010-07-05

Family

ID=41716640

Family Applications (1)

Application Number Title Priority Date Filing Date
GR20090100396A GR1006835B (en) 2009-07-15 2009-07-15 Synthetic method for 5-(difluoromethoxy)-2-[[(3,4-dimethoxy-2-pyridinyl)methyl]sulfinyl]-1h-benzimidazole and the sesquihydrate of the sodium salt thereof in crystalline form and the application of apharmaceutical formulation thereof.

Country Status (1)

Country Link
GR (1) GR1006835B (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004111029A2 (en) * 2003-06-10 2004-12-23 Teva Pharmaceutical Industries Ltd. Process for preparing 2-[(pyridinyl)methyl]sulfinyl-substituted benzimidazoles and novel chlorinated derivatives of pantoprazole
WO2008045777A2 (en) * 2006-10-06 2008-04-17 Dr. Reddy's Labortories, Ltd. A process for the preparation of benzimidazole derivatives and their salts

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004111029A2 (en) * 2003-06-10 2004-12-23 Teva Pharmaceutical Industries Ltd. Process for preparing 2-[(pyridinyl)methyl]sulfinyl-substituted benzimidazoles and novel chlorinated derivatives of pantoprazole
WO2008045777A2 (en) * 2006-10-06 2008-04-17 Dr. Reddy's Labortories, Ltd. A process for the preparation of benzimidazole derivatives and their salts

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