GR1003235B - Διεργασια παραγωγης υδρογονου και ηλεκτρικης ενεργειας απο αναμορφωση βιο-αιθανολης, με χρηση κυψελιδων καυσιμου και με μηδενικη εκπομπη ρυπων - Google Patents
Διεργασια παραγωγης υδρογονου και ηλεκτρικης ενεργειας απο αναμορφωση βιο-αιθανολης, με χρηση κυψελιδων καυσιμου και με μηδενικη εκπομπη ρυπωνInfo
- Publication number
- GR1003235B GR1003235B GR980100180A GR980100180A GR1003235B GR 1003235 B GR1003235 B GR 1003235B GR 980100180 A GR980100180 A GR 980100180A GR 980100180 A GR980100180 A GR 980100180A GR 1003235 B GR1003235 B GR 1003235B
- Authority
- GR
- Greece
- Prior art keywords
- ethanol
- hydrogen
- mixture
- reactor
- bio
- Prior art date
Links
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
- H01M8/0625—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material in a modular combined reactor/fuel cell structure
- H01M8/0631—Reactor construction specially adapted for combination reactor/fuel cell
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
- H01M8/0643—Gasification of solid fuel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Organic Chemistry (AREA)
- Sustainable Energy (AREA)
- Manufacturing & Machinery (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Fuel Cell (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Catalysts (AREA)
Abstract
Μια διεργασία παραγωγής υδρογόνου και ηλεκτρικής ενέργειας, με μηδενική εκπομπή ρύπων, από αιθανόλη παραγόμενη από βιομάζα, που χαρακτηρίζεται από την μερική οξείδωση/αναμόρφωση της αιθανόλης με νερό για παραγωγή υδρογόνου το οποίο στη συνέχεια παρέχεται σε κυψελίδα καυσίμου για παραγωγή ηλεκτρικής ενέργειας, ειδικότερα όπου υδατικό διάλυμα αιθανόλης που προέρχεται από ζύμωση βιομάζας διαχωρίζεται με απόσταξη ή οποιαδήποτε άλλη τεχνική έτσι ώστε να περιέχει περίπου 40-70 % κατά βάρος αιθανόλη, κατά προτίμηση 50-60 %, το μίγμα αυτό, αναμιγνυόμενο με κατάλληλη ποσότητα αέρα, έτσι ώστε ο λόγος mol οξυγόνου προς αιθανόλη να είναι από μηδέν έως 0,5, παρέχεται σε αντιδραστήρα στον οποίο διεξάγονται οι αντιδράσεις μερικής οξείδωσης και αναμόρφωσης της αιθανόλης, σε κατάλληλο καταλύτη, όπου στον ίδιο ή σε διαφορετικό αντιδραστήρα διεξάγεται και η αντίδραση μετατόπισης και, εάν είναι αναγκαίο η αντίδραση καύσης του μονοξειδίου του άνθρακα ή μετατροπής του σε μεθάνιο, όπου το αέριο μίγμα στην έξοδο των αντιδραστήρων το οποίο περιέχει υδρογόνο σε μίγμα με διοξείδιο του άνθρακα, άζωτο, μεθάνιο ή άλλα αέρια σε μικρές ποσότητες, διαχωρίζεται στον βαθμό που είναι επιθυμητός για οποιαδήποτε χρήση.ΰ
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GR98100180 | 1998-05-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GR1003235B true GR1003235B (el) | 1999-10-13 |
Family
ID=10943392
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GR980100180A GR1003235B (el) | 1998-05-22 | 1998-05-22 | Διεργασια παραγωγης υδρογονου και ηλεκτρικης ενεργειας απο αναμορφωση βιο-αιθανολης, με χρηση κυψελιδων καυσιμου και με μηδενικη εκπομπη ρυπων |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US6387554B1 (el) |
| EP (1) | EP1007472B1 (el) |
| AT (1) | ATE248766T1 (el) |
| CA (2) | CA2294361A1 (el) |
| DE (1) | DE69910957T2 (el) |
| DK (1) | DK1007472T3 (el) |
| EA (1) | EA002382B1 (el) |
| ES (1) | ES2209430T3 (el) |
| GR (1) | GR1003235B (el) |
| PT (1) | PT1007472E (el) |
| WO (1) | WO1999061369A1 (el) |
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| EP1375628A3 (en) * | 2000-01-21 | 2004-12-08 | Integrated Environmental Technologies, Llc. | Methods and apparatus for treating waste |
| US7025875B2 (en) * | 2001-05-14 | 2006-04-11 | Delphi Technologies, Inc. | Diesel fuel reforming strategy |
| JP4098508B2 (ja) * | 2001-08-20 | 2008-06-11 | 財団法人 ひろしま産業振興機構 | 炭化水素と水蒸気とを反応させるための触媒の製造方法および当該触媒を使用した炭化水素から水素を製造する方法 |
| DE10157155A1 (de) * | 2001-11-22 | 2003-06-12 | Omg Ag & Co Kg | Verfahren zur katalytischen autothermen Dampfreformierung von höheren Alkoholen, insbesondere Ethanol |
| US6699457B2 (en) * | 2001-11-29 | 2004-03-02 | Wisconsin Alumni Research Foundation | Low-temperature hydrogen production from oxygenated hydrocarbons |
| CA2467443C (en) * | 2001-11-29 | 2012-01-10 | Wisconsin Alumni Research Foundation | Low-temperature hydrogen production from oxygenated hydrocarbons |
| BRPI0309915B1 (pt) * | 2002-05-10 | 2020-06-23 | Wisconsin Alumni Research Foundation | Método de produção de hidrocarboneto a partir de hidrocarbonetos oxigenados |
| AUPS244802A0 (en) * | 2002-05-21 | 2002-06-13 | Ceramic Fuel Cells Limited | Fuel cell system |
| US7255848B2 (en) * | 2002-10-01 | 2007-08-14 | Regents Of The Univeristy Of Minnesota | Production of hydrogen from alcohols |
| US7262334B2 (en) | 2002-11-13 | 2007-08-28 | Regents Of The University Of Minnesota | Catalytic partial oxidation of hydrocarbons |
| US7276306B2 (en) * | 2003-03-12 | 2007-10-02 | The Regents Of The University Of California | System for the co-production of electricity and hydrogen |
| US7195059B2 (en) * | 2003-05-06 | 2007-03-27 | H2Gen Innovations, Inc. | Heat exchanger and method of performing chemical processes |
| JP2007501998A (ja) * | 2003-08-07 | 2007-02-01 | シービーエイチ2 テクノロジーズ,インコーポレイテッド. | 燃料電池発電装置用の自己着火性水素製造システム |
| DE102004006516A1 (de) * | 2004-02-10 | 2005-08-25 | Voith Paper Patent Gmbh | Verfahren zur Erzeugung von Prozesswärme und/oder elektrischer Energie |
| US7592290B2 (en) * | 2004-04-08 | 2009-09-22 | Sulzer Metco(Canada) Inc. | Supported catalyst for stream methane reforming and autothermal reforming reactions |
| US20050226808A1 (en) * | 2004-04-12 | 2005-10-13 | King Fahd University Of Petroleum And Minerals | Laser photo-catalytic process for the production of hydrogen |
| US7683232B2 (en) | 2004-05-25 | 2010-03-23 | Regents Of The University Of Minnesota | Production of olefins having a functional group |
| WO2006006479A1 (ja) * | 2004-07-12 | 2006-01-19 | Sumitomo Seika Chemicals Co., Ltd. | 水素製造システムおよび改質装置 |
| WO2006021087A1 (en) * | 2004-08-23 | 2006-03-02 | Marshall Richard M | Self-sustaining and continuous system and method of anaerobically digesting ethanol stillage |
| US7585339B2 (en) * | 2004-09-15 | 2009-09-08 | Haldor Topsoe A/S | Process for reforming ethanol to hydrogen-rich products |
| EP1669323B1 (en) * | 2004-12-08 | 2017-07-05 | Karlsruher Institut für Technologie | Reactor and method for the production of hydrogen |
| US20080028675A1 (en) * | 2005-05-10 | 2008-02-07 | Nbe,Llc | Biomass treatment of organic waste materials in fuel production processes to increase energy efficiency |
| WO2007002502A2 (en) * | 2005-06-23 | 2007-01-04 | Grdc, Llc | Efficient production of fuels |
| US7915196B2 (en) * | 2005-10-07 | 2011-03-29 | Alliance For Sustainable Energy, Llc | Attrition resistant fluidizable reforming catalyst |
| US20100252422A1 (en) * | 2005-10-14 | 2010-10-07 | Ohio University | Carbon fiber-electrocatalysts for the oxidation of ammonia and ethanol in alkaline media and their application to hydrogen production, fuel cells, and purification processes |
| US8231857B2 (en) | 2005-12-21 | 2012-07-31 | Virent, Inc. | Catalysts and methods for reforming oxygenated compounds |
| KR100711509B1 (ko) | 2006-01-02 | 2007-04-27 | 재단법인서울대학교산학협력재단 | 자열개질 반응에 의해 물과 에탄올 혼합물로부터 수소를 제조하는데 사용되는 복합 금속 담지 촉매, 그 제조 방법 및 상기 촉매를 이용하여 수소를 제조하는 방법 |
| US8354564B2 (en) | 2006-04-07 | 2013-01-15 | BHS Technology LLC | Production of dry alcohol |
| US7428810B2 (en) * | 2006-04-25 | 2008-09-30 | Caterpillar Inc. | System for increasing efficiency of an SCR catalyst |
| CA2651770C (en) * | 2006-05-08 | 2014-09-09 | Virent Energy Systems, Inc. | Methods and systems for generating polyols |
| CN104962586A (zh) | 2006-07-21 | 2015-10-07 | 希乐克公司 | 生物质转化系统 |
| NZ577547A (en) * | 2006-12-20 | 2012-05-25 | Virent Inc | Reactor system for producing gaseous products |
| US8017818B2 (en) | 2007-03-08 | 2011-09-13 | Virent Energy Systems, Inc. | Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons |
| DE102007015623A1 (de) * | 2007-03-29 | 2008-10-02 | Be Bioenergie Gmbh & Co. Kg | Heizkraftwerk und Verfahren zur energetischen Nutzung von landwirtschaftlich erzeugten Rohstoffen |
| GR1006128B (el) * | 2007-05-25 | 2008-11-03 | . | Υψηλα θερμικα ολοκληρωμενος αναμορφωτης για παραγωγη υδρογονου |
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| AU2009285699B2 (en) * | 2008-08-27 | 2014-04-10 | Virent, Inc. | Synthesis of liquid fuels from biomass |
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| WO2010064932A1 (en) | 2008-12-01 | 2010-06-10 | Lanzatech New Zealand Limited | Optimised fermentation media |
| KR101008025B1 (ko) * | 2008-12-22 | 2011-01-14 | 삼성에스디아이 주식회사 | 탄화수소 개질촉매, 그의 제조 방법 및 이를 포함하는 연료전지 |
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| US20100187822A1 (en) * | 2009-01-23 | 2010-07-29 | Louisville Clean Energy, Llc | Multi-process method of combined heat and power generation, biodiesel production, ethanol production, town gas production, methane production, and syngas production |
| EP2448675A2 (en) * | 2009-06-30 | 2012-05-09 | Virent, Inc. | Process and reactor systems for converting sugars and sugar alcohols |
| US8026087B2 (en) * | 2009-09-23 | 2011-09-27 | Russell W Spitz | Method of continuously producing ethanol and electricity from a sustainable renewable biomass feedstock |
| US7818969B1 (en) | 2009-12-18 | 2010-10-26 | Energyield, Llc | Enhanced efficiency turbine |
| US9303226B2 (en) * | 2009-12-31 | 2016-04-05 | Shell Oil Company | Direct aqueous phase reforming of bio-based feedstocks |
| US9447347B2 (en) | 2009-12-31 | 2016-09-20 | Shell Oil Company | Biofuels via hydrogenolysis-condensation |
| PL2547619T3 (pl) | 2010-03-16 | 2018-04-30 | Shell Internationale Research Maatschappij B.V. | Proces otrzymywania wodoru |
| AU2011227474B2 (en) * | 2010-03-16 | 2014-04-03 | Shell Internationale Research Maatschappij B.V. | A process for producing hydrogen |
| AU2011227476A1 (en) * | 2010-03-16 | 2012-09-13 | Shell Internationale Research Maatschappij B.V. | A process for producing hydrogen |
| BR112012028663A2 (pt) | 2010-05-12 | 2016-08-16 | Shell Int Research | método, e, sistema |
| BR112012028664A2 (pt) | 2010-05-12 | 2016-08-16 | Shell Int Research | método, e, sistema |
| US20120045699A1 (en) * | 2010-08-20 | 2012-02-23 | Shailesh Atreya | Fuel Cell Power and Water Generation |
| EP2455334A1 (en) | 2010-11-18 | 2012-05-23 | Tecnicas Reunidas, S.A. | Ethanol processing system |
| US10961122B2 (en) | 2012-02-06 | 2021-03-30 | Helbio S.A. | Heat integrated reformer with catalytic combustion for hydrogen production |
| US11607657B2 (en) | 2012-02-06 | 2023-03-21 | Helbio S.A. | Heat integrated reformer with catalytic combustion for hydrogen production |
| US10960372B2 (en) | 2012-03-08 | 2021-03-30 | Helbio S.A. | Catalytically heated fuel processor with replaceable structured supports bearing catalyst for fuel cell |
| EP2671842A1 (en) * | 2012-06-06 | 2013-12-11 | Ammonia Casale S.A. | A process for gas-heated reforming of a hydrocarbon source and a related plant |
| CN107302100A (zh) * | 2017-07-31 | 2017-10-27 | 北京理工大学 | 一种基于乙醇重整制氢的氢燃料电池系统及其发电方法 |
| CN111048809A (zh) * | 2019-12-13 | 2020-04-21 | 沈阳航空航天大学 | 基于秸秆乙醇发酵重整制氢气的氢氧燃料电池智能发电系统 |
| CN118062807B (zh) * | 2024-02-26 | 2024-11-19 | 中国矿业大学 | 镍铁镧三元负载型催化剂在微波驱动低碳醇水蒸气重整制氢反应中的应用 |
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| JPS59189935A (ja) * | 1983-04-14 | 1984-10-27 | Mitsubishi Heavy Ind Ltd | エタノ−ル改質用触媒 |
| JPS6339626A (ja) * | 1986-08-01 | 1988-02-20 | Yamaha Motor Co Ltd | 燃料電池用改質装置 |
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1998
- 1998-05-22 GR GR980100180A patent/GR1003235B/el not_active IP Right Cessation
-
1999
- 1999-05-19 CA CA002294361A patent/CA2294361A1/en not_active Abandoned
- 1999-05-19 US US09/446,561 patent/US6387554B1/en not_active Expired - Fee Related
- 1999-05-19 WO PCT/GR1999/000020 patent/WO1999061369A1/en not_active Ceased
- 1999-05-19 AT AT99919449T patent/ATE248766T1/de not_active IP Right Cessation
- 1999-05-19 EA EA199901058A patent/EA002382B1/ru not_active IP Right Cessation
- 1999-05-19 ES ES99919449T patent/ES2209430T3/es not_active Expired - Lifetime
- 1999-05-19 DE DE69910957T patent/DE69910957T2/de not_active Expired - Lifetime
- 1999-05-19 DK DK99919449T patent/DK1007472T3/da active
- 1999-05-19 PT PT99919449T patent/PT1007472E/pt unknown
- 1999-05-19 CA CA2704690A patent/CA2704690A1/en not_active Abandoned
- 1999-05-19 EP EP99919449A patent/EP1007472B1/en not_active Expired - Lifetime
-
2000
- 2000-12-01 US US09/728,569 patent/US6605376B2/en not_active Expired - Fee Related
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Also Published As
| Publication number | Publication date |
|---|---|
| ATE248766T1 (de) | 2003-09-15 |
| CA2294361A1 (en) | 1999-12-02 |
| DK1007472T3 (da) | 2003-12-22 |
| EP1007472A1 (en) | 2000-06-14 |
| PT1007472E (pt) | 2004-01-30 |
| CA2704690A1 (en) | 1999-12-02 |
| WO1999061369A1 (en) | 1999-12-02 |
| EA199901058A1 (ru) | 2000-10-30 |
| DE69910957D1 (de) | 2003-10-09 |
| ES2209430T3 (es) | 2004-06-16 |
| US20010023034A1 (en) | 2001-09-20 |
| EA002382B1 (ru) | 2002-04-25 |
| US6605376B2 (en) | 2003-08-12 |
| DE69910957T2 (de) | 2004-08-12 |
| EP1007472B1 (en) | 2003-09-03 |
| US6387554B1 (en) | 2002-05-14 |
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