GB998830A - Decorating compositions and method of decorating therewith - Google Patents
Decorating compositions and method of decorating therewithInfo
- Publication number
- GB998830A GB998830A GB4673763A GB4673763A GB998830A GB 998830 A GB998830 A GB 998830A GB 4673763 A GB4673763 A GB 4673763A GB 4673763 A GB4673763 A GB 4673763A GB 998830 A GB998830 A GB 998830A
- Authority
- GB
- United Kingdom
- Prior art keywords
- composition
- silver
- mercaptan
- stirring
- mercaptans
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 10
- 238000000034 method Methods 0.000 title abstract 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical group ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 abstract 6
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 abstract 4
- 238000003756 stirring Methods 0.000 abstract 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 abstract 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 abstract 3
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 abstract 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- -1 alkyl mercaptans Chemical group 0.000 abstract 3
- 239000011347 resin Substances 0.000 abstract 3
- 229920005989 resin Polymers 0.000 abstract 3
- 229910052709 silver Inorganic materials 0.000 abstract 3
- 239000004332 silver Substances 0.000 abstract 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 abstract 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- 125000002723 alicyclic group Chemical group 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 abstract 2
- 230000004907 flux Effects 0.000 abstract 2
- 125000000623 heterocyclic group Chemical group 0.000 abstract 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 abstract 2
- 239000000843 powder Substances 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 abstract 2
- 125000001443 terpenyl group Chemical group 0.000 abstract 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 abstract 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- RFCQDOVPMUSZMN-UHFFFAOYSA-N 2-Naphthalenethiol Chemical compound C1=CC=CC2=CC(S)=CC=C21 RFCQDOVPMUSZMN-UHFFFAOYSA-N 0.000 abstract 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 abstract 1
- ZHUWXKIPGGZNJW-UHFFFAOYSA-N 6-methylheptyl 3-sulfanylpropanoate Chemical compound CC(C)CCCCCOC(=O)CCS ZHUWXKIPGGZNJW-UHFFFAOYSA-N 0.000 abstract 1
- 235000007173 Abies balsamea Nutrition 0.000 abstract 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 abstract 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical group S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- 244000018716 Impatiens biflora Species 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 abstract 1
- 229910052770 Uranium Inorganic materials 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229940072049 amyl acetate Drugs 0.000 abstract 1
- PGMYKACGEOXYJE-UHFFFAOYSA-N anhydrous amyl acetate Natural products CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000010426 asphalt Substances 0.000 abstract 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 abstract 1
- 230000001680 brushing effect Effects 0.000 abstract 1
- 229910052793 cadmium Inorganic materials 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 238000004144 decalcomania Methods 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000000706 filtrate Substances 0.000 abstract 1
- 238000010304 firing Methods 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 239000002241 glass-ceramic Substances 0.000 abstract 1
- 229910052737 gold Inorganic materials 0.000 abstract 1
- MNWFXJYAOYHMED-UHFFFAOYSA-M heptanoate Chemical compound CCCCCCC([O-])=O MNWFXJYAOYHMED-UHFFFAOYSA-M 0.000 abstract 1
- 229910052741 iridium Inorganic materials 0.000 abstract 1
- 239000004922 lacquer Substances 0.000 abstract 1
- 229910052745 lead Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000010445 mica Substances 0.000 abstract 1
- 229910052618 mica group Inorganic materials 0.000 abstract 1
- ZVEZMVFBMOOHAT-UHFFFAOYSA-N nonane-1-thiol Chemical group CCCCCCCCCS ZVEZMVFBMOOHAT-UHFFFAOYSA-N 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 239000010453 quartz Substances 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010979 ruby Substances 0.000 abstract 1
- 229910001750 ruby Inorganic materials 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical class [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 abstract 1
- 239000001632 sodium acetate Substances 0.000 abstract 1
- 235000017281 sodium acetate Nutrition 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 235000017550 sodium carbonate Nutrition 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 229910001220 stainless steel Inorganic materials 0.000 abstract 1
- 239000010935 stainless steel Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 150000003505 terpenes Chemical class 0.000 abstract 1
- 235000007586 terpenes Nutrition 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
- 239000000341 volatile oil Substances 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical class OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/06—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals
- C03C17/10—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals by deposition from the liquid phase
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/88—Metals
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Structural Engineering (AREA)
- Catalysts (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Chemically Coating (AREA)
Abstract
Silver mercaptides are prepared by the reaction between a silver salt or oxide and a mercaptan. The term mercaptan includes tertiary alkyl mercaptans containing 7 or more carbon atoms in the tertiary alkyl radical, primary and secondary alkyl mercaptans and other mercaptans which may be aliphatic, alicyclic, heterocyclic, aryl, alkaryl, aralkyl or terpenyl, and other compounds named in a list, e.g. p-chlorophenyl and 2-hydroxyethyl mercaptans, thioglycolic acid and esters thereof, and isooctyl 3mercaptopropionate. The mercaptides may be made by stirring an aqueous solution of a silver salt with a mercaptan. In Example 1, to a mixture of 8 mole tertiary nonyl mercaptan, chloroform, 4 mole Na2CO3, and water, was added 8.4 mole AgNO3 with stirring during 20 minutes. After stirring the mixture was allowed to settle. The chloroform layer was washed with water, filtered, stirred with activated charcoal, and filtered. The filtrate was kept for 4 hrs. in an open dish on a steam bath, with occasional stirring. A deep ruby, moderately viscous oil resulted. In Example 2, 2-naphthalenethiol, AgNo3 and sodium acetate were used.ALSO:A metallic coating is formed by use of a decorating composition comprising a silver mercaptide, a flux and a vehicle. The composition may be applied to an article and fired to a metallic film, lustre colour or stain. The mercaptide may be aliphatic, alicyclic, heterocyclic, aryl, alkaryl, aralkyl or terpenyl, and is preferably tertiary alkyl, e.g. with 7-30 carbon atoms per molecule. A long list of suitable mercaptides is given. The flux may be a salt or resinate of Rh, Ir, Bi, Cr, Pb, Cd, Sn, Cu, Co, Sb or U. The salt may be, e.g., borate, nitrate, silicate. The vehicle may be a mixture of essential oil, terpenes, resins, methyl ethyl ketone, cyclohexanone, ethyl acetate, amyl acetate, "Cellosolve" (Registered Trade Mark), butanol, nitrobenzene, toluene, xylene, petroleum ether, chloroform, carbon tetrachloride, Assyrian asphalt, balsams, or artificial resins, or may be lacquer or wax. The composition may also contain Au, Pt and/or Pd, e.g. as sulphoresinates, organic complexes or powder; Ag powder, amorphous, flakes or spherules, may also be employed. The composition may contain, e.g., 0.1-40.0% or more of silver. The composition may be applied by brushing, spraying, stippling, stamping, printing, or decalcomania transfer. The material may be fired at 250-900 DEG C. by kiln, flash, lehr or infra-red firing. Substrates include laminated artificial resins, glass, glass-ceramic, ceramic, quartz, mica, alumina, aluminium, stainless steel. Specific compositions and method of use are disclosed in the examples. Specification 926,979 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US24042762A | 1962-11-27 | 1962-11-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB998830A true GB998830A (en) | 1965-07-21 |
Family
ID=22906476
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4673763A Expired GB998830A (en) | 1962-11-27 | 1963-11-26 | Decorating compositions and method of decorating therewith |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE1286867B (en) |
| GB (1) | GB998830A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4262040A (en) * | 1978-08-30 | 1981-04-14 | Engelhard Minerals & Chemicals Corporation | Decoration for ceramics having the appearance of gold |
| GB2231884A (en) * | 1989-04-27 | 1990-11-28 | Amp Akzo J V Inc | Heat decomposable fluid compositions containing organogold and organosilver compounds |
| US5059242A (en) * | 1990-04-27 | 1991-10-22 | Firmstone Michael G | Seed layer compositions containing organogold and organosilver compounds |
| GB2253635A (en) * | 1991-01-25 | 1992-09-16 | Amp Akzo Corp | Heat decomposable compositions containing organogold compound and glass forming resinate |
| GB2253636A (en) * | 1991-01-25 | 1992-09-16 | Amp Akzo Corp | Heat decomposable compositions containing organogold compound and resin binder |
-
1963
- 1963-11-26 GB GB4673763A patent/GB998830A/en not_active Expired
- 1963-11-27 DE DE1963E0025934 patent/DE1286867B/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4262040A (en) * | 1978-08-30 | 1981-04-14 | Engelhard Minerals & Chemicals Corporation | Decoration for ceramics having the appearance of gold |
| GB2231884A (en) * | 1989-04-27 | 1990-11-28 | Amp Akzo J V Inc | Heat decomposable fluid compositions containing organogold and organosilver compounds |
| US5059242A (en) * | 1990-04-27 | 1991-10-22 | Firmstone Michael G | Seed layer compositions containing organogold and organosilver compounds |
| GB2253635A (en) * | 1991-01-25 | 1992-09-16 | Amp Akzo Corp | Heat decomposable compositions containing organogold compound and glass forming resinate |
| GB2253636A (en) * | 1991-01-25 | 1992-09-16 | Amp Akzo Corp | Heat decomposable compositions containing organogold compound and resin binder |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1286867B (en) | 1969-01-09 |
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