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GB995186A - Transition metal flourides - Google Patents

Transition metal flourides

Info

Publication number
GB995186A
GB995186A GB32695/63A GB3269563A GB995186A GB 995186 A GB995186 A GB 995186A GB 32695/63 A GB32695/63 A GB 32695/63A GB 3269563 A GB3269563 A GB 3269563A GB 995186 A GB995186 A GB 995186A
Authority
GB
United Kingdom
Prior art keywords
transition metal
complexed
chlorine
electron donor
diluent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB32695/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Montedison SpA
Original Assignee
Montecatini Societa Generale per lIndustria Mineraria e Chimica SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montecatini Societa Generale per lIndustria Mineraria e Chimica SpA filed Critical Montecatini Societa Generale per lIndustria Mineraria e Chimica SpA
Publication of GB995186A publication Critical patent/GB995186A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
    • C07F13/005—Compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B9/00—General methods of preparing halides
    • C01B9/08—Fluorides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G1/00—Methods of preparing compounds of metals not covered by subclasses C01B, C01C, C01D, or C01F, in general
    • C01G1/06—Halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
    • C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/06—Cobalt compounds
    • C07F15/065—Cobalt compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/005—Compounds of elements of Group 5 of the Periodic Table without metal-carbon linkages

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

Transition metal halides in which at least half the halogen content is fluorine and the rest is chlorine or bromine, are prepared by fluorinating a transition metal chloride or bromide with ethylidene difluoride or boron trifluoride, or both under anhydrous conditions in the presence of a chlorine-containing organic diluent. The transition metal may be Ti, V, Cr, Mo, Fe, Co, Ni, W or Zr. The molar ratio of the diluent, e.g. methyl, ethyl or n-propyl chloride to the transition metal halide is at least 1 : 1, preferably 5 : 1 to 50 : 1. The reactants may be introduced into an autoclave cooled to e.g. -78 DEG C. and reaction may take place at 0-200 DEG C. for e.g. 15 hours, in e.g. a nitrogen atmosphere. Optionally an electron donor compound may be present in the reaction mixture, or the starting halide may be complexed with such a compound, and the product is then so complexed, but only organic electron donor compounds are mentioned.
GB32695/63A 1962-08-22 1963-08-19 Transition metal flourides Expired GB995186A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT1677362 1962-08-22

Publications (1)

Publication Number Publication Date
GB995186A true GB995186A (en) 1965-06-16

Family

ID=11149311

Family Applications (1)

Application Number Title Priority Date Filing Date
GB32695/63A Expired GB995186A (en) 1962-08-22 1963-08-19 Transition metal flourides

Country Status (4)

Country Link
BE (1) BE636434A (en)
DE (1) DE1210766B (en)
GB (1) GB995186A (en)
NL (1) NL296753A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4275046A (en) 1978-01-16 1981-06-23 Exxon Research & Engineering Co. Preparation of high surface area metal fluorides and metal oxyfluorides, especially aluminum fluoride extrudates
WO2004060806A1 (en) 2003-01-07 2004-07-22 Humboldt-Universität Zu Berlin Method for the preparation of high surface area metal fluorides
EP1440939A1 (en) * 2003-01-07 2004-07-28 Humboldt-Universität zu Berlin Method for the preparation of amorphous metal fluorides
WO2015063692A1 (en) * 2013-10-31 2015-05-07 Sabic Global Technologies B.V. Process for making axially fluorinated-phthalocyanines and their use in photovoltaic applications

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4275046A (en) 1978-01-16 1981-06-23 Exxon Research & Engineering Co. Preparation of high surface area metal fluorides and metal oxyfluorides, especially aluminum fluoride extrudates
WO2004060806A1 (en) 2003-01-07 2004-07-22 Humboldt-Universität Zu Berlin Method for the preparation of high surface area metal fluorides
EP1440939A1 (en) * 2003-01-07 2004-07-28 Humboldt-Universität zu Berlin Method for the preparation of amorphous metal fluorides
US7592287B2 (en) 2003-01-07 2009-09-22 Humboldt-Universitaet Zu Berlin Method for the preparation of high surface area metal fluorides
WO2015063692A1 (en) * 2013-10-31 2015-05-07 Sabic Global Technologies B.V. Process for making axially fluorinated-phthalocyanines and their use in photovoltaic applications
US9472771B2 (en) 2013-10-31 2016-10-18 Sabic Global Technologies B.V. Method of making axially fluorinated-phthalocyanines with an aprotic fluoride compound

Also Published As

Publication number Publication date
NL296753A (en) 1900-01-01
BE636434A (en) 1900-01-01
DE1210766B (en) 1966-02-17

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