GB986814A - Method for forming resin foams - Google Patents
Method for forming resin foamsInfo
- Publication number
- GB986814A GB986814A GB7982/62A GB798262A GB986814A GB 986814 A GB986814 A GB 986814A GB 7982/62 A GB7982/62 A GB 7982/62A GB 798262 A GB798262 A GB 798262A GB 986814 A GB986814 A GB 986814A
- Authority
- GB
- United Kingdom
- Prior art keywords
- zone
- mixture
- ingredients
- agitation
- pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000006260 foam Substances 0.000 title abstract 4
- 239000011347 resin Substances 0.000 title abstract 3
- 229920005989 resin Polymers 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 abstract 7
- 239000004604 Blowing Agent Substances 0.000 abstract 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 4
- 238000013019 agitation Methods 0.000 abstract 4
- 239000004615 ingredient Substances 0.000 abstract 4
- 238000005187 foaming Methods 0.000 abstract 3
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 2
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 2
- 239000001569 carbon dioxide Substances 0.000 abstract 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- KTHSXIDIBJLTIB-UHFFFAOYSA-N 1-(2-chloropropan-2-yl)-2-methylbenzene Chemical compound CC1=CC=CC=C1C(C)(C)Cl KTHSXIDIBJLTIB-UHFFFAOYSA-N 0.000 abstract 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 abstract 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 abstract 1
- BJEMXPVDXFSROA-UHFFFAOYSA-N 3-butylbenzene-1,2-diol Chemical group CCCCC1=CC=CC(O)=C1O BJEMXPVDXFSROA-UHFFFAOYSA-N 0.000 abstract 1
- XLZHGKDRKSKCAU-UHFFFAOYSA-N 3-isopropylcatechol Chemical compound CC(C)C1=CC=CC(O)=C1O XLZHGKDRKSKCAU-UHFFFAOYSA-N 0.000 abstract 1
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004793 Polystyrene Substances 0.000 abstract 1
- UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical compound [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 abstract 1
- 229940120693 copper naphthenate Drugs 0.000 abstract 1
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 abstract 1
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 abstract 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 abstract 1
- 229960001826 dimethylphthalate Drugs 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 abstract 1
- 238000001879 gelation Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 229920002223 polystyrene Polymers 0.000 abstract 1
- 150000003242 quaternary ammonium salts Chemical group 0.000 abstract 1
- 238000010008 shearing Methods 0.000 abstract 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 abstract 1
- 229920006305 unsaturated polyester Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/40—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft
- B29B7/401—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft having a casing closely surrounding the rotor, e.g. with a plunger for feeding the material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/40—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft
- B29B7/404—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft with feeding or valve actuating means, e.g. with cleaning means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/40—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft
- B29B7/405—Mixing heads
- B29B7/407—Mixing heads with a casing closely surrounding the rotor, e.g. with conical rotor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7404—Mixing devices specially adapted for foamable substances
- B29B7/7409—Mixing devices specially adapted for foamable substances with supply of gas
- B29B7/7414—Mixing devices specially adapted for foamable substances with supply of gas with rotatable stirrer, e.g. using an intermeshing rotor-stator system
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7461—Combinations of dissimilar mixers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/802—Constructions or methods for cleaning the mixing or kneading device
- B29B7/803—Cleaning of mixers of the gun type, stream-impigement type, mixing heads
- B29B7/805—Cleaning of the mixing conduit, module or chamber part
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/82—Heating or cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/36—Feeding the material to be shaped
- B29C44/365—Feeding the material to be shaped using elongate feed conduits provided with throttle devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7471—Mixers in which the mixing takes place at the inlet of a mould, e.g. mixing chambers situated in the mould opening
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
- B29K2067/06—Unsaturated polyesters
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
A process of forming a resin foam comprises introducing into a zone of agitation liquid polymerizable resin-forming ingredients comprising a >CH = CH2 monomer and a polyester of a glycol or dihydric alcohol and of an alpha-beta ethylenically unsaturated dicarboxylic acid, a curing agent for the ingredients, and a blowing agent soluble in the ingredients, said blowing agent being adapted to be absorbed in the mixture at relatively high pressures and at relatively low temperatures, but being adapted at lower pressures and higher temperatures to produce foaming, the introduction of the ingredients into the zone of agitation being at a temperature and under a pressure sufficient to maintain the blowing agent in solution without appreciable bubble formation, ejecting the mixture from the zone of agitation into a zone at the pressure of foaming and allowing the material to foam and cure, the material being ejected through a pressure reduction zone have a sufficiently low ratio of depth to diameter that the formation of bubbles in the mixture is substantially inhibited until the mixture has essentially escaped from the pressure reduction zone into the zone of lower pressure. The blowing agent may be a chlorofluorocarbon. The reaction may also generate a gas, such as carbon dioxide, which under the conditions in the zone of agitation is also absorbed in the resin-forming components. In the example the unsaturated polyester is prepared by reacting isophthalic acid, triethylene glycol and maleic anhydride. For storage it is mixed with a gelation inhibitor, e.g. hydroquinone, 3-isopropyl-catechol or tertiary butyl catechol, or a quaternary ammonium salt, e.g. trimethyl benzyl chloride or diisobutylphenoxyethoxy ethyl dimethyl benzyl ammonium chloride, or copper naphthenate. Mixed with polystyrene it gives an interpolymerizable mixture. To it may be added emulsifiers or flameretardants such as chlorinated wax. Foam stability is improved by adding an organic acid, e.g. fumaric or maleic. Such a mixture is passed to a suitable mixing apparatus (see Division B1) having a shearing effect in which it is mixed under pressure with a mixture of CC12F2, CC13F and methyl ethyl ketone peroxide (or benzoyl peroxide or cumene hydroperoxide) (to which carbon dioxide may be added) dissolved in dimethylphthalate, added at a lower level in the mixing chamber. Foaming and the gelling and setting of the resin take place after the discharge from a suitably proportioned orifice, and may be accelerated by heating, e.g. at 100 DEG to 250 DEG F.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US9427961A | 1961-03-08 | 1961-03-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB986814A true GB986814A (en) | 1965-03-24 |
Family
ID=22244206
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7982/62A Expired GB986814A (en) | 1961-03-08 | 1962-03-01 | Method for forming resin foams |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE1504654A1 (en) |
| GB (1) | GB986814A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2247411A (en) * | 1990-06-26 | 1992-03-04 | Ics Texicon Ltd | Producing foam |
| WO1992014595A1 (en) * | 1991-02-15 | 1992-09-03 | Exlan Limited | Mixing process for reactive liquids |
| CN100588530C (en) * | 2008-07-25 | 2010-02-10 | 浙江爱华新材料科技有限公司 | A feeding tank for polypropylene foaming |
| CN107848143A (en) * | 2015-07-03 | 2018-03-27 | 松德赫夫工程有限公司 | Mixing arrangement including pressurizer |
| CN107889477A (en) * | 2015-07-03 | 2018-04-06 | 松德赫夫工程有限公司 | Mixing apparatus with the adjusting device for gap adjustment |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1779028C3 (en) * | 1968-06-29 | 1978-08-03 | Basf Ag, 6700 Ludwigshafen | Valve for plastic molding machines |
| DE2440022C2 (en) * | 1974-08-21 | 1982-07-08 | Bayer Ag, 5090 Leverkusen | Process for the production of insulating and lightweight building materials and device for carrying out this process |
| DE102012103885B4 (en) * | 2012-05-03 | 2015-07-23 | Sonderhoff Engineering Gmbh | Apparatus for producing a multi-component mixture |
| AT516946B1 (en) * | 2015-07-03 | 2016-10-15 | Sonderhoff Eng Gmbh | mixing device |
| AT519978B1 (en) * | 2017-12-19 | 2018-12-15 | Sonderhoff Eng Gmbh | Device for producing plastic parts |
| BE1030143B1 (en) * | 2021-12-30 | 2023-07-31 | Soudal Nv | PROCEDURE FOR STIRING AND STIRRER FOR TUBES AND THE FINAL PRODUCTS OBTAINED |
-
1962
- 1962-03-01 GB GB7982/62A patent/GB986814A/en not_active Expired
- 1962-03-06 DE DE19621504654 patent/DE1504654A1/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2247411A (en) * | 1990-06-26 | 1992-03-04 | Ics Texicon Ltd | Producing foam |
| WO1992014595A1 (en) * | 1991-02-15 | 1992-09-03 | Exlan Limited | Mixing process for reactive liquids |
| CN100588530C (en) * | 2008-07-25 | 2010-02-10 | 浙江爱华新材料科技有限公司 | A feeding tank for polypropylene foaming |
| CN107848143A (en) * | 2015-07-03 | 2018-03-27 | 松德赫夫工程有限公司 | Mixing arrangement including pressurizer |
| CN107889477A (en) * | 2015-07-03 | 2018-04-06 | 松德赫夫工程有限公司 | Mixing apparatus with the adjusting device for gap adjustment |
| US20180178412A1 (en) * | 2015-07-03 | 2018-06-28 | Sonderhoff Engineering Gmbh | Mixing device with a pressure holding device |
| US11034059B2 (en) | 2015-07-03 | 2021-06-15 | Henkel Ag & Co. Kgaa | Mixing device with adjustment device for gap setting |
| CN107848143B (en) * | 2015-07-03 | 2022-12-13 | 汉高股份有限及两合公司 | Mixing device comprising a pressure maintaining device |
| US11897168B2 (en) | 2015-07-03 | 2024-02-13 | Henkel Ag & Co. Kgaa | Mixing device with a pressure holding device |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1504654A1 (en) | 1969-05-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB986814A (en) | Method for forming resin foams | |
| JPS5844467B2 (en) | Setsuenbutsushitsu Oyobi Keiryoukenchikuzairiyounoseizohouhou Narabini Seizouyousouchi | |
| US3362919A (en) | Process for foaming thermoset organic materials | |
| US3051665A (en) | Method of foaming an admixture of epoxy resin, a chlorofluorocarbon, and a curing catalyst | |
| US3920589A (en) | Low-density polyester resin foams and method of preparation | |
| US4744700A (en) | Method for filling abandoned mines | |
| US3920590A (en) | Low-density polyester resin foams and method of preparation | |
| JPS6033141B2 (en) | Simultaneous expansion and curing of polyester resin compositions | |
| US3479303A (en) | Process for the production of molded foam bodies of polyesters | |
| US4613628A (en) | Resin composition for closed-cell foam and cured resin foam prepared by using said resin composition | |
| US4692427A (en) | Dispersions and the preparation of foamed resins therefrom | |
| US4431752A (en) | Unsaturated polyester foams | |
| US4636528A (en) | Foaming of unsaturated polyester resin at elevated temperatures | |
| US3573233A (en) | Process for the production of foamed materials | |
| US3940349A (en) | Compositions and process for making rigid plastic foams of modified vinyl ester resins and silicone compounds | |
| US4397965A (en) | Expandable and curable polyester resin composition and method for making same | |
| US4388419A (en) | Unsaturated polyester resin foams and method of preparation | |
| EP0105644B1 (en) | Azocarboxylate blowing agent | |
| US4689352A (en) | Production of plastic foam material with gas-release control agent | |
| US4560706A (en) | Method of producing polyester foams using borohydride dispersions | |
| US2937152A (en) | Cellular polyester-urethane resin and preparation of same | |
| US4918113A (en) | Production of plastic foam material | |
| GB2153362A (en) | Foamable thermoset resins | |
| US3766102A (en) | Molded microporous unsaturated polyester resin | |
| SU798129A1 (en) | Method of preparing phenol porous plastic material |