GB952927A - - Google Patents
Info
- Publication number
- GB952927A GB952927A GB952927DA GB952927A GB 952927 A GB952927 A GB 952927A GB 952927D A GB952927D A GB 952927DA GB 952927 A GB952927 A GB 952927A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hafnium
- resin
- zirconium
- sulphuric acid
- april
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052735 hafnium Inorganic materials 0.000 abstract 4
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 3
- 239000011347 resin Substances 0.000 abstract 3
- 229920005989 resin Polymers 0.000 abstract 3
- 235000011149 sulphuric acid Nutrition 0.000 abstract 3
- 239000001117 sulphuric acid Substances 0.000 abstract 3
- 229910052726 zirconium Inorganic materials 0.000 abstract 3
- 239000003957 anion exchange resin Substances 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-M bisulphate group Chemical group S([O-])(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 abstract 1
- 229920001429 chelating resin Polymers 0.000 abstract 1
- 238000006073 displacement reaction Methods 0.000 abstract 1
- 238000010828 elution Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 abstract 1
- 230000001172 regenerating effect Effects 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 150000003754 zirconium Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
952,927. Zirconium and hafnium separation. COMMISSARIAT A L'ENERGIE ATOMIQUE. April 17, 1961 [April 19, 1960], No. 13829/61. Drawings to Specification. Heading C1A. Zirconium and hafnium are separated from a material containing them by dissolving the material in sulphuric acid of concentration between 0.1 and 0.4 M, contacting an anionexchange resin in the bisulphate form with the solution formed, developing the resin by displacement using a sulphuric acid solution of a zirconium salt and recovering the hafnium thus displaced, and regenerating the resin by elution with sulphuric acid, at least part of the zirconium free from hafnium being obtained in the eluant. The process is preferably effected in a continuous and countercurrent fashion using a movable mass of resin. The anion exchange resins are advantageously of the strong base type, e.g. those known under the Trade Marks "Dowex 2" " and " Amberlite IRA-410." Specifications 755,601 and 838,262 are referred to.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB952927A true GB952927A (en) | 1900-01-01 |
Family
ID=1754141
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB952927D Expired GB952927A (en) |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB952927A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU711961B2 (en) * | 1995-07-17 | 1999-10-28 | Westinghouse Electric Company Llc | Zirconium and hafnium separation in sulfate solutions using continuous ion exchange chromatography |
| CN101209858B (en) * | 2006-12-28 | 2010-05-19 | 北京有色金属研究总院 | Method for separating zirconium and hafnium by tributyl phosphate extraction chromatography |
-
0
- GB GB952927D patent/GB952927A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU711961B2 (en) * | 1995-07-17 | 1999-10-28 | Westinghouse Electric Company Llc | Zirconium and hafnium separation in sulfate solutions using continuous ion exchange chromatography |
| CN101209858B (en) * | 2006-12-28 | 2010-05-19 | 北京有色金属研究总院 | Method for separating zirconium and hafnium by tributyl phosphate extraction chromatography |
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