GB950208A - Basic aluminium salts - Google Patents
Basic aluminium saltsInfo
- Publication number
- GB950208A GB950208A GB16817/61A GB1681761A GB950208A GB 950208 A GB950208 A GB 950208A GB 16817/61 A GB16817/61 A GB 16817/61A GB 1681761 A GB1681761 A GB 1681761A GB 950208 A GB950208 A GB 950208A
- Authority
- GB
- United Kingdom
- Prior art keywords
- salts
- aluminium
- pentahydroxy
- prepared
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 159000000013 aluminium salts Chemical class 0.000 title 1
- 150000003839 salts Chemical class 0.000 abstract 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical class [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 5
- 229910052782 aluminium Inorganic materials 0.000 abstract 5
- 239000004411 aluminium Substances 0.000 abstract 5
- QSDQMOYYLXMEPS-UHFFFAOYSA-N dialuminium Chemical compound [Al]#[Al] QSDQMOYYLXMEPS-UHFFFAOYSA-N 0.000 abstract 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 3
- 230000001166 anti-perspirative effect Effects 0.000 abstract 3
- 239000003213 antiperspirant Substances 0.000 abstract 3
- 239000007864 aqueous solution Substances 0.000 abstract 3
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 abstract 3
- 239000003906 humectant Substances 0.000 abstract 3
- 239000000243 solution Substances 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract 2
- 229910002651 NO3 Inorganic materials 0.000 abstract 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 2
- 235000011128 aluminium sulphate Nutrition 0.000 abstract 2
- 239000001164 aluminium sulphate Substances 0.000 abstract 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 2
- 229910052794 bromium Inorganic materials 0.000 abstract 2
- 229910052801 chlorine Inorganic materials 0.000 abstract 2
- 239000000460 chlorine Substances 0.000 abstract 2
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 abstract 2
- 239000000539 dimer Substances 0.000 abstract 2
- 238000011065 in-situ storage Methods 0.000 abstract 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 239000000376 reactant Substances 0.000 abstract 2
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 2
- 239000013638 trimer Substances 0.000 abstract 2
- VFXOSPUHTCXECQ-UHFFFAOYSA-K (2,2-dioxo-1,3,2,4-dioxathialumetan-4-yl) hydrogen sulfate Chemical class OS(=O)(=O)O[Al]1OS(=O)(=O)O1 VFXOSPUHTCXECQ-UHFFFAOYSA-K 0.000 abstract 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 abstract 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000002537 cosmetic Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000000600 sorbitol Substances 0.000 abstract 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-M sulfamate Chemical compound NS([O-])(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-M 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/78—Compounds containing aluminium, with or without oxygen or hydrogen, and containing two or more other elements
- C01F7/786—Compounds containing aluminium, with or without oxygen or hydrogen, and containing two or more other elements containing, besides aluminium, only anions, e.g. Al[OH]xCly[SO4]z
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
Salts of aluminium having general formula Al8(OH)20X2SO4, wherein X is the salt radical of a strong monobasic acid, are prepared from basic aluminium sulphate and dialuminium pentahydroxy salts of formula Al2(OH)5X, where X is as above, by mixing aqueous solutions. Either one or both of the reactants may be prepared in situ. The product is soluble in water and may exist as a dimer or trimer. X may be chlorine, bromine, iodine, nitrate, sulphonate phenol sulphonate or arylsulphonate. Separation of the product from solution is preferably carried out under reduced pressure and low pressures, whereby water is evaporated away and solid deposited. When mixing the solution the molar ratio of pentahydroxy salt basic sulphate is not less than 2:1. Examples refer to production of aluminium hydroxychlorosulphates, aluminium hydroxy-nitratosulphate and aluminium hydroxy-sulphamatesulphate whilst other examples refer to antiperspirants, cosmetic preparations containing the above compounds.ALSO:Salts of aluminium having the general formula Al8(OH)20X2SO4 wherein X is the salt radical of a strong monobasic acid, are prepared from basic aluminium sulphate and dialuminium pentahydroxy salts of formula Al2(OH)5X where X is as above, by mixing aqueous solutions. Either one or both of the reactants may be prepared in situ. The product is soluble in water and may exist as a dimer or trimer. X may be phenol sulphonate or arylsulphonate. When mixing the solution the molar ratio of pentahydroxy salt to basic sulphate is not less than 2:1. An example refers to the production of aluminium hydroxy sulphonate-sulphates.ALSO:Antiperspirant compositions comprise salts of general formula Al8(OH)2X2SO4 in which X is the salt radical of a strong monobasic acid, a water-soluble monohydroxy aliphatic alcohol, and a humectant. The above salts may also be used as an antiperspirant when mixed with Al2(OH)5Cl. In the above X may represent chlorine, bromine, iodine, nitrate, sulphamate, phenolsulphonate or arylsulphonates; examples of alcohols are ethanol and isopropanol, and humectants are glycerol, sorbitol and propylene glycol. The salts are used in concentrated aqueous solutions and are mixed with alcohol and humectants.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB16817/61A GB950208A (en) | 1961-05-09 | 1961-05-09 | Basic aluminium salts |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB16817/61A GB950208A (en) | 1961-05-09 | 1961-05-09 | Basic aluminium salts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB950208A true GB950208A (en) | 1964-02-19 |
Family
ID=10084212
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB16817/61A Expired GB950208A (en) | 1961-05-09 | 1961-05-09 | Basic aluminium salts |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB950208A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2534897A1 (en) * | 1982-10-26 | 1984-04-27 | Ugine Kuhlmann | PROCESS FOR THE PRODUCTION OF BASIC ALUMINUM CHLOROSULFATES |
| EP1108679A3 (en) * | 1999-12-16 | 2001-07-25 | Sachtleben Chemie GmbH | Polyaluminium nitrate sulfates, process for the preparation thereof |
-
1961
- 1961-05-09 GB GB16817/61A patent/GB950208A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2534897A1 (en) * | 1982-10-26 | 1984-04-27 | Ugine Kuhlmann | PROCESS FOR THE PRODUCTION OF BASIC ALUMINUM CHLOROSULFATES |
| GB2128977A (en) * | 1982-10-26 | 1984-05-10 | Ugine Kuhlmann | Process for the manufacture of basic aluminium chlorosulphates |
| EP1108679A3 (en) * | 1999-12-16 | 2001-07-25 | Sachtleben Chemie GmbH | Polyaluminium nitrate sulfates, process for the preparation thereof |
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