GB946143A - Process for the conversion of complex organo-aluminium and organo-boron compounds - Google Patents
Process for the conversion of complex organo-aluminium and organo-boron compoundsInfo
- Publication number
- GB946143A GB946143A GB20449/61A GB2044961A GB946143A GB 946143 A GB946143 A GB 946143A GB 20449/61 A GB20449/61 A GB 20449/61A GB 2044961 A GB2044961 A GB 2044961A GB 946143 A GB946143 A GB 946143A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sodium
- amalgam
- potassium
- aluminium
- lead
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000002370 organoaluminium group Chemical group 0.000 title abstract 2
- 238000006243 chemical reaction Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 239000011734 sodium Substances 0.000 abstract 17
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 8
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 8
- 239000004411 aluminium Substances 0.000 abstract 8
- 229910052782 aluminium Inorganic materials 0.000 abstract 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 8
- 229910052700 potassium Inorganic materials 0.000 abstract 8
- 239000011591 potassium Substances 0.000 abstract 8
- 229910052708 sodium Inorganic materials 0.000 abstract 8
- 229910000497 Amalgam Inorganic materials 0.000 abstract 6
- MRMOZBOQVYRSEM-UHFFFAOYSA-N tetraethyllead Chemical compound CC[Pb](CC)(CC)CC MRMOZBOQVYRSEM-UHFFFAOYSA-N 0.000 abstract 6
- 229910000567 Amalgam (chemistry) Inorganic materials 0.000 abstract 4
- 239000003792 electrolyte Substances 0.000 abstract 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 238000005868 electrolysis reaction Methods 0.000 abstract 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 2
- 229910052753 mercury Inorganic materials 0.000 abstract 2
- MJGFBOZCAJSGQW-UHFFFAOYSA-N mercury sodium Chemical compound [Na].[Hg] MJGFBOZCAJSGQW-UHFFFAOYSA-N 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 229910001023 sodium amalgam Inorganic materials 0.000 abstract 2
- 150000003388 sodium compounds Chemical class 0.000 abstract 2
- 229910000104 sodium hydride Inorganic materials 0.000 abstract 2
- 239000012312 sodium hydride Substances 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- FVIZARNDLVOMSU-UHFFFAOYSA-N ginsenoside K Natural products C1CC(C2(CCC3C(C)(C)C(O)CCC3(C)C2CC2O)C)(C)C2C1C(C)(CCC=C(C)C)OC1OC(CO)C(O)C(O)C1O FVIZARNDLVOMSU-UHFFFAOYSA-N 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/027—Organoboranes and organoborohydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/01—Products
- C25B3/13—Organo-metallic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
<FORM:0946143/C2/1> Potassium organo-boron and/or organo-aluminium complex compounds are obtained by reacting melts or solutions of the sodium compounds with potassium amalgam. The products are useful as electrolytes in the electrolytic production of a metal alkyl, e.g. tetraethyl lead and triethyl aluminium. Compounds used include:-Na[AlR4], Na[AlR3H], Na[AlR3OR1], Na[AlR3X], Na[Al2R6X], Na[BR4], Na[BR3H], Na[BRnOR1m] in which R and R1 are hydrocarbon radicals, X is F, CN, or N3, and n and m together equal 4 and may be 0 or an integer from 1 to 4. In the drawing sodium hydride is formed in reactor 1 from sodium and hydrogen. This is treated with trialkyl aluminium and then ethylene to give sodium tetraalkyl aluminium. This is passed to exchanger 3 in which it is passed in counter current to a sodium amalgam containing some potassium to produce potassium tetraalkyl aluminium which is then passed to electrolytic cell 6. Electrolysis gives trialkyl aluminium and potassium in the amalgam. If a lead anode is used tetraalkyl lead would be produced. The amalgam is recycled to exchanger 3. To prevent overconcentrating the amalgam with sodium, a portion is cycled through cell 11 and the sodium obtained is then returned to reactor 1, the mercury being returned to cell 6. 3/4 of the trialkyl aluminium is recycled, the remainder being withdrawn.ALSO:In the production of metal alkyls by electrolysis, the electrolyte consists of complex aluminium-organic and boron-organic compounds of potassium which are obtained by treating the corresponding sodium compounds with potassium amalgam. In the production of trialkyl aluminium, a compound K[AlR4] is electrolyzed between an aluminium anode and a sodium amalgam cathode. Trialkyl aluminium is obtained at the cathode while the amalgam, now containing potassium, is recycled through an exchanger containing Na[AlR4] at such a rate that the potassium content of the mercury is below 0.1% and the sodium content at 0.5-1%. In the production of tetraalkyl lead, the electrolyte may be a mixture of K[Al(C2H5)4] and K[Al(C2H5)3F] to form tetraethyl lead and K[Al2(C2H5)6F] at the lead anode and potassium amalgam at the cathode. After separating off tetraethyl lead the electrolyte is regenerated by treatment with sodium hydride, ethylene and is stirred with the potassium amalgam at such a rate as to maintain the potassium and sodium concentrations in the amalgam at the values stated above. To prevent overconcentrating the amalgam with sodium a second cell may be used to remove sodium.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEZ8056A DE1153371B (en) | 1960-06-07 | 1960-06-07 | Process for the conversion of organic sodium-aluminum complexes into organic potassium-aluminum complexes |
| DEZ8197A DE1166196B (en) | 1960-06-07 | 1960-08-11 | Process for the production of tetraethyl lead by electrolysis |
| DEZ8715A DE1157620B (en) | 1960-06-07 | 1961-05-02 | Process for converting organic sodium boron complexes into organic potassium boron complexes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB946143A true GB946143A (en) | 1964-01-08 |
Family
ID=27213509
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB20449/61A Expired GB946143A (en) | 1960-06-07 | 1961-06-06 | Process for the conversion of complex organo-aluminium and organo-boron compounds |
Country Status (2)
| Country | Link |
|---|---|
| DE (2) | DE1153371B (en) |
| GB (1) | GB946143A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014531397A (en) * | 2011-07-15 | 2014-11-27 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツングＭｅｒｃｋ Ｐａｔｅｎｔ Ｇｅｓｅｌｌｓｃｈａｆｔ ｍｉｔ ｂｅｓｃｈｒａｅｎｋｔｅｒ Ｈａｆｔｕｎｇ | Compounds containing alkyl-alkoxy-cyano-borate anions |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6262200B1 (en) * | 1996-08-19 | 2001-07-17 | Northwestern University | (Polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon |
-
1960
- 1960-06-07 DE DEZ8056A patent/DE1153371B/en active Pending
-
1961
- 1961-05-02 DE DEZ8715A patent/DE1157620B/en active Pending
- 1961-06-06 GB GB20449/61A patent/GB946143A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014531397A (en) * | 2011-07-15 | 2014-11-27 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツングＭｅｒｃｋ Ｐａｔｅｎｔ Ｇｅｓｅｌｌｓｃｈａｆｔ ｍｉｔ ｂｅｓｃｈｒａｅｎｋｔｅｒ Ｈａｆｔｕｎｇ | Compounds containing alkyl-alkoxy-cyano-borate anions |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1157620B (en) | 1963-11-21 |
| DE1153371B (en) | 1963-08-29 |
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