GB932852A - Blends of vinyl chloride polymers and graft polymers - Google Patents
Blends of vinyl chloride polymers and graft polymersInfo
- Publication number
- GB932852A GB932852A GB2713060A GB2713060A GB932852A GB 932852 A GB932852 A GB 932852A GB 2713060 A GB2713060 A GB 2713060A GB 2713060 A GB2713060 A GB 2713060A GB 932852 A GB932852 A GB 932852A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl chloride
- copolymer
- butadiene
- blends
- graft
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000578 graft copolymer Polymers 0.000 title abstract 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 title abstract 3
- 229920000642 polymer Polymers 0.000 title 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 6
- 229920001577 copolymer Polymers 0.000 abstract 2
- OZDOQMMXEACZAA-NRFIWDAESA-L (z)-4-butoxy-4-oxobut-2-enoate;dibutyltin(2+) Chemical compound CCCCOC(=O)\C=C/C(=O)O[Sn](CCCC)(CCCC)OC(=O)\C=C/C(=O)OCCCC OZDOQMMXEACZAA-NRFIWDAESA-L 0.000 abstract 1
- ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- 235000021355 Stearic acid Nutrition 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 239000012170 montan wax Substances 0.000 abstract 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 abstract 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 abstract 1
- -1 phthalic acid ester Chemical class 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 abstract 1
- 229920002959 polymer blend Polymers 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 239000008117 stearic acid Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/02—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine
- C08F259/04—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine on to polymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/22—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L27/24—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment halogenated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
A polymer blend comprises (1) a homopolymer or copolymer of vinyl chloride, e.g. a vinyl chloride-vinyl acetate copolymer, and (2) a rubbery graft copolymer obtainable by polymerizing at least one monomer on to a vinyl chloride homo- or copolymer, e.g. graft copolymers of polyvinyl chloride with mixtures of butadiene and acrylonitrile, butadiene and methyl methacrylate and butadiene and ethyl acrylate. The graft copolymers may be obtained by the methods described in French Specification 1,309,809. Also present in the blends may be stabilizers, e.g. dibutyl tin maleate, dibutyl tin bis(monobutyl maleate) or a sulphur containing organo-tin compound, plasticizers, e.g. a phthalic acid ester of C7-C9 alcohols, further polymeric constituents, e.g. styrene-acrylonitrile copolymers, montan wax and stearic acid.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2713060A GB932852A (en) | 1960-08-04 | 1960-08-04 | Blends of vinyl chloride polymers and graft polymers |
| DE1961B0063437 DE1291116B (en) | 1960-08-04 | 1961-07-28 | Thermoplastic compound for the production of transparent or semi-transparent impact-resistant molded bodies |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2713060A GB932852A (en) | 1960-08-04 | 1960-08-04 | Blends of vinyl chloride polymers and graft polymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB932852A true GB932852A (en) | 1963-07-31 |
Family
ID=10254711
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2713060A Expired GB932852A (en) | 1960-08-04 | 1960-08-04 | Blends of vinyl chloride polymers and graft polymers |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE1291116B (en) |
| GB (1) | GB932852A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3686363A (en) * | 1969-12-04 | 1972-08-22 | Stauffer Chemical Co | Polyvinyl chloride-polymethacrylonitrile interpolymer processing air for polyvinyl chloride |
| US3764638A (en) * | 1970-07-09 | 1973-10-09 | Stauffer Chemical Co | Processing aids for polyvinyl chloride and methods for their preparation |
| US4518743A (en) * | 1982-08-04 | 1985-05-21 | Bayer Aktiengesellschaft | Moulding compositions of vinyl chloride polymers, certain copolymers and polymeric plasticisers having a high resistance to ageing |
| WO2002059171A3 (en) * | 2001-01-26 | 2003-08-21 | Univ Pennsylvania | Living radical graft copolymerization of vinyl monomers initiated from the structural defects of polyvinylchloride |
| US6838535B2 (en) | 2001-03-23 | 2005-01-04 | University Of Pennsylvania | Process for the living radical polymerization of chlorine containing monomers |
| US6911515B2 (en) | 2001-03-23 | 2005-06-28 | University Of Pennsylvania | Aqueous room temperature living radical polymerization of vinyl halides |
| US7345127B2 (en) | 2001-03-23 | 2008-03-18 | University Of Pennsylvania | Living radical polymerization of halogen-containing and acrylic monomers and the formation of block copolymers therefrom |
| CN104725569A (en) * | 2015-04-02 | 2015-06-24 | 马清洪 | PVC (polyvinyl chloride) processing modifying assistant and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2802809A (en) * | 1953-11-30 | 1957-08-13 | Firestone Tire & Rubber Co | Compositions of vinyl chloride resins and graft copolymers of acrylonitrile-type monomer compositions upon diene polymers and articles formed therefrom |
-
1960
- 1960-08-04 GB GB2713060A patent/GB932852A/en not_active Expired
-
1961
- 1961-07-28 DE DE1961B0063437 patent/DE1291116B/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3686363A (en) * | 1969-12-04 | 1972-08-22 | Stauffer Chemical Co | Polyvinyl chloride-polymethacrylonitrile interpolymer processing air for polyvinyl chloride |
| US3764638A (en) * | 1970-07-09 | 1973-10-09 | Stauffer Chemical Co | Processing aids for polyvinyl chloride and methods for their preparation |
| US4518743A (en) * | 1982-08-04 | 1985-05-21 | Bayer Aktiengesellschaft | Moulding compositions of vinyl chloride polymers, certain copolymers and polymeric plasticisers having a high resistance to ageing |
| WO2002059171A3 (en) * | 2001-01-26 | 2003-08-21 | Univ Pennsylvania | Living radical graft copolymerization of vinyl monomers initiated from the structural defects of polyvinylchloride |
| US6838535B2 (en) | 2001-03-23 | 2005-01-04 | University Of Pennsylvania | Process for the living radical polymerization of chlorine containing monomers |
| US6911515B2 (en) | 2001-03-23 | 2005-06-28 | University Of Pennsylvania | Aqueous room temperature living radical polymerization of vinyl halides |
| US7026420B2 (en) | 2001-03-23 | 2006-04-11 | University Of Pennsylvania | Aqueous room temperature living radical polymerization of vinyl halides |
| US7345127B2 (en) | 2001-03-23 | 2008-03-18 | University Of Pennsylvania | Living radical polymerization of halogen-containing and acrylic monomers and the formation of block copolymers therefrom |
| US7470762B2 (en) | 2001-03-23 | 2008-12-30 | University Of Pennsylvania | Living radical polymerization of acrylic monomers and the formation of block copolymers therefrom |
| CN104725569A (en) * | 2015-04-02 | 2015-06-24 | 马清洪 | PVC (polyvinyl chloride) processing modifying assistant and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1291116B (en) | 1969-03-20 |
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