GB920860A - Surface treatment of films and other polymeric shaped structures - Google Patents
Surface treatment of films and other polymeric shaped structuresInfo
- Publication number
- GB920860A GB920860A GB2162361A GB2162361A GB920860A GB 920860 A GB920860 A GB 920860A GB 2162361 A GB2162361 A GB 2162361A GB 2162361 A GB2162361 A GB 2162361A GB 920860 A GB920860 A GB 920860A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl
- resins
- organic compound
- polymeric
- styrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004381 surface treatment Methods 0.000 title 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 8
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 7
- 150000002894 organic compounds Chemical class 0.000 abstract 6
- 229920005989 resin Polymers 0.000 abstract 6
- 239000011347 resin Substances 0.000 abstract 6
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 abstract 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 4
- FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 abstract 4
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 abstract 4
- -1 ethylene, propylene Chemical group 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- 229920000642 polymer Polymers 0.000 abstract 3
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 abstract 2
- KTZVZZJJVJQZHV-UHFFFAOYSA-N 1-chloro-4-ethenylbenzene Chemical compound ClC1=CC=C(C=C)C=C1 KTZVZZJJVJQZHV-UHFFFAOYSA-N 0.000 abstract 2
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 abstract 2
- MBDUIEKYVPVZJH-UHFFFAOYSA-N 1-ethylsulfonylethane Chemical compound CCS(=O)(=O)CC MBDUIEKYVPVZJH-UHFFFAOYSA-N 0.000 abstract 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 abstract 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 abstract 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 2
- LLLVZDVNHNWSDS-UHFFFAOYSA-N 4-methylidene-3,5-dioxabicyclo[5.2.2]undeca-1(9),7,10-triene-2,6-dione Chemical compound C1(C2=CC=C(C(=O)OC(=C)O1)C=C2)=O LLLVZDVNHNWSDS-UHFFFAOYSA-N 0.000 abstract 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 229920000877 Melamine resin Polymers 0.000 abstract 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 2
- 229920001807 Urea-formaldehyde Polymers 0.000 abstract 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 2
- 150000001241 acetals Chemical class 0.000 abstract 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 abstract 2
- 150000001408 amides Chemical class 0.000 abstract 2
- 239000001569 carbon dioxide Substances 0.000 abstract 2
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 2
- 239000012159 carrier gas Substances 0.000 abstract 2
- 229920002301 cellulose acetate Polymers 0.000 abstract 2
- 229920003086 cellulose ether Polymers 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 239000011248 coating agent Substances 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 2
- 238000010494 dissociation reaction Methods 0.000 abstract 2
- 230000005593 dissociations Effects 0.000 abstract 2
- 239000003822 epoxy resin Substances 0.000 abstract 2
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 abstract 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 239000004615 ingredient Substances 0.000 abstract 2
- 239000012948 isocyanate Substances 0.000 abstract 2
- 150000002513 isocyanates Chemical class 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 2
- 229910052753 mercury Inorganic materials 0.000 abstract 2
- 150000002734 metacrylic acid derivatives Chemical class 0.000 abstract 2
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 abstract 2
- 229920003023 plastic Polymers 0.000 abstract 2
- 239000004033 plastic Substances 0.000 abstract 2
- 229920000647 polyepoxide Polymers 0.000 abstract 2
- 102000004169 proteins and genes Human genes 0.000 abstract 2
- 108090000623 proteins and genes Proteins 0.000 abstract 2
- 239000004627 regenerated cellulose Substances 0.000 abstract 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 abstract 2
- 150000003673 urethanes Chemical class 0.000 abstract 2
- 239000008096 xylene Substances 0.000 abstract 2
- KPAPHODVWOVUJL-UHFFFAOYSA-N 1-benzofuran;1h-indene Chemical compound C1=CC=C2CC=CC2=C1.C1=CC=C2OC=CC2=C1 KPAPHODVWOVUJL-UHFFFAOYSA-N 0.000 abstract 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- MKHQGHBXHQUJHN-UHFFFAOYSA-N cyclohexane;tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl.C1CCCCC1 MKHQGHBXHQUJHN-UHFFFAOYSA-N 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 abstract 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
- B29C59/10—Surface shaping of articles, e.g. embossing; Apparatus therefor by electric discharge treatment
- B29C59/12—Surface shaping of articles, e.g. embossing; Apparatus therefor by electric discharge treatment in an environment other than air
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/36—After-treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Toxicology (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Abstract
A process for modifying the surface characteristics of films and other polymeric shaped structures to improve, for example, their receptiveness to dyes and their adhesiveness, comprises subjecting the surface of such a structure to the action of an electrical discharge having an energy level below 15 electron volts in a gaseous atmosphere containing as an essential ingredient the vapour of an organic compound having a vapour pressure of at least 1 mm. of mercury at 60 DEG C., said organic compound being a polymerizable compound, a non-polymerizable organic compound having replaceable hydrogen atoms, or a perhalohydrocarbon having a bond dissociation energy for the carbon-halogen bond below 100 kilo-calories. The surface is preferably exposed to the discharge for at least 1x10-5 second by passing the structure, preferably a film, or foamed structure, between spaced positive and negative electrodes with a gap of 0,005 to 0,25 inch. The voltage may be from 100 to 100,000, the frequency from 60 to 500,000 cycles per second, and the current from 0,3 to 2,1 RF amperes. Specified polymeric materials are the polymers or polycondensates of perfluorocarbons (e.g. tetrafluoroethylene/hexafluoropropene copolymer), vinyl fluoride, vinylidene fluoride, vinyl chloride, vinylidene chloride, vinyl acetate, ethylene, propylene, butene-1, styrene, ethylene terephthalate, amides, acrylates, methacrylates, acetals, spiroacetals, urethanes and carbonates; regenerated cellulose, cellulose acetate and cellulose ethers; coumaroneindene resins, epoxy resins, phenol-aldehyde resins, urea-formaldehyde resins, melamineformaldehyde resins, isocyanate resins and protein plastics. The organic agent may be glycidyl methacrylate, methyl methacrylate, acrylonitrile, cyclopentadiene, styrene, p-chlorostyrene, vinyl butyl ether, methyl vinyl ketone, vinyl acetate, 1-hexene and N-vinyl-2-pyrrolidone; xylene, hexane, cyclohexane, carbon tetrachloride, chloroform, tetrahydrofurane, diethylsulphone and tetraisopropyl titanate. Nitrogen or carbon dioxide may also be present as a carrier gas. The flow of the carrier gas/organic vapour mixture to the electrodes may be 1/2 to 10 cubic feet per minute. The permanency of the adhesiveness effect produced on the surfaces of perfluorocarbon polymer structures by the process of the invention is greatly improved by heating the surfaces to at least 150 DEG C. for at least one hour and/or by coating the freshly treated surfaces with a polymeric, and preferably an adhesive polymeric, coating. The heat treatment may also be used to restore the adhesiveness of the electrically treated surfaces after prolonged storage of the structures before use. Specification 829,600 is referred to.ALSO:A process for modifying the surface characteristics of polymeric shaped structures comprises subjecting the surface of such a structure to the action of an electrical discharge having an energy level below 15 electrons volts in a gaseous atmosphere containing as an essential ingredient the vapour of an organic compound having a vapour pressure of at least 1 mm. of mercury at 60 DEG C, said organic compound being a polymerizable compound, a non-polymerizable organic compound having replaceable hydrogen atoms, or a perhalohydrocarbon having a bond dissociation energy for the carbon halogen bond below 100 Kilocalories. The surface is preferably exposed to the discharge for at least 1 X 10-5 second by passing the structure, preferably a film between spaced electrodes with a gap of 0,005 to 0,25 inch. The voltage may be from 100 to 100,000 and frequencies from 60 to 500,000 cycles per second, and the current from 0,3 to 2,1 RF amperes. Specified polymeric material are the polymers of perfluorocarbons, vinyl fluoride, vinylidene fluoride, vinyl chloride, vinylidene chloride, vinyl acetate, ethylene, propylene, butene-1, styrene, ethylene terephthalate, amides, acrylates, methacrylates, acetals, spiroacetals, urethanes and carbonates; regenerated cellulose, cellulose acetate and cellulose ethers; counarone indene resins, epoxy resins, phenolaldehyde resins, urea-formaldehyde resins, melamine formaldehyde resins, isocyanate resins and protein plastics. The organic agent may be glycidyl methacrylate, methyl methacrylate, acrylonitrile, cyclopentadine, styrene, p-chlorostyrene, vinyl butyl ether, methyl vinyl ketone, vinyl acetate, 1-hexane and N-vinyl-2-pyroolidone; xylene, hexane, cyclohexane carbon tetrachloride, chloroform, tetrahydrofurane, diethylsulphone and tetraisopropyl titanate. Nitrogen or carbon dioxide may also be present.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US3640760A | 1960-06-15 | 1960-06-15 | |
| US9233061A | 1961-02-28 | 1961-02-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB920860A true GB920860A (en) | 1963-03-13 |
Family
ID=26713151
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2162361A Expired GB920860A (en) | 1960-06-15 | 1961-06-15 | Surface treatment of films and other polymeric shaped structures |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE604952A (en) |
| DE (1) | DE1290717C2 (en) |
| FR (1) | FR1296789A (en) |
| GB (1) | GB920860A (en) |
| NL (1) | NL265914A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3333032A (en) * | 1963-11-12 | 1967-07-25 | Union Carbide Corp | Treated polymer surfaces of shaped articles |
| FR2210492A1 (en) * | 1972-12-15 | 1974-07-12 | Teijin Ltd | |
| US4527969A (en) * | 1982-05-25 | 1985-07-09 | Softal Electronic Gmbh | Apparatus for the electric pretreatment of non-conductive foils |
| US4845132A (en) * | 1986-05-07 | 1989-07-04 | Agency Of Industrial Science And Technology | Hydrophilic porous membrane, method for production thereof, and plasma separator using said membrane |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL290497A (en) * | 1962-03-21 | |||
| FR2578176B1 (en) * | 1985-03-04 | 1989-01-13 | Electricite De France | PROCESS AND DEVICE FOR TREATING A FLAT SUBSTRATE BY CROWN DISCHARGE. |
| DE3908418C2 (en) * | 1989-03-15 | 1999-06-02 | Buck Chem Tech Werke | Process for the internal coating of plastic containers and device for coating |
| US5916404A (en) * | 1992-01-06 | 1999-06-29 | Pilot Industries, Inc. | Fluoropolymer composite tube and method of preparation |
| US5759329A (en) * | 1992-01-06 | 1998-06-02 | Pilot Industries, Inc. | Fluoropolymer composite tube and method of preparation |
| JPH085167B2 (en) * | 1992-01-06 | 1996-01-24 | パイロット インダストリーズ、インコーポレイテッド | Fluoropolymer composite tube and method of manufacturing the same |
| US6517657B1 (en) | 1992-01-06 | 2003-02-11 | Pilot Industries, Inc. | Fluoropolymer composite tube and method of preparation |
| JPH05318553A (en) * | 1992-05-26 | 1993-12-03 | Daikin Ind Ltd | Tubular laminate and production thereof |
| DE19802740A1 (en) * | 1998-01-26 | 1999-07-29 | Leybold Systems Gmbh | Process for treating surfaces of plastic substrates |
| DE60011544T2 (en) * | 1999-10-28 | 2005-09-15 | Bridgestone Corp. | Process for the surface treatment and lamination of a fluorine-containing resin |
| DE10017846C2 (en) * | 2000-04-11 | 2002-03-14 | Fraunhofer Ges Forschung | Method of depositing and using a polymer layer |
-
1961
- 1961-06-13 BE BE604952A patent/BE604952A/xx unknown
- 1961-06-14 NL NL265914A patent/NL265914A/xx unknown
- 1961-06-14 FR FR864955A patent/FR1296789A/en not_active Expired
- 1961-06-15 DE DE1961P0027362 patent/DE1290717C2/en not_active Expired
- 1961-06-15 GB GB2162361A patent/GB920860A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3333032A (en) * | 1963-11-12 | 1967-07-25 | Union Carbide Corp | Treated polymer surfaces of shaped articles |
| FR2210492A1 (en) * | 1972-12-15 | 1974-07-12 | Teijin Ltd | |
| US4527969A (en) * | 1982-05-25 | 1985-07-09 | Softal Electronic Gmbh | Apparatus for the electric pretreatment of non-conductive foils |
| US4845132A (en) * | 1986-05-07 | 1989-07-04 | Agency Of Industrial Science And Technology | Hydrophilic porous membrane, method for production thereof, and plasma separator using said membrane |
Also Published As
| Publication number | Publication date |
|---|---|
| BE604952A (en) | 1961-12-13 |
| DE1290717C2 (en) | 1973-11-15 |
| DE1290717B (en) | 1969-03-13 |
| FR1296789A (en) | 1962-06-22 |
| NL265914A (en) | 1964-07-10 |
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