GB926037A - Improvements in or relating to the treatment of epoxy resins - Google Patents
Improvements in or relating to the treatment of epoxy resinsInfo
- Publication number
- GB926037A GB926037A GB4208359A GB4208359A GB926037A GB 926037 A GB926037 A GB 926037A GB 4208359 A GB4208359 A GB 4208359A GB 4208359 A GB4208359 A GB 4208359A GB 926037 A GB926037 A GB 926037A
- Authority
- GB
- United Kingdom
- Prior art keywords
- epoxy resin
- treated
- borate
- silicate
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4078—Curing agents not provided for by the groups C08G59/42 - C08G59/66 boron containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4085—Curing agents not provided for by the groups C08G59/42 - C08G59/66 silicon containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Insulating Of Coils (AREA)
- Manufacture Of Motors, Generators (AREA)
- Organic Insulating Materials (AREA)
Abstract
A treatment of epoxy resins prior to hardening comprises evacuating at a temperature of 80 DEG to 180 DEG C. and at a pressure of less than 5 mm. Hg. an epoxy resin which contains not more than one hydroxyl group in the molecule and has an epoxy equivalent of between 165 and 400, restoring normal pressure, and stirring into the hot melt 0,1 to 40 parts per 100 parts by weight of resin of a trialkyl borate or tetraalkyl orthosilicate, whereupon the vacuum treatment is repeated to remove the volatile reaction products of epoxy resin and borate or silicate. Specified reactants are the tri-methyl, ethyl, propyl, isobutyl and isoamyl borates, and methyl and ethyl orthosilicates. In the reaction, the alcohol is given off and a glycidyl polyether borate or silicate is formed. The latter will harden only after the addition of hardening agents. In the examples, glycidyl polyethers are treated as above and are hardened in (4) with dodecenyl succinic anhydride, (5) with hexahydrophthalic anhydride, and ground quartz added, to form coatings, and (6) with hexahydrophthalic anhydride and used to impregnate mica-glass fabric insulation. Specification 819,191 is referred to.ALSO:For the preparation of a temperature-resistant, high-voltage insulation, several layers of an absorptive mica-glass fabric strip are wound around the copper conductor and dried at 140 DEG C. under 0,1 mm. pressure; the temperature is reduced to 60 DEG C. and the wrapping is vacuum impregnated with a preheated mixture of a treated epoxy resin and hexahydrophthalic anhydride hardener. The epoxy resin is one which has been treated by reacting with tetraethyl silicate (see Group IV(a)). After restoring normal pressure, the impregnated layer is calibrated to size by pressing on all sides and is then cured at 170 DEG C. Specification 819,191 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH6717458 | 1958-12-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB926037A true GB926037A (en) | 1963-05-15 |
Family
ID=4527720
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4208359A Expired GB926037A (en) | 1958-12-11 | 1959-12-10 | Improvements in or relating to the treatment of epoxy resins |
Country Status (4)
| Country | Link |
|---|---|
| ES (1) | ES253754A1 (en) |
| FR (1) | FR1243142A (en) |
| GB (1) | GB926037A (en) |
| NL (1) | NL246167A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0079857A1 (en) * | 1981-11-13 | 1983-05-25 | Ciba-Geigy Ag | Process for increasing the viscosity of mixtures containing epoxy resins |
| GB2173524A (en) * | 1985-04-13 | 1986-10-15 | Matsushita Electric Works Ltd | Resin-impregnated base and method of manufacturing same |
| US5346939A (en) * | 1993-01-25 | 1994-09-13 | Minnesota Mining And Manufacturing Company | Water curable resin compositions |
| US5364693A (en) * | 1993-01-25 | 1994-11-15 | Minnesota Mining And Manufacturing Company | Orthopedic support materials |
| CN117255474A (en) * | 2023-09-26 | 2023-12-19 | 广东格斯泰科技有限公司 | A high-temperature resistant resin-based copper foil laminate and its preparation method |
-
0
- NL NL246167D patent/NL246167A/xx unknown
-
1959
- 1959-11-27 ES ES0253754A patent/ES253754A1/en not_active Expired
- 1959-12-10 GB GB4208359A patent/GB926037A/en not_active Expired
- 1959-12-11 FR FR812845A patent/FR1243142A/en not_active Expired
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0079857A1 (en) * | 1981-11-13 | 1983-05-25 | Ciba-Geigy Ag | Process for increasing the viscosity of mixtures containing epoxy resins |
| US4431756A (en) * | 1981-11-13 | 1984-02-14 | Ciba-Geigy Corporation | Method of increasing the viscosity of epoxide resin compositions |
| GB2173524A (en) * | 1985-04-13 | 1986-10-15 | Matsushita Electric Works Ltd | Resin-impregnated base and method of manufacturing same |
| US4738890A (en) * | 1985-04-13 | 1988-04-19 | Matsushita Electric Works, Ltd. | Resin-impregnated base and method of manufacturing same |
| GB2173524B (en) * | 1985-04-13 | 1989-09-20 | Matsushita Electric Works Ltd | Resin-impregnated base and method of manufacturing same |
| US5346939A (en) * | 1993-01-25 | 1994-09-13 | Minnesota Mining And Manufacturing Company | Water curable resin compositions |
| US5364693A (en) * | 1993-01-25 | 1994-11-15 | Minnesota Mining And Manufacturing Company | Orthopedic support materials |
| CN117255474A (en) * | 2023-09-26 | 2023-12-19 | 广东格斯泰科技有限公司 | A high-temperature resistant resin-based copper foil laminate and its preparation method |
| CN117255474B (en) * | 2023-09-26 | 2024-03-26 | 广东格斯泰科技有限公司 | High-temperature-resistant resin-based copper-clad laminate and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1243142A (en) | 1960-10-07 |
| ES253754A1 (en) | 1960-05-01 |
| NL246167A (en) |
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