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GB917091A - Improvements in or relating to the catalytic isomerization of hydrocarbons - Google Patents

Improvements in or relating to the catalytic isomerization of hydrocarbons

Info

Publication number
GB917091A
GB917091A GB32196/61A GB3219661A GB917091A GB 917091 A GB917091 A GB 917091A GB 32196/61 A GB32196/61 A GB 32196/61A GB 3219661 A GB3219661 A GB 3219661A GB 917091 A GB917091 A GB 917091A
Authority
GB
United Kingdom
Prior art keywords
feed
sulphur
fraction
vol
added
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB32196/61A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Publication of GB917091A publication Critical patent/GB917091A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/13—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation with simultaneous isomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2778—Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2778—Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C07C5/2781—Acids of sulfur; Salts thereof; Sulfur oxides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/04—Sulfides
    • C07C2527/043—Sulfides with iron group metals or platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/04—Sulfides
    • C07C2527/047—Sulfides with chromium, molybdenum, tungsten or polonium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

In the isomerization of olefins as described in the parent Specification there is added to the feed a sulphur-containing petroleum which is simultaneously desulphurized. The reaction is effected at 100 DEG -500 DEG C., 10-100 atmospheres and 0,5-20 vol./vol./hr. over a solid acidic catalyst carrying one or more sulphides, selenides, tellurides, antimonides and/or arsenides of a Group VI and/or VIII metal. The petroleum fraction may boil in the range 0 DEG -250 DEG C. and contain 0,01-0,5% sulphur. If of different boiling range from the olefinic feed, it may be separated from the product by fractional distillation or condensation.ALSO:In the production of branched chain hydrocarbons as in the parent Specification in which a feed containing unbranched or sparsely branched olefins is contacted at elevated temperature and pressure with hydrogen and a solid acidic isomerisation catalyst carrying one or more sulphides, selenides, tellurides, antimonides and/or arsenides of Group VIa and/or Group VIII metals, there is added to the feed sulphur or a compound thereof which is vaporizable and readily decomposed under the reaction conditions. Suitable compounds of sulphur are hydrogen sulphide, alkyl mercaptans, dialkyl sulphides and dialkyl disulphides, the amount of sulphur added being 0.001-1% by weight of the feed. In a preferred form there is added a petroleum fraction containing 0.01-0.5% sulphur and boiling in the range 0-250 DEG C., preferably in an amount such that the weight ratio to olefinic feed is 0.005-0.1 times the difference between the bromine numbers of the olefinic feed and the fraction. Preferably this fraction is heated to 10-100 DEG C. above the reaction starting temperature and the olefinic feed heated by mixing. The fraction is simultaneously desulphurised and, if of different boiling range from the olefinic feed, may be separated from the product by fractional distillation or condensation and subjected to reforming. Alternatively the mixed product may be used as such as a motor fuel. The olefinic feed may be a gasoline obtained by thermal reforming or thermal or catalytic cracking and is treated at 100-500 DEG C., 10-100 atmospheres and 0.5-20 vol./vol./hr. The product is generally saturated, and specific olefins may be converted to products having a different number of carbon atoms.
GB32196/61A 1960-09-09 1961-09-07 Improvements in or relating to the catalytic isomerization of hydrocarbons Expired GB917091A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL255780 1960-09-09
NL260563 1961-01-27

Publications (1)

Publication Number Publication Date
GB917091A true GB917091A (en) 1963-01-30

Family

ID=26641732

Family Applications (1)

Application Number Title Priority Date Filing Date
GB32196/61A Expired GB917091A (en) 1960-09-09 1961-09-07 Improvements in or relating to the catalytic isomerization of hydrocarbons

Country Status (3)

Country Link
US (1) US3156640A (en)
DE (1) DE1443121A1 (en)
GB (1) GB917091A (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3434961A (en) * 1967-07-14 1969-03-25 Exxon Research Engineering Co Production of liquefied petroleum gas from olefin hydrogenation during catalytic reforming
US5288393A (en) * 1990-12-13 1994-02-22 Union Oil Company Of California Gasoline fuel
EP0980908A1 (en) 1998-08-15 2000-02-23 ENITECNOLOGIE S.p.a. Process and catalysts for upgrading of hydrocarbons boiling in the naphtha range
IT1304792B1 (en) * 1998-12-22 2001-03-29 Agip Petroli CATALYTIC COMPOSITION FOR THE UPGRADING OF HYDROCARBONS WITH POINT BOILING IN THE NAFTA INTERVAL.
IT1312337B1 (en) * 1999-05-07 2002-04-15 Agip Petroli CATALYTIC COMPOSITION FOR UPGRADING OF HYDROCARBONS WITH BOILING POINTS IN THE NAFTA INTERVAL

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2905636A (en) * 1957-06-27 1959-09-22 Universal Oil Prod Co Manufacture and use of supported molybdenum-containing catalysts
US3011971A (en) * 1958-09-05 1961-12-05 Kellogg M W Co Hydrodesulfurizing dissimilar hydrocarbons
US3016348A (en) * 1959-11-02 1962-01-09 Universal Oil Prod Co Manufacture and use of sulfided hydrocarbon purification catalyst

Also Published As

Publication number Publication date
US3156640A (en) 1964-11-10
DE1443121A1 (en) 1968-10-31

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