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GB903701A - Polymeric materials - Google Patents

Polymeric materials

Info

Publication number
GB903701A
GB903701A GB3281/60A GB328160A GB903701A GB 903701 A GB903701 A GB 903701A GB 3281/60 A GB3281/60 A GB 3281/60A GB 328160 A GB328160 A GB 328160A GB 903701 A GB903701 A GB 903701A
Authority
GB
United Kingdom
Prior art keywords
oil
vinyl
group
phosphorus
esters
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3281/60A
Inventor
Peter Kirby
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Research Ltd
Original Assignee
Shell Research Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL260549D priority Critical patent/NL260549A/xx
Priority to NL269800D priority patent/NL269800A/xx
Priority to BE599594D priority patent/BE599594A/xx
Priority to BE608759D priority patent/BE608759A/xx
Application filed by Shell Research Ltd filed Critical Shell Research Ltd
Priority to GB3281/60A priority patent/GB903701A/en
Priority to US60305A priority patent/US3160593A/en
Priority to US60303A priority patent/US3166505A/en
Priority to DES72257A priority patent/DE1124620B/en
Priority to FR851125A priority patent/FR1281579A/en
Priority to FR874742A priority patent/FR80808E/en
Priority to GB35536/61A priority patent/GB948528A/en
Publication of GB903701A publication Critical patent/GB903701A/en
Priority to US400194A priority patent/US3239492A/en
Priority to US411142A priority patent/US3243417A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M153/00—Lubricating compositions characterised by the additive being a macromolecular compound containing phosphorus
    • C10M153/02—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C—CHEMISTRY; METALLURGY
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/09—Esters of phosphoric acids
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/32—Esters thereof
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
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    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
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    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
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    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
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    • C07F9/657181—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms the ring phosphorus atom being bound to at least one carbon atom the ring phosphorus atom and, at least, one ring oxygen atom being part of a (thio)phosphonic acid derivative
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    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
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    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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    • C08F30/00—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
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    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
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    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
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    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
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    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
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    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
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    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C10M2223/065—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds containing sulfur
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    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/12—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy
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    • C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
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    • C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2225/02—Macromolecular compounds from phosphorus-containg monomers, obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
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    • C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
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    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
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    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
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    • C10N2010/12—Groups 6 or 16
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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    • C10N2040/02—Bearings
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    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/135—Steam engines or turbines
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    • C10N2040/25—Internal-combustion engines
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    • C10N2040/00—Specified use or application for which the lubricating composition is intended
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    • C10N2040/251—Alcohol-fuelled engines
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    • C10N2040/255—Gasoline engines
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    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives

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  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A composition for adding to lubricating oil comprises a copolymer of an alkenyl-substituted organo-phosphorus compound containing a phosphinylidene group: ­ P -->O and at least one polymerizable mono-olefinically unsaturated compound having no phosphorus atoms in the molecule, at least one of the components of the polymer having an oleophilic hydrocarbon chain of at least 8 carbon atoms, the ratio of monomers lying between 1:20 and 20:1. The lubricating oil can be any natural or synthetic oil having lubricating properties. It can be a hydro-carbon oil obtained from paraffinic or naphthenic crude, or mixtures thereof. The oil may also be blended with fatty oils such as castor oil or lard oil, and/or with synthetic oils such as polymerized olefins, copolymers of alkylene glycols and alkylene oxides, organic esters (such as dioctyl sebacate, dioctyl phthalate and trioctyl phosphate and polyalkyl silicone polymers. The composition is present in a minor proportion by weight, generally from 0,01% to 20% by weight. Minor proportions of other additives such as methacrylate polymers, metal dithiophosphates, metal organic sulphonates, metal thiocarbamates, amines, alkylated phenols and bisphenols or organic sulphides may be added.ALSO:A composition for adding to lubricating oil (see Group III) comprises a copolymer of an alkenyl-substituted organo-phosphorus compound containing a phosphinylidene group (­P-->O) and at least one polymerizable mono-olefinically unsaturated compound having no phosphorus atoms in the molecule, at least one of the components of the copolymer having an oleophilic hydrocarbon chain of at least 8 carbon atoms, the ratio of monomers lying between 20:1 and 1:20. The phosphoruscontaining compound may have the formula <FORM:0903701/IV(a)/1> or <FORM:0903701/IV(a)/2> wherein at least one of the groups R1, R2 or R3 is an alkenyl or cycloalkenyl group and the other group(s) is (are) hydrogen or an unsubstituted or substituted alkyl, cycloalkyl, aryl, aralkyl or alkaryl radical. The copolymerizable monomer may be acrylic acid and a -substituted acrylic acids and their derivatives such as esters, nitriles and amides, vinyl esters, vinyl ethers, vinyl ketones, vinyl aryl compounds, vinyl halides, allyl esters, ethers and ketones, a ,b -unsaturated polycarboxylic acids and derivatives, a -olefins, vinyl pyridines and vinyl lactams. The monomer not containing phosphorus preferably has a straight chain with more than 8 carbon atoms. The polymerization catalyst can be a peroxide, azo compound, sodium bisulphite, diethyl sulphoxide, ammonium persulphate or sodium perborate. Polymerization can be carried out in the presence or absence of an inert solvent under a blanket of an inert gas. In the examples, lauryl methacrylate is polymerized with a variety of monomers. Other additives can be added to the oil.
GB3281/60A 1960-01-29 1960-01-29 Polymeric materials Expired GB903701A (en)

Priority Applications (13)

Application Number Priority Date Filing Date Title
NL260549D NL260549A (en) 1960-01-29
NL269800D NL269800A (en) 1960-01-29
BE599594D BE599594A (en) 1960-01-29
BE608759D BE608759A (en) 1960-01-29
GB3281/60A GB903701A (en) 1960-01-29 1960-01-29 Polymeric materials
US60305A US3160593A (en) 1960-01-29 1960-10-04 Mineral oil compositions
US60303A US3166505A (en) 1960-01-29 1960-10-04 Copolymers of dialkenyl phosphorus esters as lubricating oil additives
DES72257A DE1124620B (en) 1960-01-29 1961-01-27 Lubricating oil preparation
FR851125A FR1281579A (en) 1960-01-29 1961-01-30 New phosphorus polymer compounds
FR874742A FR80808E (en) 1960-01-29 1961-10-02 New phosphorus polymer compounds
GB35536/61A GB948528A (en) 1960-01-29 1961-10-02 Polymerization process
US400194A US3239492A (en) 1960-01-29 1964-09-29 Linear cyclic phosphorus-containing polymers
US411142A US3243417A (en) 1960-01-29 1964-11-13 Polymers of alkenyl phosphorus esters

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3281/60A GB903701A (en) 1960-01-29 1960-01-29 Polymeric materials

Publications (1)

Publication Number Publication Date
GB903701A true GB903701A (en) 1962-08-15

Family

ID=9755375

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3281/60A Expired GB903701A (en) 1960-01-29 1960-01-29 Polymeric materials

Country Status (1)

Country Link
GB (1) GB903701A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3426004A (en) * 1965-01-13 1969-02-04 Goodrich Co B F Crosslinked acrylic acid interpolymers
US5478368A (en) * 1990-04-19 1995-12-26 Exxon Chemical Patents Inc. Additives for distillate fuels and distillate fuels containing them
US5593466A (en) * 1985-09-06 1997-01-14 Exxon Chemical Patents Inc Oil and fuel oil compositions
US7579305B2 (en) 2002-03-27 2009-08-25 Sanyo Chemical Industries, Ltd. Friction regulator for lubricating oil and lubricating oil composition
EP1860175A3 (en) * 2006-05-23 2009-09-23 Shell Internationale Researchmaatschappij B.V. Lubricating oil composition
WO2012159828A1 (en) * 2011-05-24 2012-11-29 Evonik Rohmax Additives Gmbh Lubricant composition with phosphorus-functionalized polymers

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3426004A (en) * 1965-01-13 1969-02-04 Goodrich Co B F Crosslinked acrylic acid interpolymers
US5593466A (en) * 1985-09-06 1997-01-14 Exxon Chemical Patents Inc Oil and fuel oil compositions
US5478368A (en) * 1990-04-19 1995-12-26 Exxon Chemical Patents Inc. Additives for distillate fuels and distillate fuels containing them
US7579305B2 (en) 2002-03-27 2009-08-25 Sanyo Chemical Industries, Ltd. Friction regulator for lubricating oil and lubricating oil composition
EP1860175A3 (en) * 2006-05-23 2009-09-23 Shell Internationale Researchmaatschappij B.V. Lubricating oil composition
WO2012159828A1 (en) * 2011-05-24 2012-11-29 Evonik Rohmax Additives Gmbh Lubricant composition with phosphorus-functionalized polymers
US9914896B2 (en) 2011-05-24 2018-03-13 Evonik Oil Additives Gmbh Lubricant composition with phosphorus-functionalized polymers

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